-------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 1 converged, 1 successes so far. Misfit function evaluations this try => 197 Misfit this try = 2.263975E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.070482E-06 Bayes score, PP * exp(-Misfit) = 1.046519E-06 Best Bayes score so far = 1.046519E-06 obtained on Try 1 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 10000.0 900.000 0.500000 0.500000 0.166667 0.166667 0.166667 0.166667 0.166667 0.166667 Final coordinates: 9371.70 926.634 0.825242 0.601647 4.299559E-02 0.245135 0.337367 0.226244 0.111699 3.655924E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.263975E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.716 0.011651 0.001167 0.000000 0.086182 0.009375 0.000000 0.007926 0.280006 0.603692 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.3 0. 0.8 2.8E-02 -0.5 Chi 1.4E-04 0. 0. 3.4E-05 3.4E-04 0. 4.0E-03 8.0E-07 2.3E-05 Composition Misfit: 5.690716E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.689 0.000000 0.029477 0.000000 0.000000 0.308082 0.034312 0.065046 0.136788 0.426295 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 0.8 -7.2E-03 -1. 0.5 -0.2 Chi 0. 2.7E-03 0. 0. 6.2E-04 1.2E-07 1.6E-03 3.6E-04 6.3E-06 Composition Misfit: 5.311602E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 36.907 0.098597 0.047212 0.000000 0.002797 0.000000 0.000000 0.000000 0.148606 0.702788 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.6 0.4 0. -0.4 0. 0. 0. 0.9 -0.4 Chi 4.9E-04 4.1E-04 0. 7.4E-04 0. 0. 0. 1.0E-03 9.8E-05 Composition Misfit: 2.751261E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 22.785 0.000000 0.000000 0.028966 0.075755 0.206680 0.000879 0.166281 0.136324 0.385116 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.2 0.2 0.3 2. Chi 0. 0. 2.0E-03 1.0E-03 2.4E-03 3.4E-04 6.3E-05 1.2E-04 2.5E-03 Composition Misfit: 8.389138E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.979 0.000000 0.000000 0.348095 0.000000 0.632213 0.008359 0.011333 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. -0.1 0.3 -0.2 0. 0. Chi 0. 0. 1.0E-05 0. 7.7E-06 3.2E-04 1.6E-04 0. 0. Composition Misfit: 4.970354E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.279 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.647 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.030289 0.021415 0.041916 0.021302 0.183111 0.009384 0.051504 0.036390 0.009444 0.137017 0.458229 Mica 0.009729 0.000975 0.000000 0.071964 0.007828 0.000000 0.006619 0.164361 0.000615 0.233812 0.504097 Gt 0.000000 0.029399 0.000000 0.000000 0.307266 0.034221 0.064874 0.000000 0.002648 0.136425 0.425166 Fsp 0.098597 0.047212 0.000000 0.002797 0.000000 0.000000 0.000000 0.000000 0.000000 0.148606 0.702788 Bio 0.000000 0.000000 0.025702 0.067220 0.183395 0.000780 0.147547 0.108738 0.003924 0.120965 0.341728 Ilm 0.000000 0.000000 0.323523 0.000000 0.587584 0.007769 0.010533 0.000000 0.070591 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -771678. -753976. -930228. -838381. -313180. -468450. -638441. -293713. -408771. -1634096. -884556. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 2 converged, 2 successes so far. Misfit function evaluations this try => 413 Misfit this try = 2.424595E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 7.601226E-07 Bayes score, PP * exp(-Misfit) = 7.419143E-07 Best Bayes score so far = 1.046519E-06 obtained on Try 1 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 5474.26 810.966 0.292163 0.731351 0.154754 7.320267E-02 3.580967E-03 0.116218 5.675165E-02 0.595493 Final coordinates: 9483.95 949.726 0.918767 0.973032 0.146491 0.261824 9.730421E-02 0.316375 0.166667 1.133804E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.424595E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.554 0.012224 0.001210 0.000000 0.085563 0.009786 0.000000 0.007838 0.279706 0.603672 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.3 0. 0. -0.1 0.2 0. 0.8 4.5E-02 -0.5 Chi 2.8E-04 0. 0. 1.4E-05 1.9E-04 0. 4.2E-03 2.1E-06 2.2E-05 Composition Misfit: 5.880503E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.136 0.000000 0.023612 0.000000 0.000000 0.309184 0.035108 0.068671 0.137036 0.426389 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.4 0. 0. 0.7 -0.1 -1. 0.5 -0.2 Chi 0. 4.0E-04 0. 0. 5.2E-04 2.1E-05 2.8E-03 3.4E-04 7.0E-06 Composition Misfit: 4.091543E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 10.924 0.099828 0.044008 0.000000 0.003168 0.000000 0.000000 0.000000 0.147004 0.705992 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.7 0.7 0. -0.5 0. 0. 0. 1. -0.5 Chi 6.7E-04 1.3E-03 0. 1.0E-03 0. 0. 0. 1.3E-03 1.9E-04 Composition Misfit: 4.512564E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 34.155 0.000000 0.000000 0.029676 0.075925 0.208217 0.000996 0.162474 0.138874 0.383837 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -2. 0.1 0.5 0.1 2. Chi 0. 0. 2.3E-03 1.1E-03 2.7E-03 1.8E-04 3.1E-04 1.5E-05 2.7E-03 Composition Misfit: 9.286318E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 12.180 0.000000 0.000000 0.348114 0.000000 0.630767 0.009033 0.012087 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. -3.5E-02 0.2 -0.3 0. 0. Chi 0. 0. 1.0E-05 0. 9.3E-07 1.0E-04 3.6E-04 0. 0. Composition Misfit: 4.750254E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.989 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 2.062 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.009798 0.009657 0.060440 0.032168 0.231578 0.010291 0.066650 0.058197 0.013298 0.131824 0.376099 Mica 0.010208 0.001010 0.000000 0.071448 0.008172 0.000000 0.006545 0.164322 0.000647 0.233564 0.504085 Gt 0.000000 0.023552 0.000000 0.000000 0.308399 0.035019 0.068496 0.000000 0.002540 0.136688 0.425306 Fsp 0.099828 0.044008 0.000000 0.003168 0.000000 0.000000 0.000000 0.000000 0.000000 0.147004 0.705992 Bio 0.000000 0.000000 0.026343 0.067396 0.184826 0.000884 0.144222 0.108449 0.003889 0.123274 0.340717 Ilm 0.000000 0.000000 0.323543 0.000000 0.586245 0.008395 0.011234 0.000000 0.070583 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776313. -757760. -933035. -843752. -315817. -471195. -640400. -295417. -410121. -1637599. -886833. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 3 converged, 3 successes so far. Misfit function evaluations this try => 912 Misfit this try = 2.994272E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 5.207049E-07 Bayes score, PP * exp(-Misfit) = 5.053447E-07 Best Bayes score so far = 1.046519E-06 obtained on Try 1 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 7829.77 980.531 7.867482E-02 0.911307 0.169370 0.207168 1.529109E-02 3.402537E-03 0.587192 1.757604E-02 Final coordinates: 9510.52 966.143 0.970547 0.803478 0.236204 0.510381 4.824034E-03 4.856556E-02 0.196283 3.743021E-03 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.994272E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 36.728 0.011250 0.001091 0.000000 0.086555 0.010499 0.000000 0.007638 0.279111 0.603856 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.1 0. 0. -0.2 0.1 0. 0.9 0.1 -0.5 Chi 7.1E-05 0. 0. 5.1E-05 4.1E-05 0. 4.6E-03 6.7E-06 2.5E-05 Composition Misfit: 5.855184E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 44.013 0.000000 0.020262 0.000000 0.000000 0.314482 0.034248 0.067462 0.137124 0.426422 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. 3.7E-02 0. 0. 0.4 -2.1E-04 -1. 0.5 -0.2 Chi 0. 4.0E-06 0. 0. 1.8E-04 1.0E-10 2.4E-03 3.3E-04 7.3E-06 Composition Misfit: 2.894290E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.026 0.100238 0.041707 0.000000 0.003908 0.000000 0.000000 0.000000 0.145854 0.708293 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.7 1. 0. -0.7 0. 0. 0. 1. -0.6 Chi 7.4E-04 2.3E-03 0. 1.7E-03 0. 0. 0. 1.6E-03 2.7E-04 Composition Misfit: 6.564878E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.790 0.000000 0.000000 0.030926 0.076120 0.215708 0.001049 0.152106 0.141793 0.382300 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -2. 0.1 1. -0.1 2. Chi 0. 0. 3.0E-03 1.1E-03 4.5E-03 1.3E-04 2.0E-03 1.5E-05 3.0E-03 Composition Misfit: 1.368679E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.689 0.000000 0.000000 0.337992 0.000000 0.641566 0.008971 0.011470 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.7 0. -0.5 0.2 -0.2 0. 0. Chi 0. 0. 4.3E-04 0. 2.1E-04 1.2E-04 1.9E-04 0. 0. Composition Misfit: 9.415781E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.753 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.002732 0.010018 0.065070 0.021950 0.279544 0.018205 0.038640 0.049150 0.016957 0.138376 0.359358 Mica 0.009394 0.000911 0.000000 0.072278 0.008767 0.000000 0.006378 0.164257 0.000688 0.233073 0.504252 Gt 0.000000 0.020211 0.000000 0.000000 0.313695 0.034163 0.067293 0.000000 0.002502 0.136781 0.425355 Fsp 0.100238 0.041707 0.000000 0.003908 0.000000 0.000000 0.000000 0.000000 0.000000 0.145854 0.708293 Bio 0.000000 0.000000 0.027473 0.067621 0.191623 0.000932 0.135123 0.107769 0.003884 0.125962 0.339615 Ilm 0.000000 0.000000 0.312665 0.000000 0.593491 0.008299 0.010611 0.000000 0.074934 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -779932. -760633. -935350. -846379. -317639. -473530. -642265. -297360. -411382. -1640246. -888599. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 6 converged, 4 successes so far. Misfit function evaluations this try => 521 Misfit this try = 2.46150 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 3.254295E-07 Bayes score, PP * exp(-Misfit) = 2.776128E-08 Best Bayes score so far = 1.046519E-06 obtained on Try 1 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 13844.6 810.962 0.949612 0.625890 0.304729 4.407598E-02 0.215734 0.359305 4.248801E-02 3.366935E-02 Final coordinates: 7584.24 833.019 0.955693 0.656479 0.601704 6.612129E-02 2.766909E-02 0.266490 1.477325E-02 2.324246E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.46150 Extraneous predicted phases: 4.051526E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.874 0.006478 0.000525 0.000000 0.091939 0.007251 0.000000 0.007271 0.283098 0.603438 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.6 0. 0. -0.6 0.6 0. 0.9 -0.2 -0.4 Chi 2.3E-03 0. 0. 6.1E-04 2.1E-03 0. 5.4E-03 2.4E-05 2.0E-05 Composition Misfit: 1.101904E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.261 0.000000 0.061085 0.000000 0.000000 0.266519 0.067357 0.044874 0.134665 0.425499 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -5. 0. 0. 3. -4. 0.9 0.7 -0.1 Chi 0. 2.7E-02 0. 0. 1.2E-02 1.6E-02 2.2E-03 6.2E-04 1.7E-06 Composition Misfit: 5.751131E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 45.626 0.020369 0.001529 0.000000 0.103867 0.000000 0.000000 0.000000 0.125764 0.748471 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -3.0E+01 0. 0. 0. 2. -2. Chi 0.2 2. 0. 0.1 0. 0. 0. 9.8E-03 3.9E-03 Composition Misfit: 2.00405 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.317 0.000000 0.000000 0.026290 0.075440 0.198459 0.001146 0.181060 0.131595 0.386010 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.6 -1. -0.9 0.1 -0.8 0.6 2. Chi 0. 0. 9.2E-04 9.6E-04 9.9E-04 6.7E-05 7.4E-04 5.8E-04 2.3E-03 Composition Misfit: 6.566465E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.171 0.000000 0.000000 0.144467 0.000000 0.847606 0.005893 0.002033 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 1.1E+01 0. -1.0E+01 0.7 1. 0. 0. Chi 0. 0. 0.3 0. 0.1 2.9E-03 3.1E-02 0. 0. Composition Misfit: 0.382350 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.748 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 ab 0.002 0.125000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.125000 0.750000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.008124 0.002512 0.009797 0.063718 0.078200 0.002517 0.051767 0.039224 0.004671 0.204361 0.535109 Mica 0.005408 0.000438 0.000000 0.076742 0.006053 0.000000 0.006069 0.164738 0.000550 0.236305 0.503697 Gt 0.000000 0.060867 0.000000 0.000000 0.265568 0.067116 0.044714 0.000000 0.003571 0.134184 0.423980 Fsp 0.020369 0.001529 0.000000 0.103867 0.000000 0.000000 0.000000 0.000000 0.000000 0.125764 0.748471 Bio 0.000000 0.000000 0.023269 0.066771 0.175655 0.001015 0.160255 0.110273 0.004635 0.116473 0.341654 Ilm 0.000000 0.000000 0.122662 0.000000 0.719672 0.005004 0.001727 0.000000 0.150935 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -756884. -742932. -924985. -817172. -304850. -453513. -632560. -292204. -400793. -1623516. -878801. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 7 converged, 5 successes so far. Misfit function evaluations this try => 232 Misfit this try = 2.471185E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 8.799463E-07 Bayes score, PP * exp(-Misfit) = 8.584677E-07 Best Bayes score so far = 1.046519E-06 obtained on Try 1 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 13000.6 945.991 0.791245 0.150437 2.521945E-02 1.922170E-02 0.362086 0.107434 0.180992 0.305048 Final coordinates: 9410.91 941.334 0.990294 0.287476 2.334955E-02 2.394540E-03 0.843477 6.276964E-02 1.912218E-02 4.888710E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.471185E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.613 0.011819 0.001543 0.000000 0.085804 0.009408 0.000000 0.008154 0.279900 0.603372 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.3 0. 0.8 3.4E-02 -0.4 Chi 1.8E-04 0. 0. 2.1E-05 3.2E-04 0. 3.6E-03 1.2E-06 1.9E-05 Composition Misfit: 5.654320E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.240 0.000000 0.032295 0.000000 0.000000 0.299632 0.036911 0.068538 0.136454 0.426170 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -0.3 -1. 0.5 -0.2 Chi 0. 4.3E-03 0. 0. 1.7E-03 1.9E-04 2.8E-03 4.0E-04 5.4E-06 Composition Misfit: 9.283582E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 82.302 0.095524 0.053493 0.000000 0.002729 0.000000 0.000000 0.000000 0.151747 0.696507 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.2 0. -0.4 0. 0. 0. 0.6 -0.1 Chi 1.6E-04 6.7E-05 0. 6.9E-04 0. 0. 0. 5.5E-04 5.8E-06 Composition Misfit: 1.471189E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.949 0.000000 0.000000 0.029243 0.075840 0.200800 0.001006 0.171003 0.137598 0.384511 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.1 -0.1 0.2 2. Chi 0. 0. 2.1E-03 1.0E-03 1.3E-03 1.7E-04 1.3E-05 5.4E-05 2.6E-03 Composition Misfit: 7.301937E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.098 0.000000 0.000000 0.357169 0.000000 0.620229 0.009614 0.012988 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.4 0. 0.4 0.1 -0.5 0. 0. Chi 0. 0. 1.4E-04 0. 1.5E-04 1.6E-05 6.9E-04 0. 0. Composition Misfit: 1.000826E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.321 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.477 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.076566 0.042739 0.007881 0.011231 0.024723 0.000356 0.011714 0.017511 0.001530 0.161981 0.643768 Mica 0.009869 0.001288 0.000000 0.071650 0.007856 0.000000 0.006809 0.164327 0.000629 0.233729 0.503842 Gt 0.000000 0.032205 0.000000 0.000000 0.298795 0.036808 0.068346 0.000000 0.002794 0.136072 0.424979 Fsp 0.095524 0.053493 0.000000 0.002729 0.000000 0.000000 0.000000 0.000000 0.000000 0.151747 0.696507 Bio 0.000000 0.000000 0.025952 0.067304 0.178200 0.000893 0.151757 0.108657 0.003892 0.122111 0.341235 Ilm 0.000000 0.000000 0.333362 0.000000 0.578888 0.008973 0.012122 0.000000 0.066655 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775591. -754813. -931784. -842532. -315143. -469827. -639449. -294551. -409041. -1636388. -886075. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 8 converged, 6 successes so far. Misfit function evaluations this try => 194 Misfit this try = 3.478135E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.121753E-06 Bayes score, PP * exp(-Misfit) = 1.083408E-06 Best Bayes score so far = 1.083408E-06 obtained on Try 8 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 9921.77 891.231 9.407108E-02 0.552155 6.649955E-03 0.690282 7.116839E-02 2.305753E-03 1.367711E-02 0.215917 Final coordinates: 8746.89 897.712 0.186829 0.699022 4.717592E-03 0.738713 1.579038E-02 1.757907E-03 1.595946E-02 0.223061 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.478135E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 32.843 0.013828 0.000809 0.000000 0.084414 0.008363 0.000000 0.006466 0.282815 0.603305 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.5 0. 0. 4.0E-03 0.4 0. 1. -0.1 -0.4 Chi 8.7E-04 0. 0. 2.7E-08 9.3E-04 0. 7.8E-03 1.9E-05 1.8E-05 Composition Misfit: 1.040082E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 63.707 0.000000 0.021074 0.000000 0.000000 0.322841 0.034287 0.057196 0.137893 0.426710 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.1 0. 0. -0.1 -4.4E-03 -0.2 0.4 -0.2 Chi 0. 1.3E-05 0. 0. 2.6E-06 4.7E-08 1.0E-04 2.6E-04 9.9E-06 Composition Misfit: 3.825565E-04 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.814 0.103773 0.037513 0.000000 0.002471 0.000000 0.000000 0.000000 0.143756 0.712487 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -1. 1. 0. -0.3 0. 0. 0. 1. -0.8 Chi 1.4E-03 5.3E-03 0. 5.0E-04 0. 0. 0. 2.0E-03 4.5E-04 Composition Misfit: 9.701759E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.097 0.000000 0.000000 0.027253 0.075728 0.221592 0.000775 0.153454 0.135917 0.385282 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.7 -1. -2. 0.2 1. 0.3 2. Chi 0. 0. 1.3E-03 1.0E-03 6.2E-03 5.5E-04 1.7E-03 1.4E-04 2.4E-03 Composition Misfit: 1.331664E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.306 0.000000 0.000000 0.352623 0.000000 0.630880 0.007475 0.009022 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.1 0. -4.0E-02 0.4 0.2 0. 0. Chi 0. 0. 2.0E-05 0. 1.2E-06 8.5E-04 1.1E-04 0. 0. Composition Misfit: 9.795710E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.232 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.003627 0.015240 0.005358 0.018464 0.238904 0.024260 0.041945 0.043079 0.002790 0.164775 0.441558 Mica 0.011543 0.000676 0.000000 0.070466 0.006981 0.000000 0.005398 0.164694 0.000542 0.236084 0.503617 Gt 0.000000 0.021028 0.000000 0.000000 0.322141 0.034212 0.057072 0.000000 0.002167 0.137594 0.425785 Fsp 0.103773 0.037513 0.000000 0.002471 0.000000 0.000000 0.000000 0.000000 0.000000 0.143756 0.712487 Bio 0.000000 0.000000 0.024147 0.067096 0.196334 0.000686 0.135962 0.110045 0.003941 0.120424 0.341365 Ilm 0.000000 0.000000 0.328422 0.000000 0.587582 0.006962 0.008403 0.000000 0.068631 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -766650. -754022. -928302. -835657. -309892. -465202. -637136. -291727. -410398. -1630858. -882870. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 9 converged, 7 successes so far. Misfit function evaluations this try => 760 Misfit this try = 1.60475 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 4.120567E-07 Bayes score, PP * exp(-Misfit) = 8.279852E-08 Best Bayes score so far = 1.083408E-06 obtained on Try 8 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 12422.5 810.444 0.196856 0.441588 0.299405 7.774230E-03 8.294593E-02 2.585286E-03 4.544173E-02 0.561848 Final coordinates: 6244.85 900.564 0.723687 0.204520 0.717492 2.933742E-02 2.148777E-02 8.627134E-03 2.129509E-02 0.201760 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.60427 Extraneous predicted phases: 4.846949E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.003 0.005043 0.000877 0.000000 0.093392 0.007668 0.000000 0.005036 0.285793 0.602190 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.8 0. 0. -0.7 0.5 0. 1. -0.3 -0.3 Chi 5.6E-03 0. 0. 8.5E-04 1.6E-03 0. 1.4E-02 9.9E-05 8.0E-06 Composition Misfit: 2.340424E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.310 0.000000 0.032852 0.000000 0.000000 0.250852 0.110541 0.041490 0.137646 0.426617 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 4. -8. 1. 0.4 -0.2 Chi 0. 4.6E-03 0. 0. 2.0E-02 0.1 4.3E-03 2.8E-04 9.0E-06 Composition Misfit: 8.195268E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 63.016 0.017606 0.002362 0.000000 0.106214 0.000000 0.000000 0.000000 0.126181 0.747638 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -3.0E+01 0. 0. 0. 2. -2. Chi 0.3 1. 0. 0.1 0. 0. 0. 9.6E-03 3.8E-03 Composition Misfit: 1.45468 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 9.643 0.000000 0.000000 0.033669 0.076934 0.224038 0.002833 0.133127 0.154008 0.375392 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -3. -0.4 2. -1. 2. Chi 0. 0. 4.5E-03 1.3E-03 7.0E-03 7.0E-04 9.9E-03 1.2E-03 4.4E-03 Composition Misfit: 2.902403E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.643 0.000000 0.000000 0.323845 0.000000 0.640240 0.028511 0.007404 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 1. 0. -0.5 -3. 0.4 0. 0. Chi 0. 0. 2.1E-03 0. 1.6E-04 1.2E-02 9.1E-04 0. 0. Composition Misfit: 1.520436E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.372 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.013 0.000000 0.000000 0.224906 0.000000 0.638332 0.021928 0.004796 0.000000 0.110037 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.010147 0.001511 0.006744 0.069093 0.030645 0.001086 0.013894 0.012311 0.001386 0.235510 0.617672 Mica 0.004208 0.000732 0.000000 0.077926 0.006399 0.000000 0.004202 0.165000 0.000600 0.238466 0.502467 Gt 0.000000 0.032778 0.000000 0.000000 0.250282 0.110290 0.041396 0.000000 0.002275 0.137333 0.425647 Fsp 0.017606 0.002362 0.000000 0.106214 0.000000 0.000000 0.000000 0.000000 0.000000 0.126181 0.747638 Bio 0.000000 0.000000 0.029934 0.068400 0.199186 0.002519 0.118360 0.106865 0.004062 0.136924 0.333751 Ilm 0.000000 0.000000 0.297630 0.000000 0.588414 0.026203 0.006805 0.000000 0.080948 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -783411. -755088. -933228. -840738. -314253. -459375. -641564. -299031. -409714. -1636720. -888918. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 10 converged, 8 successes so far. Misfit function evaluations this try => 397 Misfit this try = 2.388101E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 5.642395E-07 Bayes score, PP * exp(-Misfit) = 5.509245E-07 Best Bayes score so far = 1.083408E-06 obtained on Try 8 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 7671.19 982.612 0.771516 0.813997 5.433094E-03 6.444909E-02 5.843541E-02 0.314425 0.389796 0.167462 Final coordinates: 9653.60 963.413 0.796694 0.934521 1.135706E-04 0.178284 0.361156 0.155827 7.112570E-02 0.233494 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.388101E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.652 0.011480 0.001467 0.000000 0.086105 0.010214 0.000000 0.008222 0.278879 0.603632 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.1 0. 0.8 0.1 -0.5 Chi 1.1E-04 0. 0. 3.1E-05 8.7E-05 0. 3.4E-03 9.2E-06 2.2E-05 Composition Misfit: 5.173224E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 13.632 0.000000 0.027030 0.000000 0.000000 0.306030 0.033263 0.070909 0.136559 0.426209 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.8 0. 0. 0.9 0.1 -2. 0.5 -0.2 Chi 0. 1.6E-03 0. 0. 8.2E-04 2.9E-05 3.7E-03 3.9E-04 5.7E-06 Composition Misfit: 6.463905E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 37.391 0.096947 0.049498 0.000000 0.003304 0.000000 0.000000 0.000000 0.149749 0.700502 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.4 0.2 0. -0.6 0. 0. 0. 0.8 -0.3 Chi 2.9E-04 8.9E-05 0. 1.1E-03 0. 0. 0. 8.3E-04 5.1E-05 Composition Misfit: 2.406336E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 14.568 0.000000 0.000000 0.030331 0.075986 0.205400 0.000997 0.164142 0.139791 0.383354 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.1 0.4 3.8E-02 2. Chi 0. 0. 2.6E-03 1.1E-03 2.1E-03 1.8E-04 1.8E-04 1.9E-06 2.8E-03 Composition Misfit: 8.988838E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.740 0.000000 0.000000 0.345547 0.000000 0.632613 0.008935 0.012904 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.2 0. -0.1 0.2 -0.5 0. 0. Chi 0. 0. 5.7E-05 0. 1.1E-05 1.3E-04 6.5E-04 0. 0. Composition Misfit: 8.487018E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.747 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.269 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.033305 0.020907 0.026464 0.028743 0.125228 0.006600 0.037562 0.056104 0.006236 0.160470 0.498380 Mica 0.009587 0.001225 0.000000 0.071907 0.008530 0.000000 0.006866 0.164214 0.000679 0.232894 0.504098 Gt 0.000000 0.026955 0.000000 0.000000 0.305189 0.033172 0.070714 0.000000 0.002748 0.136183 0.425038 Fsp 0.096947 0.049498 0.000000 0.003304 0.000000 0.000000 0.000000 0.000000 0.000000 0.149749 0.700502 Bio 0.000000 0.000000 0.026936 0.067482 0.182412 0.000885 0.145771 0.108028 0.003889 0.124146 0.340450 Ilm 0.000000 0.000000 0.320775 0.000000 0.587261 0.008295 0.011979 0.000000 0.071690 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -779405. -758055. -934369. -845977. -317436. -473303. -641344. -296465. -410039. -1639483. -887966. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 12 converged, 9 successes so far. Misfit function evaluations this try => 266 Misfit this try = 2.333411E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.010469E-06 Bayes score, PP * exp(-Misfit) = 9.871636E-07 Best Bayes score so far = 1.083408E-06 obtained on Try 8 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 6365.52 929.894 0.697280 0.466721 2.423924E-02 1.448729E-02 9.535680E-02 5.705242E-02 3.031876E-02 0.778545 Final coordinates: 9425.11 931.993 0.768211 0.884486 4.825211E-02 0.330524 0.243498 7.419900E-02 9.893343E-02 0.204593 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.333411E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 32.767 0.012273 0.001158 0.000000 0.085569 0.009435 0.000000 0.007836 0.280052 0.603677 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.3 0. 0. -0.1 0.3 0. 0.8 2.5E-02 -0.5 Chi 3.0E-04 0. 0. 1.4E-05 3.1E-04 0. 4.2E-03 6.5E-07 2.2E-05 Composition Misfit: 5.967933E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.808 0.000000 0.026547 0.000000 0.000000 0.310800 0.033021 0.066310 0.136962 0.426361 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.8 0. 0. 0.6 0.1 -1. 0.5 -0.2 Chi 0. 1.4E-03 0. 0. 4.0E-04 4.5E-05 2.0E-03 3.4E-04 6.8E-06 Composition Misfit: 4.150428E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.354 0.099792 0.044735 0.000000 0.002840 0.000000 0.000000 0.000000 0.147368 0.705265 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.7 0.7 0. -0.4 0. 0. 0. 0.9 -0.5 Chi 6.6E-04 1.1E-03 0. 7.7E-04 0. 0. 0. 1.2E-03 1.6E-04 Composition Misfit: 3.896486E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.562 0.000000 0.000000 0.028909 0.075779 0.207722 0.000866 0.165091 0.136679 0.384954 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -2. 0.2 0.3 0.3 2. Chi 0. 0. 2.0E-03 1.0E-03 2.6E-03 3.6E-04 1.2E-04 9.7E-05 2.5E-03 Composition Misfit: 8.669938E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.274 0.000000 0.000000 0.348105 0.000000 0.632353 0.008096 0.011446 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. -0.1 0.3 -0.2 0. 0. Chi 0. 0. 1.0E-05 0. 8.8E-06 4.5E-04 1.8E-04 0. 0. Composition Misfit: 6.493248E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.764 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 0.471 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023391 0.018156 0.033968 0.025003 0.173761 0.011645 0.032928 0.053616 0.008343 0.157636 0.461554 Mica 0.010248 0.000967 0.000000 0.071451 0.007878 0.000000 0.006543 0.164366 0.000618 0.233848 0.504080 Gt 0.000000 0.026479 0.000000 0.000000 0.310000 0.032936 0.066139 0.000000 0.002573 0.136609 0.425264 Fsp 0.099792 0.044735 0.000000 0.002840 0.000000 0.000000 0.000000 0.000000 0.000000 0.147368 0.705265 Bio 0.000000 0.000000 0.025650 0.067236 0.184305 0.000768 0.146480 0.108822 0.003912 0.121271 0.341557 Ilm 0.000000 0.000000 0.323533 0.000000 0.587717 0.007525 0.010638 0.000000 0.070587 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772444. -755143. -930866. -839832. -313701. -469383. -638851. -293928. -409257. -1634843. -885018. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 14 converged, 10 successes so far. Misfit function evaluations this try => 501 Misfit this try = 0.948075 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.875154E-07 Bayes score, PP * exp(-Misfit) = 7.265963E-08 Best Bayes score so far = 1.083408E-06 obtained on Try 8 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 13872.6 980.066 0.434370 0.656382 0.337277 2.407461E-02 1.325043E-02 0.534363 3.590022E-02 5.513458E-02 Final coordinates: 8329.11 991.981 0.727756 0.952332 0.871762 3.025220E-02 3.444377E-02 1.006671E-02 1.896548E-02 3.450971E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.948075 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 27.317 0.005489 0.001218 0.000000 0.092353 0.010717 0.000000 0.006609 0.280482 0.603131 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.8 0. 0. -0.7 0.1 0. 1. -2.0E-04 -0.4 Chi 4.3E-03 0. 0. 6.7E-04 1.8E-05 0. 7.3E-03 4.3E-11 1.6E-05 Composition Misfit: 1.352650E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.564 0.000000 0.027944 0.000000 0.000000 0.274593 0.078443 0.056025 0.136724 0.426271 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.9 0. 0. 3. -5. -0.1 0.5 -0.2 Chi 0. 2.0E-03 0. 0. 8.2E-03 2.5E-02 2.7E-05 3.7E-04 6.1E-06 Composition Misfit: 3.541793E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 44.300 0.024436 0.003999 0.000000 0.098564 0.000000 0.000000 0.000000 0.127000 0.746001 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -2.8E+01 0. 0. 0. 2. -2. Chi 0.2 0.6 0. 0.1 0. 0. 0. 9.0E-03 3.6E-03 Composition Misfit: 0.859764 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.520 0.000000 0.000000 0.037084 0.076942 0.219883 0.002841 0.133327 0.154127 0.375796 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -2. -0.4 2. -1. 2. Chi 0. 0. 6.7E-03 1.3E-03 5.7E-03 7.1E-04 9.8E-03 1.2E-03 4.3E-03 Composition Misfit: 2.971878E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.550 0.000000 0.000000 0.327551 0.000000 0.638014 0.023756 0.010679 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 1. 0. -0.4 -2. -0.1 0. 0. Chi 0. 0. 1.5E-03 0. 1.0E-04 8.0E-03 4.3E-05 0. 0. Composition Misfit: 9.647892E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.749 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.011010 0.002105 0.006015 0.067815 0.029537 0.001088 0.013894 0.056892 0.001343 0.233018 0.577283 Mica 0.004583 0.001017 0.000000 0.077101 0.008947 0.000000 0.005518 0.164384 0.000770 0.234159 0.503521 Gt 0.000000 0.027869 0.000000 0.000000 0.273858 0.078233 0.055875 0.000000 0.002676 0.136358 0.425131 Fsp 0.024436 0.003999 0.000000 0.098564 0.000000 0.000000 0.000000 0.000000 0.000000 0.127000 0.746001 Bio 0.000000 0.000000 0.033078 0.068629 0.196125 0.002534 0.118922 0.104179 0.003866 0.137474 0.335193 Ilm 0.000000 0.000000 0.301550 0.000000 0.587368 0.021870 0.009831 0.000000 0.079380 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -794903. -763030. -940860. -851360. -322947. -471420. -647237. -304474. -411832. -1647127. -894238. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 15 converged, 11 successes so far. Misfit function evaluations this try => 643 Misfit this try = 0.925130 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.652928E-07 Bayes score, PP * exp(-Misfit) = 6.553527E-08 Best Bayes score so far = 1.083408E-06 obtained on Try 8 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 8259.50 822.387 0.901179 0.941285 4.074764E-03 7.394679E-02 4.390453E-03 0.416405 4.843764E-02 0.452745 Final coordinates: 9278.71 999.999 0.342328 0.999273 1.751921E-09 0.196058 8.580289E-04 0.378908 4.276844E-02 0.381407 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.925130 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.633 0.005619 0.001117 0.000000 0.092083 0.011960 0.000000 0.007368 0.277935 0.603920 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.7 0. 0. -0.6 -0.1 0. 0.9 0.1 -0.5 Chi 4.0E-03 0. 0. 6.3E-04 5.4E-05 0. 5.2E-03 2.3E-05 2.5E-05 Composition Misfit: 1.102925E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.896 0.000000 0.028644 0.000000 0.000000 0.296258 0.053463 0.059279 0.136259 0.426097 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -2. -0.4 0.5 -0.2 Chi 0. 2.3E-03 0. 0. 2.2E-03 6.9E-03 3.4E-04 4.2E-04 4.9E-06 Composition Misfit: 1.218319E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.059 0.026102 0.003845 0.000000 0.096976 0.000000 0.000000 0.000000 0.126923 0.746155 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 5. 5. 0. -2.8E+01 0. 0. 0. 2. -2. Chi 0.2 0.6 0. 0.1 0. 0. 0. 9.1E-03 3.6E-03 Composition Misfit: 0.864497 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 55.997 0.000000 0.000000 0.037218 0.076707 0.222854 0.001932 0.133003 0.150599 0.377688 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -3. -0.1 2. -0.7 2. Chi 0. 0. 6.8E-03 1.2E-03 6.6E-03 1.3E-04 1.0E-02 7.0E-04 3.9E-03 Composition Misfit: 2.933782E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.573 0.000000 0.000000 0.312051 0.000000 0.662179 0.015394 0.010377 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 2. 0. -1. -0.9 -0.1 0. 0. Chi 0. 0. 4.6E-03 0. 1.6E-03 1.9E-03 1.4E-05 0. 0. Composition Misfit: 8.082347E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 13.324 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 2.518 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.003771 0.003812 0.021586 0.053891 0.153681 0.007189 0.075401 0.060842 0.003288 0.176393 0.440146 Mica 0.004692 0.000933 0.000000 0.076897 0.009987 0.000000 0.006153 0.164111 0.000804 0.232099 0.504325 Gt 0.000000 0.028561 0.000000 0.000000 0.295405 0.053310 0.059108 0.000000 0.002878 0.135867 0.424871 Fsp 0.026102 0.003845 0.000000 0.096976 0.000000 0.000000 0.000000 0.000000 0.000000 0.126923 0.746155 Bio 0.000000 0.000000 0.033215 0.068456 0.198883 0.001724 0.118697 0.103697 0.003864 0.134400 0.337064 Ilm 0.000000 0.000000 0.285245 0.000000 0.605296 0.014071 0.009486 0.000000 0.085902 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -791789. -762395. -940214. -847986. -322518. -474702. -646841. -304153. -411708. -1646431. -892967. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 16 converged, 12 successes so far. Misfit function evaluations this try => 1011 Misfit this try = 1.75455 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 9.646313E-08 Bayes score, PP * exp(-Misfit) = 1.668675E-08 Best Bayes score so far = 1.083408E-06 obtained on Try 8 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 14269.0 858.578 0.946215 0.837637 0.106939 1.047351E-02 0.156439 0.451443 8.891270E-03 0.265814 Final coordinates: 14138.0 977.791 0.940852 0.844884 0.136208 3.365044E-03 0.127985 0.572362 5.106655E-03 0.154973 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.75455 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.843 0.006109 0.000467 0.000000 0.090527 0.014249 0.000000 0.019630 0.259539 0.609478 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.7 0. 0. -0.5 -0.5 0. -0.9 1. -1. Chi 3.0E-03 0. 0. 4.1E-04 6.7E-04 0. 1.9E-03 1.7E-03 1.5E-04 Composition Misfit: 8.224316E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 9.793 0.000000 0.038875 0.000000 0.000000 0.282232 0.006192 0.117203 0.131271 0.424227 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. 3. -6. 0.9 0.1 Chi 0. 8.6E-03 0. 0. 5.6E-03 0.1 3.3E-02 1.2E-03 4.4E-07 Composition Misfit: 0.175763 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 39.547 0.038989 0.002628 0.000000 0.084697 0.000000 0.000000 0.000000 0.126314 0.747372 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 4. 5. 0. -2.4E+01 0. 0. 0. 2. -2. Chi 0.1 0.9 0. 0.1 0. 0. 0. 9.5E-03 3.7E-03 Composition Misfit: 1.07889 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 31.767 0.000000 0.000000 0.030123 0.074684 0.147148 0.000175 0.235435 0.120254 0.392181 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. 2. 0.4 -4. 1. 1. Chi 0. 0. 2.5E-03 8.0E-04 9.5E-03 8.9E-03 1.8E-02 3.3E-03 1.4E-03 Composition Misfit: 4.498966E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.445 0.000000 0.000000 0.149727 0.000000 0.843611 0.000708 0.005954 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 1.1E+01 0. -10. 1. 0.6 0. 0. Chi 0. 0. 0.3 0. 0.1 0.1 2.7E-03 0. 0. Composition Misfit: 0.446682 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 10.606 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.013055 0.005907 0.012410 0.055854 0.100161 0.000869 0.089599 0.047777 0.005890 0.162065 0.506412 Mica 0.005112 0.000391 0.000000 0.075753 0.011924 0.000000 0.016427 0.162121 0.001078 0.217183 0.510011 Gt 0.000000 0.038679 0.000000 0.000000 0.280809 0.006161 0.116612 0.000000 0.005043 0.130609 0.422087 Fsp 0.038989 0.002628 0.000000 0.084697 0.000000 0.000000 0.000000 0.000000 0.000000 0.126314 0.747372 Bio 0.000000 0.000000 0.026790 0.066420 0.130866 0.000155 0.209384 0.106049 0.004602 0.106947 0.348786 Ilm 0.000000 0.000000 0.127412 0.000000 0.717884 0.000602 0.005066 0.000000 0.149035 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -759465. -751252. -931155. -815058. -316278. -484639. -635132. -297407. -385485. -1632105. -879366. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 17 converged, 13 successes so far. Misfit function evaluations this try => 969 Misfit this try = 1.66835 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 4.880214E-07 Bayes score, PP * exp(-Misfit) = 9.201990E-08 Best Bayes score so far = 1.083408E-06 obtained on Try 8 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 12215.5 864.669 0.870461 0.566841 0.330725 0.240340 0.119194 1.261474E-03 3.050788E-03 0.305428 Final coordinates: 7020.40 864.735 0.916970 0.717794 0.558464 6.440202E-02 2.416012E-02 4.544553E-03 9.099283E-02 0.257436 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.66835 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.287 0.006626 0.000655 0.000000 0.091900 0.007989 0.000000 0.004693 0.285426 0.602710 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.6 0. 0. -0.6 0.5 0. 1. -0.3 -0.3 Chi 2.1E-03 0. 0. 6.0E-04 1.3E-03 0. 1.7E-02 8.6E-05 1.2E-05 Composition Misfit: 2.141056E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.459 0.000000 0.041098 0.000000 0.000000 0.305963 0.055141 0.033924 0.137363 0.426511 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 0.9 -2. 2. 0.5 -0.2 Chi 0. 1.0E-02 0. 0. 8.3E-04 7.9E-03 1.3E-02 3.0E-04 8.1E-06 Composition Misfit: 3.217834E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 44.382 0.022037 0.002017 0.000000 0.101954 0.000000 0.000000 0.000000 0.126008 0.747983 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -2.9E+01 0. 0. 0. 2. -2. Chi 0.2 1. 0. 0.1 0. 0. 0. 9.7E-03 3.8E-03 Composition Misfit: 1.55132 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 10.811 0.000000 0.000000 0.032170 0.076484 0.251827 0.001117 0.111652 0.147254 0.379497 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -4. 0.1 4. -0.5 2. Chi 0. 0. 3.6E-03 1.2E-03 1.8E-02 8.5E-05 3.0E-02 3.3E-04 3.5E-03 Composition Misfit: 5.673193E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.444 0.000000 0.000000 0.382174 0.000000 0.599859 0.011710 0.006256 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 1. -0.3 0.6 0. 0. Chi 0. 0. 2.7E-03 0. 1.5E-03 2.5E-04 2.2E-03 0. 0. Composition Misfit: 6.712770E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.618 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.009489 0.002286 0.028421 0.061612 0.078292 0.002778 0.014468 0.043417 0.004487 0.215871 0.538878 Mica 0.005530 0.000546 0.000000 0.076691 0.006667 0.000000 0.003916 0.164988 0.000509 0.238189 0.502964 Gt 0.000000 0.040999 0.000000 0.000000 0.305229 0.055009 0.033842 0.000000 0.002398 0.137034 0.425488 Fsp 0.022037 0.002017 0.000000 0.101954 0.000000 0.000000 0.000000 0.000000 0.000000 0.126008 0.747983 Bio 0.000000 0.000000 0.028593 0.067979 0.223823 0.000992 0.099236 0.107364 0.003837 0.130879 0.337297 Ilm 0.000000 0.000000 0.360912 0.000000 0.566486 0.011058 0.005908 0.000000 0.055635 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -767510. -748931. -927635. -828110. -307913. -459265. -638496. -295161. -412988. -1629499. -883349. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 20 converged, 14 successes so far. Misfit function evaluations this try => 566 Misfit this try = 0.946912 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.818266E-07 Bayes score, PP * exp(-Misfit) = 7.053729E-08 Best Bayes score so far = 1.083408E-06 obtained on Try 8 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 14388.6 979.961 0.761413 0.172406 8.459949E-03 0.200200 9.023326E-03 2.268775E-02 6.798635E-02 0.691643 Final coordinates: 9353.89 997.797 0.910851 0.169438 6.586101E-03 0.240889 5.776724E-02 1.190729E-02 0.115684 0.567167 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.946912 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.010 0.005639 0.001096 0.000000 0.092077 0.012464 0.000000 0.006765 0.277976 0.603983 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.7 0. 