-------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 1 converged, 1 successes so far. Misfit function evaluations this try => 123 Misfit this try = 6.240287E-02 Best Misfit so far = 6.240287E-02 obtained on Try 1 Prior probability, PP = 1.012022E-06 Bayes score, PP * exp(-Misfit) = 9.507987E-07 Best Bayes score so far = 9.507987E-07 obtained on Try 1 P_bar T_K C_O2 C_H2O Initial coordinates: 10000.0 900.000 0.500000 0.500000 Final coordinates: 8407.73 911.573 0.433223 0.498539 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.240287E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.014 0.021560 0.002775 0.000000 0.075937 0.006573 0.000000 0.005771 0.286889 0.600494 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.4 -0.1 Chi 5.8E-03 0. 0. 9.6E-04 3.2E-03 0. 1.0E-02 1.4E-04 4.1E-07 Composition Misfit: 2.336344E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.127 0.000000 0.031601 0.000000 0.000000 0.298262 0.040242 0.066765 0.136823 0.426309 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.7 -1. 0.5 -0.2 Chi 0. 3.9E-03 0. 0. 1.9E-03 8.9E-04 2.1E-03 3.6E-04 6.4E-06 Composition Misfit: 9.147273E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.558 0.094623 0.057918 0.000000 0.001418 0.000000 0.000000 0.000000 0.153959 0.692082 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -1.7E-02 0. 0. 0. 0.5 0.1 Chi 9.3E-05 6.9E-04 0. 2.6E-06 0. 0. 0. 3.1E-04 8.5E-06 Composition Misfit: 1.107240E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.581 0.000000 0.000000 0.024440 0.075697 0.198717 0.000953 0.179472 0.135450 0.385271 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.9 0.1 -0.7 0.4 2. Chi 0. 0. 3.9E-04 1.0E-03 1.0E-03 2.3E-04 5.5E-04 1.7E-04 2.4E-03 Composition Misfit: 5.821368E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.953 0.000000 0.000000 0.004565 0.000000 0.150111 0.002716 0.051302 0.427894 0.363411 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.7E-03 0. 2.4E-03 4.6E-04 1.6E-02 1.0E-03 1.4E-03 Composition Misfit: 2.269585E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.340 0.000000 0.000000 0.348488 0.000000 0.630160 0.009647 0.011704 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. -7.4E-03 0.1 -0.3 0. 0. Chi 0. 0. 6.6E-06 0. 4.1E-08 1.3E-05 2.5E-04 0. 0. Composition Misfit: 2.677030E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.107 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.320 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023315 0.014752 0.006980 0.016473 0.052931 0.000919 0.040318 0.029003 0.001433 0.108493 0.705382 Mica 0.017991 0.002316 0.000000 0.063367 0.005485 0.000000 0.004816 0.165033 0.000497 0.239401 0.501094 Gt 0.000000 0.031518 0.000000 0.000000 0.297476 0.040136 0.066589 0.000000 0.002633 0.136462 0.425186 Fsp 0.094623 0.057918 0.000000 0.001418 0.000000 0.000000 0.000000 0.000000 0.000000 0.153959 0.692082 Bio 0.000000 0.000000 0.021599 0.066898 0.175618 0.000842 0.158610 0.112196 0.004046 0.119705 0.340487 St 0.000000 0.000000 0.004152 0.000000 0.136528 0.002471 0.046660 0.088141 0.002344 0.389176 0.330528 Ilm 0.000000 0.000000 0.323947 0.000000 0.585783 0.008968 0.010880 0.000000 0.070421 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -773175. -753097. -930346. -847360. -312474. -466226. -637474. -290538. -409462. -1633781. -885132. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 2 converged, 2 successes so far. Misfit function evaluations this try => 139 Misfit this try = 0.107080 Best Misfit so far = 6.240287E-02 obtained on Try 1 Prior probability, PP = 9.401260E-08 Bayes score, PP * exp(-Misfit) = 8.446597E-08 Best Bayes score so far = 9.507987E-07 obtained on Try 1 P_bar T_K C_O2 C_H2O Initial coordinates: 5474.26 810.966 0.292163 0.731351 Final coordinates: 6962.58 803.361 0.475732 0.492504 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.107080 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.207 0.024647 0.001723 0.000000 0.073803 0.003874 0.000000 0.003752 0.291912 0.600288 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 1. 0. 1. -0.7 -3.7E-02 Chi 8.3E-03 0. 0. 1.5E-03 1.4E-02 0. 2.6E-02 4.5E-04 1.4E-07 Composition Misfit: 5.123696E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.971 0.000000 0.044577 0.000000 0.000000 0.293840 0.052484 0.045215 0.137370 0.426514 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 2. -2. 0.9 0.5 -0.2 Chi 0. 1.3E-02 0. 0. 2.7E-03 6.3E-03 2.0E-03 3.0E-04 8.1E-06 Composition Misfit: 2.431483E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.392 0.095262 0.057983 0.000000 0.000746 0.000000 0.000000 0.000000 0.153992 0.692017 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.4E-04 7.0E-04 0. 5.0E-04 0. 0. 0. 3.1E-04 8.9E-06 Composition Misfit: 1.660682E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.721 0.000000 0.000000 0.020228 0.075079 0.204448 0.000719 0.183581 0.126186 0.389759 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 0.1 -1. -1. 0.2 -1. 1. 1. Chi 0. 0. 6.4E-05 8.8E-04 2.0E-03 6.9E-04 1.1E-03 1.6E-03 1.8E-03 Composition Misfit: 8.007519E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.341 0.000000 0.000000 0.003305 0.000000 0.162631 0.002527 0.038690 0.429208 0.363638 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. 0.3 -2. 1. 1. Chi 0. 0. 4.9E-03 0. 6.1E-03 6.8E-04 6.4E-03 8.7E-04 1.4E-03 Composition Misfit: 2.042834E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.509 0.000000 0.000000 0.361886 0.000000 0.621237 0.009441 0.007435 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.7 0. 0.4 0.1 0.4 0. 0. Chi 0. 0. 3.9E-04 0. 1.2E-04 3.3E-05 8.8E-04 0. 0. Composition Misfit: 1.431800E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.875 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.984 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023320 0.014755 0.006982 0.016477 0.052943 0.000919 0.040327 0.028658 0.001574 0.108516 0.705530 Mica 0.020557 0.001437 0.000000 0.061554 0.003231 0.000000 0.003130 0.165658 0.000310 0.243464 0.500659 Gt 0.000000 0.044470 0.000000 0.000000 0.293136 0.052358 0.045107 0.000000 0.002395 0.137042 0.425493 Fsp 0.095262 0.057983 0.000000 0.000746 0.000000 0.000000 0.000000 0.000000 0.000000 0.153992 0.692017 Bio 0.000000 0.000000 0.017826 0.066164 0.180172 0.000634 0.161783 0.114503 0.004234 0.111203 0.343481 St 0.000000 0.000000 0.003006 0.000000 0.147920 0.002299 0.035191 0.088199 0.002253 0.390385 0.330746 Ilm 0.000000 0.000000 0.338510 0.000000 0.581108 0.008831 0.006955 0.000000 0.064596 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -754513. -742379. -920233. -828955. -301285. -452171. -630382. -283970. -407481. -1620540. -877253. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 5 converged, 3 successes so far. Misfit function evaluations this try => 236 Misfit this try = 7.033102E-02 Best Misfit so far = 6.240287E-02 obtained on Try 1 Prior probability, PP = 1.001690E-06 Bayes score, PP * exp(-Misfit) = 9.336605E-07 Best Bayes score so far = 9.507987E-07 obtained on Try 1 P_bar T_K C_O2 C_H2O Initial coordinates: 5786.75 982.261 0.769568 0.803342 Final coordinates: 8849.23 925.878 0.472739 0.602186 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.025844E-2 Extraneous predicted phases: 7.257222E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.074 0.022539 0.003316 0.000000 0.074623 0.006765 0.000000 0.006283 0.286314 0.600161 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.3 -2.1E-02 Chi 6.6E-03 0. 0. 1.3E-03 2.9E-03 0. 8.4E-03 1.2E-04 4.3E-08 Composition Misfit: 2.255913E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.079 0.000000 0.033285 0.000000 0.000000 0.294190 0.036550 0.073483 0.136358 0.426134 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.3 -2. 0.5 -0.2 Chi 0. 4.9E-03 0. 0. 2.6E-03 1.5E-04 4.8E-03 4.1E-04 5.1E-06 Composition Misfit: 1.280029E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.903 0.094204 0.058725 0.000000 0.001433 0.000000 0.000000 0.000000 0.154363 0.691275 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -2.2E-02 0. 0. 0. 0.5 0.1 Chi 6.9E-05 8.7E-04 0. 3.9E-06 0. 0. 0. 2.8E-04 1.5E-05 Composition Misfit: 1.230463E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.997 0.000000 0.000000 0.024607 0.075628 0.189948 0.000911 0.188656 0.134425 0.385825 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.4 0.1 -1. 0.4 2. Chi 0. 0. 4.3E-04 1.0E-03 1.6E-04 2.9E-04 1.9E-03 2.6E-04 2.4E-03 Composition Misfit: 6.422073E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.869 0.000000 0.000000 0.004861 0.000000 0.144703 0.002552 0.056946 0.427581 0.363356 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.3E-03 0. 1.3E-03 6.5E-04 2.0E-02 1.0E-03 1.4E-03 Composition Misfit: 2.599313E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.423 0.000000 0.000000 0.339013 0.000000 0.638804 0.009165 0.013018 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.6 0. -0.4 0.1 -0.5 0. 0. Chi 0. 0. 3.6E-04 0. 1.2E-04 7.6E-05 7.0E-04 0. 0. Composition Misfit: 1.253354E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.098 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.530 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.026 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000021 -.000021 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023172 0.014662 0.006937 0.016372 0.052607 0.000913 0.040072 0.034818 0.001554 0.107829 0.701063 Mica 0.018810 0.002767 0.000000 0.062276 0.005645 0.000000 0.005244 0.164938 0.000519 0.238941 0.500859 Gt 0.000000 0.033190 0.000000 0.000000 0.293356 0.036446 0.073274 0.000000 0.002835 0.135971 0.424926 Fsp 0.094204 0.058725 0.000000 0.001433 0.000000 0.000000 0.000000 0.000000 0.000000 0.154363 0.691275 Bio 0.000000 0.000000 0.021752 0.066855 0.167913 0.000805 0.166772 0.111958 0.004044 0.118832 0.341068 St 0.000000 0.000000 0.004421 0.000000 0.131608 0.002322 0.051793 0.088127 0.002367 0.388887 0.330475 Ilm 0.000000 0.000000 0.313758 0.000000 0.591215 0.008482 0.012049 0.000000 0.074497 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774688. -753602. -931096. -849178. -313933. -468409. -637811. -290911. -408319. -1635108. -885670. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 6 converged, 4 successes so far. Misfit function evaluations this try => 204 Misfit this try = 6.112505E-02 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.419843E-07 Bayes score, PP * exp(-Misfit) = 8.861299E-07 Best Bayes score so far = 9.507987E-07 obtained on Try 1 P_bar T_K C_O2 C_H2O Initial coordinates: 7316.63 812.575 0.920498 8.210769E-02 Final coordinates: 8615.67 927.205 0.423493 0.497823 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.112505E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.010 0.021231 0.002955 0.000000 0.076113 0.006983 0.000000 0.006056 0.286162 0.600499 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.2E-04 2.5E-03 0. 9.3E-03 1.1E-04 4.2E-07 Composition Misfit: 2.130746E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.202 0.000000 0.030205 0.000000 0.000000 0.299075 0.037760 0.069945 0.136738 0.426277 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.4 -1. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 1.7E-03 3.3E-04 3.3E-03 3.7E-04 6.2E-06 Composition Misfit: 8.815310E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.577 0.094545 0.057829 0.000000 0.001541 0.000000 0.000000 0.000000 0.153914 0.692171 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.9E-05 6.7E-04 0. 2.2E-05 0. 0. 0. 3.2E-04 7.8E-06 Composition Misfit: 1.106816E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.536 0.000000 0.000000 0.025042 0.075772 0.198009 0.000958 0.178885 0.136574 0.384761 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.4E-04 1.0E-03 9.3E-04 2.3E-04 4.9E-04 1.0E-04 2.5E-03 Composition Misfit: 5.840235E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.087 0.000000 0.000000 0.004756 0.000000 0.148409 0.002664 0.053062 0.427726 0.363384 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 5.2E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.351868E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.315 0.000000 0.000000 0.348524 0.000000 0.629531 0.009451 0.012494 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. 2.2E-02 0.1 -0.4 0. 0. Chi 0. 0. 6.2E-06 0. 3.5E-07 3.2E-05 5.0E-04 0. 0. Composition Misfit: 5.365511E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.929 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.344 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023317 0.014753 0.006981 0.016474 0.052935 0.000919 0.040321 0.028963 0.001401 0.108501 0.705434 Mica 0.017718 0.002466 0.000000 0.063519 0.005828 0.000000 0.005054 0.164941 0.000525 0.238812 0.501137 Gt 0.000000 0.030124 0.000000 0.000000 0.298276 0.037659 0.069759 0.000000 0.002670 0.136373 0.425139 Fsp 0.094545 0.057829 0.000000 0.001541 0.000000 0.000000 0.000000 0.000000 0.000000 0.153914 0.692171 Bio 0.000000 0.000000 0.022141 0.066993 0.175069 0.000847 0.158160 0.111846 0.004008 0.120752 0.340185 St 0.000000 0.000000 0.004325 0.000000 0.134981 0.002423 0.048260 0.088134 0.002349 0.389024 0.330504 Ilm 0.000000 0.000000 0.323986 0.000000 0.585208 0.008785 0.011615 0.000000 0.070406 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775939. -754709. -931888. -850085. -314145. -468538. -638555. -291573. -409904. -1635828. -886349. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Bio F sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Bio F sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 10 converged, 5 successes so far. Misfit function evaluations this try => 268 Misfit this try = 0.167341 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 8.520260E-07 Bayes score, PP * exp(-Misfit) = 7.207384E-07 Best Bayes score so far = 9.507987E-07 obtained on Try 1 P_bar T_K C_O2 C_H2O Initial coordinates: 5530.50 824.246 0.951129 0.820856 Final coordinates: 7847.15 887.566 0.732617 0.660581 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.167341 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.613 0.023885 0.002935 0.000000 0.073703 0.005257 0.000000 0.005252 0.289180 0.599789 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 0.9 0. 1. -0.5 2.7E-02 Chi 7.7E-03 0. 0. 1.6E-03 6.6E-03 0. 1.3E-02 2.6E-04 7.4E-08 Composition Misfit: 3.214228E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.154 0.000000 0.033641 0.000000 0.000000 0.269014 0.067323 0.066585 0.137045 0.426392 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 3. -4. -1. 0.5 -0.2 Chi 0. 5.1E-03 0. 0. 1.0E-02 1.6E-02 2.1E-03 3.4E-04 7.1E-06 Composition Misfit: 3.418175E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.622 0.093462 0.060764 0.000000 0.001156 0.000000 0.000000 0.000000 0.155382 0.689236 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.1 -0.9 0. 0.1 0. 0. 0. 0.4 0.2 Chi 3.5E-05 1.4E-03 0. 3.5E-05 0. 0. 0. 2.0E-04 4.0E-05 Composition Misfit: 1.689670E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.806 0.000000 0.000000 0.023142 0.075557 0.182392 0.001444 0.198057 0.133349 0.386059 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.2 -1. 0.1 -5.6E-03 -2. 0.5 2. Chi 0. 0. 1.4E-04 9.8E-04 2.4E-05 2.6E-07 4.1E-03 3.6E-04 2.3E-03 Composition Misfit: 7.931762E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.157 0.000000 0.000000 0.004449 0.000000 0.143475 0.004481 0.056116 0.428041 0.363438 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.9 -0.1 -4. 1. 1. Chi 0. 0. 1.9E-03 0. 1.1E-03 9.2E-05 2.0E-02 9.8E-04 1.4E-03 Composition Misfit: 2.508698E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.715 0.000000 0.000000 0.241212 0.000000 0.737450 0.013577 0.007761 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. -0.6 0.4 0. 0. Chi 0. 0. 4.9E-02 0. 1.6E-02 9.4E-04 6.5E-04 0. 0. Composition Misfit: 6.630829E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.003 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.930 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023075 0.014600 0.006908 0.016303 0.052386 0.000909 0.039903 0.038033 0.002399 0.107374 0.698110 Mica 0.019926 0.002449 0.000000 0.061489 0.004385 0.000000 0.004382 0.165279 0.000441 0.241257 0.500392 Gt 0.000000 0.033556 0.000000 0.000000 0.268332 0.067152 0.066416 0.000000 0.002536 0.136697 0.425310 Fsp 0.093462 0.060764 0.000000 0.001156 0.000000 0.000000 0.000000 0.000000 0.000000 0.155382 0.689236 Bio 0.000000 0.000000 0.020431 0.066704 0.161022 0.001275 0.174851 0.112977 0.004188 0.117725 0.340826 St 0.000000 0.000000 0.004047 0.000000 0.130494 0.004076 0.051038 0.088148 0.002328 0.389313 0.330556 Ilm 0.000000 0.000000 0.213577 0.000000 0.652961 0.012021 0.006872 0.000000 0.114569 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -770258. -751040. -928092. -845379. -310883. -459909. -635531. -288948. -406339. -1631223. -883851. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 11 converged, 6 successes so far. Misfit function evaluations this try => 179 Misfit this try = 6.567302E-02 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.833979E-07 Bayes score, PP * exp(-Misfit) = 9.208902E-07 Best Bayes score so far = 9.507987E-07 obtained on Try 1 P_bar T_K C_O2 C_H2O Initial coordinates: 6554.92 944.454 0.558262 0.470131 Final coordinates: 8209.40 896.996 0.420999 0.505230 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.567302E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.120 0.021937 0.002630 0.000000 0.075695 0.006140 0.000000 0.005497 0.287630 0.600471 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.8 0. 1. -0.4 -0.1 Chi 6.1E-03 0. 0. 1.0E-03 4.1E-03 0. 1.2E-02 1.8E-04 3.7E-07 Composition Misfit: 2.581469E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.049 0.000000 0.032909 0.000000 0.000000 0.297246 0.042677 0.063749 0.137031 0.426387 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -0.9 -0.9 0.5 -0.2 Chi 0. 4.6E-03 0. 0. 2.0E-03 1.7E-03 1.3E-03 3.4E-04 7.0E-06 Composition Misfit: 9.959117E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.521 0.094669 0.058044 0.000000 0.001309 0.000000 0.000000 0.000000 0.154022 0.691956 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. 1.4E-02 0. 0. 0. 0.5 0.1 Chi 9.6E-05 7.2E-04 0. 1.8E-06 0. 0. 0. 3.1E-04 9.4E-06 Composition Misfit: 1.130744E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.529 0.000000 0.000000 0.024000 0.075630 0.199166 0.000948 0.179933 0.134446 0.385879 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. -1. 0.1 -0.7 0.4 2. Chi 0. 0. 2.9E-04 1.0E-03 1.1E-03 2.4E-04 6.0E-04 2.6E-04 2.3E-03 Composition Misfit: 5.811796E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.146 0.000000 0.000000 0.004458 0.000000 0.151413 0.002781 0.049760 0.428127 0.363461 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -3. 1. 1. Chi 0. 0. 1.9E-03 0. 2.7E-03 4.0E-04 1.4E-02 9.7E-04 1.4E-03 Composition Misfit: 2.187577E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.345 0.000000 0.000000 0.363382 0.000000 0.614980 0.010037 0.011602 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.7 0. 0.7 -5.9E-03 -0.3 0. 0. Chi 0. 0. 4.9E-04 0. 3.7E-04 1.3E-07 2.2E-04 0. 0. Composition Misfit: 1.080895E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.973 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.316 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023307 0.014747 0.006978 0.016467 0.052913 0.000918 0.040304 0.029382 0.001392 0.108455 0.705136 Mica 0.018304 0.002195 0.000000 0.063161 0.005123 0.000000 0.004587 0.165125 0.000463 0.240001 0.501040 Gt 0.000000 0.032826 0.000000 0.000000 0.296491 0.042569 0.063587 0.000000 0.002542 0.136683 0.425303 Fsp 0.094669 0.058044 0.000000 0.001309 0.000000 0.000000 0.000000 0.000000 0.000000 0.154022 0.691956 Bio 0.000000 0.000000 0.021205 0.066822 0.175972 0.000837 0.158979 0.112440 0.004013 0.118789 0.340942 St 0.000000 0.000000 0.004054 0.000000 0.137717 0.002529 0.045259 0.088156 0.002299 0.389401 0.330584 Ilm 0.000000 0.000000 0.340147 0.000000 0.575657 0.009395 0.010860 0.000000 0.063941 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -770637. -751611. -928831. -844872. -310935. -464090. -636481. -289590. -409588. -1631911. -884023. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 13 converged, 7 successes so far. Misfit function evaluations this try => 181 Misfit this try = 0.220144 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 1.109170E-06 Bayes score, PP * exp(-Misfit) = 8.900024E-07 Best Bayes score so far = 9.507987E-07 obtained on Try 1 P_bar T_K C_O2 C_H2O Initial coordinates: 13323.5 883.595 0.778514 0.854104 Final coordinates: 9088.85 918.912 0.915457 0.529475 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.220144 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.512 0.024210 0.003533 0.000000 0.072839 0.006665 0.000000 0.006506 0.286365 0.599882 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 0.7 0. 1. -0.3 1.5E-02 Chi 7.9E-03 0. 0. 1.9E-03 3.0E-03 0. 7.6E-03 1.2E-04 2.3E-08 Composition Misfit: 2.407770E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.636 0.000000 0.037214 0.000000 0.000000 0.293270 0.031137 0.077441 0.135228 0.425711 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. 0.3 -2. 0.6 -0.1 Chi 0. 7.5E-03 0. 0. 2.8E-03 3.1E-04 6.6E-03 5.5E-04 2.6E-06 Composition Misfit: 1.774539E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.710 0.094736 0.057907 0.000000 0.001311 0.000000 0.000000 0.000000 0.153953 0.692093 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 1.4E-02 0. 0. 0. 0.5 0.1 Chi 1.0E-04 6.9E-04 0. 1.7E-06 0. 0. 0. 3.1E-04 8.4E-06 Composition Misfit: 1.111588E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.842 0.000000 0.000000 0.022279 0.075379 0.182454 0.000738 0.201475 0.130690 0.386985 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.1 -1. 0.1 0.2 -2. 0.7 2. Chi 0. 0. 3.7E-05 9.4E-04 2.2E-05 6.4E-04 5.1E-03 7.1E-04 2.2E-03 Composition Misfit: 9.588676E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.150 0.000000 0.000000 0.003970 0.000000 0.142288 0.002097 0.061007 0.427402 0.363235 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -0.8 0.4 -5. 1. 1. Chi 0. 0. 2.8E-03 0. 8.9E-04 1.4E-03 2.4E-02 1.0E-03 1.5E-03 Composition Misfit: 3.146177E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.932 0.000000 0.000000 0.206635 0.000000 0.781987 0.004942 0.006435 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 8. 0. -7. 0.8 0.6 0. 0. Chi 0. 0. 0.1 0. 3.0E-02 5.2E-03 2.0E-03 0. 0. Composition Misfit: 0.136158 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.127 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.091 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023236 0.014702 0.006957 0.016417 0.052752 0.000915 0.040182 0.030698 0.003018 0.108126 0.702995 Mica 0.020204 0.002948 0.000000 0.060785 0.005562 0.000000 0.005429 0.164927 0.000552 0.238978 0.500614 Gt 0.000000 0.037090 0.000000 0.000000 0.292294 0.031034 0.077183 0.000000 0.003327 0.134778 0.424294 Fsp 0.094736 0.057907 0.000000 0.001311 0.000000 0.000000 0.000000 0.000000 0.000000 0.153953 0.692093 Bio 0.000000 0.000000 0.019656 0.066503 0.160969 0.000651 0.177751 0.113351 0.004403 0.115301 0.341416 St 0.000000 0.000000 0.003610 0.000000 0.129379 0.001907 0.055472 0.088075 0.002652 0.388625 0.330280 Ilm 0.000000 0.000000 0.180203 0.000000 0.681956 0.004310 0.005612 0.000000 0.127919 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -771915. -751925. -931330. -846764. -312975. -468517. -636489. -289843. -403784. -1633472. -884365. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 14 converged, 8 successes so far. Misfit function evaluations this try => 257 Misfit this try = 0.139645 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.883899E-07 Bayes score, PP * exp(-Misfit) = 8.595696E-07 Best Bayes score so far = 9.507987E-07 obtained on Try 1 P_bar T_K C_O2 C_H2O Initial coordinates: 9090.75 829.673 0.800061 0.729953 Final coordinates: 8884.41 927.720 0.655482 0.497590 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.139645 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.262 0.022237 0.003203 0.000000 0.074956 0.007015 0.000000 0.006351 0.285932 0.600306 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.6 0. 1. -0.3 -3.9E-02 Chi 6.3E-03 0. 0. 1.2E-03 2.4E-03 0. 8.2E-03 1.0E-04 1.6E-07 Composition Misfit: 2.145387E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.460 0.000000 0.032624 0.000000 0.000000 0.297853 0.033575 0.073815 0.136097 0.426036 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. 0.1 -2. 0.6 -0.2 Chi 0. 4.5E-03 0. 0. 1.9E-03 1.3E-05 4.9E-03 4.4E-04 4.5E-06 Composition Misfit: 1.177302E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.290 0.094669 0.057715 0.000000 0.001473 0.000000 0.000000 0.000000 0.153857 0.692285 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -3.3E-02 0. 0. 0. 0.5 0.1 Chi 9.6E-05 6.5E-04 0. 9.1E-06 0. 0. 0. 3.2E-04 7.1E-06 Composition Misfit: 1.083299E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.552 0.000000 0.000000 0.024134 0.075622 0.191851 0.000842 0.187647 0.134337 0.385566 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.5 0.2 -1. 0.4 2. Chi 0. 0. 3.2E-04 9.9E-04 2.8E-04 4.0E-04 1.8E-03 2.7E-04 2.4E-03 Composition Misfit: 6.411235E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.126 0.000000 0.000000 0.004514 0.000000 0.145833 0.002342 0.056498 0.427505 0.363308 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.8E-03 0. 1.5E-03 9.6E-04 2.0E-02 1.0E-03 1.5E-03 Composition Misfit: 2.665530E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.593 0.000000 0.000000 0.238631 0.000000 0.746577 0.006679 0.008113 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. 0.5 0.3 0. 0. Chi 0. 0. 0.1 0. 1.8E-02 1.7E-03 4.4E-04 0. 0. Composition Misfit: 7.226873E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.535 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.183 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023299 0.014742 0.006975 0.016462 0.052895 0.000918 0.040291 0.028928 0.002167 0.108419 0.704903 Mica 0.018558 0.002673 0.000000 0.062555 0.005854 0.000000 0.005300 0.164899 0.000548 0.238626 0.500987 Gt 0.000000 0.032528 0.000000 0.000000 0.296975 0.033476 0.073597 0.000000 0.002949 0.135696 0.424780 Fsp 0.094669 0.057715 0.000000 0.001473 0.000000 0.000000 0.000000 0.000000 0.000000 0.153857 0.692285 Bio 0.000000 0.000000 0.021323 0.066814 0.169504 0.000744 0.165790 0.112305 0.004177 0.118689 0.340655 St 0.000000 0.000000 0.004105 0.000000 0.132623 0.002130 0.051380 0.088106 0.002480 0.388779 0.330397 Ilm 0.000000 0.000000 0.211050 0.000000 0.660287 0.005907 0.007175 0.000000 0.115580 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774872. -753917. -931901. -849280. -314042. -469259. -637954. -291096. -407359. -1635328. -885790. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 15 converged, 9 successes so far. Misfit function evaluations this try => 165 Misfit this try = 6.133223E-02 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.466046E-07 Bayes score, PP * exp(-Misfit) = 8.902917E-07 Best Bayes score so far = 9.507987E-07 obtained on Try 1 P_bar T_K C_O2 C_H2O Initial coordinates: 12912.4 830.087 0.240399 0.194338 Final coordinates: 8632.72 927.100 0.424335 0.498792 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.133223E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.077 0.021284 0.002969 0.000000 0.076053 0.006981 0.000000 0.006069 0.286153 0.600492 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.3E-04 2.5E-03 0. 9.2E-03 1.1E-04 4.0E-07 Composition Misfit: 2.132468E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.223 0.000000 0.030384 0.000000 0.000000 0.299198 0.037354 0.070072 0.136721 0.426270 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.3 -1. 0.5 -0.2 Chi 0. 3.2E-03 0. 0. 1.7E-03 2.6E-04 3.3E-03 3.7E-04 6.1E-06 Composition Misfit: 8.874942E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.560 0.094558 0.057813 0.000000 0.001536 0.000000 0.000000 0.000000 0.153906 0.692187 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.9E-05 6.7E-04 0. 2.1E-05 0. 0. 0. 3.2E-04 7.7E-06 Composition Misfit: 1.103875E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.483 0.000000 0.000000 0.025021 0.075763 0.197844 0.000945 0.179150 0.136452 0.384824 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.7 0.3 2. Chi 0. 0. 5.3E-04 1.0E-03 9.0E-04 2.4E-04 5.2E-04 1.1E-04 2.5E-03 Composition Misfit: 5.850917E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.099 0.000000 0.000000 0.004759 0.000000 0.148353 0.002628 0.053156 0.427721 0.363383 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 5.6E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.361745E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.318 0.000000 0.000000 0.348577 0.000000 0.629566 0.009337 0.012520 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. 2.0E-02 0.1 -0.4 0. 0. Chi 0. 0. 5.8E-06 0. 3.0E-07 4.7E-05 5.1E-04 0. 0. Composition Misfit: 5.603754E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.905 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.336 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023316 0.014753 0.006980 0.016473 0.052932 0.000919 0.040319 0.029018 0.001404 0.108494 0.705392 Mica 0.017762 0.002477 0.000000 0.063469 0.005826 0.000000 0.005065 0.164939 0.000525 0.238805 0.501132 Gt 0.000000 0.030302 0.000000 0.000000 0.298397 0.037254 0.069885 0.000000 0.002677 0.136355 0.425129 Fsp 0.094558 0.057813 0.000000 0.001536 0.000000 0.000000 0.000000 0.000000 0.000000 0.153906 0.692187 Bio 0.000000 0.000000 0.022122 0.066986 0.174922 0.000836 0.158394 0.111849 0.004009 0.120643 0.340239 St 0.000000 0.000000 0.004329 0.000000 0.134929 0.002391 0.048346 0.088134 0.002349 0.389019 0.330503 Ilm 0.000000 0.000000 0.324044 0.000000 0.585255 0.008680 0.011639 0.000000 0.070383 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775835. -754644. -931837. -849994. -314114. -468593. -638515. -291533. -409866. -1635774. -886299. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 16 converged, 10 successes so far. Misfit function evaluations this try => 255 Misfit this try = 0.232056 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 1.135802E-06 Bayes score, PP * exp(-Misfit) = 9.005791E-07 Best Bayes score so far = 9.507987E-07 obtained on Try 1 P_bar T_K C_O2 C_H2O Initial coordinates: 13196.2 914.828 0.694309 0.686985 Final coordinates: 9147.37 916.743 1.00000 0.684501 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.232056 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.445 0.026347 0.004209 0.000000 0.070422 0.006075 0.000000 0.006450 0.287463 0.599033 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -3. 0. 0. 1. 0.8 0. 1. -0.4 0.1 Chi 9.7E-03 0. 0. 2.8E-03 4.2E-03 0. 7.8E-03 1.7E-04 1.6E-06 Composition Misfit: 2.893715E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.879 0.000000 0.040811 0.000000 0.000000 0.278306 0.039322 0.081027 0.134934 0.425600 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 2. -0.6 -3. 0.6 -0.1 Chi 0. 1.0E-02 0. 0. 6.8E-03 6.6E-04 8.5E-03 5.9E-04 2.1E-06 Composition Misfit: 2.663223E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.758 0.093598 0.060411 0.000000 0.001197 0.000000 0.000000 0.000000 0.155205 0.689589 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.9 0. 4.7E-02 0. 0. 0. 0.4 0.2 Chi 4.1E-05 1.3E-03 0. 2.2E-05 0. 0. 0. 2.1E-04 3.5E-05 Composition Misfit: 1.592254E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.791 0.000000 0.000000 0.022021 0.075286 0.171015 0.000914 0.213758 0.129297 0.387709 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.1 -1. 0.9 0.1 -3. 0.8 1. Chi 0. 0. 1.9E-05 9.2E-04 1.1E-03 2.9E-04 9.2E-03 9.4E-04 2.1E-03 Composition Misfit: 1.443956E-2 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.367 0.000000 0.000000 0.004193 0.000000 0.135782 0.002662 0.066814 0.427317 0.363233 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.3 0.2 -5. 1. 1. Chi 0. 0. 2.4E-03 0. 1.7E-04 5.2E-04 2.9E-02 1.1E-03 1.5E-03 Composition Misfit: 3.438280E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.051 0.000000 0.000000 0.208923 0.000000 0.777316 0.006565 0.007197 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 8. 0. -7. 0.5 0.4 0. 0. Chi 0. 0. 0.1 0. 2.8E-02 1.8E-03 1.1E-03 0. 0. Composition Misfit: 0.126072 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.030 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.678 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023023 0.014567 0.006893 0.016267 0.052268 0.000907 0.039813 0.039322 0.003267 0.107133 0.696540 Mica 0.021986 0.003512 0.000000 0.058764 0.005070 0.000000 0.005382 0.165013 0.000527 0.239877 0.499870 Gt 0.000000 0.040670 0.000000 0.000000 0.277345 0.039186 0.080747 0.000000 0.003455 0.134468 0.424130 Fsp 0.093598 0.060411 0.000000 0.001197 0.000000 0.000000 0.000000 0.000000 0.000000 0.155205 0.689589 Bio 0.000000 0.000000 0.019426 0.066416 0.150866 0.000806 0.188573 0.113407 0.004410 0.114064 0.342030 St 0.000000 0.000000 0.003813 0.000000 0.123467 0.002420 0.060754 0.088077 0.002622 0.388560 0.330288 Ilm 0.000000 0.000000 0.182379 0.000000 0.678559 0.005731 0.006282 0.000000 0.127048 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -771387. -751020. -930445. -846765. -313095. -466399. -635826. -289264. -401987. -1632999. -883997. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 19 converged, 11 successes so far. Misfit function evaluations this try => 225 Misfit this try = 1.03993 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 5.482395E-07 Bayes score, PP * exp(-Misfit) = 1.937909E-07 Best Bayes score so far = 9.507987E-07 obtained on Try 1 P_bar T_K C_O2 C_H2O Initial coordinates: 7471.36 915.856 0.742251 5.221785E-02 Final coordinates: 7281.51 864.546 0.665330 0.508145 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.182928E-2 Extraneous predicted phases: 0.948103 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.278 0.022292 0.002188 0.000000 0.075740 0.005054 0.000000 0.004669 0.289739 0.600318 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.9 0. 1. -0.5 -4.1E-02 Chi 6.4E-03 0. 0. 1.0E-03 7.4E-03 0. 1.7E-02 3.0E-04 1.7E-07 Composition Misfit: 3.412417E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.485 0.000000 0.031828 0.000000 0.000000 0.278434 0.068242 0.057236 0.137643 0.426616 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -4. -0.2 0.4 -0.2 Chi 0. 4.0E-03 0. 0. 6.8E-03 1.7E-02 1.0E-04 2.8E-04 9.0E-06 Composition Misfit: 2.811590E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.540 0.094387 0.058983 0.000000 0.001121 0.000000 0.000000 0.000000 0.154492 0.691017 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.1 0. 0. 0. 0.4 0.2 Chi 7.9E-05 9.3E-04 0. 5.0E-05 0. 0. 0. 2.7E-04 1.8E-05 Composition Misfit: 1.337826E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.437 0.000000 0.000000 0.022787 0.075611 0.196715 0.001323 0.183794 0.134167 0.385603 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.2 -1. -0.8 2.9E-02 -1. 0.4 2. Chi 0. 0. 8.8E-05 9.9E-04 7.6E-04 7.9E-06 1.1E-03 2.8E-04 2.4E-03 Composition Misfit: 5.629663E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.888 0.000000 0.000000 0.003990 0.000000 0.152368 0.004240 0.047387 0.428499 0.363516 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -2. -0.1 -3. 1. 1. Chi 0. 0. 2.8E-03 0. 3.0E-03 3.8E-05 1.3E-02 9.4E-04 1.4E-03 Composition Misfit: 2.081401E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.046 0.000000 0.000000 0.349028 0.000000 0.625924 0.015195 0.009853 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. 0.2 -0.8 2.3E-02 0. 0. Chi 0. 0. 2.7E-06 0. 2.7E-05 1.8E-03 2.2E-06 0. 0. Composition Misfit: 1.807707E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.306 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.464 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.555 0.000000 0.000000 0.203016 0.000000 0.662362 0.010700 0.005129 0.000000 0.118794 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023284 0.014733 0.006971 0.016451 0.052861 0.000917 0.040265 0.029522 0.002198 0.108349 0.704447 Mica 0.018596 0.001826 0.000000 0.063183 0.004216 0.000000 0.003895 0.165384 0.000412 0.241702 0.500788 Gt 0.000000 0.031756 0.000000 0.000000 0.277800 0.068087 0.057106 0.000000 0.002276 0.137330 0.425645 Fsp 0.094387 0.058983 0.000000 0.001121 0.000000 0.000000 0.000000 0.000000 0.000000 0.154492 0.691017 Bio 0.000000 0.000000 0.020109 0.066724 0.173594 0.001167 0.162192 0.113339 0.004195 0.118398 0.340281 St 0.000000 0.000000 0.003629 0.000000 0.138583 0.003857 0.043100 0.088168 0.002301 0.389733 0.330629 Ilm 0.000000 0.000000 0.324530 0.000000 0.581992 0.014129 0.009161 0.000000 0.070188 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -767224. -749864. -926692. -841822. -308382. -457502. -634805. -288230. -408061. -1628905. -882731. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 20 converged, 12 successes so far. Misfit function evaluations this try => 201 Misfit this try = 0.118555 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.726692E-07 Bayes score, PP * exp(-Misfit) = 8.639278E-07 Best Bayes score so far = 9.507987E-07 obtained on Try 1 P_bar T_K C_O2 C_H2O Initial coordinates: 6968.56 888.318 0.883366 0.164340 Final coordinates: 8712.40 926.138 0.595563 0.517683 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.118555 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.150 0.021952 0.003125 0.000000 0.075308 0.006863 0.000000 0.006177 0.286261 0.600312 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.3 -4.0E-02 Chi 6.1E-03 0. 0. 1.1E-03 2.7E-03 0. 8.8E-03 1.2E-04 1.6E-07 Composition Misfit: 2.195223E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.126 0.000000 0.031605 0.000000 0.000000 0.294992 0.038645 0.072119 0.136464 0.426174 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -0.5 -2. 0.5 -0.2 Chi 0. 3.9E-03 0. 0. 2.5E-03 5.0E-04 4.2E-03 4.0E-04 5.4E-06 Composition Misfit: 1.139214E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.348 0.094426 0.058187 0.000000 0.001481 0.000000 0.000000 0.000000 0.154093 0.691813 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -3.6E-02 0. 0. 0. 0.5 0.1 Chi 8.2E-05 7.5E-04 0. 1.0E-05 0. 0. 0. 3.0E-04 1.0E-05 Composition Misfit: 1.149264E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.602 0.000000 0.000000 0.024631 0.075690 0.192972 0.000970 0.185161 0.135352 0.385224 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.6 0.1 -1. 0.4 2. Chi 0. 0. 4.3E-04 1.0E-03 3.7E-04 2.1E-04 1.3E-03 1.8E-04 2.5E-03 Composition Misfit: 5.984074E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.463 0.000000 0.000000 0.004723 0.000000 0.146120 0.002719 0.055494 0.427596 0.363348 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 1.6E-03 4.6E-04 1.9E-02 1.0E-03 1.5E-03 Composition Misfit: 2.504619E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.511 0.000000 0.000000 0.251497 0.000000 0.731207 0.008394 0.008902 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.3 0.2 0. 0. Chi 0. 0. 3.9E-02 0. 1.4E-02 3.1E-04 1.4E-04 0. 0. Composition Misfit: 5.303092E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.433 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.365 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023277 0.014728 0.006969 0.016446 0.052844 0.000917 0.040252 0.030067 0.001967 0.108314 0.704219 Mica 0.018320 0.002608 0.000000 0.062847 0.005728 0.000000 0.005155 0.164941 0.000530 0.238893 0.500978 Gt 0.000000 0.031517 0.000000 0.000000 0.294169 0.038538 0.071918 0.000000 0.002789 0.136083 0.424985 Fsp 0.094426 0.058187 0.000000 0.001481 0.000000 0.000000 0.000000 0.000000 0.000000 0.154093 0.691813 Bio 0.000000 0.000000 0.021771 0.066901 0.170564 0.000857 0.163660 0.112031 0.004090 0.119635 0.340492 St 0.000000 0.000000 0.004295 0.000000 0.132893 0.002473 0.050470 0.088122 0.002398 0.388890 0.330458 Ilm 0.000000 0.000000 0.223702 0.000000 0.650394 0.007466 0.007918 0.000000 0.110519 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775295. -754179. -931601. -849674. -314056. -468137. -638123. -291223. -408429. -1635446. -886011. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 23 converged, 13 successes so far. Misfit function evaluations this try => 235 Misfit this try = 0.162440 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 1.095355E-06 Bayes score, PP * exp(-Misfit) = 9.311258E-07 Best Bayes score so far = 9.507987E-07 obtained on Try 1 P_bar T_K C_O2 C_H2O Initial coordinates: 6906.85 947.298 0.717044 0.931673 Final coordinates: 9310.32 923.710 0.768750 0.693091 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.161176 Extraneous predicted phases: 1.263318E-3 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.694 0.025742 0.004143 0.000000 0.071023 0.006315 0.000000 0.006549 0.286943 0.599285 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 0.7 0. 1. -0.4 0.1 Chi 9.2E-03 0. 0. 2.5E-03 3.7E-03 0. 7.5E-03 1.5E-04 8.5E-07 Composition Misfit: 2.721074E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.226 0.000000 0.039471 0.000000 0.000000 0.286597 0.032517 0.080203 0.135427 0.425785 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. 0.2 -2. 0.6 -0.1 Chi 0. 9.1E-03 0. 0. 4.4E-03 9.2E-05 8.0E-03 5.2E-04 3.0E-06 Composition Misfit: 2.209133E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.885 0.093983 0.059510 0.000000 0.001262 0.000000 0.000000 0.000000 0.154755 0.690490 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 2.8E-02 0. 0. 0. 0.4 0.2 Chi 5.8E-05 1.1E-03 0. 7.2E-06 0. 0. 0. 2.4E-04 2.3E-05 Composition Misfit: 1.384657E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.303 0.000000 0.000000 0.023535 0.075361 0.176067 0.000782 0.206122 0.130415 0.387719 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. 0.6 0.2 -2. 0.7 1. Chi 0. 0. 2.0E-04 9.4E-04 4.0E-04 5.3E-04 6.5E-03 7.5E-04 2.1E-03 Composition Misfit: 1.137659E-2 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.414 0.000000 0.000000 0.004876 0.000000 0.137892 0.002217 0.064414 0.427312 0.363289 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.5 0.3 -5. 1. 1. Chi 0. 0. 1.2E-03 0. 3.4E-04 1.2E-03 2.7E-02 1.1E-03 1.5E-03 Composition Misfit: 3.199586E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.795 0.000000 0.000000 0.241615 0.000000 0.742075 0.006763 0.009546 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. 0.5 0.1 0. 0. Chi 0. 0. 4.9E-02 0. 1.7E-02 1.5E-03 2.2E-05 0. 0. Composition Misfit: 6.711704E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.043 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.532 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.109 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000016 -.000016 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023029 0.014571 0.006894 0.016271 0.052282 0.000907 0.039823 0.039826 0.002512 0.107161 0.696723 Mica 0.021482 0.003457 0.000000 0.059271 0.005270 0.000000 0.005465 0.164963 0.000512 0.239461 0.500119 Gt 0.000000 0.039343 0.000000 0.000000 0.285669 0.032411 0.079943 0.000000 0.003240 0.134988 0.424406 Fsp 0.093983 0.059510 0.000000 0.001262 0.000000 0.000000 0.000000 0.000000 0.000000 0.154755 0.690490 Bio 0.000000 0.000000 0.020792 0.066580 0.155552 0.000691 0.182105 0.112368 0.004149 0.115219 0.342543 St 0.000000 0.000000 0.004435 0.000000 0.125405 0.002016 0.058581 0.088105 0.002448 0.388618 0.330392 Ilm 0.000000 0.000000 0.213972 0.000000 0.657174 0.005989 0.008454 0.000000 0.114411 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772232. -751639. -929931. -847408. -313530. -468618. -636468. -289707. -404927. -1633759. -884379. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 24 converged, 14 successes so far. Misfit function evaluations this try => 272 Misfit this try = 0.113941 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.458890E-07 Bayes score, PP * exp(-Misfit) = 8.440271E-07 Best Bayes score so far = 9.507987E-07 obtained on Try 1 P_bar T_K C_O2 C_H2O Initial coordinates: 14441.5 900.286 0.396231 0.250245 Final coordinates: 8599.24 926.479 0.565683 0.493597 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.113921 Extraneous predicted phases: 1.984251E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.171 0.021446 0.002994 0.000000 0.075884 0.006923 0.000000 0.006075 0.286257 0.600420 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.7E-03 0. 0. 9.7E-04 2.6E-03 0. 9.2E-03 1.2E-04 2.9E-07 Composition Misfit: 2.158650E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.107 0.000000 0.030412 0.000000 0.000000 0.295903 0.040116 0.070720 0.136618 0.426232 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.6 -2. 0.5 -0.2 Chi 0. 3.2E-03 0. 0. 2.3E-03 8.6E-04 3.6E-03 3.8E-04 5.8E-06 Composition Misfit: 1.031834E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.558 0.094483 0.057990 0.000000 0.001522 0.000000 0.000000 0.000000 0.153995 0.692010 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.8E-02 0. 0. 0. 0.5 0.1 Chi 8.5E-05 7.1E-04 0. 1.8E-05 0. 0. 0. 3.1E-04 9.0E-06 Composition Misfit: 1.126125E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.405 0.000000 0.000000 0.024816 0.075751 0.195817 0.001013 0.181578 0.136266 0.384759 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.8 0.1 -0.8 0.3 2. Chi 0. 0. 4.8E-04 1.0E-03 6.6E-04 1.7E-04 8.0E-04 1.2E-04 2.5E-03 Composition Misfit: 5.776363E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.536 0.000000 0.000000 0.004684 0.000000 0.147396 0.002835 0.054084 0.427644 0.363357 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.8E-03 3.6E-04 1.8E-02 1.0E-03 1.4E-03 Composition Misfit: 2.408528E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.459 0.000000 0.000000 0.253064 0.000000 0.729409 0.008752 0.008776 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.4E-02 1.8E-04 1.7E-04 0. 0. Composition Misfit: 5.102819E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.414 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.335 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.014 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000022 -.000022 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023312 0.014750 0.006979 0.016471 0.052923 0.000918 0.040312 0.028711 0.001871 0.108477 0.705276 Mica 0.017897 0.002499 0.000000 0.063327 0.005778 0.000000 0.005070 0.164947 0.000532 0.238887 0.501063 Gt 0.000000 0.030329 0.000000 0.000000 0.295097 0.040007 0.070527 0.000000 0.002722 0.136246 0.425072 Fsp 0.094483 0.057990 0.000000 0.001522 0.000000 0.000000 0.000000 0.000000 0.000000 0.153995 0.692010 Bio 0.000000 0.000000 0.021936 0.066959 0.173090 0.000896 0.160504 0.111982 0.004081 0.120450 0.340103 St 0.000000 0.000000 0.004260 0.000000 0.134054 0.002578 0.049188 0.088125 0.002393 0.388934 0.330467 Ilm 0.000000 0.000000 0.225252 0.000000 0.649247 0.007790 0.007811 0.000000 0.109899 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775850. -754635. -931908. -850108. -314161. -467997. -638416. -291491. -408967. -1635746. -886308. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 25 converged, 15 successes so far. Misfit function evaluations this try => 181 Misfit this try = 0.126940 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 1.068951E-06 Bayes score, PP * exp(-Misfit) = 9.415175E-07 Best Bayes score so far = 9.507987E-07 obtained on Try 1 P_bar T_K C_O2 C_H2O Initial coordinates: 11507.0 824.099 0.928158 0.553147 Final coordinates: 9114.86 923.686 0.627893 0.528084 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.126940 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.593 0.023708 0.003466 0.000000 0.073374 0.006701 0.000000 0.006382 0.286322 0.600047 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 0.7 0. 1. -0.3 -6.1E-03 Chi 7.5E-03 0. 0. 1.7E-03 3.0E-03 0. 8.0E-03 1.2E-04 3.7E-09 Composition Misfit: 2.377914E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.758 0.000000 0.035375 0.000000 0.000000 0.298761 0.028848 0.074929 0.136063 0.426024 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. 0.6 -2. 0.6 -0.2 Chi 0. 6.2E-03 0. 0. 1.8E-03 1.0E-03 5.4E-03 4.4E-04 4.4E-06 Composition Misfit: 1.487925E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.908 0.094858 0.057534 0.000000 0.001375 0.000000 0.000000 0.000000 0.153767 0.692466 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. -5.1E-03 0. 0. 0. 0.5 0.1 Chi 1.1E-04 6.1E-04 0. 2.2E-07 0. 0. 0. 3.3E-04 6.0E-06 Composition Misfit: 1.058184E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.534 0.000000 0.000000 0.024314 0.075503 0.188156 0.000702 0.191951 0.132550 0.386824 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.2 0.2 -2. 0.6 2. Chi 0. 0. 3.6E-04 9.7E-04 7.2E-05 7.4E-04 2.6E-03 4.5E-04 2.2E-03 Composition Misfit: 7.412419E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.058 0.000000 0.000000 0.004895 0.000000 0.144391 0.001959 0.057920 0.427497 0.363338 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.4 -4. 1. 1. Chi 0. 0. 1.2E-03 0. 1.2E-03 1.8E-03 2.1E-02 1.0E-03 1.5E-03 Composition Misfit: 2.787838E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.598 0.000000 0.000000 0.254122 0.000000 0.729918 0.006374 0.009587 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.6 0.1 0. 0. Chi 0. 0. 3.6E-02 0. 1.4E-02 2.1E-03 1.8E-05 0. 0. Composition Misfit: 5.193294E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.431 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.119 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023260 0.014718 0.006964 0.016434 0.052807 0.000916 0.040223 0.030649 0.002072 0.108237 0.703719 Mica 0.019785 0.002892 0.000000 0.061235 0.005592 0.000000 0.005326 0.164932 0.000513 0.238952 0.500772 Gt 0.000000 0.035271 0.000000 0.000000 0.297876 0.028762 0.074707 0.000000 0.002964 0.135660 0.424761 Fsp 0.094858 0.057534 0.000000 0.001375 0.000000 0.000000 0.000000 0.000000 0.000000 0.153767 0.692466 Bio 0.000000 0.000000 0.021493 0.066742 0.166323 0.000620 0.169678 0.111992 0.004044 0.117170 0.341939 St 0.000000 0.000000 0.004452 0.000000 0.131323 0.001782 0.052678 0.088121 0.002385 0.388805 0.330453 Ilm 0.000000 0.000000 0.226301 0.000000 0.650007 0.005676 0.008537 0.000000 0.109480 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772895. -752592. -930255. -847578. -313340. -469671. -637189. -290274. -407700. -1634180. -884823. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 26 converged, 16 successes so far. Misfit function evaluations this try => 149 Misfit this try = 6.211479E-02 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 1.020237E-06 Bayes score, PP * exp(-Misfit) = 9.587928E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 10564.4 919.219 0.313954 0.482145 Final coordinates: 8500.25 914.420 0.423828 0.493878 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.211479E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.003 0.021622 0.002833 0.000000 0.075830 0.006654 0.000000 0.005854 0.286713 0.600494 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.4 -0.1 Chi 5.9E-03 0. 0. 9.8E-04 3.0E-03 0. 1.0E-02 1.4E-04 4.1E-07 Composition Misfit: 2.297181E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.239 0.000000 0.031705 0.000000 0.000000 0.299768 0.037928 0.067500 0.136799 0.426300 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.4 -1. 0.5 -0.2 Chi 0. 3.9E-03 0. 0. 1.6E-03 3.6E-04 2.4E-03 3.6E-04 6.3E-06 Composition Misfit: 8.680255E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.551 0.094689 0.057754 0.000000 0.001434 0.000000 0.000000 0.000000 0.153877 0.692246 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -2.2E-02 0. 0. 0. 0.5 0.1 Chi 9.8E-05 6.6E-04 0. 4.0E-06 0. 0. 0. 3.2E-04 7.3E-06 Composition Misfit: 1.085858E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.592 0.000000 0.000000 0.024567 0.075693 0.198615 0.000907 0.179444 0.135398 0.385377 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.9 0.1 -0.7 0.4 2. Chi 0. 0. 4.2E-04 1.0E-03 1.0E-03 2.9E-04 5.5E-04 1.8E-04 2.4E-03 Composition Misfit: 5.881851E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.722 0.000000 0.000000 0.004630 0.000000 0.149809 0.002576 0.051702 0.427872 0.363411 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.6E-03 0. 2.3E-03 6.2E-04 1.6E-02 1.0E-03 1.4E-03 Composition Misfit: 2.300225E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.332 0.000000 0.000000 0.353452 0.000000 0.625287 0.009197 0.012065 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.2 0. 0.2 0.1 -0.3 0. 0. Chi 0. 0. 3.4E-05 0. 3.6E-05 7.0E-05 3.5E-04 0. 0. Composition Misfit: 4.927708E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.285 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.276 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023322 0.014757 0.006982 0.016478 0.052947 0.000919 0.040331 0.028740 0.001403 0.108526 0.705595 Mica 0.018044 0.002364 0.000000 0.063280 0.005553 0.000000 0.004885 0.165010 0.000500 0.239259 0.501106 Gt 0.000000 0.031621 0.000000 0.000000 0.298976 0.037828 0.067322 0.000000 0.002644 0.136437 0.425173 Fsp 0.094689 0.057754 0.000000 0.001434 0.000000 0.000000 0.000000 0.000000 0.000000 0.153877 0.692246 Bio 0.000000 0.000000 0.021714 0.066905 0.175554 0.000802 0.158609 0.112095 0.004012 0.119677 0.340632 St 0.000000 0.000000 0.004211 0.000000 0.136255 0.002343 0.047024 0.088142 0.002335 0.389160 0.330531 Ilm 0.000000 0.000000 0.329321 0.000000 0.582597 0.008569 0.011241 0.000000 0.068271 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -773424. -753233. -930488. -847607. -312695. -466953. -637599. -290640. -409682. -1634033. -885227. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 27 converged, 17 successes so far. Misfit function evaluations this try => 126 Misfit this try = 0.117793 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.379099E-07 Bayes score, PP * exp(-Misfit) = 8.336892E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 6365.52 929.894 0.697280 0.466721 Final coordinates: 8456.34 923.983 0.586293 0.533798 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.117793 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.061 0.021538 0.002999 0.000000 0.075818 0.006718 0.000000 0.005989 0.286617 0.600322 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.4 -4.1E-02 Chi 5.8E-03 0. 0. 9.9E-04 2.9E-03 0. 9.5E-03 1.3E-04 1.7E-07 Composition Misfit: 2.238341E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.781 0.000000 0.030128 0.000000 0.000000 0.289900 0.046351 0.070629 0.136721 0.426271 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -1. -2. 0.5 -0.2 Chi 0. 3.0E-03 0. 0. 3.5E-03 3.2E-03 3.6E-03 3.7E-04 6.1E-06 Composition Misfit: 1.366977E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.407 0.094173 0.058661 0.000000 0.001496 0.000000 0.000000 0.000000 0.154330 0.691339 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -4.0E-02 0. 0. 0. 0.5 0.1 Chi 6.8E-05 8.5E-04 0. 1.3E-05 0. 0. 0. 2.8E-04 1.4E-05 Composition Misfit: 1.225243E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.633 0.000000 0.000000 0.024718 0.075764 0.193445 0.001164 0.183841 0.136460 0.384608 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.6 0.1 -1. 0.3 2. Chi 0. 0. 4.5E-04 1.0E-03 4.2E-04 5.8E-05 1.1E-03 1.1E-04 2.6E-03 Composition Misfit: 5.733543E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.475 0.000000 0.000000 0.004676 0.000000 0.146171 0.003299 0.054815 0.427674 0.363364 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.1 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.6E-03 8.8E-05 1.9E-02 1.0E-03 1.4E-03 Composition Misfit: 2.417922E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.487 0.000000 0.000000 0.252959 0.000000 0.728076 0.010154 0.008811 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. -2.5E-02 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.3E-02 2.3E-06 1.6E-04 0. 0. Composition Misfit: 5.060206E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.613 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.544 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023256 0.014715 0.006962 0.016431 0.052796 0.000916 0.040216 0.030975 0.001935 0.108216 0.703582 Mica 0.017973 0.002502 0.000000 0.063269 0.005606 0.000000 0.004998 0.164987 0.000525 0.239178 0.500961 Gt 0.000000 0.030047 0.000000 0.000000 0.289124 0.046227 0.070440 0.000000 0.002677 0.136355 0.425129 Fsp 0.094173 0.058661 0.000000 0.001496 0.000000 0.000000 0.000000 0.000000 0.000000 0.154330 0.691339 Bio 0.000000 0.000000 0.021846 0.066962 0.170971 0.001029 0.162482 0.112077 0.004101 0.120606 0.339925 St 0.000000 0.000000 0.004253 0.000000 0.132941 0.003000 0.049854 0.088127 0.002385 0.388965 0.330475 Ilm 0.000000 0.000000 0.225148 0.000000 0.648031 0.009038 0.007842 0.000000 0.109941 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775950. -754632. -931799. -850315. -314140. -466708. -638300. -291437. -408630. -1635655. -886364. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 28 converged, 18 successes so far. Misfit function evaluations this try => 286 Misfit this try = 0.120033 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.524703E-07 Bayes score, PP * exp(-Misfit) = 8.447374E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 13145.1 944.820 0.945279 0.911781 Final coordinates: 8485.11 923.094 0.605106 0.566529 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.120033 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.988 0.021897 0.003090 0.000000 0.075420 0.006611 0.000000 0.006024 0.286742 0.600218 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.4 -2.8E-02 Chi 6.1E-03 0. 0. 1.1E-03 3.1E-03 0. 9.4E-03 1.4E-04 7.9E-08 Composition Misfit: 2.290782E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.681 0.000000 0.030808 0.000000 0.000000 0.287269 0.047508 0.071483 0.136677 0.426254 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -1. -2. 0.5 -0.2 Chi 0. 3.4E-03 0. 0. 4.2E-03 3.7E-03 3.9E-03 3.7E-04 6.0E-06 Composition Misfit: 1.557504E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.215 0.094018 0.059038 0.000000 0.001463 0.000000 0.000000 0.000000 0.154519 0.690962 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -3.0E-02 0. 0. 0. 0.4 0.2 Chi 6.0E-05 9.4E-04 0. 7.6E-06 0. 0. 0. 2.6E-04 1.8E-05 Composition Misfit: 1.286812E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.858 0.000000 0.000000 0.024624 0.075731 0.190860 0.001185 0.186762 0.135972 0.384866 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.4 0.1 -1. 0.3 2. Chi 0. 0. 4.3E-04 1.0E-03 2.1E-04 4.8E-05 1.6E-03 1.4E-04 2.5E-03 Composition Misfit: 5.953043E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.786 0.000000 0.000000 0.004722 0.000000 0.144939 0.003373 0.055948 0.427655 0.363363 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.1 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 1.3E-03 6.4E-05 1.9E-02 1.0E-03 1.4E-03 Composition Misfit: 2.479789E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.521 0.000000 0.000000 0.253744 0.000000 0.726728 0.010486 0.009042 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -4. -0.1 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.3E-02 2.3E-05 1.0E-04 0. 0. Composition Misfit: 4.951252E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.318 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.633 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023210 0.014686 0.006949 0.016399 0.052693 0.000914 0.040137 0.032810 0.001993 0.108004 0.702205 Mica 0.018272 0.002579 0.000000 0.062937 0.005517 0.000000 0.005027 0.164996 0.000520 0.239281 0.500872 Gt 0.000000 0.030725 0.000000 0.000000 0.286495 0.047380 0.071291 0.000000 0.002696 0.136309 0.425105 Fsp 0.094018 0.059038 0.000000 0.001463 0.000000 0.000000 0.000000 0.000000 0.000000 0.154519 0.690962 Bio 0.000000 0.000000 0.021762 0.066931 0.168682 0.001047 0.165060 0.112100 0.004102 0.120172 0.340144 St 0.000000 0.000000 0.004294 0.000000 0.131821 0.003068 0.050885 0.088127 0.002380 0.388949 0.330476 Ilm 0.000000 0.000000 0.225926 0.000000 0.647057 0.009336 0.008051 0.000000 0.109629 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775652. -754345. -931540. -850130. -314082. -466391. -638086. -291253. -408254. -1635451. -886201. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 30 converged, 19 successes so far. Misfit function evaluations this try => 210 Misfit this try = 0.117169 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.391512E-07 Bayes score, PP * exp(-Misfit) = 8.353138E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 6716.70 842.863 0.933160 0.157192 Final coordinates: 8473.05 924.271 0.584255 0.532806 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.117166 Extraneous predicted phases: 3.373146E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.023 0.021541 0.003004 0.000000 0.075809 0.006736 0.000000 0.006002 0.286581 0.600326 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.4 -4.2E-02 Chi 5.8E-03 0. 0. 9.9E-04 2.9E-03 0. 9.5E-03 1.3E-04 1.8E-07 Composition Misfit: 2.230817E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.803 0.000000 0.030196 0.000000 0.000000 0.290314 0.045808 0.070708 0.136708 0.426266 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -1. -2. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 3.4E-03 2.9E-03 3.6E-03 3.7E-04 6.1E-06 Composition Misfit: 1.340030E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.411 0.094192 0.058620 0.000000 0.001498 0.000000 0.000000 0.000000 0.154310 0.691380 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -4.1E-02 0. 0. 0. 0.5 0.1 Chi 6.9E-05 8.4E-04 0. 1.3E-05 0. 0. 0. 2.8E-04 1.4E-05 Composition Misfit: 1.218634E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.665 0.000000 0.000000 0.024737 0.075762 0.193544 0.001151 0.183741 0.136428 0.384636 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.6 0.1 -1. 0.3 2. Chi 0. 0. 4.6E-04 1.0E-03 4.3E-04 6.5E-05 1.1E-03 1.1E-04 2.6E-03 Composition Misfit: 5.735762E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.378 0.000000 0.000000 0.004685 0.000000 0.146255 0.003255 0.054770 0.427671 0.363364 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.1 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.6E-03 1.0E-04 1.9E-02 1.0E-03 1.4E-03 Composition Misfit: 2.416250E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.485 0.000000 0.000000 0.253191 0.000000 0.727915 0.010059 0.008835 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -4. -9.3E-03 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.3E-02 3.4E-07 1.5E-04 0. 0. Composition Misfit: 5.034028E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.700 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.529 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.006 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000021 -.000021 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023257 0.014716 0.006963 0.016432 0.052800 0.000916 0.040218 0.030919 0.001928 0.108223 0.703628 Mica 0.017976 0.002507 0.000000 0.063262 0.005621 0.000000 0.005009 0.164983 0.000526 0.239150 0.500967 Gt 0.000000 0.030115 0.000000 0.000000 0.289535 0.045685 0.070518 0.000000 0.002683 0.136341 0.425122 Fsp 0.094192 0.058620 0.000000 0.001498 0.000000 0.000000 0.000000 0.000000 0.000000 0.154310 0.691380 Bio 0.000000 0.000000 0.021864 0.066962 0.171063 0.001017 0.162399 0.112059 0.004096 0.120581 0.339959 St 0.000000 0.000000 0.004261 0.000000 0.133017 0.002961 0.049812 0.088127 0.002384 0.388962 0.330476 Ilm 0.000000 0.000000 0.225378 0.000000 0.647955 0.008954 0.007865 0.000000 0.109849 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775946. -754618. -931808. -850299. -314149. -466831. -638307. -291438. -408643. -1635665. -886357. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 39 converged, 20 successes so far. Misfit function evaluations this try => 213 Misfit this try = 0.127372 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 1.025579E-06 Bayes score, PP * exp(-Misfit) = 9.029262E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 6118.90 928.832 0.721554 0.323346 Final coordinates: 8866.09 923.816 0.654862 0.610510 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.127372 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.897 0.023276 0.003476 0.000000 0.073824 0.006551 0.000000 0.006302 0.286636 0.599934 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 0.7 0. 1. -0.4 8.4E-03 Chi 7.2E-03 0. 0. 1.5E-03 3.2E-03 0. 8.3E-03 1.3E-04 7.2E-09 Composition Misfit: 2.387290E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.902 0.000000 0.034317 0.000000 0.000000 0.288583 0.039800 0.074998 0.136220 0.426082 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.6 -2. 0.5 -0.2 Chi 0. 5.5E-03 0. 0. 3.9E-03 7.7E-04 5.4E-03 4.3E-04 4.8E-06 Composition Misfit: 1.602295E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.736 0.094008 0.059227 0.000000 0.001378 0.000000 0.000000 0.000000 0.154614 0.690773 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -5.8E-03 0. 0. 0. 0.4 0.2 Chi 5.9E-05 9.8E-04 0. 2.9E-07 0. 0. 0. 2.6E-04 2.0E-05 Composition Misfit: 1.318339E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.365 0.000000 0.000000 0.024302 0.075573 0.185225 0.000980 0.194171 0.133595 0.386155 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -5.0E-02 0.1 -2. 0.5 2. Chi 0. 0. 3.5E-04 9.8E-04 3.1E-06 2.0E-04 3.1E-03 3.4E-04 2.3E-03 Composition Misfit: 7.311021E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.038 0.000000 0.000000 0.004858 0.000000 0.142396 0.002774 0.059118 0.427514 0.363339 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.8 0.2 -4. 1. 1. Chi 0. 0. 1.3E-03 0. 9.0E-04 4.1E-04 2.2E-02 1.0E-03 1.5E-03 Composition Misfit: 2.721448E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.617 0.000000 0.000000 0.252235 0.000000 0.729424 0.008795 0.009546 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 0.1 0. 0. Chi 0. 0. 3.8E-02 0. 1.4E-02 1.7E-04 2.2E-05 0. 0. Composition Misfit: 5.163224E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.848 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.597 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023147 0.014646 0.006930 0.016355 0.052551 0.000912 0.040028 0.035261 0.002151 0.107712 0.700307 Mica 0.019425 0.002901 0.000000 0.061607 0.005467 0.000000 0.005259 0.164965 0.000516 0.239203 0.500657 Gt 0.000000 0.034218 0.000000 0.000000 0.287748 0.039684 0.074781 0.000000 0.002895 0.135825 0.424849 Fsp 0.094008 0.059227 0.000000 0.001378 0.000000 0.000000 0.000000 0.000000 0.000000 0.154614 0.690773 Bio 0.000000 0.000000 0.021478 0.066792 0.163702 0.000866 0.171609 0.112105 0.004092 0.118071 0.341285 St 0.000000 0.000000 0.004419 0.000000 0.129508 0.002523 0.053768 0.088121 0.002389 0.388820 0.330453 Ilm 0.000000 0.000000 0.224431 0.000000 0.649022 0.007826 0.008494 0.000000 0.110227 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774174. -753165. -930745. -848899. -313829. -467487. -637427. -290598. -407230. -1634740. -885407. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 42 converged, 21 successes so far. Misfit function evaluations this try => 278 Misfit this try = 6.247359E-02 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.693228E-07 Bayes score, PP * exp(-Misfit) = 9.106186E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 5854.86 823.473 0.527823 0.148680 Final coordinates: 8714.05 926.498 0.438384 0.485150 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.247359E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.014 0.021465 0.002987 0.000000 0.075854 0.007027 0.000000 0.006118 0.286052 0.600498 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.7E-03 0. 0. 9.8E-04 2.4E-03 0. 9.0E-03 1.1E-04 4.1E-07 Composition Misfit: 2.126322E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.418 0.000000 0.030986 0.000000 0.000000 0.301413 0.034436 0.070363 0.136583 0.426219 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -2.1E-02 -1. 0.5 -0.2 Chi 0. 3.5E-03 0. 0. 1.4E-03 1.0E-06 3.4E-03 3.9E-04 5.7E-06 Composition Misfit: 8.747940E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.551 0.094720 0.057520 0.000000 0.001519 0.000000 0.000000 0.000000 0.153760 0.692480 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. -4.7E-02 0. 0. 0. 0.5 0.1 Chi 1.0E-04 6.1E-04 0. 1.7E-05 0. 0. 0. 3.3E-04 5.9E-06 Composition Misfit: 1.064142E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.563 0.000000 0.000000 0.024881 0.075726 0.197845 0.000867 0.179731 0.135884 0.385066 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.9 0.2 -0.7 0.3 2. Chi 0. 0. 5.0E-04 1.0E-03 9.0E-04 3.6E-04 5.8E-04 1.4E-04 2.5E-03 Composition Misfit: 5.978448E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.308 0.000000 0.000000 0.004722 0.000000 0.148594 0.002404 0.053243 0.427670 0.363367 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.1E-03 8.6E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.409907E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.339 0.000000 0.000000 0.337484 0.000000 0.641989 0.008463 0.012065 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.7 0. -0.6 0.2 -0.3 0. 0. Chi 0. 0. 4.6E-04 0. 2.2E-04 2.8E-04 3.5E-04 0. 0. Composition Misfit: 1.320770E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.581 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.226 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023333 0.014764 0.006985 0.016486 0.052972 0.000919 0.040349 0.028245 0.001451 0.108576 0.705920 Mica 0.017913 0.002493 0.000000 0.063304 0.005865 0.000000 0.005106 0.164926 0.000529 0.238723 0.501143 Gt 0.000000 0.030902 0.000000 0.000000 0.300588 0.034342 0.070170 0.000000 0.002738 0.136209 0.425052 Fsp 0.094720 0.057520 0.000000 0.001519 0.000000 0.000000 0.000000 0.000000 0.000000 0.153760 0.692480 Bio 0.000000 0.000000 0.021997 0.066947 0.174909 0.000766 0.158895 0.111897 0.004035 0.120131 0.340425 St 0.000000 0.000000 0.004295 0.000000 0.135145 0.002187 0.048424 0.088128 0.002375 0.388965 0.330481 Ilm 0.000000 0.000000 0.312122 0.000000 0.593742 0.007827 0.011158 0.000000 0.075151 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775309. -754337. -931669. -849477. -313922. -469061. -638346. -291359. -409490. -1635501. -886047. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 46 converged, 22 successes so far. Misfit function evaluations this try => 185 Misfit this try = 0.114419 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.471136E-07 Bayes score, PP * exp(-Misfit) = 8.447153E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 7984.00 831.714 0.921737 0.144487 Final coordinates: 8590.53 926.170 0.569755 0.498367 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.114419 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.353 0.021488 0.003004 0.000000 0.075841 0.006895 0.000000 0.006072 0.286299 0.600401 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.8E-03 0. 0. 9.8E-04 2.6E-03 0. 9.2E-03 1.2E-04 2.7E-07 Composition Misfit: 2.169787E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.065 0.000000 0.030468 0.000000 0.000000 0.295150 0.040733 0.070794 0.136622 0.426233 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -0.7 -2. 0.5 -0.2 Chi 0. 3.2E-03 0. 0. 2.4E-03 1.0E-03 3.6E-03 3.8E-04 5.8E-06 Composition Misfit: 1.069309E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.528 0.094438 0.058092 0.000000 0.001516 0.000000 0.000000 0.000000 0.154046 0.691908 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.6E-02 0. 0. 0. 0.5 0.1 Chi 8.2E-05 7.3E-04 0. 1.6E-05 0. 0. 0. 3.0E-04 9.7E-06 Composition Misfit: 1.139617E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.253 0.000000 0.000000 0.024800 0.075748 0.195324 0.001029 0.182094 0.136227 0.384777 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.7 0.1 -0.9 0.3 2. Chi 0. 0. 4.8E-04 1.0E-03 6.0E-04 1.5E-04 8.7E-04 1.2E-04 2.5E-03 Composition Misfit: 5.768864E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.859 0.000000 0.000000 0.004689 0.000000 0.147176 0.002879 0.054254 0.427644 0.363358 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.8E-03 3.2E-04 1.8E-02 1.0E-03 1.4E-03 Composition Misfit: 2.413589E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.465 0.000000 0.000000 0.253030 0.000000 0.729287 0.008893 0.008789 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.4E-02 1.4E-04 1.7E-04 0. 0. Composition Misfit: 5.098410E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.108 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.370 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023305 0.014746 0.006977 0.016466 0.052908 0.000918 0.040301 0.028980 0.001884 0.108445 0.705071 Mica 0.017932 0.002507 0.000000 0.063290 0.005754 0.000000 0.005067 0.164952 0.000531 0.238921 0.501045 Gt 0.000000 0.030385 0.000000 0.000000 0.294347 0.040622 0.070602 0.000000 0.002720 0.136250 0.425074 Fsp 0.094438 0.058092 0.000000 0.001516 0.000000 0.000000 0.000000 0.000000 0.000000 0.154046 0.691908 Bio 0.000000 0.000000 0.021921 0.066956 0.172652 0.000910 0.160958 0.111991 0.004082 0.120415 0.340115 St 0.000000 0.000000 0.004265 0.000000 0.133854 0.002619 0.049343 0.088125 0.002391 0.388936 0.330468 Ilm 0.000000 0.000000 0.225219 0.000000 0.649130 0.007916 0.007823 0.000000 0.109912 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775826. -754602. -931871. -850103. -314152. -467847. -638383. -291466. -408896. -1635716. -886294. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 51 converged, 23 successes so far. Misfit function evaluations this try => 299 Misfit this try = 0.114792 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.562358E-07 Bayes score, PP * exp(-Misfit) = 8.525336E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 13076.1 929.625 0.935667 0.147851 Final coordinates: 8548.37 924.263 0.565196 0.486256 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.114792 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.006 0.021428 0.002944 0.000000 0.075938 0.006866 0.000000 0.006012 0.286374 0.600437 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.7E-03 0. 0. 9.6E-04 2.7E-03 0. 9.4E-03 1.2E-04 3.2E-07 Composition Misfit: 2.186060E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.090 0.000000 0.030352 0.000000 0.000000 0.295861 0.040847 0.070020 0.136669 0.426251 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.7 -1. 0.5 -0.2 Chi 0. 3.2E-03 0. 0. 2.3E-03 1.1E-03 3.3E-03 3.8E-04 6.0E-06 Composition Misfit: 1.022073E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.596 0.094500 0.057979 0.000000 0.001510 0.000000 0.000000 0.000000 0.153990 0.692021 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.4E-02 0. 0. 0. 0.5 0.1 Chi 8.6E-05 7.0E-04 0. 1.5E-05 0. 0. 0. 3.1E-04 8.9E-06 Composition Misfit: 1.122879E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.552 0.000000 0.000000 0.024764 0.075751 0.196341 0.001024 0.181100 0.136265 0.384755 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.8 0.1 -0.8 0.3 2. Chi 0. 0. 4.7E-04 1.0E-03 7.2E-04 1.6E-04 7.4E-04 1.2E-04 2.5E-03 Composition Misfit: 5.753474E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.347 0.000000 0.000000 0.004657 0.000000 0.147821 0.002873 0.053606 0.427679 0.363364 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.9E-03 3.2E-04 1.8E-02 1.0E-03 1.4E-03 Composition Misfit: 2.378943E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.457 0.000000 0.000000 0.252233 0.000000 0.730305 0.008844 0.008618 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 0.2 0. 0. Chi 0. 0. 3.8E-02 0. 1.4E-02 1.5E-04 2.2E-04 0. 0. Composition Misfit: 5.204479E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.618 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.334 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023322 0.014756 0.006982 0.016478 0.052945 0.000919 0.040330 0.028296 0.001870 0.108523 0.705579 Mica 0.017882 0.002457 0.000000 0.063371 0.005730 0.000000 0.005017 0.164963 0.000528 0.238982 0.501070 Gt 0.000000 0.030270 0.000000 0.000000 0.295062 0.040737 0.069831 0.000000 0.002700 0.136300 0.425100 Fsp 0.094500 0.057979 0.000000 0.001510 0.000000 0.000000 0.000000 0.000000 0.000000 0.153990 0.692021 Bio 0.000000 0.000000 0.021889 0.066956 0.173545 0.000905 0.160073 0.112023 0.004082 0.120444 0.340083 St 0.000000 0.000000 0.004235 0.000000 0.134441 0.002613 0.048754 0.088126 0.002389 0.388967 0.330474 Ilm 0.000000 0.000000 0.224430 0.000000 0.649805 0.007869 0.007668 0.000000 0.110228 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775548. -754483. -931733. -849795. -313939. -467620. -638308. -291386. -409002. -1635501. -886183. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 55 converged, 24 successes so far. Misfit function evaluations this try => 152 Misfit this try = 0.120262 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.230751E-07 Bayes score, PP * exp(-Misfit) = 8.184800E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 6910.01 950.883 0.174231 0.890255 Final coordinates: 8345.42 922.649 0.591580 0.551971 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.120262 Extraneous predicted phases: 3.304514E-8 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.369 0.021490 0.002972 0.000000 0.075896 0.006609 0.000000 0.005915 0.286830 0.600287 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.4 -3.7E-02 Chi 5.8E-03 0. 0. 9.7E-04 3.1E-03 0. 9.8E-03 1.4E-04 1.4E-07 Composition Misfit: 2.281703E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.615 0.000000 0.029652 0.000000 0.000000 0.286333 0.050563 0.070319 0.136824 0.426309 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -2. -1. 0.5 -0.2 Chi 0. 2.8E-03 0. 0. 4.4E-03 5.3E-03 3.4E-03 3.6E-04 6.4E-06 Composition Misfit: 1.627616E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.358 0.094025 0.058968 0.000000 0.001491 0.000000 0.000000 0.000000 0.154484 0.691032 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -3.9E-02 0. 0. 0. 0.4 0.2 Chi 6.0E-05 9.2E-04 0. 1.2E-05 0. 0. 0. 2.7E-04 1.7E-05 Composition Misfit: 1.277216E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.356 0.000000 0.000000 0.024709 0.075786 0.192586 0.001265 0.184451 0.136792 0.384410 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.5 4.5E-02 -1. 0.3 2. Chi 0. 0. 4.5E-04 1.0E-03 3.4E-04 2.0E-05 1.2E-03 9.1E-05 2.6E-03 Composition Misfit: 5.731812E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.334 0.000000 0.000000 0.004667 0.000000 0.145675 0.003613 0.054971 0.427703 0.363371 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 4.8E-02 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.5E-03 1.4E-05 1.9E-02 1.0E-03 1.4E-03 Composition Misfit: 2.414705E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.492 0.000000 0.000000 0.253347 0.000000 0.726687 0.011144 0.008822 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -4. -0.2 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.3E-02 1.2E-04 1.6E-04 0. 0. Composition Misfit: 5.001242E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.828 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.647 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000021 -.000021 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023231 0.014699 0.006955 0.016413 0.052740 0.000915 0.040172 0.031995 0.001950 0.108100 0.702829 Mica 0.017933 0.002480 0.000000 0.063333 0.005515 0.000000 0.004936 0.165012 0.000522 0.239350 0.500919 Gt 0.000000 0.029574 0.000000 0.000000 0.285579 0.050430 0.070134 0.000000 0.002633 0.136464 0.425187 Fsp 0.094025 0.058968 0.000000 0.001491 0.000000 0.000000 0.000000 0.000000 0.000000 0.154484 0.691032 Bio 0.000000 0.000000 0.021837 0.066978 0.170202 0.001118 0.163012 0.112119 0.004110 0.120893 0.339731 St 0.000000 0.000000 0.004245 0.000000 0.132491 0.003286 0.049995 0.088129 0.002379 0.388992 0.330483 Ilm 0.000000 0.000000 0.225533 0.000000 0.646907 0.009920 0.007854 0.000000 0.109787 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776149. -754755. -931819. -850563. -314166. -465986. -638298. -291470. -408521. -1635682. -886473. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 56 converged, 25 successes so far. Misfit function evaluations this try => 204 Misfit this try = 0.189583 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 4.668551E-07 Bayes score, PP * exp(-Misfit) = 3.862312E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 12411.0 822.826 0.286763 0.664874 Final coordinates: 7480.86 850.220 0.768914 0.541558 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.189583 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.969 0.024647 0.002384 0.000000 0.073340 0.004570 0.000000 0.004532 0.290525 0.600002 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 1. 0. 1. -0.6 -2.0E-04 Chi 8.3E-03 0. 0. 1.7E-03 9.5E-03 0. 1.8E-02 3.5E-04 3.9E-12 Composition Misfit: 4.012189E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.587 0.000000 0.037883 0.000000 0.000000 0.279789 0.061598 0.056939 0.137303 0.426489 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -3. -0.2 0.5 -0.2 Chi 0. 7.9E-03 0. 0. 6.3E-03 1.2E-02 8.1E-05 3.1E-04 7.9E-06 Composition Misfit: 2.682040E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.125 0.094373 0.059346 0.000000 0.000954 0.000000 0.000000 0.000000 0.154673 0.690654 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 0.1 0. 0. 0. 0.4 0.2 Chi 7.9E-05 1.0E-03 0. 1.7E-04 0. 0. 0. 2.5E-04 2.1E-05 Composition Misfit: 1.533507E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.142 0.000000 0.000000 0.021949 0.075347 0.191359 0.001092 0.192277 0.130198 0.387779 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.1 -1. -0.5 0.1 -2. 0.7 1. Chi 0. 0. 1.5E-05 9.4E-04 2.5E-04 1.0E-04 2.7E-03 7.9E-04 2.0E-03 Composition Misfit: 6.827373E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.576 0.000000 0.000000 0.004008 0.000000 0.151866 0.003592 0.048422 0.428575 0.363537 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -2. 0.1 -3. 1. 1. Chi 0. 0. 2.8E-03 0. 2.9E-03 1.7E-05 1.3E-02 9.3E-04 1.4E-03 Composition Misfit: 2.140922E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.762 0.000000 0.000000 0.226038 0.000000 0.757835 0.010456 0.005671 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -6. -0.1 0.7 0. 0. Chi 0. 0. 0.1 0. 2.2E-02 2.0E-05 3.3E-03 0. 0. Composition Misfit: 9.287038E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.455 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.383 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023231 0.014699 0.006955 0.016414 0.052741 0.000915 0.040173 0.031392 0.002535 0.108102 0.702842 Mica 0.020560 0.001989 0.000000 0.061178 0.003812 0.000000 0.003780 0.165464 0.000374 0.242345 0.500499 Gt 0.000000 0.037792 0.000000 0.000000 0.279110 0.061448 0.056801 0.000000 0.002424 0.136970 0.425455 Fsp 0.094373 0.059346 0.000000 0.000954 0.000000 0.000000 0.000000 0.000000 0.000000 0.154673 0.690654 Bio 0.000000 0.000000 0.019364 0.066474 0.168826 0.000963 0.169636 0.113585 0.004168 0.114867 0.342117 St 0.000000 0.000000 0.003645 0.000000 0.138130 0.003267 0.044042 0.088175 0.002273 0.389812 0.330656 Ilm 0.000000 0.000000 0.198806 0.000000 0.666532 0.009197 0.004988 0.000000 0.120478 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -763071. -747101. -924324. -838007. -306525. -456300. -633148. -286590. -407146. -1626305. -880793. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 58 converged, 26 successes so far. Misfit function evaluations this try => 172 Misfit this try = 6.821174E-02 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.745960E-07 Bayes score, PP * exp(-Misfit) = 9.103337E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 7798.36 966.608 0.143938 0.827543 Final coordinates: 8980.24 930.340 0.402087 0.463007 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.821174E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.108 0.021979 0.003116 0.000000 0.075246 0.007115 0.000000 0.006297 0.285738 0.600508 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.6 0. 1. -0.3 -0.1 Chi 6.1E-03 0. 0. 1.1E-03 2.3E-03 0. 8.3E-03 9.7E-05 4.3E-07 Composition Misfit: 2.112366E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.013 0.000000 0.031775 0.000000 0.000000 0.306111 0.027223 0.072116 0.136563 0.426211 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 0.9 0.8 -2. 0.5 -0.2 Chi 0. 4.0E-03 0. 0. 8.2E-04 1.8E-03 4.2E-03 3.9E-04 5.7E-06 Composition Misfit: 1.114813E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.468 0.095130 0.056700 0.000000 0.001520 0.000000 0.000000 0.000000 0.153350 0.693300 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.5 0. -4.7E-02 0. 0. 0. 0.5 0.1 Chi 1.3E-04 4.6E-04 0. 1.7E-05 0. 0. 0. 3.7E-04 2.1E-06 Composition Misfit: 9.776355E-4 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.530 0.000000 0.000000 0.025083 0.075672 0.197043 0.000691 0.180673 0.135085 0.385753 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.8 0.2 -0.8 0.4 2. Chi 0. 0. 5.5E-04 1.0E-03 8.0E-04 7.8E-04 6.9E-04 2.0E-04 2.4E-03 Composition Misfit: 6.392361E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.008 0.000000 0.000000 0.004926 0.000000 0.148087 0.001889 0.054019 0.427690 0.363389 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.4 -4. 1. 1. Chi 0. 0. 1.2E-03 0. 2.0E-03 2.0E-03 1.8E-02 1.0E-03 1.4E-03 Composition Misfit: 2.550835E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.324 0.000000 0.000000 0.362758 0.000000 0.616968 0.006840 0.013434 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.7 0. 0.6 0.5 -0.5 0. 0. Chi 0. 0. 4.5E-04 0. 2.8E-04 1.5E-03 8.8E-04 0. 0. Composition Misfit: 3.061618E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.578 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.972 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023366 0.014784 0.006995 0.016509 0.053047 0.000921 0.040406 0.026994 0.001333 0.108729 0.706916 Mica 0.018344 0.002601 0.000000 0.062800 0.005939 0.000000 0.005256 0.164887 0.000519 0.238475 0.501181 Gt 0.000000 0.031687 0.000000 0.000000 0.305271 0.027149 0.071918 0.000000 0.002746 0.136188 0.425041 Fsp 0.095130 0.056700 0.000000 0.001520 0.000000 0.000000 0.000000 0.000000 0.000000 0.153350 0.693300 Bio 0.000000 0.000000 0.022183 0.066925 0.174267 0.000611 0.159790 0.111667 0.003922 0.119470 0.341164 St 0.000000 0.000000 0.004480 0.000000 0.134692 0.001718 0.049133 0.088138 0.002316 0.389003 0.330519 Ilm 0.000000 0.000000 0.339464 0.000000 0.577349 0.006401 0.012572 0.000000 0.064215 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774975. -754154. -931446. -849216. -314033. -471124. -638309. -291267. -410321. -1635542. -885856. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 65 converged, 27 successes so far. Misfit function evaluations this try => 228 Misfit this try = 0.117824 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.934174E-07 Bayes score, PP * exp(-Misfit) = 8.830016E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 8697.66 920.532 0.907204 0.910744 Final coordinates: 8556.91 920.195 0.575898 0.481602 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.117824 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.045 0.021665 0.002934 0.000000 0.075718 0.006771 0.000000 0.005979 0.286510 0.600424 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.4 -0.1 Chi 5.9E-03 0. 0. 1.0E-03 2.8E-03 0. 9.6E-03 1.3E-04 3.0E-07 Composition Misfit: 2.238790E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.167 0.000000 0.031206 0.000000 0.000000 0.296805 0.039617 0.069497 0.136636 0.426239 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.6 -1. 0.5 -0.2 Chi 0. 3.6E-03 0. 0. 2.1E-03 7.3E-04 3.1E-03 3.8E-04 5.9E-06 Composition Misfit: 9.988218E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.572 0.094597 0.057868 0.000000 0.001468 0.000000 0.000000 0.000000 0.153934 0.692132 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -3.2E-02 0. 0. 0. 0.5 0.1 Chi 9.2E-05 6.8E-04 0. 8.3E-06 0. 0. 0. 3.1E-04 8.1E-06 Composition Misfit: 1.103169E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.546 0.000000 0.000000 0.024578 0.075708 0.196281 0.000971 0.181742 0.135627 0.385093 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.8 0.1 -0.8 0.3 2. Chi 0. 0. 4.2E-04 1.0E-03 7.1E-04 2.1E-04 8.2E-04 1.6E-04 2.5E-03 Composition Misfit: 5.811893E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.000 0.000000 0.000000 0.004627 0.000000 0.148197 0.002746 0.053350 0.427711 0.363369 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.6E-03 0. 