-------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 1 converged, 1 successes so far. Misfit function evaluations this try => 150 Misfit this try = 3.696255E-05 Best Misfit so far = 3.696255E-05 obtained on Try 1 Prior probability, PP = 1.482857E-07 Bayes score, PP * exp(-Misfit) = 1.482803E-07 Best Bayes score so far = 1.482803E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10500.0 900.000 0.500000 0.500000 0.500000 Final coordinates: 11507.3 1032.00 0.149033 0.384815 0.615185 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.654077E-5 Extraneous predicted phases: 4.217816E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 38.469 0.013562 0.139512 0.007087 0.216995 0.118265 0.504579 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.1 0.4 0.2 0.7 -0.7 -0.5 Chi 4.7E-07 2.2E-06 7.7E-06 2.9E-06 6.1E-06 8.4E-07 Composition Misfit: 2.017279E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 61.530 0.000000 0.052816 0.124590 0.158045 0.242827 0.421721 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.6 0.2 -0.5 0.8 0.1 Chi 0. 8.4E-06 6.6E-07 3.3E-06 4.0E-06 2.8E-08 Composition Misfit: 1.636798E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005151 0.085360 0.079065 0.179291 0.193767 0.007219 0.450148 Augite(G) 0.013480 0.138664 0.007044 0.215677 0.117547 0.006073 0.501515 Gt(W) 0.000000 0.052398 0.123602 0.156792 0.240902 0.007929 0.418378 ----- ----- ----- ----- ----- ----- ----- Potentials -782231. -643458. -1658568. -746659. -322951. -443497. -891551. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 2 converged, 2 successes so far. Misfit function evaluations this try => 225 Misfit this try = 7.151131E-04 Best Misfit so far = 3.696255E-05 obtained on Try 1 Prior probability, PP = 1.338284E-07 Bayes score, PP * exp(-Misfit) = 1.337327E-07 Best Bayes score so far = 1.482803E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 1901.09 632.898 0.292163 5.850630E-02 0.941494 Final coordinates: 5693.44 903.762 0.134463 0.121892 0.878108 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.133933E-4 Extraneous predicted phases: 1.719801E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 12.770 0.012994 0.142803 0.009227 0.221366 0.113483 0.500127 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.9 -2. -2. -3. 3. 3. Chi 1.8E-05 5.3E-05 3.9E-04 5.8E-05 1.4E-04 2.9E-05 Composition Misfit: 6.879578E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 87.228 0.000000 0.051302 0.125207 0.156499 0.245040 0.421952 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 0.8 -0.3 0.5 -1. -0.1 Chi 0. 1.4E-05 8.6E-07 4.4E-06 6.1E-06 3.6E-08 Composition Misfit: 2.543549E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 Fsp(C1) 0.002 0.078593 0.000000 0.171407 0.092814 0.000000 0.000000 0.657186 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.001631 0.062388 0.109706 0.163442 0.226669 0.007620 0.428546 Augite(G) 0.012899 0.141758 0.009160 0.219745 0.112652 0.007321 0.496466 Gt(W) 0.000000 0.050909 0.124247 0.155299 0.243162 0.007663 0.418719 ----- ----- ----- ----- ----- ----- ----- Potentials -738900. -630071. -1645748. -737066. -307020. -461544. -896768. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 3 converged, 3 successes so far. Misfit function evaluations this try => 145 Misfit this try = 9.111075E-04 Best Misfit so far = 3.696255E-05 obtained on Try 1 Prior probability, PP = 1.484472E-08 Bayes score, PP * exp(-Misfit) = 1.483120E-08 Best Bayes score so far = 1.482803E-07 obtained on Try 1 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17793.8 762.800 0.923576 0.119607 0.880393 Final coordinates: 18265.8 1148.72 0.135230 0.137410 0.862590 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.104000E-4 Extraneous predicted phases: 7.074661E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 13.392 0.013915 0.136154 0.005796 0.213800 0.122971 0.507364 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.8 3. 1. 4. -5. -3. Chi 1.3E-05 1.1E-04 4.0E-04 7.5E-05 2.5E-04 2.3E-05 Composition Misfit: 8.750753E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 86.607 0.000000 0.053185 0.124533 0.158239 0.242342 0.421700 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 0.3 -0.6 1. 0.1 Chi 0. 2.0E-05 9.5E-07 5.3E-06 9.0E-06 4.0E-08 Composition Misfit: 3.532473E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.001838 0.063743 0.107898 0.164376 0.224727 0.007597 0.429820 Augite(G) 0.013841 0.135436 0.005765 0.212672 0.122322 0.005277 0.504686 Gt(W) 0.000000 0.052762 0.123543 0.156981 0.240415 0.007953 0.418346 ----- ----- ----- ----- ----- ----- ----- Potentials -798113. -649371. -1669083. -748391. -330983. -449151. -890202. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 4 converged, 4 successes so far. Misfit function evaluations this try => 115 Misfit this try = 3.991131E-05 Best Misfit so far = 3.696255E-05 obtained on Try 1 Prior probability, PP = 1.545428E-07 Bayes score, PP * exp(-Misfit) = 1.545366E-07 Best Bayes score so far = 1.545366E-07 obtained on Try 4 P_bar T_K C_O2 Cpx Gt Initial coordinates: 6376.56 1141.59 7.867482E-02 0.230432 0.769568 Final coordinates: 11278.3 1026.38 0.134220 0.115871 0.884129 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.859143E-5 Extraneous predicted phases: 1.319881E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 11.596 0.013580 0.139190 0.006996 0.216971 0.118608 0.504656 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.2 0.6 0.3 0.8 -1. -0.6 Chi 7.1E-07 5.5E-06 1.5E-05 3.1E-06 1.2E-05 1.1E-06 Composition Misfit: 3.733459E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 88.402 0.000000 0.052348 0.124810 0.157492 0.243545 0.421804 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.2 0.1 -0.1 0.2 2.4E-02 Chi 0. 7.4E-07 3.6E-08 1.8E-07 3.0E-07 1.5E-09 Composition Misfit: 1.256845E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.001550 0.061862 0.110407 0.163078 0.227421 0.007631 0.428050 Augite(G) 0.013497 0.138345 0.006953 0.215653 0.117888 0.006071 0.501592 Gt(W) 0.000000 0.051938 0.123833 0.156259 0.241637 0.007834 0.418500 ----- ----- ----- ----- ----- ----- ----- Potentials -781261. -643150. -1657992. -746453. -322419. -443824. -891422. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 5 converged, 5 successes so far. Misfit function evaluations this try => 191 Misfit this try = 6.454709E-04 Best Misfit so far = 3.696255E-05 obtained on Try 1 Prior probability, PP = 1.775848E-07 Bayes score, PP * exp(-Misfit) = 1.774702E-07 Best Bayes score so far = 1.774702E-07 obtained on Try 5 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16263.5 738.998 6.287349E-02 0.917892 8.210769E-02 Final coordinates: 7492.51 936.101 0.213225 0.988912 1.108811E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.439475E-4 Extraneous predicted phases: 1.523362E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.290 0.013566 0.140672 0.006547 0.218258 0.116527 0.504430 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.2 -0.4 0.6 -0.4 0.8 -0.4 Chi 5.3E-07 2.7E-06 9.1E-05 9.9E-07 6.8E-06 5.0E-07 Composition Misfit: 1.028191E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 1.709 0.000000 0.048719 0.126971 0.152552 0.249144 0.422614 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 3. -2. 3. -4. -0.7 Chi 0. 2.4E-04 3.5E-05 1.5E-04 1.1E-04 1.5E-06 Composition Misfit: 5.411284E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.185940 0.000000 0.000000 0.480727 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013248 0.138211 0.008569 0.215756 0.118070 0.006294 0.499851 Augite(G) 0.013481 0.139788 0.006506 0.216887 0.115794 0.006283 0.501261 Gt(W) 0.000000 0.048382 0.126094 0.151499 0.247424 0.006902 0.419697 ----- ----- ----- ----- ----- ----- ----- Potentials -734357. -629782. -1648777. -735256. -306559. -476833. -898166. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 6 converged, 6 successes so far. Misfit function evaluations this try => 351 Misfit this try = 5.641564E-03 Best Misfit so far = 3.696255E-05 obtained on Try 1 Prior probability, PP = 5.317464E-09 Bayes score, PP * exp(-Misfit) = 5.287549E-09 Best Bayes score so far = 1.774702E-07 obtained on Try 5 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2132.96 645.944 0.587327 0.927315 7.268520E-02 Final coordinates: 19997.3 1179.74 0.215280 0.999970 3.011100E-05 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.640916E-3 Extraneous predicted phases: 6.475948E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.930 0.013491 0.140120 0.007249 0.217816 0.117344 0.503981 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -1.7E-02 -4.2E-02 0.1 -2.1E-02 0.1 -4.2E-02 Chi 6.1E-09 2.4E-08 7.0E-07 2.5E-09 4.5E-08 5.6E-09 Composition Misfit: 7.834537E-07 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.069 0.000000 0.053435 0.115128 0.183903 0.229361 0.418173 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 8. -1.7E+01 1.2E+01 3. Chi 0. 3.1E-05 8.3E-04 3.8E-03 9.1E-04 3.2E-05 Composition Misfit: 5.640133E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013397 0.139179 0.007278 0.216423 0.116683 0.006280 0.500760 Augite(G) 0.013406 0.139241 0.007203 0.216449 0.116607 0.006276 0.500818 Gt(W) 0.000000 0.052795 0.113748 0.181698 0.226612 0.011986 0.413161 ----- ----- ----- ----- ----- ----- ----- Potentials -806368. -651063. -1671623. -748460. -334911. -429505. -890156. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 7 converged, 7 successes so far. Misfit function evaluations this try => 144 Misfit this try = 4.729208E-04 Best Misfit so far = 3.696255E-05 obtained on Try 1 Prior probability, PP = 7.122302E-08 Bayes score, PP * exp(-Misfit) = 7.118935E-08 Best Bayes score so far = 1.774702E-07 obtained on Try 5 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18519.2 647.704 0.695635 0.906661 9.333873E-02 Final coordinates: 14382.8 1090.79 0.177863 0.729984 0.270016 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 4.715642E-4 Extraneous predicted phases: 1.356693E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 72.518 0.013603 0.139870 0.007085 0.216272 0.118209 0.504960 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.2 0.1 0.2 1. -0.7 -0.8 Chi 1.1E-06 2.6E-07 7.8E-06 1.1E-05 5.3E-06 2.1E-06 Composition Misfit: 2.723267E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 27.481 0.000000 0.054716 0.122740 0.162730 0.238787 0.421027 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 2. -3. 4. 0.8 Chi 0. 1.2E-04 3.7E-05 1.8E-04 1.1E-04 1.5E-06 Composition Misfit: 4.443315E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.009776 0.115546 0.038801 0.200117 0.150532 0.006694 0.478535 Augite(G) 0.013522 0.139043 0.007044 0.214993 0.117510 0.005915 0.501973 Gt(W) 0.000000 0.054238 0.121669 0.161310 0.236704 0.008725 0.417354 ----- ----- ----- ----- ----- ----- ----- Potentials -791518. -646646. -1664351. -748175. -327827. -442049. -891948. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 8 converged, 8 successes so far. Misfit function evaluations this try => 203 Misfit this try = 9.176412E-04 Best Misfit so far = 3.696255E-05 obtained on Try 1 Prior probability, PP = 6.358183E-09 Bayes score, PP * exp(-Misfit) = 6.352351E-09 Best Bayes score so far = 1.774702E-07 obtained on Try 5 P_bar T_K C_O2 Cpx Gt Initial coordinates: 19070.6 1104.91 5.305008E-02 4.887126E-02 0.951129 Final coordinates: 19561.2 1179.79 0.143531 0.293910 0.706090 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.144663E-4 Extraneous predicted phases: 3.174856E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 28.655 0.013894 0.136576 0.006041 0.213547 0.122677 0.507265 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.8 2. 1. 4. -4. -3. Chi 1.2E-05 8.9E-05 2.7E-04 8.4E-05 2.3E-04 2.2E-05 Composition Misfit: 7.039602E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 71.342 0.000000 0.054616 0.123957 0.159762 0.240181 0.421484 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 0.7 -2. 3. 0.3 Chi 0. 1.1E-04 6.8E-06 3.7E-05 5.5E-05 2.8E-07 Composition Misfit: 2.105061E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.003 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.003933 0.077415 0.089661 0.173809 0.205145 0.007361 0.442676 Augite(G) 0.013821 0.135859 0.006009 0.212426 0.122033 0.005250 0.504602 Gt(W) 0.000000 0.054168 0.122940 0.158452 0.238212 0.008201 0.418027 ----- ----- ----- ----- ----- ----- ----- Potentials -803440. -651307. -1672835. -749640. -333938. -449277. -891147. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 9 converged, 9 successes so far. Misfit function evaluations this try => 166 Misfit this try = 3.548456E-03 Best Misfit so far = 3.696255E-05 obtained on Try 1 Prior probability, PP = 1.028259E-08 Bayes score, PP * exp(-Misfit) = 1.024617E-08 Best Bayes score so far = 1.774702E-07 obtained on Try 5 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16596.3 693.295 0.722271 0.529869 0.470131 Final coordinates: 19352.5 1145.72 0.198398 0.894875 0.105125 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.547402E-3 Extraneous predicted phases: 1.053837E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 87.601 0.013782 0.141907 0.005755 0.216378 0.116038 0.506141 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.6 -1. 1. 1. 1. -2. Chi 6.5E-06 2.4E-05 4.3E-04 9.3E-06 1.6E-05 9.7E-06 Composition Misfit: 4.915503E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 12.397 0.000000 0.052936 0.117505 0.176733 0.233762 0.419065 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.8 6. -1.2E+01 8. 3. Chi 0. 1.2E-05 4.6E-04 2.1E-03 4.3E-04 1.8E-05 Composition Misfit: 3.055852E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.011987 0.129977 0.019552 0.210074 0.129862 0.006441 0.492107 Augite(G) 0.013702 0.141084 0.005722 0.215124 0.115365 0.005793 0.503209 Gt(W) 0.000000 0.052355 0.116216 0.174794 0.231197 0.010970 0.414467 ----- ----- ----- ----- ----- ----- ----- Potentials -799898. -648039. -1666107. -746257. -330543. -432357. -887376. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 10 converged, 10 successes so far. Misfit function evaluations this try => 229 Misfit this try = 1.93063 Best Misfit so far = 3.696255E-05 obtained on Try 1 Prior probability, PP = 4.112362E-09 Bayes score, PP * exp(-Misfit) = 5.965272E-10 Best Bayes score so far = 1.774702E-07 obtained on Try 5 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17804.7 632.887 0.949612 0.167645 0.832355 Final coordinates: 19987.9 1200.00 0.323492 1.00000 4.532252E-13 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.223229 Extraneous predicted phases: 1.70740 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.330 0.013656 0.141870 0.007413 0.220596 0.118920 0.497545 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 -1. -0.1 -3. -1. 5. Chi 2.2E-06 2.3E-05 1.2E-06 3.6E-05 1.9E-05 8.2E-05 Composition Misfit: 1.629413E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.005 0.000000 0.044111 0.039492 0.238243 0.288344 0.389810 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 8. 6.8E+01 -5.1E+01 -3.7E+01 3.0E+01 Chi 0. 1.5E-03 0.2 2.7E-02 6.9E-03 2.6E-03 Composition Misfit: 0.223066 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 1.665 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013355 0.138744 0.007251 0.215744 0.116312 0.009406 0.499187 Augite(G) 0.013526 0.140519 0.007342 0.218495 0.117787 0.009525 0.492806 Gt(W) 0.000000 0.042203 0.037783 0.227936 0.275869 0.043266 0.372944 ----- ----- ----- ----- ----- ----- ----- Potentials -825866. -653254. -1690859. -749753. -340177. -372708. -892735. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 11 converged, 11 successes so far. Misfit function evaluations this try => 425 Misfit this try = 5.773865E-03 Best Misfit so far = 3.696255E-05 obtained on Try 1 Prior probability, PP = 6.000463E-09 Bayes score, PP * exp(-Misfit) = 5.965917E-09 Best Bayes score so far = 1.774702E-07 obtained on Try 5 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8941.49 1067.11 0.854104 0.851635 0.148365 Final coordinates: 19756.3 1178.07 0.215104 0.998816 1.183836E-03 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.772483E-3 Extraneous predicted phases: 1.382244E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.978 0.013469 0.139977 0.007437 0.217731 0.117544 0.503842 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 2.4E-02 0.1 -0.1 0.1 -0.1 0.1 Chi 1.3E-08 5.1E-08 1.8E-06 1.8E-08 1.4E-07 1.4E-08 Composition Misfit: 2.067872E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.021 0.000000 0.053619 0.115299 0.184142 0.228703 0.418237 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 8. -1.7E+01 1.2E+01 3. Chi 0. 4.0E-05 8.0E-04 3.9E-03 1.0E-03 3.1E-05 Composition Misfit: 5.770415E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013381 0.139078 0.007412 0.216353 0.116828 0.006283 0.500665 Augite(G) 0.013384 0.139098 0.007390 0.216363 0.116806 0.006281 0.500678 Gt(W) 0.000000 0.052980 0.113925 0.181948 0.225979 0.011913 0.413255 ----- ----- ----- ----- ----- ----- ----- Potentials -806261. -651124. -1671732. -748615. -334922. -429889. -890491. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 12 converged, 12 successes so far. Misfit function evaluations this try => 146 Misfit this try = 1.020165E-03 Best Misfit so far = 3.696255E-05 obtained on Try 1 Prior probability, PP = 4.096116E-09 Bayes score, PP * exp(-Misfit) = 4.091939E-09 Best Bayes score so far = 1.774702E-07 obtained on Try 5 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16201.2 1037.97 0.791245 0.759601 0.240399 Final coordinates: 19998.1 1199.97 0.153482 0.449833 0.550167 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.017663E-3 Extraneous predicted phases: 2.502216E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 44.052 0.013820 0.137239 0.006503 0.213637 0.122035 0.506765 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.6 2. 0.7 4. -4. -2. Chi 8.3E-06 5.8E-05 1.0E-04 8.1E-05 1.7E-04 1.6E-05 Composition Misfit: 4.404965E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 55.946 0.000000 0.056086 0.123212 0.161767 0.237730 0.421205 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -4. 1. -3. 5. 0.6 Chi 0. 2.8E-04 2.3E-05 1.2E-04 1.6E-04 9.3E-07 Composition Misfit: 5.771660E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.006021 0.091043 0.071483 0.183212 0.185626 0.007123 0.455492 Augite(G) 0.013747 0.136508 0.006469 0.212499 0.121385 0.005328 0.504065 Gt(W) 0.000000 0.055608 0.122162 0.160389 0.235705 0.008521 0.417615 ----- ----- ----- ----- ----- ----- ----- Potentials -807377. -652918. -1675986. -751009. -336416. -448193. -892708. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 13 converged, 13 successes so far. Misfit function evaluations this try => 127 Misfit this try = 6.461987E-04 Best Misfit so far = 3.696255E-05 obtained on Try 1 Prior probability, PP = 3.080660E-08 Bayes score, PP * exp(-Misfit) = 3.078670E-08 Best Bayes score so far = 1.774702E-07 obtained on Try 5 P_bar T_K C_O2 Cpx Gt Initial coordinates: 4692.42 1091.77 0.574141 0.313015 0.686985 Final coordinates: 16582.2 1128.60 0.164527 0.592789 0.407211 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.430019E-4 Extraneous predicted phases: 3.196812E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 58.377 0.013733 0.139519 0.006559 0.215218 0.118976 0.505994 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.5 0.4 0.6 2. -1. -2. Chi 4.6E-06 2.1E-06 8.8E-05 3.1E-05 2.0E-05 8.4E-06 Composition Misfit: 1.546117E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 41.621 0.000000 0.055179 0.122893 0.162486 0.238357 0.421085 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 2. -3. 