0. -0.6 -0.2 0. 1. 0.1 -0.5 Chi 4.0E-03 0. 0. 6.3E-04 1.4E-04 0. 6.8E-03 2.3E-05 2.6E-05 Composition Misfit: 1.266032E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.124 0.000000 0.029101 0.000000 0.000000 0.317253 0.037593 0.053522 0.136386 0.426145 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 0.3 -0.4 0.1 0.5 -0.2 Chi 0. 2.5E-03 0. 0. 6.9E-05 3.0E-04 3.0E-05 4.1E-04 5.2E-06 Composition Misfit: 3.322748E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 48.359 0.026058 0.003746 0.000000 0.097069 0.000000 0.000000 0.000000 0.126873 0.746254 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 5. 5. 0. -2.8E+01 0. 0. 0. 2. -2. Chi 0.2 0.6 0. 0.1 0. 0. 0. 9.1E-03 3.6E-03 Composition Misfit: 0.883408 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 9.429 0.000000 0.000000 0.037362 0.076750 0.237848 0.001340 0.117788 0.151257 0.377654 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -4. 2.4E-02 4. -0.8 2. Chi 0. 0. 6.8E-03 1.3E-03 1.2E-02 5.3E-06 2.3E-02 7.9E-04 3.9E-03 Composition Misfit: 4.747377E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.064 0.000000 0.000000 0.348934 0.000000 0.630335 0.010677 0.010054 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. -1.5E-02 -0.1 -8.5E-03 0. 0. Chi 0. 0. 3.3E-06 0. 1.8E-07 4.3E-05 2.9E-07 0. 0. Composition Misfit: 4.659535E-05 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.013 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.010335 0.007293 0.037472 0.045374 0.146253 0.008667 0.022207 0.010410 0.008326 0.189951 0.513712 Mica 0.004709 0.000915 0.000000 0.076894 0.010408 0.000000 0.005649 0.164120 0.000779 0.232138 0.504387 Gt 0.000000 0.029019 0.000000 0.000000 0.316357 0.037487 0.053371 0.000000 0.002823 0.136001 0.424942 Fsp 0.026058 0.003746 0.000000 0.097069 0.000000 0.000000 0.000000 0.000000 0.000000 0.126873 0.746254 Bio 0.000000 0.000000 0.033350 0.068508 0.212305 0.001197 0.105139 0.103667 0.003723 0.135014 0.337098 Ilm 0.000000 0.000000 0.324429 0.000000 0.586068 0.009927 0.009348 0.000000 0.070228 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -790832. -761952. -939911. -847003. -321594. -477201. -647345. -303870. -414644. -1645894. -892542. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 21 converged, 15 successes so far. Misfit function evaluations this try => 347 Misfit this try = 2.471458E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 8.911501E-07 Bayes score, PP * exp(-Misfit) = 8.693956E-07 Best Bayes score so far = 1.083408E-06 obtained on Try 8 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 7655.97 822.268 0.878870 0.670122 0.213430 2.462811E-03 0.153065 6.716375E-02 0.530341 3.353707E-02 Final coordinates: 9416.83 940.595 0.945248 0.449755 1.019525E-03 4.404311E-04 0.694795 0.208297 5.179227E-02 4.365587E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.471458E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.557 0.011809 0.001524 0.000000 0.085823 0.009394 0.000000 0.008173 0.279882 0.603396 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.3 0. 0.8 3.5E-02 -0.4 Chi 1.8E-04 0. 0. 2.2E-05 3.3E-04 0. 3.5E-03 1.3E-06 1.9E-05 Composition Misfit: 5.607261E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.326 0.000000 0.032375 0.000000 0.000000 0.299439 0.036981 0.068580 0.136454 0.426170 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -0.3 -1. 0.5 -0.2 Chi 0. 4.3E-03 0. 0. 1.7E-03 2.0E-04 2.8E-03 4.0E-04 5.4E-06 Composition Misfit: 9.386332E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 69.959 0.095611 0.053325 0.000000 0.002727 0.000000 0.000000 0.000000 0.151663 0.696675 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.2 0. -0.4 0. 0. 0. 0.6 -0.1 Chi 1.6E-04 5.6E-05 0. 6.9E-04 0. 0. 0. 5.6E-04 6.8E-06 Composition Misfit: 1.476371E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.575 0.000000 0.000000 0.029220 0.075830 0.200512 0.001006 0.171392 0.137453 0.384586 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.1 -0.1 0.2 2. Chi 0. 0. 2.1E-03 1.0E-03 1.3E-03 1.7E-04 2.1E-05 6.0E-05 2.6E-03 Composition Misfit: 7.245500E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.045 0.000000 0.000000 0.357211 0.000000 0.620150 0.009658 0.012982 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.4 0. 0.5 0.1 -0.5 0. 0. Chi 0. 0. 1.5E-04 0. 1.6E-04 1.2E-05 6.8E-04 0. 0. Composition Misfit: 9.991168E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.550 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.987 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.062139 0.034738 0.021873 0.018080 0.069457 0.000804 0.035319 0.027106 0.004103 0.148816 0.577564 Mica 0.009861 0.001273 0.000000 0.071666 0.007844 0.000000 0.006825 0.164327 0.000628 0.233714 0.503863 Gt 0.000000 0.032285 0.000000 0.000000 0.298602 0.036878 0.068389 0.000000 0.002793 0.136073 0.424980 Fsp 0.095611 0.053325 0.000000 0.002727 0.000000 0.000000 0.000000 0.000000 0.000000 0.151663 0.696675 Bio 0.000000 0.000000 0.025931 0.067295 0.177944 0.000893 0.152102 0.108659 0.003892 0.121982 0.341300 Ilm 0.000000 0.000000 0.333407 0.000000 0.578825 0.009014 0.012117 0.000000 0.066637 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775374. -754714. -931670. -842300. -315055. -469696. -639365. -294490. -408945. -1636255. -885980. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 22 converged, 16 successes so far. Misfit function evaluations this try => 634 Misfit this try = 0.890167 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.478048E-07 Bayes score, PP * exp(-Misfit) = 6.068680E-08 Best Bayes score so far = 1.083408E-06 obtained on Try 8 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 14121.5 893.573 0.275834 0.907581 0.116855 5.004524E-02 9.809577E-02 7.002805E-02 1.614109E-02 0.648835 Final coordinates: 8573.21 999.764 0.957256 0.641762 0.151094 5.559478E-02 1.943631E-02 0.193661 0.109922 0.470292 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.890167 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.294 0.004816 0.001528 0.000000 0.092809 0.011181 0.000000 0.006777 0.279827 0.603062 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.9 0. 0. -0.7 -3.9E-03 0. 1. 3.8E-02 -0.4 Chi 6.4E-03 0. 0. 7.5E-04 5.8E-08 0. 6.8E-03 1.5E-06 1.6E-05 Composition Misfit: 1.543492E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.683 0.000000 0.036068 0.000000 0.000000 0.280284 0.066580 0.055001 0.136049 0.426018 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -4. -2.0E-02 0.6 -0.2 Chi 0. 6.7E-03 0. 0. 6.2E-03 1.6E-02 7.7E-07 4.5E-04 4.3E-06 Composition Misfit: 2.901566E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 40.797 0.021695 0.004677 0.000000 0.100967 0.000000 0.000000 0.000000 0.127339 0.745323 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -2.9E+01 0. 0. 0. 2. -2. Chi 0.2 0.5 0. 0.1 0. 0. 0. 8.8E-03 3.5E-03 Composition Misfit: 0.806817 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 31.582 0.000000 0.000000 0.037922 0.076961 0.221970 0.002472 0.130382 0.154408 0.375886 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -2. -0.3 3. -1. 2. Chi 0. 0. 7.2E-03 1.3E-03 6.3E-03 4.4E-04 1.2E-02 1.3E-03 4.3E-03 Composition Misfit: 3.261004E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.482 0.000000 0.000000 0.351688 0.000000 0.615704 0.020929 0.011679 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.1 0. 0.7 -2. -0.3 0. 0. Chi 0. 0. 8.1E-06 0. 3.3E-04 5.7E-03 2.4E-04 0. 0. Composition Misfit: 6.288803E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.161 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.007555 0.001972 0.039172 0.060192 0.119330 0.003014 0.041728 0.039426 0.007139 0.195427 0.485045 Mica 0.004021 0.001276 0.000000 0.077489 0.009335 0.000000 0.005658 0.164297 0.000773 0.233636 0.503515 Gt 0.000000 0.035961 0.000000 0.000000 0.279452 0.066382 0.054837 0.000000 0.002970 0.135645 0.424753 Fsp 0.021695 0.004677 0.000000 0.100967 0.000000 0.000000 0.000000 0.000000 0.000000 0.127339 0.745323 Bio 0.000000 0.000000 0.033852 0.068702 0.198149 0.002206 0.116390 0.103551 0.003762 0.137838 0.335549 Ilm 0.000000 0.000000 0.327409 0.000000 0.573198 0.019484 0.010873 0.000000 0.069037 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -797435. -761654. -941196. -851570. -323558. -473561. -647837. -305014. -413063. -1647917. -894566. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 23 converged, 17 successes so far. Misfit function evaluations this try => 292 Misfit this try = 2.492737E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.072984E-06 Bayes score, PP * exp(-Misfit) = 1.046568E-06 Best Bayes score so far = 1.083408E-06 obtained on Try 8 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 6490.14 819.801 0.191001 0.754415 1.289257E-02 0.495680 0.174914 7.872510E-03 2.456758E-02 0.284073 Final coordinates: 9180.11 924.222 0.159110 0.853112 1.708023E-02 0.468918 0.242472 2.480261E-02 8.267545E-04 0.245901 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.492737E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 35.594 0.013045 0.001140 0.000000 0.084888 0.009069 0.000000 0.007317 0.281116 0.603425 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.4 0. 0. -3.6E-02 0.3 0. 0.9 -3.7E-02 -0.4 Chi 5.5E-04 0. 0. 2.1E-06 4.8E-04 0. 5.3E-03 1.4E-06 1.9E-05 Composition Misfit: 7.499357E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 37.885 0.000000 0.025340 0.000000 0.000000 0.314683 0.032670 0.063634 0.137217 0.426456 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 0.4 0.2 -0.8 0.5 -0.2 Chi 0. 9.1E-04 0. 0. 1.7E-04 7.6E-05 1.2E-03 3.2E-04 7.6E-06 Composition Misfit: 2.703315E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 24.816 0.100343 0.044022 0.000000 0.002646 0.000000 0.000000 0.000000 0.147011 0.705978 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.7 0.7 0. -0.4 0. 0. 0. 1. -0.5 Chi 7.5E-04 1.3E-03 0. 6.3E-04 0. 0. 0. 1.3E-03 1.9E-04 Composition Misfit: 4.181356E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.053 0.000000 0.000000 0.028300 0.075793 0.212151 0.000829 0.161192 0.136888 0.384847 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.9 -1. -2. 0.2 0.6 0.2 2. Chi 0. 0. 1.7E-03 1.0E-03 3.6E-03 4.3E-04 4.3E-04 8.6E-05 2.5E-03 Composition Misfit: 9.798270E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.167 0.000000 0.000000 0.353770 0.000000 0.627536 0.007798 0.010895 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.2 0. 0.1 0.4 -0.1 0. 0. Chi 0. 0. 4.0E-05 0. 9.7E-06 6.2E-04 7.4E-05 0. 0. Composition Misfit: 7.450718E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.375 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 0.109 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023614 0.020963 0.000776 0.022909 0.150493 0.015242 0.031682 0.051907 0.001497 0.173890 0.507027 Mica 0.010892 0.000952 0.000000 0.070875 0.007572 0.000000 0.006109 0.164485 0.000593 0.234710 0.503812 Gt 0.000000 0.025277 0.000000 0.000000 0.313908 0.032590 0.063477 0.000000 0.002461 0.136879 0.425407 Fsp 0.100343 0.044022 0.000000 0.002646 0.000000 0.000000 0.000000 0.000000 0.000000 0.147011 0.705978 Bio 0.000000 0.000000 0.025095 0.067210 0.188129 0.000735 0.142940 0.109325 0.003907 0.121388 0.341270 Ilm 0.000000 0.000000 0.329667 0.000000 0.584780 0.007267 0.010153 0.000000 0.068133 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -771587. -754968. -930485. -839841. -312875. -468668. -638590. -293326. -410051. -1634124. -884732. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 25 converged, 18 successes so far. Misfit function evaluations this try => 265 Misfit this try = 2.387681E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 9.922161E-07 Bayes score, PP * exp(-Misfit) = 9.688058E-07 Best Bayes score so far = 1.083408E-06 obtained on Try 8 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 6411.00 963.972 0.223991 0.143617 0.169908 2.737167E-02 0.372094 4.901198E-02 5.856962E-03 0.375757 Final coordinates: 9170.91 931.176 0.490419 0.300202 6.739362E-02 2.701985E-02 0.853636 1.453060E-02 3.733103E-03 3.368660E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.387681E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 9.280 0.011919 0.001454 0.000000 0.085811 0.009257 0.000000 0.007650 0.280667 0.603242 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.3 0. 0.9 -1.1E-02 -0.4 Chi 2.0E-04 0. 0. 2.1E-05 3.9E-04 0. 4.5E-03 1.3E-07 1.7E-05 Composition Misfit: 6.629675E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.828 0.000000 0.032129 0.000000 0.000000 0.306523 0.034282 0.064314 0.136547 0.426205 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 0.9 -3.9E-03 -0.9 0.5 -0.2 Chi 0. 4.2E-03 0. 0. 7.7E-04 3.7E-08 1.4E-03 3.9E-04 5.6E-06 Composition Misfit: 6.751537E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 82.576 0.095731 0.053312 0.000000 0.002613 0.000000 0.000000 0.000000 0.151656 0.696688 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.2 0. -0.4 0. 0. 0. 0.6 -0.1 Chi 1.7E-04 5.5E-05 0. 6.0E-04 0. 0. 0. 5.6E-04 6.9E-06 Composition Misfit: 1.402098E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.617 0.000000 0.000000 0.028735 0.075851 0.207746 0.000899 0.164679 0.137765 0.384326 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.9 -1. -2. 0.2 0.3 0.2 2. Chi 0. 0. 1.9E-03 1.0E-03 2.6E-03 3.1E-04 1.4E-04 4.7E-05 2.6E-03 Composition Misfit: 8.639941E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.202 0.000000 0.000000 0.349236 0.000000 0.630807 0.008499 0.011458 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 4.2E-02 0. -3.7E-02 0.2 -0.2 0. 0. Chi 0. 0. 1.7E-06 0. 1.0E-06 2.7E-04 1.9E-04 0. 0. Composition Misfit: 4.535630E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.186 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.312 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.077794 0.043762 0.001587 0.010469 0.014579 0.000965 0.005250 0.018327 0.000447 0.168401 0.658420 Mica 0.009952 0.001214 0.000000 0.071649 0.007729 0.000000 0.006388 0.164417 0.000616 0.234348 0.503687 Gt 0.000000 0.032041 0.000000 0.000000 0.305679 0.034188 0.064137 0.000000 0.002753 0.136171 0.425032 Fsp 0.095731 0.053312 0.000000 0.002613 0.000000 0.000000 0.000000 0.000000 0.000000 0.151656 0.696688 Bio 0.000000 0.000000 0.025488 0.067280 0.184270 0.000797 0.146070 0.109072 0.003932 0.122197 0.340896 Ilm 0.000000 0.000000 0.324756 0.000000 0.586589 0.007903 0.010655 0.000000 0.070098 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774209. -754139. -931235. -841342. -313947. -469262. -639092. -293983. -409438. -1635263. -885511. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 26 converged, 19 successes so far. Misfit function evaluations this try => 339 Misfit this try = 2.815159E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.867815E-07 Bayes score, PP * exp(-Misfit) = 1.815966E-07 Best Bayes score so far = 1.083408E-06 obtained on Try 8 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 14439.8 973.348 0.114592 0.142090 2.227208E-02 0.330780 0.182032 0.424552 2.008550E-03 3.835545E-02 Final coordinates: 10131.2 997.929 0.229323 0.432206 3.623896E-02 0.400086 0.408257 0.105083 5.045718E-03 4.528831E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.815159E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.132 0.010431 0.001484 0.000000 0.086994 0.011386 0.000000 0.008742 0.276905 0.604058 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -1.1E-02 0. 0. -0.2 -3.6E-02 0. 0.7 0.2 -0.5 Chi 5.0E-07 0. 0. 7.4E-05 4.7E-06 0. 2.6E-03 4.6E-05 2.7E-05 Composition Misfit: 4.275490E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 34.858 0.000000 0.023988 0.000000 0.000000 0.306870 0.030516 0.076045 0.136422 0.426158 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.4 0. 0. 0.8 0.4 -2. 0.5 -0.2 Chi 0. 4.9E-04 0. 0. 7.4E-04 4.6E-04 5.9E-03 4.0E-04 5.3E-06 Composition Misfit: 8.034190E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 44.838 0.096792 0.047752 0.000000 0.004332 0.000000 0.000000 0.000000 0.148876 0.702248 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.4 0.4 0. -0.9 0. 0. 0. 0.8 -0.3 Chi 2.7E-04 3.1E-04 0. 2.0E-03 0. 0. 0. 9.7E-04 8.5E-05 Composition Misfit: 3.680673E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.560 0.000000 0.000000 0.032366 0.076156 0.205340 0.001047 0.160619 0.142340 0.382132 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.1 0.6 -0.1 2. Chi 0. 0. 3.7E-03 1.1E-03 2.1E-03 1.4E-04 4.9E-04 2.9E-05 3.0E-03 Composition Misfit: 1.062188E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.626 0.000000 0.000000 0.344661 0.000000 0.632137 0.008875 0.014327 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.3 0. -0.1 0.2 -0.7 0. 0. Chi 0. 0. 8.3E-05 0. 7.2E-06 1.4E-04 1.3E-03 0. 0. Composition Misfit: 1.539365E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.987 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.037023 0.028337 0.003882 0.014007 0.147339 0.013452 0.039567 0.026313 0.002112 0.155638 0.532330 Mica 0.008712 0.001239 0.000000 0.072663 0.009510 0.000000 0.007302 0.163989 0.000749 0.231288 0.504547 Gt 0.000000 0.023921 0.000000 0.000000 0.306008 0.030430 0.075832 0.000000 0.002807 0.136039 0.424962 Fsp 0.096792 0.047752 0.000000 0.004332 0.000000 0.000000 0.000000 0.000000 0.000000 0.148876 0.702248 Bio 0.000000 0.000000 0.028789 0.067739 0.182645 0.000931 0.142867 0.106689 0.003834 0.126608 0.339898 Ilm 0.000000 0.000000 0.319821 0.000000 0.586578 0.008235 0.013294 0.000000 0.072072 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -785499. -761989. -937907. -850635. -321237. -478212. -644016. -299502. -411127. -1644232. -890771. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 27 converged, 20 successes so far. Misfit function evaluations this try => 1035 Misfit this try = 0.994074 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 2.439837E-07 Bayes score, PP * exp(-Misfit) = 9.029008E-08 Best Bayes score so far = 1.083408E-06 obtained on Try 8 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 9449.09 846.503 0.369766 0.602659 0.303326 0.316586 0.103711 9.185045E-03 3.403344E-02 0.233159 Final coordinates: 8678.59 986.963 0.208235 0.352672 0.358127 6.462855E-02 4.206472E-02 7.765720E-02 1.855769E-02 0.438965 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.994074 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.019 0.004961 0.001372 0.000000 0.092794 0.010229 0.000000 0.006665 0.280420 0.603559 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.9 0. 0. -0.7 0.1 0. 1. 3.4E-03 -0.5 Chi 5.9E-03 0. 0. 7.5E-04 8.4E-05 0. 7.1E-03 1.2E-08 2.1E-05 Composition Misfit: 1.519937E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.058 0.000000 0.035495 0.000000 0.000000 0.285176 0.062374 0.052133 0.138053 0.426770 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -3. 0.3 0.4 -0.2 Chi 0. 6.3E-03 0. 0. 4.7E-03 1.3E-02 1.4E-04 2.4E-04 1.0E-05 Composition Misfit: 2.410009E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 56.180 0.021657 0.004165 0.000000 0.101261 0.000000 0.000000 0.000000 0.127083 0.745835 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -2.9E+01 0. 0. 0. 2. -2. Chi 0.2 0.5 0. 0.1 0. 0. 0. 9.0E-03 3.5E-03 Composition Misfit: 0.877390 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.964 0.000000 0.000000 0.039308 0.076968 0.223637 0.002198 0.125433 0.154525 0.377930 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -3. -0.2 3. -1. 2. Chi 0. 0. 8.2E-03 1.3E-03 6.9E-03 2.7E-04 1.5E-02 1.3E-03 3.8E-03 Composition Misfit: 3.724773E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.002 0.000000 0.000000 0.433697 0.000000 0.532408 0.020012 0.013883 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -5. 0. 4. -2. -0.6 0. 0. Chi 0. 0. 1.6E-02 0. 1.8E-02 5.0E-03 1.1E-03 0. 0. Composition Misfit: 4.013655E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 23.776 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.010915 0.003153 0.007349 0.065409 0.050209 0.002262 0.024952 0.021421 0.000653 0.225771 0.587907 Mica 0.004143 0.001146 0.000000 0.077487 0.008541 0.000000 0.005566 0.164406 0.000545 0.234165 0.504001 Gt 0.000000 0.035420 0.000000 0.000000 0.284578 0.062243 0.052024 0.000000 0.002097 0.137764 0.425875 Fsp 0.021657 0.004165 0.000000 0.101261 0.000000 0.000000 0.000000 0.000000 0.000000 0.127083 0.745835 Bio 0.000000 0.000000 0.035166 0.068858 0.200071 0.001966 0.112215 0.102549 0.002828 0.138242 0.338105 Ilm 0.000000 0.000000 0.419781 0.000000 0.515324 0.019370 0.013438 0.000000 0.032088 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -793309. -759933. -938119. -847827. -321613. -472327. -646769. -303711. -423816. -1645526. -892860. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 28 converged, 21 successes so far. Misfit function evaluations this try => 249 Misfit this try = 2.577110E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 2.973335E-07 Bayes score, PP * exp(-Misfit) = 2.897688E-07 Best Bayes score so far = 1.083408E-06 obtained on Try 8 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 9461.51 938.362 0.630594 0.703393 3.782123E-02 0.130787 0.462715 0.249511 4.736392E-03 0.114429 Final coordinates: 9729.85 985.107 0.403695 0.690146 4.868009E-02 0.101678 0.569837 0.157881 1.364844E-02 0.108275 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.577110E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 14.237 0.011436 0.001716 0.000000 0.085989 0.010624 0.000000 0.008259 0.278532 0.603445 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.1 0. 0.8 0.1 -0.4 Chi 1.0E-04 0. 0. 2.7E-05 2.7E-05 0. 3.4E-03 1.4E-05 2.0E-05 Composition Misfit: 5.288463E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.413 0.000000 0.025920 0.000000 0.000000 0.304283 0.033437 0.073756 0.136440 0.426165 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.7 0. 0. 1. 0.1 -2. 0.5 -0.2 Chi 0. 1.1E-03 0. 0. 1.0E-03 2.0E-05 4.9E-03 4.0E-04 5.3E-06 Composition Misfit: 7.435637E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 57.718 0.095480 0.051899 0.000000 0.003571 0.000000 0.000000 0.000000 0.150950 0.698101 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -3.0E-02 0. -0.6 0. 0. 0. 0.7 -0.2 Chi 1.5E-04 1.8E-06 0. 1.4E-03 0. 0. 0. 6.6E-04 1.9E-05 Composition Misfit: 2.200881E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.061 0.000000 0.000000 0.031058 0.076141 0.205310 0.001097 0.162117 0.142115 0.382163 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.1 0.5 -0.1 2. Chi 0. 0. 3.0E-03 1.1E-03 2.1E-03 9.8E-05 3.4E-04 2.3E-05 3.0E-03 Composition Misfit: 9.693520E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.623 0.000000 0.000000 0.345336 0.000000 0.631303 0.009526 0.013836 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.3 0. -0.1 0.1 -0.6 0. 0. Chi 0. 0. 6.3E-05 0. 2.7E-06 2.4E-05 1.1E-03 0. 0. Composition Misfit: 1.152596E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.354 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.594 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.051520 0.030127 0.007798 0.023536 0.069080 0.003677 0.033100 0.041549 0.001743 0.165018 0.572853 Mica 0.009550 0.001433 0.000000 0.071812 0.008872 0.000000 0.006897 0.164157 0.000714 0.232610 0.503954 Gt 0.000000 0.025847 0.000000 0.000000 0.303431 0.033343 0.073549 0.000000 0.002800 0.136058 0.424972 Fsp 0.095480 0.051899 0.000000 0.003571 0.000000 0.000000 0.000000 0.000000 0.000000 0.150950 0.698101 Bio 0.000000 0.000000 0.027593 0.067646 0.182404 0.000975 0.144030 0.107699 0.003869 0.126259 0.339526 Ilm 0.000000 0.000000 0.320547 0.000000 0.585987 0.008842 0.012842 0.000000 0.071781 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -784518. -760557. -937057. -851114. -320074. -476117. -643227. -298183. -411082. -1642936. -890232. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 30 converged, 22 successes so far. Misfit function evaluations this try => 451 Misfit this try = 2.770191E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 2.066532E-07 Bayes score, PP * exp(-Misfit) = 2.010070E-07 Best Bayes score so far = 1.083408E-06 obtained on Try 8 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 5922.21 871.059 0.936424 0.365649 6.996102E-02 0.162801 0.683043 7.655444E-03 1.717417E-02 5.936631E-02 Final coordinates: 9939.89 995.341 0.999667 8.259109E-02 2.997805E-02 4.343634E-02 0.877987 1.007503E-02 1.968741E-02 1.883591E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.770191E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.501 0.010094 0.001633 0.000000 0.087286 0.011274 0.000000 0.008554 0.277370 0.603789 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 4.2E-02 0. 0. -0.2 -1.8E-02 0. 0.7 0.2 -0.5 Chi 6.9E-06 0. 0. 9.1E-05 1.3E-06 0. 2.9E-03 3.5E-05 2.4E-05 Composition Misfit: 4.704261E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.185 0.000000 0.026679 0.000000 0.000000 0.305111 0.031993 0.073908 0.136225 0.426084 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.8 0. 0. 0.9 0.2 -2. 0.5 -0.2 Chi 0. 1.4E-03 0. 0. 9.3E-04 1.6E-04 4.9E-03 4.3E-04 4.8E-06 Composition Misfit: 7.866394E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 87.857 0.094535 0.052568 0.000000 0.004181 0.000000 0.000000 0.000000 0.151284 0.697432 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.1 0. -0.8 0. 0. 0. 0.7 -0.1 Chi 8.8E-05 1.8E-05 0. 1.9E-03 0. 0. 0. 6.1E-04 1.2E-05 Composition Misfit: 2.635263E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.587 0.000000 0.000000 0.032279 0.076201 0.206463 0.001092 0.159241 0.143008 0.381717 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.1 0.7 -0.2 2. Chi 0. 0. 3.7E-03 1.1E-03 2.3E-03 1.0E-04 6.6E-04 5.1E-05 3.1E-03 Composition Misfit: 1.103916E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.309 0.000000 0.000000 0.340615 0.000000 0.636270 0.009253 0.013862 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.5 0. -0.3 0.1 -0.6 0. 0. Chi 0. 0. 2.6E-04 0. 6.2E-05 6.0E-05 1.1E-03 0. 0. Composition Misfit: 1.456830E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.611 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 0.949 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.080417 0.045875 0.007057 0.005948 0.028591 0.001687 0.004912 0.005084 0.001786 0.161500 0.657141 Mica 0.008431 0.001364 0.000000 0.072903 0.009417 0.000000 0.007145 0.164031 0.000749 0.231665 0.504297 Gt 0.000000 0.026602 0.000000 0.000000 0.304228 0.031900 0.073694 0.000000 0.002893 0.135831 0.424852 Fsp 0.094535 0.052568 0.000000 0.004181 0.000000 0.000000 0.000000 0.000000 0.000000 0.151284 0.697432 Bio 0.000000 0.000000 0.028706 0.067766 0.183610 0.000971 0.141615 0.106827 0.003859 0.127179 0.339467 Ilm 0.000000 0.000000 0.315475 0.000000 0.589306 0.008570 0.012839 0.000000 0.073810 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -786232. -761222. -937990. -850983. -321141. -477670. -644078. -299500. -411082. -1644208. -890915. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 31 converged, 23 successes so far. Misfit function evaluations this try => 293 Misfit this try = 2.425065E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 6.834720E-07 Bayes score, PP * exp(-Misfit) = 6.670967E-07 Best Bayes score so far = 1.083408E-06 obtained on Try 8 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 14420.1 892.150 0.369566 0.149644 0.524799 3.522266E-03 0.387004 1.697447E-02 1.981936E-02 4.788054E-02 Final coordinates: 9483.04 954.807 0.622736 0.352609 4.570751E-02 1.218043E-02 0.833944 3.856652E-02 5.497538E-03 6.410446E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.425065E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 9.399 0.011500 0.001576 0.000000 0.086070 0.009816 0.000000 0.008186 0.279444 0.603408 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.2 0. 0.8 0.1 -0.4 Chi 1.1E-04 0. 0. 3.0E-05 1.8E-04 0. 3.5E-03 3.8E-06 1.9E-05 Composition Misfit: 5.434645E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.793 0.000000 0.030188 0.000000 0.000000 0.300418 0.036858 0.069956 0.136422 0.426158 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.3 -1. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 1.5E-03 1.9E-04 3.3E-03 4.0E-04 5.3E-06 Composition Misfit: 8.496020E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 80.917 0.095355 0.053266 0.000000 0.003012 0.000000 0.000000 0.000000 0.151633 0.696734 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.2 0. -0.5 0. 0. 0. 0.6 -0.1 Chi 1.4E-04 5.2E-05 0. 9.1E-04 0. 0. 0. 5.7E-04 7.2E-06 Composition Misfit: 1.678017E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.899 0.000000 0.000000 0.029871 0.075948 0.202406 0.001069 0.167873 0.139222 0.383611 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.1 0.1 0.1 2. Chi 0. 0. 2.4E-03 1.1E-03 1.6E-03 1.2E-04 1.6E-05 8.6E-06 2.7E-03 Composition Misfit: 7.945431E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.269 0.000000 0.000000 0.347573 0.000000 0.629620 0.009844 0.012962 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. 1.7E-02 2.5E-02 -0.5 0. 0. Chi 0. 0. 1.7E-05 0. 2.3E-07 2.5E-06 6.8E-04 0. 0. Composition Misfit: 6.965384E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.371 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.353 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.075856 0.042323 0.002688 0.012703 0.015377 0.000515 0.008554 0.021474 0.000598 0.168342 0.651570 Mica 0.009604 0.001316 0.000000 0.071874 0.008197 0.000000 0.006836 0.164271 0.000661 0.233355 0.503886 Gt 0.000000 0.030103 0.000000 0.000000 0.299575 0.036755 0.069760 0.000000 0.002808 0.136039 0.424962 Fsp 0.095355 0.053266 0.000000 0.003012 0.000000 0.000000 0.000000 0.000000 0.000000 0.151633 0.696734 Bio 0.000000 0.000000 0.026518 0.067424 0.179689 0.000949 0.149031 0.108330 0.003908 0.123596 0.340556 Ilm 0.000000 0.000000 0.322960 0.000000 0.585033 0.009147 0.012044 0.000000 0.070816 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778474. -756603. -933485. -845106. -316692. -471532. -640651. -295769. -409408. -1638434. -887398. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 32 converged, 24 successes so far. Misfit function evaluations this try => 604 Misfit this try = 2.845202E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.721873E-07 Bayes score, PP * exp(-Misfit) = 1.673573E-07 Best Bayes score so far = 1.083408E-06 obtained on Try 8 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 14450.3 986.964 0.903988 0.461240 7.037542E-02 0.548870 0.156324 0.193872 1.272935E-02 1.782969E-02 Final coordinates: 10096.1 1000.000 0.220741 0.111199 7.023776E-03 0.208034 0.704624 6.906164E-02 2.728524E-03 8.527840E-03 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.845202E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.642 0.009878 0.001559 0.000000 0.087499 0.011511 0.000000 0.008725 0.276826 0.604001 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.1 0. 0. -0.3 -0.1 0. 0.7 0.2 -0.5 Chi 2.3E-05 0. 0. 1.1E-04 1.1E-05 0. 2.7E-03 4.8E-05 2.7E-05 Composition Misfit: 4.437622E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.924 0.000000 0.025821 0.000000 0.000000 0.306253 0.030600 0.074961 0.136265 0.426099 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.7 0. 0. 0.9 0.4 -2. 0.5 -0.2 Chi 0. 1.1E-03 0. 0. 8.0E-04 4.3E-04 5.4E-03 4.2E-04 4.9E-06 Composition Misfit: 8.163427E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 74.417 0.095122 0.050871 0.000000 0.004442 0.000000 0.000000 0.000000 0.150436 0.699129 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 0.1 0. -0.9 0. 0. 0. 0.7 -0.2 Chi 1.3E-04 1.0E-05 0. 2.1E-03 0. 0. 0. 7.3E-04 3.1E-05 Composition Misfit: 3.036897E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.502 0.000000 0.000000 0.032731 0.076201 0.206336 0.001057 0.158865 0.143015 0.381795 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.1 0.7 -0.2 2. Chi 0. 0. 3.9E-03 1.1E-03 2.3E-03 1.3E-04 7.1E-04 5.1E-05 3.1E-03 Composition Misfit: 1.133333E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.255 0.000000 0.000000 0.345730 0.000000 0.630979 0.008964 0.014327 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.2 0. -4.5E-02 0.2 -0.7 0. 0. Chi 0. 0. 5.3E-05 0. 1.5E-06 1.2E-04 1.3E-03 0. 0. Composition Misfit: 1.480736E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.777 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 0.484 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.064225 0.040307 0.002411 0.006839 0.080953 0.007192 0.023158 0.006841 0.001117 0.156094 0.610863 Mica 0.008251 0.001302 0.000000 0.073085 0.009614 0.000000 0.007288 0.163976 0.000756 0.231224 0.504504 Gt 0.000000 0.025746 0.000000 0.000000 0.305373 0.030512 0.074746 0.000000 0.002876 0.135873 0.424874 Fsp 0.095122 0.050871 0.000000 0.004442 0.000000 0.000000 0.000000 0.000000 0.000000 0.150436 0.699129 Bio 0.000000 0.000000 0.029121 0.067796 0.183578 0.000940 0.141343 0.106472 0.003824 0.127241 0.339685 Ilm 0.000000 0.000000 0.320972 0.000000 0.585794 0.008322 0.013301 0.000000 0.071611 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -786521. -761733. -938239. -850882. -321545. -478533. -644342. -299915. -411308. -1644660. -891089. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 33 converged, 25 successes so far. Misfit function evaluations this try => 232 Misfit this try = 2.449051E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.185980E-06 Bayes score, PP * exp(-Misfit) = 1.157288E-06 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 9352.38 946.060 0.683446 7.361984E-02 0.294026 0.135026 0.192384 7.474515E-03 0.354831 1.625838E-02 Final coordinates: 9073.69 903.427 0.929990 0.117529 2.299888E-02 0.291748 0.551523 1.023633E-02 0.109220 1.427384E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.449051E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.758 0.011305 0.001029 0.000000 0.086672 0.008917 0.000000 0.007559 0.280902 0.603616 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.1 0. 0. -0.2 0.3 0. 0.9 -2.5E-02 -0.5 Chi 7.9E-05 0. 0. 5.6E-05 5.6E-04 0. 4.7E-03 6.4E-07 2.2E-05 Composition Misfit: 6.489860E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 23.084 0.000000 0.032589 0.000000 0.000000 0.310665 0.034174 0.059472 0.136800 0.426300 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 0.6 8.0E-03 -0.4 0.5 -0.2 Chi 0. 4.4E-03 0. 0. 4.1E-04 1.5E-07 3.7E-04 3.6E-04 6.3E-06 Composition Misfit: 5.592482E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 59.968 0.098432 0.048047 0.000000 0.002544 0.000000 0.000000 0.000000 0.149023 0.701953 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.6 0.3 0. -0.3 0. 0. 0. 0.8 -0.3 Chi 4.7E-04 2.6E-04 0. 5.5E-04 0. 0. 0. 9.5E-04 7.9E-05 Composition Misfit: 2.307987E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.083 0.000000 0.000000 0.028208 0.075658 0.210638 0.000791 0.164051 0.134877 0.385777 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.9 -1. -2. 0.2 0.4 0.4 2. Chi 0. 0. 1.7E-03 1.0E-03 3.3E-03 5.1E-04 1.8E-04 2.2E-04 2.4E-03 Composition Misfit: 9.180314E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.213 0.000000 0.000000 0.343295 0.000000 0.639087 0.007743 0.009875 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.4 0. -0.4 0.4 2.0E-02 0. 0. Chi 0. 0. 1.3E-04 0. 1.3E-04 6.6E-04 1.6E-06 0. 0. Composition Misfit: 9.198664E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.012 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 0.882 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.050082 0.033875 0.037803 0.004506 0.162273 0.010913 0.018996 0.007285 0.009432 0.140208 0.524629 Mica 0.009439 0.000859 0.000000 0.072366 0.007446 0.000000 0.006312 0.164471 0.000580 0.234539 0.503988 Gt 0.000000 0.032502 0.000000 0.000000 0.309844 0.034084 0.059315 0.000000 0.002643 0.136438 0.425173 Fsp 0.098432 0.048047 0.000000 0.002544 0.000000 0.000000 0.000000 0.000000 0.000000 0.149023 0.701953 Bio 0.000000 0.000000 0.025016 0.067098 0.186804 0.000701 0.145489 0.109179 0.003971 0.119615 0.342126 Ilm 0.000000 0.000000 0.318351 0.000000 0.592652 0.007180 0.009158 0.000000 0.072660 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -767617. -751354. -928012. -833968. -310616. -465724. -636934. -292303. -408276. -1631048. -882734. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 34 converged, 26 successes so far. Misfit function evaluations this try => 604 Misfit this try = 2.03485 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 2.251694E-07 Bayes score, PP * exp(-Misfit) = 2.942951E-08 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 13361.7 812.120 0.439143 0.314085 0.255172 7.483630E-03 4.804736E-03 1.597635E-03 0.225535 0.505406 Final coordinates: 5582.19 870.751 0.844022 0.193233 0.618839 2.379246E-02 1.622471E-02 1.133925E-02 1.480265E-02 0.315002 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.03485 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.047 0.005199 0.000700 0.000000 0.093448 0.006479 0.000000 0.004856 0.287299 0.602020 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.8 0. 0. -0.8 0.7 0. 1. -0.4 -0.3 Chi 5.1E-03 0. 0. 8.6E-04 3.4E-03 0. 1.6E-02 1.6E-04 6.8E-06 Composition Misfit: 2.577787E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.190 0.000000 0.030540 0.000000 0.000000 0.229678 0.133908 0.040709 0.138301 0.426863 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 5. -1.1E+01 1. 0.4 -0.3 Chi 0. 3.3E-03 0. 0. 3.7E-02 0.1 4.9E-03 2.2E-04 1.1E-05 Composition Misfit: 0.119593 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 63.774 0.016785 0.001847 0.000000 0.107291 0.000000 0.000000 0.000000 0.125924 0.748153 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -3.1E+01 0. 0. 0. 2. -2. Chi 0.3 1. 0. 0.1 0. 0. 0. 9.7E-03 3.8E-03 Composition Misfit: 1.79180 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.895 0.000000 0.000000 0.032373 0.076835 0.212447 0.003039 0.146893 0.152519 0.375894 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -2. -0.5 2. -0.9 2. Chi 0. 0. 3.7E-03 1.3E-03 3.7E-03 8.6E-04 3.5E-03 9.8E-04 4.3E-03 Composition Misfit: 1.828380E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.447 0.000000 0.000000 0.240582 0.000000 0.726806 0.027741 0.004871 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -4. -3. 0.8 0. 0. Chi 0. 0. 5.0E-02 0. 1.3E-02 1.1E-02 5.4E-03 0. 0. Composition Misfit: 7.940449E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.647 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.009818 0.001167 0.004771 0.070077 0.025947 0.000861 0.014097 0.011597 0.001369 0.237133 0.623162 Mica 0.004337 0.000584 0.000000 0.077961 0.005406 0.000000 0.004051 0.165181 0.000541 0.239687 0.502252 Gt 0.000000 0.030479 0.000000 0.000000 0.229221 0.133642 0.040628 0.000000 0.001989 0.138026 0.426014 Fsp 0.016785 0.001847 0.000000 0.107291 0.000000 0.000000 0.000000 0.000000 0.000000 0.125924 0.748153 Bio 0.000000 0.000000 0.028750 0.068236 0.188672 0.002699 0.130454 0.107722 0.004187 0.135451 0.333828 Ilm 0.000000 0.000000 0.212959 0.000000 0.643356 0.024556 0.004312 0.000000 0.114816 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -778941. -753364. -930570. -837468. -311897. -455078. -639216. -297333. -407742. -1633525. -887283. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 35 converged, 27 successes so far. Misfit function evaluations this try => 1009 Misfit this try = 7.818515E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 7.362552E-07 Bayes score, PP * exp(-Misfit) = 6.808837E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 11412.5 985.417 6.828439E-02 0.810976 6.006011E-02 0.648998 6.021105E-02 3.001817E-02 0.181476 1.923624E-02 Final coordinates: 8925.03 947.712 0.302284 0.999873 0.297798 1.508821E-02 0.645117 8.678298E-03 3.530570E-03 2.978778E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.208815E-2 Extraneous predicted phases: 6.096999E-3 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 33.291 0.014145 0.001820 0.000000 0.083556 0.007991 0.000000 0.006805 0.282852 0.602831 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.6 0. 0. 0.1 0.5 0. 1. -0.1 -0.4 Chi 1.0E-03 0. 0. 9.8E-06 1.3E-03 0. 6.7E-03 2.0E-05 1.3E-05 Composition Misfit: 1.080746E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.015 0.000000 0.025130 0.000000 0.000000 0.309543 0.034518 0.064272 0.139300 0.427238 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.6 0. 0. 0.7 -3.0E-02 -0.9 0.3 -0.3 Chi 0. 8.4E-04 0. 0. 4.9E-04 2.1E-06 1.4E-03 1.5E-04 1.6E-05 Composition Misfit: 2.893008E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 59.740 0.095656 0.053691 0.000000 0.002499 0.000000 0.000000 0.000000 0.151845 0.696309 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.2 0. -0.3 0. 0. 0. 0.6 -0.1 Chi 1.7E-04 8.2E-05 0. 5.2E-04 0. 0. 0. 