2.0E-03 4.4E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.381385E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.476 0.000000 0.000000 0.250314 0.000000 0.732836 0.008428 0.008422 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.3 0.3 0. 0. Chi 0. 0. 4.0E-02 0. 1.4E-02 2.9E-04 3.0E-04 0. 0. Composition Misfit: 5.471896E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.919 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.275 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023327 0.014760 0.006984 0.016482 0.052959 0.000919 0.040339 0.028032 0.001906 0.108549 0.705744 Mica 0.018079 0.002448 0.000000 0.063186 0.005650 0.000000 0.004989 0.164980 0.000519 0.239093 0.501054 Gt 0.000000 0.031121 0.000000 0.000000 0.296000 0.039509 0.069308 0.000000 0.002714 0.136266 0.425082 Fsp 0.094597 0.057868 0.000000 0.001468 0.000000 0.000000 0.000000 0.000000 0.000000 0.153934 0.692132 Bio 0.000000 0.000000 0.021722 0.066912 0.173476 0.000858 0.160626 0.112102 0.004083 0.119869 0.340350 St 0.000000 0.000000 0.004208 0.000000 0.134783 0.002497 0.048521 0.088128 0.002387 0.388997 0.330479 Ilm 0.000000 0.000000 0.222532 0.000000 0.651501 0.007493 0.007488 0.000000 0.110987 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774544. -753872. -931192. -848816. -313421. -467321. -637933. -291012. -408862. -1634831. -885722. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 66 converged, 28 successes so far. Misfit function evaluations this try => 155 Misfit this try = 0.120065 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.928859E-07 Bayes score, PP * exp(-Misfit) = 8.805535E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 12697.3 845.684 0.523110 0.603215 Final coordinates: 8797.20 925.784 0.611446 0.556579 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.119721 Extraneous predicted phases: 3.445317E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.038 0.022407 0.003252 0.000000 0.074790 0.006785 0.000000 0.006247 0.286322 0.600198 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.3 -2.5E-02 Chi 6.5E-03 0. 0. 1.3E-03 2.8E-03 0. 8.5E-03 1.2E-04 6.5E-08 Composition Misfit: 2.244455E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.108 0.000000 0.032652 0.000000 0.000000 0.293701 0.037927 0.073219 0.136364 0.426137 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.4 -2. 0.5 -0.2 Chi 0. 4.5E-03 0. 0. 2.7E-03 3.6E-04 4.6E-03 4.1E-04 5.1E-06 Composition Misfit: 1.260573E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.133 0.094342 0.058423 0.000000 0.001446 0.000000 0.000000 0.000000 0.154211 0.691577 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -2.6E-02 0. 0. 0. 0.5 0.1 Chi 7.7E-05 8.0E-04 0. 5.4E-06 0. 0. 0. 2.9E-04 1.2E-05 Composition Misfit: 1.182253E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.863 0.000000 0.000000 0.024561 0.075645 0.190445 0.000949 0.188117 0.134671 0.385612 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.4 0.1 -1. 0.4 2. Chi 0. 0. 4.2E-04 1.0E-03 1.9E-04 2.4E-04 1.8E-03 2.4E-04 2.4E-03 Composition Misfit: 6.302784E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.497 0.000000 0.000000 0.004785 0.000000 0.144962 0.002655 0.056692 0.427561 0.363345 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 1.3E-03 5.3E-04 2.0E-02 1.0E-03 1.5E-03 Composition Misfit: 2.581075E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.544 0.000000 0.000000 0.252802 0.000000 0.729643 0.008347 0.009208 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.3 0.1 0. 0. Chi 0. 0. 3.7E-02 0. 1.4E-02 3.3E-04 6.8E-05 0. 0. Composition Misfit: 5.137447E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.371 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.389 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.058 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000020 -.000020 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023223 0.014694 0.006953 0.016408 0.052722 0.000915 0.040159 0.032251 0.002015 0.108064 0.702595 Mica 0.018699 0.002714 0.000000 0.062415 0.005662 0.000000 0.005213 0.164942 0.000525 0.238945 0.500885 Gt 0.000000 0.032559 0.000000 0.000000 0.292869 0.037820 0.073012 0.000000 0.002832 0.135978 0.424930 Fsp 0.094342 0.058423 0.000000 0.001446 0.000000 0.000000 0.000000 0.000000 0.000000 0.154211 0.691577 Bio 0.000000 0.000000 0.021710 0.066863 0.168336 0.000839 0.166278 0.112016 0.004079 0.119036 0.340844 St 0.000000 0.000000 0.004352 0.000000 0.131841 0.002415 0.051561 0.088122 0.002393 0.388860 0.330457 Ilm 0.000000 0.000000 0.224993 0.000000 0.649380 0.007429 0.008195 0.000000 0.110003 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774865. -753806. -931283. -849355. -313979. -468159. -637886. -291002. -408096. -1635206. -885778. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 68 converged, 29 successes so far. Misfit function evaluations this try => 195 Misfit this try = 0.188775 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 1.072661E-06 Bayes score, PP * exp(-Misfit) = 8.881338E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 7891.16 916.888 0.832655 0.728486 Final coordinates: 9026.00 921.855 0.852994 0.710781 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.184487 Extraneous predicted phases: 4.288104E-3 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.299 0.024733 0.003888 0.000000 0.072167 0.006354 0.000000 0.006480 0.286917 0.599461 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 0.7 0. 1. -0.4 0.1 Chi 8.4E-03 0. 0. 2.1E-03 3.6E-03 0. 7.7E-03 1.4E-04 4.8E-07 Composition Misfit: 2.581333E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.788 0.000000 0.037536 0.000000 0.000000 0.281331 0.040702 0.079144 0.135482 0.425806 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.7 -2. 0.6 -0.1 Chi 0. 7.7E-03 0. 0. 5.9E-03 1.0E-03 7.5E-03 5.2E-04 3.1E-06 Composition Misfit: 2.257703E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.087 0.093648 0.060133 0.000000 0.001286 0.000000 0.000000 0.000000 0.155066 0.689867 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 2.1E-02 0. 0. 0. 0.4 0.2 Chi 4.3E-05 1.2E-03 0. 4.0E-06 0. 0. 0. 2.2E-04 3.1E-05 Composition Misfit: 1.509080E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.484 0.000000 0.000000 0.023002 0.075421 0.176349 0.000980 0.206043 0.131321 0.386884 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.2 -1. 0.5 0.1 -2. 0.6 2. Chi 0. 0. 1.2E-04 9.5E-04 3.7E-04 2.0E-04 6.5E-03 6.2E-04 2.2E-03 Composition Misfit: 1.091917E-2 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.629 0.000000 0.000000 0.004458 0.000000 0.138050 0.002814 0.064049 0.427363 0.363267 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.5 0.2 -5. 1. 1. Chi 0. 0. 1.9E-03 0. 3.6E-04 3.7E-04 2.6E-02 1.1E-03 1.5E-03 Composition Misfit: 3.149513E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.868 0.000000 0.000000 0.225293 0.000000 0.759024 0.007606 0.008077 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -6. 0.4 0.3 0. 0. Chi 0. 0. 0.1 0. 2.2E-02 7.5E-04 4.6E-04 0. 0. Composition Misfit: 9.217315E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.015 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.630 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.201 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000015 -.000015 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022999 0.014552 0.006886 0.016250 0.052214 0.000906 0.039772 0.040790 0.002784 0.107023 0.695824 Mica 0.020640 0.003244 0.000000 0.060223 0.005302 0.000000 0.005408 0.164970 0.000532 0.239431 0.500249 Gt 0.000000 0.037415 0.000000 0.000000 0.280426 0.040571 0.078889 0.000000 0.003216 0.135046 0.424436 Fsp 0.093648 0.060133 0.000000 0.001286 0.000000 0.000000 0.000000 0.000000 0.000000 0.155066 0.689867 Bio 0.000000 0.000000 0.020307 0.066585 0.155687 0.000865 0.181902 0.112863 0.004301 0.115935 0.341555 St 0.000000 0.000000 0.004054 0.000000 0.125539 0.002559 0.058244 0.088092 0.002540 0.388631 0.330343 Ilm 0.000000 0.000000 0.198085 0.000000 0.667360 0.006687 0.007102 0.000000 0.120766 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -773096. -752211. -930895. -848185. -313697. -466924. -636658. -290009. -403938. -1634079. -884828. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 69 converged, 30 successes so far. Misfit function evaluations this try => 210 Misfit this try = 0.214571 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 2.074590E-07 Bayes score, PP * exp(-Misfit) = 1.673960E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 5484.63 878.499 0.942737 6.941835E-02 Final coordinates: 7382.61 820.428 0.813328 0.508248 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.214571 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.765 0.027224 0.002265 0.000000 0.070945 0.003806 0.000000 0.003914 0.292055 0.599791 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -3. 0. 0. 1. 1. 0. 1. -0.7 2.7E-02 Chi 1.0E-02 0. 0. 2.6E-03 1.4E-02 0. 2.4E-02 4.6E-04 7.3E-08 Composition Misfit: 5.363827E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.898 0.000000 0.045381 0.000000 0.000000 0.286724 0.053140 0.051095 0.137208 0.426453 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 2. -2. 0.4 0.5 -0.2 Chi 0. 1.4E-02 0. 0. 4.3E-03 6.7E-03 2.7E-04 3.2E-04 7.6E-06 Composition Misfit: 2.522182E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.053 0.094903 0.058662 0.000000 0.000767 0.000000 0.000000 0.000000 0.154331 0.691338 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.1E-04 8.5E-04 0. 4.6E-04 0. 0. 0. 2.8E-04 1.4E-05 Composition Misfit: 1.712552E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.478 0.000000 0.000000 0.020986 0.075062 0.193387 0.000793 0.193586 0.125937 0.390248 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 4.8E-02 -1. -0.6 0.2 -2. 1. 1. Chi 0. 0. 6.9E-06 8.8E-04 4.1E-04 5.0E-04 3.0E-03 1.6E-03 1.7E-03 Composition Misfit: 8.124362E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.447 0.000000 0.000000 0.003885 0.000000 0.156325 0.002735 0.044475 0.428958 0.363624 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -2. 0.2 -3. 1. 1. Chi 0. 0. 3.1E-03 0. 4.1E-03 4.5E-04 1.0E-02 8.9E-04 1.4E-03 Composition Misfit: 2.034258E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.848 0.000000 0.000000 0.220763 0.000000 0.766068 0.008282 0.004887 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -6. 0.3 0.8 0. 0. Chi 0. 0. 0.1 0. 2.4E-02 3.6E-04 5.4E-03 0. 0. Composition Misfit: 0.105532 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.448 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.062 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023273 0.014725 0.006967 0.016443 0.052835 0.000917 0.040245 0.029514 0.002686 0.108296 0.704099 Mica 0.022706 0.001889 0.000000 0.059172 0.003174 0.000000 0.003265 0.165645 0.000308 0.243588 0.500254 Gt 0.000000 0.045269 0.000000 0.000000 0.286017 0.053009 0.050969 0.000000 0.002466 0.136869 0.425401 Fsp 0.094903 0.058662 0.000000 0.000767 0.000000 0.000000 0.000000 0.000000 0.000000 0.154331 0.691338 Bio 0.000000 0.000000 0.018510 0.066206 0.170570 0.000699 0.170746 0.113903 0.004080 0.111079 0.344205 St 0.000000 0.000000 0.003534 0.000000 0.142195 0.002488 0.040455 0.088202 0.002183 0.390186 0.330757 Ilm 0.000000 0.000000 0.193717 0.000000 0.672215 0.007267 0.004288 0.000000 0.122513 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -756609. -743290. -920650. -831658. -303022. -453776. -630886. -284362. -407431. -1622102. -877993. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 71 converged, 31 successes so far. Misfit function evaluations this try => 255 Misfit this try = 0.126955 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.791761E-07 Bayes score, PP * exp(-Misfit) = 8.624324E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 8741.21 812.934 0.918267 0.234843 Final coordinates: 8565.28 922.128 0.636091 0.631905 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.125448 Extraneous predicted phases: 1.507017E-3 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.255 0.022486 0.003247 0.000000 0.074756 0.006485 0.000000 0.006096 0.286875 0.600056 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.4 -7.1E-03 Chi 6.5E-03 0. 0. 1.3E-03 3.4E-03 0. 9.1E-03 1.4E-04 5.2E-09 Composition Misfit: 2.366158E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.594 0.000000 0.032058 0.000000 0.000000 0.284507 0.047788 0.072886 0.136553 0.426208 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -1. -2. 0.5 -0.2 Chi 0. 4.1E-03 0. 0. 4.9E-03 3.8E-03 4.5E-03 3.9E-04 5.6E-06 Composition Misfit: 1.777392E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.905 0.093831 0.059509 0.000000 0.001415 0.000000 0.000000 0.000000 0.154755 0.690491 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. -1.7E-02 0. 0. 0. 0.4 0.2 Chi 5.1E-05 1.1E-03 0. 2.3E-06 0. 0. 0. 2.4E-04 2.3E-05 Composition Misfit: 1.372454E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.795 0.000000 0.000000 0.024444 0.075673 0.187230 0.001182 0.191054 0.135102 0.385314 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.2 0.1 -1. 0.4 2. Chi 0. 0. 3.9E-04 1.0E-03 4.1E-05 5.0E-05 2.4E-03 2.0E-04 2.4E-03 Composition Misfit: 6.548783E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.354 0.000000 0.000000 0.004776 0.000000 0.143204 0.003379 0.057671 0.427613 0.363357 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.9 0.1 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 1.0E-03 6.2E-05 2.1E-02 1.0E-03 1.4E-03 Composition Misfit: 2.586870E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.574 0.000000 0.000000 0.253032 0.000000 0.727121 0.010579 0.009268 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -4. -0.1 0.1 0. 0. Chi 0. 0. 3.7E-02 0. 1.3E-02 3.2E-05 5.8E-05 0. 0. Composition Misfit: 5.022229E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.723 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.677 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.121 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000019 -.000019 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023120 0.014629 0.006921 0.016335 0.052488 0.000911 0.039981 0.036454 0.002087 0.107586 0.699487 Mica 0.018764 0.002710 0.000000 0.062382 0.005411 0.000000 0.005087 0.165003 0.000515 0.239392 0.500736 Gt 0.000000 0.031970 0.000000 0.000000 0.283724 0.047657 0.072685 0.000000 0.002750 0.136178 0.425035 Fsp 0.093831 0.059509 0.000000 0.001415 0.000000 0.000000 0.000000 0.000000 0.000000 0.154755 0.690491 Bio 0.000000 0.000000 0.021603 0.066876 0.165463 0.001044 0.168843 0.112149 0.004109 0.119395 0.340519 St 0.000000 0.000000 0.004343 0.000000 0.130243 0.003074 0.052452 0.088126 0.002379 0.388912 0.330471 Ilm 0.000000 0.000000 0.225221 0.000000 0.647202 0.009416 0.008249 0.000000 0.109912 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775115. -753870. -931168. -849755. -313979. -466149. -637757. -290959. -407631. -1635122. -885912. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 72 converged, 32 successes so far. Misfit function evaluations this try => 217 Misfit this try = 0.116469 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.670525E-07 Bayes score, PP * exp(-Misfit) = 8.607326E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 5922.21 871.059 0.936424 0.365649 Final coordinates: 8732.84 927.075 0.577630 0.515277 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.115466 Extraneous predicted phases: 1.002463E-3 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.606 0.021811 0.003090 0.000000 0.075459 0.006939 0.000000 0.006177 0.286149 0.600374 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.6 0. 1. -0.3 -4.8E-02 Chi 6.0E-03 0. 0. 1.1E-03 2.6E-03 0. 8.8E-03 1.1E-04 2.3E-07 Composition Misfit: 2.164256E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.251 0.000000 0.031360 0.000000 0.000000 0.297237 0.036952 0.071781 0.136487 0.426183 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.3 -2. 0.5 -0.2 Chi 0. 3.7E-03 0. 0. 2.0E-03 2.0E-04 4.0E-03 4.0E-04 5.5E-06 Composition Misfit: 1.039555E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.425 0.094561 0.057879 0.000000 0.001499 0.000000 0.000000 0.000000 0.153940 0.692121 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.1E-02 0. 0. 0. 0.5 0.1 Chi 9.0E-05 6.8E-04 0. 1.3E-05 0. 0. 0. 3.1E-04 8.2E-06 Composition Misfit: 1.107735E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.043 0.000000 0.000000 0.024744 0.075702 0.194455 0.000931 0.183469 0.135530 0.385169 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.7 0.1 -1. 0.3 2. Chi 0. 0. 4.6E-04 1.0E-03 5.1E-04 2.6E-04 1.1E-03 1.7E-04 2.5E-03 Composition Misfit: 5.936316E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.552 0.000000 0.000000 0.004734 0.000000 0.146847 0.002595 0.054873 0.427600 0.363350 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 1.7E-03 6.0E-04 1.9E-02 1.0E-03 1.5E-03 Composition Misfit: 2.479598E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.485 0.000000 0.000000 0.252910 0.000000 0.730096 0.008063 0.008931 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.3 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.4E-02 4.7E-04 1.3E-04 0. 0. Composition Misfit: 5.158831E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.296 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.243 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.099 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000021 -.000021 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023281 0.014731 0.006970 0.016449 0.052855 0.000917 0.040260 0.029933 0.001908 0.108336 0.704360 Mica 0.018202 0.002579 0.000000 0.062974 0.005791 0.000000 0.005155 0.164931 0.000531 0.238802 0.501034 Gt 0.000000 0.031272 0.000000 0.000000 0.296411 0.036850 0.071581 0.000000 0.002779 0.136108 0.424998 Fsp 0.094561 0.057879 0.000000 0.001499 0.000000 0.000000 0.000000 0.000000 0.000000 0.153940 0.692121 Bio 0.000000 0.000000 0.021873 0.066918 0.171891 0.000823 0.162180 0.111963 0.004073 0.119803 0.340476 St 0.000000 0.000000 0.004306 0.000000 0.133555 0.002361 0.049906 0.088123 0.002394 0.388895 0.330461 Ilm 0.000000 0.000000 0.225100 0.000000 0.649815 0.007176 0.007949 0.000000 0.109960 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775395. -754302. -931686. -849716. -314090. -468578. -638236. -291307. -408735. -1635553. -886066. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 74 converged, 33 successes so far. Misfit function evaluations this try => 550 Misfit this try = 0.138694 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 1.057675E-06 Bayes score, PP * exp(-Misfit) = 9.207003E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 8066.70 847.974 0.942007 0.460749 Final coordinates: 9011.27 923.161 0.682153 0.699549 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.133323 Extraneous predicted phases: 5.370858E-3 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.332 0.024209 0.003738 0.000000 0.072765 0.006400 0.000000 0.006384 0.286833 0.599671 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 0.7 0. 1. -0.4 4.2E-02 Chi 7.9E-03 0. 0. 1.9E-03 3.5E-03 0. 8.0E-03 1.4E-04 1.8E-07 Composition Misfit: 2.525141E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.888 0.000000 0.036324 0.000000 0.000000 0.286382 0.038438 0.076841 0.136012 0.426004 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.5 -2. 0.6 -0.2 Chi 0. 6.9E-03 0. 0. 4.4E-03 4.6E-04 6.3E-03 4.5E-04 4.3E-06 Composition Misfit: 1.849756E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.306 0.093844 0.059666 0.000000 0.001323 0.000000 0.000000 0.000000 0.154833 0.690334 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 1.0E-02 0. 0. 0. 0.4 0.2 Chi 5.1E-05 1.1E-03 0. 9.2E-07 0. 0. 0. 2.4E-04 2.5E-05 Composition Misfit: 1.406558E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.207 0.000000 0.000000 0.024132 0.075496 0.181095 0.000936 0.199114 0.132435 0.386792 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. 0.2 0.1 -2. 0.6 2. Chi 0. 0. 3.2E-04 9.7E-04 6.3E-05 2.5E-04 4.4E-03 4.7E-04 2.2E-03 Composition Misfit: 8.668645E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.561 0.000000 0.000000 0.004962 0.000000 0.140335 0.002660 0.061261 0.427450 0.363331 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.7 0.3 -5. 1. 1. Chi 0. 0. 1.1E-03 0. 6.1E-04 5.2E-04 2.4E-02 1.0E-03 1.5E-03 Composition Misfit: 2.875016E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.669 0.000000 0.000000 0.252993 0.000000 0.728473 0.008564 0.009970 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 4.8E-03 0. 0. Chi 0. 0. 3.7E-02 0. 1.3E-02 2.4E-04 9.1E-08 0. 0. Composition Misfit: 5.074870E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.228 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.584 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.225 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000018 -.000018 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023027 0.014570 0.006894 0.016269 0.052277 0.000907 0.039820 0.040194 0.002229 0.107152 0.696662 Mica 0.020203 0.003120 0.000000 0.060724 0.005341 0.000000 0.005328 0.164973 0.000508 0.239367 0.500437 Gt 0.000000 0.036215 0.000000 0.000000 0.285527 0.038323 0.076611 0.000000 0.002986 0.135605 0.424732 Fsp 0.093844 0.059666 0.000000 0.001323 0.000000 0.000000 0.000000 0.000000 0.000000 0.154833 0.690334 Bio 0.000000 0.000000 0.021328 0.066723 0.160052 0.000827 0.175976 0.112118 0.004085 0.117046 0.341845 St 0.000000 0.000000 0.004513 0.000000 0.127634 0.002419 0.055717 0.088120 0.002383 0.388764 0.330449 Ilm 0.000000 0.000000 0.225182 0.000000 0.648394 0.007623 0.008874 0.000000 0.109927 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -773425. -752523. -930233. -848346. -313697. -467536. -637025. -290218. -406551. -1634320. -885003. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 75 converged, 34 successes so far. Misfit function evaluations this try => 281 Misfit this try = 0.113709 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.408240E-07 Bayes score, PP * exp(-Misfit) = 8.397017E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 8695.66 829.929 0.914609 6.706613E-02 Final coordinates: 8558.75 926.114 0.562694 0.489285 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.113709 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.050 0.021356 0.002964 0.000000 0.075994 0.006910 0.000000 0.006040 0.286302 0.600433 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.7E-03 0. 0. 9.4E-04 2.6E-03 0. 9.3E-03 1.2E-04 3.1E-07 Composition Misfit: 2.162535E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.069 0.000000 0.030138 0.000000 0.000000 0.295536 0.041050 0.070364 0.136664 0.426249 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.7 -1. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 2.4E-03 1.1E-03 3.4E-03 3.8E-04 5.9E-06 Composition Misfit: 1.036157E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.591 0.094465 0.058018 0.000000 0.001526 0.000000 0.000000 0.000000 0.154009 0.691982 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.9E-02 0. 0. 0. 0.5 0.1 Chi 8.4E-05 7.1E-04 0. 1.9E-05 0. 0. 0. 3.1E-04 9.2E-06 Composition Misfit: 1.130580E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.506 0.000000 0.000000 0.024829 0.075764 0.196187 0.001037 0.181074 0.136459 0.384650 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.8 0.1 -0.8 0.3 2. Chi 0. 0. 4.8E-04 1.0E-03 7.0E-04 1.4E-04 7.4E-04 1.1E-04 2.5E-03 Composition Misfit: 5.745590E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.517 0.000000 0.000000 0.004675 0.000000 0.147579 0.002905 0.053821 0.427660 0.363360 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.9E-03 3.0E-04 1.8E-02 1.0E-03 1.4E-03 Composition Misfit: 2.386542E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.452 0.000000 0.000000 0.253038 0.000000 0.729285 0.008955 0.008722 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.4E-02 1.2E-04 1.9E-04 0. 0. Composition Misfit: 5.098088E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.458 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.356 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023318 0.014754 0.006981 0.016475 0.052937 0.000919 0.040323 0.028468 0.001862 0.108505 0.705460 Mica 0.017822 0.002473 0.000000 0.063418 0.005767 0.000000 0.005040 0.164954 0.000531 0.238923 0.501070 Gt 0.000000 0.030056 0.000000 0.000000 0.294737 0.040939 0.070174 0.000000 0.002702 0.136294 0.425097 Fsp 0.094465 0.058018 0.000000 0.001526 0.000000 0.000000 0.000000 0.000000 0.000000 0.154009 0.691982 Bio 0.000000 0.000000 0.021947 0.066970 0.173414 0.000917 0.160056 0.111993 0.004083 0.120619 0.340002 St 0.000000 0.000000 0.004252 0.000000 0.134221 0.002642 0.048949 0.088125 0.002390 0.388950 0.330471 Ilm 0.000000 0.000000 0.225226 0.000000 0.649129 0.007971 0.007764 0.000000 0.109909 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775945. -754710. -931954. -850185. -314161. -467812. -638453. -291530. -409018. -1635776. -886361. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 78 converged, 35 successes so far. Misfit function evaluations this try => 180 Misfit this try = 6.115634E-02 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.405630E-07 Bayes score, PP * exp(-Misfit) = 8.847652E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 8503.99 961.590 0.545077 0.597743 Final coordinates: 8628.32 927.597 0.424685 0.499072 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.114270E-2 Extraneous predicted phases: 1.363919E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.008 0.021239 0.002961 0.000000 0.076100 0.006999 0.000000 0.006068 0.286132 0.600500 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.2E-04 2.5E-03 0. 9.2E-03 1.1E-04 4.2E-07 Composition Misfit: 2.124880E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.219 0.000000 0.030236 0.000000 0.000000 0.299239 0.037464 0.070069 0.136721 0.426271 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.4 -1. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 1.7E-03 2.8E-04 3.3E-03 3.7E-04 6.1E-06 Composition Misfit: 8.805405E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.573 0.094555 0.057805 0.000000 0.001543 0.000000 0.000000 0.000000 0.153902 0.692195 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.9E-05 6.7E-04 0. 2.2E-05 0. 0. 0. 3.2E-04 7.7E-06 Composition Misfit: 1.103956E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.536 0.000000 0.000000 0.025045 0.075770 0.197988 0.000952 0.178924 0.136556 0.384765 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.4E-04 1.0E-03 9.2E-04 2.3E-04 4.9E-04 1.0E-04 2.5E-03 Composition Misfit: 5.850239E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.032 0.000000 0.000000 0.004757 0.000000 0.148379 0.002644 0.053122 0.427716 0.363382 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 5.4E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.358171E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.316 0.000000 0.000000 0.347401 0.000000 0.630757 0.009370 0.012472 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. -3.5E-02 0.1 -0.4 0. 0. Chi 0. 0. 1.9E-05 0. 9.1E-07 4.2E-05 4.9E-04 0. 0. Composition Misfit: 5.525887E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.973 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.332 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.012 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000023 -.000023 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023315 0.014752 0.006980 0.016473 0.052931 0.000919 0.040318 0.029034 0.001405 0.108493 0.705380 Mica 0.017725 0.002471 0.000000 0.063508 0.005841 0.000000 0.005064 0.164937 0.000526 0.238788 0.501140 Gt 0.000000 0.030155 0.000000 0.000000 0.298438 0.037364 0.069881 0.000000 0.002677 0.136355 0.425129 Fsp 0.094555 0.057805 0.000000 0.001543 0.000000 0.000000 0.000000 0.000000 0.000000 0.153902 0.692195 Bio 0.000000 0.000000 0.022143 0.066992 0.175051 0.000841 0.158196 0.111841 0.004010 0.120736 0.340189 St 0.000000 0.000000 0.004327 0.000000 0.134953 0.002405 0.048315 0.088134 0.002351 0.389014 0.330501 Ilm 0.000000 0.000000 0.322774 0.000000 0.586042 0.008706 0.011588 0.000000 0.070891 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775972. -754731. -931920. -850120. -314177. -468637. -638571. -291588. -409875. -1635863. -886363. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 79 converged, 36 successes so far. Misfit function evaluations this try => 168 Misfit this try = 0.102143 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 1.288795E-07 Bayes score, PP * exp(-Misfit) = 1.163653E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 5888.94 816.643 0.435238 0.730301 Final coordinates: 7127.51 809.713 0.447623 0.483846 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.102120 Extraneous predicted phases: 2.291118E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.015 0.024535 0.001782 0.000000 0.073857 0.004033 0.000000 0.003891 0.291571 0.600331 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 1. 0. 1. -0.6 -4.2E-02 Chi 8.2E-03 0. 0. 1.5E-03 1.3E-02 0. 2.4E-02 4.2E-04 1.8E-07 Composition Misfit: 4.845645E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.096 0.000000 0.044304 0.000000 0.000000 0.297417 0.048086 0.046327 0.137358 0.426509 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 1. -2. 0.8 0.5 -0.2 Chi 0. 1.3E-02 0. 0. 2.0E-03 4.0E-03 1.5E-03 3.1E-04 8.0E-06 Composition Misfit: 2.060042E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.417 0.095382 0.057682 0.000000 0.000777 0.000000 0.000000 0.000000 0.153841 0.692318 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.5E-04 6.4E-04 0. 4.3E-04 0. 0. 0. 3.2E-04 6.9E-06 Composition Misfit: 1.552904E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.876 0.000000 0.000000 0.020552 0.075098 0.204810 0.000684 0.182589 0.126470 0.389797 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 0.1 -1. -1. 0.2 -0.9 1. 1. Chi 0. 0. 3.2E-05 8.8E-04 2.0E-03 8.0E-04 9.4E-04 1.5E-03 1.8E-03 Composition Misfit: 7.942424E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.029 0.000000 0.000000 0.003422 0.000000 0.162241 0.002352 0.039138 0.429201 0.363646 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. 0.3 -2. 1. 1. Chi 0. 0. 4.5E-03 0. 6.0E-03 9.4E-04 6.7E-03 8.7E-04 1.4E-03 Composition Misfit: 2.040513E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.473 0.000000 0.000000 0.375326 0.000000 0.607807 0.008864 0.008003 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 1. 0.2 0.3 0. 0. Chi 0. 0. 1.7E-03 0. 8.1E-04 1.5E-04 5.0E-04 0. 0. Composition Misfit: 3.163083E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.155 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.936 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.003 0.000000 0.000000 0.176274 0.000000 0.685678 0.005468 0.003090 0.000000 0.129491 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023334 0.014764 0.006986 0.016486 0.052974 0.000919 0.040351 0.028171 0.001482 0.108581 0.705952 Mica 0.020464 0.001487 0.000000 0.061602 0.003364 0.000000 0.003245 0.165618 0.000315 0.243190 0.500717 Gt 0.000000 0.044197 0.000000 0.000000 0.296703 0.047970 0.046216 0.000000 0.002400 0.137028 0.425485 Fsp 0.095382 0.057682 0.000000 0.000777 0.000000 0.000000 0.000000 0.000000 0.000000 0.153841 0.692318 Bio 0.000000 0.000000 0.018118 0.066203 0.180552 0.000603 0.160963 0.114289 0.004152 0.111491 0.343629 St 0.000000 0.000000 0.003113 0.000000 0.147570 0.002139 0.035599 0.088203 0.002225 0.390389 0.330762 Ilm 0.000000 0.000000 0.353302 0.000000 0.572141 0.008344 0.007534 0.000000 0.058679 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -755211. -742760. -920588. -829595. -301780. -453357. -630706. -284221. -408068. -1621098. -877506. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 81 converged, 37 successes so far. Misfit function evaluations this try => 240 Misfit this try = 0.115806 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.659147E-07 Bayes score, PP * exp(-Misfit) = 8.602897E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 13531.5 836.829 0.914639 7.632803E-02 Final coordinates: 8696.83 926.494 0.582281 0.507371 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.115806 Extraneous predicted phases: 1.630341E-8 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.820 0.021816 0.003091 0.000000 0.075461 0.006893 0.000000 0.006156 0.286233 0.600351 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.3 -4.5E-02 Chi 6.0E-03 0. 0. 1.1E-03 2.6E-03 0. 8.9E-03 1.2E-04 2.0E-07 Composition Misfit: 2.180645E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.153 0.000000 0.031316 0.000000 0.000000 0.295764 0.038477 0.071744 0.136508 0.426191 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.5 -2. 0.5 -0.2 Chi 0. 3.7E-03 0. 0. 2.3E-03 4.7E-04 4.0E-03 3.9E-04 5.5E-06 Composition Misfit: 1.088352E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.417 0.094471 0.058070 0.000000 0.001494 0.000000 0.000000 0.000000 0.154035 0.691930 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -3.9E-02 0. 0. 0. 0.5 0.1 Chi 8.4E-05 7.2E-04 0. 1.2E-05 0. 0. 0. 3.1E-04 9.6E-06 Composition Misfit: 1.133782E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.876 0.000000 0.000000 0.024722 0.075706 0.193932 0.000968 0.183957 0.135591 0.385124 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.6 0.1 -1. 0.3 2. Chi 0. 0. 4.6E-04 1.0E-03 4.6E-04 2.2E-04 1.1E-03 1.6E-04 2.5E-03 Composition Misfit: 5.910489E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.079 0.000000 0.000000 0.004728 0.000000 0.146566 0.002707 0.055040 0.427607 0.363352 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 1.6E-03 4.7E-04 1.9E-02 1.0E-03 1.5E-03 Composition Misfit: 2.476280E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.491 0.000000 0.000000 0.252933 0.000000 0.729726 0.008402 0.008939 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.3 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.4E-02 3.0E-04 1.3E-04 0. 0. Composition Misfit: 5.130932E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.821 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.341 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000021 -.000021 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023292 0.014737 0.006973 0.016457 0.052878 0.000918 0.040278 0.029487 0.001924 0.108384 0.704672 Mica 0.018206 0.002580 0.000000 0.062975 0.005752 0.000000 0.005137 0.164940 0.000530 0.238870 0.501011 Gt 0.000000 0.031229 0.000000 0.000000 0.294945 0.038371 0.071545 0.000000 0.002770 0.136130 0.425010 Fsp 0.094471 0.058070 0.000000 0.001494 0.000000 0.000000 0.000000 0.000000 0.000000 0.154035 0.691930 Bio 0.000000 0.000000 0.021852 0.066919 0.171424 0.000856 0.162606 0.111986 0.004078 0.119854 0.340425 St 0.000000 0.000000 0.004300 0.000000 0.133299 0.002462 0.050058 0.088123 0.002393 0.388902 0.330462 Ilm 0.000000 0.000000 0.225123 0.000000 0.649492 0.007479 0.007956 0.000000 0.109951 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775437. -754299. -931664. -849775. -314089. -468232. -638214. -291299. -408665. -1635537. -886086. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 82 converged, 38 successes so far. Misfit function evaluations this try => 215 Misfit this try = 0.265937 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 1.193799E-07 Bayes score, PP * exp(-Misfit) = 9.150324E-08 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 13361.7 812.120 0.439143 0.314085 Final coordinates: 5566.48 836.972 0.733084 0.521297 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.265937 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.005 0.021002 0.001545 0.000000 0.077559 0.003947 0.000000 0.003580 0.292115 0.600251 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.6 1. 0. 1. -0.7 -3.2E-02 Chi 5.4E-03 0. 0. 6.1E-04 1.3E-02 0. 2.8E-02 4.6E-04 1.1E-07 Composition Misfit: 4.891910E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.038 0.000000 0.022738 0.000000 0.000000 0.242463 0.119034 0.049553 0.139063 0.427149 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.3 0. 0. 4. -9. 0.5 0.3 -0.3 Chi 0. 2.1E-04 0. 0. 2.6E-02 0.1 5.5E-04 1.6E-04 1.5E-05 Composition Misfit: 8.737451E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.608 0.094158 0.059532 0.000000 0.001077 0.000000 0.000000 0.000000 0.154766 0.690468 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 0.1 0. 0. 0. 0.4 0.2 Chi 6.7E-05 1.1E-03 0. 7.3E-05 0. 0. 0. 2.4E-04 2.4E-05 Composition Misfit: 1.464648E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.619 0.000000 0.000000 0.022351 0.075966 0.194781 0.002120 0.182934 0.139487 0.382360 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.1 -1. -0.7 -0.2 -0.9 0.1 2. Chi 0. 0. 4.3E-05 1.1E-03 5.5E-04 2.3E-04 9.8E-04 4.9E-06 3.0E-03 Composition Misfit: 5.827586E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.665 0.000000 0.000000 0.003545 0.000000 0.151570 0.007653 0.044486 0.429112 0.363634 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. -0.8 -3. 1. 1. Chi 0. 0. 4.0E-03 0. 2.8E-03 1.9E-03 1.0E-02 8.8E-04 1.4E-03 Composition Misfit: 2.146960E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.651 0.000000 0.000000 0.224316 0.000000 0.750321 0.020589 0.004774 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -6. -2. 0.8 0. 0. Chi 0. 0. 0.1 0. 1.9E-02 5.4E-03 5.7E-03 0. 0. Composition Misfit: 0.100881 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.580 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.833 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023261 0.014718 0.006964 0.016435 0.052809 0.000916 0.040225 0.030257 0.002420 0.108242 0.703752 Mica 0.017515 0.001289 0.000000 0.064681 0.003292 0.000000 0.002986 0.165681 0.000362 0.243611 0.500584 Gt 0.000000 0.022701 0.000000 0.000000 0.242061 0.118837 0.049471 0.000000 0.001657 0.138832 0.426441 Fsp 0.094158 0.059532 0.000000 0.001077 0.000000 0.000000 0.000000 0.000000 0.000000 0.154766 0.690468 Bio 0.000000 0.000000 0.019700 0.066958 0.171683 0.001869 0.161241 0.114215 0.004369 0.122946 0.337019 St 0.000000 0.000000 0.003224 0.000000 0.137865 0.006961 0.040464 0.088201 0.002222 0.390310 0.330753 Ilm 0.000000 0.000000 0.197141 0.000000 0.659425 0.018095 0.004196 0.000000 0.121143 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -768422. -751556. -926606. -843626. -307563. -451941. -634647. -288611. -408149. -1628467. -883825. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Sp Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Sp Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Ilm Gt Mica Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Ilm Gt Mica Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 89 converged, 39 successes so far. Misfit function evaluations this try => 189 Misfit this try = 0.197675 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 3.607775E-07 Bayes score, PP * exp(-Misfit) = 2.960672E-07 Best Bayes score so far = 9.587928E-07 obtained on Try 26 P_bar T_K C_O2 C_H2O Initial coordinates: 5693.18 896.112 0.944492 0.356238 Final coordinates: 7625.65 836.358 0.791437 0.516510 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.197675 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.899 0.026448 0.002419 0.000000 0.071573 0.004225 0.000000 0.004288 0.291201 0.599847 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -3. 0. 0. 1. 1. 0. 1. -0.6 2.0E-02 Chi 9.8E-03 0. 0. 2.3E-03 1.1E-02 0. 2.0E-02 3.9E-04 3.9E-08 Composition Misfit: 4.628326E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.918 0.000000 0.043411 0.000000 0.000000 0.287887 0.050706 0.054574 0.137034 0.426388 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 2. -2. 2.1E-02 0.5 -0.2 Chi 0. 1.2E-02 0. 0. 4.0E-03 5.3E-03 8.9E-07 3.4E-04 7.0E-06 Composition Misfit: 2.175248E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.042 0.094812 0.058682 0.000000 0.000847 0.000000 0.000000 0.000000 0.154341 0.691318 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 8.6E-04 0. 3.1E-04 0. 0. 0. 2.8E-04 1.5E-05 Composition Misfit: 1.562635E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.321 0.000000 0.000000 0.021430 0.075147 0.192364 0.000825 0.193503 0.127198 0.389533 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -7.9E-03 -1. -0.5 0.2 -2. 0.9 1. Chi 0. 0. 1.8E-07 8.9E-04 3.2E-04 4.4E-04 3.0E-03 1.4E-03 1.8E-03 Composition Misfit: 7.771411E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.980 0.000000 0.000000 0.003991 0.000000 0.154313 0.002748 0.046663 0.428715 0.363571 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -2. 0.2 -3. 1. 1. Chi 0. 0. 2.8E-03 0. 3.5E-03 4.3E-04 1.2E-02 9.2E-04 1.4E-03 Composition Misfit: 2.115167E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.813 0.000000 0.000000 0.223523 0.000000 0.762899 0.008235 0.005343 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -6. 0.3 0.7 0. 0. Chi 0. 0. 0.1 0. 2.3E-02 3.8E-04 4.1E-03 0. 0. Composition Misfit: 9.915350E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.902 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.125 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023263 0.014719 0.006965 0.016436 0.052814 0.000917 0.040229 0.029981 0.002612 0.108251 0.703812 Mica 0.022061 0.002017 0.000000 0.059700 0.003524 0.000000 0.003576 0.165540 0.000339 0.242897 0.500345 Gt 0.000000 0.043301 0.000000 0.000000 0.287155 0.050577 0.054435 0.000000 0.002541 0.136686 0.425304 Fsp 0.094812 0.058682 0.000000 0.000847 0.000000 0.000000 0.000000 0.000000 0.000000 0.154341 0.691318 Bio 0.000000 0.000000 0.018906 0.066295 0.169707 0.000728 0.170711 0.113685 0.004100 0.112216 0.343652 St 0.000000 0.000000 0.003630 0.000000 0.140360 0.002499 0.042443 0.088186 0.002233 0.389951 0.330697 Ilm 0.000000 0.000000 0.196376 0.000000 0.670245 0.007235 0.004694 0.000000 0.121450 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -759192. -744739. -922214. -834181. -304613. -455814. -631843. -285247. -407220. -1623921. -879045. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 91 converged, 40 successes so far. Misfit function evaluations this try => 185 Misfit this try = 6.256110E-02 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 1.026579E-06 Bayes score, PP * exp(-Misfit) = 9.643230E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 8712.64 961.922 8.472907E-02 0.944073 Final coordinates: 8448.90 910.690 0.423170 0.494696 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.256110E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.009 0.021701 0.002792 0.000000 0.075788 0.006551 0.000000 0.005784 0.286894 0.600491 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.4 -0.1 Chi 5.9E-03 0. 0. 9.9E-04 3.2E-03 0. 1.0E-02 1.4E-04 4.0E-07 Composition Misfit: 2.351045E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.217 0.000000 0.032046 0.000000 0.000000 0.299577 0.038522 0.066708 0.136834 0.426313 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.5 -1. 0.5 -0.2 Chi 0. 4.1E-03 0. 0. 1.7E-03 4.7E-04 2.1E-03 3.6E-04 6.4E-06 Composition Misfit: 8.758523E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.546 0.094705 0.057780 0.000000 0.001405 0.000000 0.000000 0.000000 0.153890 0.692220 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. -1.4E-02 0. 0. 0. 0.5 0.1 Chi 9.9E-05 6.6E-04 0. 1.6E-06 0. 0. 0. 3.2E-04 7.5E-06 Composition Misfit: 1.088632E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.598 0.000000 0.000000 0.024440 0.075676 0.198788 0.000907 0.179535 0.135144 0.385510 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -1. 0.1 -0.7 0.4 2. Chi 0. 0. 3.9E-04 1.0E-03 1.0E-03 3.0E-04 5.6E-04 2.0E-04 2.4E-03 Composition Misfit: 5.879511E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.728 0.000000 0.000000 0.004592 0.000000 0.150203 0.002591 0.051272 0.427922 0.363420 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.6E-03 0. 2.4E-03 6.0E-04 1.6E-02 9.9E-04 1.4E-03 Composition Misfit: 2.278421E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.335 0.000000 0.000000 0.355565 0.000000 0.623209 0.009267 0.011958 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.3 0. 0.3 0.1 -0.3 0. 0. Chi 0. 0. 8.7E-05 0. 7.4E-05 5.8E-05 3.2E-04 0. 0. Composition Misfit: 5.397759E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.294 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.273 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023321 0.014756 0.006982 0.016477 0.052945 0.000919 0.040329 0.028787 0.001400 0.108521 0.705563 Mica 0.018109 0.002330 0.000000 0.063243 0.005466 0.000000 0.004826 0.165033 0.000492 0.239406 0.501095 Gt 0.000000 0.031962 0.000000 0.000000 0.298789 0.038421 0.066533 0.000000 0.002628 0.136474 0.425192 Fsp 0.094705 0.057780 0.000000 0.001405 0.000000 0.000000 0.000000 0.000000 0.000000 0.153890 0.692220 Bio 0.000000 0.000000 0.021600 0.066884 0.175693 0.000802 0.158677 0.112168 0.004013 0.119443 0.340721 St 0.000000 0.000000 0.004176 0.000000 0.136614 0.002357 0.046633 0.088144 0.002329 0.389207 0.330541 Ilm 0.000000 0.000000 0.331616 0.000000 0.581234 0.008643 0.011153 0.000000 0.067353 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772775. -752854. -930113. -846966. -312299. -466398. -637346. -290398. -409650. -1633552. -884942. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 92 converged, 41 successes so far. Misfit function evaluations this try => 167 Misfit this try = 6.125360E-02 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.452842E-07 Bayes score, PP * exp(-Misfit) = 8.891198E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 6171.30 872.801 0.483875 0.317306 Final coordinates: 8578.44 926.093 0.423127 0.500970 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.125360E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.028 0.021215 0.002935 0.000000 0.076146 0.006941 0.000000 0.006022 0.286244 0.600497 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.1E-04 2.6E-03 0. 9.4E-03 1.2E-04 4.1E-07 Composition Misfit: 2.147584E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.151 0.000000 0.030156 0.000000 0.000000 0.298407 0.038734 0.069637 0.136775 0.426291 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.5 -1. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 1.9E-03 5.2E-04 3.2E-03 3.6E-04 6.3E-06 Composition Misfit: 8.967765E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.576 0.094513 0.057904 0.000000 0.001534 0.000000 0.000000 0.000000 0.153952 0.692096 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.7E-05 6.9E-04 0. 2.0E-05 0. 0. 0. 3.1E-04 8.4E-06 Composition Misfit: 1.116054E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.518 0.000000 0.000000 0.025018 0.075775 0.198034 0.000979 0.178840 0.136619 0.384735 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.3E-04 1.0E-03 9.3E-04 2.0E-04 4.9E-04 1.0E-04 2.5E-03 Composition Misfit: 5.811358E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.251 0.000000 0.000000 0.004744 0.000000 0.148453 0.002730 0.052940 0.427745 0.363388 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 4.5E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.337517E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.314 0.000000 0.000000 0.349521 0.000000 0.628308 0.009693 0.012479 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 2.6E-02 0. 0.1 4.9E-02 -0.4 0. 0. Chi 0. 0. 6.6E-07 0. 4.6E-06 9.7E-06 4.9E-04 0. 0. Composition Misfit: 5.074137E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.793 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.368 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023313 0.014751 0.006979 0.016471 0.052926 0.000919 0.040314 0.029141 0.001400 0.108481 0.705306 Mica 0.017705 0.002450 0.000000 0.063546 0.005792 0.000000 0.005026 0.164951 0.000522 0.238878 0.501131 Gt 0.000000 0.030076 0.000000 0.000000 0.297615 0.038631 0.069452 0.000000 0.002654 0.136412 0.425159 Fsp 0.094513 0.057904 0.000000 0.001534 0.000000 0.000000 0.000000 0.000000 0.000000 0.153952 0.692096 Bio 0.000000 0.000000 0.022119 0.066994 0.175087 0.000865 0.158117 0.111869 0.004009 0.120788 0.340153 St 0.000000 0.000000 0.004314 0.000000 0.135020 0.002483 0.048150 0.088136 0.002346 0.389042 0.330508 Ilm 0.000000 0.000000 0.325063 0.000000 0.584342 0.009014 0.011606 0.000000 0.069975 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775845. -754659. -931813. -849996. -314059. -468231. -638507. -291532. -409913. -1635730. -886313. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 98 converged, 42 successes so far. Misfit function evaluations this try => 196 Misfit this try = 0.134003 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 1.057925E-06 Bayes score, PP * exp(-Misfit) = 9.252485E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 5831.66 974.785 0.894253 0.491679 Final coordinates: 9012.85 923.162 0.684231 0.652610 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.134003 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.306 0.024200 0.003734 0.000000 0.072775 0.006406 0.000000 0.006386 0.286822 0.599677 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 0.7 0. 1. -0.4 4.1E-02 Chi 7.9E-03 0. 0. 1.9E-03 3.5E-03 0. 8.0E-03 1.4E-04 1.7E-07 Composition Misfit: 2.521835E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.902 0.000000 0.036329 0.000000 0.000000 0.286529 0.038300 0.076841 0.136001 0.426001 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.4 -2. 0.6 -0.2 Chi 0. 6.9E-03 0. 0. 4.4E-03 4.3E-04 6.3E-03 4.5E-04 4.2E-06 Composition Misfit: 1.843551E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.374 0.093859 0.059636 0.000000 0.001324 0.000000 0.000000 0.000000 0.154818 0.690364 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 9.9E-03 0. 0. 0. 0.4 0.2 Chi 5.2E-05 1.1E-03 0. 8.8E-07 0. 0. 0. 2.4E-04 2.5E-05 Composition Misfit: 1.400307E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.278 0.000000 0.000000 0.024114 0.075495 0.181160 0.000933 0.199088 0.132422 0.386789 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. 0.2 0.1 -2. 0.6 2. Chi 0. 0. 3.1E-04 9.7E-04 6.1E-05 2.6E-04 4.4E-03 4.7E-04 2.2E-03 Composition Misfit: 8.661646E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.479 0.000000 0.000000 0.004953 0.000000 0.140389 0.002649 0.061228 0.427449 0.363331 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.7 0.3 -5. 1. 1. Chi 0. 0. 1.1E-03 0. 6.2E-04 5.3E-04 2.4E-02 1.0E-03 1.5E-03 Composition Misfit: 2.875129E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.672 0.000000 0.000000 0.252372 0.000000 0.729223 0.008493 0.009912 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 1.4E-02 0. 0. Chi 0. 0. 3.8E-02 0. 1.4E-02 2.7E-04 7.7E-07 0. 0. Composition Misfit: 5.153543E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.320 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.669 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023089 0.014609 0.006912 0.016313 0.052418 0.000910 0.039927 0.037598 0.002242 0.107441 0.698541 Mica 0.020196 0.003116 0.000000 0.060732 0.005346 0.000000 0.005329 0.164972 0.000508 0.239359 0.500442 Gt 0.000000 0.036220 0.000000 0.000000 0.285672 0.038185 0.076611 0.000000 0.002990 0.135595 0.424727 Fsp 0.093859 0.059636 0.000000 0.001324 0.000000 0.000000 0.000000 0.000000 0.000000 0.154818 0.690364 Bio 0.000000 0.000000 0.021311 0.066721 0.160105 0.000824 0.175950 0.112130 0.004089 0.117032 0.341837 St 0.000000 0.000000 0.004505 0.000000 0.127683 0.002410 0.055687 0.088119 0.002385 0.388763 0.330447 Ilm 0.000000 0.000000 0.224568 0.000000 0.648882 0.007557 0.008820 0.000000 0.110173 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -773417. -752521. -930244. -848335. -313693. -467557. -637024. -290217. -406531. -1634317. -885000. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 100 converged, 43 successes so far. Misfit function evaluations this try => 217 Misfit this try = 0.123846 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.781170E-07 Bayes score, PP * exp(-Misfit) = 8.641817E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 9713.53 972.813 0.867246 0.167751 Final coordinates: 8586.00 922.775 0.630278 0.598796 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.123800 Extraneous predicted phases: 4.646035E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.931 0.022386 0.003226 0.000000 0.074860 0.006547 0.000000 0.006110 0.286774 0.600098 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.4 -1.3E-02 Chi 6.5E-03 0. 0. 1.2E-03 3.2E-03 0. 9.1E-03 1.4E-04 1.6E-08 Composition Misfit: 2.335323E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.665 0.000000 0.031978 0.000000 0.000000 0.286127 0.046399 0.072760 0.136535 0.426201 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -1. -2. 0.5 -0.2 Chi 0. 4.1E-03 0. 0. 4.5E-03 3.2E-03 4.4E-03 3.9E-04 5.6E-06 Composition Misfit: 1.657711E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.998 0.093917 0.059315 0.000000 0.001426 0.000000 0.000000 0.000000 0.154657 0.690685 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. -2.0E-02 0. 0. 0. 0.4 0.2 Chi 5.5E-05 1.0E-03 0. 3.2E-06 0. 0. 0. 2.5E-04 2.1E-05 Composition Misfit: 1.335310E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.088 0.000000 0.000000 0.024464 0.075677 0.188154 0.001150 0.190117 0.135150 0.385288 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.2 0.1 -1. 0.4 2. Chi 0. 0. 3.9E-04 1.0E-03 7.2E-05 6.5E-05 2.2E-03 2.0E-04 2.4E-03 Composition Misfit: 6.405724E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.788 0.000000 0.000000 0.004758 0.000000 0.143682 0.003279 0.057317 0.427610 0.363355 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.9 0.1 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 1.1E-03 9.6E-05 2.1E-02 1.0E-03 1.4E-03 Composition Misfit: 2.570764E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.566 0.000000 0.000000 0.252918 0.000000 0.727556 0.010304 0.009221 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -4. -4.8E-02 0.1 0. 0. Chi 0. 0. 3.7E-02 0. 1.3E-02 9.0E-06 6.6E-05 0. 0. Composition Misfit: 5.042076E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.276 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.667 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.021 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000020 -.000020 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023165 0.014657 0.006935 0.016367 0.052590 0.000913 0.040059 0.034611 0.002072 0.107794 0.700837 Mica 0.018681 0.002692 0.000000 0.062470 0.005463 0.000000 0.005098 0.164993 0.000518 0.239310 0.500775 Gt 0.000000 0.031889 0.000000 0.000000 0.285338 0.046271 0.072560 0.000000 0.002758 0.136159 0.425025 Fsp 0.093917 0.059315 0.000000 0.001426 0.000000 0.000000 0.000000 0.000000 0.000000 0.154657 0.690685 Bio 0.000000 0.000000 0.021620 0.066879 0.166281 0.001016 0.168016 0.112139 0.004109 0.119439 0.340500 St 0.000000 0.000000 0.004327 0.000000 0.130677 0.002982 0.052129 0.088125 0.002385 0.388907 0.330468 Ilm 0.000000 0.000000 0.225108 0.000000 0.647557 0.009171 0.008207 0.000000 0.109957 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775158. -753928. -931249. -849754. -313995. -466437. -637820. -291007. -407755. -1635181. -885935. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 103 converged, 44 successes so far. Misfit function evaluations this try => 234 Misfit this try = 0.148100 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 7.927543E-08 Bayes score, PP * exp(-Misfit) = 6.836276E-08 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 6576.99 826.456 0.163457 0.302481 Final coordinates: 5876.30 815.857 0.458947 0.536609 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.148100 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.006 0.021616 0.001472 0.000000 0.076992 0.003811 0.000000 0.003539 0.292206 0.600364 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.6 1. 0. 1. -0.7 -4.7E-02 Chi 5.9E-03 0. 0. 7.2E-04 1.4E-02 0. 2.8E-02 4.7E-04 2.2E-07 Composition Misfit: 5.097261E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.204 0.000000 0.028870 0.000000 0.000000 0.260291 0.098999 0.045956 0.138825 0.427059 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 3. -7. 0.8 0.4 -0.3 Chi 0. 2.4E-03 0. 0. 1.5E-02 4.2E-02 1.7E-03 1.8E-04 1.4E-05 Composition Misfit: 6.123740E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.567 0.094388 0.059402 0.000000 0.000911 0.000000 0.000000 0.000000 0.154701 0.690598 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 0.1 0. 0. 0. 0.4 0.2 Chi 7.9E-05 1.0E-03 0. 2.2E-04 0. 0. 0. 2.5E-04 2.2E-05 Composition Misfit: 1.594808E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.709 0.000000 0.000000 0.021425 0.075645 0.201162 0.001535 0.180479 0.134682 0.385072 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -7.2E-03 -1. -1. -3.2E-02 -0.7 0.4 2. Chi 0. 0. 1.5E-07 1.0E-03 1.4E-03 7.9E-06 6.7E-04 2.4E-04 2.5E-03 Composition Misfit: 5.770022E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.307 0.000000 0.000000 0.003376 0.000000 0.157574 0.005580 0.040428 0.429360 0.363683 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. -0.4 -2. 1. 1. Chi 0. 0. 4.6E-03 0. 4.5E-03 5.4E-04 7.6E-03 8.6E-04 1.4E-03 Composition Misfit: 1.948650E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.425 0.000000 0.000000 0.373664 0.000000 0.597457 0.020563 0.008316 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 1. -2. 0.3 0. 0. Chi 0. 0. 1.5E-03 0. 1.8E-03 5.4E-03 3.4E-04 0. 0. Composition Misfit: 9.038618E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.153 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.629 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023262 0.014718 0.006964 0.016435 0.052810 0.000916 0.040226 0.031146 0.001515 0.108244 0.703763 Mica 0.018027 0.001227 0.000000 0.064209 0.003178 0.000000 0.002952 0.165700 0.000329 0.243691 0.500686 Gt 0.000000 0.028819 0.000000 0.000000 0.259832 0.098825 0.045875 0.000000 0.001761 0.138580 0.426307 Fsp 0.094388 0.059402 0.000000 0.000911 0.000000 0.000000 0.000000 0.000000 0.000000 0.154701 0.690598 Bio 0.000000 0.000000 0.018881 0.066663 0.177275 0.001353 0.159048 0.114445 0.004302 0.118689 0.339346 St 0.000000 0.000000 0.003071 0.000000 0.143329 0.005075 0.036773 0.088215 0.002187 0.390545 0.330805 Ilm 0.000000 0.000000 0.351463 0.000000 0.561959 0.019341 0.007822 0.000000 0.059415 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -762232. -747561. -923625. -836986. -304396. -450446. -632698. -286583. -408506. -1624696. -880981. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 104 converged, 45 successes so far. Misfit function evaluations this try => 179 Misfit this try = 0.113905 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.430356E-07 Bayes score, PP * exp(-Misfit) = 8.415109E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 13028.7 851.734 0.766798 0.358647 Final coordinates: 8552.64 925.751 0.563270 0.489077 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.113905 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.043 0.021360 0.002959 0.000000 0.075994 0.006900 0.000000 0.006032 0.286320 0.600434 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.7E-03 0. 0. 9.4E-04 2.6E-03 0. 9.4E-03 1.2E-04 3.1E-07 Composition Misfit: 2.167089E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.067 0.000000 0.030160 0.000000 0.000000 0.295505 0.041139 0.070278 0.136668 0.426250 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.8 -1. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 2.4E-03 1.2E-03 3.4E-03 3.8E-04 6.0E-06 Composition Misfit: 1.037174E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.593 0.094467 0.058020 0.000000 0.001523 0.000000 0.000000 0.000000 0.154010 0.691980 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.8E-02 0. 0. 0. 0.5 0.1 Chi 8.4E-05 7.1E-04 0. 1.8E-05 0. 0. 0. 3.1E-04 9.2E-06 Composition Misfit: 1.130426E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.513 0.000000 0.000000 0.024815 0.075763 0.196215 0.001038 0.181071 0.136441 0.384658 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.8 0.1 -0.8 0.3 2. Chi 0. 0. 4.8E-04 1.0E-03 7.0E-04 1.4E-04 7.4E-04 1.1E-04 2.5E-03 Composition Misfit: 5.743776E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.505 0.000000 0.000000 0.004671 0.000000 0.147622 0.002908 0.053773 0.427664 0.363361 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.9E-03 3.0E-04 1.8E-02 1.0E-03 1.4E-03 Composition Misfit: 2.383786E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.453 0.000000 0.000000 0.252899 0.000000 0.729436 0.008963 0.008701 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.4E-02 1.2E-04 1.9E-04 0. 0. Composition Misfit: 5.115047E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.471 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.355 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023318 0.014754 0.006981 0.016475 0.052938 0.000919 0.040323 0.028456 0.001864 0.108506 0.705467 Mica 0.017825 0.002469 0.000000 0.063418 0.005758 0.000000 0.005034 0.164956 0.000531 0.238938 0.501070 Gt 0.000000 0.030078 0.000000 0.000000 0.294707 0.041028 0.070088 0.000000 0.002700 0.136299 0.425099 Fsp 0.094467 0.058020 0.000000 0.001523 0.000000 0.000000 0.000000 0.000000 0.000000 0.154010 0.691980 Bio 0.000000 0.000000 0.021934 0.066968 0.173437 0.000918 0.160051 0.112002 0.004084 0.120602 0.340005 St 0.000000 0.000000 0.004248 0.000000 0.134260 0.002645 0.048906 0.088126 0.002390 0.388954 0.330471 Ilm 0.000000 0.000000 0.225090 0.000000 0.649224 0.007978 0.007744 0.000000 0.109964 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775886. -754676. -931920. -850127. -314123. -467754. -638430. -291508. -409014. -1635731. -886335. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 105 converged, 46 successes so far. Misfit function evaluations this try => 229 Misfit this try = 0.216062 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 1.152406E-06 Bayes score, PP * exp(-Misfit) = 9.284766E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 9124.09 856.125 0.877296 0.828328 Final coordinates: 9058.17 911.989 0.946713 0.675376 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.216062 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.007 0.026333 0.004064 0.000000 0.070534 0.005955 0.000000 0.006281 0.287712 0.599122 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -3. 0. 0. 1. 0.8 0. 1. -0.4 0.1 Chi 9.7E-03 0. 0. 2.8E-03 4.5E-03 0. 8.4E-03 1.8E-04 1.3E-06 Composition Misfit: 2.963134E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.891 0.000000 0.040796 0.000000 0.000000 0.280034 0.039485 0.078823 0.135172 0.425689 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 2. -0.6 -2. 0.6 -0.1 Chi 0. 1.0E-02 0. 0. 6.3E-03 7.0E-04 7.3E-03 5.6E-04 2.5E-06 Composition Misfit: 2.489158E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.860 0.093687 0.060273 0.000000 0.001177 0.000000 0.000000 0.000000 0.155136 0.689727 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 0.1 0. 0. 0. 0.4 0.2 Chi 4.4E-05 1.2E-03 0. 2.8E-05 0. 0. 0. 2.1E-04 3.3E-05 Composition Misfit: 1.568251E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.137 0.000000 0.000000 0.022210 0.075290 0.173076 0.000902 0.211354 0.129343 0.387826 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.1 -1. 0.8 0.1 -3. 0.8 1. Chi 0. 0. 3.2E-05 9.2E-04 7.5E-04 3.0E-04 8.3E-03 9.3E-04 2.0E-03 Composition Misfit: 1.326131E-2 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.155 0.000000 0.000000 0.004279 0.000000 0.137384 0.002642 0.065018 0.427412 0.363264 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.5 0.3 -5. 1. 1. Chi 0. 0. 2.2E-03 0. 2.9E-04 5.4E-04 2.7E-02 1.0E-03 1.5E-03 Composition Misfit: 3.276804E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.992 0.000000 0.000000 0.214504 0.000000 0.771339 0.006803 0.007354 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -6. 0.5 0.4 0. 0. Chi 0. 0. 0.1 0. 2.6E-02 1.5E-03 9.5E-04 0. 0. Composition Misfit: 0.113942 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.305 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.652 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023039 0.014578 0.006897 0.016278 0.052304 0.000908 0.039841 0.038825 0.003095 0.107208 0.697027 Mica 0.021973 0.003391 0.000000 0.058856 0.004969 0.000000 0.005241 0.165050 0.000509 0.240078 0.499932 Gt 0.000000 0.040659 0.000000 0.000000 0.279096 0.039353 0.078559 0.000000 0.003351 0.134719 0.424263 Fsp 0.093687 0.060273 0.000000 0.001177 0.000000 0.000000 0.000000 0.000000 0.000000 0.155136 0.689727 Bio 0.000000 0.000000 0.019597 0.066434 0.152719 0.000796 0.186495 0.113271 0.004349 0.114130 0.342210 St 0.000000 0.000000 0.003891 0.000000 0.124929 0.002402 0.059124 0.088088 0.002570 0.388664 0.330331 Ilm 0.000000 0.000000 0.187709 0.000000 0.674986 0.005953 0.006435 0.000000 0.124916 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -770643. -750645. -929758. -845977. -312539. -465849. -635624. -289018. -402770. -1632436. -883688. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 106 converged, 47 successes so far. Misfit function evaluations this try => 340 Misfit this try = 0.221009 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 1.060808E-06 Bayes score, PP * exp(-Misfit) = 8.504599E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 12287.7 981.303 0.887702 0.949111 Final coordinates: 8873.38 920.123 0.964131 0.674689 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.221001 Extraneous predicted phases: 7.951798E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.460 0.024549 0.003822 0.000000 0.072396 0.006301 0.000000 0.006445 0.287041 0.599445 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 0.7 0. 1. -0.4 0.1 Chi 8.2E-03 0. 0. 2.0E-03 3.7E-03 0. 7.8E-03 1.5E-04 5.1E-07 Composition Misfit: 2.574923E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.581 0.000000 0.036834 0.000000 0.000000 0.276010 0.046542 0.079450 0.135392 0.425772 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 3. -1. -2. 0.6 -0.1 Chi 0. 7.2E-03 0. 0. 7.6E-03 3.2E-03 7.7E-03 5.3E-04 2.9E-06 Composition Misfit: 2.626523E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.151 0.093452 0.060535 0.000000 0.001280 0.000000 0.000000 0.000000 0.155267 0.689465 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.1 -0.9 0. 2.2E-02 0. 0. 0. 0.4 0.2 Chi 3.5E-05 1.3E-03 0. 4.7E-06 0. 0. 0. 2.0E-04 3.7E-05 Composition Misfit: 1.600444E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.373 0.000000 0.000000 0.022346 0.075427 0.174385 0.001114 0.208808 0.131401 0.386518 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.1 -1. 0.7 0.1 -3. 0.6 2. Chi 0. 0. 4.3E-05 9.5E-04 5.8E-04 8.6E-05 7.4E-03 6.0E-04 2.2E-03 Composition Misfit: 1.190528E-2 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.587 0.000000 0.000000 0.004112 0.000000 0.137027 0.003238 0.065021 0.427363 0.363238 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -0.4 0.1 -5. 1. 1. Chi 0. 0. 2.5E-03 0. 2.6E-04 1.1E-04 2.7E-02 1.1E-03 1.5E-03 Composition Misfit: 3.265968E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.987 0.000000 0.000000 0.209784 0.000000 0.775350 0.007842 0.007024 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 8. 0. -7. 0.3 0.5 0. 0. Chi 0. 0. 0.1 0. 2.7E-02 5.9E-04 1.3E-03 0. 0. Composition Misfit: 0.122821 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.078 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.775 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.009 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000014 -.000014 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023039 0.014577 0.006897 0.016278 0.052304 0.000908 0.039840 0.038785 0.003152 0.107206 0.697015 Mica 0.020485 0.003190 0.000000 0.060412 0.005258 0.000000 0.005378 0.164985 0.000546 0.239527 0.500219 Gt 0.000000 0.036714 0.000000 0.000000 0.275112 0.046391 0.079191 0.000000 0.003255 0.134951 0.424386 Fsp 0.093452 0.060535 0.000000 0.001280 0.000000 0.000000 0.000000 0.000000 0.000000 0.155267 0.689465 Bio 0.000000 0.000000 0.019714 0.066541 0.153841 0.000983 0.184209 0.113368 0.004441 0.115921 0.340983 St 0.000000 0.000000 0.003739 0.000000 0.124598 0.002945 0.059124 0.088077 0.002628 0.388599 0.330290 Ilm 0.000000 0.000000 0.183200 0.000000 0.677098 0.006848 0.006134 0.000000 0.126720 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -773392. -752401. -931562. -848537. -313777. -465824. -636603. -290072. -402663. -1634133. -884989. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 112 converged, 48 successes so far. Misfit function evaluations this try => 429 Misfit this try = 0.114073 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.430932E-07 Bayes score, PP * exp(-Misfit) = 8.414214E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 7333.56 818.945 0.919687 0.185183 Final coordinates: 8559.48 925.898 0.565475 0.493424 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.114073 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.164 0.021396 0.002974 0.000000 0.075951 0.006894 0.000000 0.006043 0.286322 0.600420 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.7E-03 0. 0. 9.5E-04 2.6E-03 0. 9.3E-03 1.2E-04 2.9E-07 Composition Misfit: 2.169103E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.053 0.000000 0.030235 0.000000 0.000000 0.295162 0.041252 0.070447 0.136658 0.426247 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -0.8 -1. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 2.4E-03 1.2E-03 3.5E-03 3.8E-04 5.9E-06 Composition Misfit: 1.057927E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.569 0.094446 0.058066 0.000000 0.001521 0.000000 0.000000 0.000000 0.154033 0.691934 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.7E-02 0. 0. 0. 0.5 0.1 Chi 8.3E-05 7.2E-04 0. 1.8E-05 0. 0. 0. 3.1E-04 9.5E-06 Composition Misfit: 1.136696E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.410 0.000000 0.000000 0.024814 0.075760 0.195876 0.001041 0.181429 0.136399 0.384681 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.8 0.1 -0.8 0.3 2. Chi 0. 0. 4.8E-04 1.0E-03 6.6E-04 1.4E-04 7.8E-04 1.1E-04 2.5E-03 Composition Misfit: 5.744743E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.687 0.000000 0.000000 0.004678 0.000000 0.147431 0.002918 0.053954 0.427658 0.363360 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.8E-03 2.9E-04 1.8E-02 1.0E-03 1.4E-03 Composition Misfit: 2.392850E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.457 0.000000 0.000000 0.253001 0.000000 0.729260 0.009001 0.008738 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.4E-02 1.1E-04 1.8E-04 0. 0. Composition Misfit: 5.099232E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.293 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.368 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023312 0.014750 0.006979 0.016471 0.052924 0.000918 0.040313 0.028701 0.001870 0.108478 0.705283 Mica 0.017855 0.002482 0.000000 0.063382 0.005753 0.000000 0.005043 0.164956 0.000531 0.238940 0.501059 Gt 0.000000 0.030153 0.000000 0.000000 0.294363 0.041140 0.070256 0.000000 0.002705 0.136288 0.425094 Fsp 0.094446 0.058066 0.000000 0.001521 0.000000 0.000000 0.000000 0.000000 0.000000 0.154033 0.691934 Bio 0.000000 0.000000 0.021934 0.066966 0.173138 0.000920 0.160368 0.111998 0.004083 0.120566 0.340027 St 0.000000 0.000000 0.004255 0.000000 0.134086 0.002654 0.049070 0.088126 0.002390 0.388949 0.330471 Ilm 0.000000 0.000000 0.225190 0.000000 0.649096 0.008012 0.007778 0.000000 0.109924 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775895. -754669. -931910. -850152. -314145. -467740. -638420. -291502. -408976. -1635739. -886336. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 113 converged, 49 successes so far. Misfit function evaluations this try => 206 Misfit this try = 0.120655 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.927700E-07 Bayes score, PP * exp(-Misfit) = 8.799315E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 6182.12 841.652 0.948813 0.612671 Final coordinates: 8730.54 924.484 0.619992 0.569025 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.120655 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.515 0.022474 0.003262 0.000000 0.074732 0.006678 0.000000 0.006203 0.286510 0.600141 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.4 -1.8E-02 Chi 6.5E-03 0. 0. 1.3E-03 3.0E-03 0. 8.7E-03 1.3E-04 3.3E-08 Composition Misfit: 2.288105E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.923 0.000000 0.032589 0.000000 0.000000 0.290689 0.040974 0.073175 0.136417 0.426156 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.7 -2. 0.5 -0.2 Chi 0. 4.4E-03 0. 0. 3.4E-03 1.1E-03 4.6E-03 4.0E-04 5.3E-06 Composition Misfit: 1.393380E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.064 0.094157 0.058822 0.000000 0.001432 0.000000 0.000000 0.000000 0.154411 0.691178 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -2.2E-02 0. 0. 0. 0.4 0.1 Chi 6.7E-05 8.9E-04 0. 3.9E-06 0. 0. 0. 2.7E-04 1.6E-05 Composition Misfit: 1.246836E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.465 0.000000 0.000000 0.024516 0.075649 0.189242 0.001019 0.189278 0.134739 0.385557 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.3 0.1 -1. 0.4 2. Chi 0. 0. 4.0E-04 1.0E-03 1.2E-04 1.6E-04 2.1E-03 2.3E-04 2.4E-03 Composition Misfit: 6.376431E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.572 0.000000 0.000000 0.004792 0.000000 0.144319 0.002876 0.057086 0.427576 0.363349 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.3E-03 0. 1.2E-03 3.2E-04 2.0E-02 1.0E-03 1.5E-03 Composition Misfit: 2.580768E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.556 0.000000 0.000000 0.253268 0.000000 0.728434 0.009031 0.009267 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 0.1 0. 0. Chi 0. 0. 3.7E-02 0. 1.3E-02 1.0E-04 5.8E-05 0. 0. Composition Misfit: 5.040917E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.378 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.526 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023206 0.014683 0.006947 0.016396 0.052683 0.000914 0.040129 0.032948 0.002041 0.107983 0.702069 Mica 0.018755 0.002722 0.000000 0.062365 0.005573 0.000000 0.005176 0.164962 0.000521 0.239097 0.500828 Gt 0.000000 0.032497 0.000000 0.000000 0.289872 0.040858 0.072970 0.000000 0.002810 0.136034 0.424959 Fsp 0.094157 0.058822 0.000000 0.001432 0.000000 0.000000 0.000000 0.000000 0.000000 0.154411 0.691178 Bio 0.000000 0.000000 0.021668 0.066863 0.167263 0.000901 0.167294 0.112058 0.004087 0.119090 0.340776 St 0.000000 0.000000 0.004359 0.000000 0.131257 0.002616 0.051920 0.088123 0.002386 0.388876 0.330463 Ilm 0.000000 0.000000 0.225454 0.000000 0.648439 0.008039 0.008250 0.000000 0.109818 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774885. -753774. -931197. -849432. -313960. -467461. -637816. -290959. -407932. -1635142. -885790. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 117 converged, 50 successes so far. Misfit function evaluations this try => 153 Misfit this try = 6.143102E-02 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.334985E-07 Bayes score, PP * exp(-Misfit) = 8.778786E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 6357.96 937.561 0.428359 0.436923 Final coordinates: 8541.01 926.466 0.425496 0.505165 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.143102E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.043 0.021123 0.002925 0.000000 0.076246 0.006938 0.000000 0.006004 0.286271 0.600493 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.5E-03 0. 0. 8.9E-04 2.6E-03 0. 9.5E-03 1.2E-04 4.0E-07 Composition Misfit: 2.145120E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.075 0.000000 0.029856 0.000000 0.000000 0.297330 0.040139 0.069582 0.136796 0.426298 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.6 -1. 0.5 -0.2 Chi 0. 2.9E-03 0. 0. 2.0E-03 8.6E-04 3.1E-03 3.6E-04 6.3E-06 Composition Misfit: 9.311051E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.583 0.094450 0.058013 0.000000 0.001543 0.000000 0.000000 0.000000 0.154006 0.691987 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.3E-05 7.1E-04 0. 2.2E-05 0. 0. 0. 3.1E-04 9.1E-06 Composition Misfit: 1.132590E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.495 0.000000 0.000000 0.025038 0.075791 0.197992 0.001017 0.178719 0.136858 0.384585 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.2 2. Chi 0. 0. 5.4E-04 1.0E-03 9.2E-04 1.6E-04 4.7E-04 8.7E-05 2.6E-03 Composition Misfit: 5.775492E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.493 0.000000 0.000000 0.004733 0.000000 0.148350 0.002839 0.052950 0.427741 0.363386 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 3.5E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.327831E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.313 0.000000 0.000000 0.347997 0.000000 0.629552 0.010035 0.012417 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. 2.1E-02 -5.5E-03 -0.4 0. 0. Chi 0. 0. 1.2E-05 0. 3.2E-07 1.2E-07 4.7E-04 0. 0. Composition Misfit: 4.823775E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.589 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.409 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023307 0.014747 0.006978 0.016467 0.052912 0.000918 0.040304 0.029378 0.001407 0.108454 0.705128 Mica 0.017628 0.002441 0.000000 0.063629 0.005790 0.000000 0.005010 0.164954 0.000524 0.238900 0.501125 Gt 0.000000 0.029777 0.000000 0.000000 0.296544 0.040032 0.069398 0.000000 0.002645 0.136434 0.425171 Fsp 0.094450 0.058013 0.000000 0.001543 0.000000 0.000000 0.000000 0.000000 0.000000 0.154006 0.691987 Bio 0.000000 0.000000 0.022136 0.067007 0.175046 0.000899 0.158006 0.111877 0.004019 0.120997 0.340013 St 0.000000 0.000000 0.004305 0.000000 0.134926 0.002582 0.048159 0.088135 0.002350 0.389038 0.330505 Ilm 0.000000 0.000000 0.323416 0.000000 0.585085 0.009326 0.011540 0.000000 0.070633 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776108. -754818. -931943. -850255. -314162. -468049. -638589. -291622. -409888. -1635871. -886440. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 122 converged, 51 successes so far. Misfit function evaluations this try => 272 Misfit this try = 7.902184E-02 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.589136E-07 Bayes score, PP * exp(-Misfit) = 8.860551E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 14412.6 814.897 0.317795 0.865978 Final coordinates: 8464.76 921.790 0.489925 0.675392 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.637706E-2 Extraneous predicted phases: 2.644777E-3 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.589 0.022095 0.003171 0.000000 0.075191 0.006489 0.000000 0.006027 0.286915 0.600111 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.4 -1.4E-02 Chi 6.2E-03 0. 0. 1.1E-03 3.4E-03 0. 9.4E-03 1.4E-04 2.1E-08 Composition Misfit: 2.342697E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.460 0.000000 0.031414 0.000000 0.000000 0.284093 0.049683 0.071875 0.136680 0.426255 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -2. -2. 0.5 -0.2 Chi 0. 3.8E-03 0. 0. 5.0E-03 4.8E-03 4.1E-03 3.7E-04 6.0E-06 Composition Misfit: 1.803036E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.835 0.093679 0.059778 0.000000 0.001432 0.000000 0.000000 0.000000 0.154889 0.690222 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. -2.2E-02 0. 0. 0. 0.4 0.2 Chi 4.4E-05 1.1E-03 0. 3.8E-06 0. 0. 0. 2.3E-04 2.7E-05 Composition Misfit: 1.427319E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.460 0.000000 0.000000 0.024565 0.075716 0.188657 0.001232 0.189080 0.135740 0.385010 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.3 0.1 -1. 0.3 2. Chi 0. 0. 4.2E-04 1.0E-03 9.3E-05 3.0E-05 2.0E-03 1.5E-04 2.5E-03 Composition Misfit: 6.219283E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.252 0.000000 0.000000 0.004765 0.000000 0.143834 0.003529 0.056833 0.427668 0.363370 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.9 0.1 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 1.1E-03 2.7E-05 2.0E-02 1.0E-03 1.4E-03 Composition Misfit: 2.524157E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.429 0.000000 0.000000 0.333968 0.000000 0.640815 0.012560 0.012657 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.9 0. -0.5 -0.4 -0.4 0. 0. Chi 0. 0. 7.7E-04 0. 1.8E-04 5.2E-04 5.6E-04 0. 0. Composition Misfit: 2.031552E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.006 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.809 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.160 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000020 -.000020 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023074 0.014599 0.006908 0.016302 0.052383 0.000909 0.039900 0.038884 0.001604 0.107368 0.698069 Mica 0.018438 0.002646 0.000000 0.062745 0.005415 0.000000 0.005030 0.165012 0.000514 0.239424 0.500778 Gt 0.000000 0.031329 0.000000 0.000000 0.283327 0.049549 0.071682 0.000000 0.002695 0.136312 0.425106 Fsp 0.093679 0.059778 0.000000 0.001432 0.000000 0.000000 0.000000 0.000000 0.000000 0.154889 0.690222 Bio 0.000000 0.000000 0.021710 0.066917 0.166732 0.001089 0.167106 0.112123 0.004093 0.119965 0.340266 St 0.000000 0.000000 0.004334 0.000000 0.130818 0.003210 0.051690 0.088130 0.002364 0.388967 0.330487 Ilm 0.000000 0.000000 0.308369 0.000000 0.591695 0.011597 0.011687 0.000000 0.076653 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775503. -754108. -931314. -850053. -314029. -465904. -637919. -291113. -408061. -1635286. -886106. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 126 converged, 52 successes so far. Misfit function evaluations this try => 213 Misfit this try = 0.136165 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 1.057908E-06 Bayes score, PP * exp(-Misfit) = 9.232348E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 8171.02 820.661 0.946827 0.525180 Final coordinates: 8998.05 922.908 0.687083 0.681251 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.134825 Extraneous predicted phases: 1.340434E-3 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.428 0.024228 0.003743 0.000000 0.072747 0.006380 0.000000 0.006376 0.286871 0.599656 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 0.7 0. 1. -0.4 4.4E-02 Chi 7.9E-03 0. 0. 1.9E-03 3.6E-03 0. 8.1E-03 1.4E-04 2.0E-07 Composition Misfit: 2.534941E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.854 0.000000 0.036379 0.000000 0.000000 0.285751 0.039019 0.076840 0.136008 0.426003 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.5 -2. 0.6 -0.2 Chi 0. 6.9E-03 0. 0. 4.6E-03 5.8E-04 6.3E-03 4.5E-04 4.2E-06 Composition Misfit: 1.883031E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.319 0.093805 0.059750 0.000000 0.001320 0.000000 0.000000 0.000000 0.154875 0.690250 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 1.1E-02 0. 0. 0. 0.4 0.2 Chi 5.0E-05 1.1E-03 0. 1.1E-06 0. 0. 0. 2.3E-04 2.6E-05 Composition Misfit: 1.423882E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.153 0.000000 0.000000 0.024105 0.075496 0.180830 0.000949 0.199406 0.132439 0.386776 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. 0.2 0.1 -2. 0.6 2. Chi 0. 0. 3.1E-04 9.7E-04 7.3E-05 2.4E-04 4.5E-03 4.7E-04 2.2E-03 Composition Misfit: 8.739530E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.743 0.000000 0.000000 0.004956 0.000000 0.140176 0.002706 0.061380 0.427451 0.363331 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.7 0.2 -5. 1. 1. Chi 0. 0. 1.1E-03 0. 5.9E-04 4.7E-04 2.4E-02 1.0E-03 1.5E-03 Composition Misfit: 2.879182E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.675 0.000000 0.000000 0.252160 0.000000 0.729280 0.008649 0.009910 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 1.4E-02 0. 0. Chi 0. 0. 3.8E-02 0. 1.4E-02 2.1E-04 8.1E-07 0. 0. Composition Misfit: 5.169003E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.065 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.651 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.113 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000018 -.000018 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023051 0.014585 0.006901 0.016286 0.052331 0.000908 0.039861 0.039183 0.002247 0.107263 0.697384 Mica 0.020219 0.003124 0.000000 0.060708 0.005324 0.000000 0.005321 0.164977 0.000508 0.239398 0.500422 Gt 0.000000 0.036271 0.000000 0.000000 0.284897 0.038903 0.076610 0.000000 0.002988 0.135601 0.424730 Fsp 0.093805 0.059750 0.000000 0.001320 0.000000 0.000000 0.000000 0.000000 0.000000 0.154875 0.690250 Bio 0.000000 0.000000 0.021303 0.066721 0.159812 0.000839 0.176229 0.112139 0.004090 0.117045 0.341821 St 0.000000 0.000000 0.004507 0.000000 0.127490 0.002461 0.055825 0.088120 0.002384 0.388765 0.330448 Ilm 0.000000 0.000000 0.224358 0.000000 0.648872 0.007696 0.008818 0.000000 0.110257 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -773436. -752509. -930234. -848363. -313695. -467400. -637010. -290209. -406472. -1634309. -885006. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 127 converged, 53 successes so far. Misfit function evaluations this try => 169 Misfit this try = 7.740936E-02 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 5.724955E-07 Bayes score, PP * exp(-Misfit) = 5.298508E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 10497.7 820.624 0.454664 0.230345 Final coordinates: 7875.03 853.199 0.437809 0.476029 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.740936E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.004 0.023710 0.002250 0.000000 0.074270 0.005104 0.000000 0.004768 0.289497 0.600401 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 0.9 0. 1. -0.5 -0.1 Chi 7.5E-03 0. 0. 1.4E-03 7.2E-03 0. 1.6E-02 2.8E-04 2.7E-07 Composition Misfit: 3.478290E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.389 0.000000 0.039953 0.000000 0.000000 0.302753 0.038566 0.055394 0.136971 0.426364 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -0.5 -0.1 0.5 -0.2 Chi 0. 9.4E-03 0. 0. 1.2E-03 4.8E-04 6.5E-06 3.4E-04 6.8E-06 Composition Misfit: 1.147906E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.426 0.095360 0.057277 0.000000 0.001001 0.000000 0.000000 0.000000 0.153639 0.692723 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.4E-04 5.6E-04 0. 1.3E-04 0. 0. 0. 3.4E-04 4.6E-06 Composition Misfit: 1.182514E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.804 0.000000 0.000000 0.022165 0.075301 0.201983 0.000687 0.181995 0.129514 0.388355 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.1 -1. -1. 0.2 -0.9 0.8 1. Chi 0. 0. 2.9E-05 9.3E-04 1.5E-03 7.9E-04 8.6E-04 9.0E-04 2.0E-03 Composition Misfit: 6.981990E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.011 0.000000 0.000000 0.003946 0.000000 0.157124 0.002161 0.044645 0.428589 0.363535 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -2. 0.4 -3. 1. 1. Chi 0. 0. 2.9E-03 0. 4.3E-03 1.3E-03 1.1E-02 9.3E-04 1.4E-03 Composition Misfit: 2.145903E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.425 0.000000 0.000000 0.365717 0.000000 0.616758 0.007917 0.009608 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.9 0. 0.6 0.3 0.1 0. 0. Chi 0. 0. 6.8E-04 0. 2.8E-04 5.5E-04 1.6E-05 0. 0. Composition Misfit: 1.523862E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.983 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.958 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023345 0.014771 0.006989 0.016494 0.053000 0.000920 0.040371 0.027729 0.001450 0.108634 0.706296 Mica 0.019780 0.001877 0.000000 0.061961 0.004258 0.000000 0.003977 0.165358 0.000387 0.241514 0.500887 Gt 0.000000 0.039850 0.000000 0.000000 0.301975 0.038467 0.055252 0.000000 0.002569 0.136619 0.425269 Fsp 0.095360 0.057277 0.000000 0.001001 0.000000 0.000000 0.000000 0.000000 0.000000 0.153639 0.692723 Bio 0.000000 0.000000 0.019562 0.066458 0.178264 0.000606 0.160624 0.113354 0.004076 0.114305 0.342750 St 0.000000 0.000000 0.003589 0.000000 0.142911 0.001965 0.040607 0.088173 0.002284 0.389820 0.330651 Ilm 0.000000 0.000000 0.342707 0.000000 0.577953 0.007419 0.009004 0.000000 0.062917 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -761857. -746519. -924231. -836188. -305982. -459565. -633255. -286491. -408492. -1625899. -880198. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 135 converged, 54 successes so far. Misfit function evaluations this try => 153 Misfit this try = 6.179329E-02 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.348870E-07 Bayes score, PP * exp(-Misfit) = 8.788659E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 13950.2 848.937 0.339176 0.349695 Final coordinates: 8578.08 927.124 0.436954 0.501468 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.179326E-2 Extraneous predicted phases: 2.534794E-8 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.048 0.021165 0.002943 0.000000 0.076189 0.006983 0.000000 0.006040 0.286191 0.600490 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.5E-03 0. 0. 9.0E-04 2.5E-03 0. 9.3E-03 1.1E-04 4.0E-07 Composition Misfit: 2.129322E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.127 0.000000 0.030028 0.000000 0.000000 0.297951 0.039137 0.069901 0.136715 0.426268 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.5 -1. 0.5 -0.2 Chi 0. 3.0E-03 0. 0. 1.9E-03 6.1E-04 3.3E-03 3.7E-04 6.1E-06 Composition Misfit: 9.173521E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.578 0.094486 0.057940 0.000000 0.001544 0.000000 0.000000 0.000000 0.153970 0.692060 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.5E-05 6.9E-04 0. 2.3E-05 0. 0. 0. 3.1E-04 8.6E-06 Composition Misfit: 1.122547E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.497 0.000000 0.000000 0.024990 0.075780 0.197871 0.000993 0.179045 0.136706 0.384614 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.3E-04 1.0E-03 9.1E-04 1.9E-04 5.1E-04 9.5E-05 2.6E-03 Composition Misfit: 5.804327E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.261 0.000000 0.000000 0.004712 0.000000 0.148321 0.002768 0.053128 0.427698 0.363373 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 2.0E-03 4.1E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.351468E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.326 0.000000 0.000000 0.338751 0.000000 0.639428 0.009721 0.012100 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.6 0. -0.4 4.4E-02 -0.3 0. 0. Chi 0. 0. 3.7E-04 0. 1.4E-04 8.0E-06 3.6E-04 0. 0. Composition Misfit: 8.849604E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.783 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.379 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000023 -.000023 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023311 0.014750 0.006979 0.016470 0.052922 0.000918 0.040311 0.029168 0.001445 0.108473 0.705253 Mica 0.017662 0.002456 0.000000 0.063582 0.005828 0.000000 0.005041 0.164944 0.000530 0.238834 0.501125 Gt 0.000000 0.029948 0.000000 0.000000 0.297152 0.039032 0.069714 0.000000 0.002680 0.136349 0.425126 Fsp 0.094486 0.057940 0.000000 0.001544 0.000000 0.000000 0.000000 0.000000 0.000000 0.153970 0.692060 Bio 0.000000 0.000000 0.022093 0.066995 0.174930 0.000878 0.158287 0.111897 0.004041 0.120857 0.340023 St 0.000000 0.000000 0.004286 0.000000 0.134898 0.002517 0.048320 0.088130 0.002369 0.388992 0.330488 Ilm 0.000000 0.000000 0.313477 0.000000 0.591721 0.008996 0.011197 0.000000 0.074609 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776093. -754805. -932005. -850242. -314197. -468291. -638589. -291622. -409617. -1635896. -886426. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 136 converged, 55 successes so far. Misfit function evaluations this try => 388 Misfit this try = 1.12270 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 1.028043E-06 Bayes score, PP * exp(-Misfit) = 3.345265E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 8343.14 887.084 0.842205 0.820014 Final coordinates: 8930.13 924.732 0.643412 0.608853 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.927037E-2 Extraneous predicted phases: 1.04343 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.695 0.023304 0.003491 0.000000 0.073778 0.006614 0.000000 0.006344 0.286513 0.599957 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 0.7 0. 1. -0.4 5.6E-03 Chi 7.2E-03 0. 0. 1.5E-03 3.1E-03 0. 8.2E-03 1.3E-04 3.1E-09 Composition Misfit: 2.365222E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.043 0.000000 0.034526 0.000000 0.000000 0.290671 0.037377 0.075186 0.136174 0.426065 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.3 -2. 0.5 -0.2 Chi 0. 5.7E-03 0. 0. 3.4E-03 2.6E-04 5.5E-03 4.3E-04 4.7E-06 Composition Misfit: 1.524657E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.748 0.094142 0.058949 0.000000 0.001383 0.000000 0.000000 0.000000 0.154474 0.691051 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -7.4E-03 0. 0. 0. 0.4 0.2 Chi 6.6E-05 9.2E-04 0. 4.7E-07 0. 0. 0. 2.7E-04 1.7E-05 Composition Misfit: 1.267929E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.532 0.000000 0.000000 0.024341 0.075563 0.185792 0.000921 0.193674 0.133449 0.386260 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.1 0.1 -2. 0.5 2. Chi 0. 0. 3.6E-04 9.8E-04 9.4E-06 2.7E-04 3.0E-03 3.5E-04 2.3E-03 Composition Misfit: 7.278396E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.457 0.000000 0.000000 0.004879 0.000000 0.142706 0.002597 0.058982 0.427499 0.363337 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.9 0.3 -4. 1. 1. Chi 0. 0. 1.2E-03 0. 9.5E-04 5.9E-04 2.2E-02 1.0E-03 1.5E-03 Composition Misfit: 2.730758E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.021 0.000000 0.000000 0.320404 0.000000 0.657697 0.009247 0.012652 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 2. 0. -1. 0.1 -0.4 0. 0. Chi 0. 0. 2.7E-03 0. 1.2E-03 6.1E-05 5.6E-04 0. 0. Composition Misfit: 4.517682E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.366 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.500 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.586 0.000000 0.000000 0.224757 0.000000 0.649300 0.007328 0.008518 0.000000 0.110097 0.000000 0.000000 F 0.054 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000019 -.000019 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023151 0.014648 0.006931 0.016357 0.052558 0.000912 0.040034 0.035170 0.002114 0.107727 0.700400 Mica 0.019448 0.002913 0.000000 0.061570 0.005519 0.000000 0.005294 0.164951 0.000517 0.239104 0.500683 Gt 0.000000 0.034425 0.000000 0.000000 0.289824 0.037268 0.074967 0.000000 0.002915 0.135777 0.424823 Fsp 0.094142 0.058949 0.000000 0.001383 0.000000 0.000000 0.000000 0.000000 0.000000 0.154474 0.691051 Bio 0.000000 0.000000 0.021514 0.066787 0.164214 0.000814 0.171181 0.112061 0.004081 0.117950 0.341399 St 0.000000 0.000000 0.004437 0.000000 0.129790 0.002362 0.053643 0.088120 0.002389 0.388807 0.330452 Ilm 0.000000 0.000000 0.294003 0.000000 0.603504 0.008485 0.011610 0.000000 0.082399 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774084. -753131. -930747. -848789. -313830. -468025. -637441. -290594. -407322. -1634748. -885360. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 139 converged, 56 successes so far. Misfit function evaluations this try => 213 Misfit this try = 0.113970 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.396932E-07 Bayes score, PP * exp(-Misfit) = 8.384741E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 11353.0 867.147 0.605649 0.530088 Final coordinates: 8565.65 926.379 0.561278 0.500655 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.113522 Extraneous predicted phases: 4.473767E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.016 0.021338 0.002969 0.000000 0.076008 0.006924 0.000000 0.006048 0.286279 0.600435 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.4E-04 2.6E-03 0. 9.3E-03 1.2E-04 3.1E-07 Composition Misfit: 2.155906E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.081 0.000000 0.030134 0.000000 0.000000 0.295715 0.040836 0.070410 0.136659 0.426247 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.7 -1. 0.5 -0.2 Chi 0. 3.0E-03 0. 0. 2.3E-03 1.1E-03 3.5E-03 3.8E-04 5.9E-06 Composition Misfit: 1.028049E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.579 0.094475 0.057993 0.000000 0.001528 0.000000 0.000000 0.000000 0.153997 0.692007 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.9E-02 0. 0. 0. 0.5 0.1 Chi 8.4E-05 7.1E-04 0. 1.9E-05 0. 0. 0. 3.1E-04 9.0E-06 Composition Misfit: 1.127443E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.521 0.000000 0.000000 0.024845 0.075765 0.196273 0.001032 0.180964 0.136471 0.384649 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.8 0.1 -0.8 0.3 2. Chi 0. 0. 4.9E-04 1.0E-03 7.1E-04 1.5E-04 7.2E-04 1.1E-04 2.5E-03 Composition Misfit: 5.750544E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.452 0.000000 0.000000 0.004677 0.000000 0.147590 0.002890 0.053826 0.427656 0.363360 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.9E-03 3.1E-04 1.8E-02 1.0E-03 1.4E-03 Composition Misfit: 2.387917E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.450 0.000000 0.000000 0.253104 0.000000 0.729262 0.008903 0.008731 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.4E-02 1.4E-04 1.8E-04 0. 0. Composition Misfit: 5.092559E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.514 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.322 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.066 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000022 -.000022 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023302 0.014744 0.006976 0.016464 0.052902 0.000918 0.040296 0.029110 0.001856 0.108434 0.704997 Mica 0.017807 0.002478 0.000000 0.063430 0.005778 0.000000 0.005047 0.164951 0.000532 0.238905 0.501073 Gt 0.000000 0.030053 0.000000 0.000000 0.294915 0.040725 0.070219 0.000000 0.002705 0.136289 0.425094 Fsp 0.094475 0.057993 0.000000 0.001528 0.000000 0.000000 0.000000 0.000000 0.000000 0.153997 0.692007 Bio 0.000000 0.000000 0.021962 0.066971 0.173493 0.000913 0.159961 0.111981 0.004081 0.120632 0.340006 St 0.000000 0.000000 0.004254 0.000000 0.134231 0.002629 0.048954 0.088125 0.002391 0.388947 0.330470 Ilm 0.000000 0.000000 0.225292 0.000000 0.649129 0.007925 0.007771 0.000000 0.109883 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775977. -754727. -931970. -850211. -314181. -467886. -638471. -291544. -409052. -1635803. -886374. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 142 converged, 57 successes so far. Misfit function evaluations this try => 209 Misfit this try = 0.114012 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.327422E-07 Bayes score, PP * exp(-Misfit) = 8.322367E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 10638.5 833.061 0.786912 0.942195 Final coordinates: 8513.31 925.920 0.561337 0.492911 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.114007 Extraneous predicted phases: 4.927114E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.014 0.021270 0.002943 0.000000 0.076096 0.006891 0.000000 0.006009 0.286357 0.600434 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.2E-04 2.6E-03 0. 9.5E-03 1.2E-04 3.1E-07 Composition Misfit: 2.167253E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.007 0.000000 0.029863 0.000000 0.000000 0.294600 0.042437 0.070133 0.136704 0.426264 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -0.9 -1. 0.5 -0.2 Chi 0. 2.9E-03 0. 0. 2.5E-03 1.6E-03 3.4E-03 3.7E-04 6.1E-06 Composition Misfit: 1.075204E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.604 0.094420 0.058097 0.000000 0.001531 0.000000 0.000000 0.000000 0.154048 0.691903 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.1E-05 7.3E-04 0. 2.0E-05 0. 0. 0. 3.0E-04 9.8E-06 Composition Misfit: 1.142646E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.527 0.000000 0.000000 0.024849 0.075779 0.196312 0.001073 0.180779 0.136685 0.384524 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.8 0.1 -0.8 0.3 2. Chi 0. 0. 4.9E-04 1.0E-03 7.1E-04 1.2E-04 7.0E-04 9.6E-05 2.6E-03 Composition Misfit: 5.712428E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.675 0.000000 0.000000 0.004663 0.000000 0.147575 0.003011 0.053718 0.427671 0.363362 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.9E-03 2.3E-04 1.8E-02 1.0E-03 1.4E-03 Composition Misfit: 2.372414E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.447 0.000000 0.000000 0.252920 0.000000 0.729142 0.009256 0.008683 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.1 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.3E-02 6.0E-05 2.0E-04 0. 0. Composition Misfit: 5.100321E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.334 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.385 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.007 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000022 -.000022 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023313 0.014751 0.006980 0.016472 0.052926 0.000919 0.040314 0.028673 0.001857 0.108482 0.705314 Mica 0.017750 0.002456 0.000000 0.063502 0.005751 0.000000 0.005015 0.164961 0.000531 0.238967 0.501067 Gt 0.000000 0.029783 0.000000 0.000000 0.293809 0.042323 0.069945 0.000000 0.002685 0.136336 0.425119 Fsp 0.094420 0.058097 0.000000 0.001531 0.000000 0.000000 0.000000 0.000000 0.000000 0.154048 0.691903 Bio 0.000000 0.000000 0.021964 0.066982 0.173523 0.000948 0.159793 0.112000 0.004086 0.120818 0.339886 St 0.000000 0.000000 0.004241 0.000000 0.134217 0.002738 0.048856 0.088126 0.002390 0.388960 0.330472 Ilm 0.000000 0.000000 0.225109 0.000000 0.648968 0.008238 0.007728 0.000000 0.109956 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776106. -754817. -932019. -850341. -314199. -467578. -638502. -291586. -409055. -1635843. -886444. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 145 converged, 58 successes so far. Misfit function evaluations this try => 246 Misfit this try = 0.116693 Best Misfit so far = 6.112505E-02 obtained on Try 6 Prior probability, PP = 9.628737E-07 Bayes score, PP * exp(-Misfit) = 8.568215E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 13641.9 841.798 0.559074 0.796826 Final coordinates: 8630.84 925.439 0.589378 0.525713 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.116693 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.167 0.021824 0.003089 0.000000 0.075466 0.006810 0.000000 0.006116 0.286384 0.600312 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.3 -4.0E-02 Chi 6.0E-03 0. 0. 1.1E-03 2.8E-03 0. 9.0E-03 1.2E-04 1.6E-07 Composition Misfit: 2.210519E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.995 0.000000 0.031157 0.000000 0.000000 0.293265 0.041183 0.071629 0.136558 0.426209 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -0.8 -2. 0.5 -0.2 Chi 0. 3.6E-03 0. 0. 2.8E-03 1.2E-03 4.0E-03 3.9E-04 5.6E-06 Composition Misfit: 1.192990E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.359 0.094324 0.058383 0.000000 0.001485 0.000000 0.000000 0.000000 0.154191 0.691617 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -3.7E-02 0. 0. 0. 0.5 0.1 Chi 7.6E-05 7.9E-04 0. 1.1E-05 0. 0. 0. 2.9E-04 1.2E-05 Composition Misfit: 1.179310E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.572 0.000000 0.000000 0.024694 0.075715 0.193046 0.001033 0.184755 0.135718 0.385039 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.6 0.1 -1. 0.3 2. Chi 0. 0. 4.5E-04 1.0E-03 3.8E-04 1.5E-04 1.3E-03 1.6E-04 2.5E-03 Composition Misfit: 5.886199E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.934 0.000000 0.000000 0.004726 0.000000 0.146133 0.002904 0.055259 0.427623 0.363356 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 1.6E-03 3.0E-04 1.9E-02 1.0E-03 1.4E-03 Composition Misfit: 2.468663E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.500 0.000000 0.000000 0.252972 0.000000 0.729061 0.009016 0.008950 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.3E-02 1.1E-04 1.2E-04 0. 0. Composition Misfit: 5.090546E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.038 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.436 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023266 0.014721 0.006966 0.016439 0.052821 0.000917 0.040234 0.030520 0.001946 0.108266 0.703906 Mica 0.018212 0.002578 0.000000 0.062977 0.005683 0.000000 0.005104 0.164957 0.000527 0.238992 0.500970 Gt 0.000000 0.031071 0.000000 0.000000 0.292459 0.041070 0.071432 0.000000 0.002748 0.136183 0.425038 Fsp 0.094324 0.058383 0.000000 0.001485 0.000000 0.000000 0.000000 0.000000 0.000000 0.154191 0.691617 Bio 0.000000 0.000000 0.021827 0.066924 0.170632 0.000913 0.163304 0.112020 0.004085 0.119961 0.340334 St 0.000000 0.000000 0.004298 0.000000 0.132906 0.002641 0.050257 0.088125 0.002389 0.388918 0.330467 Ilm 0.000000 0.000000 0.225162 0.000000 0.648912 0.008025 0.007966 0.000000 0.109935 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775505. -754313. -931634. -849880. -314083. -467636. -638178. -291287. -408538. -1635511. -886122. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 147 converged, 59 successes so far. Misfit function evaluations this try => 351 Misfit this try = 6.112359E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.379531E-07 Bayes score, PP * exp(-Misfit) = 8.823390E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 5861.49 917.228 0.789398 8.410294E-02 Final coordinates: 8574.21 926.738 0.420555 0.501133 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.112359E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 0.021165 0.002934 0.000000 0.076195 0.006954 0.000000 0.006023 0.286226 0.600502 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.5E-03 0. 0. 9.0E-04 2.5E-03 0. 9.4E-03 1.2E-04 4.2E-07 Composition Misfit: 2.139924E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.138 0.000000 0.029997 0.000000 0.000000 0.298325 0.038929 0.069659 0.136793 0.426297 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.5 -1. 0.5 -0.2 Chi 0. 3.0E-03 0. 0. 1.9E-03 5.6E-04 3.2E-03 3.6E-04 6.3E-06 Composition Misfit: 8.946411E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.585 0.094499 0.057917 0.000000 0.001542 0.000000 0.000000 0.000000 0.153959 0.692083 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.6E-05 6.9E-04 0. 2.2E-05 0. 0. 0. 3.1E-04 8.4E-06 Composition Misfit: 1.119058E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.537 0.000000 0.000000 0.025065 0.075783 0.198068 0.000989 0.178664 0.136748 0.384683 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.5E-04 1.0E-03 9.3E-04 1.9E-04 4.7E-04 9.3E-05 2.5E-03 Composition Misfit: 5.803238E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.289 0.000000 0.000000 0.004754 0.000000 0.148453 0.002748 0.052905 0.427749 0.363390 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 4.3E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.331442E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.310 0.000000 0.000000 0.350840 0.000000 0.626847 0.009765 0.012549 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -4.6E-02 0. 0.1 3.7E-02 -0.4 0. 0. Chi 0. 0. 2.0E-06 0. 1.6E-05 5.7E-06 5.2E-04 0. 0. Composition Misfit: 5.412213E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.764 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.377 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023313 0.014751 0.006979 0.016471 0.052926 0.000918 0.040314 0.029150 0.001391 0.108481 0.705305 Mica 0.017663 0.002449 0.000000 0.063587 0.005804 0.000000 0.005026 0.164949 0.000523 0.238864 0.501136 Gt 0.000000 0.029918 0.000000 0.000000 0.297536 0.038826 0.069474 0.000000 0.002646 0.136431 0.425169 Fsp 0.094499 0.057917 0.000000 0.001542 0.000000 0.000000 0.000000 0.000000 0.000000 0.153959 0.692083 Bio 0.000000 0.000000 0.022161 0.067004 0.175122 0.000874 0.157966 0.111847 0.004001 0.120906 0.340119 St 0.000000 0.000000 0.004324 0.000000 0.135021 0.002500 0.048118 0.088136 0.002342 0.389048 0.330511 Ilm 0.000000 0.000000 0.326490 0.000000 0.583341 0.009087 0.011678 0.000000 0.069404 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776017. -754765. -931897. -850161. -314143. -468275. -638574. -291597. -409995. -1635842. -886393. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio F sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio F sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 149 converged, 60 successes so far. Misfit function evaluations this try => 211 Misfit this try = 0.198595 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 3.614673E-07 Bayes score, PP * exp(-Misfit) = 2.963605E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 13075.7 830.665 0.209011 0.336935 Final coordinates: 7307.24 841.730 0.779775 0.533119 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.198595 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.749 0.024753 0.002262 0.000000 0.073333 0.004357 0.000000 0.004336 0.290945 0.600015 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 1. 0. 1. -0.6 -1.9E-03 Chi 8.4E-03 0. 0. 1.7E-03 1.1E-02 0. 2.0E-02 3.8E-04 3.8E-10 Composition Misfit: 4.286926E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.569 0.000000 0.038109 0.000000 0.000000 0.278543 0.064427 0.054902 0.137468 0.426550 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -3. -1.0E-02 0.5 -0.2 Chi 0. 8.1E-03 0. 0. 6.8E-03 1.4E-02 2.1E-07 2.9E-04 8.4E-06 Composition Misfit: 2.928822E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.172 0.094425 0.059324 0.000000 0.000913 0.000000 0.000000 0.000000 0.154662 0.690676 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 0.1 0. 0. 0. 0.4 0.2 Chi 8.2E-05 1.0E-03 0. 2.2E-04 0. 0. 0. 2.5E-04 2.1E-05 Composition Misfit: 1.577457E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.341 0.000000 0.000000 0.021717 0.075323 0.192228 0.001096 0.191829 0.129850 0.387957 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -4.4E-02 -1. -0.5 0.1 -2. 0.8 1. Chi 0. 0. 5.6E-06 9.3E-04 3.1E-04 9.9E-05 2.6E-03 8.4E-04 2.0E-03 Composition Misfit: 6.806860E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.155 0.000000 0.000000 0.003926 0.000000 0.153022 0.003671 0.047105 0.428712 0.363564 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -2. 3.6E-02 -3. 1. 1. Chi 0. 0. 3.0E-03 0. 3.2E-03 7.7E-06 1.2E-02 9.2E-04 1.4E-03 Composition Misfit: 2.086847E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.777 0.000000 0.000000 0.223981 0.000000 0.759971 0.010685 0.005362 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -6. -0.1 0.7 0. 0. Chi 0. 0. 0.1 0. 2.2E-02 4.4E-05 4.0E-03 0. 0. Composition Misfit: 9.718483E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.886 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.351 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023242 0.014706 0.006958 0.016421 0.052765 0.000916 0.040191 0.030917 0.002572 0.108151 0.703161 Mica 0.020647 0.001887 0.000000 0.061169 0.003635 0.000000 0.003616 0.165518 0.000358 0.242684 0.500487 Gt 0.000000 0.038020 0.000000 0.000000 0.277888 0.064275 0.054773 0.000000 0.002352 0.137145 0.425547 Fsp 0.094425 0.059324 0.000000 0.000913 0.000000 0.000000 0.000000 0.000000 0.000000 0.154662 0.690676 Bio 0.000000 0.000000 0.019156 0.066443 0.169565 0.000966 0.169213 0.113729 0.004171 0.114541 0.342217 St 0.000000 0.000000 0.003571 0.000000 0.139184 0.003339 0.042845 0.088183 0.002250 0.389942 0.330686 Ilm 0.000000 0.000000 0.196819 0.000000 0.667808 0.009389 0.004712 0.000000 0.121273 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -761875. -746470. -923599. -836833. -305721. -455109. -632694. -286183. -407263. -1625410. -880320. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 150 converged, 61 successes so far. Misfit function evaluations this try => 295 Misfit this try = 9.035410E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.035665E-07 Bayes score, PP * exp(-Misfit) = 8.255052E-07 Best Bayes score so far = 9.643230E-07 obtained on Try 91 P_bar T_K C_O2 C_H2O Initial coordinates: 5488.56 978.296 0.885599 8.483039E-02 Final coordinates: 8170.27 919.382 0.514148 0.676067 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 8.501290E-2 Extraneous predicted phases: 5.341199E-3 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.208 0.021655 0.002998 0.000000 0.075753 0.006345 0.000000 0.005815 0.287289 0.600146 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.4 -1.9E-02 Chi 5.9E-03 0. 0. 1.0E-03 3.6E-03 0. 1.0E-02 1.6E-04 3.5E-08 Composition Misfit: 2.398002E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.237 0.000000 0.029477 0.000000 0.000000 0.278348 0.058548 0.070334 0.136940 0.426352 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -3. -1. 0.5 -0.2 Chi 0. 2.7E-03 0. 0. 6.8E-03 1.0E-02 3.4E-03 3.5E-04 6.7E-06 Composition Misfit: 2.339911E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.945 0.093564 0.059969 0.000000 0.001451 0.000000 0.000000 0.000000 0.154985 0.690031 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. -2.7E-02 0. 0. 0. 0.4 0.2 Chi 3.9E-05 1.2E-03 0. 6.0E-06 0. 0. 0. 2.3E-04 2.9E-05 Composition Misfit: 1.468946E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.731 0.000000 0.000000 0.024577 0.075798 0.189110 0.001453 0.187835 0.136966 0.384261 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.3 -8.2E-03 -1. 0.2 2. Chi 0. 0. 4.2E-04 1.0E-03 1.1E-04 5.6E-07 1.8E-03 8.2E-05 2.6E-03 Composition Misfit: 6.048273E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.326 0.000000 0.000000 0.004665 0.000000 0.143887 0.004216 0.056116 0.427737 0.363379 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.9 -0.1 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.1E-03 3.4E-05 2.0E-02 1.0E-03 1.4E-03 Composition Misfit: 2.479232E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.412 0.000000 0.000000 0.320469 0.000000 0.652977 0.014707 0.011847 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 2. 0. -1. -0.7 -0.3 0. 0. Chi 0. 0. 2.7E-03 0. 8.1E-04 1.5E-03 2.9E-04 0. 0. Composition Misfit: 5.324230E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.033 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.901 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.026 0.000000 0.000000 0.225728 0.000000 0.645014 0.011598 0.007951 0.000000 0.109709 0.000000 0.000000 F 0.180 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000020 -.000020 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023071 0.014598 0.006907 0.016300 0.052376 0.000909 0.039896 0.038918 0.001683 0.107355 0.697986 Mica 0.018069 0.002502 0.000000 0.063210 0.005294 0.000000 0.004852 0.165061 0.000513 0.239721 0.500778 Gt 0.000000 0.029401 0.000000 0.000000 0.277629 0.058397 0.070153 0.000000 0.002582 0.136586 0.425251 Fsp 0.093564 0.059969 0.000000 0.001451 0.000000 0.000000 0.000000 0.000000 0.000000 0.154985 0.690031 Bio 0.000000 0.000000 0.021717 0.066977 0.167103 0.001284 0.165977 0.112237 0.004134 0.121027 0.339544 St 0.000000 0.000000 0.004243 0.000000 0.130865 0.003835 0.051037 0.088132 0.002368 0.389027 0.330494 Ilm 0.000000 0.000000 0.294072 0.000000 0.599190 0.013496 0.010871 0.000000 0.082371 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776237. -754704. -931643. -850808. -314139. -464624. -638118. -291371. -408012. -1635539. -886520. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 151 converged, 62 successes so far. Misfit function evaluations this try => 204 Misfit this try = 7.128856E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.071006E-06 Bayes score, PP * exp(-Misfit) = 9.973139E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 13725.8 873.864 0.641899 0.708331 Final coordinates: 8579.19 907.573 0.434104 0.589258 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.128856E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.680 0.022916 0.003062 0.000000 0.074455 0.006238 0.000000 0.005871 0.287262 0.600196 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.8 0. 1. -0.4 -2.5E-02 Chi 6.9E-03 0. 0. 1.3E-03 3.9E-03 0. 1.0E-02 1.6E-04 6.4E-08 Composition Misfit: 2.535718E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.018 0.000000 0.034711 0.000000 0.000000 0.294282 0.039159 0.068875 0.136708 0.426266 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.5 -1. 0.5 -0.2 Chi 0. 5.8E-03 0. 0. 2.6E-03 6.2E-04 2.9E-03 3.7E-04 6.1E-06 Composition Misfit: 1.224661E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.968 0.094325 0.058735 0.000000 0.001307 0.000000 0.000000 0.000000 0.154368 0.691265 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 1.5E-02 0. 0. 0. 0.5 0.1 Chi 7.6E-05 8.7E-04 0. 2.0E-06 0. 0. 0. 2.8E-04 1.5E-05 Composition Misfit: 1.237036E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.384 0.000000 0.000000 0.024151 0.075562 0.191789 0.000902 0.187644 0.133429 0.386523 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.5 0.1 -1. 0.5 2. Chi 0. 0. 3.2E-04 9.8E-04 2.8E-04 3.0E-04 1.8E-03 3.6E-04 2.2E-03 Composition Misfit: 6.231303E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.519 0.000000 0.000000 0.004733 0.000000 0.147128 0.002610 0.054182 0.427916 0.363431 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 1.8E-03 5.8E-04 1.8E-02 9.9E-04 1.4E-03 Composition Misfit: 2.422736E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.397 0.000000 0.000000 0.365821 0.000000 0.611425 0.009665 0.013089 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.9 0. 0.9 0.1 -0.5 0. 0. Chi 0. 0. 6.8E-04 0. 5.6E-04 1.2E-05 7.3E-04 0. 0. Composition Misfit: 1.989075E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.531 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.504 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023193 0.014675 0.006944 0.016387 0.052653 0.000914 0.040107 0.034100 0.001429 0.107923 0.701677 Mica 0.019123 0.002555 0.000000 0.062130 0.005205 0.000000 0.004900 0.165061 0.000473 0.239710 0.500843 Gt 0.000000 0.034618 0.000000 0.000000 0.293492 0.039054 0.068690 0.000000 0.002683 0.136341 0.425122 Fsp 0.094325 0.058735 0.000000 0.001307 0.000000 0.000000 0.000000 0.000000 0.000000 0.154368 0.691265 Bio 0.000000 0.000000 0.021345 0.066782 0.169505 0.000797 0.165842 0.112220 0.003969 0.117926 0.341613 St 0.000000 0.000000 0.004305 0.000000 0.133821 0.002374 0.049282 0.088149 0.002294 0.389214 0.330561 Ilm 0.000000 0.000000 0.342822 0.000000 0.572984 0.009057 0.012266 0.000000 0.062871 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -771562. -751817. -929198. -846071. -311960. -465758. -636642. -289757. -408985. -1632775. -884309. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 152 converged, 63 successes so far. Misfit function evaluations this try => 243 Misfit this try = 0.202857 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 3.785630E-07 Bayes score, PP * exp(-Misfit) = 3.090568E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 5716.35 853.155 0.939003 0.587055 Final coordinates: 7665.65 837.670 0.810983 0.515070 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.202857 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.970 0.026456 0.002429 0.000000 0.071553 0.004269 0.000000 0.004321 0.291116 0.599856 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -3. 0. 0. 1. 1. 0. 1. -0.6 1.8E-02 Chi 9.8E-03 0. 0. 2.3E-03 1.1E-02 0. 2.0E-02 3.9E-04 3.4E-08 Composition Misfit: 4.574376E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.950 0.000000 0.043328 0.000000 0.000000 0.288768 0.049631 0.054914 0.136989 0.426371 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 2. -2. -1.1E-02 0.5 -0.2 Chi 0. 1.2E-02 0. 0. 3.8E-03 4.8E-03 2.6E-07 3.4E-04 6.9E-06 Composition Misfit: 2.089990E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.023 0.094825 0.058647 0.000000 0.000851 0.000000 0.000000 0.000000 0.154324 0.691353 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.1E-04 8.5E-04 0. 3.0E-04 0. 0. 0. 2.8E-04 1.4E-05 Composition Misfit: 1.549993E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.267 0.000000 0.000000 0.021340 0.075140 0.191863 0.000813 0.194206 0.127105 0.389534 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 3.6E-03 -1. -0.5 0.2 -2. 1. 1. Chi 0. 0. 3.7E-08 8.9E-04 2.8E-04 4.6E-04 3.1E-03 1.4E-03 1.8E-03 Composition Misfit: 7.941352E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.836 0.000000 0.000000 0.003974 0.000000 0.154276 0.002695 0.046801 0.428691 0.363563 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -2. 0.2 -3. 1. 1. Chi 0. 0. 2.8E-03 0. 3.5E-03 4.9E-04 1.2E-02 9.2E-04 1.4E-03 Composition Misfit: 2.134159E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.836 0.000000 0.000000 0.220408 0.000000 0.766450 0.007908 0.005234 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -6. 0.3 0.8 0. 0. Chi 0. 0. 0.1 0. 2.4E-02 5.5E-04 4.3E-03 0. 0. Composition Misfit: 0.105381 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.008 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.110 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023264 0.014720 0.006965 0.016437 0.052815 0.000917 0.040229 0.029898 0.002677 0.108254 0.703825 Mica 0.022068 0.002026 0.000000 0.059684 0.003561 0.000000 0.003605 0.165530 0.000343 0.242828 0.500357 Gt 0.000000 0.043217 0.000000 0.000000 0.288028 0.049503 0.054774 0.000000 0.002561 0.136638 0.425279 Fsp 0.094825 0.058647 0.000000 0.000851 0.000000 0.000000 0.000000 0.000000 0.000000 0.154324 0.691353 Bio 0.000000 0.000000 0.018824 0.066284 0.169249 0.000717 0.171316 0.113744 0.004121 0.112124 0.343621 St 0.000000 0.000000 0.003615 0.000000 0.140325 0.002451 0.042568 0.088183 0.002245 0.389926 0.330687 Ilm 0.000000 0.000000 0.193375 0.000000 0.672445 0.006938 0.004592 0.000000 0.122650 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -759324. -744782. -922392. -834299. -304719. -456086. -631888. -285289. -407037. -1624029. -879087. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 153 converged, 64 successes so far. Misfit function evaluations this try => 200 Misfit this try = 0.164666 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.023406E-06 Bayes score, PP * exp(-Misfit) = 8.680295E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 12046.2 878.760 0.941794 9.184474E-02 Final coordinates: 8713.38 920.736 0.772166 0.692502 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.161939 Extraneous predicted phases: 2.726927E-3 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.255 0.023541 0.003542 0.000000 0.073553 0.006349 0.000000 0.006261 0.287013 0.599742 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 0.7 0. 1. -0.4 3.3E-02 Chi 7.4E-03 0. 0. 1.6E-03 3.6E-03 0. 8.5E-03 1.5E-04 1.1E-07 Composition Misfit: 2.480715E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.520 0.000000 0.034483 0.000000 0.000000 0.279639 0.047781 0.076009 0.136064 0.426024 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -1. -2. 0.6 -0.2 Chi 0. 5.6E-03 0. 0. 6.4E-03 3.8E-03 5.9E-03 4.4E-04 4.4E-06 Composition Misfit: 2.222648E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.429 0.093549 0.060226 0.000000 0.001339 0.000000 0.000000 0.000000 0.155113 0.689774 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 5.6E-03 0. 0. 0. 0.4 0.2 Chi 3.9E-05 1.2E-03 0. 2.8E-07 0. 0. 0. 2.2E-04 3.2E-05 Composition Misfit: 1.523576E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.211 0.000000 0.000000 0.023520 0.075549 0.180382 0.001162 0.200177 0.133237 0.385973 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. 0.3 0.1 -2. 0.5 2. Chi 0. 0. 2.0E-04 9.8E-04 9.3E-05 5.9E-05 4.7E-03 3.8E-04 2.3E-03 Composition Misfit: 8.728737E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.897 0.000000 0.000000 0.004526 0.000000 0.139953 0.003354 0.061371 0.427491 0.363305 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.7 0.1 -5. 1. 1. Chi 0. 0. 1.7E-03 0. 5.7E-04 7.0E-05 2.4E-02 1.0E-03 1.5E-03 Composition Misfit: 2.895173E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.756 0.000000 0.000000 0.234501 0.000000 0.747576 0.009503 0.008420 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. 0.1 0.3 0. 0. Chi 0. 0. 0.1 0. 1.8E-02 2.6E-05 3.0E-04 0. 0. Composition Misfit: 7.570157E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.021 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.750 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.162 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000017 -.000017 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023030 0.014572 0.006895 0.016271 0.052283 0.000907 0.039824 0.039793 0.002523 0.107164 0.696739 Mica 0.019645 0.002955 0.000000 0.061378 0.005298 0.000000 0.005224 0.165000 0.000525 0.239505 0.500470 Gt 0.000000 0.034381 0.000000 0.000000 0.278811 0.047639 0.075784 0.000000 0.002963 0.135661 0.424761 Fsp 0.093549 0.060226 0.000000 0.001339 0.000000 0.000000 0.000000 0.000000 0.000000 0.155113 0.689774 Bio 0.000000 0.000000 0.020770 0.066716 0.159293 0.001026 0.176773 0.112663 0.004254 0.117659 0.340847 St 0.000000 0.000000 0.004116 0.000000 0.127275 0.003050 0.055812 0.088105 0.002482 0.388765 0.330394 Ilm 0.000000 0.000000 0.207019 0.000000 0.659966 0.008390 0.007433 0.000000 0.117192 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774207. -753066. -931116. -849118. -313849. -465844. -637148. -290473. -405327. -1634578. -885422. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 155 converged, 65 successes so far. Misfit function evaluations this try => 398 Misfit this try = 0.155214 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 2.965185E-07 Bayes score, PP * exp(-Misfit) = 2.538885E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 12873.2 821.720 5.153725E-02 0.323575 Final coordinates: 6168.88 862.383 0.495572 0.551903 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.141001 Extraneous predicted phases: 1.421330E-2 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 0.020447 0.001788 0.000000 0.077883 0.004665 0.000000 0.004080 0.290805 0.600332 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.6 1. 0. 1. -0.6 -4.3E-02 Chi 5.0E-03 0. 0. 5.6E-04 9.0E-03 0. 2.2E-02 3.7E-04 1.8E-07 Composition Misfit: 3.867753E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.003 0.000000 0.023272 0.000000 0.000000 0.253894 0.103538 0.053718 0.138602 0.426976 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.3 0. 0. 4. -8. 0.1 0.4 -0.3 Chi 0. 3.2E-04 0. 0. 1.8E-02 4.6E-02 2.2E-05 2.0E-04 1.3E-05 Composition Misfit: 6.514771E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.613 0.094018 0.059485 0.000000 0.001239 0.000000 0.000000 0.000000 0.154742 0.690515 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 3.4E-02 0. 0. 0. 0.4 0.2 Chi 6.0E-05 1.0E-03 0. 1.1E-05 0. 0. 0. 2.4E-04 2.3E-05 Composition Misfit: 1.385071E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.542 0.000000 0.000000 0.023316 0.076023 0.197346 0.002075 0.178798 0.140341 0.382101 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.2 -1. -0.9 -0.2 -0.6 -2.0E-03 2. Chi 0. 0. 1.6E-04 1.1E-03 8.4E-04 2.0E-04 4.8E-04 5.3E-09 3.0E-03 Composition Misfit: 5.770184E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.704 0.000000 0.000000 0.003814 0.000000 0.150861 0.006976 0.046041 0.428745 0.363563 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -1. -0.7 -3. 1. 1. Chi 0. 0. 3.2E-03 0. 2.6E-03 1.4E-03 1.2E-02 9.1E-04 1.4E-03 Composition Misfit: 2.120085E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.323 0.000000 0.000000 0.347038 0.000000 0.619028 0.024484 0.009451 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.2 0. 0.5 -2. 0.1 0. 0. Chi 0. 0. 2.5E-05 0. 1.9E-04 8.6E-03 3.2E-05 0. 0. Composition Misfit: 8.819719E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.786 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.960 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.068 0.000000 0.000000 0.206496 0.000000 0.653945 0.017183 0.004975 0.000000 0.117402 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023238 0.014704 0.006957 0.016419 0.052757 0.000916 0.040185 0.032001 0.001634 0.108135 0.703054 Mica 0.017054 0.001491 0.000000 0.064960 0.003891 0.000000 0.003403 0.165519 0.000411 0.242552 0.500719 Gt 0.000000 0.023229 0.000000 0.000000 0.253422 0.103345 0.053618 0.000000 0.001858 0.138345 0.426182 Fsp 0.094018 0.059485 0.000000 0.001239 0.000000 0.000000 0.000000 0.000000 0.000000 0.154742 0.690515 Bio 0.000000 0.000000 0.020568 0.067064 0.174090 0.001831 0.157727 0.113559 0.004286 0.123802 0.337072 St 0.000000 0.000000 0.003469 0.000000 0.137216 0.006345 0.041877 0.088181 0.002269 0.389965 0.330679 Ilm 0.000000 0.000000 0.322382 0.000000 0.575047 0.022744 0.008779 0.000000 0.071047 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -771635. -753176. -928610. -846439. -309700. -455329. -636116. -289816. -408639. -1630982. -885058. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 156 converged, 66 successes so far. Misfit function evaluations this try => 210 Misfit this try = 6.250550E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.586569E-07 Bayes score, PP * exp(-Misfit) = 9.005698E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 8019.86 966.039 0.111824 0.495640 Final coordinates: 8792.90 928.915 0.415687 0.481698 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.250550E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.017 0.021534 0.003032 0.000000 0.075751 0.007073 0.000000 0.006179 0.285923 0.600509 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.8E-03 0. 0. 1.0E-03 2.4E-03 0. 8.8E-03 1.0E-04 4.3E-07 Composition Misfit: 2.107711E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.546 0.000000 0.031002 0.000000 0.000000 0.302706 0.032479 0.070950 0.136627 0.426235 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. 0.2 -2. 0.5 -0.2 Chi 0. 3.5E-03 0. 0. 1.2E-03 9.6E-05 3.7E-03 3.8E-04 5.8E-06 Composition Misfit: 8.905751E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.539 0.094793 0.057347 0.000000 0.001533 0.000000 0.000000 0.000000 0.153673 0.692653 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 1.0E-04 5.8E-04 0. 2.0E-05 0. 0. 0. 3.4E-04 4.9E-06 Composition Misfit: 1.045600E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.562 0.000000 0.000000 0.025054 0.075725 0.197751 0.000825 0.179563 0.135879 0.385203 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.2 -0.7 0.3 2. Chi 0. 0. 5.4E-04 1.0E-03 8.9E-04 4.4E-04 5.6E-04 1.4E-04 2.5E-03 Composition Misfit: 6.048254E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.148 0.000000 0.000000 0.004824 0.000000 0.148364 0.002273 0.053462 0.427695 0.363382 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.3E-03 0. 2.0E-03 1.1E-03 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.430678E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.319 0.000000 0.000000 0.353355 0.000000 0.625672 0.008129 0.012844 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.2 0. 0.2 0.3 -0.5 0. 0. Chi 0. 0. 3.2E-05 0. 3.0E-05 4.3E-04 6.3E-04 0. 0. Composition Misfit: 1.122003E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.688 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.181 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023339 0.014768 0.006987 0.016490 0.052986 0.000920 0.040360 0.028052 0.001377 0.108606 0.706115 Mica 0.017971 0.002530 0.000000 0.063219 0.005903 0.000000 0.005156 0.164911 0.000525 0.238621 0.501164 Gt 0.000000 0.030918 0.000000 0.000000 0.301884 0.032391 0.070757 0.000000 0.002718 0.136255 0.425076 Fsp 0.094793 0.057347 0.000000 0.001533 0.000000 0.000000 0.000000 0.000000 0.000000 0.153673 0.692653 Bio 0.000000 0.000000 0.022154 0.066961 0.174863 0.000729 0.158780 0.111767 0.003977 0.120152 0.340618 St 0.000000 0.000000 0.004387 0.000000 0.134941 0.002068 0.048625 0.088135 0.002341 0.388999 0.330505 Ilm 0.000000 0.000000 0.329216 0.000000 0.582930 0.007574 0.011966 0.000000 0.068314 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775520. -754456. -931719. -849693. -314109. -469748. -638458. -291445. -410032. -1635719. -886129. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio F sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio F sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 160 converged, 67 successes so far. Misfit function evaluations this try => 254 Misfit this try = 0.116103 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.692967E-07 Bayes score, PP * exp(-Misfit) = 8.630458E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 7868.01 922.897 0.761137 0.656291 Final coordinates: 8522.95 922.160 0.570178 0.486968 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.116103 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.039 0.021496 0.002928 0.000000 0.075888 0.006804 0.000000 0.005977 0.286480 0.600429 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.4 -0.1 Chi 5.8E-03 0. 0. 9.7E-04 2.8E-03 0. 9.6E-03 1.3E-04 3.1E-07 Composition Misfit: 2.216064E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.079 0.000000 0.030545 0.000000 0.000000 0.295706 0.041185 0.069622 0.136685 0.426257 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.8 -1. 0.5 -0.2 Chi 0. 3.3E-03 0. 0. 2.3E-03 1.2E-03 3.2E-03 3.7E-04 6.0E-06 Composition Misfit: 1.030231E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.587 0.094507 0.058001 0.000000 0.001493 0.000000 0.000000 0.000000 0.154000 0.691999 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -3.9E-02 0. 0. 0. 0.5 0.1 Chi 8.6E-05 7.1E-04 0. 1.2E-05 0. 0. 0. 3.1E-04 9.0E-06 Composition Misfit: 1.123775E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.532 0.000000 0.000000 0.024678 0.075739 0.196295 0.001024 0.181334 0.136090 0.384840 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.8 0.1 -0.8 0.3 2. Chi 0. 0. 4.4E-04 1.0E-03 7.1E-04 1.6E-04 7.7E-04 1.3E-04 2.5E-03 Composition Misfit: 5.749377E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.345 0.000000 0.000000 0.004636 0.000000 0.148000 0.002881 0.053413 0.427702 0.363368 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.6E-03 0. 1.9E-03 3.2E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.369103E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.464 0.000000 0.000000 0.251417 0.000000 0.731220 0.008851 0.008511 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 0.2 0. 0. Chi 0. 0. 3.9E-02 0. 1.4E-02 1.5E-04 2.6E-04 0. 0. Composition Misfit: 5.307586E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.622 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.332 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023320 0.014756 0.006982 0.016477 0.052943 0.000919 0.040327 0.028336 0.001887 0.108517 0.705537 Mica 0.017938 0.002443 0.000000 0.063328 0.005678 0.000000 0.004988 0.164976 0.000523 0.239067 0.501058 Gt 0.000000 0.030463 0.000000 0.000000 0.294910 0.041074 0.069434 0.000000 0.002693 0.136317 0.425109 Fsp 0.094507 0.058001 0.000000 0.001493 0.000000 0.000000 0.000000 0.000000 0.000000 0.154000 0.691999 Bio 0.000000 0.000000 0.021812 0.066942 0.173493 0.000905 0.160271 0.112071 0.004086 0.120282 0.340138 St 0.000000 0.000000 0.004217 0.000000 0.134604 0.002621 0.048578 0.088127 0.002387 0.388989 0.330478 Ilm 0.000000 0.000000 0.223623 0.000000 0.650383 0.007873 0.007570 0.000000 0.110551 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775166. -754253. -931519. -849422. -313713. -467311. -638155. -291239. -408932. -1635219. -886013. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 162 converged, 68 successes so far. Misfit function evaluations this try => 177 Misfit this try = 0.213702 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.103224E-06 Bayes score, PP * exp(-Misfit) = 8.909519E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 6758.56 918.872 0.948310 0.742854 Final coordinates: 9242.39 922.069 0.943811 0.679833 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.213702 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.254 0.025955 0.004212 0.000000 0.070782 0.006270 0.000000 0.006589 0.287054 0.599138 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 0.8 0. 1. -0.4 0.1 Chi 9.4E-03 0. 0. 2.6E-03 3.8E-03 0. 7.3E-03 1.5E-04 1.2E-06 Composition Misfit: 2.753000E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.994 0.000000 0.040001 0.000000 0.000000 0.280957 0.036664 0.081752 0.135001 0.425625 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.3 -3. 0.6 -0.1 Chi 0. 9.5E-03 0. 0. 6.0E-03 1.6E-04 8.9E-03 5.8E-04 2.2E-06 Composition Misfit: 2.506109E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.812 0.093711 0.060101 0.000000 0.001239 0.000000 0.000000 0.000000 0.155050 0.689899 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 3.5E-02 0. 0. 0. 0.4 0.2 Chi 4.5E-05 1.2E-03 0. 1.1E-05 0. 0. 0. 2.2E-04 3.1E-05 Composition Misfit: 1.511603E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.902 0.000000 0.000000 0.022448 0.075319 0.172263 0.000873 0.211752 0.129781 0.387564 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.1 -1. 0.8 0.2 -3. 0.8 1. Chi 0. 0. 5.2E-05 9.3E-04 8.7E-04 3.5E-04 8.4E-03 8.5E-04 2.1E-03 Composition Misfit: 1.355410E-2 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.345 0.000000 0.000000 0.004337 0.000000 0.136028 0.002504 0.066635 0.427265 0.363231 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.4 0.3 -5. 1. 1. Chi 0. 0. 2.1E-03 0. 1.8E-04 7.1E-04 2.9E-02 1.1E-03 1.5E-03 Composition Misfit: 3.415785E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.988 0.000000 0.000000 0.215618 0.000000 0.770201 0.006458 0.007724 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -6. 0.6 0.4 0. 0. Chi 0. 0. 0.1 0. 2.6E-02 1.9E-03 6.7E-04 0. 0. Composition Misfit: 0.111887 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.059 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.645 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023033 0.014574 0.006896 0.016274 0.052292 0.000907 0.039831 0.039072 0.003085 0.107181 0.696855 Mica 0.021659 0.003515 0.000000 0.059067 0.005233 0.000000 0.005499 0.164967 0.000535 0.239546 0.499980 Gt 0.000000 0.039864 0.000000 0.000000 0.279995 0.036538 0.081472 0.000000 0.003426 0.134538 0.424167 Fsp 0.093711 0.060101 0.000000 0.001239 0.000000 0.000000 0.000000 0.000000 0.000000 0.155050 0.689899 Bio 0.000000 0.000000 0.019811 0.066470 0.152024 0.000771 0.186873 0.113128 0.004362 0.114533 0.342028 St 0.000000 0.000000 0.003944 0.000000 0.123693 0.002277 0.060593 0.088078 0.002601 0.388520 0.330294 Ilm 0.000000 0.000000 0.188776 0.000000 0.674319 0.005654 0.006762 0.000000 0.124490 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772198. -751531. -930766. -847483. -313573. -467561. -636221. -289617. -402575. -1633644. -884356. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 169 converged, 69 successes so far. Misfit function evaluations this try => 278 Misfit this try = 0.170558 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 7.996908E-07 Bayes score, PP * exp(-Misfit) = 6.742943E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 5934.30 828.713 0.213671 0.911868 Final coordinates: 7733.31 916.441 0.281176 0.751107 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.126039 Extraneous predicted phases: 4.451978E-2 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.554 0.020982 0.002696 0.000000 0.076666 0.005524 0.000000 0.005366 0.288294 0.600472 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.9 0. 1. -0.5 -0.1 Chi 5.4E-03 0. 0. 7.9E-04 5.7E-03 0. 1.2E-02 2.1E-04 3.7E-07 Composition Misfit: 2.728755E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.111 0.000000 0.025054 0.000000 0.000000 0.275489 0.067212 0.065980 0.139102 0.427163 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 3. -4. -1. 0.3 -0.3 Chi 0. 8.1E-04 0. 0. 7.8E-03 1.6E-02 1.9E-03 1.6E-04 1.5E-05 Composition Misfit: 2.687605E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.150 0.093657 0.059656 0.000000 0.001515 0.000000 0.000000 0.000000 0.154828 0.690344 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. -4.6E-02 0. 0. 0. 0.4 0.2 Chi 4.3E-05 1.1E-03 0. 1.6E-05 0. 0. 0. 2.4E-04 2.5E-05 Composition Misfit: 1.411279E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.949 0.000000 0.000000 0.026213 0.076041 0.192522 0.001681 0.178169 0.140619 0.384754 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.6 -1. -0.5 -0.1 -0.6 -2.2E-02 2. Chi 0. 0. 9.0E-04 1.1E-03 3.4E-04 3.9E-05 4.2E-04 6.6E-07 2.5E-03 Composition Misfit: 5.309017E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.576 0.000000 0.000000 0.005491 0.000000 0.144153 0.004882 0.052281 0.429337 0.363856 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.3 0. -1. -0.2 -4. 1. 1. Chi 0. 0. 6.2E-04 0. 1.2E-03 2.2E-04 1.6E-02 8.6E-04 1.4E-03 Composition Misfit: 2.075679E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.164 0.000000 0.000000 0.438226 0.000000 0.526842 0.018670 0.016261 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -5. 0. 5. -1. -1. 0. 0. Chi 0. 0. 1.8E-02 0. 2.0E-02 4.0E-03 2.4E-03 0. 0. Composition Misfit: 4.439802E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.003 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.813 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.660 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000044 -.000044 0.000000 0.000000 ru 0.021 0.000000 0.000000 1.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022989 0.014546 0.006883 0.016243 0.052191 0.000906 0.039754 0.043085 0.000917 0.106975 0.695512 Mica 0.017508 0.002250 0.000000 0.063973 0.004609 0.000000 0.004478 0.165211 0.000354 0.240562 0.501054 Gt 0.000000 0.025013 0.000000 0.000000 0.275037 0.067102 0.065872 0.000000 0.001640 0.138874 0.426463 Fsp 0.093657 0.059656 0.000000 0.001515 0.000000 0.000000 0.000000 0.000000 0.000000 0.154828 0.690344 Bio 0.000000 0.000000 0.023211 0.067333 0.170475 0.001489 0.157766 0.111455 0.003062 0.124516 0.340693 St 0.000000 0.000000 0.004997 0.000000 0.131186 0.004443 0.047578 0.088300 0.001652 0.390717 0.331127 Ilm 0.000000 0.000000 0.425097 0.000000 0.511057 0.018111 0.015774 0.000000 0.029961 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777427. -755761. -931019. -851919. -314115. -463610. -638675. -291851. -420407. -1636016. -887204. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 175 converged, 70 successes so far. Misfit function evaluations this try => 158 Misfit this try = 6.118793E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.409209E-07 Bayes score, PP * exp(-Misfit) = 8.850739E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 5726.88 885.711 0.519637 0.608903 Final coordinates: 8620.29 927.402 0.424410 0.499264 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.118793E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.051 0.021231 0.002958 0.000000 0.076110 0.006991 0.000000 0.006062 0.286148 0.600499 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.2E-04 2.5E-03 0. 9.2E-03 1.1E-04 4.1E-07 Composition Misfit: 2.127534E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.198 0.000000 0.030195 0.000000 0.000000 0.298964 0.037788 0.070053 0.136727 0.426273 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.4 -1. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 1.8E-03 3.3E-04 3.3E-03 3.7E-04 6.1E-06 Composition Misfit: 8.875318E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.569 0.094537 0.057845 0.000000 0.001540 0.000000 0.000000 0.000000 0.153923 0.692155 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.8E-05 6.8E-04 0. 2.2E-05 0. 0. 0. 3.2E-04 8.0E-06 Composition Misfit: 1.108914E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.501 0.000000 0.000000 0.025037 0.075771 0.197912 0.000958 0.179002 0.136563 0.384757 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.4E-04 1.0E-03 9.1E-04 2.3E-04 5.0E-04 1.0E-04 2.5E-03 Composition Misfit: 5.838924E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.146 0.000000 0.000000 0.004763 0.000000 0.148352 0.002660 0.053116 0.427725 0.363385 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 5.2E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.354445E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.316 0.000000 0.000000 0.348378 0.000000 0.629590 0.009501 0.012530 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. 1.9E-02 0.1 -0.4 0. 0. Chi 0. 0. 7.6E-06 0. 2.7E-07 2.6E-05 5.1E-04 0. 0. Composition Misfit: 5.449794E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.871 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.348 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023315 0.014752 0.006980 0.016473 0.052931 0.000919 0.040318 0.029045 0.001404 0.108491 0.705373 Mica 0.017718 0.002469 0.000000 0.063517 0.005835 0.000000 0.005059 0.164939 0.000526 0.238801 0.501137 Gt 0.000000 0.030114 0.000000 0.000000 0.298164 0.037687 0.069865 0.000000 0.002675 0.136362 0.425133 Fsp 0.094537 0.057845 0.000000 0.001540 0.000000 0.000000 0.000000 0.000000 0.000000 0.153923 0.692155 Bio 0.000000 0.000000 0.022136 0.066992 0.174982 0.000847 0.158263 0.111848 0.004012 0.120741 0.340179 St 0.000000 0.000000 0.004332 0.000000 0.134928 0.002419 0.048310 0.088135 0.002347 0.389024 0.330505 Ilm 0.000000 0.000000 0.323828 0.000000 0.585224 0.008832 0.011647 0.000000 0.070469 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775966. -754721. -931899. -850117. -314167. -468559. -638561. -291580. -409899. -1635849. -886360. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 176 converged, 71 successes so far. Misfit function evaluations this try => 143 Misfit this try = 6.190775E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.993339E-07 Bayes score, PP * exp(-Misfit) = 9.393435E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 5783.38 935.066 0.563608 0.810323 Final coordinates: 8473.48 916.704 0.430385 0.498501 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.190775E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.009 0.021445 0.002836 0.000000 0.076002 0.006706 0.000000 0.005865 0.286653 0.600493 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.4 -0.1 Chi 5.7E-03 0. 0. 9.4E-04 3.0E-03 0. 1.0E-02 1.3E-04 4.0E-07 Composition Misfit: 2.265098E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.145 0.000000 0.031132 0.000000 0.000000 0.298443 0.039530 0.067797 0.136799 0.426300 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.6 -1. 0.5 -0.2 Chi 0. 3.6E-03 0. 0. 1.8E-03 7.1E-04 2.5E-03 3.6E-04 6.3E-06 Composition Misfit: 9.012799E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.566 0.094593 0.057896 0.000000 0.001458 0.000000 0.000000 0.000000 0.153948 0.692104 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -2.9E-02 0. 0. 0. 0.5 0.1 Chi 9.2E-05 6.9E-04 0. 6.9E-06 0. 0. 0. 3.1E-04 8.3E-06 Composition Misfit: 1.106190E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.568 0.000000 0.000000 0.024642 0.075723 0.198488 0.000958 0.179254 0.135841 0.385095 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.9 0.1 -0.7 0.3 2. Chi 0. 0. 4.4E-04 1.0E-03 9.9E-04 2.3E-04 5.3E-04 1.5E-04 2.5E-03 Composition Misfit: 5.817744E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.012 0.000000 0.000000 0.004624 0.000000 0.149497 0.002714 0.051931 0.427834 0.363401 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.6E-03 0. 2.3E-03 4.7E-04 1.6E-02 1.0E-03 1.4E-03 Composition Misfit: 2.297514E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.332 0.000000 0.000000 0.347988 0.000000 0.630421 0.009637 0.011954 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. -1.9E-02 0.1 -0.3 0. 0. Chi 0. 0. 1.2E-05 0. 2.8E-07 1.4E-05 3.2E-04 0. 0. Composition Misfit: 3.449014E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.037 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.332 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023316 0.014752 0.006980 0.016473 0.052932 0.000919 0.040319 0.029001 0.001424 0.108494 0.705390 Mica 0.017896 0.002366 0.000000 0.063423 0.005596 0.000000 0.004895 0.165003 0.000507 0.239209 0.501106 Gt 0.000000 0.031049 0.000000 0.000000 0.297654 0.039426 0.067618 0.000000 0.002643 0.136437 0.425173 Fsp 0.094593 0.057896 0.000000 0.001458 0.000000 0.000000 0.000000 0.000000 0.000000 0.153948 0.692104 Bio 0.000000 0.000000 0.021781 0.066930 0.175441 0.000846 0.158440 0.112080 0.004032 0.120068 0.340381 St 0.000000 0.000000 0.004206 0.000000 0.135969 0.002468 0.047232 0.088138 0.002348 0.389121 0.330518 Ilm 0.000000 0.000000 0.323407 0.000000 0.585890 0.008957 0.011109 0.000000 0.070637 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774092. -753632. -930859. -848265. -313025. -466959. -637830. -290879. -409583. -1634455. -885535. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 177 converged, 72 successes so far. Misfit function evaluations this try => 118 Misfit this try = 6.181176E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.437384E-07 Bayes score, PP * exp(-Misfit) = 8.871706E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 5610.87 924.256 0.150342 0.875134 Final coordinates: 8487.77 924.137 0.429331 0.506842 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.181176E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.042 0.021133 0.002892 0.000000 0.076264 0.006867 0.000000 0.005950 0.286406 0.600488 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.5E-03 0. 0. 8.8E-04 2.7E-03 0. 9.7E-03 1.2E-04 4.0E-07 Composition Misfit: 2.176453E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.028 0.000000 0.029927 0.000000 0.000000 0.296645 0.041267 0.069026 0.136826 0.426310 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.8 -1. 0.5 -0.2 Chi 0. 2.9E-03 0. 0. 2.2E-03 1.2E-03 2.9E-03 3.6E-04 6.4E-06 Composition Misfit: 9.586411E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.584 0.094435 0.058077 0.000000 0.001527 0.000000 0.000000 0.000000 0.154038 0.691923 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.9E-02 0. 0. 0. 0.5 0.1 Chi 8.2E-05 7.2E-04 0. 1.9E-05 0. 0. 0. 3.1E-04 9.6E-06 Composition Misfit: 1.139075E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.499 0.000000 0.000000 0.024958 0.075787 0.198068 0.001036 0.178750 0.136810 0.384591 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.2E-04 1.0E-03 9.3E-04 1.5E-04 4.8E-04 9.0E-05 2.6E-03 Composition Misfit: 5.749746E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.567 0.000000 0.000000 0.004700 0.000000 0.148549 0.002907 0.052686 0.427769 0.363390 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 2.1E-03 3.0E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.309829E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.318 0.000000 0.000000 0.345696 0.000000 0.631767 0.010310 0.012228 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.2 0. -0.1 -4.9E-02 -0.4 0. 0. Chi 0. 0. 5.4E-05 0. 4.9E-06 9.3E-06 4.1E-04 0. 0. Composition Misfit: 4.736986E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.538 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.424 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023304 0.014745 0.006977 0.016465 0.052907 0.000918 0.040299 0.029472 0.001420 0.108442 0.705050 Mica 0.017636 0.002414 0.000000 0.063643 0.005730 0.000000 0.004966 0.164971 0.000521 0.239008 0.501112 Gt 0.000000 0.029848 0.000000 0.000000 0.295864 0.041158 0.068845 0.000000 0.002632 0.136466 0.425188 Fsp 0.094435 0.058077 0.000000 0.001527 0.000000 0.000000 0.000000 0.000000 0.000000 0.154038 0.691923 Bio 0.000000 0.000000 0.022064 0.066999 0.175100 0.000916 0.158022 0.111934 0.004027 0.120945 0.339993 St 0.000000 0.000000 0.004274 0.000000 0.135107 0.002644 0.047919 0.088136 0.002350 0.389062 0.330509 Ilm 0.000000 0.000000 0.320935 0.000000 0.586516 0.009572 0.011352 0.000000 0.071626 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775798. -754642. -931767. -849952. -313947. -467577. -638454. -291500. -409757. -1635612. -886308. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 178 converged, 73 successes so far. Misfit function evaluations this try => 169 Misfit this try = 6.141324E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.671255E-07 Bayes score, PP * exp(-Misfit) = 9.095182E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 8348.49 920.424 0.336575 0.799579 Final coordinates: 8653.04 925.480 0.426457 0.491471 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.141324E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.004 0.021382 0.002958 0.000000 0.075961 0.006967 0.000000 0.006064 0.286167 0.600501 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.7E-03 0. 0. 9.5E-04 2.5E-03 0. 9.2E-03 1.1E-04 4.2E-07 Composition Misfit: 2.145526E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.311 0.000000 0.030746 0.000000 0.000000 0.300346 0.036095 0.069866 0.136688 0.426258 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.2 -1. 0.5 -0.2 Chi 0. 3.4E-03 0. 0. 1.5E-03 9.5E-05 3.3E-03 3.7E-04 6.0E-06 Composition Misfit: 8.657726E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.563 0.094646 0.057670 0.000000 0.001518 0.000000 0.000000 0.000000 0.153835 0.692330 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.7E-02 0. 0. 0. 0.5 0.1 Chi 9.5E-05 6.4E-04 0. 1.7E-05 0. 0. 0. 3.2E-04 6.8E-06 Composition Misfit: 1.082715E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.561 0.000000 0.000000 0.024932 0.075741 0.198051 0.000905 0.179260 0.136120 0.384991 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.7 0.3 2. Chi 0. 0. 5.1E-04 1.0E-03 9.3E-04 3.0E-04 5.3E-04 1.3E-04 2.5E-03 Composition Misfit: 5.907620E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.691 0.000000 0.000000 0.004737 0.000000 0.148677 0.002518 0.052962 0.427724 0.363382 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.1E-03 6.9E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.369793E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.324 0.000000 0.000000 0.346850 0.000000 0.631856 0.008934 0.012360 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.2 0. -0.1 0.2 -0.4 0. 0. Chi 0. 0. 2.9E-05 0. 5.5E-06 1.3E-04 4.5E-04 0. 0. Composition Misfit: 6.119893E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.266 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.280 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023325 0.014759 0.006983 0.016480 0.052954 0.000919 0.040336 0.028604 0.001411 0.108540 0.705688 Mica 0.017844 0.002468 0.000000 0.063392 0.005814 0.000000 0.005061 0.164941 0.000523 0.238817 0.501139 Gt 0.000000 0.030663 0.000000 0.000000 0.299538 0.035998 0.069678 0.000000 0.002692 0.136320 0.425111 Fsp 0.094646 0.057670 0.000000 0.001518 0.000000 0.000000 0.000000 0.000000 0.000000 0.153835 0.692330 Bio 0.000000 0.000000 0.022042 0.066963 0.175097 0.000800 0.158484 0.111884 0.004013 0.120344 0.340371 St 0.000000 0.000000 0.004308 0.000000 0.135223 0.002291 0.048170 0.088133 0.002354 0.389020 0.330501 Ilm 0.000000 0.000000 0.322180 0.000000 0.586913 0.008298 0.011481 0.000000 0.071128 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775352. -754361. -931612. -849511. -313875. -468628. -638349. -291364. -409747. -1635469. -886076. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 180 converged, 74 successes so far. Misfit function evaluations this try => 137 Misfit this try = 6.640393E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.740922E-07 Bayes score, PP * exp(-Misfit) = 9.115095E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 5682.82 810.784 0.950954 0.696663 Final coordinates: 8719.58 926.140 0.448608 0.576767 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.601877E-2 Extraneous predicted phases: 3.851595E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.938 0.021943 0.003151 0.000000 0.075306 0.006825 0.000000 0.006173 0.286297 0.600304 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.3 -3.9E-02 Chi 6.1E-03 0. 0. 1.1E-03 2.7E-03 0. 8.8E-03 1.2E-04 1.5E-07 Composition Misfit: 2.205070E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.047 0.000000 0.031799 0.000000 0.000000 0.295198 0.038303 0.071915 0.136571 0.426214 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -0.4 -2. 0.5 -0.2 Chi 0. 4.0E-03 0. 0. 2.4E-03 4.3E-04 4.1E-03 3.9E-04 5.7E-06 Composition Misfit: 1.129684E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.158 0.094277 0.058494 0.000000 0.001476 0.000000 0.000000 0.000000 0.154247 0.691506 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -3.4E-02 0. 0. 0. 0.5 0.1 Chi 7.3E-05 8.1E-04 0. 9.5E-06 0. 0. 0. 2.9E-04 1.3E-05 Composition Misfit: 1.195858E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.906 0.000000 0.000000 0.024807 0.075696 0.193062 0.000961 0.184703 0.135437 0.385333 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.6 0.1 -1. 0.4 2. Chi 0. 0. 4.8E-04 1.0E-03 3.8E-04 2.2E-04 1.2E-03 1.8E-04 2.4E-03 Composition Misfit: 5.950190E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.757 0.000000 0.000000 0.004825 0.000000 0.146111 0.002690 0.055342 0.427659 0.363373 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.3E-03 0. 1.6E-03 4.9E-04 1.9E-02 1.0E-03 1.4E-03 Composition Misfit: 2.480022E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.375 0.000000 0.000000 0.346388 0.000000 0.631021 0.009641 0.012951 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.2 0. -4.7E-02 0.1 -0.5 0. 0. Chi 0. 0. 3.8E-05 0. 1.7E-06 1.3E-05 6.7E-04 0. 0. Composition Misfit: 7.249604E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.277 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.481 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.061 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000022 -.000022 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023208 0.014685 0.006948 0.016398 0.052689 0.000914 0.040134 0.033400 0.001477 0.107996 0.702151 Mica 0.018312 0.002630 0.000000 0.062846 0.005696 0.000000 0.005152 0.164945 0.000520 0.238925 0.500974 Gt 0.000000 0.031712 0.000000 0.000000 0.294388 0.038198 0.071718 0.000000 0.002743 0.136196 0.425045 Fsp 0.094277 0.058494 0.000000 0.001476 0.000000 0.000000 0.000000 0.000000 0.000000 0.154247 0.691506 Bio 0.000000 0.000000 0.021931 0.066920 0.170680 0.000850 0.163290 0.111909 0.004023 0.119735 0.340661 St 0.000000 0.000000 0.004388 0.000000 0.132890 0.002446 0.050335 0.088132 0.002352 0.388963 0.330494 Ilm 0.000000 0.000000 0.321681 0.000000 0.586011 0.008953 0.012027 0.000000 0.071328 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775294. -754106. -931425. -849648. -314038. -468205. -638130. -291205. -409062. -1635431. -885995. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Mica Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Mica Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 184 converged, 75 successes so far. Misfit function evaluations this try => 128 Misfit this try = 6.317120E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.040490E-06 Bayes score, PP * exp(-Misfit) = 9.767939E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 8024.82 925.548 0.247375 0.693790 Final coordinates: 8431.88 905.075 0.431116 0.488644 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.317120E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.008 0.021956 0.002748 0.000000 0.075571 0.006431 0.000000 0.005712 0.287094 0.600487 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.4 -0.1 Chi 6.1E-03 0. 0. 1.0E-03 3.5E-03 0. 1.1E-02 1.5E-04 3.9E-07 Composition Misfit: 2.428617E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.302 0.000000 0.032997 0.000000 0.000000 0.300770 0.037373 0.065777 0.136789 0.426296 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -0.3 -1. 0.5 -0.2 Chi 0. 4.7E-03 0. 0. 1.5E-03 2.6E-04 1.8E-03 3.6E-04 6.3E-06 Composition Misfit: 8.648004E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.527 0.094825 0.057637 0.000000 0.001357 0.000000 0.000000 0.000000 0.153819 0.692363 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 3.6E-04 0. 0. 0. 0.5 0.1 Chi 1.1E-04 6.3E-04 0. 1.1E-09 0. 0. 0. 3.3E-04 6.6E-06 Composition Misfit: 1.071893E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.629 0.000000 0.000000 0.024168 0.075626 0.199010 0.000857 0.180081 0.134393 0.385864 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -1. 0.2 -0.7 0.4 2. Chi 0. 0. 3.2E-04 1.0E-03 1.1E-03 3.8E-04 6.2E-04 2.6E-04 2.3E-03 Composition Misfit: 5.984804E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.303 0.000000 0.000000 0.004517 0.000000 0.150921 0.002465 0.050717 0.427957 0.363423 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -3. 1. 1. Chi 0. 0. 1.8E-03 0. 2.6E-03 7.7E-04 1.5E-02 9.9E-04 1.4E-03 Composition Misfit: 2.279510E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.353 0.000000 0.000000 0.351813 0.000000 0.627811 0.008818 0.011558 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.1 0. 0.1 0.2 -0.2 0. 0. Chi 0. 0. 9.3E-06 0. 7.6E-06 1.6E-04 2.1E-04 0. 0. Composition Misfit: 3.852257E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.675 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.205 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023329 0.014761 0.006984 0.016483 0.052962 0.000919 0.040342 0.028444 0.001427 0.108556 0.705793 Mica 0.018322 0.002293 0.000000 0.063061 0.005366 0.000000 0.004767 0.165058 0.000484 0.239568 0.501081 Gt 0.000000 0.032909 0.000000 0.000000 0.299973 0.037274 0.065603 0.000000 0.002648 0.136426 0.425167 Fsp 0.094825 0.057637 0.000000 0.001357 0.000000 0.000000 0.000000 0.000000 0.000000 0.153819 0.692363 Bio 0.000000 0.000000 0.021357 0.066828 0.175859 0.000757 0.159132 0.112300 0.004032 0.118759 0.340975 St 0.000000 0.000000 0.004109 0.000000 0.137266 0.002242 0.046128 0.088144 0.002337 0.389235 0.330540 Ilm 0.000000 0.000000 0.327544 0.000000 0.584503 0.008210 0.010760 0.000000 0.068982 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -771518. -752114. -929479. -845728. -311622. -465910. -636880. -289943. -409325. -1632700. -884378. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 186 converged, 76 successes so far. Misfit function evaluations this try => 146 Misfit this try = 0.138124 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.076703E-06 Bayes score, PP * exp(-Misfit) = 9.377980E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 11403.6 886.607 0.901483 0.185912 Final coordinates: 9203.69 924.180 0.693069 0.655293 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.138090 Extraneous predicted phases: 3.489785E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.743 0.024922 0.003918 0.000000 0.071952 0.006399 0.000000 0.006482 0.286790 0.599537 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 0.7 0. 1. -0.4 0.1 Chi 8.5E-03 0. 0. 2.2E-03 3.5E-03 0. 7.7E-03 1.4E-04 3.6E-07 Composition Misfit: 2.597610E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.180 0.000000 0.037826 0.000000 0.000000 0.288667 0.033497 0.078300 0.135789 0.425921 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. 0.1 -2. 0.6 -0.1 Chi 0. 7.9E-03 0. 0. 3.8E-03 1.7E-05 7.1E-03 4.8E-04 3.7E-06 Composition Misfit: 1.927571E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.191 0.094048 0.059304 0.000000 0.001300 0.000000 0.000000 0.000000 0.154652 0.690696 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 1.7E-02 0. 0. 0. 0.4 0.2 Chi 6.1E-05 1.0E-03 0. 2.5E-06 0. 0. 0. 2.5E-04 2.1E-05 Composition Misfit: 1.338694E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.000 0.000000 0.000000 0.024047 0.075432 0.179622 0.000813 0.201276 0.131475 0.387336 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. 0.3 0.2 -2. 0.6 1. Chi 0. 0. 3.0E-04 9.5E-04 1.3E-04 4.6E-04 5.0E-03 5.9E-04 2.1E-03 Composition Misfit: 9.563658E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.076 0.000000 0.000000 0.005028 0.000000 0.139656 0.002297 0.062314 0.427384 0.363320 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.3 -5. 1. 1. Chi 0. 0. 1.1E-03 0. 5.3E-04 1.0E-03 2.5E-02 1.0E-03 1.5E-03 Composition Misfit: 3.001936E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.697 0.000000 0.000000 0.252749 0.000000 0.729634 0.007431 0.010186 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.4 -3.0E-02 0. 0. Chi 0. 0. 3.7E-02 0. 1.4E-02 8.9E-04 3.4E-06 0. 0. Composition Misfit: 5.191603E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.538 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.557 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.018 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000018 -.000018 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023085 0.014607 0.006911 0.016310 0.052408 0.000910 0.039920 0.037745 0.002270 0.107421 0.698413 Mica 0.020798 0.003270 0.000000 0.060047 0.005340 0.000000 0.005409 0.164959 0.000506 0.239336 0.500334 Gt 0.000000 0.037709 0.000000 0.000000 0.287778 0.033394 0.078059 0.000000 0.003083 0.135370 0.424608 Fsp 0.094048 0.059304 0.000000 0.001300 0.000000 0.000000 0.000000 0.000000 0.000000 0.154652 0.690696 Bio 0.000000 0.000000 0.021254 0.066670 0.158757 0.000718 0.177897 0.112086 0.004071 0.116203 0.342344 St 0.000000 0.000000 0.004573 0.000000 0.127017 0.002089 0.056675 0.088117 0.002387 0.388705 0.330439 Ilm 0.000000 0.000000 0.224941 0.000000 0.649357 0.006614 0.009065 0.000000 0.110024 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772790. -752093. -929940. -847805. -313602. -468541. -636802. -289980. -406269. -1634066. -884674. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 188 converged, 77 successes so far. Misfit function evaluations this try => 143 Misfit this try = 0.120649 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.500134E-07 Bayes score, PP * exp(-Misfit) = 8.420393E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 13344.8 849.748 0.650214 0.229845 Final coordinates: 8471.81 923.023 0.605463 0.568321 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.120635 Extraneous predicted phases: 1.410696E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.956 0.021867 0.003082 0.000000 0.075455 0.006607 0.000000 0.006014 0.286755 0.600220 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.4 -2.8E-02 Chi 6.1E-03 0. 0. 1.1E-03 3.1E-03 0. 9.4E-03 1.4E-04 8.1E-08 Composition Misfit: 2.291345E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.670 0.000000 0.030718 0.000000 0.000000 0.287063 0.047871 0.071399 0.136690 0.426259 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -1. -2. 0.5 -0.2 Chi 0. 3.4E-03 0. 0. 4.2E-03 3.9E-03 3.9E-03 3.7E-04 6.0E-06 Composition Misfit: 1.571805E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.220 0.094013 0.059044 0.000000 0.001465 0.000000 0.000000 0.000000 0.154522 0.690956 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -3.1E-02 0. 0. 0. 0.4 0.2 Chi 5.9E-05 9.4E-04 0. 7.8E-06 0. 0. 0. 2.6E-04 1.8E-05 Composition Misfit: 1.288095E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.880 0.000000 0.000000 0.024626 0.075736 0.190936 0.001194 0.186644 0.136037 0.384827 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.4 0.1 -1. 0.3 2. Chi 0. 0. 4.3E-04 1.0E-03 2.2E-04 4.5E-05 1.6E-03 1.3E-04 2.5E-03 Composition Misfit: 5.937361E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.777 0.000000 0.000000 0.004716 0.000000 0.144966 0.003400 0.055895 0.427659 0.363364 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.1 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.3E-03 5.7E-05 1.9E-02 1.0E-03 1.4E-03 Composition Misfit: 2.475803E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.521 0.000000 0.000000 0.253311 0.000000 0.727126 0.010560 0.009003 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -4. -0.1 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.3E-02 3.0E-05 1.1E-04 0. 0. Composition Misfit: 5.002038E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.332 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.633 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.012 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000020 -.000020 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023208 0.014684 0.006948 0.016397 0.052687 0.000914 0.040133 0.032910 0.001994 0.107993 0.702131 Mica 0.018247 0.002572 0.000000 0.062966 0.005513 0.000000 0.005019 0.164998 0.000520 0.239292 0.500873 Gt 0.000000 0.030635 0.000000 0.000000 0.286291 0.047743 0.071207 0.000000 0.002691 0.136322 0.425112 Fsp 0.094013 0.059044 0.000000 0.001465 0.000000 0.000000 0.000000 0.000000 0.000000 0.154522 0.690956 Bio 0.000000 0.000000 0.021764 0.066935 0.168747 0.001055 0.164955 0.112105 0.004104 0.120229 0.340107 St 0.000000 0.000000 0.004289 0.000000 0.131846 0.003092 0.050836 0.088127 0.002380 0.388952 0.330477 Ilm 0.000000 0.000000 0.225497 0.000000 0.647287 0.009401 0.008014 0.000000 0.109801 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775691. -754382. -931571. -850170. -314090. -466331. -638098. -291269. -408239. -1635468. -886224. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 192 converged, 78 successes so far. Misfit function evaluations this try => 176 Misfit this try = 6.266340E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.291342E-07 Bayes score, PP * exp(-Misfit) = 8.726982E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 7363.05 932.695 0.338340 0.830729 Final coordinates: 8459.10 925.011 0.409478 0.511630 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.266340E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.021 0.021061 0.002887 0.000000 0.076343 0.006834 0.000000 0.005929 0.286452 0.600495 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.4E-03 0. 0. 8.6E-04 2.7E-03 0. 9.8E-03 1.2E-04 4.1E-07 Composition Misfit: 2.183373E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.968 0.000000 0.029484 0.000000 0.000000 0.295853 0.042408 0.068930 0.136964 0.426361 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.9 -1. 0.5 -0.2 Chi 0. 2.7E-03 0. 0. 2.3E-03 1.6E-03 2.9E-03 3.4E-04 6.8E-06 Composition Misfit: 9.825655E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.595 0.094382 0.058158 0.000000 0.001540 0.000000 0.000000 0.000000 0.154079 0.691842 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 7.9E-05 7.4E-04 0. 2.1E-05 0. 0. 0. 3.0E-04 1.0E-05 Composition Misfit: 1.152892E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.504 0.000000 0.000000 0.025124 0.075812 0.198155 0.001070 0.178143 0.137177 0.384519 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.2 2. Chi 0. 0. 5.6E-04 1.0E-03 9.4E-04 1.2E-04 4.2E-04 7.2E-05 2.6E-03 Composition Misfit: 5.718566E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.896 0.000000 0.000000 0.004770 0.000000 0.148368 0.003002 0.052610 0.427836 0.363413 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 2.3E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.282369E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.294 0.000000 0.000000 0.360586 0.000000 0.615860 0.010722 0.012831 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.6 0. 0.6 -0.1 -0.5 0. 0. Chi 0. 0. 3.1E-04 0. 3.2E-04 4.9E-05 6.2E-04 0. 0. Composition Misfit: 1.308864E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.255 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.467 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023299 0.014742 0.006975 0.016462 0.052895 0.000918 0.040291 0.029744 0.001354 0.108419 0.704900 Mica 0.017575 0.002409 0.000000 0.063709 0.005703 0.000000 0.004947 0.164977 0.000514 0.239047 0.501119 Gt 0.000000 0.029408 0.000000 0.000000 0.295092 0.042299 0.068753 0.000000 0.002572 0.136612 0.425265 Fsp 0.094382 0.058158 0.000000 0.001540 0.000000 0.000000 0.000000 0.000000 0.000000 0.154079 0.691842 Bio 0.000000 0.000000 0.022214 0.067031 0.175205 0.000946 0.157510 0.111848 0.003973 0.121289 0.339984 St 0.000000 0.000000 0.004338 0.000000 0.134948 0.002731 0.047851 0.088144 0.002310 0.389136 0.330541 Ilm 0.000000 0.000000 0.337089 0.000000 0.575728 0.010023 0.011995 0.000000 0.065165 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776136. -754853. -931826. -850287. -314088. -467516. -638584. -291620. -410408. -1635815. -886469. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 193 converged, 79 successes so far. Misfit function evaluations this try => 237 Misfit this try = 0.117940 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.827570E-07 Bayes score, PP * exp(-Misfit) = 8.734249E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 5848.42 810.114 0.949155 0.749164 Final coordinates: 8775.51 926.363 0.597964 0.528118 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.117893 Extraneous predicted phases: 4.701593E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.437 0.022163 0.003185 0.000000 0.075063 0.006851 0.000000 0.006222 0.286242 0.600273 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.3 -3.5E-02 Chi 6.3E-03 0. 0. 1.2E-03 2.7E-03 0. 8.6E-03 1.2E-04 1.2E-07 Composition Misfit: 2.209252E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.179 0.000000 0.032132 0.000000 0.000000 0.295287 0.037368 0.072641 0.136415 0.426156 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.3 -2. 0.5 -0.2 Chi 0. 4.2E-03 0. 0. 2.4E-03 2.6E-04 4.4E-03 4.0E-04 5.3E-06 Composition Misfit: 1.163213E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.271 0.094445 0.058175 0.000000 0.001468 0.000000 0.000000 0.000000 0.154087 0.691825 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -3.2E-02 0. 0. 0. 0.5 0.1 Chi 8.3E-05 7.4E-04 0. 8.3E-06 0. 0. 0. 3.0E-04 1.0E-05 Composition Misfit: 1.146311E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.368 0.000000 0.000000 0.024627 0.075667 0.192133 0.000935 0.186199 0.135004 0.385436 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.5 0.1 -1. 0.4 2. Chi 0. 0. 4.3E-04 1.0E-03 3.1E-04 2.6E-04 1.5E-03 2.1E-04 2.4E-03 Composition Misfit: 6.116764E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.647 0.000000 0.000000 0.004770 0.000000 0.145753 0.002619 0.055934 0.427577 0.363347 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 1.5E-03 5.7E-04 1.9E-02 1.0E-03 1.5E-03 Composition Misfit: 2.538586E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.521 0.000000 0.000000 0.252827 0.000000 0.729904 0.008176 0.009093 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.3 0.1 0. 0. Chi 0. 0. 3.7E-02 0. 1.4E-02 4.1E-04 9.0E-05 0. 0. Composition Misfit: 5.151914E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.211 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.344 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.021 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000021 -.000021 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023263 0.014719 0.006964 0.016436 0.052812 0.000917 0.040227 0.030654 0.001974 0.108248 0.703787 Mica 0.018496 0.002658 0.000000 0.062643 0.005717 0.000000 0.005192 0.164936 0.000528 0.238879 0.500950 Gt 0.000000 0.032042 0.000000 0.000000 0.294458 0.037263 0.072437 0.000000 0.002810 0.136032 0.424958 Fsp 0.094445 0.058175 0.000000 0.001468 0.000000 0.000000 0.000000 0.000000 0.000000 0.154087 0.691825 Bio 0.000000 0.000000 0.021768 0.066884 0.169831 0.000827 0.164585 0.111999 0.004079 0.119333 0.340695 St 0.000000 0.000000 0.004338 0.000000 0.132560 0.002382 0.050871 0.088122 0.002392 0.388875 0.330459 Ilm 0.000000 0.000000 0.225018 0.000000 0.649619 0.007277 0.008093 0.000000 0.109993 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775072. -754002. -931448. -849492. -314024. -468365. -638027. -291124. -408355. -1635346. -885891. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 195 converged, 80 successes so far. Misfit function evaluations this try => 261 Misfit this try = 6.736671E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.082927E-07 Bayes score, PP * exp(-Misfit) = 8.491195E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 9874.08 825.926 0.942664 0.124196 Final coordinates: 8155.85 881.878 0.441532 0.485687 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.736671E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.007 0.022612 0.002511 0.000000 0.075126 0.005832 0.000000 0.005290 0.288174 0.600455 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.8 0. 1. -0.5 -0.1 Chi 6.6E-03 0. 0. 1.2E-03 4.9E-03 0. 1.3E-02 2.1E-04 3.4E-07 Composition Misfit: 2.825848E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.272 0.000000 0.035689 0.000000 0.000000 0.300727 0.039284 0.061085 0.136884 0.426331 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -0.6 -0.6 0.5 -0.2 Chi 0. 6.4E-03 0. 0. 1.5E-03 6.5E-04 6.5E-04 3.5E-04 6.6E-06 Composition Misfit: 9.570436E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.492 0.095003 0.057614 0.000000 0.001190 0.000000 0.000000 0.000000 0.153807 0.692386 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 4.9E-02 0. 0. 0. 0.5 0.1 Chi 1.2E-04 6.3E-04 0. 2.4E-05 0. 0. 0. 3.3E-04 6.5E-06 Composition Misfit: 1.103815E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.702 0.000000 0.000000 0.023269 0.075495 0.200225 0.000808 0.180958 0.132427 0.386819 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.2 -1. -1. 0.2 -0.8 0.6 2. Chi 0. 0. 1.6E-04 9.7E-04 1.2E-03 4.7E-04 7.2E-04 4.7E-04 2.2E-03 Composition Misfit: 6.219898E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.878 0.000000 0.000000 0.004243 0.000000 0.153566 0.002422 0.048088 0.428215 0.363465 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -2. 0.3 -3. 1. 1. Chi 0. 0. 2.2E-03 0. 