4. 0.7 Chi 0. 1.7E-04 3.2E-05 1.6E-04 1.3E-04 1.3E-06 Composition Misfit: 4.883903E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.002 0.000000 0.201788 0.000000 0.000000 0.464879 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.007937 0.103544 0.054810 0.191837 0.167723 0.006899 0.467250 Augite(G) 0.013656 0.138734 0.006523 0.214006 0.118306 0.005631 0.503145 Gt(W) 0.000000 0.054702 0.121829 0.161079 0.236293 0.008659 0.417439 ----- ----- ----- ----- ----- ----- ----- Potentials -739189. -634118. -1667782. -734330. -316075. -501422. -905958. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 14 converged, 14 successes so far. Misfit function evaluations this try => 132 Misfit this try = 4.386719E-04 Best Misfit so far = 3.696255E-05 obtained on Try 1 Prior probability, PP = 1.681208E-07 Bayes score, PP * exp(-Misfit) = 1.680471E-07 Best Bayes score so far = 1.774702E-07 obtained on Try 5 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10351.4 873.693 9.407108E-02 0.862363 0.137637 Final coordinates: 7120.14 937.360 0.188158 0.819439 0.180561 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 4.384788E-4 Extraneous predicted phases: 1.931690E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 82.395 0.013432 0.140258 0.007310 0.218711 0.116831 0.503459 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.1 -0.1 8.6E-03 -0.8 0.5 0.4 Chi 1.8E-07 2.7E-07 1.6E-08 3.9E-06 2.9E-06 4.4E-07 Composition Misfit: 7.706055E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 17.605 0.000000 0.049738 0.126937 0.152042 0.248682 0.422601 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 2. -2. 3. -4. -0.7 Chi 0. 1.2E-04 3.3E-05 1.8E-04 9.5E-05 1.4E-06 Composition Misfit: 4.307727E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.000 0.000000 0.189660 0.000000 0.000000 0.477007 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.010975 0.123374 0.028359 0.205519 0.139320 0.006554 0.485898 Augite(G) 0.013345 0.139349 0.007262 0.217295 0.116074 0.006475 0.500199 Gt(W) 0.000000 0.049394 0.126059 0.150990 0.246962 0.006917 0.419678 ----- ----- ----- ----- ----- ----- ----- Potentials -735315. -630233. -1649560. -736048. -307258. -476204. -899040. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 15 converged, 15 successes so far. Misfit function evaluations this try => 177 Misfit this try = 2.041602E-06 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.746978E-07 Bayes score, PP * exp(-Misfit) = 1.746974E-07 Best Bayes score so far = 1.774702E-07 obtained on Try 5 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18918.4 978.442 5.243804E-02 0.420720 0.579280 Final coordinates: 10240.5 1004.85 0.164350 0.589662 0.410338 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.144345E-6 Extraneous predicted phases: 8.972565E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 59.140 0.013494 0.140074 0.007280 0.217682 0.117450 0.504019 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -2.3E-02 -8.9E-03 3.2E-02 0.1 -2.9E-02 -0.1 Chi 1.2E-08 1.1E-09 2.2E-07 5.6E-08 9.6E-09 1.7E-08 Composition Misfit: 3.154442E-07 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 40.859 0.000000 0.052252 0.124781 0.157569 0.243605 0.421793 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.1 0.1 -0.2 0.2 3.4E-02 Chi 0. 1.9E-07 7.5E-08 3.7E-07 1.8E-07 3.1E-09 Composition Misfit: 8.289012E-07 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.007895 0.103270 0.055175 0.191648 0.168114 0.006907 0.466991 Augite(G) 0.013410 0.139198 0.007235 0.216321 0.116716 0.006252 0.500869 Gt(W) 0.000000 0.051842 0.123802 0.156333 0.241694 0.007846 0.418483 ----- ----- ----- ----- ----- ----- ----- Potentials -778252. -641938. -1655819. -745920. -320819. -442390. -891313. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 16 converged, 16 successes so far. Misfit function evaluations this try => 305 Misfit this try = 3.397089E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.558319E-07 Bayes score, PP * exp(-Misfit) = 1.557790E-07 Best Bayes score so far = 1.774702E-07 obtained on Try 5 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15102.8 631.331 0.196856 0.116634 0.883366 Final coordinates: 11563.0 1022.79 0.215592 0.999731 2.687200E-04 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.137098E-4 Extraneous predicted phases: 2.599907E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.798 0.013505 0.140219 0.007125 0.217894 0.117213 0.504044 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -4.4E-02 -0.1 0.2 -0.1 0.2 -0.1 Chi 4.1E-08 1.8E-07 5.4E-06 4.7E-08 3.5E-07 2.7E-08 Composition Misfit: 6.021014E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.195 0.000000 0.051883 0.122724 0.163478 0.240894 0.421021 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 0.3 2. -4. 2. 0.8 Chi 0. 1.4E-06 3.8E-05 2.3E-04 3.5E-05 1.5E-06 Composition Misfit: 3.076888E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.007 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013393 0.139157 0.007306 0.216407 0.116712 0.006291 0.500736 Augite(G) 0.013421 0.139337 0.007080 0.216525 0.116476 0.006286 0.500876 Gt(W) 0.000000 0.051430 0.121652 0.162051 0.238790 0.008731 0.417345 ----- ----- ----- ----- ----- ----- ----- Potentials -781217. -642612. -1656686. -745630. -321944. -439133. -890352. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 17 converged, 17 successes so far. Misfit function evaluations this try => 128 Misfit this try = 3.689864E-06 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.819483E-07 Bayes score, PP * exp(-Misfit) = 1.819476E-07 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 4122.47 1006.34 6.138385E-02 0.134924 0.865076 Final coordinates: 9625.16 992.020 0.138226 0.198574 0.801426 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.314740E-6 Extraneous predicted phases: 3.751241E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 20.053 0.013454 0.140305 0.007415 0.218030 0.117090 0.503707 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.1 -0.2 -0.1 -0.2 0.3 0.2 Chi 5.6E-08 4.2E-07 1.2E-06 2.6E-07 9.1E-07 9.7E-08 Composition Misfit: 2.951735E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 79.947 0.000000 0.052045 0.124915 0.157238 0.243960 0.421843 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 0.1 -3.0E-02 0.1 -0.1 -1.3E-02 Chi 0. 