5.4E-04 4.7E-06 Composition Misfit: 1.314787E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.123 0.000000 0.000000 0.030171 0.076170 0.210863 0.000982 0.154370 0.142548 0.384896 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -2. 0.1 1. -0.2 2. Chi 0. 0. 2.6E-03 1.1E-03 3.3E-03 2.0E-04 1.5E-03 3.5E-05 2.5E-03 Composition Misfit: 1.121441E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.002 0.000000 0.000000 0.450585 0.000000 0.524236 0.009523 0.015656 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -6. 0. 5. 0.1 -0.9 0. 0. Chi 0. 0. 2.2E-02 0. 2.1E-02 2.4E-05 2.0E-03 0. 0. Composition Misfit: 4.585849E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.399 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.379 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 ru 0.051 0.000000 0.000000 1.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.058756 0.031574 0.001336 0.027373 0.011594 0.000530 0.006363 0.059955 0.000219 0.187087 0.615213 Mica 0.011810 0.001520 0.000000 0.069765 0.006672 0.000000 0.005682 0.164671 0.000378 0.236168 0.503335 Gt 0.000000 0.025091 0.000000 0.000000 0.309062 0.034464 0.064172 0.000000 0.001554 0.139084 0.426574 Fsp 0.095656 0.053691 0.000000 0.002499 0.000000 0.000000 0.000000 0.000000 0.000000 0.151845 0.696309 Bio 0.000000 0.000000 0.026818 0.067704 0.187427 0.000873 0.137212 0.108590 0.002553 0.126705 0.342117 Ilm 0.000000 0.000000 0.439720 0.000000 0.511596 0.009294 0.015278 0.000000 0.024112 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -779160. -757364. -932610. -848647. -315919. -471616. -641036. -294828. -427952. -1638482. -887891. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Gt Mica Bio ky ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Gt Mica Bio ky ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 38 converged, 28 successes so far. Misfit function evaluations this try => 473 Misfit this try = 2.470651E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.099467E-06 Bayes score, PP * exp(-Misfit) = 1.072636E-06 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 6171.30 872.801 0.483875 0.317306 0.176883 5.730900E-03 0.371903 2.714307E-02 0.102976 0.315364 Final coordinates: 9222.22 922.174 0.646122 0.479851 2.236119E-03 1.341381E-02 0.765674 9.677551E-02 1.126533E-02 0.110636 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.470651E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 10.059 0.011844 0.001405 0.000000 0.085903 0.008965 0.000000 0.007982 0.280549 0.603353 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.3 0. 0.8 -4.1E-03 -0.4 Chi 1.9E-04 0. 0. 2.4E-05 5.4E-04 0. 3.9E-03 1.8E-08 1.9E-05 Composition Misfit: 6.047762E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.926 0.000000 0.034733 0.000000 0.000000 0.299165 0.038231 0.065299 0.136417 0.426156 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -0.4 -1. 0.5 -0.2 Chi 0. 5.8E-03 0. 0. 1.7E-03 4.2E-04 1.7E-03 4.0E-04 5.3E-06 Composition Misfit: 1.003722E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 74.448 0.095815 0.053413 0.000000 0.002479 0.000000 0.000000 0.000000 0.151706 0.696587 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.2 0. -0.3 0. 0. 0. 0.6 -0.1 Chi 1.8E-04 6.2E-05 0. 5.1E-04 0. 0. 0. 5.6E-04 6.2E-06 Composition Misfit: 1.313052E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 9.061 0.000000 0.000000 0.028439 0.075722 0.200895 0.000962 0.172842 0.135835 0.385306 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.9 -1. -1. 0.1 -0.2 0.3 2. Chi 0. 0. 1.8E-03 1.0E-03 1.3E-03 2.2E-04 6.4E-05 1.5E-04 2.4E-03 Composition Misfit: 6.988187E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.585 0.000000 0.000000 0.349704 0.000000 0.629007 0.009448 0.011841 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 1.6E-02 0. 4.6E-02 0.1 -0.3 0. 0. Chi 0. 0. 2.5E-07 0. 1.6E-06 3.2E-05 2.9E-04 0. 0. Composition Misfit: 3.202979E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.301 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.621 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.069187 0.038579 0.005829 0.016537 0.029604 0.000688 0.018214 0.029026 0.001195 0.165212 0.625928 Mica 0.009890 0.001173 0.000000 0.071728 0.007485 0.000000 0.006665 0.164409 0.000603 0.234255 0.503792 Gt 0.000000 0.034635 0.000000 0.000000 0.298324 0.038123 0.065115 0.000000 0.002810 0.136033 0.424959 Fsp 0.095815 0.053413 0.000000 0.002479 0.000000 0.000000 0.000000 0.000000 0.000000 0.151706 0.696587 Bio 0.000000 0.000000 0.025224 0.067162 0.178183 0.000853 0.153302 0.109100 0.003954 0.120478 0.341746 Ilm 0.000000 0.000000 0.325261 0.000000 0.585042 0.008788 0.011013 0.000000 0.069895 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -771868. -752629. -929782. -838831. -313020. -467214. -637983. -293178. -407996. -1633705. -884414. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Gt Opx Bio ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Gt Opx Bio ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 40 converged, 29 successes so far. Misfit function evaluations this try => 159 Misfit this try = 2.291808E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.004456E-06 Bayes score, PP * exp(-Misfit) = 9.816974E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 6881.83 940.752 0.910279 0.930375 3.602622E-03 0.275306 0.335858 3.841546E-02 0.126081 0.220737 Final coordinates: 9433.03 932.512 0.909505 0.919628 5.721490E-03 0.192696 0.399137 3.852725E-02 7.902349E-02 0.284895 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.291808E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 33.542 0.011641 0.001258 0.000000 0.086128 0.009513 0.000000 0.008012 0.279793 0.603657 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.3 0. 0.8 4.0E-02 -0.5 Chi 1.4E-04 0. 0. 3.2E-05 2.8E-04 0. 3.8E-03 1.7E-06 2.2E-05 Composition Misfit: 5.561349E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 14.642 0.000000 0.030108 0.000000 0.000000 0.307825 0.033089 0.066081 0.136653 0.426245 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 0.8 0.1 -1. 0.5 -0.2 Chi 0. 3.0E-03 0. 0. 6.5E-04 4.0E-05 1.9E-03 3.8E-04 5.9E-06 Composition Misfit: 6.032151E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 40.271 0.097865 0.048625 0.000000 0.002823 0.000000 0.000000 0.000000 0.149312 0.701375 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.5 0.3 0. -0.4 0. 0. 0. 0.8 -0.3 Chi 3.9E-04 1.8E-04 0. 7.6E-04 0. 0. 0. 9.0E-04 6.7E-05 Composition Misfit: 2.302490E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.021 0.000000 0.000000 0.029124 0.075784 0.206062 0.000869 0.166504 0.136759 0.384897 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.2 0.2 0.3 2. Chi 0. 0. 2.1E-03 1.0E-03 2.3E-03 3.5E-04 5.4E-05 9.2E-05 2.5E-03 Composition Misfit: 8.364764E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.412 0.000000 0.000000 0.347688 0.000000 0.632502 0.008182 0.011628 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. -0.1 0.3 -0.3 0. 0. Chi 0. 0. 1.5E-05 0. 9.9E-06 4.0E-04 2.3E-04 0. 0. Composition Misfit: 6.573260E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.370 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 0.741 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.037133 0.023028 0.026713 0.025949 0.114580 0.006982 0.020462 0.055586 0.006513 0.167747 0.515307 Mica 0.009721 0.001050 0.000000 0.071920 0.007943 0.000000 0.006690 0.164332 0.000625 0.233639 0.504079 Gt 0.000000 0.030026 0.000000 0.000000 0.306992 0.032999 0.065902 0.000000 0.002707 0.136283 0.425091 Fsp 0.097865 0.048625 0.000000 0.002823 0.000000 0.000000 0.000000 0.000000 0.000000 0.149312 0.701375 Bio 0.000000 0.000000 0.025846 0.067252 0.182864 0.000771 0.147760 0.108659 0.003919 0.121363 0.341566 Ilm 0.000000 0.000000 0.323083 0.000000 0.587742 0.007603 0.010806 0.000000 0.070767 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772934. -754361. -930838. -839626. -313843. -469457. -638855. -294068. -408910. -1634910. -885057. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 41 converged, 30 successes so far. Misfit function evaluations this try => 1006 Misfit this try = 838.901 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 3.371660E-07 Bayes score, PP * exp(-Misfit) = 0.00000 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 13568.6 947.423 0.471353 0.864066 0.515943 1.591911E-02 7.223297E-03 0.275476 0.110640 7.479793E-02 Final coordinates: 8516.03 975.913 0.544112 0.931377 0.484886 3.386973E-02 1.378819E-02 0.334982 4.876526E-02 8.370868E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.688787E-2 Extraneous predicted phases: 838.804 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.149 0.005123 0.001217 0.000000 0.092682 0.010326 0.000000 0.007316 0.279976 0.603360 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.8 0. 0. -0.7 0.1 0. 0.9 2.9E-02 -0.4 Chi 5.4E-03 0. 0. 7.3E-04 6.7E-05 0. 5.3E-03 9.0E-07 1.9E-05 Composition Misfit: 1.268832E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.345 0.000000 0.034797 0.000000 0.000000 0.266402 0.078352 0.057984 0.136338 0.426127 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 3. -5. -0.3 0.5 -0.2 Chi 0. 5.8E-03 0. 0. 1.2E-02 2.5E-02 1.8E-04 4.1E-04 5.1E-06 Composition Misfit: 4.282339E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.010 0.081220 0.074227 0.000000 0.006666 0.000000 0.000000 0.000000 0.162114 0.675773 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 0.9 -2. 0. -2. 0. 0. 0. -0.1 0.8 Chi 1.3E-03 6.9E-03 0. 4.2E-03 0. 0. 0. 9.1E-06 5.2E-04 Composition Misfit: 1.299499E-02 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 42.313 0.000000 0.000000 0.036962 0.076730 0.209028 0.002659 0.146183 0.150950 0.377488 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -2. -0.4 2. -0.8 2. Chi 0. 0. 6.6E-03 1.2E-03 2.9E-03 5.7E-04 3.7E-03 7.5E-04 3.9E-03 Composition Misfit: 1.967723E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.416 0.000000 0.000000 0.343423 0.000000 0.620648 0.023920 0.012009 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.4 0. 0.4 -2. -0.3 0. 0. Chi 0. 0. 1.3E-04 0. 1.4E-04 8.1E-03 3.4E-04 0. 0. Composition Misfit: 8.703937E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.655 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Fsp 34.111 0.022084 0.003730 0.000000 0.101051 0.000000 0.000000 0.000000 0.000000 0.000000 0.126865 0.746270 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.006583 0.001295 0.022292 0.064847 0.101004 0.001955 0.061497 0.056625 0.003435 0.196526 0.483942 Mica 0.004277 0.001016 0.000000 0.077382 0.008621 0.000000 0.006108 0.164335 0.000739 0.233759 0.503761 Gt 0.000000 0.034698 0.000000 0.000000 0.265645 0.078129 0.057819 0.000000 0.002844 0.135951 0.424915 Fsp 0.081220 0.074227 0.000000 0.006666 0.000000 0.000000 0.000000 0.000000 0.000000 0.162114 0.675773 Bio 0.000000 0.000000 0.032977 0.068458 0.186494 0.002373 0.130423 0.103938 0.003869 0.134676 0.336792 Ilm 0.000000 0.000000 0.318489 0.000000 0.575586 0.022184 0.011137 0.000000 0.072604 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -790724. -759439. -937897. -846117. -321065. -469235. -644987. -302938. -409706. -1644025. -891982. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 42 converged, 31 successes so far. Misfit function evaluations this try => 710 Misfit this try = 1.27831 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 2.350590E-07 Bayes score, PP * exp(-Misfit) = 6.546582E-08 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 7951.25 830.562 0.191315 0.899730 3.471355E-02 2.826561E-02 3.622845E-02 8.040413E-02 0.755155 6.523312E-02 Final coordinates: 6507.39 840.266 0.463996 0.927856 0.338841 4.083769E-02 1.980169E-02 0.346529 7.541279E-02 0.178578 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.27831 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.209 0.007347 0.000839 0.000000 0.091196 0.006156 0.000000 0.005199 0.286926 0.602338 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.5 0. 0. -0.6 0.8 0. 1. -0.4 -0.3 Chi 1.2E-03 0. 0. 5.0E-04 4.1E-03 0. 1.3E-02 1.4E-04 9.1E-06 Composition Misfit: 2.018771E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.111 0.000000 0.062739 0.000000 0.000000 0.262824 0.075206 0.036177 0.136766 0.426287 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -5. 0. 0. 3. -5. 2. 0.5 -0.2 Chi 0. 2.8E-02 0. 0. 1.3E-02 2.2E-02 9.6E-03 3.7E-04 6.2E-06 Composition Misfit: 7.391941E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 32.544 0.023773 0.002835 0.000000 0.099809 0.000000 0.000000 0.000000 0.126418 0.747165 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -2.9E+01 0. 0. 0. 2. -2. Chi 0.2 0.8 0. 0.1 0. 0. 0. 9.4E-03 3.7E-03 Composition Misfit: 1.14257 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 43.738 0.000000 0.000000 0.031719 0.076241 0.218379 0.001384 0.146742 0.143622 0.381913 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -2. 1.2E-02 2. -0.2 2. Chi 0. 0. 3.4E-03 1.1E-03 5.3E-03 1.2E-06 3.5E-03 7.6E-05 3.0E-03 Composition Misfit: 1.642020E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.012 0.000000 0.000000 0.419337 0.000000 0.554168 0.017547 0.008948 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -4. 0. 3. -1. 0.2 0. 0. Chi 0. 0. 1.1E-02 0. 1.0E-02 3.2E-03 1.2E-04 0. 0. Composition Misfit: 2.521121E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.387 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.006599 0.001711 0.031086 0.061558 0.119891 0.002434 0.063225 0.056246 0.003477 0.186529 0.467243 Mica 0.006130 0.000700 0.000000 0.076097 0.005137 0.000000 0.004338 0.165155 0.000407 0.239422 0.502613 Gt 0.000000 0.062572 0.000000 0.000000 0.262126 0.075006 0.036081 0.000000 0.002658 0.136403 0.425154 Fsp 0.023773 0.002835 0.000000 0.099809 0.000000 0.000000 0.000000 0.000000 0.000000 0.126418 0.747165 Bio 0.000000 0.000000 0.028198 0.067780 0.194142 0.001230 0.130456 0.107361 0.003625 0.127682 0.339526 Ilm 0.000000 0.000000 0.403080 0.000000 0.532684 0.016867 0.008602 0.000000 0.038768 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -763080. -744533. -924477. -825482. -306594. -454688. -635525. -293745. -412577. -1626923. -882002. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 43 converged, 32 successes so far. Misfit function evaluations this try => 483 Misfit this try = 1.11324 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 3.413514E-07 Bayes score, PP * exp(-Misfit) = 1.121316E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 12668.0 871.729 0.412409 0.280623 4.684988E-02 3.161707E-02 1.760688E-02 6.354030E-02 5.179807E-02 0.788588 Final coordinates: 7969.42 970.233 0.313134 0.308309 2.522204E-02 1.988867E-02 3.820533E-02 4.884047E-02 4.850266E-02 0.819341 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.11285 Extraneous predicted phases: 3.878484E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.011 0.005008 0.001276 0.000000 0.092966 0.009191 0.000000 0.005726 0.282600 0.603233 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.8 0. 0. -0.7 0.3 0. 1. -0.1 -0.4 Chi 5.7E-03 0. 0. 7.8E-04 4.2E-04 0. 1.1E-02 1.6E-05 1.7E-05 Composition Misfit: 1.890321E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.239 0.000000 0.032722 0.000000 0.000000 0.283850 0.071171 0.045910 0.139162 0.427186 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -4. 0.8 0.3 -0.3 Chi 0. 4.5E-03 0. 0. 5.1E-03 1.9E-02 1.7E-03 1.6E-04 1.5E-05 Composition Misfit: 3.068296E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 58.545 0.020682 0.003803 0.000000 0.102416 0.000000 0.000000 0.000000 0.126901 0.746197 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -2.9E+01 0. 0. 0. 2. -2. Chi 0.2 0.6 0. 0.1 0. 0. 0. 9.1E-03 3.6E-03 Composition Misfit: 0.956544 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.509 0.000000 0.000000 0.039079 0.077164 0.231794 0.002372 0.114842 0.157455 0.377294 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -3. -0.3 4. -1. 2. Chi 0. 0. 8.0E-03 1.4E-03 9.7E-03 3.8E-04 2.6E-02 1.9E-03 4.0E-03 Composition Misfit: 5.127379E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.404 0.000000 0.000000 0.450602 0.000000 0.514743 0.022179 0.012476 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -6. 0. 5. -2. -0.4 0. 0. Chi 0. 0. 2.2E-02 0. 2.6E-02 6.7E-03 4.9E-04 0. 0. Composition Misfit: 5.544753E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 24.278 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 ru 0.014 0.000000 0.000000 1.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.010933 0.002124 0.016082 0.066627 0.049434 0.001103 0.019004 0.018664 0.000967 0.225562 0.589501 Mica 0.004181 0.001065 0.000000 0.077618 0.007674 0.000000 0.004781 0.164663 0.000435 0.235943 0.503641 Gt 0.000000 0.032669 0.000000 0.000000 0.283392 0.071056 0.045836 0.000000 0.001614 0.138937 0.426496 Fsp 0.020682 0.003803 0.000000 0.102416 0.000000 0.000000 0.000000 0.000000 0.000000 0.126901 0.746197 Bio 0.000000 0.000000 0.034956 0.069023 0.207339 0.002122 0.102726 0.103089 0.002413 0.140843 0.337489 Ilm 0.000000 0.000000 0.439741 0.000000 0.502335 0.021645 0.012175 0.000000 0.024104 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -792591. -759579. -937262. -847763. -320139. -469764. -646610. -302989. -430336. -1644261. -892602. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 44 converged, 33 successes so far. Misfit function evaluations this try => 386 Misfit this try = 3.183222E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 9.125818E-07 Bayes score, PP * exp(-Misfit) = 8.839898E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 12171.8 978.221 0.918365 0.888759 8.228271E-03 0.112173 5.418458E-03 7.568643E-03 0.786853 7.975875E-02 Final coordinates: 9158.62 937.176 0.959661 0.971985 1.396531E-03 0.495155 2.995012E-03 1.776220E-03 0.166873 0.331805 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.183222E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 44.484 0.011283 0.000906 0.000000 0.086716 0.009826 0.000000 0.007194 0.280321 0.603755 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.1 0. 0. -0.2 0.2 0. 0.9 9.2E-03 -0.5 Chi 7.6E-05 0. 0. 5.9E-05 1.8E-04 0. 5.6E-03 8.8E-08 2.3E-05 Composition Misfit: 6.852541E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 39.134 0.000000 0.021032 0.000000 0.000000 0.317407 0.035951 0.061699 0.137390 0.426521 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.1 0. 0. 0.3 -0.2 -0.7 0.5 -0.2 Chi 0. 1.1E-05 0. 0. 6.4E-05 8.1E-05 7.7E-04 3.0E-04 8.1E-06 Composition Misfit: 1.239318E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.075 0.101269 0.040501 0.000000 0.003481 0.000000 0.000000 0.000000 0.145250 0.709499 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.8 1. 0. -0.6 0. 0. 0. 1. -0.7 Chi 9.1E-04 3.0E-03 0. 1.3E-03 0. 0. 0. 1.7E-03 3.2E-04 Composition Misfit: 7.250300E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.146 0.000000 0.000000 0.029874 0.076003 0.219960 0.000975 0.150016 0.140049 0.383122 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -2. 0.1 1. 1.9E-02 2. Chi 0. 0. 2.4E-03 1.1E-03 5.7E-03 2.1E-04 2.5E-03 5.0E-07 2.8E-03 Composition Misfit: 1.478155E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 13.763 0.000000 0.000000 0.332466 0.000000 0.649109 0.008632 0.009793 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 1. 0. -0.9 0.2 3.3E-02 0. 0. Chi 0. 0. 9.2E-04 0. 5.6E-04 2.2E-04 4.4E-06 0. 0. Composition Misfit: 1.708507E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.914 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 0.484 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.003449 0.009562 0.054103 0.026167 0.248628 0.017245 0.031119 0.059352 0.014912 0.153124 0.382339 Mica 0.009421 0.000756 0.000000 0.072404 0.008204 0.000000 0.006006 0.164405 0.000640 0.234055 0.504108 Gt 0.000000 0.020982 0.000000 0.000000 0.316649 0.035866 0.061552 0.000000 0.002386 0.137062 0.425503 Fsp 0.101269 0.040501 0.000000 0.003481 0.000000 0.000000 0.000000 0.000000 0.000000 0.145250 0.709499 Bio 0.000000 0.000000 0.026518 0.067465 0.195250 0.000866 0.133163 0.108412 0.003929 0.124315 0.340082 Ilm 0.000000 0.000000 0.306769 0.000000 0.598938 0.007965 0.009036 0.000000 0.077292 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774476. -757741. -932440. -840989. -314364. -469628. -640248. -295378. -410664. -1636260. -886196. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 45 converged, 34 successes so far. Misfit function evaluations this try => 278 Misfit this try = 2.284084E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.102980E-06 Bayes score, PP * exp(-Misfit) = 1.078073E-06 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 6158.67 810.443 0.496362 0.944210 9.403183E-02 0.415397 0.332511 8.861191E-02 2.956493E-03 6.649170E-02 Final coordinates: 9349.86 923.424 0.462116 0.869683 5.874836E-02 0.274756 0.290371 0.226129 4.057247E-02 0.109423 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.284084E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.099 0.011857 0.001118 0.000000 0.086016 0.009289 0.000000 0.007843 0.280176 0.603701 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.3 0. 0.8 1.8E-02 -0.5 Chi 1.9E-04 0. 0. 2.8E-05 3.7E-04 0. 4.1E-03 3.3E-07 2.3E-05 Composition Misfit: 5.879747E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.347 0.000000 0.028663 0.000000 0.000000 0.309555 0.033975 0.064570 0.136900 0.426338 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 0.7 3.0E-02 -0.9 0.5 -0.2 Chi 0. 2.3E-03 0. 0. 4.9E-04 2.2E-06 1.5E-03 3.5E-04 6.6E-06 Composition Misfit: 4.631251E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 30.578 0.099272 0.045925 0.000000 0.002765 0.000000 0.000000 0.000000 0.147963 0.704075 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.6 0.6 0. -0.4 0. 0. 0. 0.9 -0.4 Chi 5.9E-04 7.0E-04 0. 7.2E-04 0. 0. 0. 1.1E-03 1.3E-04 Composition Misfit: 3.262606E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 22.512 0.000000 0.000000 0.028794 0.075733 0.207544 0.000858 0.165775 0.136001 0.385294 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.9 -1. -2. 0.2 0.3 0.3 2. Chi 0. 0. 1.9E-03 1.0E-03 2.6E-03 3.7E-04 8.4E-05 1.4E-04 2.4E-03 Composition Misfit: 8.532396E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.611 0.000000 0.000000 0.349617 0.000000 0.631057 0.008166 0.011160 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 2.1E-02 0. -4.9E-02 0.3 -0.2 0. 0. Chi 0. 0. 4.2E-07 0. 1.8E-06 4.1E-04 1.2E-04 0. 0. Composition Misfit: 5.348412E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.264 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.589 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.026753 0.019462 0.017957 0.028059 0.148699 0.009565 0.052905 0.052183 0.004295 0.155810 0.484312 Mica 0.009901 0.000933 0.000000 0.071824 0.007757 0.000000 0.006549 0.164384 0.000607 0.233950 0.504096 Gt 0.000000 0.028588 0.000000 0.000000 0.308750 0.033886 0.064402 0.000000 0.002599 0.136544 0.425229 Fsp 0.099272 0.045925 0.000000 0.002765 0.000000 0.000000 0.000000 0.000000 0.000000 0.147963 0.704075 Bio 0.000000 0.000000 0.025547 0.067194 0.184141 0.000762 0.147082 0.108840 0.003921 0.120665 0.341848 Ilm 0.000000 0.000000 0.325167 0.000000 0.586925 0.007595 0.010380 0.000000 0.069933 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -770885. -753848. -929889. -837784. -312773. -468124. -638209. -293447. -408849. -1633628. -884257. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 46 converged, 35 successes so far. Misfit function evaluations this try => 344 Misfit this try = 2.686598E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.180006E-06 Bayes score, PP * exp(-Misfit) = 1.148726E-06 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 7333.56 818.945 0.919687 0.185183 4.551062E-03 8.929863E-03 0.629265 5.369859E-02 4.657445E-02 0.256982 Final coordinates: 9029.67 901.898 0.804665 0.277751 5.732157E-03 7.008089E-03 0.808352 0.143992 2.515685E-02 9.758342E-03 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.686598E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.018 0.012868 0.001397 0.000000 0.084972 0.008273 0.000000 0.007672 0.281701 0.603118 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.4 0. 0. -4.3E-02 0.4 0. 0.9 -0.1 -0.4 Chi 4.9E-04 0. 0. 3.1E-06 1.0E-03 0. 4.5E-03 5.3E-06 1.6E-05 Composition Misfit: 7.413457E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.699 0.000000 0.037778 0.000000 0.000000 0.299977 0.037149 0.062488 0.136442 0.426166 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -0.3 -0.7 0.5 -0.2 Chi 0. 7.9E-03 0. 0. 1.6E-03 2.3E-04 9.5E-04 4.0E-04 5.3E-06 Composition Misfit: 1.104345E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 79.763 0.096103 0.053672 0.000000 0.002061 0.000000 0.000000 0.000000 0.151836 0.696328 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.4 -0.2 0. -0.2 0. 0. 0. 0.6 -0.1 Chi 2.1E-04 8.0E-05 0. 2.4E-04 0. 0. 0. 5.4E-04 4.8E-06 Composition Misfit: 1.072019E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 12.888 0.000000 0.000000 0.027143 0.075565 0.200167 0.000848 0.176262 0.133474 0.386541 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.7 -1. -1. 0.2 -0.5 0.5 2. Chi 0. 0. 1.2E-03 9.8E-04 1.2E-03 3.9E-04 2.6E-04 3.5E-04 2.2E-03 Composition Misfit: 6.679812E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.474 0.000000 0.000000 0.358252 0.000000 0.621571 0.008757 0.011420 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.5 0. 0.4 0.2 -0.2 0. 0. Chi 0. 0. 1.9E-04 0. 1.1E-04 1.8E-04 1.8E-04 0. 0. Composition Misfit: 6.572449E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.354 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.803 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.072831 0.041054 0.011655 0.011817 0.043986 0.000683 0.024773 0.016836 0.002212 0.152653 0.621498 Mica 0.010744 0.001166 0.000000 0.070943 0.006907 0.000000 0.006405 0.164541 0.000555 0.235193 0.503546 Gt 0.000000 0.037673 0.000000 0.000000 0.299137 0.037045 0.062313 0.000000 0.002799 0.136060 0.424973 Fsp 0.096103 0.053672 0.000000 0.002061 0.000000 0.000000 0.000000 0.000000 0.000000 0.151836 0.696328 Bio 0.000000 0.000000 0.024053 0.066963 0.177381 0.000751 0.156198 0.109873 0.003961 0.118280 0.342540 Ilm 0.000000 0.000000 0.334541 0.000000 0.580433 0.008178 0.010664 0.000000 0.066183 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -767931. -750263. -927584. -835875. -310753. -464987. -636356. -291329. -407658. -1630902. -882671. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 47 converged, 36 successes so far. Misfit function evaluations this try => 407 Misfit this try = 0.961621 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.506441E-07 Bayes score, PP * exp(-Misfit) = 5.758710E-08 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 13311.0 978.189 0.690182 0.610967 1.007866E-03 8.972557E-02 7.412910E-04 0.139385 4.217843E-03 0.764923 Final coordinates: 8281.90 997.423 0.771931 0.835243 4.526714E-03 0.302112 4.118593E-03 5.970026E-03 8.025231E-02 0.603021 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.961621 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.809 0.005649 0.001212 0.000000 0.092231 0.011973 0.000000 0.005051 0.280918 0.602967 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.7 0. 0. -0.7 -0.1 0. 1. -2.6E-02 -0.4 Chi 3.9E-03 0. 0. 6.5E-04 5.6E-05 0. 1.4E-02 6.9E-07 1.5E-05 Composition Misfit: 2.014831E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 14.607 0.000000 0.026132 0.000000 0.000000 0.318560 0.049078 0.043197 0.136751 0.426282 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.7 0. 0. 0.2 -2. 1. 0.5 -0.2 Chi 0. 1.2E-03 0. 0. 3.5E-05 4.5E-03 3.1E-03 3.7E-04 6.2E-06 Composition Misfit: 9.197396E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.866 0.025357 0.004078 0.000000 0.097604 0.000000 0.000000 0.000000 0.127039 0.745922 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 5. 5. 0. -2.8E+01 0. 0. 0. 2. -2. Chi 0.2 0.6 0. 0.1 0. 0. 0. 9.0E-03 3.5E-03 Composition Misfit: 0.834510 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.378 0.000000 0.000000 0.036780 0.077162 0.257085 0.001765 0.095541 0.157430 0.374237 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -5. -0.1 5. -1. 2. Chi 0. 0. 6.5E-03 1.4E-03 2.1E-02 6.6E-05 0.1 1.9E-03 4.7E-03 Composition Misfit: 9.217148E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.666 0.000000 0.000000 0.321577 0.000000 0.657745 0.013424 0.007255 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 2. 0. -1. -0.5 0.4 0. 0. Chi 0. 0. 2.5E-03 0. 1.2E-03 8.7E-04 1.0E-03 0. 0. Composition Misfit: 5.594459E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.676 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.006219 0.005985 0.026303 0.048214 0.145139 0.010401 0.024795 0.052107 0.007002 0.200760 0.473074 Mica 0.004715 0.001012 0.000000 0.076993 0.009995 0.000000 0.004217 0.164429 0.000784 0.234506 0.503349 Gt 0.000000 0.026062 0.000000 0.000000 0.317711 0.048947 0.043082 0.000000 0.002664 0.136387 0.425146 Fsp 0.025357 0.004078 0.000000 0.097604 0.000000 0.000000 0.000000 0.000000 0.000000 0.127039 0.745922 Bio 0.000000 0.000000 0.032787 0.068785 0.229176 0.001574 0.085169 0.104784 0.003774 0.140340 0.333611 Ilm 0.000000 0.000000 0.295238 0.000000 0.603872 0.012324 0.006661 0.000000 0.081905 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -796208. -764270. -942685. -853056. -322410. -475964. -649970. -304967. -416983. -1648149. -894970. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 48 converged, 37 successes so far. Misfit function evaluations this try => 583 Misfit this try = 0.956923 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 2.082479E-07 Bayes score, PP * exp(-Misfit) = 7.998237E-08 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 6357.96 937.561 0.428359 0.436923 0.583837 8.770438E-02 3.208663E-03 4.199735E-03 4.776892E-02 0.273281 Final coordinates: 8771.45 991.920 0.247494 0.764090 0.357050 0.166209 2.725413E-02 7.489692E-02 1.864448E-02 0.355945 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.956923 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 14.482 0.005506 0.001169 0.000000 0.092291 0.011737 0.000000 0.006270 0.279552 0.603475 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.8 0. 0. -0.7 -0.1 0. 1. 0.1 -0.4 Chi 4.3E-03 0. 0. 6.6E-04 2.9E-05 0. 8.4E-03 3.1E-06 2.0E-05 Composition Misfit: 1.460306E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.271 0.000000 0.029471 0.000000 0.000000 0.306001 0.050861 0.050895 0.136562 0.426211 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 0.9 -2. 0.4 0.5 -0.2 Chi 0. 2.7E-03 0. 0. 8.3E-04 5.4E-03 3.0E-04 3.9E-04 5.7E-06 Composition Misfit: 9.648781E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 39.418 0.024724 0.003852 0.000000 0.098350 0.000000 0.000000 0.000000 0.126926 0.746148 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 5. 5. 0. -2.8E+01 0. 0. 0. 2. -2. Chi 0.2 0.6 0. 0.1 0. 0. 0. 9.1E-03 3.6E-03 Composition Misfit: 0.881200 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.997 0.000000 0.000000 0.037163 0.076895 0.238154 0.001796 0.116123 0.153419 0.376451 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -4. -0.1 4. -0.9 2. Chi 0. 0. 6.7E-03 1.3E-03 1.2E-02 7.7E-05 2.5E-02 1.1E-03 4.1E-03 Composition Misfit: 4.999104E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.010 0.000000 0.000000 0.348291 0.000000 0.627411 0.014603 0.009695 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. 0.1 -0.7 4.9E-02 0. 0. Chi 0. 0. 8.4E-06 0. 1.1E-05 1.5E-03 9.6E-06 0. 0. Composition Misfit: 1.479803E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.822 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.009025 0.004403 0.007420 0.059601 0.079461 0.005465 0.028898 0.046752 0.001229 0.218034 0.539713 Mica 0.004597 0.000976 0.000000 0.077059 0.009800 0.000000 0.005235 0.164288 0.000763 0.233411 0.503871 Gt 0.000000 0.029390 0.000000 0.000000 0.305160 0.050722 0.050755 0.000000 0.002747 0.136187 0.425040 Fsp 0.024724 0.003852 0.000000 0.098350 0.000000 0.000000 0.000000 0.000000 0.000000 0.126926 0.746148 Bio 0.000000 0.000000 0.033157 0.068606 0.212481 0.001603 0.103605 0.104054 0.003744 0.136881 0.335870 Ilm 0.000000 0.000000 0.323734 0.000000 0.583174 0.013574 0.009012 0.000000 0.070506 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -792613. -762048. -940290. -848809. -321659. -474505. -647595. -303990. -414709. -1646160. -893211. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 49 converged, 38 successes so far. Misfit function evaluations this try => 722 Misfit this try = 2.429188E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 7.558049E-07 Bayes score, PP * exp(-Misfit) = 7.376662E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 5729.52 892.020 0.879497 9.239565E-02 4.318170E-03 0.215362 0.736521 2.147467E-02 4.604537E-03 1.771969E-02 Final coordinates: 9398.90 949.630 0.525252 3.255461E-02 2.038306E-02 3.326276E-02 0.932756 8.329146E-03 4.930307E-03 3.383968E-04 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.429188E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.712 0.011872 0.001583 0.000000 0.085728 0.009755 0.000000 0.007882 0.279885 0.603294 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.2 0. 0.8 3.5E-02 -0.4 Chi 1.9E-04 0. 0. 1.9E-05 2.0E-04 0. 4.1E-03 1.3E-06 1.8E-05 Composition Misfit: 6.083993E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.431 0.000000 0.030350 0.000000 0.000000 0.307442 0.031926 0.067662 0.136451 0.426169 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 0.8 0.3 -1. 0.5 -0.2 Chi 0. 3.2E-03 0. 0. 6.8E-04 1.7E-04 2.4E-03 4.0E-04 5.4E-06 Composition Misfit: 6.868238E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 91.435 0.095532 0.053221 0.000000 0.002857 0.000000 0.000000 0.000000 0.151611 0.696779 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.2 0. -0.4 0. 0. 0. 0.6 -0.1 Chi 1.6E-04 5.0E-05 0. 7.9E-04 0. 0. 0. 5.7E-04 7.4E-06 Composition Misfit: 1.570290E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.570 0.000000 0.000000 0.029423 0.075939 0.207163 0.000905 0.163798 0.139091 0.383680 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -2. 0.1 0.4 0.1 2. Chi 0. 0. 2.2E-03 1.1E-03 2.5E-03 3.0E-04 2.0E-04 1.1E-05 2.7E-03 Composition Misfit: 8.978302E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.318 0.000000 0.000000 0.347435 0.000000 0.632074 0.008270 0.012221 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. -0.1 0.3 -0.4 0. 0. Chi 0. 0. 1.9E-05 0. 6.8E-06 3.6E-04 4.0E-04 0. 0. Composition Misfit: 7.910565E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.305 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.229 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.085486 0.048687 0.001899 0.003565 0.015542 0.001197 0.003556 0.002002 0.000510 0.161435 0.676120 Mica 0.009914 0.001322 0.000000 0.071585 0.008146 0.000000 0.006582 0.164320 0.000649 0.233712 0.503769 Gt 0.000000 0.030265 0.000000 0.000000 0.306583 0.031836 0.067473 0.000000 0.002795 0.136070 0.424978 Fsp 0.095532 0.053221 0.000000 0.002857 0.000000 0.000000 0.000000 0.000000 0.000000 0.151611 0.696779 Bio 0.000000 0.000000 0.026111 0.067390 0.183842 0.000803 0.145358 0.108670 0.003907 0.123433 0.340487 Ilm 0.000000 0.000000 0.322810 0.000000 0.587275 0.007684 0.011355 0.000000 0.070876 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777586. -756130. -933145. -844667. -315952. -472048. -640435. -295263. -410006. -1637767. -887017. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 50 converged, 39 successes so far. Misfit function evaluations this try => 597 Misfit this try = 0.908369 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.775735E-07 Bayes score, PP * exp(-Misfit) = 7.159434E-08 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 14412.6 814.897 0.317795 0.865978 0.526522 3.557131E-02 0.335153 1.605252E-02 1.244224E-02 7.425907E-02 Final coordinates: 8887.41 996.719 0.829779 0.503538 0.587455 2.332928E-02 3.507464E-02 0.188706 5.024887E-02 0.115186 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.908369 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.048 0.004778 0.001489 0.000000 0.092790 0.010991 0.000000 0.007787 0.278802 0.603363 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.9 0. 0. -0.7 2.5E-02 0. 0.8 0.1 -0.4 Chi 6.5E-03 0. 0. 7.5E-04 2.5E-06 0. 4.3E-03 1.0E-05 1.9E-05 Composition Misfit: 1.304560E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.085 0.000000 0.038474 0.000000 0.000000 0.268321 0.070925 0.060769 0.135645 0.425867 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 3. -4. -0.6 0.6 -0.1 Chi 0. 8.4E-03 0. 0. 1.1E-02 1.9E-02 5.9E-04 4.9E-04 3.4E-06 Composition Misfit: 3.911104E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 50.578 0.021384 0.004560 0.000000 0.101336 0.000000 0.000000 0.000000 0.127280 0.745440 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -2.9E+01 0. 0. 0. 2. -2. Chi 0.2 0.5 0. 0.1 0. 0. 0. 8.9E-03 3.5E-03 Composition Misfit: 0.827005 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.763 0.000000 0.000000 0.037684 0.076761 0.206952 0.002560 0.147491 0.151415 0.377137 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -1. -0.3 2. -0.8 2. Chi 0. 0. 7.1E-03 1.3E-03 2.4E-03 5.0E-04 3.3E-03 8.1E-04 4.0E-03 Composition Misfit: 1.936159E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.022 0.000000 0.000000 0.321530 0.000000 0.644145 0.022065 0.012261 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 2. 0. -0.6 -2. -0.4 0. 0. Chi 0. 0. 2.5E-03 0. 3.1E-04 6.6E-03 4.2E-04 0. 0. Composition Misfit: 9.845222E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.504 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.009492 0.002071 0.019557 0.065158 0.074012 0.001420 0.039158 0.030485 0.003838 0.210371 0.544436 Mica 0.003989 0.001244 0.000000 0.077481 0.009178 0.000000 0.006503 0.164185 0.000793 0.232806 0.503821 Gt 0.000000 0.038353 0.000000 0.000000 0.267477 0.070702 0.060577 0.000000 0.003145 0.135218 0.424527 Fsp 0.021384 0.004560 0.000000 0.101336 0.000000 0.000000 0.000000 0.000000 0.000000 0.127280 0.745440 Bio 0.000000 0.000000 0.033640 0.068523 0.184742 0.002285 0.131662 0.103406 0.003917 0.135164 0.336662 Ilm 0.000000 0.000000 0.295188 0.000000 0.591374 0.020257 0.011256 0.000000 0.081925 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -795204. -760447. -939949. -848974. -323327. -472342. -646374. -304435. -409391. -1646721. -893493. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 51 converged, 40 successes so far. Misfit function evaluations this try => 513 Misfit this try = 9.896928E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.290524E-07 Bayes score, PP * exp(-Misfit) = 1.168919E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 6300.38 847.602 0.114589 0.893501 0.255388 4.360243E-02 1.312957E-02 3.257453E-03 0.503480 0.181142 Final coordinates: 6706.31 815.702 0.338732 0.725030 0.262335 0.626020 1.482342E-02 4.904360E-03 8.791893E-02 3.999126E-03 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.896319E-2 Extraneous predicted phases: 6.086595E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.219 0.017246 0.000708 0.000000 0.081586 0.005373 0.000000 0.003618 0.289776 0.601692 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -1. 0. 0. 0.2 0.9 0. 1. -0.5 -0.2 Chi 2.8E-03 0. 0. 1.0E-04 6.2E-03 0. 2.7E-02 3.0E-04 4.8E-06 Composition Misfit: 3.733069E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 45.793 0.000000 0.023659 0.000000 0.000000 0.333552 0.040076 0.036534 0.139039 0.427140 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.4 0. 0. -0.7 -0.6 2. 0.3 -0.3 Chi 0. 4.1E-04 0. 0. 4.1E-04 8.5E-04 9.1E-03 1.7E-04 1.4E-05 Composition Misfit: 1.096955E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.060 0.102272 0.042786 0.000000 0.001335 0.000000 0.000000 0.000000 0.146393 0.707214 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.9 0.9 0. 6.7E-03 0. 0. 0. 1. -0.6 Chi 1.1E-03 1.8E-03 0. 4.0E-07 0. 0. 0. 1.4E-03 2.3E-04 Composition Misfit: 4.583176E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.105 0.000000 0.000000 0.023171 0.075745 0.250839 0.000605 0.128456 0.136169 0.385015 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.2 -1. -4. 0.2 3. 0.3 2. Chi 0. 0. 1.4E-04 1.0E-03 1.8E-02 1.1E-03 1.3E-02 1.3E-04 2.5E-03 Composition Misfit: 3.556724E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.682 0.000000 0.000000 0.389721 0.000000 0.597704 0.006930 0.005645 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 1. 0.5 0.7 0. 0. Chi 0. 0. 4.0E-03 0. 1.7E-03 1.4E-03 3.4E-03 0. 