3.3E-03 8.3E-04 1.3E-02 9.7E-04 1.4E-03 Composition Misfit: 2.194569E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.389 0.000000 0.000000 0.353636 0.000000 0.627141 0.008705 0.010518 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.2 0. 0.1 0.2 -0.1 0. 0. Chi 0. 0. 3.7E-05 0. 1.3E-05 1.9E-04 2.5E-05 0. 0. Composition Misfit: 2.683960E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.132 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.127 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023332 0.014763 0.006985 0.016485 0.052970 0.000919 0.040347 0.028275 0.001462 0.108571 0.705890 Mica 0.018867 0.002095 0.000000 0.062682 0.004866 0.000000 0.004414 0.165194 0.000442 0.240442 0.500998 Gt 0.000000 0.035596 0.000000 0.000000 0.299943 0.039182 0.060926 0.000000 0.002607 0.136527 0.425220 Fsp 0.095003 0.057614 0.000000 0.001190 0.000000 0.000000 0.000000 0.000000 0.000000 0.153807 0.692386 Bio 0.000000 0.000000 0.020549 0.066672 0.176826 0.000713 0.159810 0.112795 0.004071 0.116950 0.341613 St 0.000000 0.000000 0.003860 0.000000 0.139671 0.002203 0.043737 0.088154 0.002326 0.389471 0.330579 Ilm 0.000000 0.000000 0.329521 0.000000 0.584375 0.008112 0.009800 0.000000 0.068192 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -767305. -749663. -927175. -841569. -309125. -462817. -635270. -288410. -408779. -1629672. -882544. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 196 converged, 81 successes so far. Misfit function evaluations this try => 174 Misfit this try = 0.117310 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.485780E-07 Bayes score, PP * exp(-Misfit) = 8.435796E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 6559.10 912.624 0.533315 0.561315 Final coordinates: 8524.03 924.503 0.588688 0.534941 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.117309 Extraneous predicted phases: 3.105260E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.194 0.021672 0.003042 0.000000 0.075655 0.006742 0.000000 0.006040 0.286541 0.600308 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.4 -3.9E-02 Chi 5.9E-03 0. 0. 1.0E-03 2.9E-03 0. 9.3E-03 1.3E-04 1.6E-07 Composition Misfit: 2.231702E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.842 0.000000 0.030576 0.000000 0.000000 0.290843 0.044586 0.071086 0.136661 0.426248 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -1. -2. 0.5 -0.2 Chi 0. 3.3E-03 0. 0. 3.3E-03 2.4E-03 3.7E-03 3.8E-04 5.9E-06 Composition Misfit: 1.312301E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.370 0.094207 0.058608 0.000000 0.001489 0.000000 0.000000 0.000000 0.154304 0.691392 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -3.8E-02 0. 0. 0. 0.5 0.1 Chi 6.9E-05 8.4E-04 0. 1.2E-05 0. 0. 0. 2.8E-04 1.4E-05 Composition Misfit: 1.215647E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.530 0.000000 0.000000 0.024710 0.075743 0.193052 0.001119 0.184437 0.136149 0.384791 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.6 0.1 -1. 0.3 2. Chi 0. 0. 4.5E-04 1.0E-03 3.8E-04 8.3E-05 1.2E-03 1.3E-04 2.5E-03 Composition Misfit: 5.795612E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.438 0.000000 0.000000 0.004703 0.000000 0.146031 0.003161 0.055091 0.427653 0.363361 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.1 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.5E-03 1.5E-04 1.9E-02 1.0E-03 1.4E-03 Composition Misfit: 2.440137E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.494 0.000000 0.000000 0.253126 0.000000 0.728190 0.009788 0.008896 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 3.4E-02 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.3E-02 4.6E-06 1.4E-04 0. 0. Composition Misfit: 5.045678E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.614 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.516 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000021 -.000021 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023254 0.014714 0.006962 0.016430 0.052792 0.000916 0.040213 0.031039 0.001942 0.108208 0.703530 Mica 0.018085 0.002539 0.000000 0.063134 0.005627 0.000000 0.005040 0.164976 0.000525 0.239118 0.500956 Gt 0.000000 0.030494 0.000000 0.000000 0.290057 0.044465 0.070893 0.000000 0.002703 0.136292 0.425096 Fsp 0.094207 0.058608 0.000000 0.001489 0.000000 0.000000 0.000000 0.000000 0.000000 0.154304 0.691392 Bio 0.000000 0.000000 0.021840 0.066946 0.170630 0.000989 0.163015 0.112052 0.004094 0.120336 0.340099 St 0.000000 0.000000 0.004277 0.000000 0.132814 0.002875 0.050105 0.088126 0.002385 0.388946 0.330473 Ilm 0.000000 0.000000 0.225313 0.000000 0.648181 0.008713 0.007919 0.000000 0.109875 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775772. -754494. -931721. -850151. -314122. -467012. -638239. -291368. -408558. -1635592. -886265. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 198 converged, 82 successes so far. Misfit function evaluations this try => 269 Misfit this try = 6.113235E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.394662E-07 Bayes score, PP * exp(-Misfit) = 8.837547E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 7197.59 815.529 0.169026 0.766387 Final coordinates: 8618.15 927.500 0.422934 0.499404 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.112773E-2 Extraneous predicted phases: 4.619877E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.012 0.021221 0.002958 0.000000 0.076120 0.006991 0.000000 0.006061 0.286149 0.600499 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.1E-04 2.5E-03 0. 9.2E-03 1.1E-04 4.2E-07 Composition Misfit: 2.127058E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.200 0.000000 0.030178 0.000000 0.000000 0.299021 0.037778 0.070005 0.136740 0.426278 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.4 -1. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 1.8E-03 3.3E-04 3.3E-03 3.7E-04 6.2E-06 Composition Misfit: 8.835396E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.575 0.094541 0.057832 0.000000 0.001543 0.000000 0.000000 0.000000 0.153916 0.692168 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.8E-05 6.7E-04 0. 2.2E-05 0. 0. 0. 3.2E-04 7.9E-06 Composition Misfit: 1.107641E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.532 0.000000 0.000000 0.025053 0.075774 0.198001 0.000959 0.178864 0.136603 0.384746 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.4E-04 1.0E-03 9.2E-04 2.3E-04 4.9E-04 1.0E-04 2.5E-03 Composition Misfit: 5.840134E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.105 0.000000 0.000000 0.004760 0.000000 0.148374 0.002666 0.053093 0.427723 0.363384 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 5.2E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.352888E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.314 0.000000 0.000000 0.348972 0.000000 0.629038 0.009462 0.012528 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. 4.4E-02 0.1 -0.4 0. 0. Chi 0. 0. 3.0E-06 0. 1.5E-06 3.1E-05 5.1E-04 0. 0. Composition Misfit: 5.450976E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.912 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.344 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.007 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000023 -.000023 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023315 0.014752 0.006980 0.016473 0.052931 0.000919 0.040318 0.029053 0.001399 0.108491 0.705370 Mica 0.017710 0.002469 0.000000 0.063525 0.005834 0.000000 0.005058 0.164939 0.000525 0.238802 0.501138 Gt 0.000000 0.030097 0.000000 0.000000 0.298223 0.037677 0.069818 0.000000 0.002669 0.136375 0.425140 Fsp 0.094541 0.057832 0.000000 0.001543 0.000000 0.000000 0.000000 0.000000 0.000000 0.153916 0.692168 Bio 0.000000 0.000000 0.022151 0.066995 0.175063 0.000848 0.158143 0.111840 0.004008 0.120778 0.340174 St 0.000000 0.000000 0.004329 0.000000 0.134949 0.002425 0.048289 0.088134 0.002349 0.389022 0.330504 Ilm 0.000000 0.000000 0.324470 0.000000 0.584872 0.008798 0.011648 0.000000 0.070212 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775996. -754746. -931917. -850144. -314179. -468571. -638577. -291594. -409926. -1635870. -886376. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 200 converged, 83 successes so far. Misfit function evaluations this try => 264 Misfit this try = 0.136210 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.062102E-06 Bayes score, PP * exp(-Misfit) = 9.268531E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 12232.3 899.675 0.518970 0.756877 Final coordinates: 9030.59 923.036 0.688954 0.678741 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.135334 Extraneous predicted phases: 8.757379E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.544 0.024352 0.003778 0.000000 0.072603 0.006377 0.000000 0.006395 0.286866 0.599628 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 0.7 0. 1. -0.4 4.8E-02 Chi 8.0E-03 0. 0. 1.9E-03 3.6E-03 0. 8.0E-03 1.4E-04 2.3E-07 Composition Misfit: 2.547544E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.887 0.000000 0.036621 0.000000 0.000000 0.285988 0.038302 0.077127 0.135972 0.425989 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.4 -2. 0.6 -0.2 Chi 0. 7.1E-03 0. 0. 4.5E-03 4.3E-04 6.5E-03 4.5E-04 4.2E-06 Composition Misfit: 1.892321E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.288 0.093819 0.059733 0.000000 0.001315 0.000000 0.000000 0.000000 0.154866 0.690267 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 1.2E-02 0. 0. 0. 0.4 0.2 Chi 5.0E-05 1.1E-03 0. 1.4E-06 0. 0. 0. 2.3E-04 2.6E-05 Composition Misfit: 1.420840E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.076 0.000000 0.000000 0.024092 0.075484 0.180475 0.000931 0.199876 0.132263 0.386878 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. 0.3 0.1 -2. 0.6 2. Chi 0. 0. 3.1E-04 9.6E-04 8.9E-05 2.6E-04 4.6E-03 4.9E-04 2.2E-03 Composition Misfit: 8.909770E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.763 0.000000 0.000000 0.004969 0.000000 0.140023 0.002648 0.061591 0.427440 0.363329 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.7 0.3 -5. 1. 1. Chi 0. 0. 1.1E-03 0. 5.8E-04 5.4E-04 2.4E-02 1.0E-03 1.5E-03 Composition Misfit: 2.900158E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.680 0.000000 0.000000 0.252298 0.000000 0.729233 0.008501 0.009968 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 5.0E-03 0. 0. Chi 0. 0. 3.8E-02 0. 1.4E-02 2.6E-04 1.0E-07 0. 0. Composition Misfit: 5.160332E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.021 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.651 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.091 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000018 -.000018 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023054 0.014587 0.006902 0.016289 0.052338 0.000908 0.039867 0.039044 0.002254 0.107278 0.697480 Mica 0.020322 0.003153 0.000000 0.060589 0.005322 0.000000 0.005336 0.164975 0.000507 0.239395 0.500401 Gt 0.000000 0.036511 0.000000 0.000000 0.285130 0.038187 0.076896 0.000000 0.003003 0.135563 0.424710 Fsp 0.093819 0.059733 0.000000 0.001315 0.000000 0.000000 0.000000 0.000000 0.000000 0.154866 0.690267 Bio 0.000000 0.000000 0.021292 0.066712 0.159501 0.000823 0.176647 0.112131 0.004087 0.116892 0.341915 St 0.000000 0.000000 0.004519 0.000000 0.127351 0.002408 0.056017 0.088119 0.002384 0.388755 0.330447 Ilm 0.000000 0.000000 0.224494 0.000000 0.648870 0.007564 0.008870 0.000000 0.110202 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -773318. -752429. -930175. -848267. -313678. -467532. -636965. -290162. -406410. -1634259. -884945. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 201 converged, 84 successes so far. Misfit function evaluations this try => 174 Misfit this try = 0.105222 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.096675E-07 Bayes score, PP * exp(-Misfit) = 9.871439E-08 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 11508.2 814.127 0.361648 5.771764E-02 Final coordinates: 7066.72 806.098 0.445765 0.484445 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.105222 Extraneous predicted phases: 3.177001E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.018 0.024631 0.001749 0.000000 0.073792 0.003944 0.000000 0.003820 0.291743 0.600321 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 1. 0. 1. -0.7 -4.1E-02 Chi 8.3E-03 0. 0. 1.5E-03 1.3E-02 0. 2.5E-02 4.3E-04 1.7E-07 Composition Misfit: 4.994522E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.080 0.000000 0.044728 0.000000 0.000000 0.296895 0.048842 0.045622 0.137391 0.426522 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 1. -2. 0.9 0.5 -0.2 Chi 0. 1.3E-02 0. 0. 2.1E-03 4.4E-03 1.8E-03 3.0E-04 8.1E-06 Composition Misfit: 2.169711E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.415 0.095389 0.057703 0.000000 0.000760 0.000000 0.000000 0.000000 0.153851 0.692297 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.5E-04 6.5E-04 0. 4.7E-04 0. 0. 0. 3.2E-04 7.0E-06 Composition Misfit: 1.593514E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.881 0.000000 0.000000 0.020420 0.075079 0.205075 0.000680 0.182615 0.126192 0.389939 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 0.1 -1. -1. 0.2 -0.9 1. 1. Chi 0. 0. 4.4E-05 8.8E-04 2.1E-03 8.2E-04 9.4E-04 1.6E-03 1.7E-03 Composition Misfit: 8.064066E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.028 0.000000 0.000000 0.003382 0.000000 0.162657 0.002356 0.038689 0.429258 0.363657 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. 0.3 -2. 1. 1. Chi 0. 0. 4.6E-03 0. 6.1E-03 9.3E-04 6.4E-03 8.7E-04 1.4E-03 Composition Misfit: 2.039017E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.478 0.000000 0.000000 0.376867 0.000000 0.606325 0.008908 0.007900 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 1. 0.2 0.3 0. 0. Chi 0. 0. 1.9E-03 0. 9.2E-04 1.3E-04 5.6E-04 0. 0. Composition Misfit: 3.531960E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.170 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.931 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.000 0.000000 0.000000 0.174660 0.000000 0.686778 0.005439 0.002987 0.000000 0.130136 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023333 0.014764 0.006986 0.016486 0.052973 0.000919 0.040350 0.028205 0.001476 0.108577 0.705931 Mica 0.020543 0.001459 0.000000 0.061547 0.003290 0.000000 0.003186 0.165639 0.000308 0.243329 0.500700 Gt 0.000000 0.044622 0.000000 0.000000 0.296187 0.048725 0.045513 0.000000 0.002386 0.137064 0.425504 Fsp 0.095389 0.057703 0.000000 0.000760 0.000000 0.000000 0.000000 0.000000 0.000000 0.153851 0.692297 Bio 0.000000 0.000000 0.018000 0.066181 0.180770 0.000599 0.160972 0.114363 0.004154 0.111236 0.343725 St 0.000000 0.000000 0.003076 0.000000 0.147949 0.002143 0.035191 0.088206 0.002218 0.390443 0.330774 Ilm 0.000000 0.000000 0.355010 0.000000 0.571161 0.008392 0.007442 0.000000 0.057996 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -754655. -742455. -920287. -829047. -301434. -452875. -630497. -284038. -408072. -1620708. -877286. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 205 converged, 85 successes so far. Misfit function evaluations this try => 235 Misfit this try = 0.292141 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.073490E-06 Bayes score, PP * exp(-Misfit) = 8.015354E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 6985.09 949.346 0.931726 0.935506 Final coordinates: 9127.41 923.424 0.696265 0.904715 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.137823 Extraneous predicted phases: 0.154318 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.782 0.024742 0.003883 0.000000 0.072156 0.006365 0.000000 0.006445 0.286865 0.599543 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 0.7 0. 1. -0.4 0.1 Chi 8.4E-03 0. 0. 2.1E-03 3.6E-03 0. 7.8E-03 1.4E-04 3.5E-07 Composition Misfit: 2.591562E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.995 0.000000 0.037480 0.000000 0.000000 0.286816 0.035992 0.077916 0.135852 0.425945 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.2 -2. 0.6 -0.2 Chi 0. 7.6E-03 0. 0. 4.3E-03 8.5E-05 6.9E-03 4.7E-04 3.9E-06 Composition Misfit: 1.936370E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.890 0.093886 0.059627 0.000000 0.001300 0.000000 0.000000 0.000000 0.154814 0.690373 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 1.7E-02 0. 0. 0. 0.4 0.2 Chi 5.3E-05 1.1E-03 0. 2.5E-06 0. 0. 0. 2.4E-04 2.5E-05 Composition Misfit: 1.401391E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.686 0.000000 0.000000 0.024035 0.075449 0.179484 0.000873 0.201249 0.131741 0.387168 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. 0.3 0.2 -2. 0.6 1. Chi 0. 0. 3.0E-04 9.6E-04 1.4E-04 3.5E-04 5.0E-03 5.6E-04 2.1E-03 Composition Misfit: 9.442509E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.608 0.000000 0.000000 0.005001 0.000000 0.139548 0.002477 0.062246 0.427405 0.363323 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.6 0.3 -5. 1. 1. Chi 0. 0. 1.1E-03 0. 5.2E-04 7.5E-04 2.5E-02 1.0E-03 1.5E-03 Composition Misfit: 2.968917E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.689 0.000000 0.000000 0.252240 0.000000 0.729672 0.007988 0.010100 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.3 -1.6E-02 0. 0. Chi 0. 0. 3.8E-02 0. 1.4E-02 5.1E-04 9.8E-07 0. 0. Composition Misfit: 5.201090E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.002 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.151 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 1.197 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000018 -.000018 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022758 0.014400 0.006813 0.016079 0.051666 0.000897 0.039354 0.051374 0.002248 0.105898 0.688514 Mica 0.020648 0.003241 0.000000 0.060216 0.005312 0.000000 0.005378 0.164969 0.000506 0.239396 0.500333 Gt 0.000000 0.037365 0.000000 0.000000 0.285940 0.035882 0.077678 0.000000 0.003055 0.135437 0.424643 Fsp 0.093886 0.059627 0.000000 0.001300 0.000000 0.000000 0.000000 0.000000 0.000000 0.154814 0.690373 Bio 0.000000 0.000000 0.021242 0.066682 0.158628 0.000771 0.177863 0.112122 0.004081 0.116433 0.342178 St 0.000000 0.000000 0.004549 0.000000 0.126919 0.002252 0.056612 0.088118 0.002387 0.388723 0.330441 Ilm 0.000000 0.000000 0.224437 0.000000 0.649244 0.007108 0.008986 0.000000 0.110225 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772976. -752183. -930004. -847982. -313624. -467967. -636833. -290026. -406225. -1634111. -884766. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 210 converged, 86 successes so far. Misfit function evaluations this try => 203 Misfit this try = 0.194120 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.106761E-06 Bayes score, PP * exp(-Misfit) = 9.114835E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 12364.8 886.839 0.942924 6.866265E-02 Final coordinates: 9476.18 924.308 0.862518 0.658042 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.194119 Extraneous predicted phases: 2.953352E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.108 0.026657 0.004360 0.000000 0.069994 0.006305 0.000000 0.006644 0.286977 0.599064 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -3. 0. 0. 1. 0.7 0. 1. -0.4 0.1 Chi 1.0E-02 0. 0. 3.0E-03 3.7E-03 0. 7.2E-03 1.5E-04 1.5E-06 Composition Misfit: 2.836496E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.539 0.000000 0.041022 0.000000 0.000000 0.286866 0.029056 0.082480 0.134964 0.425612 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 2. 0.6 -3. 0.6 -0.1 Chi 0. 1.0E-02 0. 0. 4.3E-03 9.3E-04 9.3E-03 5.8E-04 2.1E-06 Composition Misfit: 2.530679E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.712 0.094228 0.059069 0.000000 0.001237 0.000000 0.000000 0.000000 0.154534 0.690931 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 3.5E-02 0. 0. 0. 0.4 0.2 Chi 7.1E-05 9.5E-04 0. 1.2E-05 0. 0. 0. 2.6E-04 1.8E-05 Composition Misfit: 1.308183E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.118 0.000000 0.000000 0.022917 0.075281 0.173194 0.000696 0.210559 0.129211 0.388142 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.2 -1. 0.7 0.2 -3. 0.8 1. Chi 0. 0. 1.0E-04 9.2E-04 7.3E-04 7.6E-04 8.0E-03 9.5E-04 2.0E-03 Composition Misfit: 1.347044E-2 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.175 0.000000 0.000000 0.004650 0.000000 0.136519 0.001965 0.066393 0.427225 0.363248 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.4 0.4 -5. 1. 1. Chi 0. 0. 1.5E-03 0. 2.2E-04 1.8E-03 2.8E-02 1.1E-03 1.5E-03 Composition Misfit: 3.453708E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.913 0.000000 0.000000 0.227680 0.000000 0.758075 0.005543 0.008702 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -6. 0.7 0.2 0. 0. Chi 0. 0. 0.1 0. 2.2E-02 3.6E-03 1.9E-04 0. 0. Composition Misfit: 9.113186E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.003 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.430 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000015 -.000015 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023068 0.014596 0.006906 0.016299 0.052371 0.000909 0.039892 0.037877 0.002823 0.107344 0.697915 Mica 0.022246 0.003638 0.000000 0.058411 0.005261 0.000000 0.005545 0.164953 0.000523 0.239489 0.499933 Gt 0.000000 0.040881 0.000000 0.000000 0.285879 0.028956 0.082196 0.000000 0.003441 0.134500 0.424147 Fsp 0.094228 0.059069 0.000000 0.001237 0.000000 0.000000 0.000000 0.000000 0.000000 0.154534 0.690931 Bio 0.000000 0.000000 0.020237 0.066476 0.152937 0.000615 0.185932 0.112715 0.004244 0.114098 0.342746 St 0.000000 0.000000 0.004229 0.000000 0.124147 0.001787 0.060377 0.088088 0.002534 0.388509 0.330330 Ilm 0.000000 0.000000 0.200394 0.000000 0.667226 0.004879 0.007659 0.000000 0.119842 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -771606. -751248. -930135. -846935. -313477. -469408. -636163. -289466. -403465. -1633495. -884065. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 211 converged, 87 successes so far. Misfit function evaluations this try => 251 Misfit this try = 6.119865E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.427785E-07 Bayes score, PP * exp(-Misfit) = 8.868118E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 7724.60 835.929 0.821883 0.210212 Final coordinates: 8645.89 927.731 0.417434 0.498925 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.117470E-2 Extraneous predicted phases: 2.395253E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.005 0.021264 0.002972 0.000000 0.076069 0.006999 0.000000 0.006078 0.286118 0.600502 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.3E-04 2.5E-03 0. 9.2E-03 1.1E-04 4.2E-07 Composition Misfit: 2.124540E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.250 0.000000 0.030297 0.000000 0.000000 0.299657 0.036902 0.070115 0.136747 0.426280 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.3 -1. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 1.7E-03 1.9E-04 3.3E-03 3.7E-04 6.2E-06 Composition Misfit: 8.703385E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.569 0.094578 0.057761 0.000000 0.001542 0.000000 0.000000 0.000000 0.153881 0.692239 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 9.1E-05 6.6E-04 0. 2.2E-05 0. 0. 0. 3.2E-04 7.4E-06 Composition Misfit: 1.098047E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.540 0.000000 0.000000 0.025083 0.075767 0.198002 0.000937 0.178860 0.136512 0.384838 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.5E-04 1.0E-03 9.2E-04 2.5E-04 4.9E-04 1.1E-04 2.5E-03 Composition Misfit: 5.863953E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.990 0.000000 0.000000 0.004787 0.000000 0.148374 0.002601 0.053113 0.427736 0.363389 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 5.9E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.357878E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.310 0.000000 0.000000 0.352658 0.000000 0.625378 0.009266 0.012697 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.1 0. 0.2 0.1 -0.4 0. 0. Chi 0. 0. 2.0E-05 0. 3.4E-05 5.8E-05 5.7E-04 0. 0. Composition Misfit: 6.851383E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.004 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.317 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.015 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000023 -.000023 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023316 0.014753 0.006980 0.016474 0.052933 0.000919 0.040320 0.029026 0.001381 0.108496 0.705403 Mica 0.017745 0.002480 0.000000 0.063482 0.005841 0.000000 0.005073 0.164935 0.000524 0.238777 0.501144 Gt 0.000000 0.030217 0.000000 0.000000 0.298859 0.036804 0.069928 0.000000 0.002666 0.136383 0.425144 Fsp 0.094578 0.057761 0.000000 0.001542 0.000000 0.000000 0.000000 0.000000 0.000000 0.153881 0.692239 Bio 0.000000 0.000000 0.022179 0.066994 0.175074 0.000829 0.158149 0.111809 0.003989 0.120704 0.340275 St 0.000000 0.000000 0.004354 0.000000 0.134950 0.002366 0.048307 0.088137 0.002337 0.389037 0.330512 Ilm 0.000000 0.000000 0.328461 0.000000 0.582468 0.008630 0.011826 0.000000 0.068616 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775925. -754697. -931866. -850072. -314166. -468756. -638562. -291571. -410064. -1635847. -886337. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 213 converged, 88 successes so far. Misfit function evaluations this try => 253 Misfit this try = 6.112737E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.389947E-07 Bayes score, PP * exp(-Misfit) = 8.833155E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 10763.6 852.884 0.458640 0.112950 Final coordinates: 8614.68 927.475 0.423015 0.501518 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.109862E-2 Extraneous predicted phases: 2.875211E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.009 0.021215 0.002956 0.000000 0.076128 0.006988 0.000000 0.006058 0.286155 0.600500 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.1E-04 2.5E-03 0. 9.3E-03 1.1E-04 4.2E-07 Composition Misfit: 2.127997E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.195 0.000000 0.030152 0.000000 0.000000 0.298974 0.037869 0.069975 0.136748 0.426281 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.4 -1. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 1.8E-03 3.5E-04 3.3E-03 3.7E-04 6.2E-06 Composition Misfit: 8.833308E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.574 0.094537 0.057839 0.000000 0.001544 0.000000 0.000000 0.000000 0.153919 0.692161 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.8E-05 6.7E-04 0. 2.2E-05 0. 0. 0. 3.2E-04 7.9E-06 Composition Misfit: 1.108660E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.532 0.000000 0.000000 0.025055 0.075775 0.198008 0.000962 0.178844 0.136618 0.384738 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.4E-04 1.0E-03 9.3E-04 2.2E-04 4.9E-04 1.0E-04 2.5E-03 Composition Misfit: 5.836619E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.116 0.000000 0.000000 0.004762 0.000000 0.148380 0.002673 0.053073 0.427727 0.363385 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 5.1E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.350304E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.314 0.000000 0.000000 0.348819 0.000000 0.629155 0.009509 0.012518 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. 3.9E-02 0.1 -0.4 0. 0. Chi 0. 0. 4.0E-06 0. 1.1E-06 2.5E-05 5.1E-04 0. 0. Composition Misfit: 5.370238E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.903 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.342 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.017 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000023 -.000023 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023312 0.014750 0.006979 0.016471 0.052924 0.000918 0.040313 0.029172 0.001399 0.108478 0.705284 Mica 0.017705 0.002467 0.000000 0.063532 0.005831 0.000000 0.005055 0.164940 0.000525 0.238806 0.501139 Gt 0.000000 0.030072 0.000000 0.000000 0.298177 0.037768 0.069789 0.000000 0.002665 0.136384 0.425144 Fsp 0.094537 0.057839 0.000000 0.001544 0.000000 0.000000 0.000000 0.000000 0.000000 0.153919 0.692161 Bio 0.000000 0.000000 0.022152 0.066996 0.175069 0.000851 0.158125 0.111840 0.004008 0.120792 0.340167 St 0.000000 0.000000 0.004331 0.000000 0.134955 0.002431 0.048271 0.088135 0.002347 0.389026 0.330505 Ilm 0.000000 0.000000 0.324304 0.000000 0.584939 0.008840 0.011638 0.000000 0.070278 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776008. -754750. -931921. -850153. -314180. -468554. -638581. -291598. -409931. -1635873. -886381. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Ilm Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Ilm Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 215 converged, 89 successes so far. Misfit function evaluations this try => 171 Misfit this try = 0.226369 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.141470E-06 Bayes score, PP * exp(-Misfit) = 9.102351E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 9636.89 868.163 0.948241 0.873460 Final coordinates: 9023.93 912.851 0.980795 0.682469 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.226369 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.181 0.026187 0.004075 0.000000 0.070671 0.005973 0.000000 0.006313 0.287674 0.599106 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 0.8 0. 1. -0.4 0.1 Chi 9.6E-03 0. 0. 2.7E-03 4.5E-03 0. 8.3E-03 1.8E-04 1.3E-06 Composition Misfit: 2.929594E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.787 0.000000 0.040479 0.000000 0.000000 0.277810 0.041582 0.079326 0.135129 0.425673 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 2. -0.8 -2. 0.6 -0.1 Chi 0. 9.8E-03 0. 0. 7.0E-03 1.3E-03 7.6E-03 5.6E-04 2.4E-06 Composition Misfit: 2.626046E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.845 0.093563 0.060510 0.000000 0.001182 0.000000 0.000000 0.000000 0.155255 0.689490 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.9 0. 0.1 0. 0. 0. 0.4 0.2 Chi 3.9E-05 1.3E-03 0. 2.6E-05 0. 0. 0. 2.0E-04 3.6E-05 Composition Misfit: 1.619853E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.979 0.000000 0.000000 0.022056 0.075299 0.172140 0.000954 0.212415 0.129489 0.387647 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.1 -1. 0.8 0.1 -3. 0.8 1. Chi 0. 0. 2.2E-05 9.3E-04 8.8E-04 2.3E-04 8.7E-03 9.0E-04 2.1E-03 Composition Misfit: 1.369908E-2 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.440 0.000000 0.000000 0.004193 0.000000 0.136695 0.002801 0.065665 0.427394 0.363252 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.4 0.2 -5. 1. 1. Chi 0. 0. 2.4E-03 0. 2.3E-04 3.8E-04 2.8E-02 1.0E-03 1.5E-03 Composition Misfit: 3.329323E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.027 0.000000 0.000000 0.210481 0.000000 0.775401 0.006986 0.007132 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 8. 0. -7. 0.5 0.5 0. 0. Chi 0. 0. 0.1 0. 2.7E-02 1.3E-03 1.2E-03 0. 0. Composition Misfit: 0.122200 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.038 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.702 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023027 0.014570 0.006894 0.016270 0.052277 0.000907 0.039820 0.039212 0.003205 0.107152 0.696665 Mica 0.021852 0.003400 0.000000 0.058970 0.004984 0.000000 0.005268 0.165044 0.000517 0.240047 0.499918 Gt 0.000000 0.040343 0.000000 0.000000 0.276874 0.041442 0.079059 0.000000 0.003370 0.134674 0.424239 Fsp 0.093563 0.060510 0.000000 0.001182 0.000000 0.000000 0.000000 0.000000 0.000000 0.155255 0.689490 Bio 0.000000 0.000000 0.019458 0.066429 0.151863 0.000841 0.187394 0.113401 0.004393 0.114236 0.341984 St 0.000000 0.000000 0.003813 0.000000 0.124299 0.002547 0.059710 0.088083 0.002597 0.388638 0.330312 Ilm 0.000000 0.000000 0.183864 0.000000 0.677348 0.006103 0.006230 0.000000 0.126454 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -771020. -750845. -930095. -846369. -312735. -465602. -635702. -289131. -402365. -1632647. -883859. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 218 converged, 90 successes so far. Misfit function evaluations this try => 531 Misfit this try = 0.152042 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 7.600406E-07 Bayes score, PP * exp(-Misfit) = 6.528386E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 8174.74 860.226 0.936571 8.880096E-02 Final coordinates: 7843.64 873.171 0.667698 0.496690 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.152042 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.510 0.023088 0.002469 0.000000 0.074739 0.005370 0.000000 0.005028 0.289033 0.600274 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.9 0. 1. -0.5 -3.5E-02 Chi 7.0E-03 0. 0. 1.3E-03 6.2E-03 0. 1.4E-02 2.5E-04 1.2E-07 Composition Misfit: 3.166800E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.829 0.000000 0.035226 0.000000 0.000000 0.289345 0.051747 0.060125 0.137132 0.426425 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -2. -0.5 0.5 -0.2 Chi 0. 6.1E-03 0. 0. 3.7E-03 5.9E-03 4.7E-04 3.3E-04 7.3E-06 Composition Misfit: 1.650910E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.450 0.094637 0.058476 0.000000 0.001125 0.000000 0.000000 0.000000 0.154238 0.691524 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 9.4E-05 8.1E-04 0. 4.8E-05 0. 0. 0. 2.9E-04 1.3E-05 Composition Misfit: 1.252405E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.280 0.000000 0.000000 0.022993 0.075494 0.196062 0.001027 0.185293 0.132405 0.386727 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.2 -1. -0.8 0.1 -1. 0.6 2. Chi 0. 0. 1.1E-04 9.7E-04 6.9E-04 1.5E-04 1.3E-03 4.7E-04 2.2E-03 Composition Misfit: 5.944694E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.138 0.000000 0.000000 0.004215 0.000000 0.152006 0.003185 0.048808 0.428302 0.363485 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -2. 0.1 -3. 1. 1. Chi 0. 0. 2.3E-03 0. 2.9E-03 1.3E-04 1.4E-02 9.6E-04 1.4E-03 Composition Misfit: 2.144385E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.616 0.000000 0.000000 0.236246 0.000000 0.747696 0.009573 0.006485 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. 0.1 0.6 0. 0. Chi 0. 0. 0.1 0. 1.9E-02 1.9E-05 1.9E-03 0. 0. Composition Misfit: 7.522386E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.902 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.275 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023300 0.014742 0.006976 0.016462 0.052896 0.000918 0.040291 0.028876 0.002207 0.108420 0.704911 Mica 0.019262 0.002059 0.000000 0.062354 0.004480 0.000000 0.004195 0.165291 0.000422 0.241136 0.500800 Gt 0.000000 0.035138 0.000000 0.000000 0.288622 0.051617 0.059975 0.000000 0.002498 0.136790 0.425359 Fsp 0.094637 0.058476 0.000000 0.001125 0.000000 0.000000 0.000000 0.000000 0.000000 0.154238 0.691524 Bio 0.000000 0.000000 0.020300 0.066652 0.173099 0.000907 0.163591 0.113004 0.004116 0.116897 0.341433 St 0.000000 0.000000 0.003834 0.000000 0.138254 0.002897 0.044393 0.088160 0.002306 0.389555 0.330602 Ilm 0.000000 0.000000 0.208721 0.000000 0.660581 0.008457 0.005730 0.000000 0.116512 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -766721. -749312. -926515. -841269. -308648. -460022. -634787. -288055. -408131. -1629007. -882344. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 222 converged, 91 successes so far. Misfit function evaluations this try => 142 Misfit this try = 6.144532E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.749449E-07 Bayes score, PP * exp(-Misfit) = 9.168424E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 7559.24 901.734 0.713273 0.432223 Final coordinates: 8542.34 922.018 0.422406 0.499113 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.144532E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.012 0.021332 0.002895 0.000000 0.076064 0.006838 0.000000 0.005958 0.286415 0.600498 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.3E-04 2.7E-03 0. 9.7E-03 1.2E-04 4.1E-07 Composition Misfit: 2.198043E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.167 0.000000 0.030618 0.000000 0.000000 0.298731 0.038719 0.068838 0.136796 0.426299 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.5 -1. 0.5 -0.2 Chi 0. 3.3E-03 0. 0. 1.8E-03 5.2E-04 2.9E-03 3.6E-04 6.3E-06 Composition Misfit: 8.861598E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.571 0.094563 0.057874 0.000000 0.001500 0.000000 0.000000 0.000000 0.153937 0.692126 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.1E-02 0. 0. 0. 0.5 0.1 Chi 9.0E-05 6.8E-04 0. 1.4E-05 0. 0. 0. 3.1E-04 8.1E-06 Composition Misfit: 1.107119E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.549 0.000000 0.000000 0.024871 0.075750 0.198254 0.000961 0.178981 0.136249 0.384933 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 4.9E-04 1.0E-03 9.6E-04 2.2E-04 5.0E-04 1.2E-04 2.5E-03 Composition Misfit: 5.818718E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.110 0.000000 0.000000 0.004705 0.000000 0.148944 0.002695 0.052464 0.427795 0.363397 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 2.2E-03 4.9E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.318306E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.318 0.000000 0.000000 0.351627 0.000000 0.626418 0.009598 0.012357 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.1 0. 0.2 0.1 -0.4 0. 0. Chi 0. 0. 7.5E-06 0. 2.0E-05 1.7E-05 4.5E-04 0. 0. Composition Misfit: 4.944021E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.930 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.344 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023315 0.014752 0.006980 0.016473 0.052932 0.000919 0.040318 0.029036 0.001397 0.108493 0.705384 Mica 0.017802 0.002416 0.000000 0.063477 0.005706 0.000000 0.004972 0.164973 0.000514 0.239017 0.501124 Gt 0.000000 0.030537 0.000000 0.000000 0.297941 0.038616 0.068656 0.000000 0.002645 0.136435 0.425171 Fsp 0.094563 0.057874 0.000000 0.001500 0.000000 0.000000 0.000000 0.000000 0.000000 0.153937 0.692126 Bio 0.000000 0.000000 0.021987 0.066966 0.175266 0.000850 0.158228 0.111946 0.004008 0.120451 0.340299 St 0.000000 0.000000 0.004279 0.000000 0.135468 0.002451 0.047717 0.088138 0.002340 0.389089 0.330518 Ilm 0.000000 0.000000 0.327342 0.000000 0.583156 0.008935 0.011504 0.000000 0.069063 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775039. -754186. -931362. -849199. -313593. -467737. -638203. -291233. -409864. -1635154. -885953. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Mica Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Mica Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 229 converged, 92 successes so far. Misfit function evaluations this try => 195 Misfit this try = 0.190920 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 4.101521E-07 Bayes score, PP * exp(-Misfit) = 3.388670E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 11121.8 813.314 0.824505 0.278299 Final coordinates: 7192.34 849.893 0.729780 0.484330 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.190920 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.041 0.022881 0.002077 0.000000 0.075254 0.004738 0.000000 0.004449 0.290295 0.600306 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 1. 0. 1. -0.6 -3.9E-02 Chi 6.9E-03 0. 0. 1.1E-03 8.7E-03 0. 1.9E-02 3.3E-04 1.6E-07 Composition Misfit: 3.767980E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.599 0.000000 0.034137 0.000000 0.000000 0.280835 0.066206 0.054538 0.137661 0.426623 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -4. 2.5E-02 0.4 -0.2 Chi 0. 5.4E-03 0. 0. 6.0E-03 1.5E-02 1.2E-06 2.8E-04 9.1E-06 Composition Misfit: 2.713452E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.569 0.094603 0.058754 0.000000 0.001020 0.000000 0.000000 0.000000 0.154377 0.691246 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 9.2E-05 8.7E-04 0. 1.1E-04 0. 0. 0. 2.8E-04 1.5E-05 Composition Misfit: 1.366834E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.702 0.000000 0.000000 0.022185 0.075490 0.197653 0.001190 0.184568 0.132356 0.386557 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.1 -1. -0.9 0.1 -1. 0.6 2. Chi 0. 0. 3.0E-05 9.7E-04 8.8E-04 4.6E-05 1.2E-03 4.8E-04 2.2E-03 Composition Misfit: 5.862836E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.476 0.000000 0.000000 0.003846 0.000000 0.154379 0.003906 0.045642 0.428677 0.363549 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -2. -1.4E-02 -3. 1. 1. Chi 0. 0. 3.2E-03 0. 3.5E-03 1.2E-06 1.1E-02 9.2E-04 1.4E-03 Composition Misfit: 2.033937E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.684 0.000000 0.000000 0.223460 0.000000 0.760353 0.010992 0.005195 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -6. -0.2 0.8 0. 0. Chi 0. 0. 0.1 0. 2.2E-02 8.9E-05 4.4E-03 0. 0. Composition Misfit: 9.853697E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.632 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.297 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023312 0.014750 0.006979 0.016471 0.052923 0.000918 0.040312 0.028172 0.002414 0.108476 0.705273 Mica 0.019086 0.001733 0.000000 0.062774 0.003952 0.000000 0.003712 0.165454 0.000385 0.242153 0.500753 Gt 0.000000 0.034060 0.000000 0.000000 0.280198 0.066056 0.054414 0.000000 0.002268 0.137349 0.425655 Fsp 0.094603 0.058754 0.000000 0.001020 0.000000 0.000000 0.000000 0.000000 0.000000 0.154377 0.691246 Bio 0.000000 0.000000 0.019571 0.066596 0.174366 0.001050 0.162822 0.113621 0.004199 0.116762 0.341013 St 0.000000 0.000000 0.003498 0.000000 0.140414 0.003553 0.041514 0.088177 0.002282 0.389900 0.330663 Ilm 0.000000 0.000000 0.196315 0.000000 0.667990 0.009657 0.004564 0.000000 0.121474 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -764210. -748096. -925098. -838830. -306698. -456005. -633712. -287179. -407923. -1626881. -881419. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 235 converged, 93 successes so far. Misfit function evaluations this try => 286 Misfit this try = 1.09533 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.961523E-07 Bayes score, PP * exp(-Misfit) = 3.331428E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 11743.1 828.212 0.877587 0.213053 Final coordinates: 8692.86 923.316 0.635625 0.614449 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.784690E-2 Extraneous predicted phases: 1.01748 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.215 0.022675 0.003311 0.000000 0.074519 0.006561 0.000000 0.006183 0.286699 0.600051 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.4 -6.6E-03 Chi 6.7E-03 0. 0. 1.3E-03 3.2E-03 0. 8.8E-03 1.3E-04 4.4E-09 Composition Misfit: 2.344580E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.756 0.000000 0.032783 0.000000 0.000000 0.287372 0.043724 0.073528 0.136431 0.426162 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -1. -2. 0.5 -0.2 Chi 0. 4.6E-03 0. 0. 4.2E-03 2.1E-03 4.8E-03 4.0E-04 5.3E-06 Composition Misfit: 1.595312E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.901 0.093960 0.059259 0.000000 0.001410 0.000000 0.000000 0.000000 0.154630 0.690741 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -1.5E-02 0. 0. 0. 0.4 0.2 Chi 5.7E-05 9.9E-04 0. 2.0E-06 0. 0. 0. 2.5E-04 2.0E-05 Composition Misfit: 1.324367E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.862 0.000000 0.000000 0.024435 0.075641 0.187307 0.001081 0.191324 0.134609 0.385604 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.2 0.1 -1. 0.4 2. Chi 0. 0. 3.9E-04 1.0E-03 4.3E-05 1.1E-04 2.5E-03 2.4E-04 2.4E-03 Composition Misfit: 6.651516E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.809 0.000000 0.000000 0.004806 0.000000 0.143323 0.003072 0.057872 0.427576 0.363350 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.9 0.2 -4. 1. 1. Chi 0. 0. 1.3E-03 0. 1.1E-03 1.9E-04 2.1E-02 1.0E-03 1.5E-03 Composition Misfit: 2.615009E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.002 0.000000 0.000000 0.320360 0.000000 0.656432 0.010856 0.012352 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 2. 0. -1. -0.1 -0.4 0. 0. Chi 0. 0. 2.7E-03 0. 1.1E-03 6.7E-05 4.5E-04 0. 0. Composition Misfit: 4.322018E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.189 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.607 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.577 0.000000 0.000000 0.225060 0.000000 0.648061 0.008592 0.008311 0.000000 0.109976 0.000000 0.000000 F 0.082 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000020 -.000020 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023144 0.014644 0.006929 0.016352 0.052542 0.000912 0.040022 0.035483 0.002087 0.107695 0.700192 Mica 0.018922 0.002763 0.000000 0.062187 0.005475 0.000000 0.005160 0.164980 0.000517 0.239251 0.500744 Gt 0.000000 0.032691 0.000000 0.000000 0.286567 0.043601 0.073322 0.000000 0.002803 0.136049 0.424967 Fsp 0.093960 0.059259 0.000000 0.001410 0.000000 0.000000 0.000000 0.000000 0.000000 0.154630 0.690741 Bio 0.000000 0.000000 0.021596 0.066851 0.165541 0.000956 0.169091 0.112106 0.004097 0.118967 0.340796 St 0.000000 0.000000 0.004371 0.000000 0.130351 0.002794 0.052634 0.088124 0.002383 0.388878 0.330465 Ilm 0.000000 0.000000 0.293957 0.000000 0.602331 0.009961 0.011334 0.000000 0.082417 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774814. -753662. -931073. -849446. -313940. -466863. -637692. -290869. -407616. -1635036. -885749. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 236 converged, 94 successes so far. Misfit function evaluations this try => 186 Misfit this try = 6.233980E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.461641E-07 Bayes score, PP * exp(-Misfit) = 8.889813E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 7597.24 857.757 0.156227 0.508957 Final coordinates: 8657.69 927.637 0.409086 0.512962 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.200121E-2 Extraneous predicted phases: 3.385809E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.150 0.021346 0.002986 0.000000 0.075981 0.006961 0.000000 0.006081 0.286151 0.600495 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.7E-03 0. 0. 9.5E-04 2.5E-03 0. 9.2E-03 1.1E-04 4.1E-07 Composition Misfit: 2.139058E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.245 0.000000 0.030390 0.000000 0.000000 0.299527 0.036776 0.070213 0.136795 0.426298 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.3 -1. 0.5 -0.2 Chi 0. 3.2E-03 0. 0. 1.7E-03 1.7E-04 3.4E-03 3.6E-04 6.3E-06 Composition Misfit: 8.789764E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.526 0.094563 0.057802 0.000000 0.001536 0.000000 0.000000 0.000000 0.153901 0.692198 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 9.0E-05 6.7E-04 0. 2.1E-05 0. 0. 0. 3.2E-04 7.7E-06 Composition Misfit: 1.102484E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.408 0.000000 0.000000 0.025125 0.075763 0.197658 0.000933 0.179129 0.136449 0.384942 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.7 0.3 2. Chi 0. 0. 5.6E-04 1.0E-03 8.8E-04 2.6E-04 5.2E-04 1.1E-04 2.5E-03 Composition Misfit: 5.848645E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.248 0.000000 0.000000 0.004832 0.000000 0.148181 0.002591 0.053223 0.427771 0.363402 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.3E-03 0. 2.0E-03 6.0E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.357451E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.305 0.000000 0.000000 0.360082 0.000000 0.617579 0.009296 0.013043 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.6 0. 0.6 0.1 -0.5 0. 0. Chi 0. 0. 2.8E-04 0. 2.5E-04 5.3E-05 7.1E-04 0. 0. Composition Misfit: 1.295229E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.748 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.312 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.057 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000024 -.000024 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023298 0.014741 0.006975 0.016461 0.052891 0.000918 0.040288 0.029819 0.001352 0.108411 0.704847 Mica 0.017814 0.002492 0.000000 0.063410 0.005809 0.000000 0.005075 0.164939 0.000518 0.238805 0.501139 Gt 0.000000 0.030310 0.000000 0.000000 0.298735 0.036679 0.070027 0.000000 0.002645 0.136434 0.425171 Fsp 0.094563 0.057802 0.000000 0.001536 0.000000 0.000000 0.000000 0.000000 0.000000 0.153901 0.692198 Bio 0.000000 0.000000 0.022217 0.066995 0.174783 0.000825 0.158399 0.111773 0.003958 0.120658 0.340392 St 0.000000 0.000000 0.004395 0.000000 0.134777 0.002356 0.048409 0.088141 0.002315 0.389076 0.330530 Ilm 0.000000 0.000000 0.336538 0.000000 0.577199 0.008689 0.012190 0.000000 0.065385 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775853. -754640. -931763. -850019. -314145. -468758. -638529. -291534. -410329. -1635806. -886300. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 237 converged, 95 successes so far. Misfit function evaluations this try => 291 Misfit this try = 0.135745 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.007949E-07 Bayes score, PP * exp(-Misfit) = 7.864523E-07 Best Bayes score so far = 9.973139E-07 obtained on Try 151 P_bar T_K C_O2 C_H2O Initial coordinates: 5893.90 930.002 0.911440 6.553026E-02 Final coordinates: 7926.56 903.246 0.607904 0.508324 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.135745 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.124 0.021369 0.002602 0.000000 0.076289 0.006145 0.000000 0.005439 0.287767 0.600389 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.8 0. 1. -0.4 -5.0E-02 Chi 5.7E-03 0. 0. 8.8E-04 4.1E-03 0. 1.2E-02 1.8E-04 2.5E-07 Composition Misfit: 2.550330E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.604 0.000000 0.029661 0.000000 0.000000 0.285333 0.056536 0.064905 0.137137 0.426427 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -2. -1. 0.5 -0.2 Chi 0. 2.8E-03 0. 0. 4.7E-03 8.8E-03 1.6E-03 3.3E-04 7.3E-06 Composition Misfit: 1.818822E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.598 0.094261 0.058703 0.000000 0.001388 0.000000 0.000000 0.000000 0.154351 0.691297 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -8.8E-03 0. 0. 0. 0.5 0.1 Chi 7.2E-05 8.6E-04 0. 6.6E-07 0. 0. 0. 2.8E-04 1.5E-05 Composition Misfit: 1.225844E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.460 0.000000 0.000000 0.024088 0.075766 0.196304 0.001309 0.181573 0.136495 0.384464 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. -0.8 3.3E-02 -0.8 0.3 2. Chi 0. 0. 3.1E-04 1.0E-03 7.1E-04 1.0E-05 8.0E-04 1.1E-04 2.6E-03 Composition Misfit: 5.542909E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.365 0.000000 0.000000 0.004358 0.000000 0.148980 0.003874 0.051387 0.427985 0.363416 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. -7.4E-03 -4. 1. 1. Chi 0. 0. 2.0E-03 0. 2.2E-03 3.2E-07 1.6E-02 9.9E-04 1.4E-03 Composition Misfit: 2.238119E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.504 0.000000 0.000000 0.243804 0.000000 0.737268 0.011456 0.007472 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. -0.2 0.4 0. 0. Chi 0. 0. 4.6E-02 0. 1.6E-02 1.8E-04 8.6E-04 0. 0. Composition Misfit: 6.290397E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.813 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.530 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023289 0.014735 0.006972 0.016454 0.052871 0.000918 0.040272 0.029538 0.002009 0.108369 0.704574 Mica 0.017830 0.002171 0.000000 0.063654 0.005127 0.000000 0.004538 0.165137 0.000489 0.240105 0.500949 Gt 0.000000 0.029587 0.000000 0.000000 0.284621 0.056395 0.064743 0.000000 0.002496 0.136795 0.425362 Fsp 0.094261 0.058703 0.000000 0.001388 0.000000 0.000000 0.000000 0.000000 0.000000 0.154351 0.691297 Bio 0.000000 0.000000 0.021277 0.066923 0.173391 0.001156 0.160380 0.112569 0.004154 0.120563 0.339589 St 0.000000 0.000000 0.003963 0.000000 0.135496 0.003523 0.046736 0.088140 0.002369 0.389249 0.330524 Ilm 0.000000 0.000000 0.216119 0.000000 0.653550 0.010155 0.006624 0.000000 0.113552 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -773395. -753353. -930320. -847767. -312224. -463057. -637283. -290512. -408554. -1633506. -885339. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 238 converged, 96 successes so far. Misfit function evaluations this try => 250 Misfit this try = 6.578959E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.085857E-06 Bayes score, PP * exp(-Misfit) = 1.016718E-06 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 12407.6 976.868 0.936892 0.162128 Final coordinates: 8640.43 907.523 0.438382 0.467320 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.578959E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.006 0.022349 0.002836 0.000000 0.075109 0.006557 0.000000 0.005852 0.286812 0.600484 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.4 -0.1 Chi 6.4E-03 0. 0. 1.2E-03 3.2E-03 0. 1.0E-02 1.4E-04 3.9E-07 Composition Misfit: 2.391314E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.716 0.000000 0.033995 0.000000 0.000000 0.304893 0.031274 0.067064 0.136563 0.426211 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. 0.3 -1. 0.5 -0.2 Chi 0. 5.3E-03 0. 0. 9.5E-04 2.8E-04 2.2E-03 3.9E-04 5.7E-06 Composition Misfit: 9.190162E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.477 0.095151 0.056990 0.000000 0.001354 0.000000 0.000000 0.000000 0.153495 0.693010 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.5 0. 1.2E-03 0. 0. 0. 0.5 0.1 Chi 1.3E-04 5.1E-04 0. 1.3E-08 0. 0. 0. 3.6E-04 3.2E-06 Composition Misfit: 9.996082E-4 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.669 0.000000 0.000000 0.024118 0.075572 0.198611 0.000719 0.181111 0.133573 0.386297 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. -0.9 0.2 -0.8 0.5 2. Chi 0. 0. 3.1E-04 9.8E-04 1.0E-03 6.9E-04 7.4E-04 3.4E-04 2.3E-03 Composition Misfit: 6.354467E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.052 0.000000 0.000000 0.004548 0.000000 0.150812 0.002050 0.051325 0.427864 0.363402 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.4 -4. 1. 1. Chi 0. 0. 1.7E-03 0. 2.6E-03 1.6E-03 1.6E-02 1.0E-03 1.4E-03 Composition Misfit: 2.401308E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.373 0.000000 0.000000 0.345132 0.000000 0.636083 0.007298 0.011486 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.3 0. -0.3 0.4 -0.2 0. 0. Chi 0. 0. 6.9E-05 0. 5.8E-05 1.0E-03 1.9E-04 0. 0. Composition Misfit: 1.319135E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.700 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.007 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023357 0.014779 0.006993 0.016503 0.053027 0.000920 0.040391 0.027236 0.001453 0.108688 0.706653 Mica 0.018650 0.002367 0.000000 0.062678 0.005472 0.000000 0.004884 0.165022 0.000490 0.239341 0.501096 Gt 0.000000 0.033902 0.000000 0.000000 0.304056 0.031188 0.066879 0.000000 0.002746 0.136188 0.425041 Fsp 0.095151 0.056990 0.000000 0.001354 0.000000 0.000000 0.000000 0.000000 0.000000 0.153495 0.693010 Bio 0.000000 0.000000 0.021313 0.066783 0.175515 0.000636 0.160050 0.112254 0.004035 0.118040 0.341375 St 0.000000 0.000000 0.004136 0.000000 0.137164 0.001864 0.046681 0.088137 0.002359 0.389144 0.330515 Ilm 0.000000 0.000000 0.320328 0.000000 0.590369 0.006774 0.010660 0.000000 0.071869 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -771119. -751886. -929411. -845367. -311638. -467369. -636796. -289828. -409063. -1632635. -884163. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 241 converged, 97 successes so far. Misfit function evaluations this try => 179 Misfit this try = 0.201965 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.120528E-06 Bayes score, PP * exp(-Misfit) = 9.156098E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 8501.44 966.571 0.913918 0.727198 Final coordinates: 9402.81 922.275 0.897609 0.683057 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.201965 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.607 0.026770 0.004401 0.000000 0.069876 0.006196 0.000000 0.006588 0.287206 0.598963 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -3. 0. 0. 1. 0.8 0. 1. -0.4 0.1 Chi 1.0E-02 0. 0. 3.0E-03 4.0E-03 0. 7.3E-03 1.6E-04 1.8E-06 Composition Misfit: 2.898407E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.268 0.000000 0.041453 0.000000 0.000000 0.283579 0.032085 0.082369 0.134919 0.425595 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 2. 0.2 -3. 0.6 -0.1 Chi 0. 1.1E-02 0. 0. 5.2E-03 1.5E-04 9.2E-03 5.9E-04 2.1E-06 Composition Misfit: 2.569402E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.620 0.093920 0.059728 0.000000 0.001217 0.000000 0.000000 0.000000 0.154864 0.690272 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 4.1E-02 0. 0. 0. 0.4 0.2 Chi 5.5E-05 1.1E-03 0. 1.6E-05 0. 0. 0. 2.3E-04 2.6E-05 Composition Misfit: 1.439378E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.722 0.000000 0.000000 0.022697 0.075275 0.171753 0.000760 0.212292 0.129123 0.388101 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.2 -1. 0.8 0.2 -3. 0.8 1. Chi 0. 0. 7.8E-05 9.2E-04 9.4E-04 5.8E-04 8.6E-03 9.7E-04 2.0E-03 Composition Misfit: 1.410858E-2 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.246 0.000000 0.000000 0.004566 0.000000 0.135807 0.002170 0.066975 0.427238 0.363244 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.4 0.4 -5. 1. 1. Chi 0. 0. 1.7E-03 0. 1.7E-04 1.3E-03 2.9E-02 1.1E-03 1.5E-03 Composition Misfit: 3.462267E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.950 0.000000 0.000000 0.223704 0.000000 0.761880 0.005985 0.008431 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -6. 0.6 0.2 0. 0. Chi 0. 0. 0.1 0. 2.3E-02 2.7E-03 2.9E-04 0. 0. Composition Misfit: 9.711632E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.017 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.569 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023033 0.014573 0.006896 0.016273 0.052290 0.000907 0.039830 0.039256 0.002933 0.107178 0.696831 Mica 0.022339 0.003673 0.000000 0.058312 0.005171 0.000000 0.005498 0.164976 0.000521 0.239674 0.499836 Gt 0.000000 0.041310 0.000000 0.000000 0.282598 0.031974 0.082084 0.000000 0.003461 0.134452 0.424122 Fsp 0.093920 0.059728 0.000000 0.001217 0.000000 0.000000 0.000000 0.000000 0.000000 0.154864 0.690272 Bio 0.000000 0.000000 0.020038 0.066456 0.151631 0.000671 0.187420 0.112874 0.004282 0.113995 0.342633 St 0.000000 0.000000 0.004152 0.000000 0.123498 0.001973 0.060905 0.088086 0.002551 0.388515 0.330321 Ilm 0.000000 0.000000 0.196550 0.000000 0.669403 0.005259 0.007407 0.000000 0.121380 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -771509. -751090. -930110. -846882. -313390. -468443. -636025. -289364. -402968. -1633329. -884012. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Sp Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Sp Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 244 converged, 98 successes so far. Misfit function evaluations this try => 196 Misfit this try = 0.103679 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.024726E-06 Bayes score, PP * exp(-Misfit) = 9.238054E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 8426.55 951.260 0.541700 0.748335 Final coordinates: 8927.76 925.016 0.408129 0.742200 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.936878E-2 Extraneous predicted phases: 2.431040E-2 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.275 0.023133 0.003476 0.000000 0.073963 0.006505 0.000000 0.006306 0.286579 0.600037 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 0.7 0. 1. -0.4 -4.8E-03 Chi 7.1E-03 0. 0. 1.5E-03 3.3E-03 0. 8.3E-03 1.3E-04 2.3E-09 Composition Misfit: 2.378593E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.018 0.000000 0.034135 0.000000 0.000000 0.292676 0.035972 0.074239 0.136711 0.426267 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.2 -2. 0.5 -0.2 Chi 0. 5.4E-03 0. 0. 2.9E-03 8.3E-05 5.1E-03 3.7E-04 6.1E-06 Composition Misfit: 1.388273E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.491 0.094031 0.059155 0.000000 0.001391 0.000000 0.000000 0.000000 0.154578 0.690845 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -9.7E-03 0. 0. 0. 0.4 0.2 Chi 6.0E-05 9.7E-04 0. 8.0E-07 0. 0. 0. 2.6E-04 1.9E-05 Composition Misfit: 1.304875E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.926 0.000000 0.000000 0.024865 0.075596 0.187211 0.000890 0.190905 0.133935 0.386597 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.2 0.2 -1. 0.5 2. Chi 0. 0. 4.9E-04 9.9E-04 4.0E-05 3.2E-04 2.4E-03 3.0E-04 2.2E-03 Composition Misfit: 6.770937E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.961 0.000000 0.000000 0.005179 0.000000 0.143156 0.002494 0.057904 0.427822 0.363445 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.9 0.3 -4. 1. 1. Chi 0. 0. 9.0E-04 0. 1.0E-03 7.3E-04 2.1E-02 1.0E-03 1.4E-03 Composition Misfit: 2.621432E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.382 0.000000 0.000000 0.383779 0.000000 0.591434 0.009403 0.015384 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 2. 0.1 -0.9 0. 0. Chi 0. 0. 3.0E-03 0. 2.5E-03 3.8E-05 1.9E-03 0. 0. Composition Misfit: 7.409982E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.004 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.463 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.480 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000023 -.000023 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022991 0.014547 0.006883 0.016244 0.052196 0.000906 0.039758 0.042578 0.001331 0.106985 0.695580 Mica 0.019306 0.002901 0.000000 0.061726 0.005429 0.000000 0.005263 0.164965 0.000480 0.239166 0.500764 Gt 0.000000 0.034043 0.000000 0.000000 0.291891 0.035876 0.074040 0.000000 0.002682 0.136344 0.425124 Fsp 0.094031 0.059155 0.000000 0.001391 0.000000 0.000000 0.000000 0.000000 0.000000 0.154578 0.690845 Bio 0.000000 0.000000 0.021992 0.066861 0.165579 0.000787 0.168847 0.111729 0.003820 0.118459 0.341926 St 0.000000 0.000000 0.004711 0.000000 0.130219 0.002268 0.052671 0.088160 0.002210 0.389160 0.330600 Ilm 0.000000 0.000000 0.362702 0.000000 0.558953 0.008886 0.014539 0.000000 0.054919 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774182. -753148. -930384. -848798. -313783. -468355. -637555. -290638. -410119. -1634799. -885396. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 245 converged, 99 successes so far. Misfit function evaluations this try => 167 Misfit this try = 0.150386 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 8.072071E-07 Bayes score, PP * exp(-Misfit) = 6.945015E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 7862.02 906.762 0.869382 5.653848E-02 Final coordinates: 7953.28 875.443 0.672638 0.505971 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.150386 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.876 0.023361 0.002557 0.000000 0.074410 0.005410 0.000000 0.005108 0.288929 0.600225 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.9 0. 1. -0.5 -2.9E-02 Chi 7.2E-03 0. 0. 1.4E-03 6.1E-03 0. 1.4E-02 2.5E-04 8.4E-08 Composition Misfit: 3.143842E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.869 0.000000 0.035868 0.000000 0.000000 0.290040 0.049567 0.061126 0.137018 0.426382 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -2. -0.6 0.5 -0.2 Chi 0. 6.5E-03 0. 0. 3.5E-03 4.7E-03 6.6E-04 3.4E-04 7.0E-06 Composition Misfit: 1.578427E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.363 0.094624 0.058504 0.000000 0.001124 0.000000 0.000000 0.000000 0.154252 0.691496 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.1 0. 0. 0. 0.5 0.1 Chi 9.4E-05 8.2E-04 0. 4.9E-05 0. 0. 0. 2.9E-04 1.3E-05 Composition Misfit: 1.257441E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.980 0.000000 0.000000 0.023006 0.075470 0.194865 0.000992 0.186685 0.132048 0.386934 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.2 -1. -0.7 0.1 -1. 0.6 2. Chi 0. 0. 1.2E-04 9.6E-04 5.5E-04 1.9E-04 1.6E-03 5.2E-04 2.2E-03 Composition Misfit: 6.094156E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.462 0.000000 0.000000 0.004265 0.000000 0.151359 0.003057 0.049595 0.428248 0.363475 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -3. 1. 1. Chi 0. 0. 2.2E-03 0. 2.7E-03 2.0E-04 1.4E-02 9.6E-04 1.4E-03 Composition Misfit: 2.186758E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.628 0.000000 0.000000 0.237007 0.000000 0.747070 0.009259 0.006664 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. 0.1 0.5 0. 0. Chi 0. 0. 0.1 0. 1.8E-02 5.9E-05 1.7E-03 0. 0. Composition Misfit: 7.394417E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.544 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.277 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023287 0.014734 0.006971 0.016453 0.052866 0.000917 0.040269 0.029399 0.002222 0.108360 0.704520 Mica 0.019490 0.002133 0.000000 0.062080 0.004513 0.000000 0.004262 0.165275 0.000425 0.241053 0.500768 Gt 0.000000 0.035776 0.000000 0.000000 0.289301 0.049441 0.060970 0.000000 0.002548 0.136669 0.425295 Fsp 0.094624 0.058504 0.000000 0.001124 0.000000 0.000000 0.000000 0.000000 0.000000 0.154252 0.691496 Bio 0.000000 0.000000 0.020313 0.066635 0.172053 0.000876 0.164831 0.112957 0.004109 0.116590 0.341638 St 0.000000 0.000000 0.003879 0.000000 0.137666 0.002781 0.045108 0.088158 0.002310 0.389505 0.330592 Ilm 0.000000 0.000000 0.209463 0.000000 0.660250 0.008183 0.005890 0.000000 0.116215 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -766772. -749271. -926554. -841364. -308807. -460514. -634793. -288046. -407973. -1629118. -882331. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 248 converged, 100 successes so far. Misfit function evaluations this try => 338 Misfit this try = 6.261359E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.012966E-06 Bayes score, PP * exp(-Misfit) = 9.514852E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 12201.8 929.438 0.834590 0.727886 Final coordinates: 8710.22 921.863 0.424505 0.480495 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.261359E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.004 0.021701 0.002953 0.000000 0.075649 0.006900 0.000000 0.006057 0.286235 0.600504 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.9E-03 0. 0. 1.0E-03 2.6E-03 0. 9.3E-03 1.2E-04 4.2E-07 Composition Misfit: 2.190939E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.522 0.000000 0.031751 0.000000 0.000000 0.302681 0.033152 0.069549 0.136631 0.426237 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. 0.1 -1. 0.5 -0.2 Chi 0. 4.0E-03 0. 0. 1.2E-03 3.6E-05 3.1E-03 3.8E-04 5.8E-06 Composition Misfit: 8.727264E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.531 0.094847 0.057353 0.000000 0.001477 0.000000 0.000000 0.000000 0.153677 0.692647 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. -3.4E-02 0. 0. 0. 0.5 0.1 Chi 1.1E-04 5.8E-04 0. 9.6E-06 0. 0. 0. 3.4E-04 5.0E-06 Composition Misfit: 1.039526E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.597 0.000000 0.000000 0.024758 0.075687 0.198099 0.000816 0.179887 0.135304 0.385450 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.9 0.2 -0.7 0.4 2. Chi 0. 0. 4.6E-04 1.0E-03 9.4E-04 4.5E-04 6.0E-04 1.9E-04 2.4E-03 Composition Misfit: 6.060856E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.001 0.000000 0.000000 0.004721 0.000000 0.149166 0.002276 0.052698 0.427752 0.363388 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.2E-03 1.1E-03 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.399317E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.335 0.000000 0.000000 0.349469 0.000000 0.630119 0.008097 0.012316 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 2.9E-02 0. -5.5E-03 0.3 -0.4 0. 0. Chi 0. 0. 8.1E-07 0. 2.2E-08 4.5E-04 4.4E-04 0. 0. Composition Misfit: 8.833933E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.848 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.161 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023340 0.014768 0.006988 0.016491 0.052989 0.000920 0.040362 0.027983 0.001406 0.108610 0.706144 Mica 0.018111 0.002465 0.000000 0.063132 0.005758 0.000000 0.005055 0.164950 0.000514 0.238873 0.501142 Gt 0.000000 0.031665 0.000000 0.000000 0.301858 0.033062 0.069360 0.000000 0.002717 0.136260 0.425079 Fsp 0.094847 0.057353 0.000000 0.001477 0.000000 0.000000 0.000000 0.000000 0.000000 0.153677 0.692647 Bio 0.000000 0.000000 0.021887 0.066912 0.175131 0.000721 0.159031 0.111936 0.004002 0.119617 0.340761 St 0.000000 0.000000 0.004294 0.000000 0.135669 0.002070 0.047929 0.088135 0.002349 0.389047 0.330507 Ilm 0.000000 0.000000 0.325007 0.000000 0.586012 0.007530 0.011454 0.000000 0.069997 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774219. -753693. -931029. -848406. -313336. -468742. -637953. -290959. -409675. -1634765. -885552. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 249 converged, 101 successes so far. Misfit function evaluations this try => 281 Misfit this try = 0.113773 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.525273E-07 Bayes score, PP * exp(-Misfit) = 8.500927E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 6865.94 922.815 0.944981 0.230559 Final coordinates: 8658.93 927.048 0.562717 0.479321 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.113773 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.003 0.021503 0.003005 0.000000 0.075813 0.006974 0.000000 0.006111 0.286154 0.600440 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.8E-03 0. 0. 9.9E-04 2.5E-03 0. 9.0E-03 1.1E-04 3.2E-07 Composition Misfit: 2.143476E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.235 0.000000 0.030632 0.000000 0.000000 0.297755 0.037928 0.070896 0.136574 0.426215 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.4 -2. 0.5 -0.2 Chi 0. 3.3E-03 0. 0. 2.0E-03 3.6E-04 3.7E-03 3.9E-04 5.7E-06 Composition Misfit: 9.686432E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.584 0.094591 0.057773 0.000000 0.001523 0.000000 0.000000 0.000000 0.153887 0.692227 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.8E-02 0. 0. 0. 0.5 0.1 Chi 9.1E-05 6.6E-04 0. 1.8E-05 0. 0. 0. 3.2E-04 7.5E-06 Composition Misfit: 1.096686E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.563 0.000000 0.000000 0.024821 0.075738 0.196202 0.000958 0.181335 0.136064 0.384881 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.8 0.1 -0.8 0.3 2. Chi 0. 0. 4.8E-04 1.0E-03 7.0E-04 2.3E-04 7.7E-04 1.3E-04 2.5E-03 Composition Misfit: 5.839376E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.964 0.000000 0.000000 0.004696 0.000000 0.147637 0.002672 0.054010 0.427630 0.363355 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.9E-03 5.1E-04 1.8E-02 1.0E-03 1.4E-03 Composition Misfit: 2.421533E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.457 0.000000 0.000000 0.252934 0.000000 0.730039 0.008250 0.008778 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.3 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.4E-02 3.7E-04 1.7E-04 0. 0. Composition Misfit: 5.150068E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.925 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.269 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023331 0.014763 0.006985 0.016484 0.052968 0.000919 0.040346 0.027904 0.001863 0.108568 0.705869 Mica 0.017945 0.002508 0.000000 0.063269 0.005820 0.000000 0.005100 0.164936 0.000533 0.238804 0.501086 Gt 0.000000 0.030548 0.000000 0.000000 0.296939 0.037824 0.070702 0.000000 0.002742 0.136199 0.425047 Fsp 0.094591 0.057773 0.000000 0.001523 0.000000 0.000000 0.000000 0.000000 0.000000 0.153887 0.692227 Bio 0.000000 0.000000 0.021941 0.066950 0.173437 0.000847 0.160294 0.111958 0.004074 0.120276 0.340223 St 0.000000 0.000000 0.004271 0.000000 0.134273 0.002430 0.049121 0.088124 0.002394 0.388922 0.330465 Ilm 0.000000 0.000000 0.225123 0.000000 0.649771 0.007343 0.007812 0.000000 0.109951 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775703. -754557. -931873. -849945. -314132. -468449. -638401. -291459. -409020. -1635709. -886233. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Sp Gt Bio sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Sp Gt Bio sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 254 converged, 102 successes so far. Misfit function evaluations this try => 154 Misfit this try = 0.266867 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 7.901212E-08 Bayes score, PP * exp(-Misfit) = 6.050553E-08 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 7677.46 809.505 0.810493 5.380426E-02 Final coordinates: 5936.97 814.588 0.810379 0.499071 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.266867 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.236 0.022694 0.001559 0.000000 0.075887 0.003651 0.000000 0.003515 0.292462 0.600232 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 1. 0. 1. -0.7 -3.0E-02 Chi 6.7E-03 0. 0. 9.7E-04 1.5E-02 0. 2.9E-02 4.9E-04 9.0E-08 Composition Misfit: 5.377853E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.262 0.000000 0.029671 0.000000 0.000000 0.256413 0.101023 0.047061 0.138787 0.427045 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 4. -7. 0.7 0.4 -0.3 Chi 0. 2.8E-03 0. 0. 1.7E-02 4.4E-02 1.3E-03 1.8E-04 1.3E-05 Composition Misfit: 6.514664E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.546 0.094420 0.059416 0.000000 0.000872 0.000000 0.000000 0.000000 0.154708 0.690584 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 0.1 0. 0. 0. 0.4 0.2 Chi 8.1E-05 1.0E-03 0. 2.7E-04 0. 0. 0. 2.5E-04 2.2E-05 Composition Misfit: 1.650876E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.559 0.000000 0.000000 0.021268 0.075571 0.196275 0.001548 0.186113 0.133571 0.385654 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1.3E-02 -1. -0.8 -3.5E-02 -1. 0.5 2. Chi 0. 0. 4.6E-07 9.8E-04 7.1E-04 9.9E-06 1.5E-03 3.4E-04 2.4E-03 Composition Misfit: 5.904381E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.960 0.000000 0.000000 0.003468 0.000000 0.155785 0.005688 0.042064 0.429316 0.363679 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. -0.4 -2. 1. 1. Chi 0. 0. 4.3E-03 0. 3.9E-03 6.0E-04 8.7E-03 8.6E-04 1.4E-03 Composition Misfit: 1.981205E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.779 0.000000 0.000000 0.214242 0.000000 0.766160 0.015482 0.004116 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -6. -0.9 0.9 0. 0. Chi 0. 0. 0.1 0. 2.4E-02 1.9E-03 8.4E-03 0. 0. Composition Misfit: 0.120574 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.186 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.473 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023285 0.014733 0.006971 0.016452 0.052864 0.000917 0.040267 0.028997 0.002677 0.108354 0.704481 Mica 0.018926 0.001300 0.000000 0.063286 0.003045 0.000000 0.002931 0.165724 0.000320 0.243901 0.500567 Gt 0.000000 0.029618 0.000000 0.000000 0.255957 0.100844 0.046977 0.000000 0.001777 0.138541 0.426286 Fsp 0.094420 0.059416 0.000000 0.000872 0.000000 0.000000 0.000000 0.000000 0.000000 0.154708 0.690584 Bio 0.000000 0.000000 0.018742 0.066597 0.172966 0.001364 0.164010 0.114451 0.004307 0.117708 0.339854 St 0.000000 0.000000 0.003154 0.000000 0.141704 0.005174 0.038262 0.088215 0.002177 0.390509 0.330806 Ilm 0.000000 0.000000 0.187458 0.000000 0.670377 0.013546 0.003602 0.000000 0.125017 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -761673. -747182. -923129. -836753. -304303. -450111. -632351. -286258. -407970. -1624380. -880715. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 255 converged, 103 successes so far. Misfit function evaluations this try => 263 Misfit this try = 0.173471 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 5.823238E-07 Bayes score, PP * exp(-Misfit) = 4.895839E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 5694.49 897.156 0.834459 0.186547 Final coordinates: 6875.42 902.501 0.593292 0.544250 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.173471 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.005 0.020029 0.002222 0.000000 0.077933 0.005645 0.000000 0.004795 0.289056 0.600320 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.5 0.8 0. 1. -0.5 -4.1E-02 Chi 4.7E-03 0. 0. 5.5E-04 5.4E-03 0. 1.6E-02 2.5E-04 1.7E-07 Composition Misfit: 2.904286E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 0.000000 0.022367 0.000000 0.000000 0.259777 0.091347 0.061720 0.138029 0.426761 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.2 0. 0. 3. -6. -0.7 0.4 -0.2 Chi 0. 1.5E-04 0. 0. 1.5E-02 3.6E-02 7.8E-04 2.4E-04 1.0E-05 Composition Misfit: 5.173783E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.662 0.093804 0.059353 0.000000 0.001520 0.000000 0.000000 0.000000 0.154676 0.690647 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. -4.7E-02 0. 0. 0. 0.4 0.2 Chi 4.9E-05 1.0E-03 0. 1.7E-05 0. 0. 0. 2.5E-04 2.2E-05 Composition Misfit: 1.352250E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.430 0.000000 0.000000 0.024520 0.076136 0.194851 0.002197 0.178965 0.142033 0.381298 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.7 -0.2 -0.6 -0.1 2. Chi 0. 0. 4.1E-04 1.1E-03 5.5E-04 2.7E-04 5.0E-04 2.1E-05 3.1E-03 Composition Misfit: 6.007161E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.622 0.000000 0.000000 0.004191 0.000000 0.146443 0.006802 0.050917 0.428191 0.363455 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. -0.6 -3. 1. 1. Chi 0. 0. 2.4E-03 0. 1.6E-03 1.3E-03 1.5E-02 9.7E-04 1.4E-03 Composition Misfit: 2.305434E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.449 0.000000 0.000000 0.246260 0.000000 0.727066 0.019425 0.007249 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -4. -2. 0.4 0. 0. Chi 0. 0. 4.4E-02 0. 1.3E-02 4.6E-03 1.0E-03 0. 0. Composition Misfit: 6.227633E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.811 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 42.019 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023241 0.014705 0.006958 0.016421 0.052763 0.000916 0.040190 0.031561 0.001956 0.108148 0.703140 Mica 0.016709 0.001853 0.000000 0.065013 0.004709 0.000000 0.004000 0.165296 0.000487 0.241136 0.500797 Gt 0.000000 0.022320 0.000000 0.000000 0.259229 0.091155 0.061590 0.000000 0.002108 0.137738 0.425861 Fsp 0.093804 0.059353 0.000000 0.001520 0.000000 0.000000 0.000000 0.000000 0.000000 0.154676 0.690647 Bio 0.000000 0.000000 0.021650 0.067224 0.172045 0.001940 0.158018 0.112798 0.004246 0.125409 0.336670 St 0.000000 0.000000 0.003812 0.000000 0.133191 0.006187 0.046309 0.088150 0.002347 0.389441 0.330563 Ilm 0.000000 0.000000 0.218535 0.000000 0.645208 0.017238 0.006433 0.000000 0.112586 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777867. -756627. -932326. -852517. -313700. -460396. -638577. -292067. -408706. -1635663. -887673. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 256 converged, 104 successes so far. Misfit function evaluations this try => 170 Misfit this try = 0.118226 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.590028E-07 Bayes score, PP * exp(-Misfit) = 8.520696E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 10019.0 874.744 0.805161 0.136713 Final coordinates: 8586.96 924.869 0.592848 0.552775 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.117439 Extraneous predicted phases: 7.865901E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.341 0.021817 0.003084 0.000000 0.075482 0.006760 0.000000 0.006088 0.286478 0.600291 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.4 -3.7E-02 Chi 6.0E-03 0. 0. 1.1E-03 2.9E-03 0. 9.1E-03 1.3E-04 1.4E-07 Composition Misfit: 2.229076E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.902 0.000000 0.031014 0.000000 0.000000 0.291680 0.042951 0.071534 0.136597 0.426224 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -1. -2. 0.5 -0.2 Chi 0. 3.5E-03 0. 0. 3.1E-03 1.8E-03 3.9E-03 3.8E-04 5.8E-06 Composition Misfit: 1.273724E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.308 0.094240 0.058557 0.000000 0.001481 0.000000 0.000000 0.000000 0.154279 0.691443 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -3.6E-02 0. 0. 0. 0.5 0.1 Chi 7.1E-05 8.3E-04 0. 1.0E-05 0. 0. 0. 2.8E-04 1.4E-05 Composition Misfit: 1.206550E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.399 0.000000 0.000000 0.024680 0.075722 0.192608 0.001077 0.185115 0.135830 0.384969 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.5 0.1 -1. 0.3 2. Chi 0. 0. 4.4E-04 1.0E-03 3.4E-04 1.1E-04 1.3E-03 1.5E-04 2.5E-03 Composition Misfit: 5.873137E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.399 0.000000 0.000000 0.004721 0.000000 0.145857 0.003036 0.055396 0.427633 0.363358 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 1.5E-03 2.1E-04 1.9E-02 1.0E-03 1.4E-03 Composition Misfit: 2.466357E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.503 0.000000 0.000000 0.253025 0.000000 0.728601 0.009419 0.008956 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.1 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.3E-02 3.6E-05 1.2E-04 0. 0. Composition Misfit: 5.066783E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.607 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.454 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.088 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000021 -.000021 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023230 0.014698 0.006954 0.016413 0.052736 0.000915 0.040170 0.032040 0.001954 0.108095 0.702795 Mica 0.018206 0.002574 0.000000 0.062991 0.005641 0.000000 0.005080 0.164967 0.000526 0.239068 0.500947 Gt 0.000000 0.030930 0.000000 0.000000 0.290884 0.042833 0.071339 0.000000 0.002732 0.136223 0.425059 Fsp 0.094240 0.058557 0.000000 0.001481 0.000000 0.000000 0.000000 0.000000 0.000000 0.154279 0.691443 Bio 0.000000 0.000000 0.021814 0.066928 0.170240 0.000952 0.163617 0.112042 0.004090 0.120055 0.340261 St 0.000000 0.000000 0.004293 0.000000 0.132655 0.002761 0.050382 0.088125 0.002387 0.388927 0.330469 Ilm 0.000000 0.000000 0.225214 0.000000 0.648517 0.008383 0.007971 0.000000 0.109914 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775577. -754349. -931631. -849975. -314093. -467285. -638169. -291293. -408480. -1635514. -886161. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 258 converged, 105 successes so far. Misfit function evaluations this try => 207 Misfit this try = 0.215530 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.091887E-06 Bayes score, PP * exp(-Misfit) = 8.801852E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 11842.3 886.118 0.866203 0.734828 Final coordinates: 9089.03 920.889 0.950992 0.671394 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.215530 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.771 0.025282 0.004020 0.000000 0.071553 0.006305 0.000000 0.006536 0.286999 0.599303 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 0.7 0. 1. -0.4 0.1 Chi 8.8E-03 0. 0. 2.3E-03 3.7E-03 0. 7.5E-03 1.5E-04 8.1E-07 Composition Misfit: 2.655508E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.834 0.000000 0.038740 0.000000 0.000000 0.279644 0.040196 0.080591 0.135148 0.425680 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.7 -2. 0.6 -0.1 Chi 0. 8.5E-03 0. 0. 6.4E-03 8.8E-04 8.3E-03 5.6E-04 2.5E-06 Composition Misfit: 2.463248E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.998 0.093634 0.060217 0.000000 0.001257 0.000000 0.000000 0.000000 0.155109 0.689783 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 2.9E-02 0. 0. 0. 0.4 0.2 Chi 4.2E-05 1.2E-03 0. 8.1E-06 0. 0. 0. 2.2E-04 3.2E-05 Composition Misfit: 1.532785E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.213 0.000000 0.000000 0.022388 0.075362 0.173613 0.000958 0.210111 0.130427 0.387143 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.1 -1. 0.7 0.1 -3. 0.7 1. Chi 0. 0. 4.6E-05 9.4E-04 6.8E-04 2.3E-04 7.8E-03 7.5E-04 2.1E-03 Composition Misfit: 1.262880E-2 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.234 0.000000 0.000000 0.004228 0.000000 0.136762 0.002763 0.065699 0.427314 0.363235 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.4 0.2 -5. 1. 1. Chi 0. 0. 2.3E-03 0. 2.4E-04 4.2E-04 2.8E-02 1.1E-03 1.5E-03 Composition Misfit: 3.330265E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.985 0.000000 0.000000 0.212913 0.000000 0.772736 0.006966 0.007384 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 8. 0. -7. 0.5 0.4 0. 0. Chi 0. 0. 0.1 0. 2.6E-02 1.3E-03 9.3E-04 0. 0. Composition Misfit: 0.116878 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.285 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.680 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023044 0.014581 0.006899 0.016281 0.052316 0.000908 0.039849 0.038604 0.003109 0.107231 0.697177 Mica 0.021098 0.003355 0.000000 0.059710 0.005262 0.000000 0.005454 0.164971 0.000540 0.239498 0.500112 Gt 0.000000 0.038610 0.000000 0.000000 0.278704 0.040061 0.080320 0.000000 0.003362 0.134693 0.424249 Fsp 0.093634 0.060217 0.000000 0.001257 0.000000 0.000000 0.000000 0.000000 0.000000 0.155109 0.689783 Bio 0.000000 0.000000 0.019754 0.066497 0.153190 0.000845 0.185394 0.113239 0.004396 0.115084 0.341601 St 0.000000 0.000000 0.003844 0.000000 0.124359 0.002513 0.059741 0.088078 0.002614 0.388560 0.330292 Ilm 0.000000 0.000000 0.186187 0.000000 0.675739 0.006092 0.006457 0.000000 0.125525 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772601. -751848. -931062. -847807. -313592. -466832. -636363. -289783. -402682. -1633788. -884579. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 259 converged, 106 successes so far. Misfit function evaluations this try => 394 Misfit this try = 6.115100E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.415099E-07 Bayes score, PP * exp(-Misfit) = 8.856607E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 6432.71 976.770 0.863230 0.615561 Final coordinates: 8634.97 927.638 0.420400 0.497728 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.114998E-2 Extraneous predicted phases: 1.018181E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.018 0.021255 0.002965 0.000000 0.076082 0.006992 0.000000 0.006070 0.286134 0.600502 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.2E-04 2.5E-03 0. 9.2E-03 1.1E-04 4.2E-07 Composition Misfit: 2.127303E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.229 0.000000 0.030235 0.000000 0.000000 0.299397 0.037264 0.070076 0.136748 0.426280 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.3 -1. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 1.7E-03 2.4E-04 3.3E-03 3.7E-04 6.2E-06 Composition Misfit: 8.747744E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.572 0.094560 0.057794 0.000000 0.001543 0.000000 0.000000 0.000000 0.153897 0.692206 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 9.0E-05 6.6E-04 0. 2.2E-05 0. 0. 0. 3.2E-04 7.6E-06 Composition Misfit: 1.102589E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.530 0.000000 0.000000 0.025058 0.075769 0.197991 0.000946 0.178907 0.136538 0.384792 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.4E-04 1.0E-03 9.2E-04 2.4E-04 4.9E-04 1.0E-04 2.5E-03 Composition Misfit: 5.856076E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.046 0.000000 0.000000 0.004777 0.000000 0.148369 0.002628 0.053107 0.427732 0.363387 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 5.6E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.355672E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.313 0.000000 0.000000 0.351131 0.000000 0.626864 0.009365 0.012640 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.1 0. 0.1 0.1 -0.4 0. 0. Chi 0. 0. 3.6E-06 0. 1.6E-05 4.3E-05 5.5E-04 0. 0. Composition Misfit: 6.138292E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.957 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.332 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.003 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000023 -.000023 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023317 0.014754 0.006981 0.016475 0.052936 0.000919 0.040322 0.028958 0.001391 0.108503 0.705445 Mica 0.017738 0.002474 0.000000 0.063493 0.005835 0.000000 0.005066 0.164937 0.000524 0.238790 0.501142 Gt 0.000000 0.030154 0.000000 0.000000 0.298599 0.037165 0.069889 0.000000 0.002666 0.136383 0.425144 Fsp 0.094560 0.057794 0.000000 0.001543 0.000000 0.000000 0.000000 0.000000 0.000000 0.153897 0.692206 Bio 0.000000 0.000000 0.022155 0.066993 0.175057 0.000836 0.158183 0.111830 0.004003 0.120722 0.340220 St 0.000000 0.000000 0.004345 0.000000 0.134945 0.002390 0.048302 0.088136 0.002341 0.389032 0.330509 Ilm 0.000000 0.000000 0.326806 0.000000 0.583436 0.008716 0.011764 0.000000 0.069278 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775951. -754717. -931890. -850101. -314171. -468678. -638567. -291580. -409983. -1635855. -886352. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 260 converged, 107 successes so far. Misfit function evaluations this try => 144 Misfit this try = 6.128880E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.564395E-07 Bayes score, PP * exp(-Misfit) = 8.995807E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 8515.45 956.803 0.784559 7.871881E-02 Final coordinates: 8668.29 926.854 0.421725 0.492112 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.128880E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.008 0.021352 0.002970 0.000000 0.075981 0.006997 0.000000 0.006084 0.286112 0.600505 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.7E-03 0. 0. 9.5E-04 2.5E-03 0. 9.2E-03 1.1E-04 4.2E-07 Composition Misfit: 2.131157E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.315 0.000000 0.030592 0.000000 0.000000 0.300460 0.035898 0.070093 0.136696 0.426261 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.2 -1. 0.5 -0.2 Chi 0. 3.3E-03 0. 0. 1.5E-03 7.6E-05 3.3E-03 3.7E-04 6.0E-06 Composition Misfit: 8.624099E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.564 0.094634 0.057668 0.000000 0.001532 0.000000 0.000000 0.000000 0.153834 0.692332 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 9.4E-05 6.4E-04 0. 2.0E-05 0. 0. 0. 3.2E-04 6.8E-06 Composition Misfit: 1.084355E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.552 0.000000 0.000000 0.025004 0.075750 0.197990 0.000908 0.179150 0.136246 0.384952 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.7 0.3 2. Chi 0. 0. 5.3E-04 1.0E-03 9.2E-04 2.9E-04 5.2E-04 1.2E-04 2.5E-03 Composition Misfit: 5.903364E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.747 0.000000 0.000000 0.004763 0.000000 0.148542 0.002518 0.053073 0.427720 0.363383 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.1E-03 6.9E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.372378E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.318 0.000000 0.000000 0.349972 0.000000 0.628496 0.008975 0.012558 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 1.5E-03 0. 0.1 0.2 -0.4 0. 0. Chi 0. 0. 2.3E-09 0. 3.6E-06 1.2E-04 5.2E-04 0. 0. Composition Misfit: 6.416408E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.211 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.285 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023325 0.014758 0.006983 0.016480 0.052953 0.000919 0.040335 0.028641 0.001396 0.108538 0.705673 Mica 0.017819 0.002478 0.000000 0.063409 0.005839 0.000000 0.005077 0.164935 0.000524 0.238772 0.501146 Gt 0.000000 0.030510 0.000000 0.000000 0.299652 0.035801 0.069905 0.000000 0.002688 0.136329 0.425115 Fsp 0.094634 0.057668 0.000000 0.001532 0.000000 0.000000 0.000000 0.000000 0.000000 0.153834 0.692332 Bio 0.000000 0.000000 0.022108 0.066975 0.175054 0.000803 0.158397 0.111841 0.004001 0.120463 0.340358 St 0.000000 0.000000 0.004332 0.000000 0.135102 0.002290 0.048271 0.088134 0.002349 0.389019 0.330503 Ilm 0.000000 0.000000 0.325551 0.000000 0.584640 0.008348 0.011681 0.000000 0.069780 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775612. -754507. -931730. -849764. -314024. -468828. -638452. -291460. -409922. -1635657. -886190. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 263 converged, 108 successes so far. Misfit function evaluations this try => 258 Misfit this try = 0.132769 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.095560E-06 Bayes score, PP * exp(-Misfit) = 9.593457E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 10702.0 980.850 0.865810 0.616967 Final coordinates: 8673.31 906.888 0.627493 0.474225 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.132769 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.658 0.022972 0.002969 0.000000 0.074430 0.006409 0.000000 0.005892 0.287018 0.600309 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.4 -4.0E-02 Chi 6.9E-03 0. 0. 1.4E-03 3.5E-03 0. 9.9E-03 1.5E-04 1.6E-07 Composition Misfit: 2.485549E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.542 0.000000 0.034838 0.000000 0.000000 0.300331 0.033694 0.068552 0.136426 0.426160 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. 0.1 -1. 0.5 -0.2 Chi 0. 5.9E-03 0. 0. 1.6E-03 9.1E-06 2.8E-03 4.0E-04 5.3E-06 Composition Misfit: 1.059049E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.363 0.094992 0.057384 0.000000 0.001315 0.000000 0.000000 0.000000 0.153692 0.692616 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 1.2E-02 0. 0. 0. 0.5 0.1 Chi 1.2E-04 5.8E-04 0. 1.4E-06 0. 0. 0. 3.4E-04 5.1E-06 Composition Misfit: 1.045803E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.137 0.000000 0.000000 0.023877 0.075525 0.194408 0.000771 0.185979 0.132876 0.386565 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. -0.7 0.2 -1. 0.5 2. Chi 0. 0. 2.6E-04 9.7E-04 5.1E-04 5.5E-04 1.5E-03 4.2E-04 2.2E-03 Composition Misfit: 6.406934E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.003 0.000000 0.000000 0.004555 0.000000 0.148872 0.002212 0.053187 0.427790 0.363383 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.7E-03 0. 2.1E-03 1.2E-03 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.469311E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.572 0.000000 0.000000 0.243778 0.000000 0.741561 0.006761 0.007899 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. 0.5 0.3 0. 0. Chi 0. 0. 4.6E-02 0. 1.7E-02 1.6E-03 5.6E-04 0. 0. Composition Misfit: 6.517767E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.678 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.047 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023333 0.014764 0.006986 0.016486 0.052972 0.000919 0.040350 0.027610 0.002077 0.108577 0.705927 Mica 0.019170 0.002478 0.000000 0.062110 0.005348 0.000000 0.004917 0.165037 0.000489 0.239509 0.500942 Gt 0.000000 0.034740 0.000000 0.000000 0.299489 0.033599 0.068359 0.000000 0.002806 0.136043 0.424964 Fsp 0.094992 0.057384 0.000000 0.001315 0.000000 0.000000 0.000000 0.000000 0.000000 0.153692 0.692616 Bio 0.000000 0.000000 0.021096 0.066731 0.171770 0.000681 0.164323 0.112365 0.004080 0.117403 0.341552 St 0.000000 0.000000 0.004143 0.000000 0.135398 0.002012 0.048373 0.088131 0.002380 0.389070 0.330493 Ilm 0.000000 0.000000 0.216094 0.000000 0.657348 0.005993 0.007002 0.000000 0.113562 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -770861. -751622. -929242. -845316. -311658. -466704. -636533. -289628. -408122. -1632463. -884020. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 265 converged, 109 successes so far. Misfit function evaluations this try => 268 Misfit this try = 0.120984 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.975811E-07 Bayes score, PP * exp(-Misfit) = 8.839052E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 7030.05 976.916 0.902282 8.209024E-02 Final coordinates: 8806.63 925.500 0.618008 0.566295 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.120664 Extraneous predicted phases: 3.197029E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.323 0.022534 0.003282 0.000000 0.074650 0.006750 0.000000 0.006256 0.286366 0.600162 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.3 -2.1E-02 Chi 6.6E-03 0. 0. 1.3E-03 2.9E-03 0. 8.5E-03 1.2E-04 4.4E-08 Composition Misfit: 2.263970E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.073 0.000000 0.032865 0.000000 0.000000 0.292898 0.038260 0.073505 0.136343 0.426129 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.4 -2. 0.5 -0.2 Chi 0. 4.6E-03 0. 0. 2.9E-03 4.2E-04 4.8E-03 4.1E-04 5.1E-06 Composition Misfit: 1.309186E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.072 0.094291 0.058547 0.000000 0.001436 0.000000 0.000000 0.000000 0.154273 0.691453 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -2.3E-02 0. 0. 0. 0.5 0.1 Chi 7.4E-05 8.3E-04 0. 4.2E-06 0. 0. 0. 2.8E-04 1.3E-05 Composition Misfit: 1.201280E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.629 0.000000 0.000000 0.024521 0.075634 0.189651 0.000955 0.189035 0.134512 0.385691 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.3 0.1 -1. 0.4 2. Chi 0. 0. 4.1E-04 1.0E-03 1.4E-04 2.3E-04 2.0E-03 2.5E-04 2.4E-03 Composition Misfit: 6.414347E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.898 0.000000 0.000000 0.004804 0.000000 0.144593 0.002675 0.057027 0.427556 0.363345 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.3E-03 0. 1.3E-03 5.1E-04 2.0E-02 1.0E-03 1.5E-03 Composition Misfit: 2.597714E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.555 0.000000 0.000000 0.252785 0.000000 0.729562 0.008395 0.009258 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.3 0.1 0. 0. Chi 0. 0. 3.7E-02 0. 1.4E-02 3.1E-04 5.9E-05 0. 0. Composition Misfit: 5.133962E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.975 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.419 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.056 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000020 -.000020 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023210 0.014685 0.006949 0.016398 0.052691 0.000914 0.040136 0.032795 0.002035 0.108001 0.702185 Mica 0.018805 0.002739 0.000000 0.062298 0.005633 0.000000 0.005221 0.164945 0.000524 0.238981 0.500854 Gt 0.000000 0.032771 0.000000 0.000000 0.292066 0.038152 0.073296 0.000000 0.002842 0.135955 0.424917 Fsp 0.094291 0.058547 0.000000 0.001436 0.000000 0.000000 0.000000 0.000000 0.000000 0.154273 0.691453 Bio 0.000000 0.000000 0.021674 0.066852 0.167630 0.000845 0.167086 0.112030 0.004082 0.118894 0.340907 St 0.000000 0.000000 0.004370 0.000000 0.131505 0.002433 0.051866 0.088122 0.002390 0.388857 0.330458 Ilm 0.000000 0.000000 0.224976 0.000000 0.649303 0.007471 0.008240 0.000000 0.110009 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774765. -753718. -931211. -849293. -313959. -468051. -637818. -290944. -407956. -1635140. -885726. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 266 converged, 110 successes so far. Misfit function evaluations this try => 256 Misfit this try = 0.115706 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.695220E-07 Bayes score, PP * exp(-Misfit) = 8.635893E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 13516.9 941.413 0.353026 0.135449 Final coordinates: 8823.75 928.446 0.566579 0.463100 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.115706 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.010 0.021797 0.003077 0.000000 0.075464 0.007062 0.000000 0.006225 0.285931 0.600443 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.6 0. 1. -0.3 -0.1 Chi 6.0E-03 0. 0. 1.1E-03 2.4E-03 0. 8.6E-03 1.0E-04 3.3E-07 Composition Misfit: 2.123745E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.553 0.000000 0.031449 0.000000 0.000000 0.301162 0.032961 0.071839 0.136429 0.426161 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. 0.1 -2. 0.5 -0.2 Chi 0. 3.8E-03 0. 0. 1.4E-03 5.0E-05 4.0E-03 4.0E-04 5.3E-06 Composition Misfit: 9.710315E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.549 0.094828 0.057317 0.000000 0.001514 0.000000 0.000000 0.000000 0.153658 0.692683 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. -4.5E-02 0. 0. 0. 0.5 0.1 Chi 1.1E-04 5.7E-04 0. 1.6E-05 0. 0. 0. 3.4E-04 4.8E-06 Composition Misfit: 1.039392E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.589 0.000000 0.000000 0.024773 0.075690 0.195850 0.000835 0.182217 0.135354 0.385281 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.8 0.2 -0.9 0.4 2. Chi 0. 0. 4.7E-04 1.0E-03 6.6E-04 4.2E-04 8.9E-04 1.8E-04 2.4E-03 Composition Misfit: 6.063886E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.003 0.000000 0.000000 0.004737 0.000000 0.147625 0.002305 0.054404 0.427583 0.363346 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 1.9E-03 1.0E-03 1.8E-02 1.0E-03 1.5E-03 Composition Misfit: 2.499527E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.473 0.000000 0.000000 0.252778 0.000000 0.731175 0.007159 0.008888 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.5 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.4E-02 1.1E-03 1.4E-04 0. 0. Composition Misfit: 5.265947E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.711 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.112 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023353 0.014776 0.006992 0.016500 0.053017 0.000920 0.040384 0.026985 0.001877 0.108669 0.706527 Mica 0.018191 0.002568 0.000000 0.062979 0.005894 0.000000 0.005195 0.164908 0.000535 0.238626 0.501104 Gt 0.000000 0.031361 0.000000 0.000000 0.300317 0.032869 0.071637 0.000000 0.002805 0.136046 0.424966 Fsp 0.094828 0.057317 0.000000 0.001514 0.000000 0.000000 0.000000 0.000000 0.000000 0.153658 0.692683 Bio 0.000000 0.000000 0.021900 0.066911 0.173134 0.000738 0.161082 0.111922 0.004065 0.119655 0.340593 St 0.000000 0.000000 0.004308 0.000000 0.134262 0.002096 0.049479 0.088122 0.002399 0.388878 0.330456 Ilm 0.000000 0.000000 0.224969 0.000000 0.650737 0.006371 0.007910 0.000000 0.110012 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775269. -754292. -931733. -849538. -314078. -469540. -638288. -291323. -408920. -1635576. -886008. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 271 converged, 111 successes so far. Misfit function evaluations this try => 183 Misfit this try = 6.179852E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.006470E-06 Bayes score, PP * exp(-Misfit) = 9.461542E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 14273.6 985.968 0.793770 0.122353 Final coordinates: 8562.47 918.681 0.430349 0.492130 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.179852E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.005 0.021543 0.002883 0.000000 0.075866 0.006782 0.000000 0.005940 0.286494 0.600493 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.4 -0.1 Chi 5.8E-03 0. 0. 9.7E-04 2.8E-03 0. 9.7E-03 1.3E-04 4.0E-07 Composition Misfit: 2.235001E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.271 0.000000 0.031375 0.000000 0.000000 0.300044 0.037128 0.068441 0.136736 0.426276 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.3 -1. 0.5 -0.2 Chi 0. 3.7E-03 0. 0. 1.6E-03 2.2E-04 2.7E-03 3.7E-04 6.1E-06 Composition Misfit: 8.650277E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.555 0.094678 0.057714 0.000000 0.001465 0.000000 0.000000 0.000000 0.153857 0.692286 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -3.1E-02 0. 0. 0. 0.5 0.1 Chi 9.7E-05 6.5E-04 0. 7.9E-06 0. 0. 0. 3.2E-04 7.1E-06 Composition Misfit: 1.082506E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.580 0.000000 0.000000 0.024683 0.075710 0.198357 0.000905 0.179483 0.135643 0.385221 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.9 0.1 -0.7 0.3 2. Chi 0. 0. 4.5E-04 1.0E-03 9.7E-04 3.0E-04 5.5E-04 1.6E-04 2.5E-03 Composition Misfit: 5.894718E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.656 0.000000 0.000000 0.004655 0.000000 0.149342 0.002554 0.052260 0.427795 0.363393 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 2.2E-03 6.5E-04 1.6E-02 1.0E-03 1.4E-03 Composition Misfit: 2.334271E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.334 0.000000 0.000000 0.346585 0.000000 0.632332 0.009064 0.012019 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.2 0. -0.1 0.1 -0.3 0. 0. Chi 0. 0. 3.4E-05 0. 8.6E-06 9.7E-05 3.4E-04 0. 0. Composition Misfit: 4.782995E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.325 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.273 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023324 0.014758 0.006983 0.016479 0.052952 0.000919 0.040334 0.028641 0.001424 0.108534 0.705652 Mica 0.017978 0.002406 0.000000 0.063310 0.005659 0.000000 0.004957 0.164982 0.000511 0.239081 0.501115 Gt 0.000000 0.031291 0.000000 0.000000 0.299243 0.037029 0.068258 0.000000 0.002671 0.136371 0.425137 Fsp 0.094678 0.057714 0.000000 0.001465 0.000000 0.000000 0.000000 0.000000 0.000000 0.153857 0.692286 Bio 0.000000 0.000000 0.021818 0.066923 0.175337 0.000800 0.158654 0.112028 0.004023 0.119901 0.340515 St 0.000000 0.000000 0.004234 0.000000 0.135828 0.002323 0.047531 0.088136 0.002353 0.389085 0.330510 Ilm 0.000000 0.000000 0.321893 0.000000 0.587283 0.008418 0.011163 0.000000 0.071243 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774151. -753656. -930935. -848326. -313147. -467603. -637879. -290912. -409575. -1634577. -885545. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 272 converged, 112 successes so far. Misfit function evaluations this try => 235 Misfit this try = 0.225774 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.094088E-06 Bayes score, PP * exp(-Misfit) = 8.729709E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 9807.64 927.409 0.947778 0.909589 Final coordinates: 9122.88 921.224 0.983264 0.683494 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.225737 Extraneous predicted phases: 3.686699E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.121 0.025556 0.004109 0.000000 0.071236 0.006274 0.000000 0.006562 0.287056 0.599207 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 0.8 0. 1. -0.4 0.1 Chi 9.0E-03 0. 0. 2.5E-03 3.8E-03 0. 7.4E-03 1.5E-04 1.0E-06 Composition Misfit: 2.698351E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.817 0.000000 0.039179 0.000000 0.000000 0.278395 0.040361 0.081381 0.135042 0.425641 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.7 -3. 0.6 -0.1 Chi 0. 8.9E-03 0. 0. 6.8E-03 9.3E-04 8.7E-03 5.7E-04 2.3E-06 Composition Misfit: 2.585063E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.896 0.093570 0.060366 0.000000 0.001247 0.000000 0.000000 0.000000 0.155183 0.689634 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.9 0. 3.2E-02 0. 0. 0. 0.4 0.2 Chi 3.9E-05 1.3E-03 0. 9.8E-06 0. 0. 0. 2.1E-04 3.4E-05 Composition Misfit: 1.568100E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.955 0.000000 0.000000 0.022228 0.075343 0.172161 0.000960 0.211930 0.130140 0.387237 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.1 -1. 0.8 0.1 -3. 0.7 1. Chi 0. 0. 3.3E-05 9.3E-04 8.8E-04 2.2E-04 8.5E-03 8.0E-04 2.1E-03 Composition Misfit: 1.348658E-2 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.434 0.000000 0.000000 0.004187 0.000000 0.135923 0.002773 0.066608 0.427285 0.363224 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.4 0.2 -5. 1. 1. Chi 0. 0. 2.4E-03 0. 1.7E-04 4.1E-04 2.9E-02 1.1E-03 1.5E-03 Composition Misfit: 3.411612E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.024 0.000000 0.000000 0.209777 0.000000 0.776121 0.006843 0.007259 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 8. 0. -7. 0.5 0.4 0. 0. Chi 0. 0. 0.1 0. 2.8E-02 1.5E-03 1.0E-03 0. 0. Composition Misfit: 0.123732 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.042 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.692 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.019 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000013 -.000013 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023026 0.014569 0.006893 0.016268 0.052274 0.000907 0.039817 0.039269 0.003212 0.107145 0.696619 Mica 0.021326 0.003429 0.000000 0.059445 0.005236 0.000000 0.005476 0.164972 0.000542 0.239544 0.500030 Gt 0.000000 0.039045 0.000000 0.000000 0.277447 0.040224 0.081104 0.000000 0.003407 0.134582 0.424191 Fsp 0.093570 0.060366 0.000000 0.001247 0.000000 0.000000 0.000000 0.000000 0.000000 0.155183 0.689634 Bio 0.000000 0.000000 0.019611 0.066471 0.151889 0.000847 0.186975 0.113331 0.004421 0.114816 0.341639 St 0.000000 0.000000 0.003807 0.000000 0.123593 0.002522 0.060566 0.088074 0.002633 0.388527 0.330277 Ilm 0.000000 0.000000 0.183193 0.000000 0.677769 0.005976 0.006339 0.000000 0.126723 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772546. -751763. -931141. -847810. -313645. -466826. -636289. -289732. -402219. -1633768. -884538. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 275 converged, 113 successes so far. Misfit function evaluations this try => 193 Misfit this try = 0.194939 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 3.975101E-07 Bayes score, PP * exp(-Misfit) = 3.271049E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 14157.5 823.335 0.717410 0.487677 Final coordinates: 7682.02 839.409 0.791470 0.534404 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.194939 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.363 0.026683 0.002514 0.000000 0.071284 0.004243 0.000000 0.004338 0.291171 0.599768 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -3. 0. 0. 1. 1. 0. 1. -0.6 3.0E-02 Chi 1.0E-02 0. 0. 2.4E-03 1.1E-02 0. 2.0E-02 3.9E-04 9.0E-08 Composition Misfit: 4.614157E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.869 0.000000 0.043456 0.000000 0.000000 0.286393 0.051167 0.055645 0.136974 0.426365 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 2. -2. -0.1 0.5 -0.2 Chi 0. 1.2E-02 0. 0. 4.4E-03 5.6E-03 1.3E-05 3.4E-04 6.8E-06 Composition Misfit: 2.244181E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.934 0.094679 0.058937 0.000000 0.000852 0.000000 0.000000 0.000000 0.154468 0.691063 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.1 0. 0. 0. 0.4 0.2 Chi 9.7E-05 9.1E-04 0. 3.0E-04 0. 0. 0. 2.7E-04 1.7E-05 Composition Misfit: 1.595713E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.946 0.000000 0.000000 0.021491 0.075150 0.190710 0.000844 0.195052 0.127250 0.389504 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1.6E-02 -1. -0.4 0.2 -2. 0.9 1. Chi 0. 0. 7.1E-07 8.9E-04 2.0E-04 4.0E-04 3.3E-03 1.3E-03 1.8E-03 Composition Misfit: 7.978819E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.736 0.000000 0.000000 0.004047 0.000000 0.153183 0.002811 0.047743 0.428656 0.363561 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -2. 0.2 -3. 1. 1. Chi 0. 0. 2.7E-03 0. 3.2E-03 3.8E-04 1.3E-02 9.2E-04 1.4E-03 Composition Misfit: 2.148622E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.816 0.000000 0.000000 0.225262 0.000000 0.760658 0.008507 0.005573 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -6. 0.2 0.7 0. 0. Chi 0. 0. 0.1 0. 2.2E-02 2.6E-04 3.5E-03 0. 0. Composition Misfit: 9.529517E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.142 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.193 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023239 0.014704 0.006957 0.016419 0.052759 0.000916 0.040187 0.030988 0.002610 0.108139 0.703082 Mica 0.022257 0.002097 0.000000 0.059460 0.003539 0.000000 0.003618 0.165531 0.000343 0.242873 0.500282 Gt 0.000000 0.043345 0.000000 0.000000 0.285658 0.051035 0.055502 0.000000 0.002567 0.136622 0.425270 Fsp 0.094679 0.058937 0.000000 0.000852 0.000000 0.000000 0.000000 0.000000 0.000000 0.154468 0.691063 Bio 0.000000 0.000000 0.018960 0.066302 0.168255 0.000745 0.172086 0.113643 0.004101 0.112267 0.343642 St 0.000000 0.000000 0.003681 0.000000 0.139332 0.002557 0.043426 0.088183 0.002237 0.389896 0.330687 Ilm 0.000000 0.000000 0.198055 0.000000 0.668788 0.007479 0.004900 0.000000 0.120778 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -759667. -744949. -922422. -834729. -304954. -456073. -631965. -285363. -407041. -1624252. -879227. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 276 converged, 114 successes so far. Misfit function evaluations this try => 303 Misfit this try = 0.113605 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.377761E-07 Bayes score, PP * exp(-Misfit) = 8.370685E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 11473.2 882.804 0.900324 0.842238 Final coordinates: 8545.13 926.122 0.561487 0.489312 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.113605 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.019 0.021316 0.002959 0.000000 0.076038 0.006909 0.000000 0.006033 0.286312 0.600434 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.3E-04 2.6E-03 0. 9.4E-03 1.2E-04 3.1E-07 Composition Misfit: 2.161052E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.053 0.000000 0.030042 0.000000 0.000000 0.295300 0.041440 0.070289 0.136675 0.426253 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.8 -1. 0.5 -0.2 Chi 0. 3.0E-03 0. 0. 2.4E-03 1.2E-03 3.4E-03 3.8E-04 6.0E-06 Composition Misfit: 1.044508E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.600 0.094454 0.058034 0.000000 0.001529 0.000000 0.000000 0.000000 0.154017 0.691966 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -5.0E-02 0. 0. 0. 0.5 0.1 Chi 8.3E-05 7.1E-04 0. 1.9E-05 0. 0. 0. 3.1E-04 9.3E-06 Composition Misfit: 1.133342E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.530 0.000000 0.000000 0.024841 0.075769 0.196283 0.001047 0.180912 0.136542 0.384605 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.8 0.1 -0.8 0.3 2. Chi 0. 0. 4.9E-04 1.0E-03 7.1E-04 1.4E-04 7.2E-04 1.0E-04 2.6E-03 Composition Misfit: 5.735546E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.540 0.000000 0.000000 0.004672 0.000000 0.147599 0.002935 0.053770 0.427663 0.363361 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.9E-03 2.8E-04 1.8E-02 1.0E-03 1.4E-03 Composition Misfit: 2.380937E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.449 0.000000 0.000000 0.253097 0.000000 0.729142 0.009046 0.008715 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.3E-02 1.0E-04 1.9E-04 0. 0. Composition Misfit: 5.087145E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.445 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.364 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023318 0.014754 0.006981 0.016475 0.052937 0.000919 0.040323 0.028469 0.001858 0.108505 0.705461 Mica 0.017789 0.002469 0.000000 0.063454 0.005766 0.000000 0.005034 0.164955 0.000532 0.238931 0.501070 Gt 0.000000 0.029961 0.000000 0.000000 0.294504 0.041328 0.070100 0.000000 0.002697 0.136307 0.425104 Fsp 0.094454 0.058034 0.000000 0.001529 0.000000 0.000000 0.000000 0.000000 0.000000 0.154017 0.691966 Bio 0.000000 0.000000 0.021957 0.066975 0.173499 0.000926 0.159913 0.111992 0.004083 0.120693 0.339962 St 0.000000 0.000000 0.004249 0.000000 0.134239 0.002670 0.048903 0.088126 0.002390 0.388953 0.330471 Ilm 0.000000 0.000000 0.225286 0.000000 0.649020 0.008052 0.007757 0.000000 0.109886 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776008. -754753. -931980. -850244. -314178. -467755. -638476. -291554. -409048. -1635806. -886393. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 288 converged, 115 successes so far. Misfit function evaluations this try => 250 Misfit this try = 6.121357E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.372244E-07 Bayes score, PP * exp(-Misfit) = 8.815742E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 6779.87 948.243 0.524240 8.453021E-02 Final coordinates: 8600.20 927.353 0.423101 0.505608 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.110462E-2 Extraneous predicted phases: 1.089458E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.003 0.021188 0.002951 0.000000 0.076160 0.006981 0.000000 0.006048 0.286174 0.600499 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.5E-03 0. 0. 9.1E-04 2.5E-03 0. 9.3E-03 1.1E-04 4.2E-07 Composition Misfit: 2.129602E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.172 0.000000 0.030090 0.000000 0.000000 0.298680 0.038296 0.069893 0.136757 0.426284 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.4 -1. 0.5 -0.2 Chi 0. 3.0E-03 0. 0. 1.8E-03 4.3E-04 3.3E-03 3.7E-04 6.2E-06 Composition Misfit: 8.896449E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.573 0.094521 0.057869 0.000000 0.001544 0.000000 0.000000 0.000000 0.153935 0.692131 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.7E-05 6.8E-04 0. 2.3E-05 0. 0. 0. 3.1E-04 8.1E-06 Composition Misfit: 1.112913E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.530 0.000000 0.000000 0.025058 0.075779 0.198033 0.000973 0.178775 0.136680 0.384703 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.4E-04 1.0E-03 9.3E-04 2.1E-04 4.8E-04 9.7E-05 2.5E-03 Composition Misfit: 5.824717E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.177 0.000000 0.000000 0.004756 0.000000 0.148385 0.002705 0.053039 0.427730 0.363385 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 4.8E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.345034E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.313 0.000000 0.000000 0.348786 0.000000 0.629105 0.009602 0.012506 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. 4.1E-02 0.1 -0.4 0. 0. Chi 0. 0. 4.2E-06 0. 1.3E-06 1.6E-05 5.0E-04 0. 0. Composition Misfit: 5.241849E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.852 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.347 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.033 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000023 -.000023 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023306 0.014747 0.006978 0.016467 0.052911 0.000918 0.040303 0.029403 0.001399 0.108452 0.705116 Mica 0.017682 0.002462 0.000000 0.063558 0.005826 0.000000 0.005047 0.164942 0.000525 0.238821 0.501136 Gt 0.000000 0.030010 0.000000 0.000000 0.297885 0.038194 0.069707 0.000000 0.002662 0.136393 0.425149 Fsp 0.094521 0.057869 0.000000 0.001544 0.000000 0.000000 0.000000 0.000000 0.000000 0.153935 0.692131 Bio 0.000000 0.000000 0.022155 0.067000 0.175090 0.000860 0.158063 0.111844 0.004009 0.120846 0.340134 St 0.000000 0.000000 0.004326 0.000000 0.134959 0.002460 0.048240 0.088135 0.002347 0.389028 0.330505 Ilm 0.000000 0.000000 0.324269 0.000000 0.584884 0.008928 0.011627 0.000000 0.070292 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776045. -754776. -931935. -850189. -314185. -468462. -638590. -291610. -409933. -1635885. -886401. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 290 converged, 116 successes so far. Misfit function evaluations this try => 274 Misfit this try = 6.140860E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.848034E-07 Bayes score, PP * exp(-Misfit) = 9.261475E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 8700.25 983.286 0.522173 6.494569E-02 Final coordinates: 8579.75 921.853 0.426500 0.493855 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.140860E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 0.021390 0.002899 0.000000 0.076000 0.006865 0.000000 0.005978 0.286360 0.600508 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.7E-03 0. 0. 9.4E-04 2.7E-03 0. 9.6E-03 1.2E-04 4.3E-07 Composition Misfit: 2.191440E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.252 0.000000 0.030893 0.000000 0.000000 0.299799 0.037255 0.069030 0.136744 0.426279 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.3 -1. 0.5 -0.2 Chi 0. 3.5E-03 0. 0. 1.6E-03 2.4E-04 2.9E-03 3.7E-04 6.2E-06 Composition Misfit: 8.648890E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.564 0.094632 0.057749 0.000000 0.001493 0.000000 0.000000 0.000000 0.153875 0.692251 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -3.9E-02 0. 0. 0. 0.5 0.1 Chi 9.4E-05 6.6E-04 0. 1.2E-05 0. 0. 0. 3.2E-04 7.3E-06 Composition Misfit: 1.089787E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.569 0.000000 0.000000 0.024824 0.075733 0.198236 0.000921 0.179238 0.135992 0.385056 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.9 0.1 -0.7 0.3 2. Chi 0. 0. 4.8E-04 1.0E-03 9.6E-04 2.7E-04 5.3E-04 1.4E-04 2.5E-03 Composition Misfit: 5.873454E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.799 0.000000 0.000000 0.004697 0.000000 0.149021 0.002583 0.052528 0.427778 0.363393 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 2.2E-03 6.1E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.339064E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.326 0.000000 0.000000 0.348119 0.000000 0.630469 0.009179 0.012233 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. -2.2E-02 0.1 -0.4 0. 0. Chi 0. 0. 1.0E-05 0. 3.5E-07 7.3E-05 4.1E-04 0. 0. Composition Misfit: 4.914222E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.192 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.297 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023322 0.014757 0.006982 0.016478 0.052947 0.000919 0.040330 0.028739 0.001411 0.108525 0.705590 Mica 0.017850 0.002419 0.000000 0.063423 0.005729 0.000000 0.004989 0.164966 0.000516 0.238973 0.501135 Gt 0.000000 0.030811 0.000000 0.000000 0.298999 0.037155 0.068846 0.000000 0.002667 0.136379 0.425142 Fsp 0.094632 0.057749 0.000000 0.001493 0.000000 0.000000 0.000000 0.000000 0.000000 0.153875 0.692251 Bio 0.000000 0.000000 0.021945 0.066950 0.175246 0.000815 0.158452 0.111955 0.004014 0.120221 0.340402 St 0.000000 0.000000 0.004272 0.000000 0.135537 0.002349 0.047775 0.088136 0.002347 0.389072 0.330512 Ilm 0.000000 0.000000 0.323549 0.000000 0.585970 0.008531 0.011369 0.000000 0.070580 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774824. -754060. -931294. -848983. -313516. -467959. -638139. -291165. -409738. -1635047. -885849. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 292 converged, 117 successes so far. Misfit function evaluations this try => 316 Misfit this try = 6.537027E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.075128E-06 Bayes score, PP * exp(-Misfit) = 1.007094E-06 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 6061.13 915.921 0.298533 4.779257E-02 Final coordinates: 8712.77 913.522 0.435719 0.466723 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.537027E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 0.022177 0.002899 0.000000 0.075226 0.006720 0.000000 0.005964 0.286521 0.600493 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.4 -0.1 Chi 6.3E-03 0. 0. 1.1E-03 2.9E-03 0. 9.6E-03 1.3E-04 4.1E-07 Composition Misfit: 2.302237E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.748 0.000000 0.033306 0.000000 0.000000 0.304999 0.030661 0.068297 0.136536 0.426201 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. 0.4 -1. 0.5 -0.2 Chi 0. 4.9E-03 0. 0. 9.4E-04 4.2E-04 2.7E-03 3.9E-04 5.6E-06 Composition Misfit: 9.310038E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.487 0.095114 0.056973 0.000000 0.001399 0.000000 0.000000 0.000000 0.153486 0.693027 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.5 0. -1.2E-02 0. 0. 0. 0.5 0.1 Chi 1.3E-04 5.1E-04 0. 1.2E-06 0. 0. 0. 3.6E-04 3.1E-06 Composition Misfit: 9.958494E-4 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.655 0.000000 0.000000 0.024344 0.075603 0.198290 0.000726 0.180923 0.134052 0.386061 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.9 0.2 -0.8 0.5 2. Chi 0. 0. 3.6E-04 9.9E-04 9.6E-04 6.7E-04 7.2E-04 2.9E-04 2.3E-03 Composition Misfit: 6.315087E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.085 0.000000 0.000000 0.004616 0.000000 0.150174 0.002043 0.051981 0.427796 0.363390 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.4 -4. 1. 1. Chi 0. 0. 1.6E-03 0. 2.4E-03 1.6E-03 1.6E-02 1.0E-03 1.4E-03 Composition Misfit: 2.430403E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.364 0.000000 0.000000 0.344591 0.000000 0.636362 0.007286 0.011761 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.3 0. -0.3 0.4 -0.3 0. 0. Chi 0. 0. 8.5E-05 0. 6.4E-05 1.0E-03 2.6E-04 0. 0. Composition Misfit: 1.422896E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.644 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.015 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023358 0.014780 0.006993 0.016504 0.053029 0.000920 0.040393 0.027202 0.001444 0.108693 0.706684 Mica 0.018507 0.002419 0.000000 0.062777 0.005608 0.000000 0.004977 0.164986 0.000501 0.239105 0.501119 Gt 0.000000 0.033214 0.000000 0.000000 0.304158 0.030577 0.068108 0.000000 0.002758 0.136159 0.425026 Fsp 0.095114 0.056973 0.000000 0.001399 0.000000 0.000000 0.000000 0.000000 0.000000 0.153486 0.693027 Bio 0.000000 0.000000 0.021516 0.066822 0.175258 0.000642 0.159908 0.112128 0.004026 0.118481 0.341219 St 0.000000 0.000000 0.004198 0.000000 0.136584 0.001858 0.047277 0.088135 0.002362 0.389082 0.330505 Ilm 0.000000 0.000000 0.319745 0.000000 0.590479 0.006761 0.010913 0.000000 0.072102 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772210. -752525. -930016. -846444. -312288. -468230. -637216. -290232. -409206. -1633429. -884643. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 294 converged, 118 successes so far. Misfit function evaluations this try => 179 Misfit this try = 6.465510E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.068661E-06 Bayes score, PP * exp(-Misfit) = 1.001753E-06 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 5863.88 817.817 0.456808 0.802873 Final coordinates: 8648.73 912.059 0.442400 0.472229 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.465510E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 0.022088 0.002868 0.000000 0.075339 0.006676 0.000000 0.005916 0.286623 0.600489 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.4 -0.1 Chi 6.2E-03 0. 0. 1.1E-03 3.0E-03 0. 9.8E-03 1.3E-04 4.0E-07 Composition Misfit: 2.317725E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.618 0.000000 0.033196 0.000000 0.000000 0.303834 0.032355 0.067839 0.136564 0.426212 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. 0.2 -1. 0.5 -0.2 Chi 0. 4.8E-03 0. 0. 1.1E-03 1.1E-04 2.5E-03 3.9E-04 5.7E-06 Composition Misfit: 8.907326E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.501 0.095024 0.057166 0.000000 0.001393 0.000000 0.000000 0.000000 0.153583 0.692834 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.5 0. -1.0E-02 0. 0. 0. 0.5 0.1 Chi 1.2E-04 5.4E-04 0. 9.1E-07 0. 0. 0. 3.5E-04 4.0E-06 Composition Misfit: 1.015744E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.647 0.000000 0.000000 0.024291 0.075612 0.198430 0.000761 0.180775 0.134174 0.385957 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.9 0.2 -0.8 0.4 2. Chi 0. 0. 3.5E-04 9.9E-04 9.8E-04 5.8E-04 7.0E-04 2.8E-04 2.3E-03 Composition Misfit: 6.218155E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.392 0.000000 0.000000 0.004579 0.000000 0.150275 0.002155 0.051790 0.427810 0.363391 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.4 -4. 1. 1. Chi 0. 0. 1.7E-03 0. 2.5E-03 1.3E-03 1.6E-02 1.0E-03 1.4E-03 Composition Misfit: 2.396624E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.368 0.000000 0.000000 0.340489 0.000000 0.640372 0.007627 0.011512 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.5 0. -0.5 0.4 -0.2 0. 0. Chi 0. 0. 2.7E-04 0. 1.7E-04 7.4E-04 2.0E-04 0. 0. Composition Misfit: 1.370383E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.403 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.070 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023350 0.014774 0.006991 0.016498 0.053011 0.000920 0.040379 0.027513 0.001466 0.108656 0.706442 Mica 0.018432 0.002393 0.000000 0.062870 0.005571 0.000000 0.004937 0.164999 0.000501 0.239187 0.501109 Gt 0.000000 0.033105 0.000000 0.000000 0.302999 0.032266 0.067653 0.000000 0.002746 0.136189 0.425041 Fsp 0.095024 0.057166 0.000000 0.001393 0.000000 0.000000 0.000000 0.000000 0.000000 0.153583 0.692834 Bio 0.000000 0.000000 0.021468 0.066824 0.175368 0.000672 0.159765 0.112180 0.004043 0.118580 0.341100 St 0.000000 0.000000 0.004165 0.000000 0.136675 0.001960 0.047103 0.088134 0.002367 0.389093 0.330503 Ilm 0.000000 0.000000 0.315339 0.000000 0.593071 0.007064 0.010661 0.000000 0.073864 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772164. -752492. -929981. -846388. -312196. -467700. -637177. -290206. -409097. -1633335. -884632. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 295 converged, 119 successes so far. Misfit function evaluations this try => 196 Misfit this try = 6.130207E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 9.393404E-07 Bayes score, PP * exp(-Misfit) = 8.834864E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 12899.6 899.174 0.710626 8.040128E-02 Final coordinates: 8618.11 927.511 0.425199 0.505603 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.113328E-2 Extraneous predicted phases: 1.687856E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.008 0.021218 0.002958 0.000000 0.076124 0.006995 0.000000 0.006062 0.286145 0.600499 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.1E-04 2.5E-03 0. 9.2E-03 1.1E-04 4.2E-07 Composition Misfit: 2.125610E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.201 0.000000 0.030177 0.000000 0.000000 0.299024 0.037779 0.070015 0.136731 0.426274 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.4 -1. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 1.8E-03 3.3E-04 3.3E-03 3.7E-04 6.1E-06 Composition Misfit: 8.839662E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.567 0.094541 0.057830 0.000000 0.001544 0.000000 0.000000 0.000000 0.153915 0.692170 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.8E-05 6.7E-04 0. 2.2E-05 0. 0. 0. 3.2E-04 7.9E-06 Composition Misfit: 1.107445E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.528 0.000000 0.000000 0.025042 0.075773 0.197999 0.000960 0.178894 0.136596 0.384737 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.4E-04 1.0E-03 9.2E-04 2.3E-04 4.9E-04 1.0E-04 2.5E-03 Composition Misfit: 5.841224E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.080 0.000000 0.000000 0.004752 0.000000 0.148379 0.002667 0.053104 0.427716 0.363381 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 5.1E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.354852E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.316 0.000000 0.000000 0.347172 0.000000 0.630925 0.009448 0.012455 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.2 0. -4.2E-02 0.1 -0.4 0. 0. Chi 0. 0. 2.3E-05 0. 1.4E-06 3.2E-05 4.8E-04 0. 0. Composition Misfit: 5.403285E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.931 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.328 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.041 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000023 -.000023 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023306 0.014747 0.006977 0.016467 0.052911 0.000918 0.040303 0.029402 0.001406 0.108451 0.705111 Mica 0.017707 0.002468 0.000000 0.063528 0.005838 0.000000 0.005059 0.164938 0.000526 0.238798 0.501138 Gt 0.000000 0.030096 0.000000 0.000000 0.298225 0.037678 0.069828 0.000000 0.002673 0.136365 0.425134 Fsp 0.094541 0.057830 0.000000 0.001544 0.000000 0.000000 0.000000 0.000000 0.000000 0.153915 0.692170 Bio 0.000000 0.000000 0.022141 0.066994 0.175058 0.000848 0.158167 0.111847 0.004013 0.120770 0.340161 St 0.000000 0.000000 0.004322 0.000000 0.134953 0.002426 0.048298 0.088133 0.002353 0.389014 0.330500 Ilm 0.000000 0.000000 0.322527 0.000000 0.586136 0.008778 0.011570 0.000000 0.070989 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775998. -754749. -931931. -850146. -314181. -468572. -638577. -291596. -409868. -1635871. -886377. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 296 converged, 120 successes so far. Misfit function evaluations this try => 279 Misfit this try = 0.201496 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 8.172398E-07 Bayes score, PP * exp(-Misfit) = 6.680994E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 8982.09 814.080 0.947993 0.933847 Final coordinates: 7667.42 906.369 0.805396 0.640159 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.201496 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.861 0.022005 0.002814 0.000000 0.075580 0.005813 0.000000 0.005481 0.288316 0.599990 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.8 0. 1. -0.5 1.3E-03 Chi 6.2E-03 0. 0. 1.0E-03 4.9E-03 0. 1.2E-02 2.1E-04 1.8E-10 Composition Misfit: 2.701253E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 0.000000 0.028188 0.000000 0.000000 0.262622 0.076355 0.069420 0.137029 0.426386 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 3. -5. -1. 0.5 -0.2 Chi 0. 2.1E-03 0. 0. 1.3E-02 2.3E-02 3.1E-03 3.4E-04 7.0E-06 Composition Misfit: 4.210715E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.885 0.093370 0.060530 0.000000 0.001365 0.000000 0.000000 0.000000 0.155265 0.689470 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.1 -0.9 0. -2.0E-03 0. 0. 0. 0.4 0.2 Chi 3.2E-05 1.3E-03 0. 3.5E-08 0. 0. 0. 2.0E-04 3.7E-05 Composition Misfit: 1.591533E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.256 0.000000 0.000000 0.023172 0.075781 0.183098 0.001805 0.195653 0.136710 0.383781 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.2 -1. 0.1 -0.1 -2. 0.3 2. Chi 0. 0. 1.4E-04 1.0E-03 1.0E-05 8.0E-05 3.5E-03 9.5E-05 2.7E-03 Composition Misfit: 7.543380E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.609 0.000000 0.000000 0.004058 0.000000 0.141477 0.005504 0.057767 0.427840 0.363354 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -0.8 -0.4 -4. 1. 1. Chi 0. 0. 2.6E-03 0. 7.7E-04 5.0E-04 2.1E-02 1.0E-03 1.4E-03 Composition Misfit: 2.737825E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.758 0.000000 0.000000 0.223122 0.000000 0.756110 0.013996 0.006772 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -6. -0.6 0.5 0. 0. Chi 0. 0. 0.1 0. 2.1E-02 1.1E-03 1.5E-03 0. 0. Composition Misfit: 9.586270E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.596 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 42.034 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023097 0.014614 0.006915 0.016319 0.052435 0.000910 0.039940 0.036892 0.002639 0.107475 0.698765 Mica 0.018359 0.002348 0.000000 0.063057 0.004850 0.000000 0.004573 0.165181 0.000511 0.240545 0.500576 Gt 0.000000 0.028116 0.000000 0.000000 0.261954 0.076160 0.069244 0.000000 0.002543 0.136681 0.425302 Fsp 0.093370 0.060530 0.000000 0.001365 0.000000 0.000000 0.000000 0.000000 0.000000 0.155265 0.689470 Bio 0.000000 0.000000 0.020445 0.066863 0.161551 0.001593 0.172628 0.113281 0.004400 0.120622 0.338618 St 0.000000 0.000000 0.003690 0.000000 0.128658 0.005005 0.052533 0.088115 0.002491 0.389075 0.330432 Ilm 0.000000 0.000000 0.195989 0.000000 0.664164 0.012294 0.005949 0.000000 0.121604 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775421. -754391. -931764. -850379. -313457. -461482. -637364. -290918. -405314. -1634560. -886269. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 297 converged, 121 successes so far. Misfit function evaluations this try => 287 Misfit this try = 0.241937 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 1.070552E-06 Bayes score, PP * exp(-Misfit) = 8.404963E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 10746.5 986.903 0.887990 0.935226 Final coordinates: 8863.82 918.724 0.999840 0.574614 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.241937 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.245 0.023777 0.003507 0.000000 0.073301 0.006575 0.000000 0.006459 0.286564 0.599816 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 0.7 0. 1. -0.4 2.4E-02 Chi 7.6E-03 0. 0. 1.7E-03 3.2E-03 0. 7.8E-03 1.3E-04 5.6E-08 Composition Misfit: 2.387448E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.010 0.000000 0.036005 0.000000 0.000000 0.284533 0.040697 0.077718 0.135307 0.425740 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.7 -2. 0.6 -0.1 Chi 0. 6.6E-03 0. 0. 4.9E-03 1.0E-03 6.8E-03 5.4E-04 2.8E-06 Composition Misfit: 1.987175E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.653 0.094103 0.059155 0.000000 0.001319 0.000000 0.000000 0.000000 0.154578 0.690845 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 1.1E-02 0. 0. 0. 0.4 0.2 Chi 6.4E-05 9.7E-04 0. 1.1E-06 0. 0. 0. 2.6E-04 1.9E-05 Composition Misfit: 1.308836E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.169 0.000000 0.000000 0.021927 0.075428 0.179804 0.000970 0.204102 0.131414 0.386356 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.1 -1. 0.3 0.1 -2. 0.6 2. Chi 0. 0. 1.4E-05 9.5E-04 1.2E-04 2.1E-04 5.9E-03 6.0E-04 2.3E-03 Composition Misfit: 1.003213E-2 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.284 0.000000 0.000000 0.003790 0.000000 0.140570 0.002794 0.062221 0.427405 0.363221 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -0.7 0.2 -5. 1. 1. Chi 0. 0. 3.3E-03 0. 6.5E-04 3.9E-04 2.5E-02 1.0E-03 1.5E-03 Composition Misfit: 3.167485E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.013 0.000000 0.000000 0.197575 0.000000 0.790273 0.006181 0.005971 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 8. 0. -7. 0.6 0.6 0. 0. Chi 0. 0. 0.1 0. 3.3E-02 2.4E-03 2.7E-03 0. 0. Composition Misfit: 0.155175 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.226 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.401 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023169 0.014660 0.006936 0.016370 0.052600 0.000913 0.040066 0.033219 0.003287 0.107814 0.700966 Mica 0.019842 0.002927 0.000000 0.061169 0.005487 0.000000 0.005390 0.164948 0.000563 0.239135 0.500540 Gt 0.000000 0.035886 0.000000 0.000000 0.283596 0.040563 0.077462 0.000000 0.003292 0.134862 0.424338 Fsp 0.094103 0.059155 0.000000 0.001319 0.000000 0.000000 0.000000 0.000000 0.000000 0.154578 0.690845 Bio 0.000000 0.000000 0.019335 0.066512 0.158552 0.000855 0.179977 0.113690 0.004507 0.115882 0.340690 St 0.000000 0.000000 0.003446 0.000000 0.127811 0.002541 0.056573 0.088067 0.002697 0.388612 0.330253 Ilm 0.000000 0.000000 0.171623 0.000000 0.686470 0.005369 0.005187 0.000000 0.131351 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772974. -752440. -932097. -847862. -313384. -466664. -636652. -290122. -402855. -1633930. -884860. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 301 converged, 122 successes so far. Misfit function evaluations this try => 205 Misfit this try = 9.155916E-02 Best Misfit so far = 6.112359E-02 obtained on Try 147 Prior probability, PP = 2.346146E-07 Bayes score, PP * exp(-Misfit) = 2.140875E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 5943.63 929.542 0.450581 5.449309E-02 Final coordinates: 7388.36 824.312 0.449225 0.480969 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.155525E-2 Extraneous predicted phases: 3.914403E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.007 0.024293 0.001939 0.000000 0.073962 0.004385 0.000000 0.004181 0.290891 0.600348 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 1. 0. 1. -0.6 -4.5E-02 Chi 8.0E-03 0. 0. 1.5E-03 1.0E-02 0. 2.1E-02 3.7E-04 2.0E-07 Composition Misfit: 4.322138E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.186 0.000000 0.042943 0.000000 0.000000 0.299405 0.044679 0.049336 0.137191 0.426447 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 1. -1. 0.5 0.5 -0.2 Chi 0. 1.2E-02 0. 0. 1.7E-03 2.4E-03 6.0E-04 3.2E-04 7.5E-06 Composition Misfit: 1.674092E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.419 0.095381 0.057545 0.000000 0.000847 0.000000 0.000000 0.000000 0.153773 0.692455 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.5E-04 6.2E-04 0. 3.1E-04 0. 0. 0. 3.3E-04 6.0E-06 Composition Misfit: 1.405587E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.857 0.000000 0.000000 0.021076 0.075165 0.203855 0.000686 0.182448 0.127476 0.389294 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 3.7E-02 -1. -1. 0.2 -0.9 0.9 1. Chi 0. 0. 4.0E-06 9.0E-04 1.8E-03 8.0E-04 9.2E-04 1.3E-03 1.8E-03 Composition Misfit: 7.574761E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.005 0.000000 0.000000 0.003587 0.000000 0.160520 0.002291 0.041030 0.428971 0.363602 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. 0.3 -2. 1. 1. Chi 0. 0. 3.9E-03 0. 5.4E-03 1.0E-03 8.0E-03 8.9E-04 1.4E-03 Composition Misfit: 2.066705E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.462 0.000000 0.000000 0.369056 0.000000 0.613980 0.008523 0.008442 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 0.7 0.2 0.2 0. 0. Chi 0. 0. 9.8E-04 0. 4.2E-04 2.6E-04 2.9E-04 0. 0. Composition Misfit: 1.945551E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.118 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.945 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.001 0.000000 0.000000 0.182640 0.000000 0.681410 0.005469 0.003537 0.000000 0.126944 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023338 0.014767 0.006987 0.016489 0.052983 0.000919 0.040357 0.028008 0.001488 0.108598 0.706066 Mica 0.020264 0.001617 0.000000 0.061694 0.003658 0.000000 0.003488 0.165532 0.000339 0.242641 0.500768 Gt 0.000000 0.042837 0.000000 0.000000 0.298664 0.044568 0.049214 0.000000 0.002473 0.136852 0.425392 Fsp 0.095381 0.057545 0.000000 0.000847 0.000000 0.000000 0.000000 0.000000 0.000000 0.153773 0.692455 Bio 0.000000 0.000000 0.018586 0.066286 0.179775 0.000605 0.160896 0.113986 0.004138 0.112418 0.343309 St 0.000000 0.000000 0.003263 0.000000 0.146002 0.002083 0.037319 0.088191 0.002256 0.390172 0.330715 Ilm 0.000000 0.000000 0.346378 0.000000 0.576251 0.007999 0.007923 0.000000 0.061449 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -757379. -743982. -921790. -831749. -303165. -455397. -631536. -284948. -408064. -1622658. -878369. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 302 converged, 123 successes so far. Misfit function evaluations this try => 345 Misfit this try = 6.108472E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.403974E-07 Bayes score, PP * exp(-Misfit) = 8.846728E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 11635.3 840.366 0.228874 6.082623E-02 Final coordinates: 8614.28 927.331 0.420883 0.498116 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.108472E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.005 0.021219 0.002954 0.000000 0.076126 0.006983 0.000000 0.006054 0.286162 0.600502 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.1E-04 2.5E-03 0. 9.3E-03 1.1E-04 4.2E-07 Composition Misfit: 2.130163E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.200 0.000000 0.030162 0.000000 0.000000 0.299069 0.037801 0.069927 0.136757 0.426284 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.4 -1. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 1.7E-03 3.3E-04 3.3E-03 3.7E-04 6.2E-06 Composition Misfit: 8.791359E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.578 0.094542 0.057832 0.000000 0.001542 0.000000 0.000000 0.000000 0.153916 0.692168 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.8E-05 6.7E-04 0. 2.2E-05 0. 0. 0. 3.2E-04 7.9E-06 Composition Misfit: 1.107493E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.539 0.000000 0.000000 0.025061 0.075774 0.198026 0.000959 0.178817 0.136605 0.384758 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.4E-04 1.0E-03 9.3E-04 2.3E-04 4.8E-04 1.0E-04 2.5E-03 Composition Misfit: 5.838949E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.111 0.000000 0.000000 0.004765 0.000000 0.148417 0.002666 0.053030 0.427734 0.363387 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 5.2E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.347720E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.312 0.000000 0.000000 0.350470 0.000000 0.627475 0.009477 0.012578 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2.6E-02 0. 0.1 0.1 -0.4 0. 0. Chi 0. 0. 6.3E-07 0. 1.0E-05 2.9E-05 5.3E-04 0. 0. Composition Misfit: 5.680888E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.908 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.347 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023317 0.014753 0.006981 0.016474 0.052935 0.000919 0.040321 0.028980 0.001392 0.108500 0.705428 Mica 0.017708 0.002465 0.000000 0.063530 0.005827 0.000000 0.005053 0.164941 0.000524 0.238812 0.501140 Gt 0.000000 0.030082 0.000000 0.000000 0.298273 0.037700 0.069741 0.000000 0.002662 0.136393 0.425149 Fsp 0.094542 0.057832 0.000000 0.001542 0.000000 0.000000 0.000000 0.000000 0.000000 0.153916 0.692168 Bio 0.000000 0.000000 0.022158 0.066996 0.175088 0.000848 0.158103 0.111835 0.004002 0.120781 0.340189 St 0.000000 0.000000 0.004334 0.000000 0.134988 0.002425 0.048232 0.088136 0.002344 0.389033 0.330508 Ilm 0.000000 0.000000 0.326090 0.000000 0.583826 0.008817 0.011703 0.000000 0.069564 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775974. -754734. -931894. -850120. -314161. -468541. -638570. -291586. -409983. -1635851. -886366. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 303 converged, 124 successes so far. Misfit function evaluations this try => 249 Misfit this try = 0.152225 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 7.731043E-07 Bayes score, PP * exp(-Misfit) = 6.639385E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 7515.30 848.880 0.811683 0.888721 Final coordinates: 7698.63 880.609 0.650184 0.493324 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.152225 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.021 0.022133 0.002399 0.000000 0.075711 0.005559 0.000000 0.005059 0.288776 0.600362 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.9 0. 1. -0.5 -4.6E-02 Chi 6.3E-03 0. 0. 1.0E-03 5.6E-03 0. 1.4E-02 2.4E-04 2.2E-07 Composition Misfit: 2.978432E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.667 0.000000 0.032137 0.000000 0.000000 0.285677 0.057799 0.060610 0.137292 0.426484 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -3. -0.6 0.5 -0.2 Chi 0. 4.2E-03 0. 0. 4.6E-03 9.6E-03 5.6E-04 3.1E-04 7.8E-06 Composition Misfit: 1.925186E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.589 0.094481 0.058613 0.000000 0.001213 0.000000 0.000000 0.000000 0.154306 0.691387 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 4.2E-02 0. 0. 0. 0.5 0.1 Chi 8.5E-05 8.4E-04 0. 1.7E-05 0. 0. 0. 2.8E-04 1.4E-05 Composition Misfit: 1.237620E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.635 0.000000 0.000000 0.023287 0.075627 0.197174 0.001201 0.182740 0.134412 0.385558 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.2 -1. -0.8 0.1 -0.9 0.4 2. Chi 0. 0. 1.6E-04 1.0E-03 8.2E-04 4.2E-05 9.6E-04 2.6E-04 2.4E-03 Composition Misfit: 5.625726E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.319 0.000000 0.000000 0.004169 0.000000 0.151448 0.003704 0.048954 0.428256 0.363469 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -2. 2.9E-02 -3. 1. 1. Chi 0. 0. 2.4E-03 0. 2.7E-03 4.9E-06 1.4E-02 9.6E-04 1.4E-03 Composition Misfit: 2.138770E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.573 0.000000 0.000000 0.236218 0.000000 0.746443 0.010850 0.006490 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. -0.1 0.6 0. 0. Chi 0. 0. 0.1 0. 1.8E-02 6.7E-05 1.9E-03 0. 0. Composition Misfit: 7.493731E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.809 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.388 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023306 0.014746 0.006977 0.016466 0.052909 0.000918 0.040302 0.028687 0.002150 0.108448 0.705090 Mica 0.018466 0.002002 0.000000 0.063166 0.004638 0.000000 0.004221 0.165264 0.000443 0.240924 0.500878 Gt 0.000000 0.032059 0.000000 0.000000 0.284983 0.057659 0.060463 0.000000 0.002429 0.136958 0.425448 Fsp 0.094481 0.058613 0.000000 0.001213 0.000000 0.000000 0.000000 0.000000 0.000000 0.154306 0.691387 Bio 0.000000 0.000000 0.020559 0.066769 0.174078 0.001060 0.161334 0.112978 0.004159 0.118667 0.340395 St 0.000000 0.000000 0.003791 0.000000 0.137744 0.003369 0.044524 0.088155 0.002332 0.389505 0.330580 Ilm 0.000000 0.000000 0.208693 0.000000 0.659465 0.009586 0.005733 0.000000 0.116523 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -769096. -750846. -927882. -843554. -309731. -460278. -635651. -288943. -408294. -1630467. -883457. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 308 converged, 125 successes so far. Misfit function evaluations this try => 147 Misfit this try = 0.125513 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.855134E-07 Bayes score, PP * exp(-Misfit) = 8.692661E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 9711.71 885.902 0.826789 0.283929 Final coordinates: 8283.04 910.080 0.601404 0.510190 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.125513 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.539 0.021780 0.002810 0.000000 0.075722 0.006394 0.000000 0.005725 0.287208 0.600360 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.4 -4.6E-02 Chi 6.0E-03 0. 0. 1.0E-03 3.5E-03 0. 1.1E-02 1.6E-04 2.2E-07 Composition Misfit: 2.419408E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.840 0.000000 0.031255 0.000000 0.000000 0.290987 0.047203 0.067419 0.136827 0.426310 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -1. -1. 0.5 -0.2 Chi 0. 3.7E-03 0. 0. 3.3E-03 3.6E-03 2.4E-03 3.6E-04 6.4E-06 Composition Misfit: 1.324142E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.491 0.094373 0.058461 0.000000 0.001397 0.000000 0.000000 0.000000 0.154231 0.691539 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -1.1E-02 0. 0. 0. 0.5 0.1 Chi 7.9E-05 8.1E-04 0. 1.1E-06 0. 0. 0. 2.9E-04 1.3E-05 Composition Misfit: 1.186730E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.127 0.000000 0.000000 0.024258 0.075701 0.195124 0.001116 0.183191 0.135520 0.385090 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.7 0.1 -0.9 0.3 2. Chi 0. 0. 3.4E-04 1.0E-03 5.8E-04 8.5E-05 1.0E-03 1.7E-04 2.5E-03 Composition Misfit: 5.686617E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.277 0.000000 0.000000 0.004521 0.000000 0.148285 0.003229 0.052723 0.427847 0.363395 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.1 -4. 1. 1. Chi 0. 0. 1.7E-03 0. 2.0E-03 1.2E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.315114E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.510 0.000000 0.000000 0.247363 0.000000 0.734839 0.009809 0.007990 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. 3.0E-02 0.3 0. 0. Chi 0. 0. 4.3E-02 0. 1.5E-02 3.7E-06 5.1E-04 0. 0. Composition Misfit: 5.805341E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.785 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.431 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023286 0.014734 0.006972 0.016453 0.052866 0.000917 0.040269 0.029644 0.001987 0.108359 0.704512 Mica 0.018174 0.002345 0.000000 0.063186 0.005336 0.000000 0.004777 0.165065 0.000500 0.239656 0.500962 Gt 0.000000 0.031173 0.000000 0.000000 0.290221 0.047079 0.067241 0.000000 0.002631 0.136466 0.425188 Fsp 0.094373 0.058461 0.000000 0.001397 0.000000 0.000000 0.000000 0.000000 0.000000 0.154231 0.691539 Bio 0.000000 0.000000 0.021433 0.066886 0.172402 0.000986 0.161859 0.112339 0.004108 0.119739 0.340247 St 0.000000 0.000000 0.004112 0.000000 0.134864 0.002936 0.047951 0.088135 0.002370 0.389125 0.330506 Ilm 0.000000 0.000000 0.219621 0.000000 0.652425 0.008709 0.007094 0.000000 0.112152 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -773416. -753208. -930411. -847787. -312596. -464934. -637366. -290523. -408522. -1633814. -885256. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Bio F sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Bio F sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio F ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio F ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 315 converged, 126 successes so far. Misfit function evaluations this try => 287 Misfit this try = 0.110429 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 8.350881E-08 Bayes score, PP * exp(-Misfit) = 7.477797E-08 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 6486.88 919.203 0.232458 5.377104E-02 Final coordinates: 6871.81 801.473 0.479729 0.504680 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.110429 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.447 0.024646 0.001703 0.000000 0.073826 0.003800 0.000000 0.003697 0.292060 0.600267 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 1. 0. 1. -0.7 -3.4E-02 Chi 8.3E-03 0. 0. 1.5E-03 1.4E-02 0. 2.6E-02 4.6E-04 1.2E-07 Composition Misfit: 5.244562E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.873 0.000000 0.044131 0.000000 0.000000 0.291059 0.055865 0.044941 0.137458 0.426547 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 2. -2. 0.9 0.5 -0.2 Chi 0. 1.3E-02 0. 0. 3.3E-03 8.4E-03 2.2E-03 3.0E-04 8.4E-06 Composition Misfit: 2.670482E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.356 0.095128 0.058269 0.000000 0.000738 0.000000 0.000000 0.000000 0.154134 0.691731 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.3E-04 7.6E-04 0. 5.2E-04 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.719264E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.515 0.000000 0.000000 0.020155 0.075085 0.203600 0.000761 0.184448 0.126273 0.389678 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 0.2 -1. -1. 0.2 -1. 1. 1. Chi 0. 0. 7.3E-05 8.8E-04 1.8E-03 5.8E-04 1.2E-03 1.6E-03 1.8E-03 Composition Misfit: 7.871024E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.892 0.000000 0.000000 0.003283 0.000000 0.162433 0.002691 0.038709 0.429239 0.363644 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. 0.2 -2. 1. 1. Chi 0. 0. 5.0E-03 0. 6.1E-03 4.9E-04 6.4E-03 8.7E-04 1.4E-03 Composition Misfit: 2.026393E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.515 0.000000 0.000000 0.361728 0.000000 0.620796 0.010068 0.007408 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.6 0. 0.4 -1.1E-02 0.4 0. 0. Chi 0. 0. 3.8E-04 0. 1.4E-04 4.6E-07 9.1E-04 0. 0. Composition Misfit: 1.424047E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.354 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.047 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023303 0.014745 0.006977 0.016465 0.052904 0.000918 0.040298 0.029345 0.001586 0.108437 0.705022 Mica 0.020555 0.001420 0.000000 0.061572 0.003170 0.000000 0.003084 0.165676 0.000307 0.243583 0.500633 Gt 0.000000 0.044027 0.000000 0.000000 0.290373 0.055733 0.044835 0.000000 0.002357 0.137134 0.425541 Fsp 0.095128 0.058269 0.000000 0.000738 0.000000 0.000000 0.000000 0.000000 0.000000 0.154134 0.691731 Bio 0.000000 0.000000 0.017760 0.066164 0.179409 0.000671 0.162533 0.114567 0.004248 0.111270 0.343378 St 0.000000 0.000000 0.002986 0.000000 0.147741 0.002447 0.035208 0.088201 0.002249 0.390415 0.330753 Ilm 0.000000 0.000000 0.338337 0.000000 0.580652 0.009417 0.006929 0.000000 0.064665 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -754506. -742376. -920177. -829002. -301215. -451612. -630317. -283944. -407355. -1620466. -877274. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 317 converged, 127 successes so far. Misfit function evaluations this try => 195 Misfit this try = 7.823096E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 4.969780E-07 Bayes score, PP * exp(-Misfit) = 4.595808E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 7052.07 926.432 8.845533E-02 0.148230 Final coordinates: 7707.75 848.989 0.453003 0.484545 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.823096E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.016 0.023512 0.002174 0.000000 0.074529 0.004991 0.000000 0.004655 0.289744 0.600396 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.9 0. 1. -0.5 -0.1 Chi 7.4E-03 0. 0. 1.3E-03 7.6E-03 0. 1.7E-02 3.0E-04 2.6E-07 Composition Misfit: 3.574504E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.183 0.000000 0.039525 0.000000 0.000000 0.299476 0.043211 0.054334 0.137058 0.426397 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -1. 4.4E-02 0.5 -0.2 Chi 0. 9.1E-03 0. 0. 1.7E-03 1.9E-03 3.9E-06 3.4E-04 7.1E-06 Composition Misfit: 1.299932E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.453 0.095187 0.057658 0.000000 0.000984 0.000000 0.000000 0.000000 0.153829 0.692342 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.3E-04 6.4E-04 0. 1.4E-04 0. 0. 0. 3.2E-04 6.7E-06 Composition Misfit: 1.241978E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.783 0.000000 0.000000 0.022007 0.075316 0.202139 0.000756 0.181924 0.129737 0.388121 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.1 -1. -1. 0.2 -0.8 0.8 1. Chi 0. 0. 1.9E-05 9.3E-04 1.5E-03 5.9E-04 8.5E-04 8.6E-04 2.0E-03 Composition Misfit: 6.787614E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.459 0.000000 0.000000 0.003856 0.000000 0.157447 0.002408 0.044133 0.428621 0.363536 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -2. 0.3 -3. 1. 1. Chi 0. 0. 3.1E-03 0. 4.4E-03 8.5E-04 1.0E-02 9.3E-04 1.4E-03 Composition Misfit: 2.095342E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.437 0.000000 0.000000 0.358408 0.000000 0.623625 0.008782 0.009186 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.5 0. 0.3 0.2 0.1 0. 0. Chi 0. 0. 2.0E-04 0. 6.5E-05 1.7E-04 7.2E-05 0. 0. Composition Misfit: 5.035909E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.626 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.042 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023333 0.014763 0.006985 0.016485 0.052971 0.000919 0.040349 0.028210 0.001500 0.108574 0.705910 Mica 0.019614 0.001814 0.000000 0.062174 0.004164 0.000000 0.003883 0.165389 0.000384 0.241712 0.500866 Gt 0.000000 0.039425 0.000000 0.000000 0.298718 0.043101 0.054196 0.000000 0.002531 0.136711 0.425318 Fsp 0.095187 0.057658 0.000000 0.000984 0.000000 0.000000 0.000000 0.000000 0.000000 0.153829 0.692342 Bio 0.000000 0.000000 0.019419 0.066457 0.178363 0.000667 0.160526 0.113495 0.004126 0.114477 0.342469 St 0.000000 0.000000 0.003507 0.000000 0.143202 0.002190 0.040140 0.088172 0.002297 0.389844 0.330647 Ilm 0.000000 0.000000 0.334711 0.000000 0.582394 0.008201 0.008579 0.000000 0.066116 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -761652. -746415. -924097. -835985. -305715. -458397. -633120. -286407. -408187. -1625629. -880148. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 318 converged, 128 successes so far. Misfit function evaluations this try => 237 Misfit this try = 0.173635 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 8.639509E-07 Bayes score, PP * exp(-Misfit) = 7.262400E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 13697.8 923.681 0.942031 4.859409E-02 Final coordinates: 8183.63 875.114 0.776236 0.624611 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.173635 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.527 0.025947 0.003113 0.000000 0.071580 0.004998 0.000000 0.005151 0.289642 0.599569 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 0.9 0. 1. -0.5 0.1 Chi 9.4E-03 0. 0. 2.3E-03 7.6E-03 0. 1.4E-02 2.9E-04 3.1E-07 Composition Misfit: 3.635358E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.618 0.000000 0.040175 0.000000 0.000000 0.280211 0.051564 0.065298 0.136547 0.426205 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 2. -2. -1. 0.5 -0.2 Chi 0. 9.6E-03 0. 0. 6.2E-03 5.8E-03 1.7E-03 3.9E-04 5.6E-06 Composition Misfit: 2.369601E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.495 0.093933 0.060092 0.000000 0.001021 0.000000 0.000000 0.000000 0.155046 0.689908 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 0.1 0. 0. 0. 0.4 0.2 Chi 5.6E-05 1.2E-03 0. 1.1E-04 0. 0. 0. 2.2E-04 3.1E-05 Composition Misfit: 1.619616E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.088 0.000000 0.000000 0.022415 0.075307 0.182944 0.001015 0.200563 0.129604 0.388151 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.1 -1. 0.1 0.1 -2. 0.8 1. Chi 0. 0. 4.9E-05 9.3E-04 1.3E-05 1.6E-04 4.8E-03 8.8E-04 2.0E-03 Composition Misfit: 8.836310E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.849 0.000000 0.000000 0.004390 0.000000 0.145736 0.003182 0.055147 0.428098 0.363448 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.1 -4. 1. 1. Chi 0. 0. 2.0E-03 0. 1.5E-03 1.4E-04 1.9E-02 9.8E-04 1.4E-03 Composition Misfit: 2.482702E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.792 0.000000 0.000000 0.233556 0.000000 0.749669 0.009618 0.007156 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. 0.1 0.5 0. 0. Chi 0. 0. 0.1 0. 1.9E-02 1.5E-05 1.1E-03 0. 0. Composition Misfit: 7.830281E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.038 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.593 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023119 0.014628 0.006922 0.016335 0.052487 0.000911 0.039980 0.036032 0.002546 0.107582 0.699458 Mica 0.021647 0.002597 0.000000 0.059717 0.004170 0.000000 0.004297 0.165324 0.000411 0.241638 0.500199 Gt 0.000000 0.040064 0.000000 0.000000 0.279440 0.051422 0.065118 0.000000 0.002753 0.136171 0.425032 Fsp 0.093933 0.060092 0.000000 0.001021 0.000000 0.000000 0.000000 0.000000 0.000000 0.155046 0.689908 Bio 0.000000 0.000000 0.019786 0.066473 0.161484 0.000896 0.177036 0.113160 0.004146 0.114401 0.342619 St 0.000000 0.000000 0.003993 0.000000 0.132550 0.002894 0.050158 0.088151 0.002325 0.389365 0.330564 Ilm 0.000000 0.000000 0.206099 0.000000 0.661538 0.008487 0.006315 0.000000 0.117560 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -765827. -748226. -925872. -841007. -308844. -459998. -634033. -287367. -406006. -1628568. -881770. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Ilm Gt Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Ilm Gt Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Sp Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Sp Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 325 converged, 129 successes so far. Misfit function evaluations this try => 290 Misfit this try = 0.126296 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 8.242091E-07 Bayes score, PP * exp(-Misfit) = 7.264202E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 5564.65 977.545 0.706606 0.900057 Final coordinates: 7898.18 920.184 0.560666 0.523751 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.126296 Extraneous predicted phases: 7.919969E-8 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 0.020565 0.002672 0.000000 0.077018 0.006485 0.000000 0.005565 0.287295 0.600400 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.6 0.7 0. 1. -0.4 -0.1 Chi 5.1E-03 0. 0. 7.2E-04 3.4E-03 0. 1.1E-02 1.6E-04 2.7E-07 Composition Misfit: 2.342963E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.408 0.000000 0.026534 0.000000 0.000000 0.280976 0.061627 0.067159 0.137239 0.426465 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.8 0. 0. 2. -3. -1. 0.5 -0.2 Chi 0. 1.4E-03 0. 0. 6.0E-03 1.2E-02 2.3E-03 3.2E-04 7.7E-06 Composition Misfit: 2.208205E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.658 0.093999 0.058883 0.000000 0.001559 0.000000 0.000000 0.000000 0.154442 0.691117 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -0.1 0. 0. 0. 0.4 0.2 Chi 5.9E-05 9.0E-04 0. 2.6E-05 0. 0. 0. 2.7E-04 1.7E-05 Composition Misfit: 1.273141E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.468 0.000000 0.000000 0.024891 0.075942 0.196169 0.001552 0.179216 0.139136 0.383093 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.8 -3.7E-02 -0.7 0.1 2. Chi 0. 0. 5.0E-04 1.1E-03 7.0E-04 1.1E-05 5.3E-04 1.0E-05 2.8E-03 Composition Misfit: 5.624869E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.545 0.000000 0.000000 0.004521 0.000000 0.147062 0.004495 0.052681 0.427846 0.363395 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. -0.1 -4. 1. 1. Chi 0. 0. 1.7E-03 0. 1.7E-03 9.6E-05 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.283886E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.423 0.000000 0.000000 0.252899 0.000000 0.725144 0.013606 0.008351 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -4. -0.6 0.3 0. 0. Chi 0. 0. 3.7E-02 0. 1.2E-02 9.6E-04 3.3E-04 0. 0. Composition Misfit: 5.104700E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.761 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.735 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000022 -.000022 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023271 0.014725 0.006967 0.016442 0.052832 0.000917 0.040242 0.030412 0.001851 0.108288 0.704052 Mica 0.017160 0.002230 0.000000 0.064264 0.005411 0.000000 0.004643 0.165078 0.000521 0.239719 0.500974 Gt 0.000000 0.026469 0.000000 0.000000 0.280288 0.061476 0.066995 0.000000 0.002452 0.136902 0.425419 Fsp 0.093999 0.058883 0.000000 0.001559 0.000000 0.000000 0.000000 0.000000 0.000000 0.154442 0.691117 Bio 0.000000 0.000000 0.021994 0.067106 0.173344 0.001372 0.158363 0.112218 0.004139 0.122947 0.338518 St 0.000000 0.000000 0.004112 0.000000 0.133752 0.004088 0.047913 0.088135 0.002371 0.389124 0.330506 Ilm 0.000000 0.000000 0.225089 0.000000 0.645404 0.012110 0.007433 0.000000 0.109964 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777512. -755888. -932501. -851831. -314378. -464581. -638819. -292033. -409116. -1636256. -887231. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Bio F sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Bio F sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 328 converged, 130 successes so far. Misfit function evaluations this try => 189 Misfit this try = 0.113979 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.570099E-07 Bayes score, PP * exp(-Misfit) = 8.539173E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 7503.37 887.691 0.849776 0.371464 Final coordinates: 8674.41 926.919 0.563951 0.478089 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.113979 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.019 0.021533 0.003011 0.000000 0.075779 0.006981 0.000000 0.006121 0.286135 0.600440 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.8E-03 0. 0. 9.9E-04 2.5E-03 0. 9.0E-03 1.1E-04 3.2E-07 Composition Misfit: 2.141986E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.266 0.000000 0.030778 0.000000 0.000000 0.298176 0.037344 0.070944 0.136551 0.426207 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.3 -2. 0.5 -0.2 Chi 0. 3.4E-03 0. 0. 1.9E-03 2.6E-04 3.7E-03 3.9E-04 5.6E-06 Composition Misfit: 9.618049E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.577 0.094616 0.057731 0.000000 0.001519 0.000000 0.000000 0.000000 0.153866 0.692269 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.7E-02 0. 0. 0. 0.5 0.1 Chi 9.3E-05 6.5E-04 0. 1.7E-05 0. 0. 0. 3.2E-04 7.2E-06 Composition Misfit: 1.090635E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.553 0.000000 0.000000 0.024805 0.075730 0.196128 0.000945 0.181495 0.135957 0.384940 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.8 0.1 -0.8 0.3 2. Chi 0. 0. 4.8E-04 1.0E-03 6.9E-04 2.4E-04 7.9E-04 1.4E-04 2.5E-03 Composition Misfit: 5.859267E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.878 0.000000 0.000000 0.004700 0.000000 0.147630 0.002634 0.054053 0.427628 0.363355 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.9E-03 5.5E-04 1.8E-02 1.0E-03 1.4E-03 Composition Misfit: 2.428448E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.460 0.000000 0.000000 0.252821 0.000000 0.730251 0.008146 0.008782 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.3 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.4E-02 4.2E-04 1.7E-04 0. 0. Composition Misfit: 5.170711E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.993 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.253 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023333 0.014764 0.006985 0.016486 0.052971 0.000919 0.040349 0.027834 0.001867 0.108575 0.705917 Mica 0.017970 0.002513 0.000000 0.063240 0.005826 0.000000 0.005108 0.164933 0.000533 0.238789 0.501088 Gt 0.000000 0.030693 0.000000 0.000000 0.297356 0.037241 0.070749 0.000000 0.002751 0.136175 0.425034 Fsp 0.094616 0.057731 0.000000 0.001519 0.000000 0.000000 0.000000 0.000000 0.000000 0.153866 0.692269 Bio 0.000000 0.000000 0.021927 0.066943 0.173371 0.000835 0.160435 0.111960 0.004073 0.120182 0.340274 St 0.000000 0.000000 0.004275 0.000000 0.134267 0.002396 0.049160 0.088124 0.002394 0.388920 0.330465 Ilm 0.000000 0.000000 0.225012 0.000000 0.649927 0.007250 0.007816 0.000000 0.109995 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775602. -754492. -931825. -849846. -314094. -468527. -638368. -291423. -409004. -1635654. -886183. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 331 converged, 131 successes so far. Misfit function evaluations this try => 159 Misfit this try = 0.208632 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.086220E-06 Bayes score, PP * exp(-Misfit) = 8.816786E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 14046.2 855.834 0.696991 0.321149 Final coordinates: 9710.79 927.583 0.844426 0.561512 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.208631 Extraneous predicted phases: 4.278265E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.781 0.027290 0.004313 0.000000 0.069363 0.006447 0.000000 0.006714 0.286689 0.599183 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -3. 0. 0. 1. 0.7 0. 1. -0.4 0.1 Chi 1.1E-02 0. 0. 3.3E-03 3.4E-03 0. 7.0E-03 1.3E-04 1.1E-06 Composition Misfit: 2.862970E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.681 0.000000 0.040375 0.000000 0.000000 0.294386 0.020957 0.083837 0.134868 0.425576 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 2. 1. -3. 0.6 -0.1 Chi 0. 9.7E-03 0. 0. 2.6E-03 8.4E-03 1.0E-02 6.0E-04 2.0E-06 Composition Misfit: 3.139782E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.855 0.095399 0.056674 0.000000 0.001264 0.000000 0.000000 0.000000 0.153337 0.693326 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.5 0. 2.7E-02 0. 0. 0. 0.5 0.1 Chi 1.5E-04 4.6E-04 0. 7.0E-06 0. 0. 0. 3.7E-04 2.0E-06 Composition Misfit: 9.841833E-4 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.288 0.000000 0.000000 0.022971 0.075241 0.174967 0.000503 0.209179 0.128615 0.388524 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.2 -1. 0.6 0.3 -3. 0.8 1. Chi 0. 0. 1.1E-04 9.1E-04 5.2E-04 1.7E-03 7.5E-03 1.1E-03 1.9E-03 Composition Misfit: 1.374941E-2 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.437 0.000000 0.000000 0.004663 0.000000 0.137514 0.001404 0.066017 0.427168 0.363234 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.5 0.5 -5. 1. 1. Chi 0. 0. 1.5E-03 0. 3.0E-04 4.2E-03 2.8E-02 1.1E-03 1.5E-03 Composition Misfit: 3.671655E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.909 0.000000 0.000000 0.227724 0.000000 0.759577 0.003960 0.008740 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -6. 1. 0.2 0. 0. Chi 0. 0. 0.1 0. 2.2E-02 9.2E-03 1.8E-04 0. 0. Composition Misfit: 9.715354E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.191 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.855 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000015 -.000015 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023199 0.014679 0.006945 0.016391 0.052667 0.000914 0.040117 0.032503 0.002780 0.107951 0.701856 Mica 0.022775 0.003600 0.000000 0.057887 0.005380 0.000000 0.005604 0.164924 0.000527 0.239256 0.500048 Gt 0.000000 0.040235 0.000000 0.000000 0.293360 0.020884 0.083545 0.000000 0.003483 0.134399 0.424093 Fsp 0.095399 0.056674 0.000000 0.001264 0.000000 0.000000 0.000000 0.000000 0.000000 0.153337 0.693326 Bio 0.000000 0.000000 0.020287 0.066451 0.154526 0.000444 0.184741 0.112614 0.004216 0.113589 0.343132 St 0.000000 0.000000 0.004240 0.000000 0.125051 0.001277 0.060034 0.088084 0.002548 0.388453 0.330314 Ilm 0.000000 0.000000 0.200437 0.000000 0.668560 0.003486 0.007692 0.000000 0.119825 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -771118. -751346. -930174. -846522. -313469. -472125. -636189. -289459. -403738. -1633512. -883885. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 332 converged, 132 successes so far. Misfit function evaluations this try => 286 Misfit this try = 0.132682 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.049653E-06 Bayes score, PP * exp(-Misfit) = 9.192267E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 12765.7 860.055 0.897383 8.355265E-02 Final coordinates: 8449.16 901.864 0.631340 0.494213 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.132682 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.747 0.022728 0.002860 0.000000 0.074763 0.006220 0.000000 0.005715 0.287410 0.600303 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.8 0. 1. -0.4 -3.9E-02 Chi 6.7E-03 0. 0. 1.3E-03 3.9E-03 0. 1.1E-02 1.7E-04 1.5E-07 Composition Misfit: 2.566289E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.181 0.000000 0.034237 0.000000 0.000000 0.296090 0.039896 0.066919 0.136624 0.426234 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -0.6 -1. 0.5 -0.2 Chi 0. 5.5E-03 0. 0. 2.3E-03 8.0E-04 2.2E-03 3.8E-04 5.8E-06 Composition Misfit: 1.110938E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.386 0.094715 0.057980 0.000000 0.001295 0.000000 0.000000 0.000000 0.153990 0.692020 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 1.8E-02 0. 0. 0. 0.5 0.1 Chi 9.9E-05 7.0E-04 0. 3.0E-06 0. 0. 0. 3.1E-04 8.9E-06 Composition Misfit: 1.123853E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.037 0.000000 0.000000 0.023796 0.075557 0.194561 0.000898 0.185563 0.133348 0.386278 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. -0.7 0.2 -1. 0.5 2. Chi 0. 0. 2.5E-04 9.8E-04 5.2E-04 3.1E-04 1.4E-03 3.6E-04 2.3E-03 Composition Misfit: 6.091323E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.090 0.000000 0.000000 0.004488 0.000000 0.149111 0.002617 0.052499 0.427883 0.363401 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.8E-03 0. 2.2E-03 5.7E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.365950E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.569 0.000000 0.000000 0.243042 0.000000 0.741346 0.007946 0.007666 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. 0.3 0.4 0. 0. Chi 0. 0. 4.7E-02 0. 1.7E-02 5.3E-04 7.1E-04 0. 0. Composition Misfit: 6.503484E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.777 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.213 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023306 0.014746 0.006977 0.016466 0.052909 0.000918 0.040302 0.028740 0.002088 0.108449 0.705098 Mica 0.018965 0.002387 0.000000 0.062385 0.005190 0.000000 0.004769 0.165087 0.000480 0.239825 0.500913 Gt 0.000000 0.034144 0.000000 0.000000 0.295285 0.039788 0.066737 0.000000 0.002720 0.136253 0.425075 Fsp 0.094715 0.057980 0.000000 0.001295 0.000000 0.000000 0.000000 0.000000 0.000000 0.153990 0.692020 Bio 0.000000 0.000000 0.021022 0.066749 0.171881 0.000793 0.163932 0.112476 0.004095 0.117803 0.341249 St 0.000000 0.000000 0.004082 0.000000 0.135615 0.002381 0.047748 0.088137 0.002368 0.389158 0.330512 Ilm 0.000000 0.000000 0.215371 0.000000 0.656942 0.007041 0.006793 0.000000 0.113851 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -770718. -751538. -929022. -845170. -311355. -464997. -636402. -289539. -408150. -1632156. -883994. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 334 converged, 133 successes so far. Misfit function evaluations this try => 262 Misfit this try = 6.220035E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.712437E-07 Bayes score, PP * exp(-Misfit) = 9.126725E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 7613.98 832.207 0.198621 0.460277 Final coordinates: 8754.90 927.085 0.418895 0.482842 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.220035E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.004 0.021536 0.003006 0.000000 0.075770 0.007025 0.000000 0.006138 0.286019 0.600506 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.8E-03 0. 0. 1.0E-03 2.4E-03 0. 8.9E-03 1.1E-04 4.3E-07 Composition Misfit: 2.128049E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.502 0.000000 0.031094 0.000000 0.000000 0.302378 0.033154 0.070494 0.136639 0.426240 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. 0.1 -2. 0.5 -0.2 Chi 0. 3.6E-03 0. 0. 1.3E-03 3.6E-05 3.5E-03 3.8E-04 5.9E-06 Composition Misfit: 8.757056E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.544 0.094779 0.057400 0.000000 0.001521 0.000000 0.000000 0.000000 0.153700 0.692600 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. -4.7E-02 0. 0. 0. 0.5 0.1 Chi 1.0E-04 5.9E-04 0. 1.8E-05 0. 0. 0. 3.4E-04 5.2E-06 Composition Misfit: 1.049983E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.576 0.000000 0.000000 0.024979 0.075721 0.197894 0.000836 0.179544 0.135818 0.385208 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.2 -0.7 0.3 2. Chi 0. 0. 5.2E-04 1.0E-03 9.1E-04 4.1E-04 5.6E-04 1.5E-04 2.5E-03 Composition Misfit: 6.025091E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.202 0.000000 0.000000 0.004791 0.000000 0.148561 0.002314 0.053241 0.427710 0.363383 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.3E-03 0. 2.1E-03 1.0E-03 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.413730E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.322 0.000000 0.000000 0.351736 0.000000 0.627328 0.008261 0.012675 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.1 0. 