2.2E-07 1.1E-08 5.0E-08 8.4E-08 4.6E-10 Composition Misfit: 3.630051E-07 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.197175 0.000000 0.000000 0.469491 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.002657 0.069086 0.100772 0.168063 0.217076 0.007501 0.434845 Augite(G) 0.013369 0.139415 0.007368 0.216647 0.116347 0.006343 0.500511 Gt(W) 0.000000 0.051639 0.123942 0.156013 0.242060 0.007789 0.418557 ----- ----- ----- ----- ----- ----- ----- Potentials -736321. -631238. -1654572. -735597. -309834. -482048. -901266. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 18 converged, 18 successes so far. Misfit function evaluations this try => 582 Misfit this try = 0.174130 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 4.114672E-09 Bayes score, PP * exp(-Misfit) = 3.457095E-09 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 6075.26 1147.84 0.771516 0.809315 0.190685 Final coordinates: 20000.0 600.428 0.214991 1.00000 2.753783E-09 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.174050 Extraneous predicted phases: 8.063719E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 95.459 0.014125 0.146034 0.001169 0.223247 0.107777 0.507647 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -1. -4. 5. -5. 8. -3. Chi 2.9E-05 2.4E-04 3.2E-02 1.3E-04 8.6E-04 2.7E-05 Composition Misfit: 3.365710E-02 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 4.533 0.000000 0.014825 0.136426 0.103705 0.318884 0.426160 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 3.6E+01 -9. 3.4E+01 -6.2E+01 -4. Chi 0. 0.1 9.8E-04 2.8E-02 1.8E-02 4.4E-05 Composition Misfit: 0.140393 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.007 0.000000 0.077492 0.000000 0.000000 0.589175 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013397 0.139183 0.007274 0.216427 0.116680 0.006271 0.500767 Augite(G) 0.014034 0.145094 0.001162 0.221810 0.107084 0.006436 0.504380 Gt(W) 0.000000 0.014784 0.136044 0.103414 0.317989 0.002806 0.424964 ----- ----- ----- ----- ----- ----- ----- Potentials -657589. -593512. -1577816. -693128. -255769. -449532. -838422. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 19 converged, 19 successes so far. Misfit function evaluations this try => 356 Misfit this try = 2.643171E-05 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.581869E-07 Bayes score, PP * exp(-Misfit) = 1.581827E-07 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14993.3 1030.23 0.931673 0.498572 0.501428 Final coordinates: 11117.1 1023.08 0.160568 0.544604 0.455396 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.620420E-5 Extraneous predicted phases: 2.275066E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 54.472 0.013535 0.139871 0.007153 0.217265 0.117815 0.504362 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.1 0.1 0.1 0.5 -0.3 -0.3 Chi 2.1E-07 2.6E-07 3.9E-06 1.3E-06 1.3E-06 3.7E-07 Composition Misfit: 7.398399E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 45.527 0.000000 0.052793 0.124522 0.158240 0.242750 0.421696 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.6 0.3 -0.6 0.9 0.1 Chi 0. 7.8E-06 1.0E-06 5.3E-06 4.7E-06 4.2E-08 Composition Misfit: 1.880581E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.007291 0.099330 0.060431 0.188929 0.173758 0.006975 0.463286 Augite(G) 0.013452 0.139011 0.007109 0.215929 0.117091 0.006145 0.501262 Gt(W) 0.000000 0.052372 0.123531 0.156980 0.240818 0.007958 0.418340 ----- ----- ----- ----- ----- ----- ----- Potentials -780998. -642918. -1657584. -746378. -322250. -442645. -891407. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 20 converged, 20 successes so far. Misfit function evaluations this try => 154 Misfit this try = 2.635790E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.726747E-07 Bayes score, PP * exp(-Misfit) = 1.726291E-07 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8528.38 750.147 0.650697 7.184188E-02 0.928158 Final coordinates: 7366.49 942.347 0.131842 6.555349E-02 0.934447 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.612065E-4 Extraneous predicted phases: 2.372492E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 6.748 0.013229 0.142339 0.008285 0.219800 0.114416 0.501931 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.5 -2. -0.8 -2. 3. 2. Chi 4.8E-06 3.6E-05 1.1E-04 1.8E-05 7.9E-05 7.9E-06 Composition Misfit: 2.586752E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 93.251 0.000000 0.051867 0.124969 0.157104 0.244197 0.421863 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 0.3 -0.1 0.1 -0.3 -3.2E-02 Chi 0. 1.6E-06 6.6E-08 3.1E-07 5.9E-07 2.8E-09 Composition Misfit: 2.531308E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.203098 0.000000 0.000000 0.463568 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000877 0.057468 0.116269 0.160047 0.233716 0.007703 0.423920 Augite(G) 0.013138 0.141366 0.008229 0.218297 0.113634 0.006838 0.498499 Gt(W) 0.000000 0.051464 0.123998 0.155884 0.242301 0.007765 0.418587 ----- ----- ----- ----- ----- ----- ----- Potentials -734460. -629691. -1649548. -735588. -307417. -473640. -899618. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 21 converged, 21 successes so far. Misfit function evaluations this try => 128 Misfit this try = 1.141782E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.153266E-07 Bayes score, PP * exp(-Misfit) = 1.153135E-07 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 11509.8 933.867 0.596096 0.517855 0.482145 Final coordinates: 12737.2 1057.35 0.149476 0.391763 0.608237 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.139428E-4 Extraneous predicted phases: 2.353897E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 38.992 0.013618 0.139061 0.006928 0.216402 0.118944 0.505047 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 0.7 0.3 1. -1. -0.9 Chi 1.4E-06 7.2E-06 2.2E-05 8.9E-06 2.0E-05 2.5E-06 Composition Misfit: 6.179538E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 61.007 0.000000 0.053348 0.124374 0.158596 0.242041 0.421640 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 0.4 -0.8 1. 