0. Composition Misfit: 1.051255E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.415 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 2.723 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Sp 0.002 0.000000 0.000000 0.015745 0.000000 0.841529 0.000000 0.002544 0.000000 0.134480 0.005701 0.000000 ab 0.001 0.125000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.125000 0.750000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.003911 0.012945 0.029328 0.021698 0.247711 0.021205 0.037634 0.044911 0.005244 0.159401 0.416012 Mica 0.014386 0.000591 0.000000 0.068056 0.004482 0.000000 0.003018 0.165476 0.000356 0.241722 0.501912 Gt 0.000000 0.023619 0.000000 0.000000 0.332996 0.040010 0.036473 0.000000 0.001668 0.138807 0.426427 Fsp 0.102272 0.042786 0.000000 0.001335 0.000000 0.000000 0.000000 0.000000 0.000000 0.146393 0.707214 Bio 0.000000 0.000000 0.020454 0.066863 0.221427 0.000534 0.113394 0.113272 0.003985 0.120202 0.339870 Ilm 0.000000 0.000000 0.369355 0.000000 0.566469 0.006568 0.005350 0.000000 0.052258 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -757166. -747573. -922911. -829060. -301991. -455599. -633600. -286965. -413607. -1622878. -879065. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 52 converged, 41 successes so far. Misfit function evaluations this try => 1011 Misfit this try = 2352.40 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.167167E-06 Bayes score, PP * exp(-Misfit) = 0.00000 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 10497.7 820.624 0.454664 0.230345 0.312646 0.117892 0.154132 7.177023E-03 1.133724E-02 0.396815 Final coordinates: 8983.98 895.310 0.637009 0.209352 0.317902 0.128004 6.503921E-02 1.479155E-02 1.536697E-02 0.458897 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.168227 Extraneous predicted phases: 2352.23 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.160 0.005592 0.000518 0.000000 0.092516 0.010075 0.000000 0.007823 0.279033 0.604443 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.8 0. 0. -0.7 0.2 0. 0.8 0.1 -0.6 Chi 4.1E-03 0. 0. 7.0E-04 1.2E-04 0. 4.2E-03 7.5E-06 3.3E-05 Composition Misfit: 9.624587E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.383 0.000000 0.038108 0.000000 0.000000 0.305581 0.043115 0.050975 0.136161 0.426060 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 0.9 -1. 0.4 0.5 -0.2 Chi 0. 8.1E-03 0. 0. 8.7E-04 1.8E-03 2.9E-04 4.3E-04 4.6E-06 Composition Misfit: 1.151244E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.463 0.095187 0.049274 0.000000 0.005176 0.000000 0.000000 0.000000 0.149637 0.700726 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 0.2 0. -1. 0. 0. 0. 0.8 -0.3 Chi 1.3E-04 1.1E-04 0. 2.8E-03 0. 0. 0. 8.5E-04 5.5E-05 Composition Misfit: 3.959941E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.566 0.000000 0.000000 0.031992 0.075835 0.220151 0.000986 0.149546 0.137519 0.383972 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -2. 0.1 1. 0.2 2. Chi 0. 0. 3.5E-03 1.0E-03 5.8E-03 2.0E-04 2.7E-03 5.7E-05 2.7E-03 Composition Misfit: 1.593386E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.699 0.000000 0.000000 0.211845 0.000000 0.777183 0.006674 0.004297 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 8. 0. -7. 0.5 0.9 0. 0. Chi 0. 0. 0.1 0. 2.8E-02 1.7E-03 7.6E-03 0. 0. Composition Misfit: 0.127196 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 24.118 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Fsp 56.609 0.020540 0.001490 0.000000 0.103715 0.000000 0.000000 0.000000 0.000000 0.000000 0.125745 0.748510 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.012578 0.005375 0.005113 0.059883 0.055926 0.004093 0.018136 0.012656 0.002227 0.223434 0.600578 Mica 0.004670 0.000433 0.000000 0.077256 0.008413 0.000000 0.006532 0.164285 0.000655 0.233009 0.504746 Gt 0.000000 0.037997 0.000000 0.000000 0.304688 0.042989 0.050826 0.000000 0.002921 0.135763 0.424816 Fsp 0.095187 0.049274 0.000000 0.005176 0.000000 0.000000 0.000000 0.000000 0.000000 0.149637 0.700726 Bio 0.000000 0.000000 0.028454 0.067447 0.195802 0.000877 0.133007 0.106441 0.004159 0.122309 0.341505 Ilm 0.000000 0.000000 0.185167 0.000000 0.679310 0.005834 0.003756 0.000000 0.125933 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -766708. -749909. -928188. -823747. -309873. -463046. -637213. -295688. -405601. -1629967. -882073. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 53 converged, 42 successes so far. Misfit function evaluations this try => 442 Misfit this try = 0.175259 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 3.807387E-07 Bayes score, PP * exp(-Misfit) = 3.195310E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 6207.54 853.655 0.722067 0.558730 9.260679E-03 0.104387 0.179971 0.237638 1.834744E-02 0.450396 Final coordinates: 6438.63 868.973 0.715832 0.745076 1.441691E-02 0.308064 0.341831 9.034464E-02 3.461406E-02 0.210730 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.175259 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 11.845 0.015991 0.001343 0.000000 0.082452 0.006234 0.000000 0.003723 0.289147 0.601112 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.9 0. 0. 0.2 0.8 0. 1. -0.5 -0.1 Chi 2.0E-03 0. 0. 4.9E-05 3.9E-03 0. 2.6E-02 2.6E-04 2.1E-06 Composition Misfit: 3.344604E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 13.314 0.000000 0.023543 0.000000 0.000000 0.313192 0.057150 0.040791 0.138417 0.426906 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.4 0. 0. 0.5 -3. 1. 0.4 -0.3 Chi 0. 3.8E-04 0. 0. 2.4E-04 9.2E-03 4.8E-03 2.1E-04 1.2E-05 Composition Misfit: 1.483442E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 37.638 0.094611 0.057594 0.000000 0.001592 0.000000 0.000000 0.000000 0.153797 0.692406 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.6 0. -0.1 0. 0. 0. 0.5 0.1 Chi 9.3E-05 6.2E-04 0. 3.5E-05 0. 0. 0. 3.3E-04 6.3E-06 Composition Misfit: 1.086010E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 22.608 0.000000 0.000000 0.024993 0.076375 0.247790 0.001161 0.124268 0.145630 0.379783 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -4. 0.1 3. -0.4 2. Chi 0. 0. 5.3E-04 1.2E-03 1.6E-02 6.0E-05 1.6E-02 1.9E-04 3.4E-03 Composition Misfit: 3.804186E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.498 0.000000 0.000000 0.233563 0.000000 0.752816 0.009760 0.003861 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 6. 0. -6. 3.8E-02 1. 0. 0. Chi 0. 0. 0.1 0. 2.0E-02 5.9E-06 9.8E-03 0. 0. Composition Misfit: 8.785063E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.270 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 4.827 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.031939 0.022741 0.013327 0.024223 0.132986 0.010461 0.033770 0.045207 0.005950 0.166176 0.513221 Mica 0.013339 0.001120 0.000000 0.068780 0.005200 0.000000 0.003105 0.165358 0.000455 0.241203 0.501439 Gt 0.000000 0.023497 0.000000 0.000000 0.312585 0.057039 0.040712 0.000000 0.001939 0.138149 0.426079 Fsp 0.094611 0.057594 0.000000 0.001592 0.000000 0.000000 0.000000 0.000000 0.000000 0.153797 0.692406 Bio 0.000000 0.000000 0.022072 0.067448 0.218825 0.001025 0.109742 0.112824 0.004069 0.128607 0.335389 Ilm 0.000000 0.000000 0.206106 0.000000 0.664317 0.008613 0.003407 0.000000 0.117558 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -771865. -753477. -929838. -843903. -308729. -460045. -638464. -291059. -414341. -1631404. -885126. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ab the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ab -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 55 converged, 43 successes so far. Misfit function evaluations this try => 1014 Misfit this try = 3112.44 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.173666E-06 Bayes score, PP * exp(-Misfit) = 0.00000 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 13771.5 815.790 0.895024 0.244684 3.505142E-02 3.672303E-02 3.429659E-02 5.266817E-02 0.364493 0.476768 Final coordinates: 10910.4 891.305 0.995881 0.128316 8.860104E-03 1.488629E-02 9.166724E-02 1.790443E-02 3.792766E-03 0.862889 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.03676 Extraneous predicted phases: 3111.41 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.506 0.004763 0.000492 0.000000 0.092678 0.010935 0.000000 0.014231 0.270173 0.606729 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.9 0. 0. -0.7 3.4E-02 0. -0.1 0.6 -0.9 Chi 6.6E-03 0. 0. 7.3E-04 4.5E-06 0. 3.3E-05 3.9E-04 7.5E-05 Composition Misfit: 8.300150E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.458 0.000000 0.070184 0.000000 0.000000 0.279623 0.022004 0.075281 0.129387 0.423520 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -6. 0. 0. 2. 1. -2. 1. 0.1 Chi 0. 3.5E-02 0. 0. 6.4E-03 6.8E-03 5.6E-03 1.6E-03 3.1E-06 Composition Misfit: 5.550495E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.665 0.096714 0.046536 0.000000 0.005018 0.000000 0.000000 0.000000 0.148268 0.703464 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.4 0.5 0. -1. 0. 0. 0. 0.9 -0.4 Chi 2.7E-04 5.5E-04 0. 2.7E-03 0. 0. 0. 1.1E-03 1.1E-04 Composition Misfit: 4.675118E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.826 0.000000 0.000000 0.022671 0.074706 0.163075 0.000453 0.227376 0.120584 0.391134 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.2 -1. 1. 0.3 -4. 1. 1. Chi 0. 0. 7.5E-05 8.0E-04 2.8E-03 2.1E-03 1.5E-02 3.2E-03 1.6E-03 Composition Misfit: 2.530103E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.206 0.000000 0.000000 0.090106 0.000000 0.907037 0.001141 0.001717 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 1.4E+01 0. -1.3E+01 1. 1. 0. 0. Chi 0. 0. 0.7 0. 0.1 0.1 4.0E-02 0. 0. Composition Misfit: 0.942975 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.456 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Fsp 62.884 0.018739 0.001334 0.000000 0.105594 0.000000 0.000000 0.000000 0.000000 0.000000 0.125667 0.748666 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.015306 0.004422 0.001502 0.065816 0.017746 0.000503 0.013784 0.007627 0.001105 0.231738 0.640451 Mica 0.003981 0.000411 0.000000 0.077465 0.009140 0.000000 0.011895 0.163302 0.000849 0.225823 0.507134 Gt 0.000000 0.069773 0.000000 0.000000 0.277985 0.021875 0.074840 0.000000 0.005859 0.128629 0.421039 Fsp 0.096714 0.046536 0.000000 0.005018 0.000000 0.000000 0.000000 0.000000 0.000000 0.148268 0.703464 Bio 0.000000 0.000000 0.020022 0.065974 0.144015 0.000400 0.200800 0.111926 0.004955 0.106490 0.345418 Ilm 0.000000 0.000000 0.074780 0.000000 0.752760 0.000947 0.001425 0.000000 0.170088 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -757098. -743520. -930778. -811352. -308694. -465707. -631935. -293653. -389557. -1625152. -877261. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ab the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ab -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 57 converged, 44 successes so far. Misfit function evaluations this try => 1008 Misfit this try = 936.736 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.806724E-07 Bayes score, PP * exp(-Misfit) = 0.00000 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 11056.5 906.018 0.606465 0.946113 0.159687 0.264226 6.322236E-03 0.513364 1.018981E-02 4.621072E-02 Final coordinates: 8162.90 991.723 0.533046 0.947919 0.559570 4.499061E-02 1.630193E-02 0.221613 4.996818E-02 0.107556 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.117726 Extraneous predicted phases: 936.618 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 12.181 0.005272 0.001318 0.000000 0.092559 0.010280 0.000000 0.006559 0.281033 0.602979 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.8 0. 0. -0.7 0.1 0. 1. -3.2E-02 -0.4 Chi 4.9E-03 0. 0. 7.1E-04 7.5E-05 0. 7.4E-03 1.1E-06 1.5E-05 Composition Misfit: 1.446795E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.464 0.000000 0.029515 0.000000 0.000000 0.266467 0.085016 0.055638 0.136993 0.426372 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 3. -6. -0.1 0.5 -0.2 Chi 0. 2.7E-03 0. 0. 1.2E-02 3.0E-02 1.3E-05 3.4E-04 6.9E-06 Composition Misfit: 4.494270E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.004 0.080239 0.075219 0.000000 0.007152 0.000000 0.000000 0.000000 0.162609 0.674781 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 0.9 -2. 0. -2. 0. 0. 0. -0.1 0.9 Chi 1.6E-03 7.4E-03 0. 4.7E-03 0. 0. 0. 1.8E-05 5.8E-04 Composition Misfit: 1.433039E-02 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 32.903 0.000000 0.000000 0.037758 0.077015 0.216435 0.003104 0.134854 0.155228 0.375606 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -2. -0.5 2. -1. 2. Chi 0. 0. 7.1E-03 1.3E-03 4.7E-03 9.1E-04 8.9E-03 1.4E-03 4.3E-03 Composition Misfit: 2.873492E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.495 0.000000 0.000000 0.369081 0.000000 0.590870 0.027535 0.012514 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 2. -3. -0.4 0. 0. Chi 0. 0. 9.9E-04 0. 2.6E-03 1.1E-02 5.1E-04 0. 0. Composition Misfit: 1.524984E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.149 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Fsp 35.804 0.023265 0.004196 0.000000 0.099637 0.000000 0.000000 0.000000 0.000000 0.000000 0.127098 0.745804 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.007675 0.001612 0.020295 0.065026 0.086103 0.002152 0.045266 0.057768 0.002869 0.207574 0.503660 Mica 0.004401 0.001101 0.000000 0.077271 0.008582 0.000000 0.005475 0.164445 0.000727 0.234614 0.503384 Gt 0.000000 0.029439 0.000000 0.000000 0.265785 0.084798 0.055496 0.000000 0.002559 0.136642 0.425281 Fsp 0.080239 0.075219 0.000000 0.007152 0.000000 0.000000 0.000000 0.000000 0.000000 0.162609 0.674781 Bio 0.000000 0.000000 0.033700 0.068739 0.193175 0.002770 0.120361 0.103777 0.003691 0.138546 0.335241 Ilm 0.000000 0.000000 0.346405 0.000000 0.554568 0.025844 0.011745 0.000000 0.061438 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -796241. -762771. -940657. -852141. -323284. -470904. -647358. -304658. -413285. -1647442. -894593. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 58 converged, 45 successes so far. Misfit function evaluations this try => 584 Misfit this try = 1.41971 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 5.387668E-07 Bayes score, PP * exp(-Misfit) = 1.302659E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 10638.5 833.061 0.786912 0.942195 0.127815 0.103432 0.157286 0.373500 1.226972E-02 0.225697 Final coordinates: 7711.33 853.043 0.883088 0.939771 6.169829E-02 5.046271E-02 2.836440E-02 0.453195 3.861613E-02 0.367663 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.41659 Extraneous predicted phases: 3.111176E-3 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.579 0.007027 0.000765 0.000000 0.091295 0.007147 0.000000 0.007041 0.283540 0.603184 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.5 0. 0. -0.6 0.6 0. 0.9 -0.2 -0.4 Chi 1.6E-03 0. 0. 5.1E-04 2.2E-03 0. 6.0E-03 3.3E-05 1.7E-05 Composition Misfit: 1.116096E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.759 0.000000 0.069839 0.000000 0.000000 0.258157 0.067673 0.044356 0.134527 0.425448 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -6. 0. 0. 4. -4. 1. 0.7 -0.1 Chi 0. 3.5E-02 0. 0. 1.6E-02 1.7E-02 2.5E-03 6.4E-04 1.5E-06 Composition Misfit: 7.014949E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 31.997 0.024075 0.002577 0.000000 0.099637 0.000000 0.000000 0.000000 0.126289 0.747423 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -2.8E+01 0. 0. 0. 2. -2. Chi 0.2 0.9 0. 0.1 0. 0. 0. 9.5E-03 3.7E-03 Composition Misfit: 1.23222 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 46.422 0.000000 0.000000 0.031587 0.075767 0.197237 0.001301 0.173043 0.136512 0.384554 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -0.8 3.5E-02 -0.2 0.3 2. Chi 0. 0. 3.3E-03 1.0E-03 8.3E-04 1.2E-05 7.2E-05 1.1E-04 2.6E-03 Composition Misfit: 7.911371E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.260 0.000000 0.000000 0.225363 0.000000 0.757128 0.012312 0.005197 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -6. -0.4 0.8 0. 0. Chi 0. 0. 0.1 0. 2.1E-02 4.3E-04 4.4E-03 0. 0. Composition Misfit: 9.514863E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.918 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 ab 0.066 0.125000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.125000 0.750000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.006482 0.002300 0.021337 0.061297 0.118614 0.002538 0.078905 0.056281 0.006547 0.180120 0.465579 Mica 0.005866 0.000638 0.000000 0.076205 0.005966 0.000000 0.005878 0.164779 0.000515 0.236673 0.503482 Gt 0.000000 0.069586 0.000000 0.000000 0.257219 0.067427 0.044195 0.000000 0.003631 0.134039 0.423903 Fsp 0.024075 0.002577 0.000000 0.099637 0.000000 0.000000 0.000000 0.000000 0.000000 0.126289 0.747423 Bio 0.000000 0.000000 0.028087 0.067373 0.175384 0.001157 0.153870 0.106659 0.004138 0.121387 0.341947 Ilm 0.000000 0.000000 0.198153 0.000000 0.665713 0.010825 0.004570 0.000000 0.120739 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -760424. -743773. -923649. -821446. -307268. -455801. -634351. -293505. -404049. -1626231. -880556. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio sill the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio sill -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 61 converged, 46 successes so far. Misfit function evaluations this try => 557 Misfit this try = 2.990567E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.941640E-07 Bayes score, PP * exp(-Misfit) = 1.884434E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 7090.11 867.387 4.885566E-02 0.891482 0.305416 3.657058E-03 0.270183 2.310350E-02 7.072026E-02 0.326920 Final coordinates: 10302.5 996.780 0.834016 2.368915E-02 3.542168E-03 7.802296E-06 0.959398 7.054078E-04 7.786712E-04 3.556831E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.990567E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.582 0.009836 0.001667 0.000000 0.087441 0.011276 0.000000 0.009408 0.276262 0.604111 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.1 0. 0. -0.3 -1.9E-02 0. 0.6 0.2 -0.5 Chi 2.8E-05 0. 0. 1.0E-04 1.3E-06 0. 1.8E-03 6.4E-05 2.8E-05 Composition Misfit: 3.709542E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.001 0.000000 0.029221 0.000000 0.000000 0.297385 0.032648 0.078712 0.136024 0.426009 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. 0.2 -2. 0.6 -0.2 Chi 0. 2.6E-03 0. 0. 2.0E-03 7.8E-05 7.3E-03 4.5E-04 4.3E-06 Composition Misfit: 1.239697E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 94.150 0.094359 0.052899 0.000000 0.004191 0.000000 0.000000 0.000000 0.151449 0.697101 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -0.1 0. -0.8 0. 0. 0. 0.7 -0.1 Chi 7.8E-05 3.2E-05 0. 1.9E-03 0. 0. 0. 5.9E-04 9.7E-06 Composition Misfit: 2.624424E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.323 0.000000 0.000000 0.032662 0.076076 0.196713 0.001112 0.169462 0.141144 0.382830 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -0.8 0.1 3.7E-03 -0.1 2. Chi 0. 0. 3.9E-03 1.1E-03 7.6E-04 8.8E-05 1.7E-08 4.9E-06 2.9E-03 Composition Misfit: 8.720401E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.031 0.000000 0.000000 0.354445 0.000000 0.619790 0.009803 0.015961 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.2 0. 0.5 3.1E-02 -0.9 0. 0. Chi 0. 0. 5.6E-05 0. 1.7E-04 3.9E-06 2.2E-03 0. 0. Composition Misfit: 2.454335E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.862 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.051 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.088200 0.049426 0.000287 0.004646 0.001058 0.000009 0.000657 0.001459 0.000055 0.165183 0.689021 Mica 0.008216 0.001393 0.000000 0.073043 0.009419 0.000000 0.007859 0.163911 0.000745 0.230774 0.504640 Gt 0.000000 0.029134 0.000000 0.000000 0.296499 0.032551 0.078478 0.000000 0.002980 0.135619 0.424739 Fsp 0.094359 0.052899 0.000000 0.004191 0.000000 0.000000 0.000000 0.000000 0.000000 0.151449 0.697101 Bio 0.000000 0.000000 0.029065 0.067697 0.175048 0.000990 0.150797 0.106330 0.003808 0.125598 0.340666 Ilm 0.000000 0.000000 0.330400 0.000000 0.577743 0.009138 0.014878 0.000000 0.067840 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -785053. -760181. -937015. -849204. -321232. -477380. -643382. -299268. -409888. -1643665. -890247. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 62 converged, 47 successes so far. Misfit function evaluations this try => 415 Misfit this try = 2.351418E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 9.625192E-07 Bayes score, PP * exp(-Misfit) = 9.401504E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 5716.35 853.155 0.939003 0.587055 3.803014E-02 1.035668E-02 0.257960 1.612337E-03 8.470082E-02 0.607340 Final coordinates: 9310.30 934.764 0.985394 0.635301 3.684333E-02 0.106189 0.628703 3.147318E-03 4.653885E-02 0.178579 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.351418E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 23.296 0.011808 0.001408 0.000000 0.085910 0.009444 0.000000 0.007832 0.280197 0.603401 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.3 0. 0.8 1.6E-02 -0.4 Chi 1.8E-04 0. 0. 2.4E-05 3.1E-04 0. 4.2E-03 2.8E-07 1.9E-05 Composition Misfit: 6.108606E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.691 0.000000 0.031319 0.000000 0.000000 0.307175 0.033212 0.065562 0.136532 0.426199 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 0.8 0.1 -1. 0.5 -0.2 Chi 0. 3.7E-03 0. 0. 7.1E-04 3.2E-05 1.8E-03 3.9E-04 5.6E-06 Composition Misfit: 6.608845E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 62.109 0.096407 0.051741 0.000000 0.002722 0.000000 0.000000 0.000000 0.150870 0.698259 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.4 -1.4E-02 0. -0.4 0. 0. 0. 0.7 -0.2 Chi 2.3E-04 4.1E-07 0. 6.8E-04 0. 0. 0. 6.7E-04 2.0E-05 Composition Misfit: 1.605647E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.148 0.000000 0.000000 0.028972 0.075839 0.206918 0.000884 0.165378 0.137578 0.384431 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.2 0.3 0.2 2. Chi 0. 0. 2.0E-03 1.0E-03 2.4E-03 3.3E-04 1.0E-04 5.4E-05 2.6E-03 Composition Misfit: 8.546272E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.086 0.000000 0.000000 0.346134 0.000000 0.634013 0.008273 0.011580 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.2 0. -0.2 0.3 -0.3 0. 0. Chi 0. 0. 4.3E-05 0. 2.5E-05 3.6E-04 2.2E-04 0. 0. Composition Misfit: 6.448137E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.713 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 0.956 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.057306 0.033147 0.015660 0.018440 0.063659 0.003932 0.009321 0.038616 0.003921 0.169751 0.586246 Mica 0.009860 0.001176 0.000000 0.071736 0.007886 0.000000 0.006540 0.164367 0.000627 0.233966 0.503844 Gt 0.000000 0.031232 0.000000 0.000000 0.306327 0.033121 0.065382 0.000000 0.002760 0.136155 0.425023 Fsp 0.096407 0.051741 0.000000 0.002722 0.000000 0.000000 0.000000 0.000000 0.000000 0.150870 0.698259 Bio 0.000000 0.000000 0.025704 0.067284 0.183579 0.000784 0.146725 0.108864 0.003931 0.122060 0.341069 Ilm 0.000000 0.000000 0.321408 0.000000 0.588721 0.007682 0.010753 0.000000 0.071437 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774301. -754494. -931410. -841261. -314242. -469847. -639215. -294212. -409243. -1635540. -885584. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky ab ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky ab ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 65 converged, 48 successes so far. Misfit function evaluations this try => 319 Misfit this try = 2.291124E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.046430E-06 Bayes score, PP * exp(-Misfit) = 1.022728E-06 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 5941.34 894.928 0.286801 0.614484 0.233598 0.139978 8.705609E-02 0.192722 8.199734E-02 0.264648 Final coordinates: 9428.85 929.162 0.384179 0.952480 0.115687 0.237248 0.374396 0.105307 1.967625E-02 0.147685 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.291124E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 29.788 0.011602 0.001190 0.000000 0.086205 0.009477 0.000000 0.007992 0.279814 0.603720 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.3 0. 0.8 3.9E-02 -0.5 Chi 1.3E-04 0. 0. 3.5E-05 3.0E-04 0. 3.9E-03 1.6E-06 2.3E-05 Composition Misfit: 5.538775E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.976 0.000000 0.029677 0.000000 0.000000 0.308884 0.032924 0.065516 0.136727 0.426272 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 0.7 0.1 -1. 0.5 -0.2 Chi 0. 2.8E-03 0. 0. 5.5E-04 5.3E-05 1.8E-03 3.7E-04 6.1E-06 Composition Misfit: 5.541445E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 37.770 0.098438 0.047469 0.000000 0.002828 0.000000 0.000000 0.000000 0.148734 0.702531 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.6 0.4 0. -0.4 0. 0. 0. 0.8 -0.4 Chi 4.7E-04 3.6E-04 0. 7.6E-04 0. 0. 0. 9.9E-04 9.2E-05 Composition Misfit: 2.677252E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 9.497 0.000000 0.000000 0.029063 0.075760 0.206667 0.000853 0.166170 0.136397 0.385090 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.2 0.2 0.3 2. Chi 0. 0. 2.0E-03 1.0E-03 2.4E-03 3.8E-04 6.7E-05 1.1E-04 2.5E-03 Composition Misfit: 8.481190E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.247 0.000000 0.000000 0.347817 0.000000 0.632689 0.008059 0.011435 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. -0.1 0.3 -0.2 0. 0. Chi 0. 0. 1.4E-05 0. 1.1E-05 4.7E-04 1.8E-04 0. 0. Composition Misfit: 6.725787E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.721 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.034826 0.022745 0.008590 0.028022 0.104489 0.007965 0.032545 0.057292 0.002509 0.172066 0.528950 Mica 0.009688 0.000994 0.000000 0.071985 0.007914 0.000000 0.006674 0.164339 0.000620 0.233656 0.504132 Gt 0.000000 0.029597 0.000000 0.000000 0.308058 0.032836 0.065341 0.000000 0.002675 0.136361 0.425132 Fsp 0.098438 0.047469 0.000000 0.002828 0.000000 0.000000 0.000000 0.000000 0.000000 0.148734 0.702531 Bio 0.000000 0.000000 0.025791 0.067230 0.183399 0.000757 0.147461 0.108670 0.003919 0.121041 0.341733 Ilm 0.000000 0.000000 0.323222 0.000000 0.587951 0.007489 0.010626 0.000000 0.070711 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -772051. -754112. -930436. -838683. -313415. -469049. -638595. -293859. -408832. -1634378. -884701. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 66 converged, 49 successes so far. Misfit function evaluations this try => 196 Misfit this try = 2.777362E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 7.556626E-07 Bayes score, PP * exp(-Misfit) = 7.349639E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 6758.56 918.872 0.948310 0.742854 0.162305 0.472662 2.486695E-02 3.796726E-02 0.224402 7.779680E-02 Final coordinates: 9291.05 949.067 0.940903 0.763868 0.128520 0.527267 1.472786E-02 5.102431E-02 0.191523 8.693879E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.777362E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 35.349 0.013625 0.001230 0.000000 0.084232 0.009495 0.000000 0.007313 0.280749 0.603357 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.5 0. 0. 1.9E-02 0.3 0. 0.9 -1.6E-02 -0.4 Chi 7.8E-04 0. 0. 6.3E-07 2.9E-04 0. 5.3E-03 2.6E-07 1.9E-05 Composition Misfit: 7.636017E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 46.359 0.000000 0.020806 0.000000 0.000000 0.313641 0.034031 0.067821 0.137237 0.426464 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3.3E-02 0. 0. 0.5 2.4E-02 -1. 0.5 -0.2 Chi 0. 3.2E-06 0. 0. 2.2E-04 1.4E-06 2.5E-03 3.2E-04 7.6E-06 Composition Misfit: 3.049937E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.289 0.101043 0.041950 0.000000 0.002982 0.000000 0.000000 0.000000 0.145975 0.708050 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.8 0.9 0. -0.5 0. 0. 0. 1. -0.6 Chi 8.7E-04 2.2E-03 0. 8.8E-04 0. 0. 0. 1.5E-03 2.6E-04 Composition Misfit: 5.759842E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.349 0.000000 0.000000 0.028917 0.075964 0.212145 0.000962 0.159111 0.139457 0.383443 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -2. 0.1 0.7 0.1 2. Chi 0. 0. 2.0E-03 1.1E-03 3.6E-03 2.2E-04 6.8E-04 5.3E-06 2.8E-03 Composition Misfit: 1.031380E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.465 0.000000 0.000000 0.338246 0.000000 0.641893 0.008572 0.011289 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.6 0. -0.5 0.2 -0.2 0. 0. Chi 0. 0. 4.1E-04 0. 2.2E-04 2.4E-04 1.5E-04 0. 0. Composition Misfit: 1.014024E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.189 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.003353 0.010855 0.063780 0.020255 0.282945 0.018767 0.039673 0.046764 0.016639 0.136505 0.360463 Mica 0.011376 0.001027 0.000000 0.070328 0.007927 0.000000 0.006106 0.164434 0.000637 0.234406 0.503760 Gt 0.000000 0.020755 0.000000 0.000000 0.312872 0.033947 0.067655 0.000000 0.002453 0.136900 0.425418 Fsp 0.101043 0.041950 0.000000 0.002982 0.000000 0.000000 0.000000 0.000000 0.000000 0.145975 0.708050 Bio 0.000000 0.000000 0.025649 0.067378 0.188166 0.000854 0.141127 0.109107 0.003923 0.123694 0.340103 Ilm 0.000000 0.000000 0.312937 0.000000 0.593863 0.007930 0.010445 0.000000 0.074825 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776740. -758815. -933578. -845716. -315782. -471519. -640641. -295149. -410779. -1637909. -887202. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 67 converged, 50 successes so far. Misfit function evaluations this try => 1022 Misfit this try = 1.11979 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 4.520164E-07 Bayes score, PP * exp(-Misfit) = 1.475149E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 10163.0 911.381 0.245147 0.881972 2.394054E-02 1.959827E-02 1.731328E-02 0.151974 0.340084 0.447090 Final coordinates: 8667.83 966.844 0.441249 0.649210 7.963410E-03 1.492070E-02 2.627759E-02 0.143902 0.101216 0.705720 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.11979 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.520 0.005334 0.001099 0.000000 0.092590 0.010126 0.000000 0.006342 0.280702 0.603806 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.8 0. 0. -0.7 0.2 0. 1. -1.3E-02 -0.5 Chi 4.7E-03 0. 0. 7.1E-04 1.0E-04 0. 8.2E-03 1.8E-07 2.4E-05 Composition Misfit: 1.485580E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.317 0.000000 0.033491 0.000000 0.000000 0.299774 0.053017 0.048381 0.138426 0.426910 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -2. 0.6 0.4 -0.3 Chi 0. 5.0E-03 0. 0. 1.6E-03 6.6E-03 8.5E-04 2.1E-04 1.2E-05 Composition Misfit: 1.435686E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 44.352 0.022454 0.003401 0.000000 0.100846 0.000000 0.000000 0.000000 0.126700 0.746599 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -2.9E+01 0. 0. 0. 2. -2. Chi 0.2 0.7 0. 0.1 0. 0. 0. 9.2E-03 3.6E-03 Composition Misfit: 1.00731 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.312 0.000000 0.000000 0.038414 0.076855 0.232699 0.001704 0.118476 0.152819 0.379034 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -3. -0.1 3. -0.9 2. Chi 0. 0. 7.6E-03 1.3E-03 1.0E-02 4.6E-05 2.2E-02 1.0E-03 3.6E-03 Composition Misfit: 4.548880E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.874 0.000000 0.000000 0.438656 0.000000 0.533531 0.015632 0.012181 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -5. 0. 4. -0.9 -0.3 0. 0. Chi 0. 0. 1.8E-02 0. 1.7E-02 2.0E-03 3.9E-04 0. 0. Composition Misfit: 3.778074E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.625 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.008849 0.001501 0.034760 0.063154 0.093063 0.001560 0.032404 0.039453 0.002566 0.204710 0.517979 Mica 0.004454 0.000917 0.000000 0.077316 0.008456 0.000000 0.005296 0.164458 0.000502 0.234398 0.504203 Gt 0.000000 0.033427 0.000000 0.000000 0.299194 0.052914 0.048287 0.000000 0.001935 0.138159 0.426084 Fsp 0.022454 0.003401 0.000000 0.100846 0.000000 0.000000 0.000000 0.000000 0.000000 0.126700 0.746599 Bio 0.000000 0.000000 0.034349 0.068721 0.208071 0.001523 0.105937 0.103093 0.002740 0.136646 0.338920 Ilm 0.000000 0.000000 0.425602 0.000000 0.517653 0.015167 0.011819 0.000000 0.029759 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -787227. -758248. -935729. -843065. -318728. -470994. -645278. -301915. -425155. -1642188. -890612. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 69 converged, 51 successes so far. Misfit function evaluations this try => 193 Misfit this try = 2.394806E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 6.603890E-07 Bayes score, PP * exp(-Misfit) = 6.447618E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 7136.71 982.374 0.850523 0.337078 0.357690 1.897088E-02 0.487713 4.262875E-02 7.055272E-02 2.244455E-02 Final coordinates: 9422.71 956.117 0.820362 0.346517 7.888138E-02 2.615621E-02 0.810329 4.459346E-02 1.504908E-02 2.499091E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.394806E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.907 0.011707 0.001601 0.000000 0.085869 0.009836 0.000000 0.007982 0.279693 0.603312 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.2 0. 0.8 4.6E-02 -0.4 Chi 1.6E-04 0. 0. 2.3E-05 1.8E-04 0. 3.9E-03 2.2E-06 1.8E-05 Composition Misfit: 5.855051E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.758 0.000000 0.029284 0.000000 0.000000 0.303370 0.035486 0.069181 0.136493 0.426185 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.1 -1. 0.5 -0.2 Chi 0. 2.6E-03 0. 0. 1.1E-03 4.3E-05 3.0E-03 3.9E-04 5.5E-06 Composition Misfit: 7.175575E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 79.304 0.095417 0.053156 0.000000 0.003006 0.000000 0.000000 0.000000 0.151578 0.696844 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.2 0. -0.5 0. 0. 0. 0.6 -0.1 Chi 1.5E-04 4.6E-05 0. 9.0E-04 0. 0. 0. 5.7E-04 7.9E-06 Composition Misfit: 1.678612E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.436 0.000000 0.000000 0.029795 0.075985 0.205170 0.001034 0.164913 0.139778 0.383326 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.1 0.3 3.9E-02 2. Chi 0. 0. 2.4E-03 1.1E-03 2.1E-03 1.5E-04 1.3E-04 2.1E-06 2.8E-03 Composition Misfit: 8.601090E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.881 0.000000 0.000000 0.347412 0.000000 0.630446 0.009420 0.012722 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. -2.0E-02 0.1 -0.4 0. 0. Chi 0. 0. 1.9E-05 0. 3.2E-07 3.6E-05 5.8E-04 0. 0. Composition Misfit: 6.377354E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.347 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.367 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.073649 0.041395 0.006080 0.012570 0.026673 0.001085 0.010313 0.021114 0.001368 0.165721 0.640034 Mica 0.009775 0.001337 0.000000 0.071705 0.008214 0.000000 0.006665 0.164297 0.000660 0.233556 0.503792 Gt 0.000000 0.029202 0.000000 0.000000 0.302528 0.035388 0.068989 0.000000 0.002776 0.136114 0.425002 Fsp 0.095417 0.053156 0.000000 0.003006 0.000000 0.000000 0.000000 0.000000 0.000000 0.151578 0.696844 Bio 0.000000 0.000000 0.026447 0.067448 0.182119 0.000917 0.146385 0.108449 0.003902 0.124074 0.340258 Ilm 0.000000 0.000000 0.322785 0.000000 0.585756 0.008753 0.011820 0.000000 0.070886 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -779029. -757022. -933870. -845921. -316822. -472055. -640937. -295884. -409963. -1638780. -887682. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 70 converged, 52 successes so far. Misfit function evaluations this try => 449 Misfit this try = 1.84566 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 3.431729E-08 Bayes score, PP * exp(-Misfit) = 5.419439E-09 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 14363.5 862.214 0.899432 0.891188 3.240249E-02 5.344485E-03 5.696804E-03 0.930300 1.459069E-02 1.166560E-02 Final coordinates: 14793.7 994.216 0.973279 0.946587 0.895403 3.251698E-03 4.914975E-02 2.154758E-02 3.993079E-03 2.665488E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.84566 Extraneous predicted phases: 1.613893E-8 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 30.422 0.004709 0.000613 0.000000 0.091739 0.014200 0.000000 0.020633 0.258117 0.609989 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.9 0. 0. -0.6 -0.5 0. -1. 1. -1. Chi 6.8E-03 0. 0. 5.8E-04 6.5E-04 0. 2.4E-03 1.9E-03 1.6E-04 Composition Misfit: 1.315791E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.454 0.000000 0.057300 0.000000 0.000000 0.268853 0.006948 0.112724 0.130309 0.423866 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -5. 0. 0. 3. 3. -6. 1. 0.1 Chi 0. 2.4E-02 0. 0. 1.0E-02 0.1 3.0E-02 1.4E-03 1.5E-06 Composition Misfit: 0.172480 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 46.527 0.025645 0.002046 0.000000 0.098332 0.000000 0.000000 0.000000 0.126023 0.747954 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 5. 5. 0. -2.8E+01 0. 0. 0. 2. -2. Chi 0.2 1. 0. 0.1 0. 0. 0. 9.7E-03 3.8E-03 Composition Misfit: 1.47925 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.423 0.000000 0.000000 0.037049 0.074829 0.142118 0.000210 0.231169 0.122437 0.392189 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. 3. 0.3 -4. 1. 1. Chi 0. 0. 6.6E-03 8.3E-04 1.3E-02 7.0E-03 1.6E-02 2.6E-03 1.4E-03 Composition Misfit: 4.762784E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.178 0.000000 0.000000 0.227693 0.000000 0.756733 0.001575 0.013999 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 7. 0. -6. 1. -0.6 0. 0. Chi 0. 0. 0.1 0. 2.1E-02 4.5E-02 1.1E-03 0. 0. Composition Misfit: 0.133137 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.996 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 ru 0.000 0.000000 0.000000 1.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.012024 0.002227 0.001589 0.067914 0.015247 0.000156 0.013996 0.055086 0.000927 0.230989 0.599845 Mica 0.003941 0.000513 0.000000 0.076789 0.011886 0.000000 0.017270 0.161973 0.000996 0.216052 0.510579 Gt 0.000000 0.056987 0.000000 0.000000 0.267385 0.006910 0.112109 0.000000 0.005460 0.129597 0.421552 Fsp 0.025645 0.002046 0.000000 0.098332 0.000000 0.000000 0.000000 0.000000 0.000000 0.126023 0.747954 Bio 0.000000 0.000000 0.033162 0.066979 0.127209 0.000188 0.206918 0.100796 0.004108 0.109593 0.351047 Ilm 0.000000 0.000000 0.200407 0.000000 0.666048 0.001386 0.012321 0.000000 0.119837 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -763567. -749524. -927304. -814453. -318197. -485510. -636163. -298498. -387476. -1633438. -879733. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio F ky ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio F ky ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Mica Bio ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Mica Bio ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 75 converged, 53 successes so far. Misfit function evaluations this try => 170 Misfit this try = 2.435760E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 9.566519E-07 Bayes score, PP * exp(-Misfit) = 9.336317E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 7473.75 938.758 0.775389 0.701173 5.121321E-03 8.575967E-03 0.143513 6.156123E-02 0.737550 4.367876E-02 Final coordinates: 9368.99 935.639 0.866573 0.662142 2.990512E-03 1.416096E-02 0.647022 0.164702 3.677855E-02 0.134345 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.435760E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 12.147 0.011789 0.001482 0.000000 0.085877 0.009297 0.000000 0.008123 0.280033 0.603400 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.3 0. 0.8 2.6E-02 -0.4 Chi 1.7E-04 0. 0. 2.3E-05 3.7E-04 0. 3.6E-03 7.1E-07 1.9E-05 Composition Misfit: 5.689637E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.116 0.000000 0.032824 0.000000 0.000000 0.299712 0.037217 0.067626 0.136452 0.426169 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -0.3 -1. 0.5 -0.2 Chi 0. 4.6E-03 0. 0. 1.6E-03 2.4E-04 2.4E-03 4.0E-04 5.4E-06 Composition Misfit: 9.313014E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 63.953 0.095769 0.053119 0.000000 0.002671 0.000000 0.000000 0.000000 0.151560 0.696881 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.1 0. -0.4 0. 0. 0. 0.6 -0.1 Chi 1.8E-04 4.4E-05 0. 6.5E-04 0. 0. 0. 5.8E-04 8.1E-06 Composition Misfit: 1.450019E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.518 0.000000 0.000000 0.029035 0.075802 0.200833 0.000993 0.171536 0.137033 0.384767 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.1 -0.1 0.2 2. Chi 0. 0. 2.0E-03 1.0E-03 1.3E-03 1.9E-04 2.4E-05 7.9E-05 2.5E-03 Composition Misfit: 7.209025E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.113 0.000000 0.000000 0.354578 0.000000 0.623256 0.009550 0.012617 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.3 0. 0.3 0.1 -0.4 0. 0. Chi 0. 0. 5.9E-05 0. 7.3E-05 2.1E-05 5.4E-04 0. 