0.1 0.3 -0.4 0. 0. Chi 0. 0. 8.6E-06 0. 1.1E-05 3.7E-04 5.6E-04 0. 0. Composition Misfit: 9.504388E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.657 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.193 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023338 0.014767 0.006987 0.016489 0.052982 0.000919 0.040357 0.028117 0.001387 0.108597 0.706060 Mica 0.017973 0.002509 0.000000 0.063234 0.005863 0.000000 0.005123 0.164923 0.000522 0.238698 0.501155 Gt 0.000000 0.031010 0.000000 0.000000 0.301558 0.033064 0.070303 0.000000 0.002713 0.136268 0.425083 Fsp 0.094779 0.057400 0.000000 0.001521 0.000000 0.000000 0.000000 0.000000 0.000000 0.153700 0.692600 Bio 0.000000 0.000000 0.022086 0.066952 0.174976 0.000739 0.158752 0.111818 0.003989 0.120089 0.340598 St 0.000000 0.000000 0.004358 0.000000 0.135119 0.002105 0.048423 0.088135 0.002345 0.389011 0.330505 Ilm 0.000000 0.000000 0.327461 0.000000 0.584032 0.007691 0.011800 0.000000 0.069016 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775259. -754305. -931580. -849430. -313930. -469385. -638351. -291345. -409922. -1635506. -886017. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 336 converged, 134 successes so far. Misfit function evaluations this try => 182 Misfit this try = 6.120136E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.432570E-07 Bayes score, PP * exp(-Misfit) = 8.872594E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 10694.5 911.591 0.903352 0.137943 Final coordinates: 8633.17 927.434 0.420332 0.497228 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.120136E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.022 0.021267 0.002966 0.000000 0.076071 0.006985 0.000000 0.006068 0.286145 0.600499 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.3E-04 2.5E-03 0. 9.2E-03 1.1E-04 4.1E-07 Composition Misfit: 2.130332E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.229 0.000000 0.030291 0.000000 0.000000 0.299412 0.037247 0.070044 0.136732 0.426274 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.3 -1. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 1.7E-03 2.4E-04 3.3E-03 3.7E-04 6.1E-06 Composition Misfit: 8.762545E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.571 0.094563 0.057793 0.000000 0.001540 0.000000 0.000000 0.000000 0.153897 0.692207 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 9.0E-05 6.6E-04 0. 2.2E-05 0. 0. 0. 3.2E-04 7.6E-06 Composition Misfit: 1.101993E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.528 0.000000 0.000000 0.025052 0.075768 0.197990 0.000945 0.178923 0.136519 0.384804 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.4E-04 1.0E-03 9.2E-04 2.4E-04 4.9E-04 1.1E-04 2.5E-03 Composition Misfit: 5.855155E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.048 0.000000 0.000000 0.004775 0.000000 0.148352 0.002631 0.053123 0.427732 0.363387 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 5.5E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.356430E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.313 0.000000 0.000000 0.351289 0.000000 0.626700 0.009374 0.012637 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.1 0. 0.2 0.1 -0.4 0. 0. Chi 0. 0. 4.7E-06 0. 1.7E-05 4.2E-05 5.5E-04 0. 0. Composition Misfit: 6.140431E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.956 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.333 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023318 0.014754 0.006981 0.016475 0.052938 0.000919 0.040323 0.028930 0.001391 0.108506 0.705466 Mica 0.017748 0.002475 0.000000 0.063484 0.005829 0.000000 0.005064 0.164938 0.000524 0.238799 0.501139 Gt 0.000000 0.030210 0.000000 0.000000 0.298612 0.037147 0.069857 0.000000 0.002673 0.136367 0.425135 Fsp 0.094563 0.057793 0.000000 0.001540 0.000000 0.000000 0.000000 0.000000 0.000000 0.153897 0.692207 Bio 0.000000 0.000000 0.022150 0.066991 0.175055 0.000836 0.158197 0.111833 0.004002 0.120705 0.340230 St 0.000000 0.000000 0.004343 0.000000 0.134929 0.002393 0.048316 0.088136 0.002342 0.389032 0.330509 Ilm 0.000000 0.000000 0.326977 0.000000 0.583327 0.008725 0.011762 0.000000 0.069209 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775912. -754692. -931865. -850061. -314148. -468654. -638552. -291565. -409994. -1635826. -886334. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 337 converged, 135 successes so far. Misfit function evaluations this try => 172 Misfit this try = 6.311983E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.544474E-07 Bayes score, PP * exp(-Misfit) = 8.960648E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 10576.3 981.310 0.185054 0.251040 Final coordinates: 8676.05 927.199 0.437573 0.529586 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.287479E-2 Extraneous predicted phases: 2.450413E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.718 0.021505 0.003035 0.000000 0.075795 0.006953 0.000000 0.006121 0.286159 0.600430 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.8E-03 0. 0. 9.9E-04 2.5E-03 0. 9.0E-03 1.1E-04 3.1E-07 Composition Misfit: 2.146254E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.180 0.000000 0.030871 0.000000 0.000000 0.298049 0.037350 0.070850 0.136640 0.426240 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.3 -2. 0.5 -0.2 Chi 0. 3.5E-03 0. 0. 1.9E-03 2.6E-04 3.6E-03 3.8E-04 5.9E-06 Composition Misfit: 9.644295E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.415 0.094475 0.058016 0.000000 0.001518 0.000000 0.000000 0.000000 0.154008 0.691984 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.6E-02 0. 0. 0. 0.5 0.1 Chi 8.4E-05 7.1E-04 0. 1.7E-05 0. 0. 0. 3.1E-04 9.2E-06 Composition Misfit: 1.129027E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.932 0.000000 0.000000 0.024934 0.075738 0.196150 0.000944 0.181170 0.136071 0.384993 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.8 0.1 -0.8 0.3 2. Chi 0. 0. 5.1E-04 1.0E-03 7.0E-04 2.4E-04 7.5E-04 1.3E-04 2.5E-03 Composition Misfit: 5.840939E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.932 0.000000 0.000000 0.004773 0.000000 0.147564 0.002628 0.053982 0.427679 0.363374 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 1.8E-03 5.6E-04 1.8E-02 1.0E-03 1.4E-03 Composition Misfit: 2.410957E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.343 0.000000 0.000000 0.344093 0.000000 0.634039 0.009331 0.012537 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.3 0. -0.2 0.1 -0.4 0. 0. Chi 0. 0. 1.0E-04 0. 2.6E-05 4.8E-05 5.1E-04 0. 0. Composition Misfit: 6.884256E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.067 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.364 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.049 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000023 -.000023 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023273 0.014726 0.006967 0.016443 0.052835 0.000917 0.040245 0.030753 0.001445 0.108296 0.704100 Mica 0.017947 0.002533 0.000000 0.063254 0.005802 0.000000 0.005109 0.164936 0.000526 0.238811 0.501082 Gt 0.000000 0.030787 0.000000 0.000000 0.297240 0.037249 0.070658 0.000000 0.002712 0.136270 0.425084 Fsp 0.094475 0.058016 0.000000 0.001518 0.000000 0.000000 0.000000 0.000000 0.000000 0.154008 0.691984 Bio 0.000000 0.000000 0.022044 0.066960 0.173417 0.000835 0.160172 0.111876 0.004024 0.120300 0.340372 St 0.000000 0.000000 0.004341 0.000000 0.134211 0.002391 0.049097 0.088131 0.002359 0.388979 0.330492 Ilm 0.000000 0.000000 0.319210 0.000000 0.588188 0.008656 0.011630 0.000000 0.072316 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775689. -754481. -931746. -849913. -314124. -468569. -638398. -291437. -409483. -1635696. -886210. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 340 converged, 136 successes so far. Misfit function evaluations this try => 426 Misfit this try = 0.435890 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 8.145544E-07 Bayes score, PP * exp(-Misfit) = 5.267632E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 5540.86 985.460 0.748580 0.911502 Final coordinates: 7753.46 914.649 0.638088 0.964921 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.148332 Extraneous predicted phases: 0.287558 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.022 0.021486 0.002823 0.000000 0.076071 0.005999 0.000000 0.005515 0.288009 0.600096 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.8 0. 1. -0.4 -1.2E-02 Chi 5.8E-03 0. 0. 9.3E-04 4.4E-03 0. 1.2E-02 2.0E-04 1.5E-08 Composition Misfit: 2.583400E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 0.000000 0.027093 0.000000 0.000000 0.267122 0.073033 0.068954 0.137308 0.426490 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.8 0. 0. 3. -4. -1. 0.5 -0.2 Chi 0. 1.6E-03 0. 0. 1.1E-02 2.1E-02 2.9E-03 3.1E-04 7.9E-06 Composition Misfit: 3.664652E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.597 0.093432 0.060231 0.000000 0.001452 0.000000 0.000000 0.000000 0.155115 0.689769 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.1 -0.8 0. -2.7E-02 0. 0. 0. 0.4 0.2 Chi 3.4E-05 1.2E-03 0. 6.2E-06 0. 0. 0. 2.2E-04 3.2E-05 Composition Misfit: 1.526105E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.538 0.000000 0.000000 0.024487 0.075888 0.187041 0.001799 0.189046 0.138315 0.383425 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.2 -0.1 -1. 0.1 2. Chi 0. 0. 4.0E-04 1.1E-03 3.5E-05 7.8E-05 2.0E-03 2.9E-05 2.8E-03 Composition Misfit: 6.369018E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.947 0.000000 0.000000 0.004562 0.000000 0.142568 0.005360 0.056267 0.427845 0.363398 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.8 -0.3 -4. 1. 1. Chi 0. 0. 1.7E-03 0. 9.3E-04 4.3E-04 2.0E-02 1.0E-03 1.4E-03 Composition Misfit: 2.524571E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.543 0.000000 0.000000 0.251987 0.000000 0.723104 0.016238 0.008670 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -4. -1. 0.2 0. 0. Chi 0. 0. 3.8E-02 0. 1.2E-02 2.4E-03 2.0E-04 0. 0. Composition Misfit: 5.271094E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.295 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.374 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 1.682 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000019 -.000019 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022684 0.014353 0.006791 0.016027 0.051499 0.000894 0.039227 0.054616 0.002054 0.105557 0.686296 Mica 0.017927 0.002356 0.000000 0.063470 0.005005 0.000000 0.004602 0.165149 0.000502 0.240300 0.500689 Gt 0.000000 0.027028 0.000000 0.000000 0.266475 0.072856 0.068787 0.000000 0.002422 0.136975 0.425457 Fsp 0.093432 0.060231 0.000000 0.001452 0.000000 0.000000 0.000000 0.000000 0.000000 0.155115 0.689769 Bio 0.000000 0.000000 0.021631 0.067037 0.165227 0.001589 0.166998 0.112443 0.004185 0.122184 0.338707 St 0.000000 0.000000 0.004149 0.000000 0.129666 0.004875 0.051175 0.088136 0.002361 0.389127 0.330512 Ilm 0.000000 0.000000 0.224187 0.000000 0.643327 0.014447 0.007714 0.000000 0.110325 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776964. -755354. -931847. -851740. -314226. -462757. -638181. -291562. -407687. -1635687. -886964. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 341 converged, 137 successes so far. Misfit function evaluations this try => 176 Misfit this try = 0.391218 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.745780E-07 Bayes score, PP * exp(-Misfit) = 6.590418E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 13940.1 819.890 0.812452 0.553739 Final coordinates: 8446.48 919.266 0.726715 0.954441 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.153525 Extraneous predicted phases: 0.237692 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.527 0.022838 0.003311 0.000000 0.074397 0.006282 0.000000 0.006062 0.287228 0.599882 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.8 0. 1. -0.4 1.5E-02 Chi 6.8E-03 0. 0. 1.4E-03 3.8E-03 0. 9.2E-03 1.6E-04 2.3E-08 Composition Misfit: 2.467014E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.322 0.000000 0.032214 0.000000 0.000000 0.276576 0.054679 0.073917 0.136446 0.426167 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 3. -2. -2. 0.5 -0.2 Chi 0. 4.2E-03 0. 0. 7.4E-03 7.6E-03 4.9E-03 4.0E-04 5.3E-06 Composition Misfit: 2.464629E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.268 0.093477 0.060299 0.000000 0.001373 0.000000 0.000000 0.000000 0.155150 0.689701 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.1 -0.8 0. -4.5E-03 0. 0. 0. 0.4 0.2 Chi 3.6E-05 1.3E-03 0. 1.8E-07 0. 0. 0. 2.1E-04 3.3E-05 Composition Misfit: 1.538506E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.447 0.000000 0.000000 0.023842 0.075647 0.182666 0.001335 0.196556 0.134704 0.385250 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. 0.1 2.5E-02 -2. 0.4 2. Chi 0. 0. 2.6E-04 1.0E-03 1.8E-05 5.9E-06 3.7E-03 2.3E-04 2.4E-03 Composition Misfit: 7.680852E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.978 0.000000 0.000000 0.004553 0.000000 0.140925 0.003885 0.059712 0.427592 0.363333 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -0.7 -9.8E-03 -5. 1. 1. Chi 0. 0. 1.7E-03 0. 6.9E-04 5.5E-07 2.3E-02 1.0E-03 1.5E-03 Composition Misfit: 2.752860E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.679 0.000000 0.000000 0.239867 0.000000 0.740463 0.011218 0.008453 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. -0.2 0.2 0. 0. Chi 0. 0. 0.1 0. 1.6E-02 1.3E-04 2.8E-04 0. 0. Composition Misfit: 6.746088E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.000 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.275 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 1.504 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000017 -.000017 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022691 0.014358 0.006793 0.016032 0.051515 0.000894 0.039240 0.054039 0.002340 0.105590 0.686508 Mica 0.019057 0.002763 0.000000 0.062080 0.005242 0.000000 0.005058 0.165037 0.000520 0.239676 0.500568 Gt 0.000000 0.032124 0.000000 0.000000 0.275802 0.054526 0.073711 0.000000 0.002797 0.136065 0.424975 Fsp 0.093477 0.060299 0.000000 0.001373 0.000000 0.000000 0.000000 0.000000 0.000000 0.155150 0.689701 Bio 0.000000 0.000000 0.021057 0.066812 0.161332 0.001180 0.173599 0.112566 0.004228 0.118971 0.340255 St 0.000000 0.000000 0.004141 0.000000 0.128163 0.003533 0.054304 0.088115 0.002443 0.388870 0.330430 Ilm 0.000000 0.000000 0.212259 0.000000 0.655238 0.009926 0.007480 0.000000 0.115096 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775033. -753724. -931336. -849869. -313965. -464884. -637469. -290801. -406083. -1634922. -885874. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 344 converged, 138 successes so far. Misfit function evaluations this try => 162 Misfit this try = 6.377643E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.019516E-06 Bayes score, PP * exp(-Misfit) = 9.565246E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 6906.70 900.955 0.367492 0.551631 Final coordinates: 8333.29 900.115 0.437541 0.491227 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.377643E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 0.022000 0.002681 0.000000 0.075583 0.006295 0.000000 0.005604 0.287356 0.600480 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.4 -0.1 Chi 6.2E-03 0. 0. 1.0E-03 3.8E-03 0. 1.1E-02 1.6E-04 3.8E-07 Composition Misfit: 2.505762E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.219 0.000000 0.033256 0.000000 0.000000 0.299738 0.039204 0.064659 0.136831 0.426312 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -0.5 -0.9 0.5 -0.2 Chi 0. 4.9E-03 0. 0. 1.6E-03 6.3E-04 1.5E-03 3.6E-04 6.4E-06 Composition Misfit: 8.994325E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.531 0.094800 0.057752 0.000000 0.001324 0.000000 0.000000 0.000000 0.153876 0.692248 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 9.7E-03 0. 0. 0. 0.5 0.1 Chi 1.0E-04 6.6E-04 0. 8.4E-07 0. 0. 0. 3.2E-04 7.3E-06 Composition Misfit: 1.089432E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.642 0.000000 0.000000 0.023980 0.075613 0.199277 0.000880 0.180139 0.134188 0.385924 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. -1. 0.2 -0.7 0.4 2. Chi 0. 0. 2.8E-04 9.9E-04 1.1E-03 3.4E-04 6.3E-04 2.8E-04 2.3E-03 Composition Misfit: 5.957088E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.404 0.000000 0.000000 0.004442 0.000000 0.151423 0.002558 0.050141 0.428007 0.363429 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -3. 1. 1. Chi 0. 0. 1.9E-03 0. 2.7E-03 6.4E-04 1.5E-02 9.9E-04 1.4E-03 Composition Misfit: 2.246026E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.361 0.000000 0.000000 0.349367 0.000000 0.630301 0.009119 0.011213 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 3.5E-02 0. -1.4E-02 0.1 -0.2 0. 0. Chi 0. 0. 1.1E-06 0. 1.4E-07 8.5E-05 1.3E-04 0. 0. Composition Misfit: 2.176982E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.616 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.226 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023325 0.014758 0.006983 0.016480 0.052953 0.000919 0.040335 0.028589 0.001448 0.108538 0.705672 Mica 0.018358 0.002237 0.000000 0.063069 0.005253 0.000000 0.004676 0.165091 0.000476 0.239779 0.501060 Gt 0.000000 0.033169 0.000000 0.000000 0.298950 0.039101 0.064489 0.000000 0.002630 0.136471 0.425190 Fsp 0.094800 0.057752 0.000000 0.001324 0.000000 0.000000 0.000000 0.000000 0.000000 0.153876 0.692248 Bio 0.000000 0.000000 0.021187 0.066805 0.176066 0.000777 0.159157 0.112424 0.004054 0.118558 0.340972 St 0.000000 0.000000 0.004040 0.000000 0.137722 0.002326 0.045604 0.088145 0.002340 0.389279 0.330544 Ilm 0.000000 0.000000 0.324897 0.000000 0.586154 0.008480 0.010428 0.000000 0.070041 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -770797. -751701. -929075. -845016. -311144. -465005. -636585. -289673. -409134. -1632132. -884073. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 345 converged, 139 successes so far. Misfit function evaluations this try => 220 Misfit this try = 6.151586E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.490936E-07 Bayes score, PP * exp(-Misfit) = 8.924688E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 10801.9 942.776 0.731649 0.654489 Final coordinates: 8508.03 924.056 0.424020 0.503950 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.151586E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.002 0.021172 0.002896 0.000000 0.076222 0.006870 0.000000 0.005958 0.286388 0.600494 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.5E-03 0. 0. 8.9E-04 2.7E-03 0. 9.7E-03 1.2E-04 4.1E-07 Composition Misfit: 2.176768E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.070 0.000000 0.030046 0.000000 0.000000 0.297331 0.040454 0.069025 0.136832 0.426312 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.7 -1. 0.5 -0.2 Chi 0. 3.0E-03 0. 0. 2.0E-03 9.5E-04 2.9E-03 3.6E-04 6.4E-06 Composition Misfit: 9.287185E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.587 0.094470 0.058010 0.000000 0.001525 0.000000 0.000000 0.000000 0.154005 0.691990 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.8E-02 0. 0. 0. 0.5 0.1 Chi 8.4E-05 7.1E-04 0. 1.8E-05 0. 0. 0. 3.1E-04 9.1E-06 Composition Misfit: 1.129216E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.538 0.000000 0.000000 0.024971 0.075781 0.198194 0.001015 0.178649 0.136718 0.384671 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.2E-04 1.0E-03 9.5E-04 1.7E-04 4.7E-04 9.5E-05 2.5E-03 Composition Misfit: 5.769814E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.425 0.000000 0.000000 0.004713 0.000000 0.148632 0.002846 0.052637 0.427778 0.363394 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 2.1E-03 3.5E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.310501E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.313 0.000000 0.000000 0.349414 0.000000 0.628128 0.010101 0.012356 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 3.2E-02 0. 0.1 -1.6E-02 -0.4 0. 0. Chi 0. 0. 9.8E-07 0. 5.6E-06 1.0E-06 4.5E-04 0. 0. Composition Misfit: 4.569481E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.663 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.402 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023309 0.014748 0.006978 0.016468 0.052916 0.000918 0.040307 0.029309 0.001402 0.108462 0.705181 Mica 0.017668 0.002417 0.000000 0.063608 0.005733 0.000000 0.004972 0.164969 0.000519 0.238995 0.501120 Gt 0.000000 0.029967 0.000000 0.000000 0.296549 0.040348 0.068844 0.000000 0.002629 0.136472 0.425191 Fsp 0.094470 0.058010 0.000000 0.001525 0.000000 0.000000 0.000000 0.000000 0.000000 0.154005 0.691990 Bio 0.000000 0.000000 0.022076 0.066996 0.175218 0.000897 0.157939 0.111916 0.004013 0.120869 0.340077 St 0.000000 0.000000 0.004287 0.000000 0.135184 0.002588 0.047875 0.088137 0.002343 0.389073 0.330514 Ilm 0.000000 0.000000 0.324948 0.000000 0.584146 0.009393 0.011491 0.000000 0.070021 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775683. -754575. -931698. -849832. -313900. -467705. -638428. -291465. -409889. -1635555. -886253. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 348 converged, 140 successes so far. Misfit function evaluations this try => 342 Misfit this try = 0.116409 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.870250E-07 Bayes score, PP * exp(-Misfit) = 8.785621E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 13985.1 854.451 0.134523 0.356533 Final coordinates: 8653.19 923.400 0.572685 0.478784 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.116409 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.103 0.021708 0.002991 0.000000 0.075628 0.006877 0.000000 0.006071 0.286299 0.600426 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.9E-03 0. 0. 1.0E-03 2.7E-03 0. 9.2E-03 1.2E-04 3.0E-07 Composition Misfit: 2.193872E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.275 0.000000 0.031280 0.000000 0.000000 0.298182 0.037364 0.070403 0.136561 0.426210 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.3 -1. 0.5 -0.2 Chi 0. 3.7E-03 0. 0. 1.9E-03 2.6E-04 3.5E-03 3.9E-04 5.7E-06 Composition Misfit: 9.685392E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.552 0.094649 0.057731 0.000000 0.001486 0.000000 0.000000 0.000000 0.153865 0.692269 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -3.7E-02 0. 0. 0. 0.5 0.1 Chi 9.5E-05 6.5E-04 0. 1.1E-05 0. 0. 0. 3.2E-04 7.2E-06 Composition Misfit: 1.086577E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.498 0.000000 0.000000 0.024664 0.075704 0.195958 0.000929 0.182041 0.135553 0.385151 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.8 0.1 -0.9 0.3 2. Chi 0. 0. 4.4E-04 1.0E-03 6.7E-04 2.6E-04 8.6E-04 1.7E-04 2.5E-03 Composition Misfit: 5.882619E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.828 0.000000 0.000000 0.004672 0.000000 0.147879 0.002603 0.053826 0.427661 0.363361 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.9E-03 5.9E-04 1.8E-02 1.0E-03 1.4E-03 Composition Misfit: 2.422432E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.475 0.000000 0.000000 0.251389 0.000000 0.731964 0.008030 0.008617 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.3 0.2 0. 0. Chi 0. 0. 3.9E-02 0. 1.4E-02 4.8E-04 2.2E-04 0. 0. Composition Misfit: 5.359116E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.033 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.236 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023331 0.014762 0.006985 0.016484 0.052967 0.000919 0.040346 0.027873 0.001896 0.108568 0.705868 Mica 0.018116 0.002496 0.000000 0.063113 0.005739 0.000000 0.005067 0.164953 0.000525 0.238923 0.501068 Gt 0.000000 0.031194 0.000000 0.000000 0.297363 0.037262 0.070210 0.000000 0.002747 0.136185 0.425039 Fsp 0.094649 0.057731 0.000000 0.001486 0.000000 0.000000 0.000000 0.000000 0.000000 0.153865 0.692269 Bio 0.000000 0.000000 0.021801 0.066914 0.173207 0.000821 0.160905 0.112028 0.004075 0.119815 0.340434 St 0.000000 0.000000 0.004249 0.000000 0.134493 0.002367 0.048954 0.088125 0.002391 0.388951 0.330471 Ilm 0.000000 0.000000 0.223595 0.000000 0.651037 0.007142 0.007664 0.000000 0.110562 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774864. -754047. -931408. -849136. -313691. -468085. -638076. -291140. -408878. -1635135. -885849. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 349 converged, 141 successes so far. Misfit function evaluations this try => 156 Misfit this try = 0.108905 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 8.398730E-08 Bayes score, PP * exp(-Misfit) = 7.532112E-08 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 6349.22 818.494 0.629372 5.763447E-02 Final coordinates: 6875.86 801.566 0.469925 0.491500 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.108905 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.080 0.024409 0.001675 0.000000 0.074072 0.003840 0.000000 0.003711 0.291979 0.600314 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 1. 0. 1. -0.7 -4.0E-02 Chi 8.1E-03 0. 0. 1.5E-03 1.4E-02 0. 2.6E-02 4.5E-04 1.6E-07 Composition Misfit: 5.167303E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.920 0.000000 0.043932 0.000000 0.000000 0.292631 0.054705 0.044687 0.137488 0.426558 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 2. -2. 1. 0.5 -0.2 Chi 0. 1.2E-02 0. 0. 2.9E-03 7.7E-03 2.3E-03 2.9E-04 8.5E-06 Composition Misfit: 2.561655E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.431 0.095224 0.058062 0.000000 0.000745 0.000000 0.000000 0.000000 0.154031 0.691938 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.3E-04 7.2E-04 0. 5.0E-04 0. 0. 0. 3.1E-04 9.5E-06 Composition Misfit: 1.674364E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.822 0.000000 0.000000 0.020218 0.075095 0.204943 0.000744 0.182944 0.126423 0.389634 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 0.1 -1. -1. 0.2 -0.9 1. 1. Chi 0. 0. 6.5E-05 8.8E-04 2.0E-03 6.2E-04 9.9E-04 1.5E-03 1.8E-03 Composition Misfit: 7.904271E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.352 0.000000 0.000000 0.003283 0.000000 0.162901 0.002627 0.038276 0.429263 0.363650 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. 0.3 -2. 1. 1. Chi 0. 0. 5.0E-03 0. 6.2E-03 5.6E-04 6.2E-03 8.7E-04 1.4E-03 Composition Misfit: 2.021854E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.500 0.000000 0.000000 0.365548 0.000000 0.617174 0.009846 0.007431 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.9 0. 0.6 2.4E-02 0.4 0. 0. Chi 0. 0. 6.6E-04 0. 2.7E-04 2.4E-06 8.9E-04 0. 0. Composition Misfit: 1.818297E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.894 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023322 0.014757 0.006982 0.016478 0.052947 0.000919 0.040330 0.028602 0.001555 0.108524 0.705585 Mica 0.020357 0.001397 0.000000 0.061778 0.003203 0.000000 0.003095 0.165668 0.000307 0.243518 0.500677 Gt 0.000000 0.043829 0.000000 0.000000 0.291945 0.054577 0.044582 0.000000 0.002344 0.137165 0.425558 Fsp 0.095224 0.058062 0.000000 0.000745 0.000000 0.000000 0.000000 0.000000 0.000000 0.154031 0.691938 Bio 0.000000 0.000000 0.017816 0.066176 0.180602 0.000656 0.161216 0.114536 0.004233 0.111408 0.343358 St 0.000000 0.000000 0.002986 0.000000 0.148168 0.002389 0.034814 0.088203 0.002241 0.390439 0.330760 Ilm 0.000000 0.000000 0.342522 0.000000 0.578298 0.009226 0.006963 0.000000 0.062991 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -754493. -742404. -920194. -828915. -301183. -451760. -630365. -283979. -407596. -1620470. -877274. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 352 converged, 142 successes so far. Misfit function evaluations this try => 186 Misfit this try = 0.265587 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.313253E-08 Bayes score, PP * exp(-Misfit) = 7.140990E-08 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 5993.11 814.149 0.903976 0.269148 Final coordinates: 6091.41 816.540 0.823736 0.485604 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.265587 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 0.022695 0.001591 0.000000 0.075851 0.003767 0.000000 0.003608 0.292228 0.600261 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 1. 0. 1. -0.7 -3.3E-02 Chi 6.7E-03 0. 0. 9.8E-04 1.4E-02 0. 2.7E-02 4.7E-04 1.1E-07 Composition Misfit: 5.161563E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.330 0.000000 0.030706 0.000000 0.000000 0.260940 0.095291 0.047461 0.138619 0.426982 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 3. -7. 0.7 0.4 -0.3 Chi 0. 3.4E-03 0. 0. 1.4E-02 3.9E-02 1.1E-03 2.0E-04 1.3E-05 Composition Misfit: 5.805808E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.593 0.094501 0.059240 0.000000 0.000879 0.000000 0.000000 0.000000 0.154620 0.690760 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.1 0. 0. 0. 0.4 0.2 Chi 8.6E-05 9.9E-04 0. 2.6E-04 0. 0. 0. 2.5E-04 2.0E-05 Composition Misfit: 1.607861E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.768 0.000000 0.000000 0.021185 0.075534 0.197302 0.001467 0.185557 0.133011 0.385943 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 2.3E-02 -1. -0.9 -1.2E-02 -1. 0.5 2. Chi 0. 0. 1.6E-06 9.8E-04 8.3E-04 1.2E-06 1.4E-03 4.0E-04 2.3E-03 Composition Misfit: 5.933506E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.296 0.000000 0.000000 0.003425 0.000000 0.156329 0.005327 0.041992 0.429264 0.363662 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. -0.3 -2. 1. 1. Chi 0. 0. 4.5E-03 0. 4.1E-03 4.2E-04 8.7E-03 8.7E-04 1.4E-03 Composition Misfit: 1.989385E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.792 0.000000 0.000000 0.210572 0.000000 0.771318 0.014122 0.003988 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 8. 0. -6. -0.7 1. 0. 0. Chi 0. 0. 0.1 0. 2.6E-02 1.2E-03 9.1E-03 0. 0. Composition Misfit: 0.128478 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.825 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.395 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023303 0.014744 0.006976 0.016464 0.052903 0.000918 0.040297 0.028235 0.002724 0.108434 0.705002 Mica 0.018927 0.001327 0.000000 0.063258 0.003142 0.000000 0.003009 0.165696 0.000327 0.243711 0.500604 Gt 0.000000 0.030649 0.000000 0.000000 0.260457 0.095115 0.047373 0.000000 0.001851 0.138363 0.426192 Fsp 0.094501 0.059240 0.000000 0.000879 0.000000 0.000000 0.000000 0.000000 0.000000 0.154620 0.690760 Bio 0.000000 0.000000 0.018669 0.066563 0.173869 0.001293 0.163519 0.114457 0.004311 0.117214 0.340106 St 0.000000 0.000000 0.003116 0.000000 0.142195 0.004846 0.038195 0.088209 0.002205 0.390453 0.330783 Ilm 0.000000 0.000000 0.183952 0.000000 0.673809 0.012336 0.003484 0.000000 0.126419 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -761429. -746962. -923225. -836395. -304283. -450582. -632340. -286201. -407843. -1624330. -880556. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 353 converged, 143 successes so far. Misfit function evaluations this try => 320 Misfit this try = 6.127325E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.600841E-07 Bayes score, PP * exp(-Misfit) = 9.030226E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 5480.57 983.665 0.632923 0.929112 Final coordinates: 8561.61 924.164 0.423735 0.499273 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.127325E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.005 0.021264 0.002915 0.000000 0.076114 0.006895 0.000000 0.005992 0.286321 0.600499 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.2E-04 2.6E-03 0. 9.5E-03 1.2E-04 4.1E-07 Composition Misfit: 2.169945E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.162 0.000000 0.030367 0.000000 0.000000 0.298619 0.038690 0.069255 0.136778 0.426292 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.5 -1. 0.5 -0.2 Chi 0. 3.2E-03 0. 0. 1.8E-03 5.1E-04 3.0E-03 3.6E-04 6.3E-06 Composition Misfit: 8.892857E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.577 0.094541 0.057881 0.000000 0.001519 0.000000 0.000000 0.000000 0.153941 0.692119 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.7E-02 0. 0. 0. 0.5 0.1 Chi 8.8E-05 6.8E-04 0. 1.7E-05 0. 0. 0. 3.1E-04 8.2E-06 Composition Misfit: 1.110525E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.547 0.000000 0.000000 0.024944 0.075763 0.198169 0.000969 0.178888 0.136443 0.384824 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.1E-04 1.0E-03 9.5E-04 2.1E-04 4.9E-04 1.1E-04 2.5E-03 Composition Misfit: 5.817177E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.145 0.000000 0.000000 0.004723 0.000000 0.148720 0.002709 0.052688 0.427768 0.363392 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.1E-03 4.7E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.327817E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.317 0.000000 0.000000 0.349607 0.000000 0.628426 0.009598 0.012369 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 2.2E-02 0. 0.1 0.1 -0.4 0. 0. Chi 0. 0. 4.4E-07 0. 3.9E-06 1.7E-05 4.5E-04 0. 0. Composition Misfit: 4.750687E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.894 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.353 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023315 0.014752 0.006980 0.016473 0.052931 0.000919 0.040318 0.029045 0.001402 0.108492 0.705374 Mica 0.017746 0.002433 0.000000 0.063518 0.005754 0.000000 0.005000 0.164961 0.000519 0.238941 0.501129 Gt 0.000000 0.030286 0.000000 0.000000 0.297827 0.038587 0.069072 0.000000 0.002653 0.136415 0.425161 Fsp 0.094541 0.057881 0.000000 0.001519 0.000000 0.000000 0.000000 0.000000 0.000000 0.153941 0.692119 Bio 0.000000 0.000000 0.022053 0.066980 0.175197 0.000857 0.158152 0.111908 0.004011 0.120626 0.340216 St 0.000000 0.000000 0.004296 0.000000 0.135264 0.002464 0.047921 0.088137 0.002344 0.389063 0.330512 Ilm 0.000000 0.000000 0.325156 0.000000 0.584475 0.008927 0.011504 0.000000 0.069938 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775462. -754435. -931606. -849615. -313837. -468006. -638363. -291391. -409863. -1635456. -886142. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 354 converged, 144 successes so far. Misfit function evaluations this try => 217 Misfit this try = 6.282810E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.950102E-07 Bayes score, PP * exp(-Misfit) = 9.344189E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 5753.48 893.012 0.696834 0.943139 Final coordinates: 8762.38 924.903 0.419552 0.479784 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.282810E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.024 0.021678 0.002995 0.000000 0.075639 0.006973 0.000000 0.006119 0.286091 0.600504 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.9E-03 0. 0. 1.0E-03 2.5E-03 0. 9.0E-03 1.1E-04 4.2E-07 Composition Misfit: 2.156822E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.568 0.000000 0.031532 0.000000 0.000000 0.303036 0.032360 0.070223 0.136617 0.426231 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. 0.2 -1. 0.5 -0.2 Chi 0. 3.8E-03 0. 0. 1.2E-03 1.1E-04 3.4E-03 3.8E-04 5.8E-06 Composition Misfit: 8.889784E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.527 0.094851 0.057301 0.000000 0.001498 0.000000 0.000000 0.000000 0.153650 0.692699 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. -4.1E-02 0. 0. 0. 0.5 0.1 Chi 1.1E-04 5.7E-04 0. 1.3E-05 0. 0. 0. 3.4E-04 4.7E-06 Composition Misfit: 1.035730E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.575 0.000000 0.000000 0.024879 0.075698 0.197899 0.000807 0.179857 0.135464 0.385397 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.9 0.2 -0.7 0.3 2. Chi 0. 0. 5.0E-04 1.0E-03 9.1E-04 4.7E-04 5.9E-04 1.7E-04 2.4E-03 Composition Misfit: 6.080858E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.983 0.000000 0.000000 0.004775 0.000000 0.148785 0.002241 0.053083 0.427729 0.363387 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.1E-03 1.1E-03 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.421340E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.329 0.000000 0.000000 0.352186 0.000000 0.627133 0.008058 0.012623 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.1 0. 0.1 0.3 -0.4 0. 0. Chi 0. 0. 1.4E-05 0. 1.3E-05 4.7E-04 5.5E-04 0. 0. Composition Misfit: 1.040106E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.842 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.153 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023342 0.014769 0.006988 0.016492 0.052992 0.000920 0.040364 0.027943 0.001390 0.108616 0.706184 Mica 0.018091 0.002500 0.000000 0.063125 0.005820 0.000000 0.005107 0.164932 0.000518 0.238757 0.501151 Gt 0.000000 0.031446 0.000000 0.000000 0.302211 0.032272 0.070032 0.000000 0.002723 0.136245 0.425071 Fsp 0.094851 0.057301 0.000000 0.001498 0.000000 0.000000 0.000000 0.000000 0.000000 0.153650 0.692699 Bio 0.000000 0.000000 0.021997 0.066928 0.174973 0.000713 0.159021 0.111860 0.003989 0.119771 0.340749 St 0.000000 0.000000 0.004343 0.000000 0.135324 0.002038 0.048280 0.088135 0.002343 0.389029 0.330508 Ilm 0.000000 0.000000 0.327948 0.000000 0.583973 0.007503 0.011755 0.000000 0.068821 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774702. -753976. -931286. -848889. -313646. -469277. -638146. -291141. -409848. -1635140. -885762. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 357 converged, 145 successes so far. Misfit function evaluations this try => 178 Misfit this try = 0.118096 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 8.848254E-07 Bayes score, PP * exp(-Misfit) = 7.862652E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 11866.5 893.433 0.297666 0.148359 Final coordinates: 8203.36 922.989 0.560485 0.512807 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.118096 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.075 0.020899 0.002810 0.000000 0.076575 0.006682 0.000000 0.005786 0.286834 0.600413 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.4 -0.1 Chi 5.3E-03 0. 0. 8.1E-04 3.0E-03 0. 1.0E-02 1.4E-04 2.8E-07 Composition Misfit: 2.248203E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.644 0.000000 0.028221 0.000000 0.000000 0.287595 0.052218 0.068618 0.136980 0.426368 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -2. -1. 0.5 -0.2 Chi 0. 2.1E-03 0. 0. 4.1E-03 6.2E-03 2.8E-03 3.4E-04 6.9E-06 Composition Misfit: 1.550211E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.626 0.094155 0.058604 0.000000 0.001543 0.000000 0.000000 0.000000 0.154302 0.691396 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -0.1 0. 0. 0. 0.5 0.1 Chi 6.7E-05 8.4E-04 0. 2.2E-05 0. 0. 0. 2.8E-04 1.4E-05 Composition Misfit: 1.222852E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.436 0.000000 0.000000 0.024879 0.075861 0.196184 0.001318 0.180036 0.137910 0.383813 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.8 3.1E-02 -0.7 0.2 2. Chi 0. 0. 5.0E-04 1.0E-03 7.0E-04 8.7E-06 6.1E-04 4.2E-05 2.7E-03 Composition Misfit: 5.597784E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.878 0.000000 0.000000 0.004595 0.000000 0.147276 0.003757 0.053234 0.427759 0.363379 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 1.7E-02 -4. 1. 1. Chi 0. 0. 1.6E-03 0. 1.8E-03 1.8E-06 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.313239E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.434 0.000000 0.000000 0.253358 0.000000 0.726647 0.011466 0.008529 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -4. -0.2 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.3E-02 1.9E-04 2.5E-04 0. 0. Composition Misfit: 5.015899E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.316 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.591 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023286 0.014734 0.006971 0.016453 0.052865 0.000917 0.040268 0.029796 0.001852 0.108357 0.704501 Mica 0.017440 0.002345 0.000000 0.063898 0.005576 0.000000 0.004828 0.165020 0.000526 0.239350 0.501017 Gt 0.000000 0.028149 0.000000 0.000000 0.286858 0.052084 0.068442 0.000000 0.002565 0.136629 0.425274 Fsp 0.094155 0.058604 0.000000 0.001543 0.000000 0.000000 0.000000 0.000000 0.000000 0.154302 0.691396 Bio 0.000000 0.000000 0.021988 0.067045 0.173385 0.001164 0.159113 0.112102 0.004110 0.121883 0.339210 St 0.000000 0.000000 0.004179 0.000000 0.133946 0.003417 0.048416 0.088131 0.002380 0.389042 0.330489 Ilm 0.000000 0.000000 0.225544 0.000000 0.646874 0.010207 0.007592 0.000000 0.109782 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776815. -755333. -932242. -851085. -314287. -465907. -638657. -291804. -409096. -1636044. -886836. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio F sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio F sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio F sill ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio F sill ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 366 converged, 146 successes so far. Misfit function evaluations this try => 190 Misfit this try = 1.31488 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 5.474409E-07 Bayes score, PP * exp(-Misfit) = 1.469907E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 8020.88 841.010 0.938622 0.936259 Final coordinates: 7838.00 851.517 0.943662 0.948325 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.31488 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.684 0.074885 0.025692 0.000000 0.012180 0.000800 0.000000 0.000386 0.311678 0.574380 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -1.0E+01 0. 0. 6. 2. 0. 2. -2. 3. Chi 0.1 0. 0. 0.4 0.1 0. 0.4 3.1E-03 1.1E-03 Composition Misfit: 1.09760 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.830 0.000000 0.057220 0.000000 0.000000 0.275172 0.051366 0.055352 0.135192 0.425697 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -5. 0. 0. 3. -2. -0.1 0.6 -0.1 Chi 0. 2.4E-02 0. 0. 7.9E-03 5.7E-03 5.6E-06 5.5E-04 2.5E-06 Composition Misfit: 3.771097E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.938 0.087904 0.072498 0.000000 0.000847 0.000000 0.000000 0.000000 0.161249 0.677502 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 0.3 -2. 0. 0.1 0. 0. 0. -2.4E-02 0.8 Chi 1.6E-04 6.0E-03 0. 3.1E-04 0. 0. 0. 7.7E-07 4.3E-04 Composition Misfit: 6.921961E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.352 0.000000 0.000000 0.020940 0.075244 0.186748 0.000922 0.199284 0.128663 0.388198 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 0.1 -1. -0.2 0.1 -2. 0.8 1. Chi 0. 0. 8.7E-06 9.1E-04 2.8E-05 2.7E-04 4.4E-03 1.1E-03 2.0E-03 Composition Misfit: 8.710095E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.588 0.000000 0.000000 0.003827 0.000000 0.150256 0.003028 0.051056 0.428365 0.363468 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -1. 0.2 -3. 1. 1. Chi 0. 0. 3.2E-03 0. 2.5E-03 2.2E-04 1.5E-02 9.5E-04 1.4E-03 Composition Misfit: 2.376819E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.956 0.000000 0.000000 0.204171 0.000000 0.783234 0.007712 0.004883 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 8. 0. -7. 0.4 0.8 0. 0. Chi 0. 0. 0.1 0. 3.0E-02 6.8E-04 5.4E-03 0. 0. Composition Misfit: 0.140177 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.427 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 43.226 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022683 0.014353 0.006791 0.016027 0.051497 0.000894 0.039226 0.053674 0.003037 0.105553 0.686266 Mica 0.062406 0.021411 0.000000 0.010150 0.000667 0.000000 0.000321 0.166522 0.000120 0.259739 0.478664 Gt 0.000000 0.057029 0.000000 0.000000 0.274252 0.051195 0.055167 0.000000 0.003342 0.134740 0.424274 Fsp 0.087904 0.072498 0.000000 0.000847 0.000000 0.000000 0.000000 0.000000 0.000000 0.161249 0.677502 Bio 0.000000 0.000000 0.018458 0.066325 0.164612 0.000813 0.175663 0.114192 0.004340 0.113412 0.342184 St 0.000000 0.000000 0.003480 0.000000 0.136653 0.002754 0.046434 0.088150 0.002385 0.389583 0.330561 Ilm 0.000000 0.000000 0.177862 0.000000 0.682310 0.006718 0.004254 0.000000 0.128855 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -762996. -744449. -924244. -836654. -306553. -457425. -632806. -285596. -404250. -1625726. -880110. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 367 converged, 147 successes so far. Misfit function evaluations this try => 301 Misfit this try = 0.118941 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.879716E-07 Bayes score, PP * exp(-Misfit) = 8.771809E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 6105.21 840.693 0.931898 0.745037 Final coordinates: 8788.36 926.098 0.604819 0.533404 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.118941 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.715 0.022294 0.003214 0.000000 0.074920 0.006819 0.000000 0.006234 0.286279 0.600240 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.3 -3.1E-02 Chi 6.4E-03 0. 0. 1.2E-03 2.8E-03 0. 8.6E-03 1.2E-04 9.6E-08 Composition Misfit: 2.227112E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.152 0.000000 0.032328 0.000000 0.000000 0.294665 0.037535 0.072935 0.136391 0.426146 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.4 -2. 0.5 -0.2 Chi 0. 4.3E-03 0. 0. 2.5E-03 2.9E-04 4.5E-03 4.1E-04 5.2E-06 Composition Misfit: 1.202443E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.217 0.094401 0.058284 0.000000 0.001457 0.000000 0.000000 0.000000 0.154142 0.691716 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -2.9E-02 0. 0. 0. 0.5 0.1 Chi 8.0E-05 7.7E-04 0. 6.8E-06 0. 0. 0. 3.0E-04 1.1E-05 Composition Misfit: 1.161746E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.144 0.000000 0.000000 0.024592 0.075656 0.191348 0.000940 0.187107 0.134833 0.385525 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.5 0.1 -1. 0.4 2. Chi 0. 0. 4.2E-04 1.0E-03 2.5E-04 2.5E-04 1.7E-03 2.2E-04 2.4E-03 Composition Misfit: 6.199833E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.019 0.000000 0.000000 0.004775 0.000000 0.145382 0.002631 0.056297 0.427569 0.363346 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 1.4E-03 5.5E-04 2.0E-02 1.0E-03 1.5E-03 Composition Misfit: 2.559710E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.533 0.000000 0.000000 0.252634 0.000000 0.730000 0.008230 0.009137 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.3 0.1 0. 0. Chi 0. 0. 3.8E-02 0. 1.4E-02 3.8E-04 8.2E-05 0. 0. Composition Misfit: 5.168643E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.844 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.378 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023255 0.014714 0.006962 0.016430 0.052794 0.000916 0.040214 0.030951 0.001996 0.108212 0.703556 Mica 0.018605 0.002682 0.000000 0.062523 0.005691 0.000000 0.005202 0.164939 0.000527 0.238909 0.500921 Gt 0.000000 0.032236 0.000000 0.000000 0.293834 0.037430 0.072729 0.000000 0.002821 0.136006 0.424944 Fsp 0.094401 0.058284 0.000000 0.001457 0.000000 0.000000 0.000000 0.000000 0.000000 0.154142 0.691716 Bio 0.000000 0.000000 0.021737 0.066873 0.169135 0.000830 0.165386 0.112009 0.004079 0.119180 0.340770 St 0.000000 0.000000 0.004343 0.000000 0.132222 0.002393 0.051202 0.088122 0.002393 0.388867 0.330457 Ilm 0.000000 0.000000 0.224827 0.000000 0.649649 0.007324 0.008131 0.000000 0.110069 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774961. -753907. -931368. -849415. -313998. -468289. -637959. -291064. -408235. -1635275. -885833. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio F q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio F q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 370 converged, 148 successes so far. Misfit function evaluations this try => 196 Misfit this try = 6.122956E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.552551E-07 Bayes score, PP * exp(-Misfit) = 8.985199E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 5490.76 926.265 0.863552 0.122630 Final coordinates: 8623.55 926.055 0.425425 0.495198 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.122956E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.002 0.021299 0.002950 0.000000 0.076050 0.006966 0.000000 0.006051 0.286185 0.600500 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.3E-04 2.5E-03 0. 9.3E-03 1.1E-04 4.2E-07 Composition Misfit: 2.141805E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.241 0.000000 0.030465 0.000000 0.000000 0.299542 0.037191 0.069816 0.136717 0.426269 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.3 -1. 0.5 -0.2 Chi 0. 3.2E-03 0. 0. 1.7E-03 2.3E-04 3.2E-03 3.7E-04 6.1E-06 Composition Misfit: 8.741327E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.572 0.094587 0.057770 0.000000 0.001528 0.000000 0.000000 0.000000 0.153885 0.692230 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.9E-02 0. 0. 0. 0.5 0.1 Chi 9.1E-05 6.6E-04 0. 1.9E-05 0. 0. 0. 3.2E-04 7.4E-06 Composition Misfit: 1.097055E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.552 0.000000 0.000000 0.024977 0.075758 0.198065 0.000937 0.179039 0.136364 0.384860 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.2E-04 1.0E-03 9.3E-04 2.5E-04 5.1E-04 1.1E-04 2.5E-03 Composition Misfit: 5.864243E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.921 0.000000 0.000000 0.004740 0.000000 0.148565 0.002610 0.052975 0.427727 0.363383 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.1E-03 5.8E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.356478E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.320 0.000000 0.000000 0.347548 0.000000 0.630798 0.009252 0.012402 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. -3.7E-02 0.1 -0.4 0. 0. Chi 0. 0. 1.7E-05 0. 1.0E-06 6.1E-05 4.7E-04 0. 0. Composition Misfit: 5.441014E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.074 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.318 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023320 0.014756 0.006982 0.016477 0.052943 0.000919 0.040327 0.028815 0.001408 0.108517 0.705537 Mica 0.017775 0.002462 0.000000 0.063466 0.005813 0.000000 0.005050 0.164943 0.000524 0.238830 0.501137 Gt 0.000000 0.030383 0.000000 0.000000 0.298740 0.037091 0.069629 0.000000 0.002679 0.136351 0.425127 Fsp 0.094587 0.057770 0.000000 0.001528 0.000000 0.000000 0.000000 0.000000 0.000000 0.153885 0.692230 Bio 0.000000 0.000000 0.022082 0.066978 0.175112 0.000829 0.158291 0.111874 0.004013 0.120561 0.340260 St 0.000000 0.000000 0.004311 0.000000 0.135122 0.002374 0.048181 0.088134 0.002352 0.389024 0.330502 Ilm 0.000000 0.000000 0.322932 0.000000 0.586120 0.008596 0.011524 0.000000 0.070827 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775626. -754526. -931734. -849778. -313988. -468499. -638443. -291460. -409830. -1635626. -886206. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 372 converged, 149 successes so far. Misfit function evaluations this try => 307 Misfit this try = 6.116877E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.429234E-07 Bayes score, PP * exp(-Misfit) = 8.869746E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 8302.10 841.631 0.605867 8.686652E-02 Final coordinates: 8627.96 927.362 0.423691 0.497181 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.116877E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.019 0.021252 0.002963 0.000000 0.076086 0.006990 0.000000 0.006067 0.286144 0.600497 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.2E-04 2.5E-03 0. 9.2E-03 1.1E-04 4.1E-07 Composition Misfit: 2.128449E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.220 0.000000 0.030264 0.000000 0.000000 0.299268 0.037433 0.070034 0.136727 0.426273 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.4 -1. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 1.7E-03 2.7E-04 3.3E-03 3.7E-04 6.1E-06 Composition Misfit: 8.796621E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.573 0.094557 0.057805 0.000000 0.001540 0.000000 0.000000 0.000000 0.153903 0.692195 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.9E-05 6.7E-04 0. 2.2E-05 0. 0. 0. 3.2E-04 7.7E-06 Composition Misfit: 1.103611E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.530 0.000000 0.000000 0.025038 0.075768 0.197981 0.000949 0.178952 0.136526 0.384784 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.4E-04 1.0E-03 9.2E-04 2.4E-04 5.0E-04 1.1E-04 2.5E-03 Composition Misfit: 5.851055E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.044 0.000000 0.000000 0.004760 0.000000 0.148371 0.002641 0.053124 0.427721 0.363383 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 5.4E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.358014E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.316 0.000000 0.000000 0.348474 0.000000 0.629641 0.009373 0.012511 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. 1.6E-02 0.1 -0.4 0. 0. Chi 0. 0. 6.7E-06 0. 2.0E-07 4.2E-05 5.0E-04 0. 0. Composition Misfit: 5.528470E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.962 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.336 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023318 0.014754 0.006981 0.016475 0.052937 0.000919 0.040323 0.028927 0.001402 0.108505 0.705460 Mica 0.017736 0.002473 0.000000 0.063497 0.005833 0.000000 0.005063 0.164938 0.000525 0.238798 0.501137 Gt 0.000000 0.030183 0.000000 0.000000 0.298468 0.037333 0.069847 0.000000 0.002675 0.136362 0.425133 Fsp 0.094557 0.057805 0.000000 0.001540 0.000000 0.000000 0.000000 0.000000 0.000000 0.153903 0.692195 Bio 0.000000 0.000000 0.022137 0.066990 0.175045 0.000839 0.158220 0.111844 0.004009 0.120710 0.340206 St 0.000000 0.000000 0.004329 0.000000 0.134946 0.002402 0.048317 0.088134 0.002349 0.389019 0.330503 Ilm 0.000000 0.000000 0.323932 0.000000 0.585297 0.008713 0.011630 0.000000 0.070427 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775919. -754697. -931883. -850069. -314149. -468610. -638550. -291566. -409891. -1635826. -886338. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 373 converged, 150 successes so far. Misfit function evaluations this try => 202 Misfit this try = 0.101375 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.349611E-07 Bayes score, PP * exp(-Misfit) = 1.219500E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 5847.02 812.312 0.792191 0.154456 Final coordinates: 7147.38 810.744 0.446256 0.483520 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.101375 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.008 0.024534 0.001795 0.000000 0.073848 0.004050 0.000000 0.003910 0.291532 0.600332 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 1. 0. 1. -0.6 -4.3E-02 Chi 8.2E-03 0. 0. 1.5E-03 1.2E-02 0. 2.4E-02 4.2E-04 1.8E-07 Composition Misfit: 4.814742E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.104 0.000000 0.044197 0.000000 0.000000 0.297589 0.047790 0.046538 0.137371 0.426514 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 1. -1. 0.8 0.5 -0.2 Chi 0. 1.3E-02 0. 0. 2.0E-03 3.8E-03 1.5E-03 3.0E-04 8.1E-06 Composition Misfit: 2.025849E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.418 0.095385 0.057667 0.000000 0.000782 0.000000 0.000000 0.000000 0.153834 0.692333 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.5E-04 6.4E-04 0. 4.2E-04 0. 0. 0. 3.2E-04 6.8E-06 Composition Misfit: 1.541209E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.880 0.000000 0.000000 0.020591 0.075103 0.204776 0.000684 0.182542 0.126539 0.389766 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 0.1 -1. -1. 0.2 -0.9 1. 1. Chi 0. 0. 2.9E-05 8.8E-04 2.0E-03 8.0E-04 9.3E-04 1.5E-03 1.8E-03 Composition Misfit: 7.918369E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.024 0.000000 0.000000 0.003432 0.000000 0.162188 0.002336 0.039216 0.429185 0.363643 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. 0.3 -2. 1. 1. Chi 0. 0. 4.4E-03 0. 6.0E-03 9.7E-04 6.8E-03 8.7E-04 1.4E-03 Composition Misfit: 2.042917E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.474 0.000000 0.000000 0.374895 0.000000 0.608288 0.008795 0.008023 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 1. 0.2 0.3 0. 0. Chi 0. 0. 1.7E-03 0. 7.7E-04 1.7E-04 4.9E-04 0. 0. Composition Misfit: 3.080611E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.156 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.935 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023335 0.014765 0.006986 0.016487 0.052975 0.000919 0.040352 0.028152 0.001478 0.108583 0.705968 Mica 0.020463 0.001497 0.000000 0.061595 0.003378 0.000000 0.003261 0.165613 0.000315 0.243159 0.500720 Gt 0.000000 0.044092 0.000000 0.000000 0.296877 0.047675 0.046427 0.000000 0.002394 0.137042 0.425493 Fsp 0.095385 0.057667 0.000000 0.000782 0.000000 0.000000 0.000000 0.000000 0.000000 0.153834 0.692333 Bio 0.000000 0.000000 0.018153 0.066209 0.180528 0.000603 0.160926 0.114266 0.004149 0.111555 0.343612 St 0.000000 0.000000 0.003122 0.000000 0.147521 0.002125 0.035669 0.088202 0.002228 0.390374 0.330759 Ilm 0.000000 0.000000 0.352825 0.000000 0.572478 0.008277 0.007550 0.000000 0.058870 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -755353. -742848. -920665. -829735. -301873. -453511. -630765. -284272. -408123. -1621204. -877563. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 374 converged, 151 successes so far. Misfit function evaluations this try => 486 Misfit this try = 0.104205 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.357101E-07 Bayes score, PP * exp(-Misfit) = 1.222803E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 5544.50 815.742 0.898286 7.782851E-02 Final coordinates: 7267.21 809.409 0.452408 0.488043 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.103833 Extraneous predicted phases: 3.719302E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.398 0.025307 0.001859 0.000000 0.073049 0.003992 0.000000 0.003893 0.291647 0.600253 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 1. 0. 1. -0.7 -3.2E-02 Chi 8.8E-03 0. 0. 1.8E-03 1.3E-02 0. 2.4E-02 4.3E-04 1.1E-07 Composition Misfit: 4.968586E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.245 0.000000 0.046259 0.000000 0.000000 0.299724 0.043619 0.046809 0.137155 0.426433 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 1. -1. 0.8 0.5 -0.2 Chi 0. 1.4E-02 0. 0. 1.6E-03 2.0E-03 1.4E-03 3.3E-04 7.4E-06 Composition Misfit: 1.964309E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.292 0.095520 0.057438 0.000000 0.000760 0.000000 0.000000 0.000000 0.153719 0.692562 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.6E-04 5.9E-04 0. 4.7E-04 0. 0. 0. 3.4E-04 5.4E-06 Composition Misfit: 1.560788E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.584 0.000000 0.000000 0.020429 0.075032 0.203642 0.000614 0.184436 0.125481 0.390366 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 0.1 -1. -1. 0.2 -1. 1. 1. Chi 0. 0. 4.3E-05 8.7E-04 1.8E-03 1.1E-03 1.2E-03 1.8E-03 1.7E-03 Composition Misfit: 8.426807E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.017 0.000000 0.000000 0.003447 0.000000 0.162037 0.002108 0.039595 0.429172 0.363641 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. 0.4 -2. 1. 1. Chi 0. 0. 4.4E-03 0. 5.9E-03 1.4E-03 7.0E-03 8.7E-04 1.4E-03 Composition Misfit: 2.103252E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.484 0.000000 0.000000 0.375630 0.000000 0.608296 0.007975 0.008099 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 1. 0.3 0.3 0. 0. Chi 0. 0. 1.7E-03 0. 7.7E-04 5.1E-04 4.5E-04 0. 0. Composition Misfit: 3.483863E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.089 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.879 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.011 0.000000 0.000000 0.175785 0.000000 0.686493 0.004918 0.003118 0.000000 0.129686 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023328 0.014760 0.006984 0.016482 0.052960 0.000919 0.040340 0.028408 0.001497 0.108552 0.705768 Mica 0.021108 0.001550 0.000000 0.060928 0.003330 0.000000 0.003247 0.165622 0.000311 0.243253 0.500651 Gt 0.000000 0.046144 0.000000 0.000000 0.298978 0.043510 0.046692 0.000000 0.002488 0.136814 0.425372 Fsp 0.095520 0.057438 0.000000 0.000760 0.000000 0.000000 0.000000 0.000000 0.000000 0.153719 0.692562 Bio 0.000000 0.000000 0.018010 0.066147 0.179527 0.000541 0.162595 0.114284 0.004133 0.110622 0.344140 St 0.000000 0.000000 0.003135 0.000000 0.147384 0.001917 0.036015 0.088202 0.002228 0.390362 0.330757 Ilm 0.000000 0.000000 0.353639 0.000000 0.572684 0.007508 0.007625 0.000000 0.058544 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -754504. -742294. -920260. -828965. -301574. -453871. -630464. -283952. -407877. -1620751. -877156. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 375 converged, 152 successes so far. Misfit function evaluations this try => 145 Misfit this try = 7.033564E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.016080E-06 Bayes score, PP * exp(-Misfit) = 9.470684E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 7264.94 956.534 0.341291 0.793426 Final coordinates: 8858.56 924.635 0.462583 0.600255 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.033564E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.184 0.022662 0.003324 0.000000 0.074500 0.006716 0.000000 0.006271 0.286379 0.600148 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.3 -1.9E-02 Chi 6.7E-03 0. 0. 1.3E-03 2.9E-03 0. 8.4E-03 1.2E-04 3.6E-08 Composition Misfit: 2.283287E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.104 0.000000 0.033607 0.000000 0.000000 0.294433 0.036083 0.073354 0.136381 0.426143 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.2 -2. 0.5 -0.2 Chi 0. 5.1E-03 0. 0. 2.6E-03 9.3E-05 4.7E-03 4.1E-04 5.2E-06 Composition Misfit: 1.284203E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.877 0.094223 0.058717 0.000000 0.001418 0.000000 0.000000 0.000000 0.154359 0.691283 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -1.8E-02 0. 0. 0. 0.5 0.1 Chi 7.0E-05 8.6E-04 0. 2.6E-06 0. 0. 0. 2.8E-04 1.5E-05 Composition Misfit: 1.228579E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.922 0.000000 0.000000 0.024588 0.075614 0.189780 0.000893 0.188927 0.134211 0.385987 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.4 0.2 -1. 0.4 2. Chi 0. 0. 4.2E-04 9.9E-04 1.5E-04 3.2E-04 2.0E-03 2.8E-04 2.3E-03 Composition Misfit: 6.477393E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.981 0.000000 0.000000 0.004882 0.000000 0.144724 0.002506 0.056911 0.427610 0.363366 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.2E-03 0. 1.3E-03 7.1E-04 2.0E-02 1.0E-03 1.4E-03 Composition Misfit: 2.599710E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.417 0.000000 0.000000 0.346384 0.000000 0.631236 0.009071 0.013308 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.2 0. -0.1 0.1 -0.5 0. 0. Chi 0. 0. 3.8E-05 0. 2.4E-06 9.5E-05 8.2E-04 0. 0. Composition Misfit: 9.576677E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.980 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.535 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023176 0.014664 0.006938 0.016375 0.052615 0.000913 0.040077 0.034711 0.001521 0.107844 0.701165 Mica 0.018912 0.002774 0.000000 0.062174 0.005605 0.000000 0.005233 0.164946 0.000513 0.238995 0.500848 Gt 0.000000 0.033512 0.000000 0.000000 0.293601 0.035981 0.073146 0.000000 0.002825 0.135995 0.424939 Fsp 0.094223 0.058717 0.000000 0.001418 0.000000 0.000000 0.000000 0.000000 0.000000 0.154359 0.691283 Bio 0.000000 0.000000 0.021736 0.066845 0.167770 0.000789 0.167016 0.111953 0.004022 0.118646 0.341222 St 0.000000 0.000000 0.004440 0.000000 0.131629 0.002280 0.051762 0.088130 0.002353 0.388919 0.330487 Ilm 0.000000 0.000000 0.321677 0.000000 0.586211 0.008424 0.012359 0.000000 0.071329 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774353. -753391. -930872. -848860. -313768. -468340. -637685. -290781. -408452. -1634888. -885513. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Sp Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Sp Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 382 converged, 153 successes so far. Misfit function evaluations this try => 218 Misfit this try = 0.269067 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 8.537098E-08 Bayes score, PP * exp(-Misfit) = 6.523130E-08 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 5780.07 954.199 0.240916 9.362533E-02 Final coordinates: 6239.13 811.378 0.856428 0.486071 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.269067 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.315 0.023493 0.001638 0.000000 0.075038 0.003671 0.000000 0.003591 0.292362 0.600208 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 1. 0. 1. -0.7 -2.7E-02 Chi 7.3E-03 0. 0. 1.2E-03 1.5E-02 0. 2.8E-02 4.8E-04 7.2E-08 Composition Misfit: 5.350363E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.397 0.000000 0.033479 0.000000 0.000000 0.264846 0.089179 0.047122 0.138454 0.426920 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 3. -6. 0.7 0.4 -0.3 Chi 0. 5.0E-03 0. 0. 1.2E-02 3.4E-02 1.2E-03 2.1E-04 1.2E-05 Composition Misfit: 5.260044E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.518 0.094557 0.059237 0.000000 0.000825 0.000000 0.000000 0.000000 0.154618 0.690763 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.2 0. 0. 0. 0.4 0.2 Chi 8.9E-05 9.9E-04 0. 3.4E-04 0. 0. 0. 2.5E-04 2.0E-05 Composition Misfit: 1.694297E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.541 0.000000 0.000000 0.020849 0.075410 0.196756 0.001323 0.187537 0.131143 0.386983 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 0.1 -1. -0.8 2.9E-02 -1. 0.7 2. Chi 0. 0. 1.3E-05 9.5E-04 7.7E-04 7.9E-06 1.7E-03 6.4E-04 2.2E-03 Composition Misfit: 6.278243E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.058 0.000000 0.000000 0.003415 0.000000 0.157011 0.004816 0.041793 0.429296 0.363670 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. -0.2 -2. 1. 1. Chi 0. 0. 4.5E-03 0. 4.3E-03 2.0E-04 8.5E-03 8.6E-04 1.4E-03 Composition Misfit: 1.977459E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.844 0.000000 0.000000 0.207716 0.000000 0.775666 0.012764 0.003854 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 8. 0. -7. -0.4 1. 0. 0. Chi 0. 0. 0.1 0. 2.7E-02 6.0E-04 9.8E-03 0. 0. Composition Misfit: 0.135216 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.021 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.306 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023300 0.014742 0.006975 0.016462 0.052896 0.000918 0.040291 0.028258 0.002831 0.108420 0.704906 Mica 0.019592 0.001366 0.000000 0.062580 0.003062 0.000000 0.002995 0.165710 0.000315 0.243822 0.500558 Gt 0.000000 0.033414 0.000000 0.000000 0.264337 0.089008 0.047032 0.000000 0.001923 0.138188 0.426099 Fsp 0.094557 0.059237 0.000000 0.000825 0.000000 0.000000 0.000000 0.000000 0.000000 0.154618 0.690763 Bio 0.000000 0.000000 0.018372 0.066449 0.173378 0.001165 0.165254 0.114527 0.004292 0.115561 0.341002 St 0.000000 0.000000 0.003106 0.000000 0.142816 0.004380 0.038015 0.088211 0.002197 0.390484 0.330791 Ilm 0.000000 0.000000 0.181231 0.000000 0.676763 0.011136 0.003363 0.000000 0.127508 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -759605. -745746. -922294. -834591. -303474. -450288. -631707. -285543. -407663. -1623261. -879702. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 383 converged, 154 successes so far. Misfit function evaluations this try => 1018 Misfit this try = 0.129946 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.218183E-07 Bayes score, PP * exp(-Misfit) = 8.094879E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 14392.1 980.692 6.051235E-02 0.575856 Final coordinates: 8450.62 925.586 0.603850 0.490840 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.129945 Extraneous predicted phases: 1.360366E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.029 0.021105 0.002905 0.000000 0.076280 0.006923 0.000000 0.006007 0.286338 0.600441 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.5E-03 0. 0. 8.8E-04 2.6E-03 0. 9.5E-03 1.2E-04 3.2E-07 Composition Misfit: 2.142255E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.951 0.000000 0.029552 0.000000 0.000000 0.293218 0.044151 0.070250 0.136603 0.426226 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -1. -1. 0.5 -0.2 Chi 0. 2.7E-03 0. 0. 2.8E-03 2.2E-03 3.4E-03 3.8E-04 5.8E-06 Composition Misfit: 1.156343E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.613 0.094371 0.058179 0.000000 0.001539 0.000000 0.000000 0.000000 0.154090 0.691821 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 7.8E-05 7.5E-04 0. 2.1E-05 0. 0. 0. 3.0E-04 1.0E-05 Composition Misfit: 1.155973E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.512 0.000000 0.000000 0.024480 0.075782 0.196026 0.001116 0.181573 0.136729 0.384294 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.8 0.1 -0.8 0.3 2. Chi 0. 0. 4.0E-04 1.0E-03 6.8E-04 8.5E-05 8.0E-04 9.4E-05 2.6E-03 Composition Misfit: 5.693927E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.509 0.000000 0.000000 0.004446 0.000000 0.147500 0.003142 0.053919 0.427653 0.363339 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.1 -4. 1. 1. Chi 0. 0. 1.9E-03 0. 1.8E-03 1.5E-04 1.8E-02 1.0E-03 1.5E-03 Composition Misfit: 2.415057E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.494 0.000000 0.000000 0.241722 0.000000 0.741456 0.008960 0.007862 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. 0.2 0.3 0. 0. Chi 0. 0. 4.9E-02 0. 1.7E-02 1.2E-04 5.8E-04 0. 0. Composition Misfit: 6.595855E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.489 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.400 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.004 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000021 -.000021 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023313 0.014751 0.006979 0.016471 0.052925 0.000918 0.040314 0.028552 0.001997 0.108480 0.705300 Mica 0.017612 0.002424 0.000000 0.063655 0.005778 0.000000 0.005013 0.164959 0.000544 0.238948 0.501067 Gt 0.000000 0.029472 0.000000 0.000000 0.292418 0.044030 0.070058 0.000000 0.002729 0.136230 0.425063 Fsp 0.094371 0.058179 0.000000 0.001539 0.000000 0.000000 0.000000 0.000000 0.000000 0.154090 0.691821 Bio 0.000000 0.000000 0.021629 0.066956 0.173197 0.000986 0.160427 0.112283 0.004175 0.120806 0.339540 St 0.000000 0.000000 0.004043 0.000000 0.134142 0.002857 0.049036 0.088115 0.002451 0.388922 0.330433 Ilm 0.000000 0.000000 0.214076 0.000000 0.656656 0.007935 0.006963 0.000000 0.114369 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776308. -754963. -932474. -850528. -314256. -467290. -638518. -291665. -408293. -1635925. -886551. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 385 converged, 155 successes so far. Misfit function evaluations this try => 142 Misfit this try = 6.171706E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.003300E-06 Bayes score, PP * exp(-Misfit) = 9.432509E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 7722.63 875.906 0.168148 0.735687 Final coordinates: 8540.47 918.419 0.424047 0.494653 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.171706E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.004 0.021503 0.002871 0.000000 0.075915 0.006759 0.000000 0.005920 0.286534 0.600498 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.4 -0.1 Chi 5.8E-03 0. 0. 9.6E-04 2.9E-03 0. 9.8E-03 1.3E-04 4.1E-07 Composition Misfit: 2.242146E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.234 0.000000 0.031253 0.000000 0.000000 0.299632 0.037762 0.068285 0.136777 0.426292 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.4 -1. 0.5 -0.2 Chi 0. 3.7E-03 0. 0. 1.7E-03 3.3E-04 2.7E-03 3.6E-04 6.3E-06 Composition Misfit: 8.687168E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.559 0.094650 0.057768 0.000000 0.001466 0.000000 0.000000 0.000000 0.153884 0.692232 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -3.1E-02 0. 0. 0. 0.5 0.1 Chi 9.5E-05 6.6E-04 0. 8.0E-06 0. 0. 0. 3.2E-04 7.4E-06 Composition Misfit: 1.089603E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.577 0.000000 0.000000 0.024714 0.075716 0.198420 0.000920 0.179289 0.135747 0.385195 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.9 0.1 -0.7 0.3 2. Chi 0. 0. 4.5E-04 1.0E-03 9.8E-04 2.8E-04 5.3E-04 1.5E-04 2.5E-03 Composition Misfit: 5.867817E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.810 0.000000 0.000000 0.004670 0.000000 0.149371 0.002595 0.052137 0.427825 0.363402 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 2.2E-03 6.0E-04 1.6E-02 1.0E-03 1.4E-03 Composition Misfit: 2.317418E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.327 0.000000 0.000000 0.351588 0.000000 0.626966 0.009252 0.012193 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.1 0. 0.1 0.1 -0.3 0. 0. Chi 0. 0. 7.2E-06 0. 1.5E-05 6.0E-05 3.9E-04 0. 0. Composition Misfit: 4.768320E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.196 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.293 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023321 0.014756 0.006982 0.016477 0.052945 0.000919 0.040329 0.028784 0.001403 0.108521 0.705563 Mica 0.017944 0.002396 0.000000 0.063352 0.005641 0.000000 0.004940 0.164988 0.000507 0.239114 0.501119 Gt 0.000000 0.031170 0.000000 0.000000 0.298837 0.037662 0.068104 0.000000 0.002653 0.136415 0.425161 Fsp 0.094650 0.057768 0.000000 0.001466 0.000000 0.000000 0.000000 0.000000 0.000000 0.153884 0.692232 Bio 0.000000 0.000000 0.021846 0.066931 0.175398 0.000813 0.158487 0.112017 0.004010 0.119997 0.340502 St 0.000000 0.000000 0.004247 0.000000 0.135856 0.002360 0.047420 0.088139 0.002339 0.389116 0.330522 Ilm 0.000000 0.000000 0.327300 0.000000 0.583656 0.008613 0.011351 0.000000 0.069080 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774190. -753682. -930918. -848361. -313142. -467470. -637891. -290924. -409738. -1634583. -885567. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 389 converged, 156 successes so far. Misfit function evaluations this try => 247 Misfit this try = 0.202895 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 3.368426E-07 Bayes score, PP * exp(-Misfit) = 2.749863E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 13697.9 880.234 0.945236 0.800349 Final coordinates: 7692.82 832.774 0.807302 0.541051 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.202895 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.762 0.027920 0.002580 0.000000 0.070054 0.003988 0.000000 0.004147 0.291724 0.599587 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -3. 0. 0. 1. 1. 0. 1. -0.7 0.1 Chi 1.1E-02 0. 0. 3.0E-03 1.3E-02 0. 2.1E-02 4.3E-04 2.8E-07 Composition Misfit: 5.120936E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.933 0.000000 0.045964 0.000000 0.000000 0.286915 0.049182 0.054730 0.136880 0.426330 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 2. -2. 6.2E-03 0.5 -0.2 Chi 0. 1.4E-02 0. 0. 4.3E-03 4.5E-03 7.7E-08 3.5E-04 6.6E-06 Composition Misfit: 2.321971E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.788 0.094729 0.058938 0.000000 0.000802 0.000000 0.000000 0.000000 0.154469 0.691062 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.4 0.2 Chi 1.0E-04 9.1E-04 0. 3.9E-04 0. 0. 0. 2.7E-04 1.7E-05 Composition Misfit: 1.685027E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.692 0.000000 0.000000 0.021238 0.075065 0.189604 0.000780 0.197093 0.125979 0.390241 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1.6E-02 -1. -0.3 0.2 -2. 1. 1. Chi 0. 0. 7.9E-07 8.8E-04 1.4E-04 5.3E-04 3.9E-03 1.6E-03 1.7E-03 Composition Misfit: 8.734110E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.758 0.000000 0.000000 0.004058 0.000000 0.153524 0.002626 0.047491 0.428722 0.363578 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -2. 0.3 -3. 1. 1. Chi 0. 0. 2.6E-03 0. 3.3E-03 5.6E-04 1.3E-02 9.2E-04 1.4E-03 Composition Misfit: 2.153714E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.848 0.000000 0.000000 0.224862 0.000000 0.761568 0.008067 0.005503 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -6. 0.3 0.7 0. 0. Chi 0. 0. 0.1 0. 2.3E-02 4.6E-04 3.7E-03 0. 0. Composition Misfit: 9.650920E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.060 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.159 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023229 0.014698 0.006954 0.016412 0.052736 0.000915 0.040169 0.031360 0.002661 0.108092 0.702774 Mica 0.023288 0.002152 0.000000 0.058431 0.003326 0.000000 0.003459 0.165590 0.000324 0.243323 0.500107 Gt 0.000000 0.045844 0.000000 0.000000 0.286167 0.049053 0.054587 0.000000 0.002608 0.136523 0.425218 Fsp 0.094729 0.058938 0.000000 0.000802 0.000000 0.000000 0.000000 0.000000 0.000000 0.154469 0.691062 Bio 0.000000 0.000000 0.018737 0.066224 0.167272 0.000688 0.173878 0.113711 0.004074 0.111140 0.344276 St 0.000000 0.000000 0.003691 0.000000 0.139645 0.002389 0.043198 0.088189 0.002213 0.389965 0.330710 Ilm 0.000000 0.000000 0.197669 0.000000 0.669470 0.007092 0.004837 0.000000 0.120933 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -758096. -743971. -921475. -833277. -304173. -455520. -631370. -284776. -406950. -1623244. -878528. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 392 converged, 157 successes so far. Misfit function evaluations this try => 193 Misfit this try = 0.122178 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.002506E-06 Bayes score, PP * exp(-Misfit) = 8.872089E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 12632.2 885.814 0.708770 0.428972 Final coordinates: 8799.93 924.884 0.627283 0.572076 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.122178 Extraneous predicted phases: 3.448488E-8 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.742 0.022682 0.003320 0.000000 0.074490 0.006686 0.000000 0.006254 0.286462 0.600106 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.4 -1.4E-02 Chi 6.7E-03 0. 0. 1.3E-03 3.0E-03 0. 8.5E-03 1.3E-04 1.9E-08 Composition Misfit: 2.296366E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.991 0.000000 0.033107 0.000000 0.000000 0.291295 0.039365 0.073770 0.136337 0.426126 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.6 -2. 0.5 -0.2 Chi 0. 4.8E-03 0. 0. 3.2E-03 6.7E-04 4.9E-03 4.1E-04 5.1E-06 Composition Misfit: 1.394706E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.001 0.094189 0.058779 0.000000 0.001422 0.000000 0.000000 0.000000 0.154389 0.691221 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -1.9E-02 0. 0. 0. 0.5 0.1 Chi 6.8E-05 8.8E-04 0. 2.9E-06 0. 0. 0. 2.7E-04 1.6E-05 Composition Misfit: 1.238984E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.293 0.000000 0.000000 0.024473 0.075624 0.188513 0.000979 0.190283 0.134367 0.385760 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.3 0.1 -1. 0.4 2. Chi 0. 0. 3.9E-04 9.9E-04 8.7E-05 2.0E-04 2.3E-03 2.6E-04 2.4E-03 Composition Misfit: 6.571217E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.588 0.000000 0.000000 0.004808 0.000000 0.143999 0.002755 0.057544 0.427550 0.363344 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.3E-03 0. 1.2E-03 4.3E-04 2.1E-02 1.0E-03 1.5E-03 Composition Misfit: 2.622294E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.570 0.000000 0.000000 0.252730 0.000000 0.729328 0.008625 0.009318 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 0.1 0. 0. Chi 0. 0. 3.7E-02 0. 1.4E-02 2.2E-04 5.0E-05 0. 0. Composition Misfit: 5.123418E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.313 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.501 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000020 -.000020 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023201 0.014680 0.006946 0.016392 0.052672 0.000914 0.040121 0.033118 0.002065 0.107962 0.701928 Mica 0.018928 0.002770 0.000000 0.062163 0.005580 0.000000 0.005219 0.164954 0.000522 0.239060 0.500804 Gt 0.000000 0.033012 0.000000 0.000000 0.290467 0.039253 0.073560 0.000000 0.002844 0.135949 0.424914 Fsp 0.094189 0.058779 0.000000 0.001422 0.000000 0.000000 0.000000 0.000000 0.000000 0.154389 0.691221 Bio 0.000000 0.000000 0.021631 0.066842 0.166620 0.000865 0.168184 0.112053 0.004085 0.118762 0.340958 St 0.000000 0.000000 0.004373 0.000000 0.130965 0.002505 0.052335 0.088122 0.002391 0.388852 0.330457 Ilm 0.000000 0.000000 0.224921 0.000000 0.649079 0.007676 0.008292 0.000000 0.110031 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774674. -753608. -931107. -849248. -313935. -467767. -637731. -290872. -407782. -1635055. -885674. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 394 converged, 158 successes so far. Misfit function evaluations this try => 355 Misfit this try = 0.146371 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.460510E-07 Bayes score, PP * exp(-Misfit) = 8.172337E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 14029.3 950.265 0.381264 9.671559E-02 Final coordinates: 8661.05 927.713 0.651324 0.466191 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.146371 Extraneous predicted phases: 1.074051E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.007 0.021323 0.002985 0.000000 0.075986 0.007127 0.000000 0.006206 0.285908 0.600465 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.5E-04 2.3E-03 0. 8.7E-03 1.0E-04 3.6E-07 Composition Misfit: 2.062850E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.303 0.000000 0.030671 0.000000 0.000000 0.297751 0.037392 0.071849 0.136245 0.426092 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.3 -2. 0.5 -0.2 Chi 0. 3.3E-03 0. 0. 2.0E-03 2.6E-04 4.0E-03 4.2E-04 4.8E-06 Composition Misfit: 1.004282E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.589 0.094626 0.057680 0.000000 0.001535 0.000000 0.000000 0.000000 0.153840 0.692320 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 9.4E-05 6.4E-04 0. 2.0E-05 0. 0. 0. 3.2E-04 6.9E-06 Composition Misfit: 1.086260E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.572 0.000000 0.000000 0.024055 0.075711 0.195533 0.000947 0.183388 0.135658 0.384709 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. -0.7 0.1 -0.9 0.3 2. Chi 0. 0. 3.0E-04 1.0E-03 6.3E-04 2.4E-04 1.0E-03 1.6E-04 2.5E-03 Composition Misfit: 5.927157E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.029 0.000000 0.000000 0.004280 0.000000 0.147514 0.002638 0.054709 0.427558 0.363301 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 2.2E-03 0. 1.8E-03 5.5E-04 1.8E-02 1.0E-03 1.5E-03 Composition Misfit: 2.551052E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.561 0.000000 0.000000 0.231547 0.000000 0.754040 0.007086 0.007327 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -6. 0.5 0.4 0. 0. Chi 0. 0. 0.1 0. 2.0E-02 1.2E-03 9.8E-04 0. 0. Composition Misfit: 8.317604E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.739 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.199 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000020 -.000020 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023342 0.014769 0.006988 0.016492 0.052993 0.000920 0.040365 0.027152 0.002157 0.108619 0.706201 Mica 0.017795 0.002491 0.000000 0.063412 0.005948 0.000000 0.005179 0.164906 0.000561 0.238600 0.501108 Gt 0.000000 0.030583 0.000000 0.000000 0.296893 0.037284 0.071641 0.000000 0.002884 0.135852 0.424863 Fsp 0.094626 0.057680 0.000000 0.001535 0.000000 0.000000 0.000000 0.000000 0.000000 0.153840 0.692320 Bio 0.000000 0.000000 0.021247 0.066872 0.172706 0.000836 0.161979 0.112498 0.004242 0.119822 0.339798 St 0.000000 0.000000 0.003892 0.000000 0.134146 0.002399 0.049751 0.088101 0.002524 0.388811 0.330377 Ilm 0.000000 0.000000 0.204145 0.000000 0.664806 0.006247 0.006460 0.000000 0.118342 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775844. -754660. -932730. -850048. -314229. -468639. -638375. -291538. -407480. -1635811. -886300. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 396 converged, 159 successes so far. Misfit function evaluations this try => 219 Misfit this try = 6.232084E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.034496E-06 Bayes score, PP * exp(-Misfit) = 9.719930E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 10801.0 916.229 0.717325 0.802058 Final coordinates: 8561.15 914.496 0.427428 0.487248 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.232084E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.005 0.021749 0.002854 0.000000 0.075686 0.006686 0.000000 0.005891 0.286638 0.600495 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.4 -0.1 Chi 6.0E-03 0. 0. 1.0E-03 3.0E-03 0. 9.9E-03 1.3E-04 4.1E-07 Composition Misfit: 2.290380E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.362 0.000000 0.032116 0.000000 0.000000 0.301262 0.035862 0.067772 0.136719 0.426270 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.2 -1. 0.5 -0.2 Chi 0. 4.2E-03 0. 0. 1.4E-03 7.3E-05 2.5E-03 3.7E-04 6.1E-06 Composition Misfit: 8.517351E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.537 0.094788 0.057570 0.000000 0.001427 0.000000 0.000000 0.000000 0.153785 0.692430 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. -2.0E-02 0. 0. 0. 0.5 0.1 Chi 1.0E-04 6.2E-04 0. 3.3E-06 0. 0. 0. 3.3E-04 6.2E-06 Composition Misfit: 1.062326E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.605 0.000000 0.000000 0.024511 0.075670 0.198550 0.000857 0.179816 0.135055 0.385542 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.9 0.2 -0.7 0.4 2. Chi 0. 0. 4.0E-04 1.0E-03 1.0E-03 3.8E-04 5.9E-04 2.0E-04 2.4E-03 Composition Misfit: 5.975879E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.322 0.000000 0.000000 0.004624 0.000000 0.149905 0.002425 0.051798 0.427844 0.363403 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.6E-03 0. 2.4E-03 8.2E-04 1.6E-02 1.0E-03 1.4E-03 Composition Misfit: 2.331936E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.340 0.000000 0.000000 0.350833 0.000000 0.628509 0.008665 0.011992 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -4.6E-02 0. 0.1 0.2 -0.3 0. 0. Chi 0. 0. 2.0E-06 0. 3.5E-06 2.1E-04 3.3E-04 0. 0. Composition Misfit: 5.421287E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.617 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.212 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023331 0.014762 0.006985 0.016484 0.052967 0.000919 0.040346 0.028365 0.001415 0.108566 0.705859 Mica 0.018150 0.002381 0.000000 0.063160 0.005580 0.000000 0.004916 0.165001 0.000501 0.239199 0.501112 Gt 0.000000 0.032030 0.000000 0.000000 0.300455 0.035766 0.067590 0.000000 0.002678 0.136353 0.425128 Fsp 0.094788 0.057570 0.000000 0.001427 0.000000 0.000000 0.000000 0.000000 0.000000 0.153785 0.692430 Bio 0.000000 0.000000 0.021664 0.066883 0.175494 0.000757 0.158936 0.112102 0.004020 0.119372 0.340772 St 0.000000 0.000000 0.004206 0.000000 0.136341 0.002206 0.047111 0.088139 0.002345 0.389131 0.330521 Ilm 0.000000 0.000000 0.326483 0.000000 0.584887 0.008064 0.011160 0.000000 0.069407 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -773159. -753072. -930397. -847347. -312618. -467323. -637521. -290553. -409557. -1633913. -885095. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 398 converged, 160 successes so far. Misfit function evaluations this try => 202 Misfit this try = 0.118913 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.458494E-07 Bayes score, PP * exp(-Misfit) = 8.398058E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 5808.47 841.801 0.846735 0.788715 Final coordinates: 8479.24 923.687 0.595955 0.550599 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.118907 Extraneous predicted phases: 5.372537E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.512 0.021716 0.003047 0.000000 0.075617 0.006674 0.000000 0.006014 0.286659 0.600272 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.4 -3.5E-02 Chi 5.9E-03 0. 0. 1.0E-03 3.0E-03 0. 9.4E-03 1.3E-04 1.2E-07 Composition Misfit: 2.259519E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.741 0.000000 0.030510 0.000000 0.000000 0.288780 0.046657 0.071104 0.136691 0.426259 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -1. -2. 0.5 -0.2 Chi 0. 3.3E-03 0. 0. 3.8E-03 3.3E-03 3.7E-03 3.7E-04 6.0E-06 Composition Misfit: 1.447673E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.311 0.094105 0.058829 0.000000 0.001480 0.000000 0.000000 0.000000 0.154414 0.691171 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -3.5E-02 0. 0. 0. 0.4 0.1 Chi 6.4E-05 8.9E-04 0. 1.0E-05 0. 0. 0. 2.7E-04 1.6E-05 Composition Misfit: 1.251741E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.254 0.000000 0.000000 0.024672 0.075746 0.192181 0.001168 0.185290 0.136193 0.384750 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.5 0.1 -1. 