0.2 Chi 0. 2.7E-05 2.0E-06 1.0E-05 1.3E-05 8.4E-08 Composition Misfit: 5.214741E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005244 0.085967 0.078255 0.179710 0.192897 0.007208 0.450720 Augite(G) 0.013537 0.138238 0.006887 0.215120 0.118239 0.005923 0.502056 Gt(W) 0.000000 0.052920 0.123377 0.157323 0.240100 0.008021 0.418258 ----- ----- ----- ----- ----- ----- ----- Potentials -785989. -644860. -1661104. -747312. -324944. -444269. -891714. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 22 converged, 22 successes so far. Misfit function evaluations this try => 627 Misfit this try = 4.511596E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 5.485442E-09 Bayes score, PP * exp(-Misfit) = 5.460750E-09 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 3594.48 989.683 0.697280 0.185491 0.814509 Final coordinates: 19978.5 1177.87 0.215219 1.00000 1.402268E-09 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 4.511596E-3 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.951 0.013488 0.140104 0.007266 0.217811 0.117360 0.503970 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -1.2E-02 -3.0E-02 4.3E-02 -1.7E-02 4.8E-02 -3.4E-02 Chi 3.3E-09 1.3E-08 4.0E-07 1.5E-09 2.7E-08 3.5E-09 Composition Misfit: 4.463767E-07 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.049 0.000000 0.053815 0.115985 0.180749 0.230957 0.418494 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 7. -1.5E+01 1.1E+01 3. Chi 0. 5.1E-05 6.8E-04 3.0E-03 7.2E-04 2.7E-05 Composition Misfit: 4.511150E-03 *mole fractions relative to measured components, complete compositions below Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013397 0.139182 0.007274 0.216425 0.116679 0.006278 0.500764 Augite(G) 0.013404 0.139225 0.007221 0.216444 0.116624 0.006275 0.500807 Gt(W) 0.000000 0.053190 0.114637 0.178649 0.228273 0.011620 0.413631 ----- ----- ----- ----- ----- ----- ----- Potentials -805440. -651184. -1671167. -748040. -334980. -427554. -889964. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 23 converged, 23 successes so far. Misfit function evaluations this try => 640 Misfit this try = 45.4159 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 2.117474E-08 Bayes score, PP * exp(-Misfit) = 3.999080E-28 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14757.9 1167.17 0.911781 5.382711E-02 0.946173 Final coordinates: 14611.1 1198.61 0.343188 0.109630 0.890370 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.609179 Extraneous predicted phases: 44.8067 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.000 0.002242 0.034393 0.113482 0.267217 0.221363 0.361304 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 2.1E+01 7.5E+01 -8.5E+01 -4.5E+01 -8.9E+01 1.1E+02 Chi 0.1 0.3 0.1 9.1E-03 4.9E-02 0.1 Composition Misfit: 0.594583 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 85.060 0.000000 0.069568 0.096938 0.175508 0.246634 0.411352 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1.7E+01 2.2E+01 -1.2E+01 -2. 10. Chi 0. 4.4E-03 8.1E-03 1.9E-03 3.2E-05 2.7E-04 Composition Misfit: 1.459600E-02 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 Sp(WPC) 1.040 0.000000 0.013978 0.013978 0.000000 0.833181 0.138864 0.000000 Fsp(C1) 6.584 0.032095 0.000000 0.217905 0.185810 0.000000 0.000000 0.564190 ky 4.050 0.000000 0.000000 0.500000 0.000000 0.000000 0.000000 0.500000 q 3.254 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 hem 0.012 0.000000 0.000000 0.000000 0.000000 0.800000 0.200000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.001449 0.060593 0.109823 0.160783 0.225510 0.019348 0.422494 Augite(G) 0.002150 0.032986 0.108839 0.256284 0.212306 0.040914 0.346522 Gt(W) 0.000000 0.068198 0.095029 0.172052 0.241777 0.019694 0.403250 ----- ----- ----- ----- ----- ----- ----- Potentials -832501. -661041. -1670866. -764384. -348636. -359693. -904830. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 24 converged, 24 successes so far. Misfit function evaluations this try => 159 Misfit this try = 6.654534E-06 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.799191E-07 Bayes score, PP * exp(-Misfit) = 1.799179E-07 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14367.5 743.729 0.171670 6.683991E-02 0.933160 Final coordinates: 9919.55 996.951 0.129571 1.258911E-02 0.987411 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.546013E-6 Extraneous predicted phases: 1.085213E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 1.270 0.013490 0.140659 0.007250 0.217815 0.116795 0.503991 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -1.5E-02 -0.4 0.1 -2.0E-02 0.5 -0.1 Chi 5.2E-09 2.5E-06 6.8E-07 2.3E-09 3.3E-06 8.0E-09 Composition Misfit: 6.544791E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.730 0.000000 0.052144 0.124878 0.157327 0.243822 0.421829 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 7.1E-03 -3.3E-04 -4.8E-04 -5.0E-03 -1.5E-04 Chi 0. 1.1E-09 1.4E-12 3.7E-12 1.5E-10 5.8E-14 Composition Misfit: 1.221870E-09 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.000 0.000000 0.197446 0.000000 0.000000 0.469221 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000168 0.052843 0.122437 0.156857 0.240339 0.007785 0.419571 Augite(G) 0.013406 0.139777 0.007205 0.216449 0.116062 0.006270 0.500831 Gt(W) 0.000000 0.051737 0.123903 0.156099 0.241919 0.007805 0.418537 ----- ----- ----- ----- ----- ----- ----- Potentials -736405. -631266. -1654931. -735479. -309993. -482774. -901319. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 25 converged, 25 successes so far. Misfit function evaluations this try => 309 Misfit this try = 5.184192E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.172833E-08 Bayes score, PP * exp(-Misfit) = 1.166769E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 3986.64 1045.39 0.571646 0.877287 0.122713 Final coordinates: 18833.2 1151.71 0.215206 0.999989 1.091086E-05 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.184030E-3 Extraneous predicted phases: 1.620311E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.745 0.013516 0.140285 0.007045 0.217882 0.117123 0.504148 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.1 -0.2 0.2 -0.1 0.2 -0.2 Chi 8.8E-08 3.6E-07 1.1E-05 3.7E-08 7.3E-07 9.6E-08 Composition Misfit: 1.208750E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.255 0.000000 0.052463 0.114938 0.183054 0.231444 0.418102 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.3 8. -1.6E+01 1.0E+01 4. Chi 0. 