0. Composition Misfit: 6.959055E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.363 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.792 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.058119 0.032231 0.015689 0.022498 0.057087 0.001041 0.029598 0.039780 0.003092 0.160577 0.580289 Mica 0.009844 0.001237 0.000000 0.071710 0.007763 0.000000 0.006783 0.164346 0.000622 0.233836 0.503858 Gt 0.000000 0.032732 0.000000 0.000000 0.298874 0.037113 0.067437 0.000000 0.002794 0.136071 0.424979 Fsp 0.095769 0.053119 0.000000 0.002671 0.000000 0.000000 0.000000 0.000000 0.000000 0.151560 0.696881 Bio 0.000000 0.000000 0.025764 0.067262 0.178206 0.000881 0.152209 0.108759 0.003911 0.121593 0.341415 Ilm 0.000000 0.000000 0.330543 0.000000 0.581010 0.008903 0.011761 0.000000 0.067783 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774388. -754177. -931162. -841293. -314493. -469039. -638996. -294150. -408671. -1635554. -885546. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio F ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio F ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 77 converged, 54 successes so far. Misfit function evaluations this try => 753 Misfit this try = 0.510279 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 1.678226E-07 Bayes score, PP * exp(-Misfit) = 1.007486E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 11291.3 813.078 0.411255 0.878426 2.698199E-02 0.353237 0.487782 0.106549 6.754884E-03 1.869548E-02 Final coordinates: 11244.7 802.469 0.348573 0.939084 8.260947E-03 0.433283 3.194886E-06 0.531534 1.988269E-02 7.036279E-03 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.504576 Extraneous predicted phases: 5.703391E-3 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.187 0.003805 0.000044 0.000000 0.094019 0.010043 0.000000 0.012661 0.272021 0.607407 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 1. 0. 0. -0.8 0.2 0. 0.1 0.5 -0.9 Chi 1.1E-02 0. 0. 9.7E-04 1.2E-04 0. 6.2E-05 2.6E-04 9.0E-05 Composition Misfit: 1.284333E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 37.052 0.000000 0.020235 0.000000 0.000000 0.324214 0.035241 0.054427 0.138824 0.427059 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. 4.0E-02 0. 0. -0.1 -0.1 3.5E-02 0.4 -0.3 Chi 0. 4.8E-06 0. 0. 1.6E-05 2.8E-05 2.5E-06 1.8E-04 1.4E-05 Composition Misfit: 2.460903E-04 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.002 0.000000 0.000000 0.000000 0.125000 0.000000 0.000000 0.000000 0.125000 0.750000 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 8. 5. 0. -3.6E+01 0. 0. 0. 2. -2. Chi 0.1 0.1 0. 0.1 0. 0. 0. 1.0E-02 4.1E-03 Composition Misfit: 0.279959 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 53.833 0.000000 0.000000 0.031042 0.074114 0.195069 0.000462 0.188532 0.111708 0.399073 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -0.7 0.3 -1. 2. 0.9 Chi 0. 0. 3.0E-03 6.9E-04 5.8E-04 2.0E-03 1.9E-03 7.3E-03 7.1E-04 Composition Misfit: 1.624245E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.405 0.000000 0.000000 0.190280 0.000000 0.802641 0.003872 0.003207 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 9. 0. -8. 1. 1. 0. 0. Chi 0. 0. 0.1 0. 3.7E-02 9.7E-03 1.4E-02 0. 0. Composition Misfit: 0.195284 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.039 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 0.370 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 ab 0.100 0.125000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.125000 0.750000 ru 0.010 0.000000 0.000000 1.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.000149 0.008364 0.017207 0.034645 0.235070 0.014837 0.107328 0.055469 0.005121 0.132639 0.389170 Mica 0.003180 0.000037 0.000000 0.078593 0.008396 0.000000 0.010584 0.163585 0.000487 0.227390 0.507749 Gt 0.000000 0.020199 0.000000 0.000000 0.323642 0.035179 0.054332 0.000000 0.001761 0.138579 0.426307 Fsp 0.000000 0.000000 0.000000 0.125000 0.000000 0.000000 0.000000 0.000000 0.000000 0.125000 0.750000 Bio 0.000000 0.000000 0.027687 0.066103 0.173983 0.000412 0.168153 0.104518 0.003575 0.099633 0.355936 Ilm 0.000000 0.000000 0.164764 0.000000 0.695011 0.003353 0.002777 0.000000 0.134094 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -735008. -741334. -910941. -786595. -296769. -450439. -626107. -287111. -398967. -1611108. -867443. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 78 converged, 55 successes so far. Misfit function evaluations this try => 199 Misfit this try = 2.471405E-02 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 8.514620E-07 Bayes score, PP * exp(-Misfit) = 8.306768E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 7363.05 932.695 0.338340 0.830729 1.016444E-03 5.839705E-04 0.204673 3.274591E-02 5.655007E-04 0.760415 Final coordinates: 9574.27 944.038 0.467198 0.943475 8.299349E-03 1.163035E-02 0.568241 0.195572 9.314257E-03 0.206942 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.471405E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.059 0.011456 0.001499 0.000000 0.086141 0.009608 0.000000 0.008479 0.279245 0.603573 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.2 0. 0.7 0.1 -0.5 Chi 1.1E-04 0. 0. 3.3E-05 2.5E-04 0. 3.0E-03 5.4E-06 2.1E-05 Composition Misfit: 4.940157E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.967 0.000000 0.032770 0.000000 0.000000 0.298261 0.036512 0.070066 0.136285 0.426107 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -0.2 -1. 0.5 -0.2 Chi 0. 4.6E-03 0. 0. 1.9E-03 1.4E-04 3.3E-03 4.2E-04 4.9E-06 Composition Misfit: 1.032724E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 55.360 0.095750 0.052812 0.000000 0.002844 0.000000 0.000000 0.000000 0.151406 0.697188 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.1 0. -0.4 0. 0. 0. 0.7 -0.1 Chi 1.8E-04 2.8E-05 0. 7.8E-04 0. 0. 0. 5.9E-04 1.0E-05 Composition Misfit: 1.585351E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.115 0.000000 0.000000 0.029491 0.075808 0.198421 0.001006 0.173447 0.137119 0.384708 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -0.9 0.1 -0.3 0.2 2. Chi 0. 0. 2.2E-03 1.0E-03 9.8E-04 1.7E-04 8.9E-05 7.4E-05 2.5E-03 Composition Misfit: 7.128160E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.297 0.000000 0.000000 0.348529 0.000000 0.628887 0.009555 0.013029 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. 0.1 0.1 -0.5 0. 0. Chi 0. 0. 6.2E-06 0. 2.0E-06 2.1E-05 7.0E-04 0. 0. Composition Misfit: 7.331445E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.381 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.822 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.051187 0.027859 0.007011 0.030203 0.045327 0.000726 0.034684 0.056154 0.001324 0.170514 0.575011 Mica 0.009567 0.001252 0.000000 0.071936 0.008023 0.000000 0.007081 0.164257 0.000645 0.233197 0.504043 Gt 0.000000 0.032676 0.000000 0.000000 0.297405 0.036407 0.069865 0.000000 0.002867 0.135894 0.424885 Fsp 0.095750 0.052812 0.000000 0.002844 0.000000 0.000000 0.000000 0.000000 0.000000 0.151406 0.697188 Bio 0.000000 0.000000 0.026179 0.067293 0.176133 0.000893 0.153964 0.108407 0.003919 0.121717 0.341495 Ilm 0.000000 0.000000 0.323991 0.000000 0.584611 0.008882 0.012112 0.000000 0.070403 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775469. -754791. -931785. -841929. -315375. -470105. -639419. -294753. -408242. -1636473. -885998. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 79 converged, 56 successes so far. Misfit function evaluations this try => 675 Misfit this try = 1.07848 Best Misfit so far = 2.263975E-02 obtained on Try 1 Prior probability, PP = 2.535180E-07 Bayes score, PP * exp(-Misfit) = 8.622452E-08 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 7559.52 848.265 0.487408 0.129628 0.681847 5.881073E-03 7.660214E-03 5.345582E-02 4.739297E-02 0.203763 Final coordinates: 9457.65 989.173 0.292335 0.525770 0.469579 0.105801 4.016149E-02 0.135835 0.120420 0.128204 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.07848 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.614 0.005793 0.000993 0.000000 0.092056 0.011009 0.000000 0.006572 0.278993 0.604584 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.7 0. 0. -0.6 2.3E-02 0. 1. 0.1 -0.6 Chi 3.6E-03 0. 0. 6.3E-04 2.0E-06 0. 7.4E-03 7.9E-06 3.5E-05 Composition Misfit: 1.266342E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.480 0.000000 0.027033 0.000000 0.000000 0.320444 0.035502 0.050431 0.139338 0.427252 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.8 0. 0. 0.1 -0.1 0.4 0.3 -0.3 Chi 0. 1.6E-03 0. 0. 6.8E-06 4.4E-05 3.8E-04 1.5E-04 1.6E-05 Composition Misfit: 2.145517E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 41.233 0.026056 0.003380 0.000000 0.097254 0.000000 0.000000 0.000000 0.126690 0.746620 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 5. 5. 0. -2.8E+01 0. 0. 0. 2. -2. Chi 0.2 0.7 0. 0.1 0. 0. 0. 9.2E-03 3.6E-03 Composition Misfit: 0.960389 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.884 0.000000 0.000000 0.039669 0.076841 0.238085 0.001225 0.111303 0.152612 0.380265 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -4. 0.1 4. -0.9 2. Chi 0. 0. 8.4E-03 1.3E-03 1.2E-02 3.3E-05 3.0E-02 9.9E-04 3.3E-03 Composition Misfit: 5.660813E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.882 0.000000 0.000000 0.454254 0.000000 0.522471 0.010534 0.012740 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -6. 0. 5. -0.1 -0.4 0. 0. Chi 0. 0. 2.4E-02 0. 2.2E-02 2.7E-05 5.9E-04 0. 0. Composition Misfit: 4.667378E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.907 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.009043 0.003889 0.041262 0.054625 0.129742 0.004599 0.034920 0.032168 0.002371 0.190884 0.496496 Mica 0.004839 0.000830 0.000000 0.076892 0.009195 0.000000 0.005489 0.164292 0.000434 0.233036 0.504994 Gt 0.000000 0.026992 0.000000 0.000000 0.319951 0.035448 0.050354 0.000000 0.001537 0.139124 0.426595 Fsp 0.026056 0.003380 0.000000 0.097254 0.000000 0.000000 0.000000 0.000000 0.000000 0.126690 0.746620 Bio 0.000000 0.000000 0.035529 0.068822 0.213239 0.001097 0.099688 0.102114 0.002243 0.136686 0.340582 Ilm 0.000000 0.000000 0.444096 0.000000 0.510788 0.010298 0.012456 0.000000 0.022361 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -787909. -760894. -936884. -844281. -320190. -476406. -646761. -302923. -433734. -1644211. -891319. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 80 converged, 57 successes so far. Misfit function evaluations this try => 409 Misfit this try = 2.258697E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 1.102484E-06 Bayes score, PP * exp(-Misfit) = 1.077861E-06 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 10215.8 929.466 0.145616 0.937950 2.882977E-02 8.616822E-03 2.082039E-02 0.335794 0.574396 3.154234E-02 Final coordinates: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.258697E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.392 0.011895 0.001140 0.000000 0.085970 0.009236 0.000000 0.007867 0.280222 0.603670 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.3 0. 0.8 1.5E-02 -0.5 Chi 2.0E-04 0. 0. 2.6E-05 4.0E-04 0. 4.1E-03 2.3E-07 2.2E-05 Composition Misfit: 5.884809E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.653 0.000000 0.028995 0.000000 0.000000 0.308001 0.034994 0.064803 0.136878 0.426329 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 0.8 -0.1 -1. 0.5 -0.2 Chi 0. 2.5E-03 0. 0. 6.3E-04 1.6E-05 1.5E-03 3.5E-04 6.6E-06 Composition Misfit: 5.011163E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.636 0.099081 0.046364 0.000000 0.002737 0.000000 0.000000 0.000000 0.148182 0.703636 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.6 0.5 0. -0.4 0. 0. 0. 0.9 -0.4 Chi 5.6E-04 5.9E-04 0. 7.0E-04 0. 0. 0. 1.1E-03 1.2E-04 Composition Misfit: 3.052379E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 32.500 0.000000 0.000000 0.028757 0.075730 0.206496 0.000884 0.166868 0.135954 0.385311 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.9 -1. -1. 0.2 0.2 0.3 2. Chi 0. 0. 1.9E-03 1.0E-03 2.3E-03 3.3E-04 4.2E-05 1.4E-04 2.4E-03 Composition Misfit: 8.214388E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.903 0.000000 0.000000 0.349669 0.000000 0.630584 0.008466 0.011281 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 1.8E-02 0. -2.7E-02 0.2 -0.2 0. 0. Chi 0. 0. 3.1E-07 0. 5.4E-07 2.8E-04 1.5E-04 0. 0. Composition Misfit: 4.242349E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.750 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 2.166 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.023215 0.016407 0.021907 0.033093 0.150875 0.007897 0.064463 0.059332 0.004818 0.151812 0.466182 Mica 0.009932 0.000952 0.000000 0.071785 0.007712 0.000000 0.006569 0.164387 0.000606 0.233987 0.504068 Gt 0.000000 0.028919 0.000000 0.000000 0.307198 0.034902 0.064634 0.000000 0.002609 0.136521 0.425217 Fsp 0.099081 0.046364 0.000000 0.002737 0.000000 0.000000 0.000000 0.000000 0.000000 0.148182 0.703636 Bio 0.000000 0.000000 0.025513 0.067189 0.183205 0.000784 0.148047 0.108864 0.003924 0.120620 0.341853 Ilm 0.000000 0.000000 0.325224 0.000000 0.586499 0.007874 0.010492 0.000000 0.069910 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -770958. -753780. -929872. -837929. -312815. -467901. -638169. -293408. -408714. -1633640. -884275. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 81 converged, 58 successes so far. Misfit function evaluations this try => 401 Misfit this try = 2.679986E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 2.277197E-07 Bayes score, PP * exp(-Misfit) = 2.216979E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 7159.06 989.947 0.723231 0.498376 0.159114 0.459134 0.274886 1.120948E-02 8.355360E-02 1.210234E-02 Final coordinates: 9881.69 992.738 0.994849 0.438105 0.106299 0.113330 0.604630 0.103102 7.261064E-02 2.876053E-05 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.679986E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 9.730 0.010565 0.001640 0.000000 0.086839 0.011061 0.000000 0.008464 0.277728 0.603704 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -3.2E-02 0. 0. -0.2 1.4E-02 0. 0.7 0.2 -0.5 Chi 4.0E-06 0. 0. 6.5E-05 8.0E-07 0. 3.1E-03 2.7E-05 2.3E-05 Composition Misfit: 4.810301E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.619 0.000000 0.025906 0.000000 0.000000 0.304710 0.032777 0.074125 0.136350 0.426131 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.7 0. 0. 1. 0.2 -2. 0.5 -0.2 Chi 0. 1.1E-03 0. 0. 9.7E-04 6.6E-05 5.0E-03 4.1E-04 5.1E-06 Composition Misfit: 7.602972E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 63.151 0.095142 0.051720 0.000000 0.003999 0.000000 0.000000 0.000000 0.150860 0.698280 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -1.2E-02 0. -0.8 0. 0. 0. 0.7 -0.2 Chi 1.3E-04 3.0E-07 0. 1.7E-03 0. 0. 0. 6.7E-04 2.0E-05 Composition Misfit: 2.560657E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 9.299 0.000000 0.000000 0.031921 0.076184 0.205941 0.001109 0.160221 0.142760 0.381864 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.1 0.6 -0.2 2. Chi 0. 0. 3.5E-03 1.1E-03 2.2E-03 9.0E-05 5.4E-04 4.2E-05 3.0E-03 Composition Misfit: 1.056060E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.840 0.000000 0.000000 0.344681 0.000000 0.631836 0.009472 0.014011 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.3 0. -0.1 0.1 -0.6 0. 0. Chi 0. 0. 8.2E-05 0. 5.3E-06 2.9E-05 1.1E-03 0. 0. Composition Misfit: 1.265328E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.181 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.180 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.054660 0.032424 0.026710 0.016156 0.099070 0.004598 0.025005 0.026678 0.006160 0.152688 0.555852 Mica 0.008824 0.001369 0.000000 0.072527 0.009238 0.000000 0.007069 0.164071 0.000736 0.231956 0.504209 Gt 0.000000 0.025833 0.000000 0.000000 0.303845 0.032684 0.073914 0.000000 0.002839 0.135963 0.424922 Fsp 0.095142 0.051720 0.000000 0.003999 0.000000 0.000000 0.000000 0.000000 0.000000 0.150860 0.698280 Bio 0.000000 0.000000 0.028380 0.067732 0.183095 0.000986 0.142446 0.107085 0.003851 0.126923 0.339501 Ilm 0.000000 0.000000 0.319842 0.000000 0.586304 0.008789 0.013002 0.000000 0.072063 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -785733. -761207. -937740. -851162. -320874. -477169. -643851. -299119. -411204. -1643894. -890751. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 82 converged, 59 successes so far. Misfit function evaluations this try => 638 Misfit this try = 2.05241 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 1.134071E-06 Bayes score, PP * exp(-Misfit) = 1.456437E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 14033.4 844.913 0.599869 0.864937 0.582741 5.649967E-03 0.285643 5.077208E-02 2.264932E-03 7.292887E-02 Final coordinates: 9369.71 879.510 0.615778 0.929107 0.844286 3.306737E-03 2.479568E-02 3.279523E-02 5.137845E-03 8.967871E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.05241 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.641 0.005791 0.000614 0.000000 0.092140 0.009604 0.000000 0.009655 0.277401 0.604795 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.7 0. 0. -0.6 0.2 0. 0.6 0.2 -0.6 Chi 3.6E-03 0. 0. 6.4E-04 2.5E-04 0. 1.6E-03 3.4E-05 3.8E-05 Composition Misfit: 6.747422E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.263 0.000000 0.064713 0.000000 0.000000 0.287801 0.034063 0.056064 0.132625 0.424734 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -6. 0. 0. 2. 2.0E-02 -0.1 0.8 -9.1E-03 Chi 0. 3.0E-02 0. 0. 4.0E-03 9.9E-07 2.9E-05 9.5E-04 1.4E-08 Composition Misfit: 3.516296E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 46.630 0.021367 0.001845 0.000000 0.102710 0.000000 0.000000 0.000000 0.125923 0.748155 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -2.9E+01 0. 0. 0. 2. -2. Chi 0.2 1. 0. 0.1 0. 0. 0. 9.7E-03 3.8E-03 Composition Misfit: 1.68616 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.819 0.000000 0.000000 0.028300 0.075317 0.193528 0.000699 0.185187 0.129755 0.387215 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.9 -1. -0.6 0.2 -1. 0.8 1. Chi 0. 0. 1.7E-03 9.3E-04 4.2E-04 7.5E-04 1.3E-03 8.6E-04 2.1E-03 Composition Misfit: 8.123297E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.041 0.000000 0.000000 0.157146 0.000000 0.836380 0.003483 0.002991 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 1.1E+01 0. -9. 1. 1. 0. 0. Chi 0. 0. 0.2 0. 0.1 1.2E-02 1.6E-02 0. 0. Composition Misfit: 0.316217 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.606 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.010333 0.001165 0.002161 0.070158 0.017964 0.000183 0.015952 0.054747 0.000691 0.234416 0.592229 Mica 0.004837 0.000513 0.000000 0.076957 0.008022 0.000000 0.008064 0.164100 0.000685 0.231690 0.505134 Gt 0.000000 0.064424 0.000000 0.000000 0.286518 0.033911 0.055814 0.000000 0.004457 0.132034 0.422842 Fsp 0.021367 0.001845 0.000000 0.102710 0.000000 0.000000 0.000000 0.000000 0.000000 0.125923 0.748155 Bio 0.000000 0.000000 0.025101 0.066802 0.171650 0.000620 0.164251 0.108504 0.004545 0.115086 0.343440 Ilm 0.000000 0.000000 0.134149 0.000000 0.713984 0.002973 0.002553 0.000000 0.146340 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -760287. -744671. -927137. -817788. -308259. -462463. -634138. -294041. -398824. -1626672. -879523. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 83 converged, 60 successes so far. Misfit function evaluations this try => 301 Misfit this try = 2.340260E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 8.041935E-07 Bayes score, PP * exp(-Misfit) = 7.855918E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 7782.77 972.829 0.198509 0.746729 0.262442 0.278953 0.223790 0.130281 2.021790E-03 0.102512 Final coordinates: 9608.42 947.287 0.199616 0.731544 6.820605E-02 0.328242 0.340957 0.188691 2.710570E-03 7.119411E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.340260E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.910 0.011603 0.001256 0.000000 0.086117 0.009927 0.000000 0.008149 0.279157 0.603791 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.2 0. 0.8 0.1 -0.5 Chi 1.3E-04 0. 0. 3.2E-05 1.5E-04 0. 3.6E-03 6.3E-06 2.4E-05 Composition Misfit: 5.177503E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 26.542 0.000000 0.026961 0.000000 0.000000 0.309007 0.032362 0.068654 0.136739 0.426277 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.8 0. 0. 0.7 0.2 -1. 0.5 -0.2 Chi 0. 1.5E-03 0. 0. 5.4E-04 1.1E-04 2.8E-03 3.7E-04 6.2E-06 Composition Misfit: 5.346755E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 36.138 0.098610 0.046508 0.000000 0.003136 0.000000 0.000000 0.000000 0.148254 0.703492 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.6 0.5 0. -0.5 0. 0. 0. 0.9 -0.4 Chi 4.9E-04 5.6E-04 0. 1.0E-03 0. 0. 0. 1.1E-03 1.1E-04 Composition Misfit: 3.249090E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.772 0.000000 0.000000 0.029782 0.075866 0.206446 0.000906 0.164717 0.137988 0.384295 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.1 0.3 0.2 2. Chi 0. 0. 2.4E-03 1.0E-03 2.3E-03 3.0E-04 1.4E-04 3.9E-05 2.6E-03 Composition Misfit: 8.847303E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.035 0.000000 0.000000 0.346460 0.000000 0.633105 0.008291 0.012144 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.2 0. -0.1 0.3 -0.3 0. 0. Chi 0. 0. 3.6E-05 0. 1.5E-05 3.5E-04 3.8E-04 0. 0. Composition Misfit: 7.819516E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.577 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.027 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.031194 0.023221 0.004752 0.023730 0.137149 0.011008 0.049509 0.044126 0.001711 0.159962 0.513638 Mica 0.009690 0.001049 0.000000 0.071916 0.008290 0.000000 0.006805 0.164259 0.000651 0.233121 0.504220 Gt 0.000000 0.026889 0.000000 0.000000 0.308182 0.032276 0.068470 0.000000 0.002670 0.136374 0.425139 Fsp 0.098610 0.046508 0.000000 0.003136 0.000000 0.000000 0.000000 0.000000 0.000000 0.148254 0.703492 Bio 0.000000 0.000000 0.026442 0.067356 0.183289 0.000804 0.146241 0.108271 0.003897 0.122510 0.341190 Ilm 0.000000 0.000000 0.321759 0.000000 0.587967 0.007700 0.011278 0.000000 0.071296 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775466. -756415. -932404. -842113. -315435. -471412. -639984. -295203. -409471. -1636930. -886279. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 84 converged, 61 successes so far. Misfit function evaluations this try => 536 Misfit this try = 3.566282E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 7.546010E-07 Bayes score, PP * exp(-Misfit) = 7.281640E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 6248.81 986.407 0.315875 0.872184 0.104456 0.259585 9.954078E-03 1.357411E-02 0.107856 0.504575 Final coordinates: 9110.91 947.953 0.424660 0.938147 8.473176E-03 0.615940 1.566351E-03 7.505379E-03 5.974225E-02 0.306773 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.566282E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 42.806 0.010859 0.000932 0.000000 0.087123 0.010181 0.000000 0.006913 0.280278 0.603715 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.1 0. 0. -0.2 0.2 0. 1. 1.2E-02 -0.5 Chi 2.3E-05 0. 0. 8.1E-05 9.3E-05 0. 6.4E-03 1.4E-07 2.3E-05 Composition Misfit: 7.515984E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 51.033 0.000000 0.020104 0.000000 0.000000 0.321654 0.034251 0.060008 0.137442 0.426541 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. 0.1 0. 0. 1.5E-02 -4.4E-04 -0.5 0.5 -0.2 Chi 0. 9.8E-06 0. 0. 2.2E-07 4.6E-10 4.5E-04 3.0E-04 8.3E-06 Composition Misfit: 7.686490E-04 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.036 0.100520 0.041337 0.000000 0.003812 0.000000 0.000000 0.000000 0.145668 0.708663 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.7 1. 0. -0.7 0. 0. 0. 1. -0.6 Chi 7.8E-04 2.5E-03 0. 1.6E-03 0. 0. 0. 1.6E-03 2.8E-04 Composition Misfit: 6.783606E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.010 0.000000 0.000000 0.030650 0.076161 0.226006 0.000977 0.141784 0.142417 0.382005 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -3. 0.1 2. -0.2 2. Chi 0. 0. 2.8E-03 1.1E-03 7.6E-03 2.0E-04 5.4E-03 3.1E-05 3.0E-03 Composition Misfit: 2.023408E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.792 0.000000 0.000000 0.346137 0.000000 0.635395 0.008482 0.009985 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.2 0. -0.2 0.2 2.4E-03 0. 0. Chi 0. 0. 4.3E-05 0. 4.6E-05 2.7E-04 2.2E-08 0. 0. Composition Misfit: 3.604982E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.323 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.003184 0.011895 0.019677 0.025337 0.224899 0.020267 0.037253 0.057255 0.005969 0.166530 0.427734 Mica 0.009066 0.000778 0.000000 0.072743 0.008501 0.000000 0.005772 0.164397 0.000653 0.234018 0.504072 Gt 0.000000 0.020057 0.000000 0.000000 0.320894 0.034170 0.059866 0.000000 0.002363 0.137117 0.425533 Fsp 0.100520 0.041337 0.000000 0.003812 0.000000 0.000000 0.000000 0.000000 0.000000 0.145668 0.708663 Bio 0.000000 0.000000 0.027220 0.067637 0.200711 0.000868 0.125915 0.108055 0.003866 0.126477 0.339251 Ilm 0.000000 0.000000 0.321411 0.000000 0.590005 0.007876 0.009272 0.000000 0.071436 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -777344. -759279. -933973. -843433. -315593. -471465. -641601. -296547. -412271. -1638118. -887492. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 85 converged, 62 successes so far. Misfit function evaluations this try => 532 Misfit this try = 1.01189 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 2.341530E-07 Bayes score, PP * exp(-Misfit) = 8.512164E-08 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 5994.26 891.058 0.736481 0.434197 0.719454 3.210645E-03 1.630892E-02 9.536668E-03 0.200948 5.054190E-02 Final coordinates: 9691.41 991.808 0.764559 0.453148 0.615044 5.736997E-03 4.591913E-02 0.140090 0.193047 1.630012E-04 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.01189 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.022 0.005524 0.001072 0.000000 0.092172 0.012218 0.000000 0.007008 0.277557 0.604448 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.8 0. 0. -0.6 -0.2 0. 1. 0.2 -0.6 Chi 4.2E-03 0. 0. 6.4E-04 9.2E-05 0. 6.1E-03 3.1E-05 3.3E-05 Composition Misfit: 1.220250E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.090 0.000000 0.031791 0.000000 0.000000 0.323493 0.028246 0.052788 0.137224 0.426459 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. -0.1 0.7 0.2 0.5 -0.2 Chi 0. 4.0E-03 0. 0. 7.7E-06 1.3E-03 7.6E-05 3.2E-04 7.6E-06 Composition Misfit: 5.661115E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 45.280 0.025239 0.003573 0.000000 0.097974 0.000000 0.000000 0.000000 0.126786 0.746427 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 5. 5. 0. -2.8E+01 0. 0. 0. 2. -2. Chi 0.2 0.6 0. 0.1 0. 0. 0. 9.2E-03 3.6E-03 Composition Misfit: 0.928346 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 24.682 0.000000 0.000000 0.038535 0.076677 0.237393 0.000972 0.116775 0.150153 0.379494 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -4. 0.1 4. -0.7 2. Chi 0. 0. 7.6E-03 1.2E-03 1.2E-02 2.1E-04 2.4E-02 6.4E-04 3.5E-03 Composition Misfit: 4.885692E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 9.424 0.000000 0.000000 0.411985 0.000000 0.568003 0.008123 0.011889 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -3. 0. 3. 0.3 -0.3 0. 0. Chi 0. 0. 9.3E-03 0. 6.8E-03 4.3E-04 3.0E-04 0. 0. Composition Misfit: 1.682659E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.501 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.009565 0.002248 0.063786 0.055508 0.141179 0.002103 0.031030 0.027535 0.006746 0.181181 0.479116 Mica 0.004614 0.000896 0.000000 0.076987 0.010205 0.000000 0.005854 0.164098 0.000647 0.231831 0.504868 Gt 0.000000 0.031713 0.000000 0.000000 0.322697 0.028176 0.052658 0.000000 0.002458 0.136887 0.425411 Fsp 0.025239 0.003573 0.000000 0.097974 0.000000 0.000000 0.000000 0.000000 0.000000 0.126786 0.746427 Bio 0.000000 0.000000 0.034456 0.068562 0.212268 0.000869 0.104416 0.102667 0.003170 0.134262 0.339330 Ilm 0.000000 0.000000 0.394618 0.000000 0.544060 0.007781 0.011388 0.000000 0.042153 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -787899. -760006. -937563. -843491. -320345. -478454. -646461. -302993. -420239. -1644149. -891082. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio ab the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio ab -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 87 converged, 63 successes so far. Misfit function evaluations this try => 268 Misfit this try = 2.595503E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 3.055095E-07 Bayes score, PP * exp(-Misfit) = 2.976820E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 9270.42 989.970 0.463689 0.340815 0.200981 7.572384E-02 0.167332 1.145001E-03 5.978774E-03 0.548840 Final coordinates: 9778.53 984.363 0.686337 0.623815 0.130404 5.636158E-02 0.711287 1.736441E-03 1.043452E-02 8.977626E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.595503E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 22.105 0.011404 0.001745 0.000000 0.085994 0.010653 0.000000 0.008351 0.278393 0.603460 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.1 0. 0.8 0.1 -0.4 Chi 9.6E-05 0. 0. 2.7E-05 2.4E-05 0. 3.2E-03 1.6E-05 2.0E-05 Composition Misfit: 5.159825E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.022 0.000000 0.026772 0.000000 0.000000 0.304637 0.032103 0.074023 0.136338 0.426127 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.8 0. 0. 1. 0.2 -2. 0.5 -0.2 Chi 0. 1.4E-03 0. 0. 9.8E-04 1.4E-04 5.0E-03 4.1E-04 5.1E-06 Composition Misfit: 7.982928E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 69.183 0.095254 0.052442 0.000000 0.003525 0.000000 0.000000 0.000000 0.151221 0.697558 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.1 0. -0.6 0. 0. 0. 0.7 -0.1 Chi 1.4E-04 1.4E-05 0. 1.3E-03 0. 0. 0. 6.2E-04 1.3E-05 Composition Misfit: 2.114909E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.103 0.000000 0.000000 0.030979 0.076115 0.204588 0.001047 0.163192 0.141718 0.382361 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.1 0.4 -0.1 2. Chi 0. 0. 3.0E-03 1.1E-03 2.0E-03 1.4E-04 2.5E-04 1.4E-05 3.0E-03 Composition Misfit: 9.408850E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.675 0.000000 0.000000 0.343661 0.000000 0.633407 0.009096 0.013836 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.3 0. -0.2 0.1 -0.6 0. 0. Chi 0. 0. 1.2E-04 0. 1.8E-05 9.0E-05 1.1E-03 0. 0. Composition Misfit: 1.288516E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.035 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 0.877 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.064839 0.036381 0.003545 0.018911 0.026422 0.001958 0.006217 0.037867 0.001133 0.177352 0.625375 Mica 0.009524 0.001458 0.000000 0.071817 0.008897 0.000000 0.006974 0.164141 0.000715 0.232498 0.503977 Gt 0.000000 0.026696 0.000000 0.000000 0.303770 0.032012 0.073813 0.000000 0.002844 0.135950 0.424915 Fsp 0.095254 0.052442 0.000000 0.003525 0.000000 0.000000 0.000000 0.000000 0.000000 0.151221 0.697558 Bio 0.000000 0.000000 0.027522 0.067621 0.181757 0.000931 0.144981 0.107720 0.003875 0.125903 0.339691 Ilm 0.000000 0.000000 0.318745 0.000000 0.587484 0.008437 0.012833 0.000000 0.072502 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -784184. -760182. -936854. -850712. -319937. -476306. -643062. -298037. -410845. -1642706. -890036. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 88 converged, 64 successes so far. Misfit function evaluations this try => 183 Misfit this try = 2.433358E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 5.871748E-07 Bayes score, PP * exp(-Misfit) = 5.730592E-07 Best Bayes score so far = 1.157288E-06 obtained on Try 33 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 10088.3 968.832 0.101379 7.115930E-02 7.549572E-03 6.993446E-03 0.239653 1.581748E-03 2.507023E-03 0.741715 Final coordinates: 9458.47 961.259 0.702170 0.136659 2.999009E-02 1.610452E-02 0.914632 8.418285E-03 4.656848E-03 2.619834E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.433358E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.091 0.011946 0.001684 0.000000 0.085584 0.009950 0.000000 0.007937 0.279666 0.603235 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.3 0. 0. -0.1 0.2 0. 0.8 4.8E-02 -0.4 Chi 2.1E-04 0. 0. 1.5E-05 1.5E-04 0. 4.0E-03 2.4E-06 1.7E-05 Composition Misfit: 6.039348E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.127 0.000000 0.028740 0.000000 0.000000 0.305669 0.033203 0.069736 0.136474 0.426178 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 0.9 0.1 -1. 0.5 -0.2 Chi 0. 2.3E-03 0. 0. 8.6E-04 3.3E-05 3.2E-03 4.0E-04 5.4E-06 Composition Misfit: 6.835585E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 89.019 0.095326 0.053328 0.000000 0.003010 0.000000 0.000000 0.000000 0.151664 0.696672 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.2 0. -0.5 0. 0. 0. 0.6 -0.1 Chi 1.4E-04 5.6E-05 0. 9.1E-04 0. 0. 0. 5.6E-04 6.8E-06 Composition Misfit: 1.673452E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.891 0.000000 0.000000 0.029809 0.076015 0.206309 0.000986 0.163550 0.140228 0.383103 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.1 0.4 6.1E-03 2. Chi 0. 0. 2.4E-03 1.1E-03 2.3E-03 1.9E-04 2.2E-04 5.2E-08 2.8E-03 Composition Misfit: 9.011812E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.278 0.000000 0.000000 0.347827 0.000000 0.630481 0.008878 0.012813 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. -2.2E-02 0.2 -0.4 0. 0. Chi 0. 0. 1.4E-05 0. 3.7E-07 1.4E-04 6.2E-04 0. 0. Composition Misfit: 7.733860E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.353 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.242 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.083662 0.047102 0.001794 0.006493 0.010207 0.000605 0.003090 0.008381 0.000448 0.164949 0.673269 Mica 0.009975 0.001406 0.000000 0.071466 0.008309 0.000000 0.006627 0.164288 0.000667 0.233533 0.503728 Gt 0.000000 0.028660 0.000000 0.000000 0.304818 0.033110 0.069542 0.000000 0.002785 0.136094 0.424991 Fsp 0.095326 0.053328 0.000000 0.003010 0.000000 0.000000 0.000000 0.000000 0.000000 0.151664 0.696672 Bio 0.000000 0.000000 0.026459 0.067473 0.183124 0.000875 0.145170 0.108486 0.003895 0.124469 0.340049 Ilm 0.000000 0.000000 0.323233 0.000000 0.585902 0.008251 0.011907 0.000000 0.070707 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -780105. -757640. -934509. -847309. -317356. -473235. -641377. -296150. -410452. -1639551. -888173. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 89 converged, 65 successes so far. Misfit function evaluations this try => 526 Misfit this try = 2.459027E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 1.193898E-06 Bayes score, PP * exp(-Misfit) = 1.164898E-06 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 5586.99 826.896 0.197986 0.932124 3.868564E-02 1.574510E-02 0.456269 7.761423E-02 2.742434E-02 0.384262 Final coordinates: 9169.80 906.783 0.204150 0.580154 2.467974E-02 0.192319 0.606431 3.776646E-03 1.993217E-03 0.170800 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.459027E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.589 0.011279 0.001102 0.000000 0.086637 0.008996 0.000000 0.007728 0.280623 0.603635 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.1 0. 0. -0.2 0.3 0. 0.8 -8.5E-03 -0.5 Chi 7.5E-05 0. 0. 5.5E-05 5.2E-04 0. 4.4E-03 7.5E-08 2.2E-05 Composition Misfit: 6.151145E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 14.188 0.000000 0.034170 0.000000 0.000000 0.309952 0.032518 0.060466 0.136650 0.426244 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 0.7 0.2 -0.5 0.5 -0.2 Chi 0. 5.4E-03 0. 0. 4.6E-04 9.2E-05 5.3E-04 3.8E-04 5.9E-06 Composition Misfit: 6.899893E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 60.200 0.097729 0.049484 0.000000 0.002529 0.000000 0.000000 0.000000 0.149742 0.700516 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.5 0.2 0. -0.3 0. 0. 0. 0.8 -0.3 Chi 3.8E-04 9.0E-05 0. 5.4E-04 0. 0. 0. 8.3E-04 5.2E-05 Composition Misfit: 1.893017E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.072 0.000000 0.000000 0.028344 0.075651 0.208834 0.000763 0.165736 0.134768 0.385904 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.9 -1. -2. 0.2 0.3 0.4 2. Chi 0. 0. 1.7E-03 1.0E-03 2.8E-03 5.7E-04 8.6E-05 2.3E-04 2.3E-03 Composition Misfit: 8.787301E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.143 0.000000 0.000000 0.352049 0.000000 0.629959 0.007511 0.010482 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.1 0. 1.9E-03 0.4 -0.1 0. 0. Chi 0. 0. 1.2E-05 0. 2.7E-09 8.2E-04 2.2E-05 0. 0. Composition Misfit: 8.589111E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.913 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 0.895 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.055521 0.033966 0.000750 0.016951 0.063656 0.006373 0.013345 0.035349 0.000812 0.174062 0.599215 Mica 0.009418 0.000920 0.000000 0.072341 0.007511 0.000000 0.006453 0.164436 0.000582 0.234315 0.504024 Gt 0.000000 0.034077 0.000000 0.000000 0.309113 0.032429 0.060303 0.000000 0.002708 0.136280 0.425090 Fsp 0.097729 0.049484 0.000000 0.002529 0.000000 0.000000 0.000000 0.000000 0.000000 0.149742 0.700516 Bio 0.000000 0.000000 0.025141 0.067102 0.185235 0.000677 0.147007 0.109064 0.003941 0.119539 0.342295 Ilm 0.000000 0.000000 0.327799 0.000000 0.586567 0.006994 0.009760 0.000000 0.068880 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -768119. -751254. -928139. -834391. -310951. -466457. -637041. -292400. -408373. -1631369. -882873. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 90 converged, 66 successes so far. Misfit function evaluations this try => 764 Misfit this try = 2.832498E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 1.723530E-07 Bayes score, PP * exp(-Misfit) = 1.675396E-07 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 7559.24 901.734 0.713273 0.432223 1.584049E-02 0.763532 6.876867E-03 0.151627 1.256761E-02 4.955598E-02 Final coordinates: 9968.14 999.992 0.895806 0.746314 1.702637E-07 3.124586E-02 0.679273 4.355421E-03 1.050339E-02 0.274622 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.832498E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.596 0.009731 0.001575 0.000000 0.087661 0.011385 0.000000 0.008639 0.277121 0.603888 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.1 0. 0. -0.3 -3.5E-02 0. 0.7 0.2 -0.5 Chi 4.0E-05 0. 0. 1.2E-04 4.6E-06 0. 2.8E-03 4.1E-05 2.5E-05 Composition Misfit: 4.589306E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.991 0.000000 0.025866 0.000000 0.000000 0.302043 0.035128 0.074596 0.136267 0.426100 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.7 0. 0. 1. -0.1 -2. 0.5 -0.2 Chi 0. 1.1E-03 0. 0. 1.3E-03 2.2E-05 5.3E-03 4.2E-04 4.9E-06 Composition Misfit: 8.104836E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 66.378 0.094523 0.051967 0.000000 0.004493 0.000000 0.000000 0.000000 0.150983 0.698033 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.2 -3.6E-02 0. -0.9 0. 0. 0. 0.7 -0.2 Chi 8.7E-05 2.7E-06 0. 2.2E-03 0. 0. 0. 6.5E-04 1.8E-05 Composition Misfit: 2.946524E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.056 0.000000 0.000000 0.032789 0.076239 0.205375 0.001226 0.159367 0.143579 0.381426 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.1 0.7 -0.2 2. Chi 0. 0. 4.0E-03 1.1E-03 2.1E-03 3.2E-05 6.5E-04 7.4E-05 3.1E-03 Composition Misfit: 1.111547E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.625 0.000000 0.000000 0.339704 0.000000 0.635846 0.010352 0.014098 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.6 0. -0.3 -0.1 -0.7 0. 0. Chi 0. 0. 3.1E-04 0. 5.4E-05 1.2E-05 1.2E-03 0. 0. Composition Misfit: 1.568848E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.582 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 0.771 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.062086 0.034037 0.003595 0.023279 0.019592 0.001127 0.005985 0.045200 0.001097 0.182561 0.621442 Mica 0.008128 0.001316 0.000000 0.073217 0.009509 0.000000 0.007216 0.164006 0.000760 0.231461 0.504388 Gt 0.000000 0.025791 0.000000 0.000000 0.301174 0.035027 0.074382 0.000000 0.002875 0.135876 0.424875 Fsp 0.094523 0.051967 0.000000 0.004493 0.000000 0.000000 0.000000 0.000000 0.000000 0.150983 0.698033 Bio 0.000000 0.000000 0.029171 0.067827 0.182714 0.001091 0.141783 0.106482 0.003855 0.127737 0.339341 Ilm 0.000000 0.000000 0.314498 0.000000 0.588666 0.009584 0.013052 0.000000 0.074201 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -787207. -761920. -938506. -851426. -321774. -477499. -644482. -300128. -410980. -1644936. -891381. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 92 converged, 67 successes so far. Misfit function evaluations this try => 475 Misfit this try = 0.922011 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 1.857491E-07 Bayes score, PP * exp(-Misfit) = 7.387582E-08 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 14444.0 983.752 0.912037 0.264564 0.824910 5.977817E-03 6.772710E-03 6.277034E-03 0.142000 1.406248E-02 Final coordinates: 8694.39 994.566 0.921104 0.778839 0.897614 3.166040E-02 3.942705E-02 4.176336E-03 2.706510E-02 5.715662E-05 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.922011 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.641 0.005281 0.001285 0.000000 0.092451 0.011190 0.000000 0.006940 0.279504 0.603350 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.8 0. 