0.3 2. Chi 0. 0. 4.4E-04 1.0E-03 3.1E-04 5.6E-05 1.3E-03 1.2E-04 2.5E-03 Composition Misfit: 5.827543E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.083 0.000000 0.000000 0.004699 0.000000 0.145579 0.003314 0.055384 0.427662 0.363363 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.1 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.5E-03 8.3E-05 1.9E-02 1.0E-03 1.4E-03 Composition Misfit: 2.449887E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.505 0.000000 0.000000 0.253182 0.000000 0.727618 0.010276 0.008924 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -4. -4.4E-02 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.3E-02 7.4E-06 1.3E-04 0. 0. Composition Misfit: 5.025726E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.008 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.579 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.007 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000021 -.000021 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023232 0.014700 0.006955 0.016415 0.052743 0.000915 0.040175 0.031918 0.001965 0.108107 0.702875 Mica 0.018121 0.002543 0.000000 0.063102 0.005569 0.000000 0.005019 0.164989 0.000523 0.239214 0.500920 Gt 0.000000 0.030428 0.000000 0.000000 0.288003 0.046532 0.070912 0.000000 0.002691 0.136323 0.425112 Fsp 0.094105 0.058829 0.000000 0.001480 0.000000 0.000000 0.000000 0.000000 0.000000 0.154414 0.691171 Bio 0.000000 0.000000 0.021805 0.066946 0.169852 0.001032 0.163762 0.112086 0.004101 0.120370 0.340047 St 0.000000 0.000000 0.004273 0.000000 0.132402 0.003014 0.050371 0.088127 0.002384 0.388954 0.330475 Ilm 0.000000 0.000000 0.225370 0.000000 0.647688 0.009147 0.007944 0.000000 0.109852 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775794. -754490. -931681. -850217. -314117. -466602. -638194. -291345. -408428. -1635558. -886279. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 399 converged, 161 successes so far. Misfit function evaluations this try => 184 Misfit this try = 0.125892 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.004063E-06 Bayes score, PP * exp(-Misfit) = 8.852926E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 11169.2 880.523 0.923630 0.218384 Final coordinates: 8702.36 922.671 0.645977 0.621514 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.125863 Extraneous predicted phases: 2.901200E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.758 0.022913 0.003370 0.000000 0.074257 0.006486 0.000000 0.006190 0.286807 0.599977 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 0.7 0. 1. -0.4 3.0E-03 Chi 6.9E-03 0. 0. 1.4E-03 3.4E-03 0. 8.7E-03 1.4E-04 9.2E-10 Composition Misfit: 2.389337E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.687 0.000000 0.033195 0.000000 0.000000 0.285673 0.044605 0.073967 0.136407 0.426153 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -1. -2. 0.5 -0.2 Chi 0. 4.8E-03 0. 0. 4.6E-03 2.4E-03 5.0E-03 4.0E-04 5.2E-06 Composition Misfit: 1.720200E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.800 0.093850 0.059518 0.000000 0.001391 0.000000 0.000000 0.000000 0.154759 0.690482 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. -9.7E-03 0. 0. 0. 0.4 0.2 Chi 5.2E-05 1.1E-03 0. 8.1E-07 0. 0. 0. 2.4E-04 2.3E-05 Composition Misfit: 1.373666E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.434 0.000000 0.000000 0.024379 0.075623 0.185797 0.001099 0.193011 0.134349 0.385740 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.1 0.1 -2. 0.4 2. Chi 0. 0. 3.7E-04 9.9E-04 9.4E-06 9.6E-05 2.9E-03 2.6E-04 2.4E-03 Composition Misfit: 6.963545E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.600 0.000000 0.000000 0.004833 0.000000 0.142567 0.003134 0.058549 0.427566 0.363350 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.8 0.1 -4. 1. 1. Chi 0. 0. 1.3E-03 0. 9.3E-04 1.6E-04 2.2E-02 1.0E-03 1.5E-03 Composition Misfit: 2.653375E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.598 0.000000 0.000000 0.253362 0.000000 0.727259 0.009904 0.009476 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -4. 1.5E-02 0.1 0. 0. Chi 0. 0. 3.7E-02 0. 1.3E-02 9.4E-07 2.9E-05 0. 0. Composition Misfit: 4.989696E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.413 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.694 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.017 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000019 -.000019 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023133 0.014637 0.006926 0.016345 0.052519 0.000911 0.040004 0.035875 0.002120 0.107647 0.699882 Mica 0.019121 0.002812 0.000000 0.061967 0.005413 0.000000 0.005165 0.164989 0.000514 0.239339 0.500679 Gt 0.000000 0.033101 0.000000 0.000000 0.284869 0.044480 0.073759 0.000000 0.002814 0.136023 0.424954 Fsp 0.093850 0.059518 0.000000 0.001391 0.000000 0.000000 0.000000 0.000000 0.000000 0.154759 0.690482 Bio 0.000000 0.000000 0.021546 0.066834 0.164204 0.000972 0.170579 0.112123 0.004098 0.118735 0.340909 St 0.000000 0.000000 0.004396 0.000000 0.129664 0.002850 0.053250 0.088124 0.002379 0.388870 0.330466 Ilm 0.000000 0.000000 0.225547 0.000000 0.647419 0.008816 0.008436 0.000000 0.109781 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774645. -753495. -930916. -849344. -313902. -466623. -637569. -290761. -407393. -1634912. -885657. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 401 converged, 162 successes so far. Misfit function evaluations this try => 222 Misfit this try = 0.270352 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 8.524609E-07 Bayes score, PP * exp(-Misfit) = 6.505224E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 6959.42 927.295 0.267527 0.948645 Final coordinates: 7943.92 917.747 0.490472 0.900552 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 8.812319E-2 Extraneous predicted phases: 0.182228 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.799 0.021278 0.002857 0.000000 0.076228 0.006240 0.000000 0.005641 0.287567 0.600190 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.8 0. 1. -0.4 -2.4E-02 Chi 5.6E-03 0. 0. 8.9E-04 3.9E-03 0. 1.1E-02 1.7E-04 6.0E-08 Composition Misfit: 2.447436E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.117 0.000000 0.027928 0.000000 0.000000 0.274772 0.064757 0.068922 0.137179 0.426442 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.9 0. 0. 3. -3. -1. 0.5 -0.2 Chi 0. 2.0E-03 0. 0. 8.1E-03 1.4E-02 2.9E-03 3.2E-04 7.5E-06 Composition Misfit: 2.764042E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.726 0.093523 0.060002 0.000000 0.001476 0.000000 0.000000 0.000000 0.155001 0.689998 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. -3.4E-02 0. 0. 0. 0.4 0.2 Chi 3.8E-05 1.2E-03 0. 9.5E-06 0. 0. 0. 2.2E-04 2.9E-05 Composition Misfit: 1.478503E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.792 0.000000 0.000000 0.024678 0.075870 0.190149 0.001608 0.185963 0.138056 0.383674 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.4 -0.1 -1. 0.2 2. Chi 0. 0. 4.4E-04 1.0E-03 1.7E-04 2.1E-05 1.5E-03 3.7E-05 2.7E-03 Composition Misfit: 5.890430E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.348 0.000000 0.000000 0.004621 0.000000 0.144207 0.004711 0.055241 0.427823 0.363397 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. -0.2 -4. 1. 1. Chi 0. 0. 1.6E-03 0. 1.2E-03 1.6E-04 1.9E-02 1.0E-03 1.4E-03 Composition Misfit: 2.430397E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.398 0.000000 0.000000 0.329893 0.000000 0.641596 0.016510 0.012001 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 1. 0. -0.5 -1. -0.3 0. 0. Chi 0. 0. 1.2E-03 0. 2.1E-04 2.6E-03 3.3E-04 0. 0. Composition Misfit: 4.335502E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.485 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 1.336 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000020 -.000020 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022778 0.014413 0.006819 0.016094 0.051712 0.000897 0.039390 0.051183 0.001585 0.105994 0.689134 Mica 0.017754 0.002383 0.000000 0.063604 0.005206 0.000000 0.004707 0.165099 0.000508 0.239944 0.500794 Gt 0.000000 0.027859 0.000000 0.000000 0.274091 0.064596 0.068751 0.000000 0.002478 0.136839 0.425385 Fsp 0.093523 0.060002 0.000000 0.001476 0.000000 0.000000 0.000000 0.000000 0.000000 0.155001 0.689998 Bio 0.000000 0.000000 0.021806 0.067039 0.168015 0.001421 0.164315 0.112271 0.004136 0.121985 0.339012 St 0.000000 0.000000 0.004203 0.000000 0.131158 0.004285 0.050242 0.088137 0.002353 0.389109 0.330514 Ilm 0.000000 0.000000 0.304034 0.000000 0.591304 0.015216 0.011060 0.000000 0.078386 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776844. -755207. -931877. -851408. -314223. -463868. -638319. -291603. -408340. -1635768. -886862. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Sp Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Sp Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Sp Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Sp Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 412 converged, 163 successes so far. Misfit function evaluations this try => 217 Misfit this try = 8.073827E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 5.381816E-07 Bayes score, PP * exp(-Misfit) = 4.964376E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 6166.41 820.207 0.635261 0.336342 Final coordinates: 7825.43 850.866 0.414166 0.479887 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 8.073827E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.002 0.023730 0.002221 0.000000 0.074278 0.005004 0.000000 0.004710 0.289648 0.600409 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 0.9 0. 1. -0.5 -0.1 Chi 7.5E-03 0. 0. 1.4E-03 7.6E-03 0. 1.7E-02 2.9E-04 2.8E-07 Composition Misfit: 3.558173E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.354 0.000000 0.039926 0.000000 0.000000 0.302410 0.039289 0.054791 0.137152 0.426432 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -0.6 3.2E-04 0.5 -0.2 Chi 0. 9.4E-03 0. 0. 1.3E-03 6.5E-04 2.0E-10 3.3E-04 7.4E-06 Composition Misfit: 1.164366E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.428 0.095340 0.057343 0.000000 0.000988 0.000000 0.000000 0.000000 0.153672 0.692657 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.4E-04 5.8E-04 0. 1.4E-04 0. 0. 0. 3.4E-04 4.9E-06 Composition Misfit: 1.201592E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.805 0.000000 0.000000 0.022206 0.075299 0.202144 0.000691 0.181634 0.129480 0.388546 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.1 -1. -1. 0.2 -0.8 0.8 1. Chi 0. 0. 3.2E-05 9.3E-04 1.5E-03 7.8E-04 8.1E-04 9.1E-04 1.9E-03 Composition Misfit: 6.928557E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.241 0.000000 0.000000 0.003986 0.000000 0.157264 0.002182 0.044251 0.428740 0.363577 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -2. 0.4 -3. 1. 1. Chi 0. 0. 2.8E-03 0. 4.4E-03 1.3E-03 1.0E-02 9.2E-04 1.4E-03 Composition Misfit: 2.105035E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.405 0.000000 0.000000 0.380860 0.000000 0.601012 0.008123 0.010005 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 1. 0.3 -7.6E-04 0. 0. Chi 0. 0. 2.5E-03 0. 1.4E-03 4.3E-04 2.3E-09 0. 0. Composition Misfit: 4.332386E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.791 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.973 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023342 0.014769 0.006988 0.016492 0.052992 0.000920 0.040365 0.027950 0.001372 0.108618 0.706193 Mica 0.019796 0.001853 0.000000 0.061966 0.004174 0.000000 0.003929 0.165378 0.000374 0.241638 0.500890 Gt 0.000000 0.039827 0.000000 0.000000 0.301657 0.039191 0.054655 0.000000 0.002490 0.136811 0.425370 Fsp 0.095340 0.057343 0.000000 0.000988 0.000000 0.000000 0.000000 0.000000 0.000000 0.153672 0.692657 Bio 0.000000 0.000000 0.019601 0.066464 0.178427 0.000610 0.160323 0.113327 0.004000 0.114288 0.342959 St 0.000000 0.000000 0.003625 0.000000 0.143046 0.001985 0.040250 0.088188 0.002226 0.389976 0.330704 Ilm 0.000000 0.000000 0.359448 0.000000 0.567222 0.007667 0.009442 0.000000 0.056221 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -761542. -746339. -923942. -835873. -305757. -459182. -633136. -286378. -409204. -1625656. -880072. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio F sill ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio F sill ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 416 converged, 164 successes so far. Misfit function evaluations this try => 206 Misfit this try = 0.230581 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.381746E-07 Bayes score, PP * exp(-Misfit) = 1.097206E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 5778.72 813.093 0.850832 0.838752 Final coordinates: 7052.96 812.650 0.835003 0.505028 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.230581 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.484 0.026554 0.002058 0.000000 0.071750 0.003649 0.000000 0.003743 0.292352 0.599895 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -3. 0. 0. 1. 1. 0. 1. -0.7 1.4E-02 Chi 9.9E-03 0. 0. 2.3E-03 1.5E-02 0. 2.6E-02 4.8E-04 1.9E-08 Composition Misfit: 5.578281E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.724 0.000000 0.043398 0.000000 0.000000 0.281332 0.062050 0.049073 0.137561 0.426585 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 2. -3. 0.5 0.4 -0.2 Chi 0. 1.2E-02 0. 0. 5.9E-03 1.2E-02 6.7E-04 2.9E-04 8.7E-06 Composition Misfit: 3.130630E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.166 0.094774 0.058954 0.000000 0.000749 0.000000 0.000000 0.000000 0.154477 0.691046 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.4 0.2 Chi 1.0E-04 9.2E-04 0. 5.0E-04 0. 0. 0. 2.7E-04 1.7E-05 Composition Misfit: 1.800773E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.683 0.000000 0.000000 0.020766 0.075100 0.194292 0.000895 0.192603 0.126493 0.389851 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 0.1 -1. -0.7 0.2 -2. 1. 1. Chi 0. 0. 1.7E-05 8.8E-04 5.0E-04 3.1E-04 2.8E-03 1.5E-03 1.7E-03 Composition Misfit: 7.736254E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.397 0.000000 0.000000 0.003738 0.000000 0.157147 0.003163 0.043180 0.429120 0.363652 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -2. 0.1 -3. 1. 1. Chi 0. 0. 3.5E-03 0. 4.3E-03 1.4E-04 9.5E-03 8.8E-04 1.4E-03 Composition Misfit: 1.972555E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.865 0.000000 0.000000 0.216657 0.000000 0.769557 0.009307 0.004480 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -6. 0.1 0.9 0. 0. Chi 0. 0. 0.1 0. 2.5E-02 5.2E-05 6.8E-03 0. 0. Composition Misfit: 0.114229 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.569 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.112 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023276 0.014727 0.006968 0.016445 0.052841 0.000917 0.040250 0.029330 0.002758 0.108308 0.704180 Mica 0.022146 0.001716 0.000000 0.059840 0.003043 0.000000 0.003122 0.165689 0.000299 0.243825 0.500319 Gt 0.000000 0.043298 0.000000 0.000000 0.280682 0.061907 0.048960 0.000000 0.002312 0.137243 0.425599 Fsp 0.094774 0.058954 0.000000 0.000749 0.000000 0.000000 0.000000 0.000000 0.000000 0.154477 0.691046 Bio 0.000000 0.000000 0.018311 0.066219 0.171317 0.000789 0.169827 0.114127 0.004123 0.111535 0.343751 St 0.000000 0.000000 0.003400 0.000000 0.142944 0.002877 0.039277 0.088209 0.002170 0.390336 0.330786 Ilm 0.000000 0.000000 0.189771 0.000000 0.674061 0.008152 0.003924 0.000000 0.124091 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -756304. -743251. -920421. -831351. -302540. -452106. -630703. -284283. -407532. -1621684. -877968. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 417 converged, 165 successes so far. Misfit function evaluations this try => 198 Misfit this try = 0.106652 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.028016E-07 Bayes score, PP * exp(-Misfit) = 9.240198E-08 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 6027.58 860.812 0.645423 4.878963E-02 Final coordinates: 7057.65 804.503 0.445401 0.485111 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.106652 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.062 0.024761 0.001741 0.000000 0.073672 0.003903 0.000000 0.003789 0.291823 0.600311 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 1. 0. 1. -0.7 -4.0E-02 Chi 8.4E-03 0. 0. 1.6E-03 1.3E-02 0. 2.5E-02 4.4E-04 1.6E-07 Composition Misfit: 5.073830E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.091 0.000000 0.045118 0.000000 0.000000 0.297059 0.048560 0.045361 0.137384 0.426519 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 1. -2. 0.9 0.5 -0.2 Chi 0. 1.3E-02 0. 0. 2.1E-03 4.2E-03 2.0E-03 3.0E-04 8.1E-06 Composition Misfit: 2.195248E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.400 0.095408 0.057683 0.000000 0.000750 0.000000 0.000000 0.000000 0.153842 0.692317 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.5E-04 6.4E-04 0. 4.9E-04 0. 0. 0. 3.2E-04 6.9E-06 Composition Misfit: 1.612380E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.850 0.000000 0.000000 0.020348 0.075064 0.205060 0.000668 0.182838 0.125953 0.390069 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 0.1 -1. -1. 0.2 -0.9 1. 1. Chi 0. 0. 5.1E-05 8.8E-04 2.1E-03 8.6E-04 9.7E-04 1.6E-03 1.7E-03 Composition Misfit: 8.175872E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.022 0.000000 0.000000 0.003367 0.000000 0.162835 0.002326 0.038530 0.429280 0.363662 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. 0.3 -2. 1. 1. Chi 0. 0. 4.7E-03 0. 6.2E-03 9.8E-04 6.3E-03 8.6E-04 1.4E-03 Composition Misfit: 2.045181E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.481 0.000000 0.000000 0.377565 0.000000 0.605754 0.008815 0.007866 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 1. 0.2 0.3 0. 0. Chi 0. 0. 2.0E-03 0. 9.7E-04 1.6E-04 5.8E-04 0. 0. Composition Misfit: 3.721348E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.173 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.921 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023333 0.014763 0.006985 0.016485 0.052970 0.000919 0.040348 0.028243 0.001474 0.108574 0.705906 Mica 0.020652 0.001452 0.000000 0.061446 0.003255 0.000000 0.003160 0.165648 0.000305 0.243394 0.500687 Gt 0.000000 0.045010 0.000000 0.000000 0.296349 0.048444 0.045252 0.000000 0.002389 0.137056 0.425500 Fsp 0.095408 0.057683 0.000000 0.000750 0.000000 0.000000 0.000000 0.000000 0.000000 0.153842 0.692317 Bio 0.000000 0.000000 0.017936 0.066165 0.180751 0.000589 0.161163 0.114394 0.004153 0.111021 0.343828 St 0.000000 0.000000 0.003063 0.000000 0.148111 0.002116 0.035046 0.088208 0.002215 0.390463 0.330778 Ilm 0.000000 0.000000 0.355785 0.000000 0.570811 0.008307 0.007412 0.000000 0.057686 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -754331. -742263. -920117. -828732. -301259. -452732. -630379. -283927. -408053. -1620498. -877149. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 418 converged, 166 successes so far. Misfit function evaluations this try => 183 Misfit this try = 6.864023E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.057648E-06 Bayes score, PP * exp(-Misfit) = 9.874864E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 13382.8 963.075 7.164445E-02 0.876999 Final coordinates: 8585.77 911.294 0.452655 0.577802 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.864023E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.365 0.022597 0.003055 0.000000 0.074760 0.006392 0.000000 0.005928 0.287034 0.600234 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.4 -3.0E-02 Chi 6.6E-03 0. 0. 1.3E-03 3.5E-03 0. 9.8E-03 1.5E-04 9.1E-08 Composition Misfit: 2.443195E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.013 0.000000 0.033853 0.000000 0.000000 0.294445 0.039485 0.069383 0.136607 0.426228 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.6 -1. 0.5 -0.2 Chi 0. 5.2E-03 0. 0. 2.6E-03 7.0E-04 3.1E-03 3.8E-04 5.8E-06 Composition Misfit: 1.194285E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.052 0.094324 0.058660 0.000000 0.001346 0.000000 0.000000 0.000000 0.154330 0.691340 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 3.5E-03 0. 0. 0. 0.5 0.1 Chi 7.6E-05 8.5E-04 0. 1.1E-07 0. 0. 0. 2.8E-04 1.4E-05 Composition Misfit: 1.220582E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.625 0.000000 0.000000 0.024206 0.075595 0.192453 0.000926 0.186789 0.133923 0.386109 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.5 0.1 -1. 0.5 2. Chi 0. 0. 3.3E-04 9.9E-04 3.3E-04 2.7E-04 1.6E-03 3.0E-04 2.3E-03 Composition Misfit: 6.129167E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.079 0.000000 0.000000 0.004695 0.000000 0.147125 0.002662 0.054296 0.427819 0.363403 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.8E-03 5.2E-04 1.8E-02 1.0E-03 1.4E-03 Composition Misfit: 2.432937E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.404 0.000000 0.000000 0.352088 0.000000 0.625662 0.009662 0.012588 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.1 0. 0.2 0.1 -0.4 0. 0. Chi 0. 0. 1.2E-05 0. 3.0E-05 1.2E-05 5.3E-04 0. 0. Composition Misfit: 5.863116E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.968 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.494 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023207 0.014684 0.006948 0.016396 0.052685 0.000914 0.040131 0.033457 0.001491 0.107988 0.702099 Mica 0.018857 0.002549 0.000000 0.062386 0.005334 0.000000 0.004947 0.165035 0.000489 0.239523 0.500881 Gt 0.000000 0.033760 0.000000 0.000000 0.293642 0.039377 0.069193 0.000000 0.002727 0.136234 0.425065 Fsp 0.094324 0.058660 0.000000 0.001346 0.000000 0.000000 0.000000 0.000000 0.000000 0.154330 0.691340 Bio 0.000000 0.000000 0.021391 0.066806 0.170079 0.000819 0.165073 0.112221 0.004035 0.118353 0.341221 St 0.000000 0.000000 0.004270 0.000000 0.133814 0.002421 0.049384 0.088140 0.002335 0.389113 0.330524 Ilm 0.000000 0.000000 0.327842 0.000000 0.582577 0.008997 0.011721 0.000000 0.068863 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772400. -752351. -929771. -846857. -312398. -466179. -636976. -290090. -408623. -1633351. -884694. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 419 converged, 167 successes so far. Misfit function evaluations this try => 225 Misfit this try = 8.822041E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 2.678842E-07 Bayes score, PP * exp(-Misfit) = 2.452638E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 7818.73 894.572 0.180032 5.941603E-02 Final coordinates: 7381.75 828.925 0.450794 0.485500 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 8.821734E-2 Extraneous predicted phases: 3.074770E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 0.023739 0.001941 0.000000 0.074495 0.004525 0.000000 0.004264 0.290635 0.600401 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 1. 0. 1. -0.6 -0.1 Chi 7.5E-03 0. 0. 1.3E-03 9.7E-03 0. 2.0E-02 3.5E-04 2.7E-07 Composition Misfit: 4.109368E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.103 0.000000 0.041528 0.000000 0.000000 0.297848 0.046627 0.050282 0.137247 0.426468 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 1. -1. 0.4 0.5 -0.2 Chi 0. 1.1E-02 0. 0. 1.9E-03 3.3E-03 4.1E-04 3.2E-04 7.7E-06 Composition Misfit: 1.656061E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.444 0.095252 0.057747 0.000000 0.000875 0.000000 0.000000 0.000000 0.153873 0.692253 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.4E-04 6.6E-04 0. 2.7E-04 0. 0. 0. 3.2E-04 7.3E-06 Composition Misfit: 1.386058E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.840 0.000000 0.000000 0.021282 0.075216 0.203494 0.000735 0.182160 0.128235 0.388878 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 1.1E-02 -1. -1. 0.2 -0.9 0.9 1. Chi 0. 0. 3.5E-07 9.1E-04 1.8E-03 6.5E-04 8.8E-04 1.1E-03 1.9E-03 Composition Misfit: 7.234870E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.327 0.000000 0.000000 0.003625 0.000000 0.159834 0.002438 0.041593 0.428918 0.363591 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -2. 0.3 -2. 1. 1. Chi 0. 0. 3.8E-03 0. 5.2E-03 8.1E-04 8.4E-03 9.0E-04 1.4E-03 Composition Misfit: 2.047564E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.454 0.000000 0.000000 0.366924 0.000000 0.615479 0.009025 0.008572 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.9 0. 0.7 0.2 0.2 0. 0. Chi 0. 0. 7.8E-04 0. 3.4E-04 1.1E-04 2.4E-04 0. 0. Composition Misfit: 1.466486E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.823 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.007 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.001 0.000000 0.000000 0.184884 0.000000 0.679526 0.005858 0.003685 0.000000 0.126047 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023332 0.014763 0.006985 0.016485 0.052969 0.000919 0.040347 0.028264 0.001492 0.108569 0.705876 Mica 0.019802 0.001619 0.000000 0.062140 0.003774 0.000000 0.003557 0.165503 0.000350 0.242433 0.500822 Gt 0.000000 0.041427 0.000000 0.000000 0.297119 0.046512 0.050159 0.000000 0.002448 0.136911 0.425424 Fsp 0.095252 0.057747 0.000000 0.000875 0.000000 0.000000 0.000000 0.000000 0.000000 0.153873 0.692253 Bio 0.000000 0.000000 0.018769 0.066337 0.179472 0.000648 0.160657 0.113904 0.004144 0.113097 0.342972 St 0.000000 0.000000 0.003297 0.000000 0.145377 0.002217 0.037831 0.088188 0.002262 0.390122 0.330704 Ilm 0.000000 0.000000 0.344033 0.000000 0.577082 0.008462 0.008037 0.000000 0.062387 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -758482. -744625. -922351. -832821. -303726. -455673. -631926. -285327. -408142. -1623350. -878849. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 420 converged, 168 successes so far. Misfit function evaluations this try => 179 Misfit this try = 6.196070E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.018327E-06 Bayes score, PP * exp(-Misfit) = 9.571457E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 6427.42 889.507 0.546576 0.178796 Final coordinates: 8585.56 917.798 0.428724 0.489201 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.196070E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.016 0.021627 0.002884 0.000000 0.075781 0.006770 0.000000 0.005942 0.286499 0.600497 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.4 -0.1 Chi 5.9E-03 0. 0. 9.9E-04 2.8E-03 0. 9.7E-03 1.3E-04 4.1E-07 Composition Misfit: 2.244693E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.337 0.000000 0.031693 0.000000 0.000000 0.300875 0.036072 0.068385 0.136709 0.426266 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.2 -1. 0.5 -0.2 Chi 0. 3.9E-03 0. 0. 1.5E-03 9.2E-05 2.7E-03 3.7E-04 6.1E-06 Composition Misfit: 8.561772E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.543 0.094737 0.057618 0.000000 0.001454 0.000000 0.000000 0.000000 0.153809 0.692382 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. -2.8E-02 0. 0. 0. 0.5 0.1 Chi 1.0E-04 6.3E-04 0. 6.4E-06 0. 0. 0. 3.3E-04 6.5E-06 Composition Misfit: 1.069501E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.582 0.000000 0.000000 0.024635 0.075693 0.198352 0.000876 0.179690 0.135392 0.385362 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.9 0.2 -0.7 0.4 2. Chi 0. 0. 4.3E-04 1.0E-03 9.7E-04 3.4E-04 5.8E-04 1.8E-04 2.4E-03 Composition Misfit: 5.941288E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.466 0.000000 0.000000 0.004657 0.000000 0.149520 0.002465 0.052155 0.427807 0.363396 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 2.3E-03 7.7E-04 1.6E-02 1.0E-03 1.4E-03 Composition Misfit: 2.341427E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.337 0.000000 0.000000 0.348409 0.000000 0.630750 0.008784 0.012056 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. -3.4E-02 0.2 -0.3 0. 0. Chi 0. 0. 7.3E-06 0. 8.9E-07 1.7E-04 3.5E-04 0. 0. Composition Misfit: 5.269433E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.483 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.237 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023328 0.014761 0.006984 0.016482 0.052961 0.000919 0.040341 0.028475 0.001419 0.108553 0.705776 Mica 0.018048 0.002407 0.000000 0.063240 0.005649 0.000000 0.004959 0.164983 0.000508 0.239086 0.501120 Gt 0.000000 0.031608 0.000000 0.000000 0.300068 0.035975 0.068201 0.000000 0.002683 0.136342 0.425122 Fsp 0.094737 0.057618 0.000000 0.001454 0.000000 0.000000 0.000000 0.000000 0.000000 0.153809 0.692382 Bio 0.000000 0.000000 0.021776 0.066908 0.175331 0.000774 0.158835 0.112040 0.004020 0.119678 0.340637 St 0.000000 0.000000 0.004236 0.000000 0.135991 0.002242 0.047436 0.088137 0.002348 0.389097 0.330514 Ilm 0.000000 0.000000 0.323862 0.000000 0.586311 0.008166 0.011206 0.000000 0.070455 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -773833. -753466. -930773. -848013. -313002. -467685. -637771. -290800. -409573. -1634386. -885396. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 422 converged, 169 successes so far. Misfit function evaluations this try => 173 Misfit this try = 0.184378 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 3.988469E-07 Bayes score, PP * exp(-Misfit) = 3.316897E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 5684.27 883.513 0.706626 0.585211 Final coordinates: 6817.63 858.135 0.667383 0.512796 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.184378 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.075 0.021849 0.001998 0.000000 0.076337 0.004744 0.000000 0.004358 0.290402 0.600313 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 1. 0. 1. -0.6 -4.0E-02 Chi 6.0E-03 0. 0. 8.6E-04 8.7E-03 0. 1.9E-02 3.4E-04 1.6E-07 Composition Misfit: 3.728166E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.294 0.000000 0.028894 0.000000 0.000000 0.268487 0.082637 0.055055 0.138130 0.426799 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 3. -5. -2.5E-02 0.4 -0.3 Chi 0. 2.4E-03 0. 0. 1.1E-02 2.8E-02 1.2E-06 2.4E-04 1.1E-05 Composition Misfit: 4.162778E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.596 0.094274 0.059214 0.000000 0.001118 0.000000 0.000000 0.000000 0.154607 0.690786 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 0.1 0. 0. 0. 0.4 0.2 Chi 7.3E-05 9.8E-04 0. 5.1E-05 0. 0. 0. 2.6E-04 2.0E-05 Composition Misfit: 1.380375E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.584 0.000000 0.000000 0.022918 0.075725 0.196617 0.001576 0.182610 0.135880 0.384674 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.2 -1. -0.8 -4.3E-02 -0.9 0.3 2. Chi 0. 0. 1.0E-04 1.0E-03 7.5E-04 1.5E-05 9.4E-04 1.4E-04 2.5E-03 Composition Misfit: 5.513118E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.292 0.000000 0.000000 0.003966 0.000000 0.152152 0.005201 0.046456 0.428668 0.363557 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -2. -0.3 -3. 1. 1. Chi 0. 0. 2.9E-03 0. 2.9E-03 3.6E-04 1.2E-02 9.2E-04 1.4E-03 Composition Misfit: 2.040331E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.589 0.000000 0.000000 0.235184 0.000000 0.743660 0.015292 0.005864 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -5. -0.8 0.7 0. 0. Chi 0. 0. 0.1 0. 1.7E-02 1.8E-03 2.9E-03 0. 0. Composition Misfit: 7.817157E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.974 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.596 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023278 0.014729 0.006969 0.016447 0.052847 0.000917 0.040254 0.029784 0.002204 0.108319 0.704252 Mica 0.018225 0.001666 0.000000 0.063675 0.003957 0.000000 0.003635 0.165467 0.000396 0.242235 0.500743 Gt 0.000000 0.028834 0.000000 0.000000 0.267932 0.082466 0.054941 0.000000 0.002064 0.137845 0.425918 Fsp 0.094274 0.059214 0.000000 0.001118 0.000000 0.000000 0.000000 0.000000 0.000000 0.154607 0.690786 Bio 0.000000 0.000000 0.020223 0.066819 0.173491 0.001391 0.161132 0.113415 0.004201 0.119898 0.339430 St 0.000000 0.000000 0.003608 0.000000 0.138392 0.004731 0.042255 0.088181 0.002254 0.389901 0.330678 Ilm 0.000000 0.000000 0.207685 0.000000 0.656706 0.013504 0.005179 0.000000 0.116926 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -767790. -750454. -926621. -842517. -308272. -455805. -634878. -288416. -408458. -1628935. -883128. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 424 converged, 170 successes so far. Misfit function evaluations this try => 245 Misfit this try = 6.120199E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.515181E-07 Bayes score, PP * exp(-Misfit) = 8.950295E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 7844.72 872.692 0.179061 0.297591 Final coordinates: 8622.00 926.396 0.426048 0.495630 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.120199E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 0.021277 0.002951 0.000000 0.076070 0.006974 0.000000 0.006053 0.286174 0.600501 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.3E-04 2.5E-03 0. 9.3E-03 1.1E-04 4.2E-07 Composition Misfit: 2.137706E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.232 0.000000 0.030388 0.000000 0.000000 0.299416 0.037343 0.069870 0.136715 0.426268 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.3 -1. 0.5 -0.2 Chi 0. 3.2E-03 0. 0. 1.7E-03 2.6E-04 3.3E-03 3.7E-04 6.1E-06 Composition Misfit: 8.763647E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.574 0.094576 0.057785 0.000000 0.001531 0.000000 0.000000 0.000000 0.153892 0.692215 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 9.1E-05 6.6E-04 0. 2.0E-05 0. 0. 0. 3.2E-04 7.5E-06 Composition Misfit: 1.099443E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.551 0.000000 0.000000 0.024988 0.075761 0.198055 0.000943 0.179008 0.136417 0.384828 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.2E-04 1.0E-03 9.3E-04 2.5E-04 5.0E-04 1.1E-04 2.5E-03 Composition Misfit: 5.859015E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.951 0.000000 0.000000 0.004742 0.000000 0.148535 0.002622 0.052993 0.427725 0.363383 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.1E-03 5.6E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.355523E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.319 0.000000 0.000000 0.346924 0.000000 0.631375 0.009300 0.012401 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.2 0. -0.1 0.1 -0.4 0. 0. Chi 0. 0. 2.7E-05 0. 3.0E-06 5.3E-05 4.6E-04 0. 0. Composition Misfit: 5.476024E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.049 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.324 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023320 0.014755 0.006982 0.016476 0.052942 0.000919 0.040326 0.028839 0.001410 0.108514 0.705518 Mica 0.017757 0.002463 0.000000 0.063483 0.005820 0.000000 0.005051 0.164942 0.000524 0.238822 0.501138 Gt 0.000000 0.030306 0.000000 0.000000 0.298613 0.037243 0.069682 0.000000 0.002680 0.136349 0.425126 Fsp 0.094576 0.057785 0.000000 0.001531 0.000000 0.000000 0.000000 0.000000 0.000000 0.153892 0.692215 Bio 0.000000 0.000000 0.022092 0.066982 0.175103 0.000833 0.158264 0.111871 0.004015 0.120609 0.340232 St 0.000000 0.000000 0.004313 0.000000 0.135094 0.002385 0.048198 0.088134 0.002352 0.389022 0.330502 Ilm 0.000000 0.000000 0.322259 0.000000 0.586487 0.008639 0.011519 0.000000 0.071096 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775715. -754579. -931784. -849866. -314034. -468513. -638474. -291492. -409819. -1635684. -886246. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 425 converged, 171 successes so far. Misfit function evaluations this try => 245 Misfit this try = 0.231766 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.102002E-06 Bayes score, PP * exp(-Misfit) = 8.740328E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 12607.7 985.688 0.939495 0.598299 Final coordinates: 9049.41 918.993 1.00000 0.679372 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.231766 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.066 0.025532 0.004055 0.000000 0.071299 0.006207 0.000000 0.006494 0.287197 0.599216 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 0.8 0. 1. -0.4 0.1 Chi 9.0E-03 0. 0. 2.4E-03 3.9E-03 0. 7.7E-03 1.6E-04 1.0E-06 Composition Misfit: 2.726381E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.746 0.000000 0.039072 0.000000 0.000000 0.277164 0.042245 0.080780 0.135083 0.425656 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 3. -0.9 -2. 0.6 -0.1 Chi 0. 8.8E-03 0. 0. 7.2E-03 1.5E-03 8.4E-03 5.7E-04 2.3E-06 Composition Misfit: 2.645095E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.927 0.093521 0.060487 0.000000 0.001236 0.000000 0.000000 0.000000 0.155244 0.689513 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.9 0. 3.5E-02 0. 0. 0. 0.4 0.2 Chi 3.7E-05 1.3E-03 0. 1.2E-05 0. 0. 0. 2.1E-04 3.6E-05 Composition Misfit: 1.598580E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.999 0.000000 0.000000 0.022106 0.075344 0.172102 0.000998 0.212106 0.130155 0.387191 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.1 -1. 0.8 0.1 -3. 0.7 1. Chi 0. 0. 2.5E-05 9.3E-04 8.9E-04 1.8E-04 8.6E-03 7.9E-04 2.1E-03 Composition Misfit: 1.351292E-2 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.427 0.000000 0.000000 0.004129 0.000000 0.136052 0.002900 0.066374 0.427319 0.363228 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -0.4 0.2 -5. 1. 1. Chi 0. 0. 2.5E-03 0. 1.8E-04 3.0E-04 2.8E-02 1.1E-03 1.5E-03 Composition Misfit: 3.393329E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.041 0.000000 0.000000 0.207353 0.000000 0.778592 0.007017 0.007039 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 8. 0. -7. 0.5 0.5 0. 0. Chi 0. 0. 0.1 0. 2.8E-02 1.3E-03 1.2E-03 0. 0. Composition Misfit: 0.129006 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.076 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.719 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023030 0.014572 0.006895 0.016271 0.052283 0.000907 0.039825 0.039039 0.003268 0.107165 0.696746 Mica 0.021306 0.003384 0.000000 0.059497 0.005179 0.000000 0.005419 0.164990 0.000539 0.239657 0.500028 Gt 0.000000 0.038939 0.000000 0.000000 0.276225 0.042102 0.080506 0.000000 0.003390 0.134625 0.424213 Fsp 0.093521 0.060487 0.000000 0.001236 0.000000 0.000000 0.000000 0.000000 0.000000 0.155244 0.689513 Bio 0.000000 0.000000 0.019500 0.066463 0.151817 0.000880 0.187106 0.113426 0.004437 0.114814 0.341555 St 0.000000 0.000000 0.003754 0.000000 0.123710 0.002637 0.060353 0.088074 0.002638 0.388556 0.330278 Ilm 0.000000 0.000000 0.180885 0.000000 0.679208 0.006121 0.006140 0.000000 0.127646 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772352. -751661. -931068. -847627. -313471. -466262. -636188. -289648. -402110. -1633571. -884464. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 426 converged, 172 successes so far. Misfit function evaluations this try => 163 Misfit this try = 6.142110E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.791470E-07 Bayes score, PP * exp(-Misfit) = 9.208164E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 9093.16 966.889 0.126128 0.892054 Final coordinates: 8579.10 922.486 0.426000 0.495626 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.142110E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.010 0.021384 0.002912 0.000000 0.075998 0.006867 0.000000 0.005987 0.286354 0.600498 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.7E-03 0. 0. 9.4E-04 2.7E-03 0. 9.5E-03 1.2E-04 4.1E-07 Composition Misfit: 2.188163E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.226 0.000000 0.030801 0.000000 0.000000 0.299439 0.037652 0.069082 0.136746 0.426280 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.4 -1. 0.5 -0.2 Chi 0. 3.4E-03 0. 0. 1.7E-03 3.1E-04 3.0E-03 3.7E-04 6.2E-06 Composition Misfit: 8.737142E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.566 0.094607 0.057787 0.000000 0.001500 0.000000 0.000000 0.000000 0.153894 0.692213 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.1E-02 0. 0. 0. 0.5 0.1 Chi 9.2E-05 6.6E-04 0. 1.3E-05 0. 0. 0. 3.2E-04 7.6E-06 Composition Misfit: 1.095505E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.557 0.000000 0.000000 0.024852 0.075740 0.198206 0.000935 0.179169 0.136103 0.384996 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.9 0.1 -0.7 0.3 2. Chi 0. 0. 4.9E-04 1.0E-03 9.5E-04 2.6E-04 5.2E-04 1.3E-04 2.5E-03 Composition Misfit: 5.856263E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.905 0.000000 0.000000 0.004702 0.000000 0.148944 0.002616 0.052577 0.427770 0.363391 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 2.2E-03 5.7E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.336802E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.324 0.000000 0.000000 0.348557 0.000000 0.629853 0.009306 0.012284 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. 6.8E-03 0.1 -0.4 0. 0. Chi 0. 0. 6.0E-06 0. 3.4E-08 5.2E-05 4.2E-04 0. 0. Composition Misfit: 4.825365E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.100 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.313 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023320 0.014755 0.006982 0.016476 0.052942 0.000919 0.040326 0.028839 0.001410 0.108514 0.705518 Mica 0.017846 0.002430 0.000000 0.063422 0.005731 0.000000 0.004996 0.164965 0.000516 0.238968 0.501126 Gt 0.000000 0.030719 0.000000 0.000000 0.298641 0.037552 0.068898 0.000000 0.002666 0.136381 0.425143 Fsp 0.094607 0.057787 0.000000 0.001500 0.000000 0.000000 0.000000 0.000000 0.000000 0.153894 0.692213 Bio 0.000000 0.000000 0.021970 0.066957 0.175222 0.000826 0.158392 0.111945 0.004015 0.120320 0.340352 St 0.000000 0.000000 0.004276 0.000000 0.135467 0.002380 0.047820 0.088136 0.002349 0.389063 0.330510 Ilm 0.000000 0.000000 0.324022 0.000000 0.585517 0.008651 0.011419 0.000000 0.070391 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774981. -754146. -931368. -849142. -313601. -467980. -638191. -291217. -409759. -1635149. -885919. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 430 converged, 173 successes so far. Misfit function evaluations this try => 212 Misfit this try = 0.118303 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.780577E-07 Bayes score, PP * exp(-Misfit) = 8.689330E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 6945.32 833.292 0.854390 0.177441 Final coordinates: 8707.99 925.515 0.601522 0.537999 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.118303 Extraneous predicted phases: 5.886983E-9 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.650 0.022121 0.003171 0.000000 0.075123 0.006786 0.000000 0.006178 0.286370 0.600251 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.3 -3.2E-02 Chi 6.3E-03 0. 0. 1.2E-03 2.8E-03 0. 8.8E-03 1.2E-04 1.0E-07 Composition Misfit: 2.230673E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.029 0.000000 0.031884 0.000000 0.000000 0.293156 0.039883 0.072430 0.136471 0.426177 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -0.6 -2. 0.5 -0.2 Chi 0. 4.0E-03 0. 0. 2.8E-03 8.0E-04 4.3E-03 4.0E-04 5.4E-06 Composition Misfit: 1.234554E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.247 0.094312 0.058447 0.000000 0.001464 0.000000 0.000000 0.000000 0.154224 0.691553 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -3.1E-02 0. 0. 0. 0.5 0.1 Chi 7.5E-05 8.0E-04 0. 7.7E-06 0. 0. 0. 2.9E-04 1.3E-05 Composition Misfit: 1.187424E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.181 0.000000 0.000000 0.024623 0.075680 0.191643 0.000997 0.186535 0.135202 0.385319 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.5 0.1 -1. 0.4 2. Chi 0. 0. 4.3E-04 1.0E-03 2.7E-04 1.8E-04 1.6E-03 1.9E-04 2.4E-03 Composition Misfit: 6.070113E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.332 0.000000 0.000000 0.004758 0.000000 0.145466 0.002803 0.056029 0.427593 0.363351 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 1.4E-03 3.8E-04 2.0E-02 1.0E-03 1.5E-03 Composition Misfit: 2.523813E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.523 0.000000 0.000000 0.252832 0.000000 0.729354 0.008736 0.009079 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 0.1 0. 0. Chi 0. 0. 3.7E-02 0. 1.4E-02 1.8E-04 9.4E-05 0. 0. Composition Misfit: 5.115463E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.600 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.437 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000021 -.000021 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023249 0.014710 0.006960 0.016426 0.052781 0.000916 0.040204 0.031209 0.001984 0.108184 0.703376 Mica 0.018460 0.002646 0.000000 0.062692 0.005663 0.000000 0.005156 0.164951 0.000526 0.238982 0.500923 Gt 0.000000 0.031795 0.000000 0.000000 0.292339 0.039772 0.072228 0.000000 0.002786 0.136090 0.424989 Fsp 0.094312 0.058447 0.000000 0.001464 0.000000 0.000000 0.000000 0.000000 0.000000 0.154224 0.691553 Bio 0.000000 0.000000 0.021764 0.066893 0.169392 0.000882 0.164877 0.112022 0.004083 0.119505 0.340581 St 0.000000 0.000000 0.004327 0.000000 0.132299 0.002550 0.050958 0.088123 0.002390 0.388890 0.330463 Ilm 0.000000 0.000000 0.225022 0.000000 0.649132 0.007775 0.008080 0.000000 0.109991 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775191. -754060. -931451. -849631. -314033. -467823. -638026. -291142. -408303. -1635356. -885954. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio sill ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio sill ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 433 converged, 174 successes so far. Misfit function evaluations this try => 193 Misfit this try = 9.457091E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.990330E-07 Bayes score, PP * exp(-Misfit) = 1.810729E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 6119.37 930.504 8.562476E-02 6.830740E-02 Final coordinates: 7317.93 819.988 0.448095 0.481938 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.457091E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.018 0.024410 0.001897 0.000000 0.073884 0.004276 0.000000 0.004095 0.291101 0.600338 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 1. 0. 1. -0.6 -4.3E-02 Chi 8.1E-03 0. 0. 1.5E-03 1.1E-02 0. 2.2E-02 3.9E-04 1.9E-07 Composition Misfit: 4.477174E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.164 0.000000 0.043436 0.000000 0.000000 0.298873 0.045526 0.048474 0.137230 0.426461 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 1. -1. 0.6 0.5 -0.2 Chi 0. 1.2E-02 0. 0. 1.8E-03 2.8E-03 8.2E-04 3.2E-04 7.6E-06 Composition Misfit: 1.778128E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.415 0.095388 0.057576 0.000000 0.000824 0.000000 0.000000 0.000000 0.153788 0.692424 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.5E-04 6.2E-04 0. 3.4E-04 0. 0. 0. 3.3E-04 6.2E-06 Composition Misfit: 1.447361E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.857 0.000000 0.000000 0.020918 0.075143 0.204128 0.000682 0.182521 0.127147 0.389461 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 0.1 -1. -1. 0.2 -0.9 0.9 1. Chi 0. 0. 9.7E-06 8.9E-04 1.9E-03 8.1E-04 9.3E-04 1.4E-03 1.8E-03 Composition Misfit: 7.696155E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.013 0.000000 0.000000 0.003540 0.000000 0.161028 0.002298 0.040484 0.429036 0.363614 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.7 0. -2. 0.3 -2. 1. 1. Chi 0. 0. 4.1E-03 0. 5.6E-03 1.0E-03 7.6E-03 8.9E-04 1.4E-03 Composition Misfit: 2.059753E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.467 0.000000 0.000000 0.370934 0.000000 0.612169 0.008582 0.008314 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 0.8 0.2 0.3 0. 0. Chi 0. 0. 1.2E-03 0. 5.2E-04 2.3E-04 3.4E-04 0. 0. Composition Misfit: 2.276844E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.127 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.940 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023337 0.014766 0.006986 0.016488 0.052979 0.000919 0.040355 0.028063 0.001483 0.108593 0.706031 Mica 0.020361 0.001582 0.000000 0.061627 0.003566 0.000000 0.003415 0.165558 0.000332 0.242810 0.500748 Gt 0.000000 0.043329 0.000000 0.000000 0.298139 0.045414 0.048355 0.000000 0.002456 0.136893 0.425414 Fsp 0.095388 0.057576 0.000000 0.000824 0.000000 0.000000 0.000000 0.000000 0.000000 0.153788 0.692424 Bio 0.000000 0.000000 0.018445 0.066260 0.179996 0.000601 0.160944 0.114075 0.004142 0.112116 0.343420 St 0.000000 0.000000 0.003220 0.000000 0.146464 0.002090 0.036823 0.088194 0.002247 0.390234 0.330729 Ilm 0.000000 0.000000 0.348448 0.000000 0.575059 0.008062 0.007810 0.000000 0.060621 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -756704. -743598. -921419. -831080. -302745. -454814. -631280. -284720. -408056. -1622178. -878096. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 435 converged, 175 successes so far. Misfit function evaluations this try => 267 Misfit this try = 0.228993 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.098444E-06 Bayes score, PP * exp(-Misfit) = 8.736298E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 10338.7 979.312 0.947814 0.944463 Final coordinates: 9129.05 920.855 0.992778 0.681158 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.228993 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.205 0.025661 0.004132 0.000000 0.071121 0.006255 0.000000 0.006561 0.287094 0.599176 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 0.8 0. 1. -0.4 0.1 Chi 9.1E-03 0. 0. 2.5E-03 3.8E-03 0. 7.4E-03 1.5E-04 1.1E-06 Composition Misfit: 2.718761E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.820 0.000000 0.039412 0.000000 0.000000 0.278081 0.040357 0.081527 0.134998 0.425624 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.7 -3. 0.6 -0.1 Chi 0. 9.0E-03 0. 0. 6.9E-03 9.3E-04 8.8E-03 5.8E-04 2.2E-06 Composition Misfit: 2.621074E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.874 0.093563 0.060393 0.000000 0.001241 0.000000 0.000000 0.000000 0.155196 0.689607 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.9 0. 3.4E-02 0. 0. 0. 0.4 0.2 Chi 3.9E-05 1.3E-03 0. 1.1E-05 0. 0. 0. 2.1E-04 3.5E-05 Composition Misfit: 1.575833E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.904 0.000000 0.000000 0.022172 0.075334 0.171785 0.000958 0.212444 0.130015 0.387291 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.1 -1. 0.8 0.1 -3. 0.7 1. Chi 0. 0. 2.9E-05 9.3E-04 9.4E-04 2.3E-04 8.7E-03 8.2E-04 2.1E-03 Composition Misfit: 1.373760E-2 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.439 0.000000 0.000000 0.004172 0.000000 0.135743 0.002772 0.066809 0.427283 0.363222 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -0.3 0.2 -5. 1. 1. Chi 0. 0. 2.4E-03 0. 1.6E-04 4.1E-04 2.9E-02 1.1E-03 1.5E-03 Composition Misfit: 3.431502E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.036 0.000000 0.000000 0.208833 0.000000 0.777217 0.006746 0.007204 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 8. 0. -7. 0.5 0.4 0. 0. Chi 0. 0. 0.1 0. 2.8E-02 1.6E-03 1.1E-03 0. 0. Composition Misfit: 0.125966 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.022 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.700 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023028 0.014571 0.006894 0.016270 0.052279 0.000907 0.039822 0.039138 0.003244 0.107156 0.696691 Mica 0.021414 0.003448 0.000000 0.059350 0.005220 0.000000 0.005475 0.164975 0.000542 0.239575 0.500003 Gt 0.000000 0.039277 0.000000 0.000000 0.277128 0.040219 0.081248 0.000000 0.003426 0.134536 0.424166 Fsp 0.093563 0.060393 0.000000 0.001241 0.000000 0.000000 0.000000 0.000000 0.000000 0.155196 0.689607 Bio 0.000000 0.000000 0.019560 0.066461 0.151551 0.000845 0.187421 0.113362 0.004426 0.114701 0.341673 St 0.000000 0.000000 0.003793 0.000000 0.123430 0.002520 0.060748 0.088073 0.002638 0.388524 0.330274 Ilm 0.000000 0.000000 0.182294 0.000000 0.678446 0.005889 0.006289 0.000000 0.127083 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772434. -751685. -931099. -847719. -313604. -466771. -636234. -289682. -402108. -1633696. -884484. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 437 converged, 176 successes so far. Misfit function evaluations this try => 273 Misfit this try = 6.904947E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.009049E-06 Bayes score, PP * exp(-Misfit) = 9.417258E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 13755.1 811.591 0.424807 0.932636 Final coordinates: 8905.98 926.154 0.467568 0.541073 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.904947E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.910 0.022386 0.003228 0.000000 0.074806 0.006904 0.000000 0.006288 0.286097 0.600291 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.3 -3.7E-02 Chi 6.5E-03 0. 0. 1.2E-03 2.6E-03 0. 8.4E-03 1.1E-04 1.4E-07 Composition Misfit: 2.204303E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.451 0.000000 0.033097 0.000000 0.000000 0.299324 0.032294 0.072840 0.136324 0.426122 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. 0.2 -2. 0.5 -0.2 Chi 0. 4.8E-03 0. 0. 1.7E-03 1.2E-04 4.5E-03 4.1E-04 5.0E-06 Composition Misfit: 1.147088E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.126 0.094607 0.057881 0.000000 0.001452 0.000000 0.000000 0.000000 0.153941 0.692119 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -2.7E-02 0. 0. 0. 0.5 0.1 Chi 9.2E-05 6.8E-04 0. 6.1E-06 0. 0. 0. 3.1E-04 8.2E-06 Composition Misfit: 1.103716E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.000 0.000000 0.000000 0.024625 0.075625 0.192688 0.000805 0.186031 0.134372 0.385854 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.5 0.2 -1. 0.4 2. Chi 0. 0. 4.3E-04 9.9E-04 3.5E-04 4.8E-04 1.5E-03 2.6E-04 2.3E-03 Composition Misfit: 6.328885E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.353 0.000000 0.000000 0.004811 0.000000 0.146272 0.002237 0.055749 0.427579 0.363352 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.3E-03 0. 1.6E-03 1.1E-03 1.9E-02 1.0E-03 1.5E-03 Composition Misfit: 2.585418E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.409 0.000000 0.000000 0.333429 0.000000 0.646122 0.007956 0.012494 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.9 0. -0.7 0.3 -0.4 0. 0. Chi 0. 0. 8.2E-04 0. 4.0E-04 5.3E-04 5.0E-04 0. 0. Composition Misfit: 2.248770E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.453 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.297 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023255 0.014714 0.006962 0.016431 0.052795 0.000916 0.040214 0.031396 0.001543 0.108213 0.703561 Mica 0.018683 0.002694 0.000000 0.062430 0.005762 0.000000 0.005247 0.164919 0.000524 0.238764 0.500977 Gt 0.000000 0.033002 0.000000 0.000000 0.298471 0.032202 0.072632 0.000000 0.002850 0.135936 0.424907 Fsp 0.094607 0.057881 0.000000 0.001452 0.000000 0.000000 0.000000 0.000000 0.000000 0.153941 0.692119 Bio 0.000000 0.000000 0.021769 0.066854 0.170339 0.000712 0.164455 0.111939 0.004043 0.118788 0.341101 St 0.000000 0.000000 0.004376 0.000000 0.133034 0.002034 0.050703 0.088124 0.002381 0.388881 0.330466 Ilm 0.000000 0.000000 0.307794 0.000000 0.596446 0.007344 0.011533 0.000000 0.076882 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774424. -753590. -931129. -848821. -313785. -469332. -637859. -290916. -408580. -1635029. -885570. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 439 converged, 177 successes so far. Misfit function evaluations this try => 193 Misfit this try = 6.888893E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.868211E-07 Bayes score, PP * exp(-Misfit) = 9.211288E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 6234.64 970.406 0.664769 6.202850E-02 Final coordinates: 8229.07 895.565 0.392364 0.500641 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.888893E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.009 0.022055 0.002623 0.000000 0.075587 0.006055 0.000000 0.005474 0.287710 0.600495 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.8 0. 1. -0.4 -0.1 Chi 6.2E-03 0. 0. 1.0E-03 4.3E-03 0. 1.2E-02 1.8E-04 4.1E-07 Composition Misfit: 2.624820E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.123 0.000000 0.033119 0.000000 0.000000 0.298607 0.041215 0.063374 0.137225 0.426459 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -0.8 -0.8 0.5 -0.2 Chi 0. 4.8E-03 0. 0. 1.8E-03 1.2E-03 1.2E-03 3.2E-04 7.6E-06 Composition Misfit: 9.257075E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.532 0.094750 0.057908 0.000000 0.001296 0.000000 0.000000 0.000000 0.153954 0.692092 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 1.8E-02 0. 0. 0. 0.5 0.1 Chi 1.0E-04 6.9E-04 0. 2.9E-06 0. 0. 0. 3.1E-04 8.4E-06 Composition Misfit: 1.113985E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.633 0.000000 0.000000 0.024117 0.075619 0.199497 0.000908 0.179345 0.134281 0.386234 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. -1. 0.1 -0.7 0.4 2. Chi 0. 0. 3.1E-04 9.9E-04 1.1E-03 2.9E-04 5.4E-04 2.7E-04 2.3E-03 Composition Misfit: 5.829377E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.964 0.000000 0.000000 0.004554 0.000000 0.151653 0.002657 0.049334 0.428292 0.363511 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -2. 0.3 -3. 1. 1. Chi 0. 0. 1.7E-03 0. 2.8E-03 5.3E-04 1.4E-02 9.6E-04 1.4E-03 Composition Misfit: 2.154309E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.321 0.000000 0.000000 0.381571 0.000000 0.596490 0.009742 0.012197 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 2. 4.1E-02 -0.3 0. 0. Chi 0. 0. 2.6E-03 0. 1.9E-03 6.8E-06 4.0E-04 0. 0. Composition Misfit: 4.897206E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.142 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.275 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023316 0.014753 0.006980 0.016473 0.052932 0.000919 0.040319 0.029125 0.001298 0.108494 0.705391 Mica 0.018403 0.002189 0.000000 0.063071 0.005052 0.000000 0.004568 0.165137 0.000445 0.240070 0.501064 Gt 0.000000 0.033037 0.000000 0.000000 0.297873 0.041114 0.063219 0.000000 0.002458 0.136888 0.425411 Fsp 0.094750 0.057908 0.000000 0.001296 0.000000 0.000000 0.000000 0.000000 0.000000 0.153954 0.692092 Bio 0.000000 0.000000 0.021314 0.066829 0.176307 0.000802 0.158498 0.112344 0.003896 0.118672 0.341338 St 0.000000 0.000000 0.004142 0.000000 0.137944 0.002416 0.044874 0.088174 0.002222 0.389576 0.330651 Ilm 0.000000 0.000000 0.360240 0.000000 0.563144 0.009197 0.011515 0.000000 0.055904 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -770204. -751359. -928464. -844437. -310706. -464146. -636353. -289440. -410641. -1631644. -883826. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 441 converged, 178 successes so far. Misfit function evaluations this try => 162 Misfit this try = 6.113541E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.377218E-07 Bayes score, PP * exp(-Misfit) = 8.821110E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 8425.63 844.863 0.532404 0.579594 Final coordinates: 8603.26 927.367 0.420470 0.500436 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.113245E-2 Extraneous predicted phases: 2.962840E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.006 0.021198 0.002952 0.000000 0.076149 0.006977 0.000000 0.006049 0.286175 0.600500 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.5E-03 0. 0. 9.1E-04 2.5E-03 0. 9.3E-03 1.1E-04 4.2E-07 Composition Misfit: 2.130986E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.176 0.000000 0.030098 0.000000 0.000000 0.298738 0.038210 0.069900 0.136767 0.426288 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.4 -1. 0.5 -0.2 Chi 0. 3.0E-03 0. 0. 1.8E-03 4.1E-04 3.3E-03 3.7E-04 6.2E-06 Composition Misfit: 8.875635E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.578 0.094525 0.057865 0.000000 0.001542 0.000000 0.000000 0.000000 0.153933 0.692135 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.7E-05 6.8E-04 0. 2.2E-05 0. 0. 0. 3.2E-04 8.1E-06 Composition Misfit: 1.111947E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.535 0.000000 0.000000 0.025071 0.075779 0.198041 0.000970 0.178741 0.136678 0.384721 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.5E-04 1.0E-03 9.3E-04 2.1E-04 4.8E-04 9.7E-05 2.5E-03 Composition Misfit: 5.826288E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.187 0.000000 0.000000 0.004765 0.000000 0.148374 0.002698 0.053038 0.427737 0.363388 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 4.8E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.344146E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.310 0.000000 0.000000 0.350810 0.000000 0.627003 0.009594 0.012593 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -4.4E-02 0. 0.1 0.1 -0.4 0. 0. Chi 0. 0. 1.9E-06 0. 1.4E-05 1.7E-05 5.3E-04 0. 0. Composition Misfit: 5.672583E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.845 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.357 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.005 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000023 -.000023 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023314 0.014751 0.006980 0.016472 0.052928 0.000919 0.040316 0.029111 0.001391 0.108486 0.705334 Mica 0.017690 0.002464 0.000000 0.063549 0.005823 0.000000 0.005048 0.164942 0.000524 0.238823 0.501137 Gt 0.000000 0.030018 0.000000 0.000000 0.297944 0.038108 0.069715 0.000000 0.002657 0.136404 0.425155 Fsp 0.094525 0.057865 0.000000 0.001542 0.000000 0.000000 0.000000 0.000000 0.000000 0.153933 0.692135 Bio 0.000000 0.000000 0.022167 0.067001 0.175101 0.000858 0.158036 0.111834 0.004001 0.120845 0.340157 St 0.000000 0.000000 0.004334 0.000000 0.134949 0.002454 0.048240 0.088136 0.002343 0.389036 0.330509 Ilm 0.000000 0.000000 0.326458 0.000000 0.583478 0.008928 0.011719 0.000000 0.069417 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776029. -754778. -931916. -850181. -314182. -468471. -638587. -291606. -410007. -1635881. -886395. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 442 converged, 179 successes so far. Misfit function evaluations this try => 176 Misfit this try = 0.107573 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.068294E-06 Bayes score, PP * exp(-Misfit) = 9.593399E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 5967.36 946.799 0.779227 0.677054 Final coordinates: 9269.03 925.764 0.538235 0.741790 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.004848E-2 Extraneous predicted phases: 1.752448E-2 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.815 0.024646 0.003865 0.000000 0.072234 0.006559 0.000000 0.006545 0.286493 0.599658 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 0.7 0. 1. -0.4 4.4E-02 Chi 8.3E-03 0. 0. 2.1E-03 3.2E-03 0. 7.5E-03 1.3E-04 2.0E-07 Composition Misfit: 2.505276E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.433 0.000000 0.037785 0.000000 0.000000 0.292911 0.029597 0.078068 0.135737 0.425902 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. 0.5 -2. 0.6 -0.1 Chi 0. 7.9E-03 0. 0. 2.9E-03 7.3E-04 6.9E-03 4.8E-04 3.6E-06 Composition Misfit: 1.889138E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.035 0.094241 0.058875 0.000000 0.001321 0.000000 0.000000 0.000000 0.154438 0.691125 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 1.1E-02 0. 0. 0. 0.4 0.2 Chi 7.1E-05 9.0E-04 0. 1.0E-06 0. 0. 0. 2.7E-04 1.6E-05 Composition Misfit: 1.259016E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.843 0.000000 0.000000 0.024121 0.075435 0.181701 0.000723 0.199164 0.131525 0.387330 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. 0.2 0.2 -2. 0.6 1. Chi 0. 0. 3.1E-04 9.5E-04 4.2E-05 6.8E-04 4.4E-03 5.9E-04 2.1E-03 Composition Misfit: 9.106559E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.570 0.000000 0.000000 0.005010 0.000000 0.140794 0.002027 0.061475 0.427377 0.363317 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.7 0.4 -5. 1. 1. Chi 0. 0. 1.1E-03 0. 6.7E-04 1.6E-03 2.4E-02 1.0E-03 1.5E-03 Composition Misfit: 3.004700E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.543 0.000000 0.000000 0.320763 0.000000 0.658613 0.007334 0.013290 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 2. 0. -1. 0.4 -0.5 0. 0. Chi 0. 0. 2.7E-03 0. 1.2E-03 9.7E-04 8.1E-04 0. 0. Composition Misfit: 5.691763E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.000 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.351 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.005 0.000000 0.000000 0.224289 0.000000 0.650677 0.005816 0.008934 0.000000 0.110284 0.000000 0.000000 F 0.404 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000018 -.000018 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022982 0.014541 0.006880 0.016238 0.052175 0.000905 0.039742 0.042537 0.001755 0.106942 0.695301 Mica 0.020568 0.003226 0.000000 0.060284 0.005474 0.000000 0.005462 0.164929 0.000512 0.239095 0.500449 Gt 0.000000 0.037668 0.000000 0.000000 0.292001 0.029505 0.077825 0.000000 0.003105 0.135316 0.424579 Fsp 0.094241 0.058875 0.000000 0.001321 0.000000 0.000000 0.000000 0.000000 0.000000 0.154438 0.691125 Bio 0.000000 0.000000 0.021321 0.066677 0.160606 0.000639 0.176042 0.112034 0.004061 0.116256 0.342363 St 0.000000 0.000000 0.004556 0.000000 0.128051 0.001843 0.055911 0.088116 0.002394 0.388696 0.330433 Ilm 0.000000 0.000000 0.294381 0.000000 0.604444 0.006731 0.012197 0.000000 0.082247 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772840. -752173. -930094. -847746. -313624. -469630. -636928. -290069. -406575. -1634179. -884696. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Sp Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Sp Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 445 converged, 180 successes so far. Misfit function evaluations this try => 171 Misfit this try = 6.146579E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.623145E-07 Bayes score, PP * exp(-Misfit) = 9.049463E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 13907.8 835.630 0.463085 6.570065E-02 Final coordinates: 8533.68 923.235 0.421687 0.502039 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.146579E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.027 0.021255 0.002900 0.000000 0.076136 0.006860 0.000000 0.005965 0.286387 0.600497 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.1E-04 2.7E-03 0. 9.6E-03 1.2E-04 4.1E-07 Composition Misfit: 2.184489E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.124 0.000000 0.030361 0.000000 0.000000 0.298102 0.039409 0.069006 0.136816 0.426306 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.6 -1. 0.5 -0.2 Chi 0. 3.2E-03 0. 0. 1.9E-03 6.8E-04 2.9E-03 3.6E-04 6.4E-06 Composition Misfit: 9.044011E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.575 0.094518 0.057938 0.000000 0.001513 0.000000 0.000000 0.000000 0.153969 0.692062 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.5E-02 0. 0. 0. 0.5 0.1 Chi 8.7E-05 6.9E-04 0. 1.6E-05 0. 0. 0. 3.1E-04 8.6E-06 Composition Misfit: 1.117505E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.526 0.000000 0.000000 0.024934 0.075765 0.198169 0.000984 0.178857 0.136469 0.384822 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.1E-04 1.0E-03 9.5E-04 2.0E-04 4.9E-04 1.1E-04 2.5E-03 Composition Misfit: 5.794317E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.288 0.000000 0.000000 0.004720 0.000000 0.148749 0.002756 0.052588 0.427790 0.363397 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.1E-03 4.3E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.315791E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.315 0.000000 0.000000 0.351716 0.000000 0.626065 0.009803 0.012416 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.1 0. 0.2 3.1E-02 -0.4 0. 0. Chi 0. 0. 8.4E-06 0. 2.5E-05 4.0E-06 4.7E-04 0. 0. Composition Misfit: 5.071465E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.773 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.371 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023311 0.014750 0.006979 0.016470 0.052923 0.000918 0.040312 0.029202 0.001395 0.108475 0.705265 Mica 0.017738 0.002420 0.000000 0.063537 0.005724 0.000000 0.004978 0.164969 0.000516 0.238994 0.501124 Gt 0.000000 0.030281 0.000000 0.000000 0.297316 0.039306 0.068824 0.000000 0.002636 0.136455 0.425182 Fsp 0.094518 0.057938 0.000000 0.001513 0.000000 0.000000 0.000000 0.000000 0.000000 0.153969 0.692062 Bio 0.000000 0.000000 0.022044 0.066982 0.175196 0.000870 0.158123 0.111920 0.004005 0.120649 0.340212 St 0.000000 0.000000 0.004293 0.000000 0.135291 0.002507 0.047830 0.088138 0.002338 0.389085 0.330519 Ilm 0.000000 0.000000 0.327439 0.000000 0.582851 0.009126 0.011559 0.000000 0.069024 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775369. -754383. -931530. -849526. -313760. -467776. -638320. -291352. -409911. -1635368. -886105. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 447 converged, 181 successes so far. Misfit function evaluations this try => 187 Misfit this try = 6.524849E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.039415E-06 Bayes score, PP * exp(-Misfit) = 9.737598E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 8791.10 834.024 5.631654E-02 0.230771 Final coordinates: 8427.23 905.008 0.445030 0.524614 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.524849E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.896 0.022191 0.002823 0.000000 0.075305 0.006348 0.000000 0.005734 0.287209 0.600389 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.4 -5.0E-02 Chi 6.3E-03 0. 0. 1.1E-03 3.6E-03 0. 1.1E-02 1.6E-04 2.5E-07 Composition Misfit: 2.468557E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.126 0.000000 0.033382 0.000000 0.000000 0.297478 0.039580 0.066537 0.136743 0.426279 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -0.6 -1. 0.5 -0.2 Chi 0. 4.9E-03 0. 0. 2.0E-03 7.2E-04 2.1E-03 3.7E-04 6.2E-06 Composition Misfit: 1.010714E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.356 0.094605 0.058113 0.000000 0.001338 0.000000 0.000000 0.000000 0.154057 0.691887 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. 5.6E-03 0. 0. 0. 0.5 0.1 Chi 9.2E-05 7.3E-04 0. 2.8E-07 0. 0. 0. 3.0E-04 9.9E-06 Composition Misfit: 1.137174E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.869 0.000000 0.000000 0.024088 0.075612 0.196608 0.000907 0.182667 0.134181 0.385937 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. -0.8 0.1 -0.9 0.4 2. Chi 0. 0. 3.1E-04 9.9E-04 7.5E-04 3.0E-04 9.5E-04 2.8E-04 2.3E-03 Composition Misfit: 5.905725E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.849 0.000000 0.000000 0.004537 0.000000 0.149726 0.002622 0.051773 0.427925 0.363416 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.7E-03 0. 2.3E-03 5.7E-04 1.6E-02 9.9E-04 1.4E-03 Composition Misfit: 2.312463E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.378 0.000000 0.000000 0.349049 0.000000 0.629877 0.009382 0.011692 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. 5.7E-03 0.1 -0.3 0. 0. Chi 0. 0. 2.6E-06 0. 2.4E-08 4.1E-05 2.4E-04 0. 0. Composition Misfit: 2.882483E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.189 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.337 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023279 0.014729 0.006969 0.016448 0.052849 0.000917 0.040256 0.030472 0.001470 0.108324 0.704286 Mica 0.018517 0.002356 0.000000 0.062838 0.005297 0.000000 0.004785 0.165067 0.000483 0.239662 0.500995 Gt 0.000000 0.033293 0.000000 0.000000 0.296685 0.039475 0.066360 0.000000 0.002668 0.136379 0.425142 Fsp 0.094605 0.058113 0.000000 0.001338 0.000000 0.000000 0.000000 0.000000 0.000000 0.154057 0.691887 Bio 0.000000 0.000000 0.021284 0.066812 0.173725 0.000801 0.161407 0.112339 0.004050 0.118564 0.341019 St 0.000000 0.000000 0.004127 0.000000 0.136178 0.002384 0.047089 0.088142 0.002342 0.389205 0.330533 Ilm 0.000000 0.000000 0.324554 0.000000 0.585673 0.008723 0.010872 0.000000 0.070179 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -771567. -752044. -929429. -845878. -311704. -465477. -636788. -289887. -408919. -1632699. -884381. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 448 converged, 182 successes so far. Misfit function evaluations this try => 260 Misfit this try = 6.136624E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.308251E-07 Bayes score, PP * exp(-Misfit) = 8.754212E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 11852.7 831.506 0.203469 7.944381E-02 Final coordinates: 8547.84 926.884 0.423636 0.508493 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.129966E-2 Extraneous predicted phases: 6.658703E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.002 0.021115 0.002928 0.000000 0.076251 0.006949 0.000000 0.006011 0.286251 0.600496 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.5E-03 0. 0. 8.8E-04 2.5E-03 0. 9.4E-03 1.2E-04 4.1E-07 Composition Misfit: 2.140115E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.086 0.000000 0.029820 0.000000 0.000000 0.297524 0.039930 0.069624 0.136801 0.426300 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.6 -1. 0.5 -0.2 Chi 0. 2.9E-03 0. 0. 2.0E-03 8.1E-04 3.2E-03 3.6E-04 6.3E-06 Composition Misfit: 9.218829E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.583 0.094459 0.057988 0.000000 0.001547 0.000000 0.000000 0.000000 0.153994 0.692012 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.4E-05 7.0E-04 0. 2.3E-05 0. 0. 0. 3.1E-04 9.0E-06 Composition Misfit: 1.129729E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.524 0.000000 0.000000 0.025066 0.075793 0.198076 0.001013 0.178576 0.136897 0.384579 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.2 2. Chi 0. 0. 5.5E-04 1.0E-03 9.3E-04 1.7E-04 4.6E-04 8.5E-05 2.6E-03 Composition Misfit: 5.782764E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.428 0.000000 0.000000 0.004742 0.000000 0.148356 0.002827 0.052945 0.427742 0.363387 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 3.6E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.327347E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.310 0.000000 0.000000 0.348626 0.000000 0.628892 0.010021 0.012462 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. 0.1 -3.3E-03 -0.4 0. 0. Chi 0. 0. 5.4E-06 0. 2.0E-06 4.2E-08 4.9E-04 0. 0. Composition Misfit: 4.937161E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.648 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.393 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.026 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000023 -.000023 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023302 0.014744 0.006976 0.016464 0.052902 0.000918 0.040296 0.029566 0.001401 0.108434 0.704996 Mica 0.017621 0.002443 0.000000 0.063633 0.005799 0.000000 0.005016 0.164952 0.000525 0.238883 0.501128 Gt 0.000000 0.029742 0.000000 0.000000 0.296738 0.039825 0.069440 0.000000 0.002643 0.136440 0.425174 Fsp 0.094459 0.057988 0.000000 0.001547 0.000000 0.000000 0.000000 0.000000 0.000000 0.153994 0.692012 Bio 0.000000 0.000000 0.022162 0.067011 0.175124 0.000896 0.157884 0.111860 0.004012 0.121035 0.340017 St 0.000000 0.000000 0.004313 0.000000 0.134933 0.002571 0.048155 0.088135 0.002347 0.389039 0.330507 Ilm 0.000000 0.000000 0.324096 0.000000 0.584642 0.009315 0.011585 0.000000 0.070362 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776174. -754861. -931979. -850317. -314201. -468132. -638620. -291650. -409939. -1635923. -886470. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 449 converged, 183 successes so far. Misfit function evaluations this try => 275 Misfit this try = 1.20223 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 6.520421E-07 Bayes score, PP * exp(-Misfit) = 1.959530E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 14263.8 815.982 0.373877 0.687440 Final coordinates: 8155.99 855.437 0.521738 0.859588 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.16944 Extraneous predicted phases: 3.279214E-2 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 12.970 0.076300 0.022464 0.000000 0.012380 0.000786 0.000000 0.000371 0.310085 0.577614 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -1.0E+01 0. 0. 6. 2. 0. 2. -2. 3. Chi 0.1 0. 0. 0.4 0.1 0. 0.5 2.8E-03 8.7E-04 Composition Misfit: 1.10724 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.353 0.000000 0.056127 0.000000 0.000000 0.291013 0.036719 0.055002 0.135374 0.425765 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -5. 0. 0. 2. -0.3 -2.0E-02 0.6 -0.1 Chi 0. 2.3E-02 0. 0. 3.3E-03 1.7E-04 7.8E-07 5.3E-04 2.9E-06 Composition Misfit: 2.653448E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.370 0.090132 0.067940 0.000000 0.000898 0.000000 0.000000 0.000000 0.158970 0.682060 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 0.1 -2. 0. 0.1 0. 0. 0. 0.1 0.6 Chi 2.6E-05 3.9E-03 0. 2.3E-04 0. 0. 0. 2.3E-05 2.3E-04 Composition Misfit: 4.442769E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.881 0.000000 0.000000 0.021883 0.075234 0.194050 0.000666 0.190919 0.128509 0.388739 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.1 -1. -0.6 0.2 -1. 0.9 1. Chi 0. 0. 1.2E-05 9.1E-04 4.7E-04 8.7E-04 2.4E-03 1.1E-03 1.9E-03 Composition Misfit: 7.651180E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.437 0.000000 0.000000 0.004166 0.000000 0.153587 0.002110 0.048310 0.428338 0.363490 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -2. 0.4 -3. 1. 1. Chi 0. 0. 2.4E-03 0. 3.3E-03 1.4E-03 1.3E-02 9.5E-04 1.4E-03 Composition Misfit: 2.285357E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.430 0.000000 0.000000 0.355317 0.000000 0.626794 0.007798 0.010091 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.3 0. 0.1 0.4 -1.4E-02 0. 0. Chi 0. 0. 8.0E-05 0. 1.6E-05 6.2E-04 8.2E-07 0. 0. Composition Misfit: 7.187748E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.792 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 42.664 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.103 0.000000 0.000000 0.195897 0.000000 0.672107 0.005394 0.004961 0.000000 0.121641 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022829 0.014445 0.006835 0.016130 0.051828 0.000899 0.039478 0.048964 0.001690 0.106231 0.690673 Mica 0.063586 0.018720 0.000000 0.010317 0.000655 0.000000 0.000309 0.166525 0.000115 0.258413 0.481360 Gt 0.000000 0.055944 0.000000 0.000000 0.290063 0.036599 0.054822 0.000000 0.003263 0.134933 0.424376 Fsp 0.090132 0.067940 0.000000 0.000898 0.000000 0.000000 0.000000 0.000000 0.000000 0.158970 0.682060 Bio 0.000000 0.000000 0.019310 0.066386 0.171229 0.000587 0.168466 0.113462 0.004143 0.113396 0.343021 St 0.000000 0.000000 0.003789 0.000000 0.139692 0.001919 0.043939 0.088161 0.002307 0.389587 0.330606 Ilm 0.000000 0.000000 0.331347 0.000000 0.584510 0.007272 0.009410 0.000000 0.067461 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -762117. -744458. -923603. -835672. -306318. -459985. -633000. -285627. -406241. -1625628. -879787. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 450 converged, 184 successes so far. Misfit function evaluations this try => 190 Misfit this try = 0.130761 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.028884E-06 Bayes score, PP * exp(-Misfit) = 9.027710E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 8569.96 963.580 0.136759 0.938833 Final coordinates: 8806.59 922.266 0.668188 0.660945 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.130246 Extraneous predicted phases: 5.146519E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.721 0.023496 0.003537 0.000000 0.073591 0.006402 0.000000 0.006261 0.286894 0.599817 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 0.7 0. 1. -0.4 2.3E-02 Chi 7.3E-03 0. 0. 1.6E-03 3.5E-03 0. 8.5E-03 1.4E-04 5.6E-08 Composition Misfit: 2.463592E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.680 0.000000 0.034558 0.000000 0.000000 0.284411 0.043436 0.075246 0.136254 0.426095 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -1. -2. 0.5 -0.2 Chi 0. 5.7E-03 0. 0. 4.9E-03 1.9E-03 5.6E-03 4.2E-04 4.9E-06 Composition Misfit: 1.855587E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.548 0.093741 0.059811 0.000000 0.001353 0.000000 0.000000 0.000000 0.154906 0.690189 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.8 0. 1.3E-03 0. 0. 0. 0.4 0.2 Chi 4.7E-05 1.1E-03 0. 1.4E-08 0. 0. 0. 2.3E-04 2.7E-05 Composition Misfit: 1.433887E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.669 0.000000 0.000000 0.024236 0.075568 0.183018 0.001063 0.196415 0.133518 0.386181 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. 0.1 0.1 -2. 0.5 2. Chi 0. 0. 3.4E-04 9.8E-04 1.2E-05 1.2E-04 3.7E-03 3.5E-04 2.3E-03 Composition Misfit: 7.781460E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.594 0.000000 0.000000 0.004887 0.000000 0.141220 0.003036 0.059995 0.427520 0.363343 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.7 0.2 -5. 1. 1. Chi 0. 0. 1.2E-03 0. 7.3E-04 2.1E-04 2.3E-02 1.0E-03 1.5E-03 Composition Misfit: 2.755597E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.638 0.000000 0.000000 0.253022 0.000000 0.727605 0.009673 0.009701 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -4. 0.1 4.8E-02 0. 0. Chi 0. 0. 3.7E-02 0. 1.3E-02 1.1E-05 9.2E-06 0. 0. Composition Misfit: 5.028318E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.361 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.719 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.070 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000019 -.000019 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023079 0.014603 0.006910 0.016306 0.052396 0.000909 0.039910 0.038062 0.002188 0.107395 0.698242 Mica 0.019608 0.002952 0.000000 0.061412 0.005343 0.000000 0.005225 0.164990 0.000510 0.239413 0.500547 Gt 0.000000 0.034458 0.000000 0.000000 0.283591 0.043311 0.075030 0.000000 0.002881 0.135861 0.424868 Fsp 0.093741 0.059811 0.000000 0.001353 0.000000 0.000000 0.000000 0.000000 0.000000 0.154906 0.690189 Bio 0.000000 0.000000 0.021419 0.066783 0.161743 0.000939 0.173582 0.112148 0.004099 0.117997 0.341289 St 0.000000 0.000000 0.004445 0.000000 0.128439 0.002761 0.054565 0.088123 0.002380 0.388829 0.330460 Ilm 0.000000 0.000000 0.225211 0.000000 0.647629 0.008610 0.008634 0.000000 0.109916 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774122. -753045. -930581. -848946. -313807. -466678. -637291. -290498. -406907. -1634621. -885375. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Sp Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Sp Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 456 converged, 185 successes so far. Misfit function evaluations this try => 221 Misfit this try = 0.384609 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.105946E-06 Bayes score, PP * exp(-Misfit) = 7.528360E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 5742.51 957.935 0.951421 0.949221 Final coordinates: 10103.7 926.458 0.583915 0.992466 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.170715 Extraneous predicted phases: 0.213893 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 10.380 0.032763 0.005602 0.000000 0.063376 0.005536 0.000000 0.006167 0.289017 0.597539 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -4. 0. 0. 2. 0.9 0. 1. -0.5 0.3 Chi 1.5E-02 0. 0. 7.0E-03 5.7E-03 0. 8.8E-03 2.5E-04 1.0E-05 Composition Misfit: 4.273435E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.435 0.000000 0.045212 0.000000 0.000000 0.290849 0.016072 0.087671 0.134688 0.425508 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 2. 2. -3. 0.7 -0.1 Chi 0. 1.3E-02 0. 0. 3.3E-03 2.1E-02 1.2E-02 6.2E-04 1.7E-06 Composition Misfit: 5.027712E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 23.599 0.095547 0.056606 0.000000 0.001150 0.000000 0.000000 0.000000 0.153303 0.693394 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.5 0. 0.1 0. 0. 0. 0.5 4.9E-02 Chi 1.6E-04 4.4E-04 0. 3.8E-05 0. 0. 0. 3.8E-04 1.8E-06 Composition Misfit: 1.017945E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 14.146 0.000000 0.000000 0.023418 0.075087 0.166788 0.000377 0.217791 0.126306 0.390233 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. 1. 0.3 -3. 1. 1. Chi 0. 0. 1.8E-04 8.8E-04 1.9E-03 2.9E-03 1.1E-02 1.6E-03 1.7E-03 Composition Misfit: 1.979676E-2 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.853 0.000000 0.000000 0.005428 0.000000 0.132741 0.001054 0.070485 0.427029 0.363264 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.3 0. -0.1 0.6 -6. 1. 1. Chi 0. 0. 6.7E-04 0. 2.2E-05 7.4E-03 3.2E-02 1.1E-03 1.5E-03 Composition Misfit: 4.268265E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.706 0.000000 0.000000 0.322758 0.000000 0.657552 0.004054 0.015636 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 1. 0. -1. 0.9 -0.9 0. 0. Chi 0. 0. 2.3E-03 0. 1.2E-03 8.7E-03 2.0E-03 0. 0. Composition Misfit: 1.420656E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.000 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 40.499 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 1.382 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000015 -.000015 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022653 0.014333 0.006782 0.016005 0.051428 0.000893 0.039173 0.056097 0.001877 0.105411 0.685347 Mica 0.027338 0.004675 0.000000 0.052882 0.004620 0.000000 0.005146 0.165116 0.000459 0.241163 0.498602 Gt 0.000000 0.045051 0.000000 0.000000 0.289813 0.016015 0.087359 0.000000 0.003561 0.134208 0.423993 Fsp 0.095547 0.056606 0.000000 0.001150 0.000000 0.000000 0.000000 0.000000 0.000000 0.153303 0.693394 Bio 0.000000 0.000000 0.020700 0.066373 0.147432 0.000333 0.192515 0.112046 0.004009 0.111648 0.344944 St 0.000000 0.000000 0.004936 0.000000 0.120728 0.000959 0.064106 0.088104 0.002396 0.388383 0.330389 Ilm 0.000000 0.000000 0.296483 0.000000 0.604023 0.003724 0.014363 0.000000 0.081407 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -769125. -749899. -928090. -845134. -313099. -473657. -635328. -288549. -403863. -1632477. -882866. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 457 converged, 186 successes so far. Misfit function evaluations this try => 154 Misfit this try = 6.513644E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.936445E-07 Bayes score, PP * exp(-Misfit) = 9.309849E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 7133.75 926.160 0.608801 5.989374E-02 Final coordinates: 8276.78 892.796 0.444698 0.487273 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.513644E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.007 0.022273 0.002619 0.000000 0.075368 0.006118 0.000000 0.005489 0.287665 0.600467 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.8 0. 1. -0.4 -0.1 Chi 6.4E-03 0. 0. 1.1E-03 4.1E-03 0. 1.2E-02 1.8E-04 3.6E-07 Composition Misfit: 2.624183E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.264 0.000000 0.034351 0.000000 0.000000 0.300406 0.038814 0.063304 0.136818 0.426307 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -0.5 -0.8 0.5 -0.2 Chi 0. 5.5E-03 0. 0. 1.5E-03 5.4E-04 1.1E-03 3.6E-04 6.4E-06 Composition Misfit: 9.134132E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.512 0.094903 0.057660 0.000000 0.001267 0.000000 0.000000 0.000000 0.153830 0.692340 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 2.6E-02 0. 0. 0. 0.5 0.1 Chi 1.1E-04 6.4E-04 0. 6.5E-06 0. 0. 0. 3.2E-04 6.7E-06 Composition Misfit: 1.087146E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.667 0.000000 0.000000 0.023668 0.075560 0.199595 0.000841 0.180632 0.133394 0.386310 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. -1. 0.2 -0.8 0.5 2. Chi 0. 0. 2.2E-04 9.8E-04 1.1E-03 4.1E-04 6.8E-04 3.6E-04 2.3E-03 Composition Misfit: 6.073293E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.084 0.000000 0.000000 0.004353 0.000000 0.152276 0.002475 0.049385 0.428073 0.363438 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -2. 0.3 -3. 1. 1. Chi 0. 0. 2.0E-03 0. 3.0E-03 7.5E-04 1.4E-02 9.8E-04 1.4E-03 Composition Misfit: 2.234258E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.379 0.000000 0.000000 0.347041 0.000000 0.633335 0.008827 0.010797 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.2 0. -0.2 0.2 -0.1 0. 0. Chi 0. 0. 2.5E-05 0. 1.8E-05 1.6E-04 5.9E-05 0. 0. Composition Misfit: 2.574645E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.915 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.172 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023330 0.014761 0.006984 0.016483 0.052964 0.000919 0.040343 0.028365 0.001472 0.108560 0.705818 Mica 0.018585 0.002186 0.000000 0.062887 0.005105 0.000000 0.004580 0.165130 0.000464 0.240029 0.501034 Gt 0.000000 0.034260 0.000000 0.000000 0.299615 0.038712 0.063137 0.000000 0.002635 0.136458 0.425184 Fsp 0.094903 0.057660 0.000000 0.001267 0.000000 0.000000 0.000000 0.000000 0.000000 0.153830 0.692340 Bio 0.000000 0.000000 0.020907 0.066745 0.176311 0.000743 0.159561 0.112583 0.004069 0.117833 0.341246 St 0.000000 0.000000 0.003959 0.000000 0.138497 0.002251 0.044916 0.088147 0.002342 0.389337 0.330551 Ilm 0.000000 0.000000 0.322386 0.000000 0.588339 0.008200 0.010030 0.000000 0.071046 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -769325. -750839. -928301. -843565. -310313. -464193. -636032. -289140. -408863. -1631108. -883422. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 458 converged, 187 successes so far. Misfit function evaluations this try => 124 Misfit this try = 6.113442E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.402073E-07 Bayes score, PP * exp(-Misfit) = 8.844500E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 6433.78 953.503 0.593768 0.379441 Final coordinates: 8619.98 927.465 0.424554 0.497639 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.113442E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.010 0.021221 0.002958 0.000000 0.076120 0.006995 0.000000 0.006063 0.286143 0.600499 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.1E-04 2.5E-03 0. 9.2E-03 1.1E-04 4.2E-07 Composition Misfit: 2.125615E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.204 0.000000 0.030193 0.000000 0.000000 0.299040 0.037736 0.070022 0.136735 0.426276 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.4 -1. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 1.8E-03 3.2E-04 3.3E-03 3.7E-04 6.1E-06 Composition Misfit: 8.840198E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.577 0.094544 0.057826 0.000000 0.001543 0.000000 0.000000 0.000000 0.153913 0.692174 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.9E-05 6.7E-04 0. 2.2E-05 0. 0. 0. 3.2E-04 7.8E-06 Composition Misfit: 1.106764E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.536 0.000000 0.000000 0.025043 0.075772 0.198001 0.000957 0.178896 0.136582 0.384749 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.4E-04 1.0E-03 9.2E-04 2.3E-04 4.9E-04 1.0E-04 2.5E-03 Composition Misfit: 5.843513E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.078 0.000000 0.000000 0.004757 0.000000 0.148370 0.002662 0.053107 0.427720 0.363383 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 5.2E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.354698E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.316 0.000000 0.000000 0.347667 0.000000 0.630449 0.009416 0.012468 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. -2.1E-02 0.1 -0.4 0. 0. Chi 0. 0. 1.6E-05 0. 3.2E-07 3.6E-05 4.9E-04 0. 0. Composition Misfit: 5.408148E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.936 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.344 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023317 0.014754 0.006981 0.016474 0.052936 0.000919 0.040322 0.028953 0.001405 0.108502 0.705439 Mica 0.017710 0.002469 0.000000 0.063525 0.005838 0.000000 0.005060 0.164938 0.000526 0.238797 0.501138 Gt 0.000000 0.030112 0.000000 0.000000 0.298241 0.037635 0.069835 0.000000 0.002671 0.136369 0.425137 Fsp 0.094544 0.057826 0.000000 0.001543 0.000000 0.000000 0.000000 0.000000 0.000000 0.153913 0.692174 Bio 0.000000 0.000000 0.022141 0.066993 0.175061 0.000846 0.158170 0.111845 0.004011 0.120758 0.340173 St 0.000000 0.000000 0.004327 0.000000 0.134945 0.002422 0.048302 0.088134 0.002350 0.389018 0.330503 Ilm 0.000000 0.000000 0.323061 0.000000 0.585828 0.008749 0.011586 0.000000 0.070776 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775980. -754735. -931918. -850127. -314173. -468577. -638570. -291588. -409875. -1635860. -886368. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 459 converged, 188 successes so far. Misfit function evaluations this try => 182 Misfit this try = 6.112132E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.398941E-07 Bayes score, PP * exp(-Misfit) = 8.841670E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 5876.89 956.523 0.582868 0.113524 Final coordinates: 8610.54 927.304 0.421633 0.498352 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.112132E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 0.021209 0.002952 0.000000 0.076137 0.006984 0.000000 0.006053 0.286163 0.600502 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.6E-03 0. 0. 9.1E-04 2.5E-03 0. 9.3E-03 1.1E-04 4.2E-07 Composition Misfit: 2.129416E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.191 0.000000 0.030160 0.000000 0.000000 0.298901 0.037967 0.069934 0.136755 0.426283 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.4 -1. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 1.8E-03 3.6E-04 3.3E-03 3.7E-04 6.2E-06 Composition Misfit: 8.850335E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.580 0.094536 0.057842 0.000000 0.001543 0.000000 0.000000 0.000000 0.153921 0.692158 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.8E-05 6.7E-04 0. 2.2E-05 0. 0. 0. 3.2E-04 7.9E-06 Composition Misfit: 1.108943E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.541 0.000000 0.000000 0.025058 0.075775 0.198047 0.000963 0.178791 0.136625 0.384742 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.4E-04 1.0E-03 9.3E-04 2.2E-04 4.8E-04 1.0E-04 2.5E-03 Composition Misfit: 5.835512E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.127 0.000000 0.000000 0.004763 0.000000 0.148384 0.002679 0.053056 0.427732 0.363386 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 5.0E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.348193E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.312 0.000000 0.000000 0.349918 0.000000 0.628015 0.009514 0.012553 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 4.5E-03 0. 0.1 0.1 -0.4 0. 0. Chi 0. 0. 1.9E-08 0. 6.3E-06 2.5E-05 5.2E-04 0. 0. Composition Misfit: 5.504357E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.897 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.351 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023316 0.014753 0.006981 0.016474 0.052934 0.000919 0.040320 0.028993 0.001395 0.108498 0.705417 Mica 0.017700 0.002464 0.000000 0.063539 0.005829 0.000000 0.005051 0.164941 0.000525 0.238813 0.501139 Gt 0.000000 0.030080 0.000000 0.000000 0.298106 0.037866 0.069747 0.000000 0.002663 0.136391 0.425148 Fsp 0.094536 0.057842 0.000000 0.001543 0.000000 0.000000 0.000000 0.000000 0.000000 0.153921 0.692158 Bio 0.000000 0.000000 0.022155 0.066997 0.175104 0.000851 0.158079 0.111839 0.004004 0.120798 0.340172 St 0.000000 0.000000 0.004332 0.000000 0.134958 0.002437 0.048255 0.088135 0.002345 0.389031 0.330507 Ilm 0.000000 0.000000 0.325493 0.000000 0.584178 0.008850 0.011677 0.000000 0.069803 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775985. -754739. -931903. -850130. -314163. -468520. -638573. -291590. -409958. -1635855. -886372. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 462 converged, 189 successes so far. Misfit function evaluations this try => 160 Misfit this try = 6.627791E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.388098E-07 Bayes score, PP * exp(-Misfit) = 8.786046E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 11939.6 880.290 0.197277 8.365569E-02 Final coordinates: 8152.29 887.434 0.434760 0.493216 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.627791E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.004 0.022287 0.002543 0.000000 0.075419 0.005946 0.000000 0.005358 0.287981 0.600465 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.8 0. 1. -0.4 -0.1 Chi 6.4E-03 0. 0. 1.1E-03 4.6E-03 0. 1.3E-02 2.0E-04 3.6E-07 Composition Misfit: 2.728339E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.154 0.000000 0.034439 0.000000 0.000000 0.298946 0.041321 0.061981 0.136955 0.426358 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -0.8 -0.7 0.5 -0.2 Chi 0. 5.6E-03 0. 0. 1.8E-03 1.2E-03 8.3E-04 3.5E-04 6.8E-06 Composition Misfit: 9.765477E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.518 0.094849 0.057830 0.000000 0.001236 0.000000 0.000000 0.000000 0.153915 0.692170 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 3.5E-02 0. 0. 0. 0.5 0.1 Chi 1.1E-04 6.7E-04 0. 1.2E-05 0. 0. 0. 3.2E-04 7.8E-06 Composition Misfit: 1.116431E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.672 0.000000 0.000000 0.023544 0.075554 0.199961 0.000874 0.180376 0.133309 0.386381 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. -1. 0.2 -0.7 0.5 2. Chi 0. 0. 2.0E-04 9.8E-04 1.2E-03 3.5E-04 6.5E-04 3.7E-04 2.3E-03 Composition Misfit: 6.012024E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.392 0.000000 0.000000 0.004313 0.000000 0.152791 0.002603 0.048648 0.428183 0.363463 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -2. 0.3 -3. 1. 1. Chi 0. 0. 2.1E-03 0. 3.1E-03 5.9E-04 1.4E-02 9.7E-04 1.4E-03 Composition Misfit: 2.179751E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.371 0.000000 0.000000 0.356487 0.000000 0.623279 0.009365 0.010869 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.4 0. 0.3 0.1 -0.1 0. 0. Chi 0. 0. 1.2E-04 0. 7.2E-05 4.3E-05 6.9E-05 0. 0. Composition Misfit: 3.030732E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.676 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.213 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023322 0.014757 0.006982 0.016478 0.052948 0.000919 0.040331 0.028702 0.001439 0.108526 0.705597 Mica 0.018596 0.002122 0.000000 0.062928 0.004962 0.000000 0.004471 0.165170 0.000451 0.240285 0.501016 Gt 0.000000 0.034351 0.000000 0.000000 0.298176 0.041215 0.061821 0.000000 0.002576 0.136602 0.425260 Fsp 0.094849 0.057830 0.000000 0.001236 0.000000 0.000000 0.000000 0.000000 0.000000 0.153915 0.692170 Bio 0.000000 0.000000 0.020796 0.066735 0.176619 0.000772 0.159321 0.112673 0.004057 0.117748 0.341279 St 0.000000 0.000000 0.003923 0.000000 0.138967 0.002368 0.044246 0.088154 0.002318 0.389444 0.330579 Ilm 0.000000 0.000000 0.332620 0.000000 0.581549 0.008738 0.010141 0.000000 0.066952 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -768634. -750446. -927836. -842879. -309819. -463166. -635749. -288880. -409057. -1630542. -883139. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 465 converged, 190 successes so far. Misfit function evaluations this try => 303 Misfit this try = 0.137795 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.070667E-06 Bayes score, PP * exp(-Misfit) = 9.328484E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 10027.7 984.293 0.936476 0.544899 Final coordinates: 9259.50 925.438 0.683874 0.620587 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.137793 Extraneous predicted phases: 1.639636E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.121 0.024819 0.003866 0.000000 0.072068 0.006506 0.000000 0.006520 0.286589 0.599632 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 0.7 0. 1. -0.4 4.7E-02 Chi 8.4E-03 0. 0. 2.1E-03 3.3E-03 0. 7.6E-03 1.3E-04 2.3E-07 Composition Misfit: 2.544634E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.435 0.000000 0.037529 0.000000 0.000000 0.291808 0.030683 0.078296 0.135770 0.425914 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. 0.4 -2. 0.6 -0.1 Chi 0. 7.7E-03 0. 0. 3.1E-03 4.1E-04 7.1E-03 4.8E-04 3.7E-06 Composition Misfit: 1.874135E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.315 0.094334 0.058696 0.000000 0.001318 0.000000 0.000000 0.000000 0.154348 0.691304 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 1.2E-02 0. 0. 0. 0.5 0.1 Chi 7.6E-05 8.6E-04 0. 1.2E-06 0. 0. 0. 2.8E-04 1.5E-05 Composition Misfit: 1.229274E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.515 0.000000 0.000000 0.024095 0.075431 0.181058 0.000748 0.199845 0.131471 0.387353 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. 0.2 0.2 -2. 0.6 1. Chi 0. 0. 3.1E-04 9.5E-04 6.4E-05 6.1E-04 4.6E-03 5.9E-04 2.1E-03 Composition Misfit: 9.248288E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.662 0.000000 0.000000 0.005014 0.000000 0.140436 0.002099 0.061757 0.427376 0.363317 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.7 0.4 -5. 1. 1. Chi 0. 0. 1.1E-03 0. 6.3E-04 1.4E-03 2.4E-02 1.0E-03 1.5E-03 Composition Misfit: 3.005893E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.686 0.000000 0.000000 0.252434 0.000000 0.730650 0.006811 0.010106 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.5 -1.7E-02 0. 0. Chi 0. 0. 3.8E-02 0. 1.4E-02 1.5E-03 1.1E-06 0. 0. Composition Misfit: 5.306881E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.851 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.411 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.004 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000018 -.000018 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023132 0.014636 0.006925 0.016344 0.052515 0.000911 0.040001 0.035819 0.002245 0.107639 0.699833 Mica 0.020713 0.003227 0.000000 0.060144 0.005430 0.000000 0.005441 0.164940 0.000510 0.239173 0.500423 Gt 0.000000 0.037413 0.000000 0.000000 0.290906 0.030588 0.078054 0.000000 0.003091 0.135351 0.424597 Fsp 0.094334 0.058696 0.000000 0.001318 0.000000 0.000000 0.000000 0.000000 0.000000 0.154348 0.691304 Bio 0.000000 0.000000 0.021297 0.066673 0.160034 0.000661 0.176640 0.112049 0.004064 0.116206 0.342376 St 0.000000 0.000000 0.004560 0.000000 0.127725 0.001909 0.056168 0.088116 0.002393 0.388695 0.330434 Ilm 0.000000 0.000000 0.224629 0.000000 0.650170 0.006061 0.008993 0.000000 0.110149 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772783. -752190. -930050. -847753. -313621. -469328. -636888. -290043. -406485. -1634147. -884683. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 469 converged, 191 successes so far. Misfit function evaluations this try => 252 Misfit this try = 0.131050 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 7.922107E-07 Bayes score, PP * exp(-Misfit) = 6.949066E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 13216.5 961.093 0.827629 0.694051 Final coordinates: 7751.13 918.694 0.557393 0.552808 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.129650 Extraneous predicted phases: 1.400148E-3 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.015 0.020434 0.002614 0.000000 0.077200 0.006375 0.000000 0.005456 0.287536 0.600385 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.6 0.7 0. 1. -0.4 -4.9E-02 Chi 5.0E-03 0. 0. 6.8E-04 3.6E-03 0. 1.2E-02 1.7E-04 2.5E-07 Composition Misfit: 2.401752E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.311 0.000000 0.025794 0.000000 0.000000 0.277646 0.066227 0.066443 0.137374 0.426515 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.7 0. 0. 2. -4. -1. 0.5 -0.2 Chi 0. 1.1E-03 0. 0. 7.1E-03 1.5E-02 2.0E-03 3.0E-04 8.1E-06 Composition Misfit: 2.592363E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.627 0.093937 0.059002 0.000000 0.001562 0.000000 0.000000 0.000000 0.154501 0.690998 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -0.1 0. 0. 0. 0.4 0.2 Chi 5.6E-05 9.3E-04 0. 2.7E-05 0. 0. 0. 2.6E-04 1.8E-05 Composition Misfit: 1.294572E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.418 0.000000 0.000000 0.024933 0.075982 0.195989 0.001668 0.178932 0.139726 0.382771 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.8 -0.1 -0.6 4.2E-02 2. Chi 0. 0. 5.1E-04 1.1E-03 6.8E-04 3.6E-05 5.0E-04 2.5E-06 2.9E-03 Composition Misfit: 5.670106E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.909 0.000000 0.000000 0.004497 0.000000 0.146871 0.004861 0.052478 0.427889 0.363404 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. -0.2 -4. 1. 1. Chi 0. 0. 1.8E-03 0. 1.7E-03 2.1E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.278817E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.415 0.000000 0.000000 0.254117 0.000000 0.722881 0.014694 0.008309 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -4. -0.7 0.3 0. 0. Chi 0. 0. 3.6E-02 0. 1.2E-02 1.5E-03 3.4E-04 0. 0. Composition Misfit: 4.995580E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.433 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.753 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.119 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000021 -.000021 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023232 0.014700 0.006955 0.016415 0.052743 0.000915 0.040175 0.032046 0.001837 0.108107 0.702874 Mica 0.017050 0.002181 0.000000 0.064414 0.005319 0.000000 0.004552 0.165107 0.000517 0.239913 0.500947 Gt 0.000000 0.025732 0.000000 0.000000 0.276982 0.066069 0.066284 0.000000 0.002393 0.137046 0.425495 Fsp 0.093937 0.059002 0.000000 0.001562 0.000000 0.000000 0.000000 0.000000 0.000000 0.154501 0.690998 Bio 0.000000 0.000000 0.022031 0.067138 0.173178 0.001474 0.158106 0.112245 0.004142 0.123463 0.338221 St 0.000000 0.000000 0.004090 0.000000 0.133579 0.004421 0.047729 0.088137 0.002363 0.389165 0.330516 Ilm 0.000000 0.000000 0.226296 0.000000 0.643738 0.013085 0.007399 0.000000 0.109482 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777816. -756136. -932569. -852174. -314412. -463982. -638881. -292126. -409165. -1636337. -887407. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 472 converged, 192 successes so far. Misfit function evaluations this try => 379 Misfit this try = 0.312351 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.030145E-06 Bayes score, PP * exp(-Misfit) = 7.537829E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 6120.03 970.350 0.149087 0.951489 Final coordinates: 8947.36 924.821 0.480643 0.949825 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.564923E-2 Extraneous predicted phases: 0.236702 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.559 0.023258 0.003523 0.000000 0.073806 0.006606 0.000000 0.006358 0.286499 0.599949 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.9 0.7 0. 1. -0.4 6.5E-03 Chi 7.2E-03 0. 0. 1.5E-03 3.1E-03 0. 8.1E-03 1.3E-04 4.3E-09 Composition Misfit: 2.360115E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.974 0.000000 0.034894 0.000000 0.000000 0.291316 0.036454 0.075028 0.136224 0.426084 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.2 -2. 0.5 -0.2 Chi 0. 5.9E-03 0. 0. 3.2E-03 1.3E-04 5.5E-03 4.3E-04 4.8E-06 Composition Misfit: 1.513255E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.152 0.093981 0.059280 0.000000 0.001379 0.000000 0.000000 0.000000 0.154640 0.690720 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -6.2E-03 0. 0. 0. 0.4 0.2 Chi 5.8E-05 1.0E-03 0. 3.3E-07 0. 0. 0. 2.5E-04 2.1E-05 Composition Misfit: 1.328069E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.489 0.000000 0.000000 0.024448 0.075564 0.185981 0.000899 0.193284 0.133458 0.386366 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.1 0.2 -2. 0.5 2. Chi 0. 0. 3.9E-04 9.8E-04 1.2E-05 3.1E-04 2.9E-03 3.5E-04 2.3E-03 Composition Misfit: 7.230220E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.837 0.000000 0.000000 0.004950 0.000000 0.142776 0.002530 0.058841 0.427547 0.363355 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.9 0.3 -4. 1. 1. Chi 0. 0. 1.1E-03 0. 9.6E-04 6.8E-04 2.2E-02 1.0E-03 1.4E-03 Composition Misfit: 2.718787E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.451 0.000000 0.000000 0.344504 0.000000 0.632556 0.009226 0.013715 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.3 0. -0.1 0.1 -0.6 0. 0. Chi 0. 0. 8.8E-05 0. 1.0E-05 6.5E-05 1.0E-03 0. 0. Composition Misfit: 1.169378E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.050 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 1.487 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000020 -.000020 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022715 0.014373 0.006801 0.016049 0.051569 0.000895 0.039281 0.053835 0.001549 0.105701 0.687232 Mica 0.019410 0.002940 0.000000 0.061594 0.005513 0.000000 0.005306 0.164949 0.000511 0.239095 0.500682 Gt 0.000000 0.034793 0.000000 0.000000 0.290473 0.036348 0.074811 0.000000 0.002893 0.135830 0.424851 Fsp 0.093981 0.059280 0.000000 0.001379 0.000000 0.000000 0.000000 0.000000 0.000000 0.154640 0.690720 Bio 0.000000 0.000000 0.021612 0.066797 0.164405 0.000795 0.170860 0.111983 0.004032 0.117975 0.341542 St 0.000000 0.000000 0.004503 0.000000 0.129857 0.002301 0.053517 0.088127 0.002355 0.388861 0.330478 Ilm 0.000000 0.000000 0.319651 0.000000 0.586924 0.008560 0.012726 0.000000 0.072140 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774063. -753034. -930623. -848727. -313805. -468210. -637441. -290572. -407799. -1634725. -885330. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 474 converged, 193 successes so far. Misfit function evaluations this try => 254 Misfit this try = 6.112567E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.382144E-07 Bayes score, PP * exp(-Misfit) = 8.825830E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 6897.37 942.616 0.782699 0.216628 Final coordinates: 8607.47 927.405 0.423332 0.499134 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.112541E-2 Extraneous predicted phases: 2.516702E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.009 0.021202 0.002954 0.000000 0.076143 0.006985 0.000000 0.006053 0.286164 0.600499 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.5E-03 0. 0. 9.1E-04 2.5E-03 0. 9.3E-03 1.1E-04 4.1E-07 Composition Misfit: 2.128667E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.183 0.000000 0.030128 0.000000 0.000000 0.298800 0.038098 0.069943 0.136750 0.426281 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.4 -1. 0.5 -0.2 Chi 0. 3.0E-03 0. 0. 1.8E-03 3.9E-04 3.3E-03 3.7E-04 6.2E-06 Composition Misfit: 8.878492E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.579 0.094528 0.057855 0.000000 0.001545 0.000000 0.000000 0.000000 0.153927 0.692145 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.8E-05 6.8E-04 0. 2.3E-05 0. 0. 0. 3.2E-04 8.0E-06 Composition Misfit: 1.110959E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.534 0.000000 0.000000 0.025050 0.075776 0.198023 0.000967 0.178822 0.136645 0.384716 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.3 2. Chi 0. 0. 5.4E-04 1.0E-03 9.3E-04 2.2E-04 4.8E-04 9.8E-05 2.5E-03 Composition Misfit: 5.832313E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.149 0.000000 0.000000 0.004758 0.000000 0.148375 0.002690 0.053066 0.427727 0.363385 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.4E-03 0. 2.0E-03 4.9E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.348480E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.314 0.000000 0.000000 0.348859 0.000000 0.629082 0.009545 0.012515 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. 4.2E-02 0.1 -0.4 0. 0. Chi 0. 0. 3.7E-06 0. 1.3E-06 2.2E-05 5.1E-04 0. 0. Composition Misfit: 5.321777E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.877 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.354 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000023 -.000023 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023315 0.014752 0.006980 0.016473 0.052931 0.000919 0.040318 0.029037 0.001400 0.108493 0.705381 Mica 0.017694 0.002465 0.000000 0.063544 0.005829 0.000000 0.005052 0.164941 0.000525 0.238814 0.501137 Gt 0.000000 0.030048 0.000000 0.000000 0.298003 0.037996 0.069757 0.000000 0.002665 0.136386 0.425145 Fsp 0.094528 0.057855 0.000000 0.001545 0.000000 0.000000 0.000000 0.000000 0.000000 0.153927 0.692145 Bio 0.000000 0.000000 0.022148 0.066997 0.175081 0.000855 0.158105 0.111846 0.004011 0.120814 0.340144 St 0.000000 0.000000 0.004327 0.000000 0.134950 0.002446 0.048265 0.088135 0.002348 0.389025 0.330505 Ilm 0.000000 0.000000 0.324347 0.000000 0.584882 0.008874 0.011636 0.000000 0.070261 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776021. -754767. -931929. -850171. -314183. -468497. -638583. -291603. -409912. -1635878. -886390. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio F sill ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio F sill ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Bio F sill q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Bio F sill q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 477 converged, 194 successes so far. Misfit function evaluations this try => 320 Misfit this try = 0.162251 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 1.096766E-06 Bayes score, PP * exp(-Misfit) = 9.325016E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 14335.9 821.496 0.855667 0.456944 Final coordinates: 9366.33 924.194 0.717799 0.744677 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.147703 Extraneous predicted phases: 1.454724E-2 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.666 0.025926 0.004180 0.000000 0.070822 0.006290 0.000000 0.006536 0.286977 0.599270 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 1. 0.7 0. 1. -0.4 0.1 Chi 9.3E-03 0. 0. 2.6E-03 3.8E-03 0. 7.5E-03 1.5E-04 8.9E-07 Composition Misfit: 2.758349E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.349 0.000000 0.039658 0.000000 0.000000 0.288277 0.030657 0.080031 0.135546 0.425830 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. 0.4 -2. 0.6 -0.1 Chi 0. 9.2E-03 0. 0. 3.9E-03 4.2E-04 8.0E-03 5.1E-04 3.2E-06 Composition Misfit: 2.202246E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.786 0.094094 0.059288 0.000000 0.001261 0.000000 0.000000 0.000000 0.154644 0.690712 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. 2.8E-02 0. 0. 0. 0.4 0.2 Chi 6.4E-05 1.0E-03 0. 7.4E-06 0. 0. 0. 2.5E-04 2.1E-05 Composition Misfit: 1.342567E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.289 0.000000 0.000000 0.023874 0.075360 0.176622 0.000738 0.205091 0.130404 0.387911 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. 0.5 0.2 -2. 0.7 1. Chi 0. 0. 2.6E-04 9.4E-04 3.5E-04 6.4E-04 6.2E-03 7.5E-04 2.0E-03 Composition Misfit: 1.113994E-2 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.410 0.000000 0.000000 0.005092 0.000000 0.138131 0.002085 0.064068 0.427316 0.363308 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -0.5 0.4 -5. 1. 1. Chi 0. 0. 9.9E-04 0. 3.6E-04 1.5E-03 2.6E-02 1.1E-03 1.5E-03 Composition Misfit: 3.175209E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.740 0.000000 0.000000 0.251720 0.000000 0.731052 0.006801 0.010428 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.5 -0.1 0. 0. Chi 0. 0. 3.8E-02 0. 1.4E-02 1.5E-03 1.8E-05 0. 0. Composition Misfit: 5.386293E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.002 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.391 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.368 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000017 -.000017 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022965 0.014531 0.006875 0.016225 0.052136 0.000905 0.039712 0.042671 0.002339 0.106862 0.694779 Mica 0.021636 0.003488 0.000000 0.059103 0.005249 0.000000 0.005455 0.164966 0.000501 0.239492 0.500111 Gt 0.000000 0.039531 0.000000 0.000000 0.287358 0.030559 0.079776 0.000000 0.003188 0.135114 0.424472 Fsp 0.094094 0.059288 0.000000 0.001261 0.000000 0.000000 0.000000 0.000000 0.000000 0.154644 0.690712 Bio 0.000000 0.000000 0.021100 0.066605 0.156102 0.000652 0.181264 0.112110 0.004069 0.115254 0.342844 St 0.000000 0.000000 0.004631 0.000000 0.125629 0.001897 0.058269 0.088114 0.002392 0.388642 0.330427 Ilm 0.000000 0.000000 0.223922 0.000000 0.650321 0.006050 0.009276 0.000000 0.110431 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772082. -751558. -929556. -847263. -313487. -469077. -636477. -289664. -405676. -1633716. -884303. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 478 converged, 195 successes so far. Misfit function evaluations this try => 186 Misfit this try = 6.244172E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.500994E-07 Bayes score, PP * exp(-Misfit) = 8.925878E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 9738.56 867.752 0.377614 0.302207 Final coordinates: 8659.57 927.296 0.425986 0.522864 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.222843E-2 Extraneous predicted phases: 2.132976E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.501 0.021424 0.003012 0.000000 0.075891 0.006952 0.000000 0.006099 0.286167 0.600455 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.6 0. 1. -0.3 -0.1 Chi 5.7E-03 0. 0. 9.7E-04 2.5E-03 0. 9.1E-03 1.1E-04 3.5E-07 Composition Misfit: 2.143972E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.189 0.000000 0.030641 0.000000 0.000000 0.298445 0.037398 0.070545 0.136706 0.426265 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.3 -2. 0.5 -0.2 Chi 0. 3.3E-03 0. 0. 1.8E-03 2.7E-04 3.5E-03 3.7E-04 6.1E-06 Composition Misfit: 9.330802E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.461 0.094497 0.057956 0.000000 0.001525 0.000000 0.000000 0.000000 0.153978 0.692044 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.9E-02 0. 0. 0. 0.5 0.1 Chi 8.6E-05 7.0E-04 0. 1.8E-05 0. 0. 0. 3.1E-04 8.7E-06 Composition Misfit: 1.121821E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.113 0.000000 0.000000 0.025009 0.075750 0.196756 0.000947 0.180335 0.136256 0.384946 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.8 0.1 -0.7 0.3 2. Chi 0. 0. 5.3E-04 1.0E-03 7.7E-04 2.4E-04 6.5E-04 1.2E-04 2.5E-03 Composition Misfit: 5.826892E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.725 0.000000 0.000000 0.004791 0.000000 0.147808 0.002636 0.053668 0.427713 0.363384 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.3 -4. 1. 1. Chi 0. 0. 1.3E-03 0. 1.9E-03 5.5E-04 1.8E-02 1.0E-03 1.4E-03 Composition Misfit: 2.386673E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.327 0.000000 0.000000 0.350694 0.000000 0.627162 0.009402 0.012742 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -3.8E-02 0. 0.1 0.1 -0.4 0. 0. Chi 0. 0. 1.4E-06 0. 1.3E-05 3.8E-05 5.9E-04 0. 0. Composition Misfit: 6.424594E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.283 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.355 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.046 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000023 -.000023 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023283 0.014732 0.006970 0.016450 0.052858 0.000917 0.040262 0.030376 0.001407 0.108342 0.704402 Mica 0.017879 0.002514 0.000000 0.063334 0.005802 0.000000 0.005090 0.164938 0.000523 0.238817 0.501103 Gt 0.000000 0.030559 0.000000 0.000000 0.297644 0.037298 0.070356 0.000000 0.002684 0.136339 0.425121 Fsp 0.094497 0.057956 0.000000 0.001525 0.000000 0.000000 0.000000 0.000000 0.000000 0.153978 0.692044 Bio 0.000000 0.000000 0.022112 0.066975 0.173964 0.000838 0.159445 0.111839 0.004001 0.120472 0.340354 St 0.000000 0.000000 0.004357 0.000000 0.134434 0.002398 0.048812 0.088135 0.002344 0.389014 0.330505 Ilm 0.000000 0.000000 0.326332 0.000000 0.583595 0.008749 0.011857 0.000000 0.069467 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775778. -754561. -931764. -849979. -314136. -468583. -638456. -291484. -409795. -1635747. -886258. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 479 converged, 196 successes so far. Misfit function evaluations this try => 244 Misfit this try = 6.639300E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.550359E-07 Bayes score, PP * exp(-Misfit) = 8.936873E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 5576.11 822.905 0.716383 0.384083 Final coordinates: 8124.11 894.499 0.457732 0.500473 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.639300E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.005 0.021848 0.002575 0.000000 0.075822 0.006116 0.000000 0.005435 0.287738 0.600465 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.8 0. 1. -0.4 -0.1 Chi 6.0E-03 0. 0. 9.8E-04 4.2E-03 0. 1.2E-02 1.8E-04 3.6E-07 Composition Misfit: 2.604010E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.984 0.000000 0.032824 0.000000 0.000000 0.295936 0.044781 0.063161 0.136944 0.426354 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -1. -0.8 0.5 -0.2 Chi 0. 4.6E-03 0. 0. 2.3E-03 2.5E-03 1.1E-03 3.5E-04 6.8E-06 Composition Misfit: 1.081217E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.554 0.094644 0.058111 0.000000 0.001301 0.000000 0.000000 0.000000 0.154055 0.691889 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. 1.7E-02 0. 0. 0. 0.5 0.1 Chi 9.5E-05 7.3E-04 0. 2.5E-06 0. 0. 0. 3.0E-04 9.9E-06 Composition Misfit: 1.141321E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.629 0.000000 0.000000 0.023777 0.075630 0.199396 0.000985 0.180097 0.134443 0.385671 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.3 -1. -1. 0.1 -0.7 0.4 2. Chi 0. 0. 2.4E-04 1.0E-03 1.1E-03 2.0E-04 6.2E-04 2.6E-04 2.4E-03 Composition Misfit: 5.808639E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.885 0.000000 0.000000 0.004324 0.000000 0.151786 0.002908 0.049487 0.428062 0.363433 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -2. 0.2 -3. 1. 1. Chi 0. 0. 2.1E-03 0. 2.8E-03 3.0E-04 1.4E-02 9.8E-04 1.4E-03 Composition Misfit: 2.189849E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.378 0.000000 0.000000 0.337632 0.000000 0.641681 0.010199 0.010487 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.7 0. -0.5 -3.2E-02 -0.1 0. 0. Chi 0. 0. 4.5E-04 0. 2.1E-04 3.9E-06 2.3E-05 0. 0. Composition Misfit: 6.922871E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.242 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.323 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023311 0.014749 0.006979 0.016470 0.052921 0.000918 0.040311 0.029110 0.001514 0.108472 0.705245 Mica 0.018230 0.002149 0.000000 0.063265 0.005103 0.000000 0.004535 0.165139 0.000471 0.240086 0.501023 Gt 0.000000 0.032739 0.000000 0.000000 0.295172 0.044665 0.062998 0.000000 0.002580 0.136591 0.425254 Fsp 0.094644 0.058111 0.000000 0.001301 0.000000 0.000000 0.000000 0.000000 0.000000 0.154055 0.691889 Bio 0.000000 0.000000 0.021002 0.066803 0.176125 0.000870 0.159078 0.112604 0.004104 0.118752 0.340661 St 0.000000 0.000000 0.003933 0.000000 0.138049 0.002645 0.045009 0.088145 0.002353 0.389323 0.330543 Ilm 0.000000 0.000000 0.312280 0.000000 0.593499 0.009434 0.009700 0.000000 0.075088 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -770434. -751519. -928846. -844666. -310753. -463493. -636374. -289518. -408756. -1631705. -883953. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 480 converged, 197 successes so far. Misfit function evaluations this try => 277 Misfit this try = 0.120337 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.946471E-07 Bayes score, PP * exp(-Misfit) = 8.818752E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 12390.6 862.507 0.896522 0.248406 Final coordinates: 8779.45 925.274 0.615494 0.554091 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.120337 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.230 0.022459 0.003259 0.000000 0.074739 0.006743 0.000000 0.006233 0.286392 0.600175 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.7 0. 1. -0.3 -2.2E-02 Chi 6.5E-03 0. 0. 1.3E-03 2.9E-03 0. 8.6E-03 1.2E-04 5.1E-08 Composition Misfit: 2.263402E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.046 0.000000 0.032657 0.000000 0.000000 0.292649 0.038915 0.073252 0.136384 0.426144 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -0.5 -2. 0.5 -0.2 Chi 0. 4.5E-03 0. 0. 2.9E-03 5.6E-04 4.7E-03 4.1E-04 5.2E-06 Composition Misfit: 1.304024E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.113 0.094277 0.058567 0.000000 0.001439 0.000000 0.000000 0.000000 0.154283 0.691433 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.7 0. -2.4E-02 0. 0. 0. 0.5 0.1 Chi 7.3E-05 8.3E-04 0. 4.6E-06 0. 0. 0. 2.8E-04 1.4E-05 Composition Misfit: 1.204698E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.712 0.000000 0.000000 0.024538 0.075643 0.189953 0.000969 0.188628 0.134652 0.385616 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.4 0.1 -1. 0.4 2. Chi 0. 0. 4.1E-04 1.0E-03 1.6E-04 2.1E-04 1.9E-03 2.4E-04 2.4E-03 Composition Misfit: 6.341988E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.888 0.000000 0.000000 0.004794 0.000000 0.144713 0.002722 0.056858 0.427566 0.363347 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.4 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.3E-03 0. 1.3E-03 4.6E-04 2.0E-02 1.0E-03 1.5E-03 Composition Misfit: 2.582153E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.550 0.000000 0.000000 0.252756 0.000000 0.729482 0.008541 0.009222 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 0.1 0. 0. Chi 0. 0. 3.7E-02 0. 1.4E-02 2.5E-04 6.6E-05 0. 0. Composition Misfit: 5.129502E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.009 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.452 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023226 0.014696 0.006953 0.016410 0.052728 0.000915 0.040164 0.032111 0.002028 0.108079 0.702689 Mica 0.018743 0.002720 0.000000 0.062372 0.005627 0.000000 0.005202 0.164949 0.000523 0.239002 0.500862 Gt 0.000000 0.032564 0.000000 0.000000 0.291822 0.038805 0.073045 0.000000 0.002824 0.135999 0.424940 Fsp 0.094277 0.058567 0.000000 0.001439 0.000000 0.000000 0.000000 0.000000 0.000000 0.154283 0.691433 Bio 0.000000 0.000000 0.021689 0.066860 0.167897 0.000857 0.166725 0.112031 0.004082 0.119017 0.340841 St 0.000000 0.000000 0.004360 0.000000 0.131615 0.002476 0.051712 0.088123 0.002389 0.388866 0.330460 Ilm 0.000000 0.000000 0.224947 0.000000 0.649223 0.007601 0.008207 0.000000 0.110021 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774833. -753770. -931232. -849348. -313960. -467922. -637846. -290971. -408022. -1635162. -885764. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 485 converged, 198 successes so far. Misfit function evaluations this try => 138 Misfit this try = 6.190132E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.249998E-07 Bayes score, PP * exp(-Misfit) = 8.694773E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 9507.08 948.438 0.316431 0.256035 Final coordinates: 8485.42 926.078 0.431270 0.507619 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.190132E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.013 0.021033 0.002900 0.000000 0.076354 0.006918 0.000000 0.005968 0.286338 0.600489 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.4E-03 0. 0. 8.6E-04 2.6E-03 0. 9.6E-03 1.2E-04 4.0E-07 Composition Misfit: 2.151642E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.996 0.000000 0.029573 0.000000 0.000000 0.296153 0.041836 0.069316 0.136816 0.426306 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.8 -1. 0.5 -0.2 Chi 0. 2.8E-03 0. 0. 2.2E-03 1.4E-03 3.0E-03 3.6E-04 6.4E-06 Composition Misfit: 9.781378E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.597 0.094396 0.058113 0.000000 0.001548 0.000000 0.000000 0.000000 0.154057 0.691887 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 8.0E-05 7.3E-04 0. 2.3E-05 0. 0. 0. 3.0E-04 9.9E-06 Composition Misfit: 1.147745E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.513 0.000000 0.000000 0.025021 0.075806 0.198066 0.001060 0.178542 0.137084 0.384421 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -0.9 0.1 -0.6 0.2 2. Chi 0. 0. 5.3E-04 1.0E-03 9.3E-04 1.3E-04 4.6E-04 7.6E-05 2.6E-03 Composition Misfit: 5.744670E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.650 0.000000 0.000000 0.004701 0.000000 0.148356 0.002968 0.052854 0.427739 0.363383 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 2.0E-03 2.6E-04 1.7E-02 1.0E-03 1.4E-03 Composition Misfit: 2.315078E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.315 0.000000 0.000000 0.343646 0.000000 0.633677 0.010466 0.012212 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.3 0. -0.2 -0.1 -0.4 0. 0. Chi 0. 0. 1.2E-04 0. 2.1E-05 2.1E-05 4.0E-04 0. 0. Composition Misfit: 5.603303E-4 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.469 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.447 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023303 0.014745 0.006977 0.016465 0.052904 0.000918 0.040297 0.029516 0.001426 0.108436 0.705014 Mica 0.017553 0.002420 0.000000 0.063718 0.005773 0.000000 0.004980 0.164962 0.000526 0.238952 0.501115 Gt 0.000000 0.029495 0.000000 0.000000 0.295373 0.041726 0.069134 0.000000 0.002636 0.136455 0.425182 Fsp 0.094396 0.058113 0.000000 0.001548 0.000000 0.000000 0.000000 0.000000 0.000000 0.154057 0.691887 Bio 0.000000 0.000000 0.022120 0.067016 0.175100 0.000937 0.157840 0.111912 0.004037 0.121189 0.339848 St 0.000000 0.000000 0.004276 0.000000 0.134931 0.002699 0.048071 0.088133 0.002359 0.389032 0.330500 Ilm 0.000000 0.000000 0.318728 0.000000 0.587729 0.009707 0.011327 0.000000 0.072509 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776268. -754930. -932030. -850414. -314194. -467728. -638630. -291676. -409776. -1635929. -886525. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Sp Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Sp Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 492 converged, 199 successes so far. Misfit function evaluations this try => 171 Misfit this try = 0.114930 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.413963E-07 Bayes score, PP * exp(-Misfit) = 8.391878E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 7522.46 878.415 0.946508 0.580865 Final coordinates: 8578.52 926.486 0.564969 0.492996 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.114828 Extraneous predicted phases: 1.012946E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.031 0.021369 0.002973 0.000000 0.075973 0.006932 0.000000 0.006059 0.286259 0.600435 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.7E-03 0. 0. 9.5E-04 2.6E-03 0. 9.3E-03 1.2E-04 3.2E-07 Composition Misfit: 2.153796E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.100 0.000000 0.030213 0.000000 0.000000 0.295933 0.040459 0.070520 0.136636 0.426238 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.7 -2. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 2.3E-03 9.5E-04 3.5E-03 3.8E-04 5.9E-06 Composition Misfit: 1.021953E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.584 0.094487 0.057970 0.000000 0.001528 0.000000 0.000000 0.000000 0.153985 0.692030 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.9E-02 0. 0. 0. 0.5 0.1 Chi 8.5E-05 7.0E-04 0. 1.9E-05 0. 0. 0. 3.1E-04 8.8E-06 Composition Misfit: 1.124095E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.518 0.000000 0.000000 0.024817 0.075760 0.196194 0.001023 0.181131 0.136398 0.384677 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.8 0.1 -0.8 0.3 2. Chi 0. 0. 4.8E-04 1.0E-03 7.0E-04 1.6E-04 7.4E-04 1.1E-04 2.5E-03 Composition Misfit: 5.761635E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.385 0.000000 0.000000 0.004667 0.000000 0.147571 0.002862 0.053892 0.427650 0.363357 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.9E-03 3.3E-04 1.8E-02 1.0E-03 1.4E-03 Composition Misfit: 2.396729E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.455 0.000000 0.000000 0.252092 0.000000 0.730464 0.008774 0.008671 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 0.2 0. 0. Chi 0. 0. 3.8E-02 0. 1.4E-02 1.7E-04 2.0E-04 0. 0. Composition Misfit: 5.221792E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.570 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.326 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.031 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000022 -.000022 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023313 0.014751 0.006979 0.016471 0.052925 0.000918 0.040314 0.028677 0.001869 0.108481 0.705302 Mica 0.017833 0.002481 0.000000 0.063401 0.005785 0.000000 0.005056 0.164949 0.000533 0.238889 0.501074 Gt 0.000000 0.030131 0.000000 0.000000 0.295130 0.040350 0.070329 0.000000 0.002714 0.136265 0.425081 Fsp 0.094487 0.057970 0.000000 0.001528 0.000000 0.000000 0.000000 0.000000 0.000000 0.153985 0.692030 Bio 0.000000 0.000000 0.021936 0.066966 0.173420 0.000904 0.160105 0.111995 0.004085 0.120565 0.340024 St 0.000000 0.000000 0.004245 0.000000 0.134213 0.002603 0.049014 0.088124 0.002395 0.388939 0.330466 Ilm 0.000000 0.000000 0.224290 0.000000 0.649905 0.007806 0.007714 0.000000 0.110284 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775942. -754707. -931983. -850180. -314179. -467955. -638458. -291534. -408984. -1635793. -886356. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 493 converged, 200 successes so far. Misfit function evaluations this try => 185 Misfit this try = 0.225834 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 3.574534E-07 Bayes score, PP * exp(-Misfit) = 2.851944E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 5685.89 884.232 0.901052 0.221491 Final coordinates: 7766.90 833.993 0.873744 0.515812 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.225834 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.447 0.027883 0.002578 0.000000 0.070077 0.004087 0.000000 0.004217 0.291535 0.599621 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -3. 0. 0. 1. 1. 0. 1. -0.6 4.9E-02 Chi 1.1E-02 0. 0. 3.0E-03 1.2E-02 0. 2.1E-02 4.2E-04 2.4E-07 Composition Misfit: 4.982466E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.080 0.000000 0.046333 0.000000 0.000000 0.289493 0.046041 0.055230 0.136657 0.426246 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 2. -1. -4.2E-02 0.5 -0.2 Chi 0. 1.4E-02 0. 0. 3.6E-03 3.0E-03 3.4E-06 3.8E-04 5.9E-06 Composition Misfit: 2.138925E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.848 0.094938 0.058506 0.000000 0.000809 0.000000 0.000000 0.000000 0.154253 0.691494 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.7 0. 0.2 0. 0. 0. 0.5 0.1 Chi 1.1E-04 8.2E-04 0. 3.7E-04 0. 0. 0. 2.9E-04 1.3E-05 Composition Misfit: 1.601687E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.959 0.000000 0.000000 0.020865 0.075042 0.190031 0.000732 0.197432 0.125632 0.390266 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. 0.1 -1. -0.4 0.2 -2. 1. 1. Chi 0. 0. 1.2E-05 8.7E-04 1.6E-04 6.5E-04 3.9E-03 1.7E-03 1.7E-03 Composition Misfit: 9.054848E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.425 0.000000 0.000000 0.003852 0.000000 0.153845 0.002454 0.047609 0.428689 0.363552 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.6 0. -2. 0.3 -3. 1. 1. Chi 0. 0. 3.1E-03 0. 3.4E-03 7.8E-04 1.3E-02 9.2E-04 1.4E-03 Composition Misfit: 2.244597E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.920 0.000000 0.000000 0.213201 0.000000 0.774963 0.006919 0.004917 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -7. 0.5 0.8 0. 0. Chi 0. 0. 0.1 0. 2.7E-02 1.4E-03 5.3E-03 0. 0. Composition Misfit: 0.121518 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.284 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.037 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023258 0.014716 0.006963 0.016433 0.052801 0.000916 0.040219 0.029934 0.002883 0.108226 0.703649 Mica 0.023257 0.002151 0.000000 0.058451 0.003409 0.000000 0.003518 0.165568 0.000334 0.243169 0.500143 Gt 0.000000 0.046207 0.000000 0.000000 0.288710 0.045917 0.055081 0.000000 0.002705 0.136287 0.425093 Fsp 0.094938 0.058506 0.000000 0.000809 0.000000 0.000000 0.000000 0.000000 0.000000 0.154253 0.691494 Bio 0.000000 0.000000 0.018401 0.066180 0.167588 0.000646 0.174115 0.113958 0.004143 0.110795 0.344175 St 0.000000 0.000000 0.003503 0.000000 0.139929 0.002232 0.043302 0.088178 0.002277 0.389912 0.330667 Ilm 0.000000 0.000000 0.186463 0.000000 0.677771 0.006051 0.004301 0.000000 0.125415 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -758015. -743959. -921911. -833152. -304195. -456056. -631365. -284787. -406351. -1623264. -878483. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 496 converged, 201 successes so far. Misfit function evaluations this try => 189 Misfit this try = 0.113580 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 9.414653E-07 Bayes score, PP * exp(-Misfit) = 8.403832E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 6695.14 976.782 0.860786 0.107442 Final coordinates: 8580.34 926.519 0.561218 0.491992 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.113489 Extraneous predicted phases: 9.016447E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.005 0.021358 0.002975 0.000000 0.075983 0.006934 0.000000 0.006058 0.286257 0.600436 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.7 0.7 0. 1. -0.3 -0.1 Chi 5.7E-03 0. 0. 9.5E-04 2.6E-03 0. 9.3E-03 1.2E-04 3.2E-07 Composition Misfit: 2.152817E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.105 0.000000 0.030204 0.000000 0.000000 0.296052 0.040372 0.070484 0.136646 0.426242 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.7 -1. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 2.3E-03 9.3E-04 3.5E-03 3.8E-04 5.9E-06 Composition Misfit: 1.015299E-2 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.589 0.094493 0.057957 0.000000 0.001528 0.000000 0.000000 0.000000 0.153979 0.692043 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -4.9E-02 0. 0. 0. 0.5 0.1 Chi 8.6E-05 7.0E-04 0. 1.9E-05 0. 0. 0. 3.1E-04 8.7E-06 Composition Misfit: 1.122390E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.541 0.000000 0.000000 0.024844 0.075761 0.196289 0.001020 0.180989 0.136415 0.384682 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -0.8 0.1 -0.8 0.3 2. Chi 0. 0. 4.9E-04 1.0E-03 7.1E-04 1.6E-04 7.3E-04 1.1E-04 2.5E-03 Composition Misfit: 5.763272E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.368 0.000000 0.000000 0.004681 0.000000 0.147604 0.002856 0.053849 0.427652 0.363359 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -1. 0.2 -4. 1. 1. Chi 0. 0. 1.5E-03 0. 1.9E-03 3.4E-04 1.8E-02 1.0E-03 1.4E-03 Composition Misfit: 2.392428E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.451 0.000000 0.000000 0.253085 0.000000 0.729378 0.008799 0.008738 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -5. 0.2 0.2 0. 0. Chi 0. 0. 3.7E-02 0. 1.4E-02 1.6E-04 1.8E-04 0. 0. Composition Misfit: 5.099830E-2 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.588 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.324 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 F 0.030 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000022 -.000022 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023314 0.014752 0.006980 0.016472 0.052929 0.000919 0.040317 0.028621 0.001857 0.108488 0.705352 Mica 0.017824 0.002482 0.000000 0.063409 0.005786 0.000000 0.005056 0.164948 0.000532 0.238887 0.501075 Gt 0.000000 0.030122 0.000000 0.000000 0.295250 0.040262 0.070293 0.000000 0.002710 0.136275 0.425087 Fsp 0.094493 0.057957 0.000000 0.001528 0.000000 0.000000 0.000000 0.000000 0.000000 0.153979 0.692043 Bio 0.000000 0.000000 0.021961 0.066968 0.173509 0.000902 0.159984 0.111976 0.004080 0.120583 0.340037 St 0.000000 0.000000 0.004257 0.000000 0.134243 0.002597 0.048975 0.088125 0.002391 0.388943 0.330469 Ilm 0.000000 0.000000 0.225274 0.000000 0.649226 0.007832 0.007778 0.000000 0.109891 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775942. -754705. -931960. -850176. -314177. -467978. -638464. -291534. -409050. -1635794. -886355. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 500 converged, 202 successes so far. Misfit function evaluations this try => 277 Misfit this try = 7.109544E-02 Best Misfit so far = 6.108472E-02 obtained on Try 302 Prior probability, PP = 8.272022E-07 Bayes score, PP * exp(-Misfit) = 7.704338E-07 Best Bayes score so far = 1.016718E-06 obtained on Try 238 P_bar T_K C_O2 C_H2O Initial coordinates: 7001.48 822.887 0.813114 0.439361 Final coordinates: 8093.10 873.508 0.419913 0.483226 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.109544E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 0.022976 0.002441 0.000000 0.074831 0.005591 0.000000 0.005141 0.288572 0.600449 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -2. 0. 0. 0.8 0.9 0. 1. -0.5 -0.1 Chi 6.9E-03 0. 0. 1.2E-03 5.5E-03 0. 1.4E-02 2.3E-04 3.4E-07 Composition Misfit: 3.011547E-2 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.340 0.000000 0.036905 0.000000 0.000000 0.301878 0.038399 0.059427 0.137012 0.426379 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -0.5 -0.4 0.5 -0.2 Chi 0. 7.2E-03 0. 0. 1.3E-03 4.5E-04 3.6E-04 3.4E-04 7.0E-06 Composition Misfit: 9.737097E-3 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.468 0.095134 0.057470 0.000000 0.001130 0.000000 0.000000 0.000000 0.153735 0.692530 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.6 0. 0.1 0. 0. 0. 0.5 0.1 Chi 1.3E-04 6.0E-04 0. 4.6E-05 0. 0. 0. 3.3E-04 5.6E-06 Composition Misfit: 1.113080E-3 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.739 0.000000 0.000000 0.023042 0.075437 0.200773 0.000757 0.181015 0.131560 0.387416 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.2 -1. -1. 0.2 -0.8 0.6 1. Chi 0. 0. 1.2E-04 9.5E-04 1.3E-03 5.9E-04 7.3E-04 5.8E-04 2.1E-03 Composition Misfit: 6.403047E-3 St vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.668 0.000000 0.000000 0.004218 0.000000 0.154577 0.002297 0.046997 0.428401 0.363510 observed 0.000000 0.000000 0.007333 0.000000 0.131046 0.003839 0.022928 0.448547 0.386307 std_resid. 0. 0. 0.5 0. -2. 0.3 -3. 1. 1. Chi 0. 0. 2.3E-03 0. 3.6E-03 1.0E-03 1.2E-02 9.5E-04 1.4E-03 Composition Misfit: 2.162152E-2 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.382 0.000000 0.000000 0.370448 0.000000 0.610427 0.008409 0.010715 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 0.9 0.3 -0.1 0. 0. Chi 0. 0. 1.1E-03 0. 6.3E-04 3.0E-04 4.8E-05 0. 0. Composition Misfit: 2.105221E-3 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.336 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 41.067 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023337 0.014766 0.006987 0.016489 0.052981 0.000919 0.040356 0.028138 0.001390 0.108594 0.706042 Mica 0.019169 0.002036 0.000000 0.062434 0.004664 0.000000 0.004289 0.165244 0.000418 0.240767 0.500977 Gt 0.000000 0.036811 0.000000 0.000000 0.301108 0.038301 0.059275 0.000000 0.002551 0.136662 0.425292 Fsp 0.095134 0.057470 0.000000 0.001130 0.000000 0.000000 0.000000 0.000000 0.000000 0.153735 0.692530 Bio 0.000000 0.000000 0.020348 0.066619 0.177302 0.000669 0.159854 0.112889 0.004011 0.116181 0.342127 St 0.000000 0.000000 0.003836 0.000000 0.140597 0.002089 0.042747 0.088169 0.002274 0.389655 0.330633 Ilm 0.000000 0.000000 0.347912 0.000000 0.573292 0.007897 0.010064 0.000000 0.060835 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -765620. -748686. -926182. -839908. -308167. -461965. -634658. -287811. -409210. -1628518. -881808. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky mstp ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky mstp ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ep Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ep Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 2 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 9274.95 955.716 0.292279 0.528760 0.421991 Mean perturbed parameters: 8944.62 941.524 0.356581 0.513438 0.241538 Parameter standard deviation: 660.669 28.3852 0.128604 3.064316E-02 0.360907 -------------------------------------------------------------------------------- Although Fsp St Ilm Mica Bio fak ky ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Mica Bio fak ky ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio F q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio F q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 3 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 10425.1 983.446 0.434463 0.716189 0.192607 Mean perturbed parameters: 9438.12 955.498 0.382542 0.581022 0.225228 Parameter standard deviation: 1363.01 44.4669 9.144229E-02 0.155716 0.271617 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Sp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Sp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky di mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky di mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 4 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 8797.19 952.765 0.426565 0.490651 4.01116 Mean perturbed parameters: 9277.89 954.815 0.393548 0.558429 1.17171 Parameter standard deviation: 1117.89 39.1641 7.473436E-02 0.127214 2.29134 -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio F fak ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio F fak ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 5 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 6418.72 897.098 0.813328 0.694825 1.87426 Mean perturbed parameters: 8706.05 943.271 0.477504 0.585708 1.31222 Parameter standard deviation: 1463.69 37.1333 0.206621 0.147686 2.18164 -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Mica Bio F fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Mica Bio F fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 6 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 8554.20 956.553 0.559919 0.425376 0.289823 Mean perturbed parameters: 8680.74 945.485 0.491240 0.558986 1.14182 Parameter standard deviation: 1309.44 35.6917 0.194987 0.136041 1.95400 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ged ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ged ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 7 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 13192.5 801.042 0.994676 0.329343 82.1904 Mean perturbed parameters: 9325.27 924.850 0.563159 0.526180 12.7202 Parameter standard deviation: 2218.59 60.9898 0.294205 0.142021 33.5766 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ep Ilm Mica fak ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ep Ilm Mica fak ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 8 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 10348.4 999.867 0.976194 0.685390 0.164403 Mean perturbed parameters: 9453.17 934.227 0.614789 0.546081 11.1507 Parameter standard deviation: 2156.06 62.7693 0.343866 0.149328 31.0859 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Sp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Sp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio F q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio F q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio F q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio F q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 9 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 9549.98 953.574 0.323992 0.706978 0.358868 Mean perturbed parameters: 9463.93 936.377 0.582478 0.563959 9.95162 Parameter standard deviation: 2043.76 59.4439 0.323477 0.158001 29.0784 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ep Ilm Gt Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ep Ilm Gt Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 10 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 7894.83 960.638 0.518009 0.502796 0.102353 Mean perturbed parameters: 9307.02 938.803 0.576031 0.557842 8.96669 Parameter standard deviation: 1941.74 57.1333 0.306690 0.148973 27.4154 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 11 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 8033.51 972.737 0.301046 0.721750 19.4914 Mean perturbed parameters: 9191.24 941.888 0.551032 0.572743 9.92348 Parameter standard deviation: 1851.23 56.0711 0.293409 0.158034 26.7244 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Gt Mica Bio ky ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Gt Mica Bio ky ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Sp Gt Mica Bio ky minm ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Sp Gt Mica Bio ky minm ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp lc ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp lc ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio F q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio F q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Sp Gt Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Sp Gt Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Gt Mica Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Gt Mica Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio F q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio F q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ep Ilm Mica Bio fak ky ged ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ep Ilm Mica Bio fak ky ged ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Sp Gt Mica Bio ky ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Sp Gt Mica Bio ky ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Mica fak ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Mica fak ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp St Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp St Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Ilm Gt Opx ky mstp ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Ilm Gt Opx ky mstp ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky di mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky di mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio F q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio F q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Sp Gt Bio ky ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Sp Gt Bio ky ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Sp Gt Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Sp Gt Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Bio ky ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Bio ky ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 12 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 9463.21 940.401 0.879490 0.457121 0.456812 Mean perturbed parameters: 9213.91 941.764 0.578404 0.563108 9.13459 Parameter standard deviation: 1783.54 53.6067 0.312062 0.151186 25.4810 -------------------------------------------------------------------------------- After 13 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 8223.91 881.567 0.426892 0.673439 9.72278 Mean perturbed parameters: 9137.75 937.133 0.566749 0.571595 9.17984 Parameter standard deviation: 1711.32 52.9975 0.298782 0.153343 24.5551 -------------------------------------------------------------------------------- After 14 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 11614.5 984.247 0.684924 0.519443 0.401471 Mean perturbed parameters: 9314.66 940.499 0.575190 0.567870 8.55281 Parameter standard deviation: 1842.76 53.3092 0.296254 0.147445 23.5920 -------------------------------------------------------------------------------- Although Fsp Fsp Sp Gt Bio ky ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Sp Gt Bio ky ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 15 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 7498.68 913.805 0.666953 0.728380 0.156747 Mean perturbed parameters: 9193.60 938.719 0.581308 0.578570 7.99308 Parameter standard deviation: 1800.58 51.4970 0.292955 0.154837 22.7338 -------------------------------------------------------------------------------- Although Fsp Ep Ilm Gt Mica fak ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ep Ilm Gt Mica fak ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 16 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 7312.16 900.556 0.738724 0.722973 43.6834 Mean perturbed parameters: 9076.01 936.334 0.591146 0.587596 10.2237 Parameter standard deviation: 1771.72 50.2289 0.294679 0.160458 24.6826 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 17 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 9365.28 934.917 0.412449 0.690202 0.438141 Mean perturbed parameters: 9093.02 936.251 0.580634 0.593631 9.64810 Parameter standard deviation: 1725.70 48.6709 0.285330 0.162615 23.8990 -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Opx fak ky di jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Opx fak ky di jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Sp Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Sp Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt Mica Bio sill minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt Mica Bio sill minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 18 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 8095.95 982.340 0.231797 0.685834 0.922404 Mean perturbed parameters: 9037.63 938.811 0.561255 0.598754 9.16334 Parameter standard deviation: 1678.89 49.0663 0.280584 0.164198 23.1864 -------------------------------------------------------------------------------- After 19 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 10583.9 903.049 0.256998 0.468963 0.294240 Mean perturbed parameters: 9119.01 936.929 0.545241 0.591923 8.69654 Parameter standard deviation: 1696.35 48.0262 0.275401 0.159720 22.5332 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 20 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 8927.23 893.019 0.302898 0.739497 0.151141 Mean perturbed parameters: 9109.42 934.733 0.533124 0.599301 8.26927 Parameter standard deviation: 1652.66 47.4034 0.269419 0.165028 21.9322 -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ep St Ilm Mica Bio fak ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ep St Ilm Mica Bio fak ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Opx ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Opx ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 21 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 11535.1 944.933 0.250638 0.567014 0.164642 Mean perturbed parameters: 9224.93 935.219 0.519672 0.597764 7.88334 Parameter standard deviation: 1738.19 46.3704 0.265342 0.161586 21.3769 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Opx fak ky di jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Opx fak ky di jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 22 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 9544.69 941.261 0.573521 0.644470 0.143636 Mean perturbed parameters: 9239.46 935.494 0.522120 0.599887 7.53153 Parameter standard deviation: 1708.40 45.3549 0.261081 0.160893 20.8617 -------------------------------------------------------------------------------- After 23 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 9629.72 927.278 0.273200 0.577694 0.160875 Mean perturbed parameters: 9256.43 935.137 0.511297 0.598922 7.21107 Parameter standard deviation: 1683.11 44.3121 0.257014 0.158107 20.3821 -------------------------------------------------------------------------------- Although Fsp Sp Gt Mica Bio ky fanth q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Sp Gt Mica Bio ky fanth q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Mica Bio fak ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Mica Bio fak ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 24 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 9549.27 926.698 0.268516 0.672061 0.644373 Mean perturbed parameters: 9268.63 934.785 0.501181 0.601969 6.93746 Parameter standard deviation: 1657.61 43.3383 0.253364 0.158828 19.9345 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica fak ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica fak ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 25 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 8027.94 980.307 0.371200 0.594620 0.108064 Mean perturbed parameters: 9219.01 936.606 0.495982 0.601675 6.66428 Parameter standard deviation: 1627.12 43.7822 0.248237 0.156727 19.5147 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky fanth mstp ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky fanth mstp ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 26 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 12758.7 978.409 0.287991 0.655476 0.271918 Mean perturbed parameters: 9355.15 938.214 0.487983 0.603745 6.41842 Parameter standard deviation: 1796.85 44.0972 0.244669 0.156752 19.1205 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 27 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 9745.87 948.473 0.859193 0.585978 3.96950 Mean perturbed parameters: 9369.62 938.594 0.501731 0.603087 6.32772 Parameter standard deviation: 1775.88 43.4392 0.254852 0.154671 18.7649 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Mica Bio F fak ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Mica Bio F fak ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Chl Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Chl Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 28 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 10162.7 956.296 0.380827 0.500307 2.28603 Mean perturbed parameters: 9397.94 939.226 0.497413 0.599416 6.18337 Parameter standard deviation: 1767.98 42.9901 0.250207 0.151781 18.4191 -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 29 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 8660.27 967.874 0.298919 0.531208 0.109356 Mean perturbed parameters: 9372.51 940.214 0.490568 0.597064 5.97393 Parameter standard deviation: 1736.14 42.9051 0.246777 0.149177 18.0872 -------------------------------------------------------------------------------- After 30 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 10425.2 925.311 0.230762 0.769148 0.344041 Mean perturbed parameters: 9407.60 939.717 0.481908 0.602800 5.78626 Parameter standard deviation: 1738.77 42.1605 0.245042 0.154982 17.7727 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Sp Gt Bio F fstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Sp Gt Bio F fstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky mstp lc q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky mstp lc q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky cen di mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky cen di mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Sp Gt Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Sp Gt Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 31 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 8367.64 931.120 0.731636 0.555508 1.04667 Mean perturbed parameters: 9374.05 939.440 0.489964 0.601274 5.63337 Parameter standard deviation: 1710.14 41.4577 0.247513 0.152737 17.4749 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky jd rieb minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky jd rieb minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 32 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 7099.33 933.634 0.552871 0.719945 0.178446 Mean perturbed parameters: 9302.96 939.258 0.491930 0.604983 5.46291 Parameter standard deviation: 1704.19 40.7992 0.244640 0.155446 17.1907 -------------------------------------------------------------------------------- After 33 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 7695.51 991.968 0.676334 0.457256 0.268445 Mean perturbed parameters: 9254.25 940.855 0.497518 0.600506 5.30550 Parameter standard deviation: 1685.20 41.7507 0.244985 0.153168 16.9200 -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky mstp lc ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky mstp lc ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt fak ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt fak ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 34 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 12485.5 999.426 0.436872 0.601750 0.156719 Mean perturbed parameters: 9349.29 942.578 0.495734 0.600543 5.15406 Parameter standard deviation: 1791.08 42.9861 0.241261 0.151904 16.6617 -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Mica ky fanth minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Mica ky fanth minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky minm mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky minm mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Mica Bio ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Mica Bio ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp St Ilm Gt Bio ky ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp St Ilm Gt Bio ky ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica fak ky minm ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica fak ky minm ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Sp Gt Mica Bio F q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Sp Gt Mica Bio F q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt Bio mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt Bio mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Mica fak ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Mica fak ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Sp Gt Bio mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Sp Gt Bio mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky ged mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky ged mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky fanth q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky fanth q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Sp Gt Mica Bio F q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Sp Gt Mica Bio F q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio fak ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio fak ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ep Ilm Gt Mica fak ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ep Ilm Gt Mica fak ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 35 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 9544.38 869.908 0.647232 0.367315 0.130801 Mean perturbed parameters: 9354.86 940.502 0.500063 0.593879 5.01054 Parameter standard deviation: 1771.74 43.4792 0.240835 0.151326 16.4148 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Opx Bio fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Opx Bio fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 36 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 10616.1 943.758 0.266277 0.662492 38.7373 Mean perturbed parameters: 9389.90 940.592 0.493569 0.595785 5.94740 Parameter standard deviation: 1778.73 42.9434 0.238804 0.151714 17.4496 -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Bio F fak and q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Bio F fak and q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky minm ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky minm ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp St Ilm Gt Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp St Ilm Gt Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Sp Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Sp Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky ged ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky ged ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Ilm Gt Bio F ky fanth q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Ilm Gt Bio F ky fanth q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 37 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 8774.27 975.760 0.301292 0.497576 1.12309 Mean perturbed parameters: 9373.26 941.543 0.488372 0.593131 5.81701 Parameter standard deviation: 1754.05 43.1052 0.236306 0.149592 17.2064 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Sp Gt Opx ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Sp Gt Opx ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ep Ilm Gt Mica Bio F ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ep Ilm Gt Mica Bio F ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 38 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 7471.34 924.805 0.664606 0.462520 0.188686 Mean perturbed parameters: 9323.21 941.102 0.493010 0.589694 5.66889 Parameter standard deviation: 1740.36 42.5207 0.236509 0.147673 16.9723 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt fak ky cen di jd acm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt fak ky cen di jd acm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Opx ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Opx ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp St Ilm Sp Gt Bio hcrd ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp St Ilm Sp Gt Bio hcrd ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ged q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ged q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 39 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 10399.7 995.546 0.180250 0.450873 19.7009 Mean perturbed parameters: 9350.81 942.498 0.484990 0.586134 6.02869 Parameter standard deviation: 1741.56 43.3922 0.236619 0.145918 17.0479 -------------------------------------------------------------------------------- After 40 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 7909.47 887.245 0.698080 0.562551 0.338060 Mean perturbed parameters: 9314.78 941.117 0.490317 0.585545 5.88642 Parameter standard deviation: 1722.79 43.3106 0.237746 0.144404 16.8279 -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Mica Bio minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Mica Bio minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky fanth q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky fanth q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Mica Bio F fak ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Mica Bio F fak ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt Bio F sill mstp ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt Bio F sill mstp ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Sp Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Sp Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio fanth q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio fanth q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 41 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 8705.72 942.692 0.765686 0.383703 0.125374 Mean perturbed parameters: 9299.92 941.155 0.497034 0.580622 5.74591 Parameter standard deviation: 1701.18 42.8347 0.241003 0.143731 16.6163 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Ilm Mica ky fanth minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Ilm Mica ky fanth minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 42 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 9411.61 924.886 0.472480 0.567943 0.152937 Mean perturbed parameters: 9302.58 940.768 0.496449 0.580320 5.61274 Parameter standard deviation: 1684.91 42.3108 0.238182 0.142385 16.4124 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica fak ky minm ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica fak ky minm ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky di mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky di mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Opx ky jd acm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Opx ky jd acm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio fak ky ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio fak ky ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 43 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 8323.25 883.791 0.478509 0.466522 0.152402 Mean perturbed parameters: 9279.81 939.443 0.496032 0.577673 5.48576 Parameter standard deviation: 1665.34 42.3405 0.235497 0.140765 16.2158 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Mica Bio fak ky ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Mica Bio fak ky ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Sp Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Sp Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 44 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 9229.02 902.758 0.434114 0.591424 0.425212 Mean perturbed parameters: 9278.65 938.609 0.494625 0.577986 5.37075 Parameter standard deviation: 1648.53 42.0128 0.232751 0.139844 16.0262 -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 45 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 6327.33 837.410 0.990973 0.843187 45.1754 Mean perturbed parameters: 9213.07 936.360 0.505655 0.583879 6.25529 Parameter standard deviation: 1665.76 43.6889 0.245618 0.147709 17.2412 -------------------------------------------------------------------------------- After 46 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 11066.4 998.761 0.351964 0.566573 0.297989 Mean perturbed parameters: 9253.36 937.717 0.502314 0.583503 6.12579 Parameter standard deviation: 1687.22 44.4937 0.243091 0.146415 17.0486 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio F sill minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio F sill minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Mica Bio F fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Mica Bio F fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 47 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 5485.21 868.351 0.351905 0.619517 0.819070 Mean perturbed parameters: 9173.18 936.241 0.499113 0.584269 6.01288 Parameter standard deviation: 1731.38 44.8584 0.240649 0.145917 16.8627 -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica fak ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica fak ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ep Ilm Gt fak ky minm mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ep Ilm Gt fak ky minm mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 48 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 8736.89 930.892 0.304988 0.768020 2.98579 Mean perturbed parameters: 9164.09 936.130 0.495069 0.588097 5.94981 Parameter standard deviation: 1712.95 44.3817 0.238675 0.149628 16.6878 -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky minm mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky minm mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky minm mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky minm mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio fak ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio fak ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 49 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 8793.45 904.028 0.446567 0.575213 157.226 Mean perturbed parameters: 9156.53 935.474 0.494079 0.587834 9.03709 Parameter standard deviation: 1695.21 44.0455 0.236205 0.148479 28.0586 -------------------------------------------------------------------------------- After 50 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 8777.66 998.090 0.176537 0.535882 1.17481 Mean perturbed parameters: 9148.95 936.727 0.487728 0.586795 8.87985 Parameter standard deviation: 1677.99 44.7504 0.236374 0.147055 27.7712 -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio F q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio F q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 51 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 8413.46 933.327 0.493194 0.543197 0.163270 Mean perturbed parameters: 9134.53 936.660 0.487836 0.585941 8.70893 Parameter standard deviation: 1661.36 44.3087 0.234221 0.145717 27.4921 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio fak ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio fak ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Mica Bio ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Mica Bio ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Opx ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Opx ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Mica fak ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Mica fak ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Sp Gt Mica Bio ky fanth q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Sp Gt Mica Bio ky fanth q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp St Mica Bio ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp St Mica Bio ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica fak ky minm ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica fak ky minm ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 52 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 9792.99 938.344 0.519344 0.478892 0.190269 Mean perturbed parameters: 9147.19 936.692 0.488442 0.583882 8.54511 Parameter standard deviation: 1653.26 43.8993 0.232323 0.144306 27.2213 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky fstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky fstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky minm mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky minm mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 53 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 7243.14 961.905 0.346860 0.457446 0.169921 Mean perturbed parameters: 9111.27 937.168 0.485770 0.581496 8.38709 Parameter standard deviation: 1648.29 43.7387 0.230307 0.143023 26.9582 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Sp Gt Opx ky mstp ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Sp Gt Opx ky mstp ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky jd ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky jd ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt Bio ky ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt Bio ky ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 54 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 9565.30 947.097 0.278343 0.423077 0.116316 Mean perturbed parameters: 9119.68 937.352 0.481929 0.578563 8.23393 Parameter standard deviation: 1637.88 43.4091 0.228963 0.142042 26.7027 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx ky jd mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx ky jd mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio F ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio F ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Mica ky minm ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Mica ky minm ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 55 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 7602.90 917.281 0.474489 0.465643 0.197706 Mean perturbed parameters: 9092.10 936.987 0.481794 0.576510 8.08781 Parameter standard deviation: 1628.47 43.0270 0.226950 0.140790 26.4543 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Sp Gt Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Sp Gt Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 56 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 10749.1 951.665 0.264906 0.493244 0.306291 Mean perturbed parameters: 9121.69 937.249 0.477921 0.575023 7.94886 Parameter standard deviation: 1639.07 42.7601 0.225859 0.139506 26.2127 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Gt Mica Bio ky zo ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Gt Mica Bio ky zo ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp St Ilm Gt Mica Bio F fak q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp St Ilm Gt Mica Bio F fak q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Opx fak ky mstp ab ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Opx fak ky mstp ab ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 57 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 8688.38 999.988 0.999998 0.617526 58.9650 Mean perturbed parameters: 9114.09 938.350 0.487080 0.575768 8.84388 Parameter standard deviation: 1624.40 43.4747 0.236834 0.139172 27.1440 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 58 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 7348.61 945.935 0.946231 0.611104 61.5094 Mean perturbed parameters: 9083.65 938.481 0.494996 0.576378 9.75190 Parameter standard deviation: 1618.79 43.1620 0.244843 0.138756 28.1090 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ep Ilm Gt Mica fak ky ged ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ep Ilm Gt Mica fak ky ged ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Sp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Sp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp St Ilm Sp Gt Bio F fak q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp St Ilm Sp Gt Bio F fak q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 59 successful perturbations: P_bar T_K C_O2 C_H2O OBJF Central model parameters: 8614.28 927.331 0.420883 0.498116 6.108472E-02 Perturbed central model parameter: 10900.6 989.613 0.978520 0.411005 99.3911 Mean perturbed parameters: 9114.44 939.347 0.503192 0.573575 11.2712 Parameter standard deviation: 1632.62 43.5628 0.253527 0.138029 30.7669 -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio ky ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio ky ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky ged q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky ged q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ky q --------------------------------------------------------------------------------