0. -0.7 -5.3E-03 0. 1. 0.1 -0.4 Chi 4.9E-03 0. 0. 6.9E-04 1.1E-07 0. 6.3E-03 3.4E-06 1.9E-05 Composition Misfit: 1.316794E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.690 0.000000 0.031544 0.000000 0.000000 0.282122 0.067178 0.056748 0.136297 0.426111 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -4. -0.2 0.5 -0.2 Chi 0. 3.8E-03 0. 0. 5.6E-03 1.6E-02 6.7E-05 4.2E-04 5.0E-06 Composition Misfit: 2.607981E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 48.474 0.023767 0.004139 0.000000 0.099163 0.000000 0.000000 0.000000 0.127070 0.745861 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -2.8E+01 0. 0. 0. 2. -2. Chi 0.2 0.5 0. 0.1 0. 0. 0. 9.0E-03 3.5E-03 Composition Misfit: 0.846988 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.939 0.000000 0.000000 0.037298 0.076854 0.220627 0.002431 0.133444 0.152808 0.376538 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -2. -0.3 2. -0.9 2. Chi 0. 0. 6.8E-03 1.3E-03 5.9E-03 4.2E-04 9.8E-03 1.0E-03 4.1E-03 Composition Misfit: 2.931922E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.058 0.000000 0.000000 0.330624 0.000000 0.638282 0.020182 0.010912 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 1. 0. -0.4 -2. -0.1 0. 0. Chi 0. 0. 1.1E-03 0. 1.1E-04 5.1E-03 7.6E-05 0. 0. Composition Misfit: 6.455955E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.198 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.011350 0.002360 0.008405 0.066940 0.033427 0.001196 0.013074 0.046595 0.001924 0.231412 0.583317 Mica 0.004409 0.001073 0.000000 0.077191 0.009343 0.000000 0.005794 0.164274 0.000780 0.233371 0.503765 Gt 0.000000 0.031454 0.000000 0.000000 0.281314 0.066986 0.056585 0.000000 0.002862 0.135906 0.424892 Fsp 0.023767 0.004139 0.000000 0.099163 0.000000 0.000000 0.000000 0.000000 0.000000 0.127070 0.745861 Bio 0.000000 0.000000 0.033280 0.068575 0.196861 0.002169 0.119070 0.103870 0.003851 0.136347 0.335977 Ilm 0.000000 0.000000 0.304811 0.000000 0.588447 0.018606 0.010060 0.000000 0.078076 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -794218. -761923. -940451. -849808. -322747. -472688. -647040. -304349. -411835. -1646774. -893691. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 93 converged, 68 successes so far. Misfit function evaluations this try => 489 Misfit this try = 0.923248 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 1.588027E-07 Bayes score, PP * exp(-Misfit) = 6.308070E-08 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 13245.0 855.660 0.850278 0.223085 6.147751E-03 0.253784 5.948395E-03 0.187059 1.333987E-03 0.545726 Final coordinates: 8329.94 996.398 0.913343 0.446557 5.065821E-03 0.145787 3.368084E-02 2.203357E-02 7.114671E-02 0.722287 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.923248 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.106 0.005126 0.001396 0.000000 0.092632 0.011698 0.000000 0.005624 0.280617 0.602908 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.8 0. 0. -0.7 -0.1 0. 1. -8.1E-03 -0.4 Chi 5.3E-03 0. 0. 7.2E-04 2.5E-05 0. 1.1E-02 6.9E-08 1.4E-05 Composition Misfit: 1.865539E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.504 0.000000 0.031876 0.000000 0.000000 0.304825 0.054145 0.046709 0.136323 0.426121 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -2. 0.8 0.5 -0.2 Chi 0. 4.0E-03 0. 0. 9.6E-04 7.3E-03 1.4E-03 4.1E-04 5.0E-06 Composition Misfit: 1.411576E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 47.975 0.022860 0.004411 0.000000 0.099935 0.000000 0.000000 0.000000 0.127205 0.745589 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -2.9E+01 0. 0. 0. 2. -2. Chi 0.2 0.5 0. 0.1 0. 0. 0. 8.9E-03 3.5E-03 Composition Misfit: 0.821415 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.069 0.000000 0.000000 0.037176 0.077098 0.245196 0.001966 0.107362 0.156464 0.374738 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -4. -0.2 4. -1. 2. Chi 0. 0. 6.7E-03 1.3E-03 1.5E-02 1.5E-04 3.6E-02 1.7E-03 4.5E-03 Composition Misfit: 6.542774E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.656 0.000000 0.000000 0.330445 0.000000 0.645738 0.015298 0.008519 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 1. 0. -0.7 -0.8 0.2 0. 0. Chi 0. 0. 1.2E-03 0. 3.8E-04 1.8E-03 2.6E-04 0. 0. Composition Misfit: 3.633377E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.691 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.009690 0.004318 0.023148 0.057436 0.094821 0.005233 0.020334 0.027458 0.005413 0.213019 0.539129 Mica 0.004279 0.001165 0.000000 0.077332 0.009766 0.000000 0.004695 0.164387 0.000783 0.234267 0.503326 Gt 0.000000 0.031785 0.000000 0.000000 0.303956 0.053991 0.046576 0.000000 0.002850 0.135935 0.424907 Fsp 0.022860 0.004411 0.000000 0.099935 0.000000 0.000000 0.000000 0.000000 0.000000 0.127205 0.745589 Bio 0.000000 0.000000 0.033156 0.068760 0.218679 0.001754 0.095751 0.104364 0.003782 0.139543 0.334212 Ilm 0.000000 0.000000 0.304620 0.000000 0.595272 0.014103 0.007853 0.000000 0.078152 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -796978. -762591. -942053. -852275. -322628. -475020. -649069. -304919. -415497. -1647872. -894742. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 95 converged, 69 successes so far. Misfit function evaluations this try => 324 Misfit this try = 5.174729E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 1.944785E-07 Bayes score, PP * exp(-Misfit) = 1.846707E-07 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 6581.78 814.795 0.674309 0.141060 0.708450 2.675386E-02 3.467079E-02 4.012529E-02 1.829685E-02 0.171703 Final coordinates: 7846.04 813.172 0.915964 0.563018 2.391334E-02 4.093227E-03 0.635707 0.237048 7.479739E-02 2.444179E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.174729E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.626 0.011772 0.000743 0.000000 0.086694 0.006249 0.000000 0.006358 0.285258 0.602926 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.2 0.8 0. 1. -0.3 -0.4 Chi 1.7E-04 0. 0. 5.7E-05 3.9E-03 0. 8.1E-03 8.0E-05 1.4E-05 Composition Misfit: 1.304254E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.805 0.000000 0.051435 0.000000 0.000000 0.297112 0.044484 0.044035 0.136679 0.426255 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -4. 0. 0. 1. -1. 1. 0.5 -0.2 Chi 0. 1.9E-02 0. 0. 2.1E-03 2.4E-03 2.6E-03 3.7E-04 6.0E-06 Composition Misfit: 2.598441E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 63.845 0.096858 0.053525 0.000000 0.001380 0.000000 0.000000 0.000000 0.151762 0.696475 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.4 -0.2 0. -6.5E-03 0. 0. 0. 0.6 -0.1 Chi 2.8E-04 7.0E-05 0. 3.6E-07 0. 0. 0. 5.5E-04 5.6E-06 Composition Misfit: 9.052398E-04 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.906 0.000000 0.000000 0.024258 0.075090 0.207349 0.000652 0.176210 0.126348 0.390094 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.4 -1. -2. 0.2 -0.5 1. 1. Chi 0. 0. 3.4E-04 8.8E-04 2.5E-03 9.1E-04 2.5E-04 1.5E-03 1.7E-03 Composition Misfit: 8.175866E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.541 0.000000 0.000000 0.376609 0.000000 0.607183 0.008300 0.007907 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 1. 0.3 0.3 0. 0. Chi 0. 0. 1.9E-03 0. 8.6E-04 3.5E-04 5.5E-04 0. 0. Composition Misfit: 3.639233E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.480 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.798 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.056479 0.031605 0.030030 0.020009 0.089104 0.001178 0.040185 0.033777 0.005101 0.143875 0.548658 Mica 0.009825 0.000620 0.000000 0.072355 0.005216 0.000000 0.005306 0.164981 0.000410 0.238079 0.503207 Gt 0.000000 0.051296 0.000000 0.000000 0.296311 0.044364 0.043917 0.000000 0.002696 0.136311 0.425106 Fsp 0.096858 0.053525 0.000000 0.001380 0.000000 0.000000 0.000000 0.000000 0.000000 0.151762 0.696475 Bio 0.000000 0.000000 0.021457 0.066421 0.183411 0.000577 0.155867 0.111385 0.004063 0.111761 0.345058 Ilm 0.000000 0.000000 0.354724 0.000000 0.571899 0.007818 0.007448 0.000000 0.058110 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -752598. -741431. -919276. -819630. -301557. -453633. -630668. -286410. -406345. -1620041. -876210. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 96 converged, 70 successes so far. Misfit function evaluations this try => 330 Misfit this try = 2.958168E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 8.764941E-07 Bayes score, PP * exp(-Misfit) = 8.509457E-07 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 5893.90 930.002 0.911440 6.553026E-02 5.021422E-02 0.134363 0.260892 3.400445E-03 0.101697 0.449433 Final coordinates: 9001.86 938.320 0.926792 0.187081 5.412132E-02 0.260442 0.577756 2.392006E-03 8.634490E-02 1.894436E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.958168E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.461 0.010159 0.001151 0.000000 0.087712 0.009935 0.000000 0.007147 0.280389 0.603507 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 3.1E-02 0. 0. -0.3 0.2 0. 0.9 5.2E-03 -0.4 Chi 3.9E-06 0. 0. 1.2E-04 1.5E-04 0. 5.7E-03 2.9E-08 2.0E-05 Composition Misfit: 7.174480E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.232 0.000000 0.027796 0.000000 0.000000 0.314716 0.035106 0.059194 0.136863 0.426324 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.9 0. 0. 0.4 -0.1 -0.4 0.5 -0.2 Chi 0. 1.9E-03 0. 0. 1.6E-04 2.1E-05 3.3E-04 3.6E-04 6.5E-06 Composition Misfit: 2.764701E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 62.677 0.096287 0.050689 0.000000 0.003369 0.000000 0.000000 0.000000 0.150345 0.699311 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.4 0.1 0. -0.6 0. 0. 0. 0.7 -0.2 Chi 2.2E-04 1.6E-05 0. 1.2E-03 0. 0. 0. 7.4E-04 3.3E-05 Composition Misfit: 2.213474E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.011 0.000000 0.000000 0.030264 0.076091 0.221313 0.000962 0.147580 0.141369 0.382421 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -2. 0.1 1. -0.1 2. Chi 0. 0. 2.6E-03 1.1E-03 6.1E-03 2.2E-04 3.3E-03 7.9E-06 2.9E-03 Composition Misfit: 1.627627E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.415 0.000000 0.000000 0.336407 0.000000 0.645208 0.008561 0.009824 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.7 0. -0.7 0.2 2.8E-02 0. 0. Chi 0. 0. 5.5E-04 0. 3.6E-04 2.4E-04 3.1E-06 0. 0. Composition Misfit: 1.152750E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.280 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 0.924 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.052661 0.034476 0.029682 0.006977 0.136776 0.009595 0.016207 0.011568 0.007923 0.148300 0.545835 Mica 0.008483 0.000961 0.000000 0.073236 0.008295 0.000000 0.005967 0.164398 0.000649 0.234111 0.503900 Gt 0.000000 0.027723 0.000000 0.000000 0.313893 0.035015 0.059040 0.000000 0.002616 0.136505 0.425209 Fsp 0.096287 0.050689 0.000000 0.003369 0.000000 0.000000 0.000000 0.000000 0.000000 0.150345 0.699311 Bio 0.000000 0.000000 0.026869 0.067556 0.196488 0.000854 0.131026 0.108243 0.003928 0.125511 0.339524 Ilm 0.000000 0.000000 0.310971 0.000000 0.596422 0.007914 0.009081 0.000000 0.075612 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776478. -756180. -932846. -841655. -314723. -470159. -640667. -295823. -410894. -1636786. -886680. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 97 converged, 71 successes so far. Misfit function evaluations this try => 545 Misfit this try = 2.61362 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 5.198472E-07 Bayes score, PP * exp(-Misfit) = 3.808860E-08 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 11438.9 812.578 4.821374E-02 0.594977 1.764197E-02 5.208901E-03 2.101368E-02 0.194334 0.414061 0.347740 Final coordinates: 7012.75 869.843 1.601939E-02 0.869253 3.236893E-03 2.478730E-03 1.438129E-02 8.202648E-05 9.227628E-02 0.887545 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.61362 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 22.061 0.006596 0.000436 0.000000 0.092174 0.006380 0.000000 0.003778 0.287061 0.603575 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.6 0. 0. -0.6 0.7 0. 1. -0.4 -0.5 Chi 2.1E-03 0. 0. 6.5E-04 3.6E-03 0. 2.5E-02 1.5E-04 2.1E-05 Composition Misfit: 3.222189E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.431 0.000000 0.021560 0.000000 0.000000 0.332431 0.046433 0.028319 0.142733 0.428525 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.1 0. 0. -0.6 -1. 3. 0.1 -0.5 Chi 0. 4.7E-05 0. 0. 3.3E-04 3.2E-03 2.5E-02 8.5E-06 3.5E-05 Composition Misfit: 2.837403E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 42.969 0.021238 0.001278 0.000000 0.103123 0.000000 0.000000 0.000000 0.125639 0.748722 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -2.9E+01 0. 0. 0. 2. -2. Chi 0.2 2. 0. 0.1 0. 0. 0. 9.9E-03 3.9E-03 Composition Misfit: 2.32903 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 12.593 0.000000 0.000000 0.035784 0.077056 0.266433 0.000956 0.080682 0.155834 0.383255 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -5. 0.1 6. -1. 2. Chi 0. 0. 5.8E-03 1.3E-03 2.5E-02 2.3E-04 0.1 1.5E-03 2.8E-03 Composition Misfit: 0.134719 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.237 0.000000 0.000000 0.498429 0.000000 0.484817 0.010029 0.006725 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -8. 0. 7. -4.6E-03 0.5 0. 0. Chi 0. 0. 4.4E-02 0. 4.3E-02 8.2E-08 1.6E-03 0. 0. Composition Misfit: 8.927183E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.710 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.009272 0.000697 0.028400 0.066179 0.060570 0.000886 0.011553 0.052278 0.000061 0.222048 0.548056 Mica 0.005506 0.000364 0.000000 0.076940 0.005325 0.000000 0.003154 0.165256 0.000016 0.239618 0.503821 Gt 0.000000 0.021558 0.000000 0.000000 0.332413 0.046430 0.028317 0.000000 0.000054 0.142725 0.428501 Fsp 0.021238 0.001278 0.000000 0.103123 0.000000 0.000000 0.000000 0.000000 0.000000 0.125639 0.748722 Bio 0.000000 0.000000 0.031994 0.068893 0.238210 0.000855 0.072136 0.105793 0.000134 0.139327 0.342658 Ilm 0.000000 0.000000 0.498037 0.000000 0.484437 0.010021 0.006720 0.000000 0.000785 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -769059. -752695. -926789. -829290. -307682. -461044. -640538. -295501. -518246. -1630296. -883899. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 98 converged, 72 successes so far. Misfit function evaluations this try => 538 Misfit this try = 1.28473 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 4.917505E-07 Bayes score, PP * exp(-Misfit) = 1.360798E-07 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 8979.97 813.347 0.695432 0.680436 6.894165E-02 0.119796 7.946893E-02 3.550109E-02 0.313317 0.382975 Final coordinates: 7172.70 939.488 0.311979 0.605723 2.943627E-02 0.195973 8.336375E-04 0.121175 3.054844E-02 0.622034 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.28226 Extraneous predicted phases: 2.471363E-3 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.018 0.004974 0.001095 0.000000 0.093181 0.009676 0.000000 0.004939 0.283676 0.602460 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.8 0. 0. -0.7 0.2 0. 1. -0.2 -0.3 Chi 5.8E-03 0. 0. 8.2E-04 2.3E-04 0. 1.5E-02 3.6E-05 1.0E-05 Composition Misfit: 2.301358E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.001 0.000000 0.034097 0.000000 0.000000 0.289506 0.073183 0.040039 0.136855 0.426321 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -4. 1. 0.5 -0.2 Chi 0. 5.4E-03 0. 0. 3.6E-03 2.1E-02 5.4E-03 3.6E-04 6.5E-06 Composition Misfit: 3.552889E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 39.406 0.019228 0.003096 0.000000 0.104223 0.000000 0.000000 0.000000 0.126548 0.746904 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -3.0E+01 0. 0. 0. 2. -2. Chi 0.3 0.8 0. 0.1 0. 0. 0. 9.3E-03 3.7E-03 Composition Misfit: 1.14691 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 32.578 0.000000 0.000000 0.035015 0.077054 0.246442 0.002147 0.108761 0.155815 0.374766 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -4. -0.2 4. -1. 2. Chi 0. 0. 5.3E-03 1.3E-03 1.6E-02 2.4E-04 3.4E-02 1.5E-03 4.5E-03 Composition Misfit: 6.247722E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.272 0.000000 0.000000 0.306201 0.000000 0.669021 0.018350 0.006428 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 2. 0. -2. -1. 0.6 0. 0. Chi 0. 0. 6.3E-03 0. 2.3E-03 3.8E-03 2.0E-03 0. 0. Composition Misfit: 1.432602E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.693 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Ilm 0.031 0.000000 0.000000 0.234400 0.000000 0.639432 0.015140 0.004788 0.000000 0.106240 0.000000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.006407 0.003821 0.012467 0.059270 0.105095 0.006749 0.037934 0.037950 0.002049 0.214076 0.514183 Mica 0.004151 0.000914 0.000000 0.077766 0.008075 0.000000 0.004122 0.164748 0.000683 0.236748 0.502795 Gt 0.000000 0.034007 0.000000 0.000000 0.288748 0.072992 0.039934 0.000000 0.002619 0.136496 0.425204 Fsp 0.019228 0.003096 0.000000 0.104223 0.000000 0.000000 0.000000 0.000000 0.000000 0.126548 0.746904 Bio 0.000000 0.000000 0.031166 0.068585 0.219353 0.001911 0.096806 0.106003 0.003916 0.138688 0.333572 Ilm 0.000000 0.000000 0.279151 0.000000 0.609920 0.016729 0.005860 0.000000 0.088340 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -788711. -757638. -936948. -844808. -317065. -466391. -645119. -301269. -413239. -1640934. -891012. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 99 converged, 73 successes so far. Misfit function evaluations this try => 227 Misfit this try = 2.394943E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 8.346972E-07 Bayes score, PP * exp(-Misfit) = 8.149442E-07 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 10417.0 949.667 0.286202 0.533809 0.531043 4.781262E-03 0.344125 5.946707E-03 1.739995E-02 9.670414E-02 Final coordinates: 9376.80 944.226 0.621198 0.649290 3.600940E-02 2.106061E-02 0.710978 7.322000E-02 9.678198E-03 0.149054 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.394943E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.476 0.011788 0.001535 0.000000 0.085842 0.009500 0.000000 0.008066 0.279927 0.603344 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.3 0. 0.8 3.2E-02 -0.4 Chi 1.7E-04 0. 0. 2.2E-05 2.9E-04 0. 3.7E-03 1.1E-06 1.9E-05 Composition Misfit: 5.761567E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.367 0.000000 0.031159 0.000000 0.000000 0.300442 0.037311 0.068452 0.136463 0.426174 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.3 -1. 0.5 -0.2 Chi 0. 3.6E-03 0. 0. 1.5E-03 2.5E-04 2.7E-03 4.0E-04 5.4E-06 Composition Misfit: 8.528506E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 68.736 0.095631 0.053133 0.000000 0.002803 0.000000 0.000000 0.000000 0.151566 0.696867 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.1 0. -0.4 0. 0. 0. 0.6 -0.1 Chi 1.7E-04 4.4E-05 0. 7.5E-04 0. 0. 0. 5.7E-04 8.0E-06 Composition Misfit: 1.537639E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.232 0.000000 0.000000 0.029310 0.075881 0.202227 0.001034 0.169225 0.138210 0.384113 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.1 2.0E-02 0.2 2. Chi 0. 0. 2.2E-03 1.1E-03 1.6E-03 1.5E-04 5.0E-07 3.2E-05 2.6E-03 Composition Misfit: 7.580879E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.479 0.000000 0.000000 0.347843 0.000000 0.629883 0.009721 0.012554 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. 5.4E-03 4.4E-02 -0.4 0. 0. Chi 0. 0. 1.3E-05 0. 2.2E-08 8.0E-06 5.2E-04 0. 0. Composition Misfit: 5.408426E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.235 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.475 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.064378 0.035622 0.004753 0.020633 0.027304 0.000885 0.015519 0.039185 0.001060 0.172375 0.618286 Mica 0.009843 0.001281 0.000000 0.071680 0.007933 0.000000 0.006735 0.164329 0.000641 0.233747 0.503810 Gt 0.000000 0.031072 0.000000 0.000000 0.299604 0.037206 0.068261 0.000000 0.002790 0.136082 0.424985 Fsp 0.095631 0.053133 0.000000 0.002803 0.000000 0.000000 0.000000 0.000000 0.000000 0.151566 0.696867 Bio 0.000000 0.000000 0.026010 0.067337 0.179459 0.000918 0.150172 0.108665 0.003923 0.122649 0.340866 Ilm 0.000000 0.000000 0.323250 0.000000 0.585350 0.009034 0.011666 0.000000 0.070700 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776394. -755415. -932340. -843356. -315502. -470145. -639803. -294872. -409027. -1636933. -886471. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 100 converged, 74 successes so far. Misfit function evaluations this try => 625 Misfit this try = 0.896404 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 1.464108E-07 Bayes score, PP * exp(-Misfit) = 5.974061E-08 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 13902.6 827.136 0.942592 0.928619 0.157988 0.112603 0.309718 0.164198 1.408144E-02 0.241412 Final coordinates: 8438.12 999.190 0.983620 0.929221 6.685787E-02 0.122214 5.865745E-05 0.190236 0.132805 0.487829 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.896404 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 12.073 0.005159 0.001397 0.000000 0.092571 0.011313 0.000000 0.006262 0.280264 0.603034 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.8 0. 0. -0.7 -2.4E-02 0. 1. 1.3E-02 -0.4 Chi 5.2E-03 0. 0. 7.1E-04 2.2E-06 0. 8.5E-03 1.6E-07 1.5E-05 Composition Misfit: 1.583545E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.122 0.000000 0.031447 0.000000 0.000000 0.289090 0.064694 0.052200 0.136413 0.426155 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 2. -3. 0.2 0.5 -0.2 Chi 0. 3.8E-03 0. 0. 3.7E-03 1.4E-02 1.3E-04 4.0E-04 5.3E-06 Composition Misfit: 2.237295E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.988 0.023205 0.004453 0.000000 0.099568 0.000000 0.000000 0.000000 0.127226 0.745547 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -2.8E+01 0. 0. 0. 2. -2. Chi 0.2 0.5 0. 0.1 0. 0. 0. 8.9E-03 3.5E-03 Composition Misfit: 0.810278 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 36.031 0.000000 0.000000 0.037557 0.077026 0.231002 0.002386 0.121299 0.155386 0.375344 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -3. -0.3 3. -1. 2. Chi 0. 0. 7.0E-03 1.3E-03 9.4E-03 3.9E-04 1.9E-02 1.5E-03 4.4E-03 Composition Misfit: 4.307833E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.326 0.000000 0.000000 0.344381 0.000000 0.625639 0.019602 0.010378 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.3 0. 0.2 -2. -0.1 0. 0. Chi 0. 0. 9.2E-05 0. 3.0E-05 4.7E-03 1.4E-05 0. 0. Composition Misfit: 4.839628E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.453 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 0.007 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.005365 0.002345 0.047151 0.055583 0.153253 0.005396 0.044576 0.057767 0.009421 0.186430 0.432714 Mica 0.004307 0.001166 0.000000 0.077285 0.009445 0.000000 0.005228 0.164350 0.000775 0.233986 0.503457 Gt 0.000000 0.031359 0.000000 0.000000 0.288278 0.064512 0.052053 0.000000 0.002811 0.136030 0.424957 Fsp 0.023205 0.004453 0.000000 0.099568 0.000000 0.000000 0.000000 0.000000 0.000000 0.127226 0.745547 Bio 0.000000 0.000000 0.033512 0.068729 0.206119 0.002129 0.108233 0.103946 0.003770 0.138648 0.334913 Ilm 0.000000 0.000000 0.319519 0.000000 0.580473 0.018187 0.009628 0.000000 0.072192 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -797053. -762795. -941738. -852368. -323325. -473831. -648400. -305046. -414157. -1648111. -894812. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 101 converged, 75 successes so far. Misfit function evaluations this try => 508 Misfit this try = 0.894941 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 1.642610E-07 Bayes score, PP * exp(-Misfit) = 6.712225E-08 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 14449.8 846.112 0.935501 0.397069 0.477697 0.151100 4.319238E-03 0.188729 0.122840 5.531444E-02 Final coordinates: 8728.86 997.944 0.667415 0.397929 0.799262 3.931659E-02 5.066718E-02 7.421279E-03 2.294415E-02 8.038889E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.894941 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.423 0.004981 0.001432 0.000000 0.092664 0.011463 0.000000 0.006818 0.279399 0.603243 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.8 0. 0. -0.7 -4.7E-02 0. 1. 0.1 -0.4 Chi 5.8E-03 0. 0. 7.3E-04 8.3E-06 0. 6.6E-03 4.2E-06 1.7E-05 Composition Misfit: 1.463488E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.129 0.000000 0.035177 0.000000 0.000000 0.287618 0.060369 0.054891 0.135960 0.425985 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -3. -9.2E-03 0.6 -0.2 Chi 0. 6.1E-03 0. 0. 4.1E-03 1.1E-02 1.7E-07 4.6E-04 4.1E-06 Composition Misfit: 2.193813E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 58.049 0.022477 0.004468 0.000000 0.100289 0.000000 0.000000 0.000000 0.127234 0.745532 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -2.9E+01 0. 0. 0. 2. -2. Chi 0.2 0.5 0. 0.1 0. 0. 0. 8.9E-03 3.5E-03 Composition Misfit: 0.819959 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 9.090 0.000000 0.000000 0.037570 0.076896 0.224862 0.002207 0.128750 0.153439 0.376277 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -3. -0.2 3. -0.9 2. Chi 0. 0. 7.0E-03 1.3E-03 7.3E-03 2.8E-04 1.3E-02 1.1E-03 4.2E-03 Composition Misfit: 3.401948E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.709 0.000000 0.000000 0.335849 0.000000 0.635149 0.018195 0.010807 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.8 0. -0.2 -1. -0.1 0. 0. Chi 0. 0. 6.0E-04 0. 4.2E-05 3.7E-03 6.0E-05 0. 0. Composition Misfit: 4.389374E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 23.601 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.012183 0.003031 0.007253 0.066307 0.033917 0.001405 0.013779 0.023939 0.001415 0.231676 0.605095 Mica 0.004159 0.001196 0.000000 0.077370 0.009571 0.000000 0.005692 0.164254 0.000786 0.233287 0.503684 Gt 0.000000 0.035071 0.000000 0.000000 0.286753 0.060187 0.054726 0.000000 0.003008 0.135551 0.424704 Fsp 0.022477 0.004468 0.000000 0.100289 0.000000 0.000000 0.000000 0.000000 0.000000 0.127234 0.745532 Bio 0.000000 0.000000 0.033529 0.068626 0.200680 0.001969 0.114904 0.103724 0.003818 0.136938 0.335812 Ilm 0.000000 0.000000 0.310375 0.000000 0.586973 0.016815 0.009987 0.000000 0.075850 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -795709. -761450. -940879. -850305. -322989. -473973. -647553. -304662. -412660. -1647272. -893998. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 102 converged, 76 successes so far. Misfit function evaluations this try => 636 Misfit this try = 7.991912E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 6.330395E-07 Bayes score, PP * exp(-Misfit) = 5.844164E-07 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 12219.6 840.533 0.736668 0.595155 0.533062 0.316269 1.282646E-02 7.608962E-02 5.187165E-02 9.880834E-03 Final coordinates: 10834.7 956.703 0.628469 0.806247 0.199740 0.646654 6.539733E-03 9.500472E-02 4.670707E-02 5.354444E-03 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.991912E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 37.218 0.008741 0.000580 0.000000 0.088965 0.011478 0.000000 0.010291 0.274242 0.605702 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.3 0. 0. -0.4 -5.0E-02 0. 0.5 0.4 -0.7 Chi 3.0E-04 0. 0. 2.3E-04 9.1E-06 0. 1.0E-03 1.4E-04 5.4E-05 Composition Misfit: 2.340936E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 56.475 0.000000 0.020034 0.000000 0.000000 0.306689 0.033314 0.076676 0.136936 0.426351 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. 0.1 0. 0. 0.9 0.1 -2. 0.5 -0.2 Chi 0. 1.3E-05 0. 0. 7.6E-04 2.6E-05 6.2E-03 3.5E-04 6.7E-06 Composition Misfit: 7.394400E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.504 0.104549 0.030523 0.000000 0.005190 0.000000 0.000000 0.000000 0.140261 0.719477 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -1. 2. 0. -1. 0. 0. 0. 1. -1. Chi 1.6E-03 1.5E-02 0. 2.8E-03 0. 0. 0. 3.0E-03 8.7E-04 Composition Misfit: 2.287264E-02 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.175 0.000000 0.000000 0.032708 0.075632 0.197045 0.000961 0.172968 0.134477 0.386210 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -0.8 0.1 -0.2 0.4 2. Chi 0. 0. 3.9E-03 1.0E-03 8.0E-04 2.2E-04 6.9E-05 2.5E-04 2.3E-03 Composition Misfit: 8.566654E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.562 0.000000 0.000000 0.264668 0.000000 0.717411 0.007862 0.010059 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 5. 0. -4. 0.3 -9.5E-03 0. 0. Chi 0. 0. 2.8E-02 0. 1.1E-02 5.8E-04 3.5E-07 0. 0. Composition Misfit: 3.874449E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.065 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.002549 0.012749 0.017196 0.022170 0.240866 0.021286 0.051262 0.048731 0.009461 0.154320 0.419410 Mica 0.007303 0.000485 0.000000 0.074332 0.009590 0.000000 0.008599 0.163756 0.000724 0.229135 0.506077 Gt 0.000000 0.019983 0.000000 0.000000 0.305896 0.033228 0.076478 0.000000 0.002584 0.136582 0.425249 Fsp 0.104549 0.030523 0.000000 0.005190 0.000000 0.000000 0.000000 0.000000 0.000000 0.140261 0.719477 Bio 0.000000 0.000000 0.029128 0.067353 0.175475 0.000856 0.154034 0.105577 0.003890 0.119756 0.343932 Ilm 0.000000 0.000000 0.236804 0.000000 0.641883 0.007034 0.009000 0.000000 0.105279 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -771019. -757903. -930947. -833136. -315559. -471220. -639251. -296658. -405810. -1635809. -884519. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 103 converged, 77 successes so far. Misfit function evaluations this try => 745 Misfit this try = 1.51448 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 3.353895E-07 Bayes score, PP * exp(-Misfit) = 7.375998E-08 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 13104.9 810.761 6.944946E-02 0.485778 0.443907 2.019522E-02 8.873310E-02 5.254928E-02 0.363915 3.070032E-02 Final coordinates: 6835.65 848.377 0.270968 0.673173 0.510706 6.909180E-03 2.877149E-02 0.117652 0.123718 0.212244 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.51448 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.362 0.007158 0.000736 0.000000 0.091441 0.006311 0.000000 0.004573 0.286937 0.602845 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.5 0. 0. -0.6 0.7 0. 1. -0.4 -0.4 Chi 1.4E-03 0. 0. 5.3E-04 3.7E-03 0. 1.8E-02 1.5E-04 1.3E-05 Composition Misfit: 2.418245E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.764 0.000000 0.049644 0.000000 0.000000 0.302513 0.048666 0.031747 0.139949 0.427481 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -4. 0. 0. 1. -2. 2. 0.3 -0.3 Chi 0. 1.7E-02 0. 0. 1.2E-03 4.3E-03 1.7E-02 1.1E-04 1.9E-05 Composition Misfit: 3.942796E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 43.802 0.022983 0.002369 0.000000 0.100832 0.000000 0.000000 0.000000 0.126184 0.747631 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -2.9E+01 0. 0. 0. 2. -2. Chi 0.2 1. 0. 0.1 0. 0. 0. 9.5E-03 3.8E-03 Composition Misfit: 1.33958 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 23.999 0.000000 0.000000 0.033509 0.076532 0.245628 0.000911 0.112308 0.147977 0.383134 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -4. 0.1 4. -0.6 2. Chi 0. 0. 4.4E-03 1.2E-03 1.5E-02 2.9E-04 2.9E-02 4.0E-04 2.8E-03 Composition Misfit: 5.346282E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.886 0.000000 0.000000 0.469157 0.000000 0.512367 0.010519 0.007957 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -7. 0. 5. -0.1 0.3 0. 0. Chi 0. 0. 3.0E-02 0. 2.7E-02 2.6E-05 5.2E-04 0. 0. Composition Misfit: 5.782102E-02 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.187 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.009082 0.001459 0.041091 0.061865 0.098599 0.001472 0.028120 0.040752 0.001670 0.201712 0.514179 Mica 0.005974 0.000614 0.000000 0.076315 0.005267 0.000000 0.003817 0.165191 0.000230 0.239471 0.503121 Gt 0.000000 0.049581 0.000000 0.000000 0.302129 0.048604 0.031707 0.000000 0.001271 0.139771 0.426938 Fsp 0.022983 0.002369 0.000000 0.100832 0.000000 0.000000 0.000000 0.000000 0.000000 0.126184 0.747631 Bio 0.000000 0.000000 0.029870 0.068219 0.218947 0.000812 0.100109 0.106568 0.002055 0.131903 0.341517 Ilm 0.000000 0.000000 0.462032 0.000000 0.504586 0.010359 0.007836 0.000000 0.015187 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -763772. -745845. -924675. -825407. -306144. -458331. -637153. -294006. -433499. -1627425. -882080. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 104 converged, 78 successes so far. Misfit function evaluations this try => 452 Misfit this try = 0.912984 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 1.776373E-07 Bayes score, PP * exp(-Misfit) = 7.129025E-08 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 14444.4 811.465 0.841707 7.700303E-02 6.965365E-02 2.430766E-02 0.208105 8.907737E-02 5.375535E-03 0.603481 Final coordinates: 9514.74 998.761 0.971915 0.769575 8.928486E-02 1.564087E-02 4.356771E-02 2.886645E-03 5.194248E-02 0.796677 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.912984 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.904 0.005293 0.001231 0.000000 0.092318 0.012021 0.000000 0.007488 0.277557 0.604092 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.8 0. 0. -0.7 -0.1 0. 0.9 0.2 -0.5 Chi 4.8E-03 0. 0. 6.7E-04 6.2E-05 0. 4.9E-03 3.1E-05 2.8E-05 Composition Misfit: 1.176914E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.567 0.000000 0.034125 0.000000 0.000000 0.302341 0.043493 0.057596 0.136324 0.426121 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -1. -0.3 0.5 -0.2 Chi 0. 5.4E-03 0. 0. 1.3E-03 2.0E-03 1.4E-04 4.1E-04 5.0E-06 Composition Misfit: 9.190239E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 48.218 0.024434 0.004035 0.000000 0.098549 0.000000 0.000000 0.000000 0.127017 0.745965 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -2.8E+01 0. 0. 0. 2. -2. Chi 0.2 0.6 0. 0.1 0. 0. 0. 9.0E-03 3.6E-03 Composition Misfit: 0.853999 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.284 0.000000 0.000000 0.038229 0.076687 0.224654 0.001563 0.130028 0.150300 0.378539 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -3. -4.0E-02 3. -0.7 2. Chi 0. 0. 7.4E-03 1.2E-03 7.2E-03 1.2E-05 1.2E-02 6.6E-04 3.7E-03 Composition Misfit: 3.222504E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.289 0.000000 0.000000 0.379807 0.000000 0.594362 0.013215 0.012617 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 2. -0.5 -0.4 0. 0. Chi 0. 0. 2.3E-03 0. 2.1E-03 7.8E-04 5.4E-04 0. 0. Composition Misfit: 5.800872E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.738 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.011538 0.002251 0.015981 0.065778 0.042205 0.000928 0.012148 0.045923 0.002564 0.226166 0.574518 Mica 0.004421 0.001028 0.000000 0.077102 0.010040 0.000000 0.006254 0.164074 0.000740 0.231812 0.504529 Gt 0.000000 0.034027 0.000000 0.000000 0.301479 0.043369 0.057432 0.000000 0.002850 0.135935 0.424907 Fsp 0.024434 0.004035 0.000000 0.098549 0.000000 0.000000 0.000000 0.000000 0.000000 0.127017 0.745965 Bio 0.000000 0.000000 0.034160 0.068524 0.200740 0.001397 0.116187 0.102888 0.003560 0.134301 0.338244 Ilm 0.000000 0.000000 0.358276 0.000000 0.560667 0.012466 0.011901 0.000000 0.056690 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -791101. -760577. -938964. -846149. -321977. -476023. -646616. -303843. -414736. -1645709. -892282. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 105 converged, 79 successes so far. Misfit function evaluations this try => 655 Misfit this try = 2.540208E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 5.576644E-07 Bayes score, PP * exp(-Misfit) = 5.436770E-07 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 13632.3 923.112 0.351545 0.784014 0.153761 3.607739E-03 0.624299 0.187630 1.360968E-02 1.709309E-02 Final coordinates: 9730.38 964.021 0.645856 0.613908 0.111026 5.359199E-03 0.675618 0.184313 1.912338E-02 4.559854E-03 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.540208E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 9.034 0.011497 0.001656 0.000000 0.085972 0.010048 0.000000 0.008595 0.278699 0.603532 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.2 0. 0.7 0.1 -0.5 Chi 1.1E-04 0. 0. 2.7E-05 1.2E-04 0. 2.9E-03 1.1E-05 2.1E-05 Composition Misfit: 4.801245E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.565 0.000000 0.030245 0.000000 0.000000 0.298288 0.035657 0.073416 0.136286 0.426107 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.2 -2. 0.5 -0.2 Chi 0. 3.1E-03 0. 0. 1.9E-03 5.6E-05 4.7E-03 4.2E-04 4.9E-06 Composition Misfit: 1.018272E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 66.843 0.095367 0.053031 0.000000 0.003118 0.000000 0.000000 0.000000 0.151515 0.696969 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.1 0. -0.5 0. 0. 0. 0.6 -0.1 Chi 1.4E-04 3.9E-05 0. 9.9E-04 0. 0. 0. 5.8E-04 8.7E-06 Composition Misfit: 1.766729E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 17.219 0.000000 0.000000 0.030221 0.075933 0.198399 0.001069 0.171605 0.138993 0.383780 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -0.9 0.1 -0.1 0.1 2. Chi 0. 0. 2.6E-03 1.1E-03 9.8E-04 1.2E-04 2.5E-05 1.3E-05 2.7E-03 Composition Misfit: 7.486702E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.927 0.000000 0.000000 0.349851 0.000000 0.626330 0.009825 0.013994 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 8.2E-03 0. 0.2 2.8E-02 -0.6 0. 0. Chi 0. 0. 6.4E-08 0. 2.2E-05 3.1E-06 1.1E-03 0. 0. Composition Misfit: 1.164681E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.546 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.868 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.060670 0.033613 0.010219 0.022127 0.047161 0.000613 0.032004 0.036873 0.001904 0.161251 0.593566 Mica 0.009602 0.001383 0.000000 0.071799 0.008391 0.000000 0.007178 0.164185 0.000677 0.232752 0.504033 Gt 0.000000 0.030158 0.000000 0.000000 0.297433 0.035555 0.073205 0.000000 0.002866 0.135896 0.424886 Fsp 0.095367 0.053031 0.000000 0.003118 0.000000 0.000000 0.000000 0.000000 0.000000 0.151515 0.696969 Bio 0.000000 0.000000 0.026839 0.067435 0.176195 0.000950 0.152399 0.108030 0.003889 0.123437 0.340827 Ilm 0.000000 0.000000 0.325420 0.000000 0.582592 0.009139 0.013017 0.000000 0.069832 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -779573. -757199. -934049. -846115. -317667. -472791. -641014. -296236. -409152. -1639417. -887858. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 106 converged, 80 successes so far. Misfit function evaluations this try => 898 Misfit this try = 2.376707E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 9.433676E-07 Bayes score, PP * exp(-Misfit) = 9.212109E-07 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 13103.3 877.781 0.918141 0.501679 4.528079E-02 0.322330 0.220215 5.497563E-02 0.141343 0.215856 Final coordinates: 9185.58 935.128 0.976139 0.370257 1.561954E-02 3.196304E-02 0.817999 7.257075E-03 1.536101E-02 0.111800 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.376707E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 12.316 0.012076 0.001496 0.000000 0.085630 0.009311 0.000000 0.007645 0.280647 0.603196 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.3 0. 0. -0.1 0.3 0. 0.9 -9.9E-03 -0.4 Chi 2.4E-04 0. 0. 1.6E-05 3.7E-04 0. 4.6E-03 1.0E-07 1.7E-05 Composition Misfit: 6.692132E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.164 0.000000 0.031352 0.000000 0.000000 0.306242 0.034523 0.065132 0.136546 0.426205 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 0.9 -3.0E-02 -1. 0.5 -0.2 Chi 0. 3.7E-03 0. 0. 8.0E-04 2.2E-06 1.6E-03 3.9E-04 5.6E-06 Composition Misfit: 6.563403E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 79.260 0.095744 0.053244 0.000000 0.002634 0.000000 0.000000 0.000000 0.151622 0.696756 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.2 0. -0.4 0. 0. 0. 0.6 -0.1 Chi 1.8E-04 5.1E-05 0. 6.2E-04 0. 0. 0. 5.7E-04 7.3E-06 Composition Misfit: 1.418818E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.964 0.000000 0.000000 0.028757 0.075875 0.207495 0.000920 0.164711 0.138125 0.384117 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.9 -1. -2. 0.1 0.3 0.2 2. Chi 0. 0. 1.9E-03 1.0E-03 2.6E-03 2.8E-04 1.4E-04 3.5E-05 2.6E-03 Composition Misfit: 8.592598E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.962 0.000000 0.000000 0.345652 0.000000 0.634208 0.008627 0.011513 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.2 0. -0.2 0.2 -0.2 0. 0. Chi 0. 0. 5.5E-05 0. 2.8E-05 2.2E-04 2.0E-04 0. 0. Composition Misfit: 5.001206E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.081 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.254 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.074463 0.041836 0.005399 0.012063 0.022183 0.001228 0.004745 0.022584 0.001353 0.168827 0.645319 Mica 0.010083 0.001249 0.000000 0.071498 0.007774 0.000000 0.006384 0.164411 0.000624 0.234330 0.503648 Gt 0.000000 0.031266 0.000000 0.000000 0.305399 0.034428 0.064952 0.000000 0.002754 0.136170 0.425031 Fsp 0.095744 0.053244 0.000000 0.002634 0.000000 0.000000 0.000000 0.000000 0.000000 0.151622 0.696756 Bio 0.000000 0.000000 0.025507 0.067299 0.184042 0.000816 0.146094 0.109091 0.003940 0.122512 0.340700 Ilm 0.000000 0.000000 0.320888 0.000000 0.588770 0.008009 0.010689 0.000000 0.071645 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -775067. -754689. -931737. -842406. -314417. -469717. -639402. -294224. -409503. -1635870. -885909. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 107 converged, 81 successes so far. Misfit function evaluations this try => 249 Misfit this try = 2.980481E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 1.094653E-06 Bayes score, PP * exp(-Misfit) = 1.062508E-06 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 12398.1 851.710 0.203005 0.884578 0.496704 4.810849E-03 0.308908 0.129843 2.935287E-02 3.038189E-02 Final coordinates: 8869.68 884.361 0.480587 0.935619 0.229233 5.488140E-03 0.633059 0.107311 3.665258E-03 2.124356E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.980481E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.284 0.012472 0.001238 0.000000 0.085485 0.007891 0.000000 0.007636 0.282095 0.603184 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.3 0. 0. -0.1 0.5 0. 0.9 -0.1 -0.4 Chi 3.6E-04 0. 0. 1.2E-05 1.4E-03 0. 4.6E-03 9.3E-06 1.7E-05 Composition Misfit: 7.558108E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.428 0.000000 0.041113 0.000000 0.000000 0.295730 0.040963 0.059710 0.136351 0.426132 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 1. -0.7 -0.5 0.5 -0.2 Chi 0. 1.0E-02 0. 0. 2.3E-03 1.1E-03 4.0E-04 4.1E-04 5.1E-06 Composition Misfit: 1.452804E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 59.806 0.096221 0.053706 0.000000 0.001926 0.000000 0.000000 0.000000 0.151853 0.696294 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.4 -0.2 0. -0.2 0. 0. 0. 0.6 -0.1 Chi 2.2E-04 8.3E-05 0. 1.7E-04 0. 0. 0. 5.4E-04 4.6E-06 Composition Misfit: 1.010861E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 9.871 0.000000 0.000000 0.026614 0.075443 0.198182 0.000862 0.179868 0.131645 0.387385 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.7 -1. -0.9 0.2 -0.7 0.6 1. Chi 0. 0. 1.0E-03 9.6E-04 9.5E-04 3.7E-04 6.0E-04 5.7E-04 2.1E-03 Composition Misfit: 6.579080E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.116 0.000000 0.000000 0.352479 0.000000 0.627631 0.009239 0.010651 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.1 0. 0.1 0.1 -0.1 0. 0. Chi 0. 0. 1.7E-05 0. 8.9E-06 6.3E-05 4.0E-05 0. 0. Composition Misfit: 1.287173E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.863 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.631 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.057182 0.030920 0.003373 0.027547 0.025156 0.000356 0.020680 0.055866 0.000756 0.177314 0.600850 Mica 0.010412 0.001033 0.000000 0.071369 0.006588 0.000000 0.006375 0.164595 0.000534 0.235513 0.503581 Gt 0.000000 0.040997 0.000000 0.000000 0.294891 0.040847 0.059541 0.000000 0.002838 0.135964 0.424922 Fsp 0.096221 0.053706 0.000000 0.001926 0.000000 0.000000 0.000000 0.000000 0.000000 0.151853 0.696294 Bio 0.000000 0.000000 0.023577 0.066834 0.175568 0.000764 0.159343 0.110091 0.004018 0.116623 0.343181 Ilm 0.000000 0.000000 0.328266 0.000000 0.584517 0.008605 0.009919 0.000000 0.068694 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -764540. -748228. -925690. -832083. -308932. -462161. -635002. -290272. -406439. -1628508. -881174. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 108 converged, 82 successes so far. Misfit function evaluations this try => 423 Misfit this try = 2236.16 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 1.671453E-07 Bayes score, PP * exp(-Misfit) = 0.00000 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 11398.7 987.513 0.880572 0.532470 0.131367 6.525157E-03 5.024831E-02 2.928295E-02 4.870197E-02 0.733874 Final coordinates: 9234.71 999.589 0.986761 0.625922 7.228854E-02 1.309591E-02 4.770841E-02 1.027502E-03 2.655319E-02 0.839326 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.705301E-2 Extraneous predicted phases: 2236.08 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.844 0.005079 0.001355 0.000000 0.092499 0.011460 0.000000 0.007876 0.277991 0.603740 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.8 0. 0. -0.7 -4.7E-02 0. 0.8 0.1 -0.5 Chi 5.5E-03 0. 0. 7.0E-04 8.1E-06 0. 4.1E-03 2.2E-05 2.3E-05 Composition Misfit: 1.167647E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.180 0.000000 0.035943 0.000000 0.000000 0.279288 0.061364 0.061650 0.135822 0.425933 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 2. -3. -0.7 0.6 -0.2 Chi 0. 6.6E-03 0. 0. 6.5E-03 1.2E-02 7.6E-04 4.7E-04 3.8E-06 Composition Misfit: 2.632386E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.000 0.081301 0.072137 0.000000 0.007631 0.000000 0.000000 0.000000 0.161069 0.677863 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 0.8 -2. 0. -2. 0. 0. 0. -1.2E-02 0.7 Chi 1.3E-03 5.8E-03 0. 5.2E-03 0. 0. 0. 1.8E-07 4.1E-04 Composition Misfit: 1.273237E-02 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.785 0.000000 0.000000 0.037868 0.076696 0.210943 0.002247 0.143919 0.150433 0.377893 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -2. -0.2 2. -0.7 2. Chi 0. 0. 7.2E-03 1.2E-03 3.3E-03 3.0E-04 4.6E-03 6.8E-04 3.8E-03 Composition Misfit: 2.111726E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.033 0.000000 0.000000 0.343822 0.000000 0.624133 0.019195 0.012851 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.3 0. 0.3 -1. -0.5 0. 0. Chi 0. 0. 1.1E-04 0. 5.5E-05 4.4E-03 6.3E-04 0. 0. Composition Misfit: 5.203054E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.619 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. The following predicted phases** are not observed: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Fsp 53.538 0.023340 0.004311 0.000000 0.099504 0.000000 0.000000 0.000000 0.000000 0.000000 0.127156 0.745689 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.012101 0.002392 0.008159 0.067556 0.027418 0.000627 0.011829 0.037342 0.001691 0.232448 0.598438 Mica 0.004241 0.001132 0.000000 0.077246 0.009570 0.000000 0.006578 0.164107 0.000787 0.232152 0.504187 Gt 0.000000 0.035833 0.000000 0.000000 0.278431 0.061176 0.061460 0.000000 0.003068 0.135405 0.424626 Fsp 0.081301 0.072137 0.000000 0.007631 0.000000 0.000000 0.000000 0.000000 0.000000 0.161069 0.677863 Bio 0.000000 0.000000 0.033817 0.068491 0.188377 0.002007 0.128523 0.103165 0.003814 0.134340 0.337467 Ilm 0.000000 0.000000 0.318918 0.000000 0.578925 0.017804 0.011920 0.000000 0.072433 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -793253. -760735. -939635. -847868. -323021. -473589. -646371. -304258. -410634. -1646456. -893021. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 109 converged, 83 successes so far. Misfit function evaluations this try => 320 Misfit this try = 3.859595E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 5.535497E-07 Bayes score, PP * exp(-Misfit) = 5.325920E-07 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 5878.37 860.212 0.950696 0.942468 0.134347 7.803257E-03 0.355082 0.368593 0.107049 2.712569E-02 Final coordinates: 8336.75 844.698 0.906473 0.966151 9.024174E-02 1.207351E-03 0.389224 0.391766 0.117433 1.012865E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.859595E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 8.014 0.011742 0.000880 0.000000 0.086528 0.007080 0.000000 0.006925 0.283665 0.603180 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.2 0.6 0. 1. -0.2 -0.4 Chi 1.6E-04 0. 0. 4.9E-05 2.3E-03 0. 6.3E-03 3.6E-05 1.7E-05 Composition Misfit: 9.819761E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.052 0.000000 0.045312 0.000000 0.000000 0.300059 0.041508 0.050104 0.136739 0.426277 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 1. -0.8 0.4 0.5 -0.2 Chi 0. 1.4E-02 0. 0. 1.6E-03 1.3E-03 4.4E-04 3.7E-04 6.2E-06 Composition Misfit: 1.721056E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 40.311 0.097116 0.052408 0.000000 0.001680 0.000000 0.000000 0.000000 0.151204 0.697592 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.4 -0.1 0. -0.1 0. 0. 0. 0.7 -0.1 Chi 3.1E-04 1.3E-05 0. 6.2E-05 0. 0. 0. 6.2E-04 1.4E-05 Composition Misfit: 1.017050E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 37.566 0.000000 0.000000 0.025658 0.075271 0.205877 0.000720 0.174582 0.129063 0.388829 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -0.5 -1. -1. 0.2 -0.3 0.8 1. Chi 0. 0. 7.2E-04 9.2E-04 2.2E-03 6.9E-04 1.5E-04 9.8E-04 1.9E-03 Composition Misfit: 7.571081E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.244 0.000000 0.000000 0.375517 0.000000 0.606892 0.008456 0.009136 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -1. 0. 1. 0.2 0.1 0. 0. Chi 0. 0. 1.7E-03 0. 8.8E-04 2.8E-04 8.2E-05 0. 0. Composition Misfit: 2.977500E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.760 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 2.055 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.034329 0.018802 0.046262 0.032949 0.138172 0.001659 0.064532 0.057072 0.007828 0.136450 0.461947 Mica 0.009801 0.000734 0.000000 0.072229 0.005910 0.000000 0.005781 0.164795 0.000460 0.236788 0.503502 Gt 0.000000 0.045191 0.000000 0.000000 0.299258 0.041397 0.049970 0.000000 0.002669 0.136374 0.425139 Fsp 0.097116 0.052408 0.000000 0.001680 0.000000 0.000000 0.000000 0.000000 0.000000 0.151204 0.697592 Bio 0.000000 0.000000 0.022718 0.066648 0.182291 0.000638 0.154581 0.110577 0.003986 0.114277 0.344284 Ilm 0.000000 0.000000 0.353513 0.000000 0.571331 0.007960 0.008600 0.000000 0.058595 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -757574. -744480. -921976. -824458. -304657. -457559. -632627. -288212. -407000. -1623621. -878272. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 110 converged, 84 successes so far. Misfit function evaluations this try => 378 Misfit this try = 2.830258E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 2.301726E-07 Bayes score, PP * exp(-Misfit) = 2.237495E-07 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 9807.64 927.409 0.947778 0.909589 1.835068E-02 1.303675E-03 9.306195E-02 3.296458E-03 0.109191 0.774796 Final coordinates: 9993.29 992.479 0.963645 0.712416 1.120866E-02 5.453130E-03 0.697134 4.937963E-02 1.639385E-02 0.220431 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.830258E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.241 0.010665 0.001714 0.000000 0.086680 0.010843 0.000000 0.008865 0.277491 0.603741 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -4.8E-02 0. 0. -0.2 4.8E-02 0. 0.7 0.2 -0.5 Chi 8.8E-06 0. 0. 5.7E-05 9.0E-06 0. 2.5E-03 3.2E-05 2.3E-05 Composition Misfit: 4.315454E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.369 0.000000 0.027175 0.000000 0.000000 0.297293 0.036040 0.077045 0.136325 0.426122 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.9 0. 0. 1. -0.2 -2. 0.5 -0.2 Chi 0. 1.6E-03 0. 0. 2.0E-03 8.9E-05 6.4E-03 4.1E-04 5.0E-06 Composition Misfit: 1.058983E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 67.709 0.094842 0.052569 0.000000 0.003873 0.000000 0.000000 0.000000 0.151284 0.697431 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.1 0. -0.7 0. 0. 0. 0.7 -0.1 Chi 1.1E-04 1.8E-05 0. 1.6E-03 0. 0. 0. 6.1E-04 1.2E-05 Composition Misfit: 2.382244E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.207 0.000000 0.000000 0.031946 0.076121 0.198921 0.001216 0.167531 0.141814 0.382451 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.1 0.1 -0.1 2. Chi 0. 0. 3.5E-03 1.1E-03 1.0E-03 3.6E-05 2.4E-05 1.6E-05 2.9E-03 Composition Misfit: 8.667339E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.876 0.000000 0.000000 0.356189 0.000000 0.617605 0.010721 0.015485 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.3 0. 0.6 -0.1 -0.9 0. 0. Chi 0. 0. 1.1E-04 0. 2.5E-04 4.8E-05 1.9E-03 0. 0. Composition Misfit: 2.347718E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.460 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.138 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.063348 0.034479 0.006491 0.022760 0.022721 0.000402 0.011440 0.043034 0.001368 0.176641 0.617316 Mica 0.008908 0.001432 0.000000 0.072398 0.009057 0.000000 0.007404 0.164044 0.000724 0.231769 0.504264 Gt 0.000000 0.027098 0.000000 0.000000 0.296446 0.035937 0.076825 0.000000 0.002850 0.135936 0.424907 Fsp 0.094842 0.052569 0.000000 0.003873 0.000000 0.000000 0.000000 0.000000 0.000000 0.151284 0.697431 Bio 0.000000 0.000000 0.028407 0.067688 0.176884 0.001081 0.148971 0.106969 0.003815 0.126103 0.340081 Ilm 0.000000 0.000000 0.332296 0.000000 0.576175 0.010002 0.014446 0.000000 0.067082 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -785264. -760642. -937169. -850759. -320954. -476274. -643396. -298842. -410585. -1643608. -890466. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio sill the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio sill -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 115 converged, 85 successes so far. Misfit function evaluations this try => 258 Misfit this try = 2.377654E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 8.770144E-07 Bayes score, PP * exp(-Misfit) = 8.564080E-07 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 6178.07 858.057 0.807887 0.200162 3.853193E-02 0.135948 0.686948 3.773419E-03 4.316783E-03 0.130482 Final coordinates: 9260.83 940.564 0.781284 4.815601E-02 2.794007E-03 4.199250E-03 0.962816 2.066397E-03 1.661777E-03 2.646268E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.377654E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.415 0.011830 0.001523 0.000000 0.085835 0.009476 0.000000 0.007777 0.280306 0.603253 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.3 0. 0.8 1.0E-02 -0.4 Chi 1.8E-04 0. 0. 2.2E-05 3.0E-04 0. 4.3E-03 1.1E-07 1.8E-05 Composition Misfit: 6.322389E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.281 0.000000 0.031270 0.000000 0.000000 0.305251 0.034694 0.066097 0.136500 0.426187 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 0.9 -4.9E-02 -1. 0.5 -0.2 Chi 0. 3.7E-03 0. 0. 9.1E-04 5.8E-06 1.9E-03 3.9E-04 5.5E-06 Composition Misfit: 6.924624E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 93.238 0.095465 0.053581 0.000000 0.002745 0.000000 0.000000 0.000000 0.151790 0.696419 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.2 0. -0.4 0. 0. 0. 0.6 -0.1 Chi 1.5E-04 7.4E-05 0. 7.0E-04 0. 0. 0. 5.5E-04 5.3E-06 Composition Misfit: 1.478458E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.330 0.000000 0.000000 0.029115 0.075903 0.206717 0.000947 0.164845 0.138546 0.383927 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.1 0.3 0.1 2. Chi 0. 0. 2.1E-03 1.1E-03 2.4E-03 2.4E-04 1.3E-04 2.3E-05 2.7E-03 Composition Misfit: 8.577646E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.095 0.000000 0.000000 0.347520 0.000000 0.631773 0.008831 0.011875 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. -0.1 0.2 -0.3 0. 0. Chi 0. 0. 1.8E-05 0. 5.0E-06 1.5E-04 3.0E-04 0. 0. Composition Misfit: 4.734201E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.335 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.305 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.088269 0.049608 0.000624 0.003905 0.003097 0.000163 0.000990 0.002959 0.000151 0.163503 0.686731 Mica 0.009878 0.001271 0.000000 0.071672 0.007913 0.000000 0.006494 0.164371 0.000634 0.234054 0.503713 Gt 0.000000 0.031183 0.000000 0.000000 0.304405 0.034598 0.065914 0.000000 0.002774 0.136121 0.425005 Fsp 0.095465 0.053581 0.000000 0.002745 0.000000 0.000000 0.000000 0.000000 0.000000 0.151790 0.696419 Bio 0.000000 0.000000 0.025831 0.067343 0.183403 0.000841 0.146254 0.108854 0.003925 0.122921 0.340628 Ilm 0.000000 0.000000 0.322902 0.000000 0.587019 0.008206 0.011034 0.000000 0.070839 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -776070. -755180. -932236. -843113. -315032. -470325. -639785. -294686. -409599. -1636588. -886334. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 116 converged, 86 successes so far. Misfit function evaluations this try => 1019 Misfit this try = 0.969630 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 1.462805E-07 Bayes score, PP * exp(-Misfit) = 5.547296E-08 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 14478.7 883.972 0.642840 0.863963 2.532215E-02 0.334965 0.128865 1.079842E-02 2.616952E-02 0.473880 Final coordinates: 8518.29 999.703 0.475084 0.995915 1.612367E-02 0.335338 3.179860E-05 2.739748E-03 4.879770E-02 0.596969 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.969630 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 29.439 0.005939 0.001094 0.000000 0.091963 0.012192 0.000000 0.005187 0.280387 0.603238 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.7 0. 0. -0.6 -0.2 0. 1. 5.4E-03 -0.4 Chi 3.3E-03 0. 0. 6.1E-04 8.8E-05 0. 1.3E-02 3.0E-08 1.7E-05 Composition Misfit: 1.856799E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 18.025 0.000000 0.023660 0.000000 0.000000 0.323618 0.045099 0.044338 0.136935 0.426351 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.4 0. 0. -0.1 -1. 1. 0.5 -0.2 Chi 0. 4.1E-04 0. 0. 8.9E-06 2.6E-03 2.5E-03 3.5E-04 6.7E-06 Composition Misfit: 5.850281E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.001 0.027026 0.003851 0.000000 0.096048 0.000000 0.000000 0.000000 0.126926 0.746149 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 5. 5. 0. -2.7E+01 0. 0. 0. 2. -2. Chi 0.2 0.6 0. 0.1 0. 0. 0. 9.1E-03 3.6E-03 Composition Misfit: 0.852420 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.714 0.000000 0.000000 0.036883 0.077103 0.256916 0.001631 0.096121 0.156550 0.374796 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -5. -0.1 5. -1. 2. Chi 0. 0. 6.5E-03 1.3E-03 2.0E-02 2.6E-05 0.1 1.7E-03 4.5E-03 Composition Misfit: 9.056153E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.329 0.000000 0.000000 0.334956 0.000000 0.644844 0.012524 0.007675 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.8 0. -0.7 -0.4 0.4 0. 0. Chi 0. 0. 6.8E-04 0. 3.4E-04 5.1E-04 7.0E-04 0. 0. Composition Misfit: 2.230362E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 13.492 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.005894 0.006394 0.015899 0.048211 0.135484 0.011111 0.025635 0.061730 0.004023 0.204640 0.480979 Mica 0.004958 0.000913 0.000000 0.076774 0.010178 0.000000 0.004330 0.164379 0.000781 0.234078 0.503607 Gt 0.000000 0.023599 0.000000 0.000000 0.322782 0.044982 0.044223 0.000000 0.002584 0.136581 0.425249 Fsp 0.027026 0.003851 0.000000 0.096048 0.000000 0.000000 0.000000 0.000000 0.000000 0.126926 0.746149 Bio 0.000000 0.000000 0.032887 0.068749 0.229080 0.001454 0.085707 0.104612 0.003735 0.139588 0.334188 Ilm 0.000000 0.000000 0.309422 0.000000 0.595687 0.011570 0.007090 0.000000 0.076231 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -794947. -764898. -942455. -852411. -322352. -476715. -649861. -304863. -417365. -1648025. -894686. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 117 converged, 87 successes so far. Misfit function evaluations this try => 458 Misfit this try = 2.552066E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 5.834937E-07 Bayes score, PP * exp(-Misfit) = 5.687910E-07 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 5488.22 887.798 0.370025 0.916431 3.853468E-02 2.449188E-03 0.277717 0.586455 1.183927E-02 8.300505E-02 Final coordinates: 9745.83 962.254 0.431159 0.631282 8.428781E-02 4.689463E-03 0.686794 0.170605 7.169520E-03 4.645474E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.552066E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 10.467 0.010998 0.001571 0.000000 0.086498 0.010125 0.000000 0.008691 0.278447 0.603669 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.1 0. 0. -0.2 0.2 0. 0.7 0.1 -0.5 Chi 3.7E-05 0. 0. 4.8E-05 1.0E-04 0. 2.7E-03 1.5E-05 2.2E-05 Composition Misfit: 4.509698E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.478 0.000000 0.030814 0.000000 0.000000 0.297347 0.036664 0.072857 0.136231 0.426087 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 1. -0.3 -2. 0.5 -0.2 Chi 0. 3.4E-03 0. 0. 2.0E-03 1.6E-04 4.5E-03 4.2E-04 4.8E-06 Composition Misfit: 1.051745E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 67.557 0.095289 0.052964 0.000000 0.003229 0.000000 0.000000 0.000000 0.151482 0.697036 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 -0.1 0. -0.5 0. 0. 0. 0.7 -0.1 Chi 1.4E-04 3.5E-05 0. 1.1E-03 0. 0. 0. 5.9E-04 9.2E-06 Composition Misfit: 1.852799E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 15.948 0.000000 0.000000 0.030462 0.075926 0.198309 0.001091 0.171501 0.138890 0.383821 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -0.9 0.1 -0.1 0.1 2. Chi 0. 0. 2.7E-03 1.1E-03 9.7E-04 1.0E-04 2.3E-05 1.5E-05 2.7E-03 Composition Misfit: 7.571096E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.163 0.000000 0.000000 0.347884 0.000000 0.628272 0.010033 0.013812 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. 0.1 -5.2E-03 -0.6 0. 0. Chi 0. 0. 1.3E-05 0. 4.8E-06 1.1E-07 1.1E-03 0. 0. Composition Misfit: 1.069618E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.599 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.788 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.061796 0.034149 0.005915 0.022487 0.037440 0.000457 0.029812 0.037920 0.001009 0.165098 0.603918 Mica 0.009185 0.001312 0.000000 0.072240 0.008456 0.000000 0.007258 0.164161 0.000682 0.232547 0.504159 Gt 0.000000 0.030725 0.000000 0.000000 0.296487 0.036558 0.072646 0.000000 0.002890 0.135837 0.424855 Fsp 0.095289 0.052964 0.000000 0.003229 0.000000 0.000000 0.000000 0.000000 0.000000 0.151482 0.697036 Bio 0.000000 0.000000 0.027059 0.067443 0.176153 0.000969 0.152340 0.107828 0.003896 0.123373 0.340939 Ilm 0.000000 0.000000 0.323295 0.000000 0.583864 0.009324 0.012835 0.000000 0.070682 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -779103. -756887. -933782. -845005. -317464. -472320. -640876. -296319. -408779. -1639091. -887625. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 119 converged, 88 successes so far. Misfit function evaluations this try => 664 Misfit this try = 0.930988 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 2.294170E-07 Bayes score, PP * exp(-Misfit) = 9.042794E-08 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 9568.08 960.575 0.789961 0.495868 2.986247E-02 1.063187E-03 8.046554E-03 9.208929E-04 0.221660 0.738447 Final coordinates: 9704.73 992.380 0.747566 0.177588 4.479332E-02 1.229939E-02 5.864241E-02 5.901503E-03 3.698973E-02 0.841374 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.930988 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.598 0.004790 0.001379 0.000000 0.092695 0.011916 0.000000 0.008073 0.276953 0.604194 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.9 0. 0. -0.7 -0.1 0. 0.8 0.2 -0.5 Chi 6.5E-03 0. 0. 7.3E-04 4.9E-05 0. 3.7E-03 4.5E-05 2.9E-05 Composition Misfit: 1.241549E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.630 0.000000 0.044280 0.000000 0.000000 0.298234 0.037628 0.058435 0.135581 0.425843 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -3. 0. 0. 1. -0.4 -0.3 0.6 -0.1 Chi 0. 1.3E-02 0. 0. 1.9E-03 3.0E-04 2.3E-04 5.0E-04 3.3E-06 Composition Misfit: 1.563656E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 64.219 0.021766 0.004203 0.000000 0.101133 0.000000 0.000000 0.000000 0.127101 0.745797 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -2.9E+01 0. 0. 0. 2. -2. Chi 0.2 0.5 0. 0.1 0. 0. 0. 9.0E-03 3.5E-03 Composition Misfit: 0.869739 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 7.858 0.000000 0.000000 0.038472 0.076570 0.218154 0.001312 0.137384 0.148543 0.379566 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -2. 3.2E-02 2. -0.6 2. Chi 0. 0. 7.6E-03 1.2E-03 5.2E-03 9.6E-06 7.5E-03 4.6E-04 3.5E-03 Composition Misfit: 2.548170E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 1.390 0.000000 0.000000 0.387078 0.000000 0.587847 0.011481 0.013595 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -2. 0. 2. -0.2 -0.6 0. 0. Chi 0. 0. 3.6E-03 0. 3.0E-03 1.9E-04 9.5E-04 0. 0. Composition Misfit: 7.715788E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 25.306 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.012832 0.002891 0.011526 0.066411 0.033713 0.000705 0.012386 0.010648 0.001575 0.229753 0.617560 Mica 0.004001 0.001152 0.000000 0.077425 0.009953 0.000000 0.006743 0.164004 0.000723 0.231332 0.504667 Gt 0.000000 0.044139 0.000000 0.000000 0.297288 0.037508 0.058249 0.000000 0.003173 0.135151 0.424491 Fsp 0.021766 0.004203 0.000000 0.101133 0.000000 0.000000 0.000000 0.000000 0.000000 0.127101 0.745797 Bio 0.000000 0.000000 0.034393 0.068451 0.195023 0.001173 0.122817 0.102509 0.003521 0.132793 0.339320 Ilm 0.000000 0.000000 0.366391 0.000000 0.556430 0.010867 0.012868 0.000000 0.053444 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -789829. -757766. -937396. -843211. -321163. -476228. -645477. -303177. -413849. -1644217. -891117. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 120 converged, 89 successes so far. Misfit function evaluations this try => 213 Misfit this try = 2.289400E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 1.034712E-06 Bayes score, PP * exp(-Misfit) = 1.011293E-06 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 10746.5 986.903 0.887990 0.935226 4.402614E-03 0.405182 0.200202 6.998438E-02 0.107911 0.212319 Final coordinates: 9453.69 930.296 0.966509 0.926508 8.340512E-03 0.260274 0.238022 0.114064 0.139336 0.239964 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.289400E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 30.816 0.012128 0.001160 0.000000 0.085704 0.009407 0.000000 0.007954 0.279931 0.603717 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.3 0. 0. -0.1 0.3 0. 0.8 3.2E-02 -0.5 Chi 2.6E-04 0. 0. 1.8E-05 3.3E-04 0. 3.9E-03 1.1E-06 2.3E-05 Composition Misfit: 5.715982E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 21.016 0.000000 0.027540 0.000000 0.000000 0.309184 0.033503 0.066541 0.136896 0.426336 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -0.9 0. 0. 0.7 0.1 -1. 0.5 -0.2 Chi 0. 1.8E-03 0. 0. 5.2E-04 1.7E-05 2.1E-03 3.5E-04 6.6E-06 Composition Misfit: 4.747947E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 24.888 0.099547 0.045279 0.000000 0.002813 0.000000 0.000000 0.000000 0.147639 0.704721 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.6 0.6 0. -0.4 0. 0. 0. 0.9 -0.5 Chi 6.3E-04 8.8E-04 0. 7.5E-04 0. 0. 0. 1.2E-03 1.5E-04 Composition Misfit: 3.599401E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 10.315 0.000000 0.000000 0.028911 0.075750 0.206111 0.000872 0.166926 0.136247 0.385183 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.2 0.2 0.3 2. Chi 0. 0. 2.0E-03 1.0E-03 2.3E-03 3.5E-04 4.0E-05 1.2E-04 2.5E-03 Composition Misfit: 8.231422E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 10.065 0.000000 0.000000 0.348921 0.000000 0.631258 0.008238 0.011583 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. -0.1 0.3 -0.3 0. 0. Chi 0. 0. 3.3E-06 0. 2.5E-06 3.8E-04 2.2E-04 0. 0. Composition Misfit: 5.992422E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 2.091 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 0.809 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.022753 0.016448 0.047775 0.026994 0.182293 0.009768 0.035785 0.055970 0.011012 0.150572 0.440629 Mica 0.010127 0.000969 0.000000 0.071565 0.007855 0.000000 0.006642 0.164353 0.000617 0.233751 0.504122 Gt 0.000000 0.027468 0.000000 0.000000 0.308380 0.033416 0.066368 0.000000 0.002601 0.136540 0.425227 Fsp 0.099547 0.045279 0.000000 0.002813 0.000000 0.000000 0.000000 0.000000 0.000000 0.147639 0.704721 Bio 0.000000 0.000000 0.025653 0.067214 0.182885 0.000774 0.148116 0.108774 0.003913 0.120894 0.341778 Ilm 0.000000 0.000000 0.324415 0.000000 0.586923 0.007659 0.010769 0.000000 0.070234 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -771979. -754671. -930534. -839185. -313517. -469035. -638611. -293780. -408927. -1634507. -884768. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio sill the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio sill -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 123 converged, 90 successes so far. Misfit function evaluations this try => 1017 Misfit this try = 0.924857 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 1.859563E-07 Bayes score, PP * exp(-Misfit) = 7.374804E-08 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 13121.6 972.951 0.797128 0.940291 3.844290E-03 4.854259E-02 9.804459E-03 0.259695 6.085387E-02 0.617260 Final coordinates: 8649.32 994.283 0.864266 0.950238 4.016978E-03 3.599038E-02 1.510603E-02 0.253700 7.248421E-02 0.618703 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.924857 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 11.692 0.005125 0.001343 0.000000 0.092578 0.010797 0.000000 0.007321 0.279540 0.603296 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.8 0. 0. -0.7 0.1 0. 0.9 0.1 -0.4 Chi 5.3E-03 0. 0. 7.1E-04 1.2E-05 0. 5.3E-03 3.1E-06 1.8E-05 Composition Misfit: 1.272245E-02 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.056 0.000000 0.033251 0.000000 0.000000 0.268314 0.076493 0.059665 0.136202 0.426076 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 3. -5. -0.5 0.5 -0.2 Chi 0. 4.9E-03 0. 0. 1.1E-02 2.3E-02 4.0E-04 4.3E-04 4.7E-06 Composition Misfit: 3.972411E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 34.268 0.023000 0.004256 0.000000 0.099872 0.000000 0.000000 0.000000 0.127128 0.745744 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. 6. 5. 0. -2.9E+01 0. 0. 0. 2. -2. Chi 0.2 0.5 0. 0.1 0. 0. 0. 9.0E-03 3.5E-03 Composition Misfit: 0.841134 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 34.219 0.000000 0.000000 0.037481 0.076828 0.210316 0.002795 0.143465 0.152421 0.376694 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -2. -1. -2. -0.4 2. -0.9 2. Chi 0. 0. 6.9E-03 1.3E-03 3.2E-03 6.7E-04 4.7E-03 9.6E-04 4.1E-03 Composition Misfit: 2.182831E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.269 0.000000 0.000000 0.332137 0.000000 0.631853 0.023960 0.012050 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 1. 0. -0.1 -2. -0.3 0. 0. Chi 0. 0. 9.6E-04 0. 5.4E-06 8.1E-03 3.5E-04 0. 0. Composition Misfit: 9.448668E-03 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 16.496 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q* NaN 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 *The indicated phase is stable but undersaturated with respect to the effective bulk composition. Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.007155 0.001387 0.028119 0.063564 0.101368 0.002118 0.049441 0.057772 0.005476 0.198962 0.484638 Mica 0.004279 0.001121 0.000000 0.077298 0.009015 0.000000 0.006113 0.164275 0.000778 0.233401 0.503720 Gt 0.000000 0.033154 0.000000 0.000000 0.267535 0.076271 0.059491 0.000000 0.002903 0.135806 0.424839 Fsp 0.023000 0.004256 0.000000 0.099872 0.000000 0.000000 0.000000 0.000000 0.000000 0.127128 0.745744 Bio 0.000000 0.000000 0.033450 0.068565 0.187695 0.002494 0.128035 0.103680 0.003874 0.136027 0.336179 Ilm 0.000000 0.000000 0.306419 0.000000 0.582927 0.022105 0.011117 0.000000 0.077433 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -794759. -761570. -940189. -849924. -323180. -471636. -646608. -304400. -410334. -1646824. -893763. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 124 converged, 91 successes so far. Misfit function evaluations this try => 621 Misfit this try = 2.893531E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 1.043562E-06 Bayes score, PP * exp(-Misfit) = 1.013799E-06 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 5607.03 977.349 9.655917E-02 0.816027 8.011464E-02 6.769753E-02 0.429210 3.565363E-02 5.811670E-03 0.381513 Final coordinates: 9879.07 931.445 0.300069 0.934330 8.778757E-02 7.527136E-02 0.485625 0.193459 7.501745E-03 0.150355 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.893531E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 20.127 0.007289 0.000844 0.000000 0.090483 0.010559 0.000000 0.009087 0.276944 0.604795 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. 0.5 0. 0. -0.5 0.1 0. 0.6 0.2 -0.6 Chi 1.3E-03 0. 0. 4.0E-04 3.4E-05 0. 2.2E-03 4.5E-05 3.8E-05 Composition Misfit: 4.841857E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 5.270 0.000000 0.037232 0.000000 0.000000 0.302058 0.035548 0.063027 0.136098 0.426037 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -2. 0. 0. 1. -0.1 -0.8 0.6 -0.2 Chi 0. 7.5E-03 0. 0. 1.3E-03 4.8E-05 1.1E-03 4.4E-04 4.5E-06 Composition Misfit: 1.034938E-02 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 49.458 0.095870 0.049504 0.000000 0.004378 0.000000 0.000000 0.000000 0.149752 0.700496 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.3 0.2 0. -0.9 0. 0. 0. 0.8 -0.3 Chi 1.9E-04 8.8E-05 0. 2.1E-03 0. 0. 0. 8.3E-04 5.1E-05 Composition Misfit: 3.238181E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 19.313 0.000000 0.000000 0.032765 0.075781 0.204778 0.000939 0.163928 0.136721 0.385088 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.1 0.4 0.3 2. Chi 0. 0. 4.0E-03 1.0E-03 2.0E-03 2.5E-04 1.9E-04 9.4E-05 2.5E-03 Composition Misfit: 1.001639E-02 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.002 0.000000 0.000000 0.354354 0.000000 0.624852 0.008982 0.011812 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. -0.2 0. 0.2 0.2 -0.3 0. 0. Chi 0. 0. 5.4E-05 0. 4.2E-05 1.2E-04 2.8E-04 0. 0. Composition Misfit: 4.894962E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 4.359 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.471 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.044293 0.025084 0.006374 0.031801 0.063461 0.002761 0.037924 0.055882 0.001190 0.172462 0.558767 Mica 0.006089 0.000705 0.000000 0.075580 0.008820 0.000000 0.007590 0.164042 0.000662 0.231330 0.505182 Gt 0.000000 0.037122 0.000000 0.000000 0.301168 0.035443 0.062841 0.000000 0.002948 0.135697 0.424781 Fsp 0.095870 0.049504 0.000000 0.004378 0.000000 0.000000 0.000000 0.000000 0.000000 0.149752 0.700496 Bio 0.000000 0.000000 0.029173 0.067473 0.182328 0.000836 0.145957 0.105774 0.003856 0.121732 0.342870 Ilm 0.000000 0.000000 0.330301 0.000000 0.582437 0.008372 0.011011 0.000000 0.067880 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -771130. -752375. -929448. -831168. -313491. -468355. -638601. -295994. -407238. -1633769. -883921. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 125 converged, 92 successes so far. Misfit function evaluations this try => 186 Misfit this try = 2.348841E-02 Best Misfit so far = 2.258697E-02 obtained on Try 80 Prior probability, PP = 9.268750E-07 Bayes score, PP * exp(-Misfit) = 9.053578E-07 Best Bayes score so far = 1.164898E-06 obtained on Try 89 P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky Initial coordinates: 7705.17 897.548 0.380554 0.513274 9.482342E-03 5.930187E-02 0.667022 4.751193E-02 9.668988E-03 0.207012 Final coordinates: 9313.72 937.405 0.519352 0.522318 2.848586E-03 9.321132E-02 0.681440 6.450818E-02 1.544666E-02 0.142545 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.348841E-2 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Mica vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 14.422 0.011809 0.001440 0.000000 0.085890 0.009480 0.000000 0.007836 0.280171 0.603374 observed 0.010359 0.000000 0.000000 0.084462 0.011155 0.000000 0.013546 0.280478 0.600000 std_resid. -0.2 0. 0. -0.1 0.3 0. 0.8 1.8E-02 -0.4 Chi 1.8E-04 0. 0. 2.4E-05 3.0E-04 0. 4.2E-03 3.4E-07 1.9E-05 Composition Misfit: 6.118262E-03 Gt vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.669 0.000000 0.031143 0.000000 0.000000 0.306687 0.033514 0.065929 0.136530 0.426199 observed 0.000000 0.020548 0.000000 0.000000 0.321918 0.034247 0.054795 0.143836 0.424658 std_resid. 0. -1. 0. 0. 0.9 0.1 -1. 0.5 -0.2 Chi 0. 3.6E-03 0. 0. 7.6E-04 1.6E-05 1.9E-03 3.9E-04 5.6E-06 Composition Misfit: 6.653578E-03 Fsp vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 67.483 0.096184 0.052141 0.000000 0.002746 0.000000 0.000000 0.000000 0.151070 0.697859 observed 0.091650 0.051595 0.000000 0.001358 0.000000 0.000000 0.000000 0.160896 0.694501 std_resid. -0.4 -0.1 0. -0.4 0. 0. 0. 0.7 -0.1 Chi 2.1E-04 5.7E-06 0. 7.0E-04 0. 0. 0. 6.4E-04 1.6E-05 Composition Misfit: 1.576505E-03 Bio vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 6.041 0.000000 0.000000 0.029062 0.075860 0.206790 0.000903 0.165207 0.137906 0.384272 observed 0.000000 0.000000 0.021368 0.066952 0.184473 0.001425 0.169516 0.140313 0.415954 std_resid. 0. 0. -1. -1. -1. 0.1 0.3 0.2 2. Chi 0. 0. 2.0E-03 1.0E-03 2.4E-03 3.0E-04 1.1E-04 4.2E-05 2.6E-03 Composition Misfit: 8.560627E-03 Ilm vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 0.925 0.000000 0.000000 0.347458 0.000000 0.632364 0.008431 0.011747 0.000000 0.000000 observed 0.000000 0.000000 0.350000 0.000000 0.630000 0.010000 0.010000 0.000000 0.000000 std_resid. 0. 0. 0.1 0. -0.1 0.2 -0.3 0. 0. Chi 0. 0. 1.9E-05 0. 8.8E-06 2.9E-04 2.6E-04 0. 0. Composition Misfit: 5.794384E-04 ky vol % Na2O CaO TiO2 K2O FeO MnO MgO Al2O3 SiO2 predicted 3.143 Composition Misfit zero by definition. *mole fractions relative to measured components, complete compositions below The following phases are in equilibrium with the observed assemblage as determined by the component saturation constraints: vol % Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 q 1.318 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O CaO TiO2 K2O FeO MnO MgO H2O O2 Al2O3 SiO2 Bulk 0.061826 0.035837 0.006558 0.016940 0.051482 0.003324 0.017560 0.031698 0.001671 0.167110 0.605993 Mica 0.009861 0.001202 0.000000 0.071719 0.007916 0.000000 0.006543 0.164362 0.000630 0.233945 0.503822 Gt 0.000000 0.031057 0.000000 0.000000 0.305840 0.033421 0.065747 0.000000 0.002761 0.136153 0.425022 Fsp 0.096184 0.052141 0.000000 0.002746 0.000000 0.000000 0.000000 0.000000 0.000000 0.151070 0.697859 Bio 0.000000 0.000000 0.025786 0.067307 0.183474 0.000801 0.146580 0.108828 0.003924 0.122356 0.340944 Ilm 0.000000 0.000000 0.322835 0.000000 0.587551 0.007833 0.010915 0.000000 0.070866 0.000000 0.000000 ky 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.500000 0.500000 ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- ----- Potentials -774951. -754798. -931728. -841928. -314568. -470125. -639442. -294414. -409395. -1635960. -885866. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Sp Gt ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Sp Gt ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 2 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 12499.0 928.496 0.524418 0.996494 8.553799E-02 0.209172 0.190525 0.456333 5.352265E-02 4.909903E-03 5.892951E-02 Mean perturbed parameters: 10918.5 925.917 0.517657 0.997202 0.120716 0.214226 0.221492 0.388063 5.044058E-02 5.062073E-03 4.075824E-02 Parameter standard deviation: 3160.97 5.15789 1.352377E-02 1.416538E-03 7.035608E-02 1.010775E-02 6.193536E-02 0.136539 6.164158E-03 3.043410E-04 3.634253E-02 -------------------------------------------------------------------------------- After 3 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 9616.34 995.319 0.689367 0.998778 0.367889 6.749332E-03 0.615215 6.088231E-03 5.477715E-04 3.511194E-03 0.153330 Mean perturbed parameters: 10484.4 949.051 0.574893 0.997727 0.203107 0.145067 0.352733 0.260738 3.380964E-02 4.545113E-03 7.828215E-02 Parameter standard deviation: 2243.79 51.0284 0.126561 1.174877E-03 0.157943 0.150452 0.260218 0.241923 3.338593E-02 1.223316E-03 9.595444E-02 -------------------------------------------------------------------------------- After 4 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 10866.5 999.656 0.950871 0.993714 0.503479 0.311834 2.083469E-02 6.143238E-02 0.102395 2.499672E-05 0.549637 Mean perturbed parameters: 10579.9 961.703 0.668888 0.996724 0.278200 0.186759 0.269758 0.210912 5.095590E-02 3.415084E-03 0.196121 Parameter standard deviation: 2033.51 60.6415 0.274235 2.605741E-03 0.238542 0.133962 0.251049 0.247524 4.186574E-02 3.158126E-03 0.314217 -------------------------------------------------------------------------------- After 5 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 14466.6 987.413 0.288086 1.00000 0.321156 0.320145 0.212992 8.262197E-02 3.023487E-02 3.285043E-02 0.184403 Mean perturbed parameters: 11357.3 966.845 0.592728 0.997379 0.286791 0.213436 0.258405 0.185254 4.681169E-02 9.302154E-03 0.193777 Parameter standard deviation: 3110.81 61.5177 0.262325 2.486768E-03 0.222496 0.126503 0.218309 0.244977 3.725399E-02 1.408617E-02 0.283893 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 6 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 11510.6 966.999 0.820355 0.999546 0.224456 0.406544 0.288226 3.715612E-03 7.416589E-02 2.891906E-03 1.68634 Mean perturbed parameters: 11382.8 966.870 0.630665 0.997740 0.276402 0.245621 0.263375 0.154997 5.137072E-02 8.233779E-03 0.442537 Parameter standard deviation: 2947.15 58.3849 0.272405 2.341521E-03 0.201355 0.140769 0.195915 0.260752 3.541207E-02 1.264178E-02 0.786186 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Gt Mica Bio fak ky mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Gt Mica Bio fak ky mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 7 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 14795.6 999.951 0.658560 0.994142 0.230860 0.258432 0.269470 0.196804 3.578320E-02 8.650619E-03 0.245516 Mean perturbed parameters: 11870.4 971.596 0.634650 0.997226 0.269896 0.247451 0.264246 0.160970 4.914393E-02 8.293328E-03 0.414391 Parameter standard deviation: 3493.19 61.7972 0.255874 2.633572E-03 0.186342 0.129494 0.178980 0.243271 3.267023E-02 1.162528E-02 0.723434 -------------------------------------------------------------------------------- Although Fsp Ilm Gt F ky mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt F ky mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 8 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 7649.01 961.770 0.101767 0.996283 0.149966 3.422301E-03 0.804345 1.576309E-05 2.185661E-02 2.039473E-02 15.4744 Mean perturbed parameters: 11342.7 970.368 0.568040 0.997108 0.254905 0.216948 0.331758 0.140850 4.573302E-02 9.806003E-03 2.29689 Parameter standard deviation: 3296.47 59.0283 0.282897 2.514589E-03 0.172533 0.145016 0.266399 0.255607 3.174544E-02 1.219678E-02 5.87851 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica fak ky mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica fak ky mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 9 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 9365.93 926.930 0.632877 0.998031 0.163186 0.228453 0.276109 0.260936 6.468981E-02 6.626196E-03 1.14528 Mean perturbed parameters: 11123.1 965.541 0.575244 0.997211 0.244714 0.218226 0.325575 0.154193 4.783933E-02 9.452691E-03 2.16893 Parameter standard deviation: 3083.58 55.2305 0.268117 2.352571E-03 0.161411 0.135689 0.249334 0.240002 3.032075E-02 1.141996E-02 5.51315 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio F minm ab the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio F minm ab -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 10 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 10300.1 904.946 0.628078 0.998700 0.297416 0.177085 0.353569 0.132214 3.776491E-02 1.951022E-03 5.580393E-02 Mean perturbed parameters: 11040.8 959.482 0.580527 0.997360 0.249984 0.214112 0.328374 0.151995 4.683189E-02 8.702524E-03 1.95762 Parameter standard deviation: 2924.86 52.4315 0.255783 2.233582E-03 0.159324 0.128699 0.237478 0.234756 2.876499E-02 1.082164E-02 5.19786 -------------------------------------------------------------------------------- After 11 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 13102.5 942.999 0.498367 0.998576 6.921399E-02 5.467806E-02 0.457314 0.407443 8.047210E-03 3.303280E-03 0.269464 Mean perturbed parameters: 11228.2 957.983 0.573058 0.997470 0.233550 0.199618 0.340096 0.175218 4.330601E-02 8.211684E-03 1.80415 Parameter standard deviation: 3019.35 50.1279 0.242690 2.129401E-03 0.153613 0.132727 0.234420 0.224427 2.998699E-02 1.028408E-02 4.93174 -------------------------------------------------------------------------------- After 12 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 8312.81 957.746 0.545436 0.994309 0.278785 0.237046 0.182862 0.237572 5.968324E-02 4.051447E-03 9.778626E-02 Mean perturbed parameters: 10985.2 957.964 0.570756 0.997207 0.237320 0.202737 0.326993 0.180414 4.467078E-02 7.864998E-03 1.66196 Parameter standard deviation: 2895.39 48.9080 0.231630 2.302407E-03 0.151078 0.126664 0.224494 0.215414 2.883195E-02 9.811753E-03 4.70229 -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 13 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 12484.4 956.176 0.549013 0.997689 0.236560 0.149965 0.546462 5.205183E-02 6.174469E-03 8.786052E-03 1.43041 Mean perturbed parameters: 11100.6 957.826 0.569084 0.997244 0.237262 0.198677 0.343876 0.170540 4.170952E-02 7.935848E-03 1.64414 Parameter standard deviation: 2917.13 47.7757 0.222041 2.205313E-03 0.146509 0.122911 0.231086 0.220250 3.005581E-02 9.450455E-03 4.52040 -------------------------------------------------------------------------------- After 14 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 12236.5 990.295 0.264965 0.994336 0.212035 0.140175 0.387890 0.237984 1.093540E-02 1.098111E-02 6.444792E-02 Mean perturbed parameters: 11181.7 960.145 0.547361 0.997036 0.235460 0.194499 0.347020 0.175357 3.951137E-02 8.153367E-03 1.53131 Parameter standard deviation: 2915.71 49.5157 0.223969 2.339189E-03 0.141620 0.120110 0.225175 0.212823 3.059269E-02 9.219503E-03 4.34308 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp St Ilm Gt Mica Bio ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp St Ilm Gt Mica Bio ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky fanth mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky fanth mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ep Ilm Gt Mica ky minm ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ep Ilm Gt Mica ky minm ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 15 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 11951.5 965.620 0.616722 0.997717 0.184923 0.231364 0.295287 0.219694 6.642394E-02 2.308480E-03 5.857687E-02 Mean perturbed parameters: 11233.0 960.510 0.551985 0.997082 0.232091 0.196956 0.343571 0.178313 4.130554E-02 7.763708E-03 1.43313 Parameter standard deviation: 2895.17 49.0344 0.217668 2.254686E-03 0.136689 0.115786 0.217286 0.206818 2.991697E-02 8.918014E-03 4.18511 -------------------------------------------------------------------------------- After 16 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 12445.3 991.060 0.758583 0.988623 0.140320 0.110062 0.615564 9.584763E-02 3.663702E-02 1.568954E-03 1.54271 Mean perturbed parameters: 11308.8 962.420 0.564897 0.996553 0.226355 0.191526 0.360570 0.173159 4.101376E-02 7.376535E-03 1.43998 Parameter standard deviation: 2909.80 50.4958 0.219797 3.239598E-03 0.132115 0.115360 0.229903 0.208004 2.903481E-02 8.666878E-03 4.06220 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica F fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica F fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 17 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 11845.5 990.881 1.00000 0.988917 0.457209 1.050754E-05 0.486966 2.241677E-06 5.581298E-02 2.831155E-13 34.1705 Mean perturbed parameters: 11340.4 964.094 0.590492 0.996104 0.239934 0.180260 0.368005 0.162973 4.188430E-02 6.942622E-03 3.36530 Parameter standard deviation: 2886.30 51.7261 0.245444 3.859282E-03 0.148452 0.124423 0.230193 0.216687 2.819218E-02 8.492313E-03 9.39947 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ep Ilm Gt Mica F ky minm ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ep Ilm Gt Mica F ky minm ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt F ky mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt F ky mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Chl Ilm Sp Gt Mica mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Chl Ilm Sp Gt Mica mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Opx fak ky ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Opx fak ky ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 18 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 8236.51 968.048 0.810624 0.994029 8.384446E-02 1.022925E-02 0.253086 0.522871 0.110453 1.951667E-02 5.257748E-02 Mean perturbed parameters: 11167.9 964.314 0.602721 0.995988 0.231263 0.170814 0.361621 0.182968 4.569367E-02 7.641180E-03 3.18126 Parameter standard deviation: 2812.83 51.3398 0.248965 3.860593E-03 0.145076 0.130924 0.223320 0.215910 3.134034E-02 8.939237E-03 9.11883 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 19 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 14984.2 962.942 0.300178 0.999988 0.205630 0.456013 0.147927 0.170302 2.012685E-02 9.700629E-07 0.311421 Mean perturbed parameters: 11368.8 964.241 0.586798 0.996199 0.229914 0.185824 0.350374 0.182301 4.434805E-02 7.239064E-03 3.03021 Parameter standard deviation: 3040.33 50.7591 0.246995 3.783642E-03 0.141475 0.138933 0.218422 0.212765 3.112631E-02 8.773849E-03 8.86217 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp iron the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp iron -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Ilm Sp Gt Mica mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Ilm Sp Gt Mica mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 20 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 10146.5 948.013 0.389753 0.997728 0.178047 0.358508 0.155197 0.271561 2.427215E-02 1.241445E-02 8.819374E-02 Mean perturbed parameters: 11307.7 963.430 0.576946 0.996275 0.227320 0.194458 0.340615 0.186764 4.334425E-02 7.497833E-03 2.88311 Parameter standard deviation: 2965.04 49.7285 0.242009 3.682963E-03 0.137795 0.138948 0.213764 0.207386 3.075560E-02 8.698126E-03 8.62581 -------------------------------------------------------------------------------- After 21 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 7266.33 927.887 0.475716 0.998355 0.120298 0.140313 0.317435 0.373011 4.059252E-02 8.349855E-03 2.998115E-02 Mean perturbed parameters: 11115.2 961.737 0.572125 0.996374 0.222224 0.191880 0.339511 0.195633 4.321322E-02 7.538405E-03 2.74725 Parameter standard deviation: 2926.86 48.4800 0.236012 3.591085E-03 0.134542 0.136576 0.208858 0.202484 3.001501E-02 8.506828E-03 8.40740 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 22 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 7189.34 997.792 0.968977 0.999663 0.466106 0.175000 2.719921E-03 0.263202 8.569455E-02 7.277107E-03 0.823601 Mean perturbed parameters: 10936.8 963.376 0.590164 0.996524 0.233310 0.191113 0.324203 0.198704 4.514419E-02 7.526528E-03 2.65981 Parameter standard deviation: 2894.55 50.0235 0.251081 3.525349E-03 0.147722 0.133635 0.210984 0.197990 3.046283E-02 8.314010E-03 8.20665 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Fsp Ilm Gt Mica Bio fak ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Fsp Ilm Gt Mica Bio fak ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio fanth the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio fanth -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 23 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 8037.16 913.395 0.563570 0.998202 0.140690 0.179106 0.259100 0.366847 4.944523E-02 4.812734E-03 5.803950E-02 Mean perturbed parameters: 10810.7 961.203 0.589008 0.996597 0.229283 0.190591 0.321372 0.206015 4.533119E-02 7.408537E-03 2.54669 Parameter standard deviation: 2841.56 48.9194 0.245565 3.444856E-03 0.144362 0.130843 0.206138 0.193698 2.976577E-02 8.123309E-03 8.01797 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 24 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 6050.62 922.710 0.959470 0.999261 0.107128 8.211945E-03 0.625785 1.740281E-03 1.372835E-03 0.255762 5.90594 Mean perturbed parameters: 10612.4 959.599 0.604444 0.996708 0.224193 0.182992 0.334056 0.197503 4.349959E-02 1.775658E-02 2.68666 Parameter standard deviation: 2862.39 47.8443 0.257738 3.380891E-03 0.141555 0.135323 0.216114 0.200713 3.064999E-02 5.284337E-02 7.93710 -------------------------------------------------------------------------------- After 25 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 8844.02 954.926 0.521640 0.996611 0.318228 0.255767 0.144927 0.207591 6.591726E-02 7.568687E-03 0.269415 Mean perturbed parameters: 10541.6 959.412 0.601131 0.996704 0.227954 0.185903 0.326491 0.197907 4.439630E-02 1.734906E-02 2.58997 Parameter standard deviation: 2803.94 47.2786 0.252321 3.320309E-03 0.142481 0.132683 0.212699 0.197818 3.024286E-02 5.173299E-02 7.77015 -------------------------------------------------------------------------------- After 26 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 9714.78 801.247 0.604718 0.999824 0.270265 2.143669E-03 0.708359 1.867046E-04 7.323504E-03 1.172247E-02 3.18957 Mean perturbed parameters: 10509.8 953.329 0.601269 0.996824 0.229582 0.178835 0.341178 0.190302 4.297042E-02 1.713266E-02 2.61303 Parameter standard deviation: 2748.32 52.3652 0.247934 3.275677E-03 0.141464 0.137064 0.227475 0.204089 3.069458E-02 5.070448E-02 7.63947 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica fak ky mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica fak ky mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky minm ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky minm ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ep St Ilm Gt Mica Bio ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ep St Ilm Gt Mica Bio ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 27 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 11249.8 866.868 0.958412 0.955465 0.275857 1.944924E-03 0.710846 9.784050E-03 3.334656E-04 1.234210E-03 5.53942 Mean perturbed parameters: 10537.2 950.127 0.614497 0.995292 0.231296 0.172284 0.354869 0.183616 4.139128E-02 1.654383E-02 2.72142 Parameter standard deviation: 2720.91 52.5290 0.258476 8.922456E-03 0.140698 0.140999 0.240492 0.209157 3.147971E-02 4.972596E-02 7.56884 -------------------------------------------------------------------------------- After 28 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 10615.5 932.236 0.575173 0.997782 0.156813 0.239258 0.281350 0.269619 4.758802E-02 5.372327E-03 5.393049E-02 Mean perturbed parameters: 10540.0 949.488 0.613093 0.995381 0.228635 0.174675 0.352244 0.186688 4.161259E-02 1.614484E-02 2.62615 Parameter standard deviation: 2681.34 51.5755 0.253946 8.755701E-03 0.138068 0.138417 0.236062 0.205474 3.089129E-02 4.879643E-02 7.42736 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt fak ky ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt fak ky ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 29 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 14089.0 979.694 0.878428 0.996528 0.185137 0.118913 0.283476 0.365686 4.066658E-02 6.122781E-03 0.279549 Mean perturbed parameters: 10662.4 950.529 0.622242 0.995421 0.227136 0.172753 0.349872 0.192860 4.157997E-02 1.579925E-02 2.54523 Parameter standard deviation: 2781.90 51.7538 0.258862 8.601892E-03 0.135693 0.137240 0.231882 0.201958 3.036099E-02 4.791745E-02 7.29368 -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica F ky fanth mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica F ky fanth mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Bio ky ab q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Bio ky ab q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt F ky minm mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt F ky minm mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 30 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 14630.4 998.244 0.550170 0.992441 0.352137 0.302689 0.303396 1.662552E-02 2.305685E-02 2.095776E-03 0.199290 Mean perturbed parameters: 10794.7 952.120 0.619840 0.995321 0.231302 0.177084 0.348323 0.186986 4.096253E-02 1.534247E-02 2.46703 Parameter standard deviation: 2904.81 52.7217 0.254464 8.513079E-03 0.138223 0.135739 0.228045 0.206277 3.017231E-02 4.708760E-02 7.16690 -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica F fak ky mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica F fak ky mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 31 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 8049.16 949.988 0.522656 0.998062 0.116598 0.217429 0.221516 0.386930 5.572590E-02 1.800446E-03 3.230858E-02 Mean perturbed parameters: 10706.1 952.051 0.616705 0.995410 0.227602 0.178385 0.344233 0.193436 4.143877E-02 1.490563E-02 2.38849 Parameter standard deviation: 2865.67 52.0634 0.250197 8.370038E-03 0.136089 0.133458 0.224283 0.203180 2.970449E-02 4.630035E-02 7.04644 -------------------------------------------------------------------------------- Although Fsp Ilm Sp Gt Mica ky mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Sp Gt Mica ky mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio F ab ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio F ab ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 32 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 10233.0 931.764 0.511324 0.999425 0.158069 0.171765 0.253424 0.351240 6.246429E-02 3.037959E-03 8.021338E-02 Mean perturbed parameters: 10691.3 951.417 0.613412 0.995535 0.225429 0.178178 0.341395 0.198367 4.209581E-02 1.453477E-02 2.31636 Parameter standard deviation: 2823.65 51.2392 0.246128 8.238428E-03 0.133876 0.131565 0.220636 0.199955 2.934714E-02 4.554913E-02 6.93186 -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Mica Bio ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Mica Bio ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky ab ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky ab ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 33 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 10344.7 997.800 0.927003 0.999829 0.236022 0.114696 0.383966 0.228409 3.587627E-02 1.030620E-03 0.167317 Mean perturbed parameters: 10680.8 952.823 0.622914 0.995665 0.225750 0.176255 0.342685 0.199277 4.190734E-02 1.412555E-02 2.25124 Parameter standard deviation: 2784.87 52.1217 0.253173 8.115775E-03 0.132527 0.130806 0.218402 0.197468 2.895618E-02 4.483787E-02 6.82274 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky minm q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky minm q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 34 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 8573.47 976.304 0.747027 0.996994 0.159971 0.235903 6.938497E-02 0.354552 0.110167 7.002114E-02 0.111882 Mean perturbed parameters: 10618.8 953.513 0.626565 0.995704 0.223816 0.178009 0.334647 0.203844 4.391499E-02 1.576954E-02 2.18832 Parameter standard deviation: 2745.58 52.1475 0.252674 7.993452E-03 0.130506 0.128842 0.217416 0.194547 3.053845E-02 4.557174E-02 6.71859 -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica Bio the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica Bio -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica fak ky mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica fak ky mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp St Ilm Gt Mica F mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp St Ilm Gt Mica F mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky rieb mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky rieb mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt ky mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt ky mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 35 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 8854.78 939.233 0.394494 0.995471 0.230942 0.174490 0.328027 0.234199 2.772708E-02 4.615399E-03 3.148017E-02 Mean perturbed parameters: 10568.4 953.105 0.619934 0.995698 0.224019 0.177909 0.334458 0.204712 4.345248E-02 1.545085E-02 2.12669 Parameter standard deviation: 2706.17 51.4471 0.249730 7.886127E-03 0.129215 0.127165 0.214587 0.192226 3.027379E-02 4.489668E-02 6.61905 -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 36 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 7550.10 884.970 0.591633 0.998246 0.360137 0.141888 0.436271 1.400954E-02 2.639203E-02 2.130279E-02 4.627290E-02 Mean perturbed parameters: 10484.6 951.213 0.619148 0.995769 0.227800 0.176908 0.337286 0.199414 4.297858E-02 1.561340E-02 2.06890 Parameter standard deviation: 2684.29 51.1199 0.246514 7.772859E-03 0.131952 0.126016 0.213769 0.196384 3.004790E-02 4.433414E-02 6.52381 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio F ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio F ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Sp Gt Mica ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Sp Gt Mica ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Sp Gt Mica Bio the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Sp Gt Mica Bio -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 37 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 9544.97 999.717 0.538095 0.484695 0.631912 0.272657 2.448539E-07 8.531751E-06 7.210340E-02 2.331850E-02 1.20443 Mean perturbed parameters: 10459.2 952.524 0.616957 0.981956 0.238722 0.179496 0.328170 0.194025 4.376574E-02 1.582165E-02 2.04554 Parameter standard deviation: 2646.97 51.9875 0.243109 8.587851E-02 0.152387 0.124572 0.214938 0.200838 2.991329E-02 4.381806E-02 6.43558 -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 38 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 7921.96 963.231 0.676523 0.998621 0.248263 0.198013 0.297865 0.180857 7.362453E-02 1.377858E-03 2.567019E-02 Mean perturbed parameters: 10392.4 952.805 0.618525 0.982394 0.238973 0.179983 0.327372 0.193678 4.455150E-02 1.544155E-02 1.99238 Parameter standard deviation: 2621.32 51.6979 0.241342 8.471012E-02 0.151079 0.122926 0.212145 0.199418 2.982059E-02 4.322647E-02 6.34801 -------------------------------------------------------------------------------- After 39 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 8738.14 992.061 0.565713 0.976379 0.263321 0.219817 0.307683 0.163304 4.208588E-02 3.789375E-03 6.652122E-02 Mean perturbed parameters: 10350.0 953.812 0.617171 0.982240 0.239598 0.181004 0.326867 0.192900 4.448827E-02 1.514278E-02 1.94300 Parameter standard deviation: 2588.43 52.2170 0.238311 8.366103E-02 0.150093 0.121298 0.209526 0.198408 2.943802E-02 4.265454E-02 6.26393 -------------------------------------------------------------------------------- Although Fsp Ilm Gt F ky minm mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt F ky minm mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica F fak ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica F fak ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 40 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 5809.49 926.905 0.587812 0.999288 0.123100 8.882570E-02 0.275476 0.449236 5.665284E-02 6.709508E-03 7.179335E-02 Mean perturbed parameters: 10236.5 953.139 0.616437 0.982666 0.236685 0.178700 0.325583 0.199308 4.479239E-02 1.493194E-02 1.89622 Parameter standard deviation: 2616.75 51.5464 0.235558 8.258178E-02 0.148249 0.121542 0.206855 0.196941 2.909625E-02 4.210481E-02 6.18311 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Opx ky mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Opx ky mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ru iron the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ru iron -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica F ky mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica F ky mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 41 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 8419.31 931.610 0.344412 0.995865 0.137906 0.178310 0.161498 0.473762 3.903164E-02 9.491396E-03 6.364266E-02 Mean perturbed parameters: 10192.2 952.614 0.609802 0.982988 0.234276 0.178690 0.321581 0.206002 4.465188E-02 1.479925E-02 1.85153 Parameter standard deviation: 2587.92 50.9148 0.234080 8.154362E-02 0.146412 0.120187 0.204759 0.195982 2.876040E-02 4.158067E-02 6.10534 -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 42 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 12048.7 983.039 0.281379 0.993802 0.175041 0.222319 0.234621 0.349213 1.621743E-02 2.588813E-03 4.899857E-02 Mean perturbed parameters: 10236.4 953.339 0.601982 0.983246 0.232865 0.179729 0.319510 0.209412 4.397487E-02 1.450852E-02 1.80861 Parameter standard deviation: 2590.98 51.1470 0.233970 8.054560E-02 0.144646 0.118714 0.202266 0.193631 2.882080E-02 4.107251E-02 6.03042 -------------------------------------------------------------------------------- After 43 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 6936.96 948.777 0.589630 0.998208 0.154132 0.215771 0.259703 0.315566 4.915650E-02 5.671645E-03 6.035306E-02 Mean perturbed parameters: 10159.7 953.232 0.601695 0.983594 0.231034 0.180567 0.318119 0.211880 4.409537E-02 1.430301E-02 1.76795 Parameter standard deviation: 2586.62 50.6867 0.231486 7.958096E-02 0.142914 0.117293 0.199846 0.191313 2.847698E-02 4.058066E-02 5.95820 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 44 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 7886.88 936.855 0.678126 0.997023 0.300772 2.129295E-02 0.458404 0.187809 2.356127E-02 8.161305E-03 0.816234 Mean perturbed parameters: 10108.0 952.860 0.603432 0.983899 0.232619 0.176948 0.321308 0.211333 4.362869E-02 1.416343E-02 1.74632 Parameter standard deviation: 2565.93 50.1362 0.230196 7.865028E-02 0.142960 0.119789 0.199990 0.190144 2.837692E-02 4.010854E-02 5.88976 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 45 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 11141.8 935.286 0.343101 0.996653 0.178689 0.287151 0.140322 0.352345 3.304402E-02 8.449210E-03 0.158586 Mean perturbed parameters: 10131.0 952.470 0.597647 0.984182 0.231421 0.179397 0.317286 0.214467 4.339348E-02 1.403645E-02 1.71104 Parameter standard deviation: 2551.13 49.5960 0.228967 7.775162E-02 0.141368 0.118861 0.198426 0.188035 2.813548E-02 3.965314E-02 5.82248 -------------------------------------------------------------------------------- After 46 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 8350.55 957.031 0.575452 0.996785 0.300318 0.119789 0.276817 0.231110 6.444356E-02 7.522879E-03 0.200214 Mean perturbed parameters: 10092.3 952.569 0.597165 0.984456 0.232919 0.178101 0.316406 0.214829 4.385109E-02 1.389485E-02 1.67819 Parameter standard deviation: 2526.92 49.2983 0.226613 7.688304E-02 0.141437 0.118465 0.196243 0.186403 2.793744E-02 3.921158E-02 5.75748 -------------------------------------------------------------------------------- After 47 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 6801.29 945.420 0.573801 0.998851 0.208148 0.180904 0.289599 0.261993 5.153006E-02 7.825391E-03 3.765916E-02 Mean perturbed parameters: 10022.3 952.417 0.596667 0.984762 0.232392 0.178160 0.315836 0.215832 4.401447E-02 1.376571E-02 1.64329 Parameter standard deviation: 2527.13 48.8681 0.224328 7.604289E-02 0.140103 0.117307 0.194175 0.184563 2.763895E-02 3.878494E-02 5.69456 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky fanth minm the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky fanth minm -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt Bio q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt Bio q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Melt Fsp St Ilm Gt Mica F mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp St Ilm Gt Mica F mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 48 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 6665.84 959.393 0.587912 0.994977 0.253763 1.573128E-03 0.713019 1.885353E-02 9.643662E-04 1.182673E-02 0.688022 Mean perturbed parameters: 9952.32 952.562 0.596485 0.984975 0.232837 0.174481 0.324110 0.211729 4.311759E-02 1.372532E-02 1.62339 Parameter standard deviation: 2530.31 48.6306 0.222213 7.523079E-02 0.139338 0.120318 0.203506 0.187792 2.816832E-02 3.838224E-02 5.63449 -------------------------------------------------------------------------------- After 49 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 10149.4 1000.000 0.999932 0.225818 0.195980 1.688898E-16 0.797248 7.238676E-09 3.377866E-03 3.394619E-03 4.91914 Mean perturbed parameters: 9956.35 953.530 0.604719 0.969482 0.232085 0.170921 0.333766 0.207408 4.230658E-02 1.351448E-02 1.69065 Parameter standard deviation: 2506.55 49.3772 0.230938 0.134019 0.138000 0.123193 0.216183 0.191472 2.858709E-02 3.798122E-02 5.62010 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt F ky mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt F ky mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 50 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 11956.6 997.084 0.999995 0.974083 0.130880 5.768630E-02 0.275130 0.472214 6.408917E-02 2.109978E-08 0.204933 Mean perturbed parameters: 9996.35 954.401 0.612624 0.969574 0.230061 0.168656 0.332593 0.212704 4.274223E-02 1.324420E-02 1.66093 Parameter standard deviation: 2508.88 49.9933 0.239010 0.132688 0.136631 0.124096 0.213990 0.190755 2.839465E-02 3.759904E-02 5.56252 -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 51 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 9578.67 931.905 0.494665 0.998041 0.191236 0.183907 0.223180 0.363620 3.264114E-02 5.415521E-03 0.186425 Mean perturbed parameters: 9988.16 953.960 0.610311 0.970132 0.229299 0.168955 0.330448 0.215663 4.254417E-02 1.309069E-02 1.63202 Parameter standard deviation: 2483.90 49.5057 0.236619 0.131354 0.135350 0.122951 0.211880 0.188939 2.818622E-02 3.722116E-02 5.50666 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica fak ky mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica fak ky mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 52 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 9938.47 993.455 0.806071 0.997658 4.600112E-02 0.125465 0.140833 0.525494 0.140208 2.199877E-02 0.158941 Mean perturbed parameters: 9987.21 954.720 0.614076 0.970662 0.225774 0.168119 0.326802 0.221621 4.442232E-02 1.326200E-02 1.60369 Parameter standard deviation: 2460.87 49.9916 0.237906 0.130060 0.134897 0.122446 0.210374 0.189282 3.078839E-02 3.692931E-02 5.45244 -------------------------------------------------------------------------------- After 53 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 10110.7 935.167 0.562674 0.998020 0.263130 0.381698 0.141440 0.139568 6.670041E-02 7.463706E-03 0.765003 Mean perturbed parameters: 9989.54 954.351 0.613106 0.971178 0.226479 0.172148 0.323304 0.220073 4.484266E-02 1.315260E-02 1.58787 Parameter standard deviation: 2439.44 49.5357 0.235717 0.128804 0.134419 0.123337 0.208910 0.189112 3.060866E-02 3.657383E-02 5.40074 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 54 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 7605.22 973.975 0.502501 0.997794 0.349942 6.788686E-02 0.312186 0.205053 5.467881E-02 1.025248E-02 0.180057 Mean perturbed parameters: 9945.38 954.714 0.611058 0.971671 0.228766 0.170218 0.323098 0.219795 4.502481E-02 1.309889E-02 1.56180 Parameter standard deviation: 2428.01 49.5567 0.233485 0.127583 0.135787 0.123925 0.207092 0.187982 3.033520E-02 3.623376E-02 5.34959 -------------------------------------------------------------------------------- After 55 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 6729.28 937.540 0.439075 0.998490 0.180310 0.188877 0.239640 0.337111 4.381966E-02 1.024202E-02 3.117453E-02 Mean perturbed parameters: 9886.91 954.402 0.607931 0.972159 0.227885 0.170557 0.321581 0.221928 4.500290E-02 1.304695E-02 1.53397 Parameter standard deviation: 2431.48 49.1337 0.231519 0.126396 0.134565 0.122842 0.205173 0.186248 3.005686E-02 3.590321E-02 5.29983 -------------------------------------------------------------------------------- Although Fsp Fsp St Ilm Gt ky mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp St Ilm Gt ky mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 56 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 9863.93 970.511 0.505663 0.998155 0.175296 0.185727 0.301007 0.292402 4.322909E-02 2.338227E-03 8.227836E-02 Mean perturbed parameters: 9886.50 954.690 0.606105 0.972623 0.226945 0.170828 0.321213 0.223186 4.497122E-02 1.285572E-02 1.50805 Parameter standard deviation: 2410.32 49.0988 0.229406 0.125241 0.133361 0.121804 0.203404 0.184584 2.978757E-02 3.557744E-02 5.25143 -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica F ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica F ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 57 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 12692.6 974.195 0.893816 0.999763 0.265165 0.308271 0.321552 5.490033E-02 4.733021E-02 2.781862E-03 1.32179 Mean perturbed parameters: 9935.73 955.032 0.611152 0.973099 0.227616 0.173239 0.321219 0.220234 4.501261E-02 1.267899E-02 1.50478 Parameter standard deviation: 2430.40 49.1307 0.233036 0.124118 0.132970 0.121296 0.201792 0.186322 2.952041E-02 3.525985E-02 5.20723 -------------------------------------------------------------------------------- After 58 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 9160.40 972.507 0.560096 0.996706 7.009961E-02 0.251932 0.192659 0.398674 7.489463E-02 1.174023E-02 3.463089E-02 Mean perturbed parameters: 9922.36 955.333 0.610272 0.973506 0.224900 0.174596 0.319003 0.223310 4.552782E-02 1.266280E-02 1.47943 Parameter standard deviation: 2409.10 49.1314 0.231075 0.123025 0.132287 0.120305 0.200170 0.184975 2.948675E-02 3.495987E-02 5.16135 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky minm ab the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky minm ab -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica Bio F the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica Bio F -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky minm the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky minm -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp St Ilm Gt ky mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp St Ilm Gt ky mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky mstp the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky mstp -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 59 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 10655.7 992.416 0.938307 0.919245 0.275444 0.120016 0.208434 0.259710 0.135902 4.939361E-04 0.170325 Mean perturbed parameters: 9934.79 955.962 0.615832 0.972586 0.225757 0.173671 0.317129 0.223927 4.705958E-02 1.245655E-02 1.45724 Parameter standard deviation: 2394.50 49.5433 0.235849 0.122396 0.132078 0.119974 0.198521 0.183543 3.145867E-02 3.466272E-02 5.11670 -------------------------------------------------------------------------------- After 60 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 7613.37 956.337 0.595889 0.998851 0.258369 0.237055 0.277130 0.177203 4.514709E-02 5.096870E-03 9.758286E-02 Mean perturbed parameters: 9896.10 955.968 0.615499 0.973024 0.226300 0.174727 0.316462 0.223149 4.702770E-02 1.233389E-02 1.43458 Parameter standard deviation: 2384.72 49.3092 0.234103 0.121355 0.131632 0.118975 0.196858 0.182926 3.119226E-02 3.436772E-02 5.07316 -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Bio ky q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Bio ky q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt ky minm mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt ky minm mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 61 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 10478.6 956.782 0.622691 0.995473 0.166743 0.177288 0.491188 0.112378 4.575128E-02 6.651085E-03 206.011 Mean perturbed parameters: 9905.65 955.981 0.615617 0.973392 0.225324 0.174769 0.319327 0.221333 4.700678E-02 1.224073E-02 4.78830 Parameter standard deviation: 2369.34 49.0868 0.232592 0.120340 0.130538 0.118104 0.197629 0.183361 3.093193E-02 3.408062E-02 27.0647 -------------------------------------------------------------------------------- After 62 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 9314.16 983.091 0.918770 0.821289 0.404571 0.311460 2.402297E-03 7.189067E-02 0.179574 3.010219E-02 1.94235 Mean perturbed parameters: 9896.11 956.418 0.620507 0.970939 0.228215 0.176974 0.314215 0.218922 4.914495E-02 1.252882E-02 4.74239 Parameter standard deviation: 2349.84 49.2803 0.236515 0.121473 0.133321 0.117725 0.198600 0.184601 3.503813E-02 3.395000E-02 26.8430 -------------------------------------------------------------------------------- After 63 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 10859.5 968.720 0.791219 0.998080 0.284776 0.199076 0.326043 0.112371 7.498758E-02 2.747356E-03 6.268827E-02 Mean perturbed parameters: 9911.40 956.614 0.623217 0.971370 0.229113 0.177325 0.314403 0.217231 4.955515E-02 1.237356E-02 4.66811 Parameter standard deviation: 2338.81 49.2198 0.237286 0.120489 0.133251 0.116800 0.197213 0.184991 3.493110E-02 3.367655E-02 26.6257 -------------------------------------------------------------------------------- After 64 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 10991.3 996.499 0.223865 0.984213 0.316266 0.314827 0.346444 1.475665E-02 6.319534E-03 1.386245E-03 5.659668E-02 Mean perturbed parameters: 9928.27 957.237 0.616977 0.971570 0.230475 0.179473 0.314903 0.214067 4.887960E-02 1.220188E-02 4.59606 Parameter standard deviation: 2329.51 49.6900 0.238157 0.119542 0.133724 0.116493 0.196000 0.187498 3.503637E-02 3.341169E-02 26.4135 -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica fak ky minm ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica fak ky minm ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky mstp ru q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky mstp ru q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 65 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 10383.4 929.999 0.540982 0.997329 0.115959 0.203919 0.310262 0.330185 3.212282E-02 7.552027E-03 9.807967E-02 Mean perturbed parameters: 9935.28 956.818 0.615808 0.971966 0.228713 0.179849 0.314832 0.215854 4.862180E-02 1.213034E-02 4.52686 Parameter standard deviation: 2314.93 49.3073 0.236319 0.118604 0.132769 0.115595 0.194597 0.186032 3.481370E-02 3.315092E-02 26.2064 -------------------------------------------------------------------------------- Although Fsp Fsp Ilm Gt Mica fak ky mstp ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Fsp Ilm Gt Mica fak ky mstp ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Fsp Ilm Gt Mica ky mstp q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Fsp Ilm Gt Mica ky mstp q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 66 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 12056.4 931.710 0.994612 0.999841 0.244217 1.757391E-04 0.754785 1.539074E-04 5.843638E-04 8.331107E-05 5.52902 Mean perturbed parameters: 9967.41 956.437 0.621547 0.972389 0.228948 0.177127 0.321498 0.212586 4.789396E-02 1.194781E-02 4.54204 Parameter standard deviation: 2321.67 48.9376 0.242048 0.117688 0.132198 0.117878 0.202897 0.188805 3.502865E-02 3.290108E-02 26.0130 -------------------------------------------------------------------------------- After 67 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 9460.06 972.274 0.996212 0.993470 0.330563 1.823334E-04 0.640383 2.872557E-02 4.571604E-06 1.410760E-04 5.83845 Mean perturbed parameters: 9959.84 956.674 0.627139 0.972703 0.230464 0.174486 0.326257 0.209841 4.717919E-02 1.177159E-02 4.56139 Parameter standard deviation: 2304.06 48.9375 0.247524 0.116795 0.132943 0.120050 0.206939 0.190764 3.524757E-02 3.265685E-02 25.8251 -------------------------------------------------------------------------------- Although Melt Fsp Ilm Gt Mica ky minm ru the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Melt Fsp Ilm Gt Mica ky minm ru -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 68 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 9821.13 942.448 0.504736 0.998483 0.207143 0.370412 0.111854 0.243434 6.314269E-02 4.015348E-03 8.667749E-02 Mean perturbed parameters: 9957.80 956.465 0.625339 0.973083 0.230122 0.177367 0.323104 0.210335 4.741395E-02 1.165753E-02 4.49559 Parameter standard deviation: 2287.56 48.6270 0.245671 0.115920 0.132096 0.120573 0.206106 0.189564 3.503664E-02 3.241256E-02 25.6316 -------------------------------------------------------------------------------- After 69 successful perturbations: P_bar T_K C_O2 C_H2O Mica Gt Fsp Bio Ilm ky OBJF Central model parameters: 9337.99 923.339 0.510895 0.997910 0.155894 0.219280 0.252460 0.319793 4.735850E-02 5.214244E-03 2.258697E-02 Perturbed central model parameter: 10321.9 985.996 0.381432 0.999066 0.195090 0.152312 0.393626 0.239575 1.904246E-02 3.538799E-04 0.125655 Mean perturbed parameters: 9963.08 956.893 0.621804 0.973459 0.229614 0.177004 0.324126 0.210759 4.700277E-02 1.149371E-02 4.43225 Parameter standard deviation: 2273.81 48.8626 0.244363 0.115064 0.131207 0.119958 0.205299 0.188417 3.494718E-02 3.217875E-02 25.4424