1.8E-06 8.6E-04 3.6E-03 6.6E-04 3.3E-05 Composition Misfit: 5.171942E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.000 0.000000 0.213654 0.000000 0.000000 0.453013 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013397 0.139181 0.007276 0.216425 0.116681 0.006278 0.500763 Augite(G) 0.013432 0.139407 0.007001 0.216518 0.116390 0.006263 0.500991 Gt(W) 0.000000 0.051830 0.113551 0.180845 0.228651 0.012067 0.413056 ----- ----- ----- ----- ----- ----- ----- Potentials -733589. -632125. -1668199. -730250. -315135. -497366. -906400. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 26 converged, 26 successes so far. Misfit function evaluations this try => 105 Misfit this try = 8.251507E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.016364E-08 Bayes score, PP * exp(-Misfit) = 1.015526E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17858.0 1140.20 0.434370 0.314278 0.685722 Final coordinates: 18675.9 1169.06 0.143271 0.290716 0.709284 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 8.250541E-4 Extraneous predicted phases: 9.666102E-8 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 28.442 0.013850 0.136401 0.006227 0.213751 0.122815 0.506956 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.7 3. 0.9 4. -5. -2. Chi 9.8E-06 9.8E-05 1.9E-04 7.6E-05 2.4E-04 1.8E-05 Composition Misfit: 6.318519E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 71.558 0.000000 0.054544 0.124042 0.159574 0.240324 0.421516 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 0.7 -1. 3. 0.3 Chi 0. 1.0E-04 5.6E-06 3.2E-05 5.1E-05 2.3E-07 Composition Misfit: 1.932021E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.003891 0.077136 0.090034 0.173617 0.205545 0.007362 0.442415 Augite(G) 0.013776 0.135675 0.006194 0.212613 0.122161 0.005324 0.504257 Gt(W) 0.000000 0.054098 0.123030 0.158271 0.238362 0.008164 0.418075 ----- ----- ----- ----- ----- ----- ----- Potentials -801989. -650999. -1672285. -749804. -333409. -449099. -891804. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 27 converged, 27 successes so far. Misfit function evaluations this try => 414 Misfit this try = 1.973550E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 6.547412E-08 Bayes score, PP * exp(-Misfit) = 6.534503E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 3560.35 647.371 0.775628 0.774138 0.225862 Final coordinates: 15083.1 1085.14 0.215490 0.999933 6.706529E-05 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.961763E-3 Extraneous predicted phases: 1.178712E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.787 0.013510 0.140245 0.007092 0.217891 0.117179 0.504083 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.1 -0.1 0.2 -0.1 0.2 -0.1 Chi 5.8E-08 2.4E-07 7.3E-06 4.4E-08 4.8E-07 4.8E-08 Composition Misfit: 8.187627E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.209 0.000000 0.052526 0.119122 0.172838 0.235843 0.419671 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.4 5. -10. 7. 2. Chi 0. 2.7E-06 2.8E-04 1.4E-03 2.7E-04 1.1E-05 Composition Misfit: 1.953575E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.004 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013396 0.139175 0.007282 0.216420 0.116687 0.006286 0.500754 Augite(G) 0.013425 0.139364 0.007048 0.216523 0.116443 0.006278 0.500919 Gt(W) 0.000000 0.051987 0.117898 0.171062 0.233419 0.010277 0.415358 ----- ----- ----- ----- ----- ----- ----- Potentials -791137. -645722. -1661937. -746399. -326826. -434203. -889675. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 28 converged, 28 successes so far. Misfit function evaluations this try => 214 Misfit this try = 5.685825E-06 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.753486E-07 Bayes score, PP * exp(-Misfit) = 1.753476E-07 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 7193.06 667.160 0.901179 0.865955 0.134045 Final coordinates: 10195.9 1003.93 0.213957 0.992275 7.725230E-03 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.924801E-6 Extraneous predicted phases: 1.761025E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.250 0.013480 0.140046 0.007343 0.217788 0.117436 0.503908 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 4.0E-03 1.1E-02 -1.8E-02 4.6E-03 -1.6E-02 1.6E-02 Chi 3.4E-10 1.6E-09 7.0E-08 1.1E-10 3.1E-09 7.6E-10 Composition Misfit: 7.599208E-08 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.748 0.000000 0.052398 0.124558 0.156994 0.244342 0.421709 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.2 0.3 0.2 -0.4 0.1 Chi 0. 1.2E-06 8.2E-07 7.0E-07 1.1E-06 3.4E-08 Composition Misfit: 3.848808E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013293 0.138505 0.008177 0.215958 0.117648 0.006293 0.500126 Augite(G) 0.013395 0.139167 0.007297 0.216420 0.116698 0.006280 0.500743 Gt(W) 0.000000 0.051982 0.123568 0.155747 0.242401 0.007942 0.418360 ----- ----- ----- ----- ----- ----- ----- Potentials -778220. -641864. -1655739. -745921. -320753. -441794. -891310. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 29 converged, 29 successes so far. Misfit function evaluations this try => 399 Misfit this try = 9.959792E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 2.497758E-08 Bayes score, PP * exp(-Misfit) = 2.473004E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15012.0 685.767 0.940542 0.194685 0.805315 Final coordinates: 13434.8 1200.00 0.203663 0.930572 6.942792E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.959792E-3 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.726 0.012710 0.134801 0.014018 0.214516 0.124735 0.499219 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 1. 4. -5. 3. -6. 4. Chi 4.7E-05 2.1E-04 3.2E-03 5.0E-05 4.3E-04 4.4E-05 Composition Misfit: 3.976434E-03 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 1.274 0.000000 0.069672 0.127037 0.143368 0.237284 0.422639 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1.7E+01 -2. 9. 5. -0.8 Chi 0. 4.4E-03 3.7E-05 1.4E-03 1.8E-04 1.6E-06 Composition Misfit: 5.983358E-03 *mole fractions relative to measured components, complete compositions below Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.012466 0.133103 0.015383 0.212231 0.125387 0.006384 0.495047 Augite(G) 0.012629 0.133942 0.013929 0.213148 0.123939 0.006378 0.496035 Gt(W) 0.000000 0.069193 0.126164 0.142382 0.235653 0.006874 0.419734 ----- ----- ----- ----- ----- ----- ----- Potentials -810281. -657416. -1687215. -760847. -342997. -460448. -907741. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 30 converged, 30 successes so far. Misfit function evaluations this try => 147 Misfit this try = 6.255539E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 2.076906E-08 Bayes score, PP * exp(-Misfit) = 2.075607E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18611.1 775.734 0.946215 0.397569 0.602431 Final coordinates: 17263.6 1147.53 0.153102 0.445019 0.554981 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.248372E-4 Extraneous predicted phases: 7.166706E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 43.789 0.013760 0.137927 0.006602 0.214577 0.120889 0.506245 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.5 2. 0.6 3. -3. -2. Chi 5.6E-06 3.3E-05 7.8E-05 4.8E-05 1.0E-04 1.1E-05 Composition Misfit: 2.752624E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 56.210 0.000000 0.055203 0.123562 0.160778 0.239121 0.421336 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 1. -2. 4. 0.5 Chi 0. 1.7E-04 1.4E-05 7.4E-05 9.2E-05 5.8E-07 Composition Misfit: 3.495748E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005957 0.090622 0.072045 0.182922 0.186229 0.007128 0.455097 Augite(G) 0.013684 0.137166 0.006566 0.213393 0.120222 0.005516 0.503453 Gt(W) 0.000000 0.054741 0.122527 0.159432 0.237120 0.008371 0.417809 ----- ----- ----- ----- ----- ----- ----- Potentials -799497. -649921. -1670397. -749651. -332158. -446643. -892326. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Augite(G) q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Augite(G) q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 32 converged, 31 successes so far. Misfit function evaluations this try => 175 Misfit this try = 9.774701E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 8.776604E-09 Bayes score, PP * exp(-Misfit) = 8.768029E-09 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14709.5 794.008 0.870461 5.248437E-02 0.947516 Final coordinates: 19352.9 1159.80 0.138037 0.194366 0.805634 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.773393E-4 Extraneous predicted phases: 1.307565E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 18.866 0.013960 0.137154 0.005574 0.213594 0.121983 0.507734 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.9 2. 1. 4. -4. -3. Chi 1.6E-05 6.2E-05 5.5E-04 8.3E-05 1.7E-04 2.9E-05 Composition Misfit: 9.068977E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 81.133 0.000000 0.053544 0.124318 0.158793 0.241726 0.421619 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 0.4 -0.9 2. 0.2 Chi 0. 3.6E-05 2.5E-06 1.4E-05 1.8E-05 1.0E-07 Composition Misfit: 7.044156E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.002601 0.068718 0.101262 0.167809 0.217602 0.007509 0.434499 Augite(G) 0.013887 0.136443 0.005545 0.212488 0.121351 0.005182 0.505103 Gt(W) 0.000000 0.053113 0.123318 0.157515 0.239781 0.008046 0.418227 ----- ----- ----- ----- ----- ----- ----- Potentials -799405. -649480. -1669237. -747997. -331401. -448362. -889120. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 33 converged, 32 successes so far. Misfit function evaluations this try => 89 Misfit this try = 7.867151E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.875712E-08 Bayes score, PP * exp(-Misfit) = 1.874237E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18654.3 1120.07 6.442385E-02 0.312629 0.687371 Final coordinates: 17756.8 1142.82 0.137229 0.177522 0.822478 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.849374E-4 Extraneous predicted phases: 1.777696E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 17.332 0.013889 0.136580 0.005921 0.213966 0.122485 0.507159 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.8 2. 1. 4. -4. -3. Chi 1.2E-05 8.9E-05 3.3E-04 6.8E-05 2.1E-04 2.1E-05 Composition Misfit: 7.298539E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 82.666 0.000000 0.053429 0.124432 0.158505 0.241971 0.421662 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 0.4 -0.7 2. 0.2 Chi 0. 3.1E-05 1.6E-06 8.8E-06 1.4E-05 6.6E-08 Composition Misfit: 5.508355E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.002375 0.067246 0.103224 0.166793 0.219709 0.007538 0.433114 Augite(G) 0.013815 0.135852 0.005890 0.212826 0.121832 0.005328 0.504457 Gt(W) 0.000000 0.053002 0.123437 0.157238 0.240036 0.007996 0.418290 ----- ----- ----- ----- ----- ----- ----- Potentials -797537. -649175. -1668791. -748524. -330770. -448587. -890625. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 34 converged, 33 successes so far. Misfit function evaluations this try => 186 Misfit this try = 9.762336E-06 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.771508E-07 Bayes score, PP * exp(-Misfit) = 1.771491E-07 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2624.24 670.420 0.527823 0.801516 0.198484 Final coordinates: 10152.9 1001.55 0.215319 0.999532 4.684893E-04 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 4.808412E-6 Extraneous predicted phases: 4.953924E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.914 0.013487 0.140097 0.007277 0.217819 0.117373 0.503947 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -9.7E-03 -2.5E-02 3.4E-02 -2.4E-02 3.7E-02 -1.6E-02 Chi 2.0E-09 9.0E-09 2.5E-07 3.2E-09 1.6E-08 7.6E-10 Composition Misfit: 2.838582E-07 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.083 0.000000 0.052023 0.124608 0.158057 0.243584 0.421728 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 0.1 0.2 -0.5 0.2 0.1 Chi 0. 3.1E-07 5.8E-07 3.4E-06 2.2E-07 2.4E-08 Composition Misfit: 4.524553E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.003 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013391 0.139140 0.007329 0.216396 0.116738 0.006284 0.500723 Augite(G) 0.013402 0.139217 0.007232 0.216451 0.116635 0.006283 0.500781 Gt(W) 0.000000 0.051611 0.123621 0.156805 0.241654 0.007921 0.418388 ----- ----- ----- ----- ----- ----- ----- Potentials -777816. -641716. -1655396. -745733. -320495. -441946. -891136. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Augite(G) q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Augite(G) q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 36 converged, 34 successes so far. Misfit function evaluations this try => 138 Misfit this try = 1.008079E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 2.550739E-08 Bayes score, PP * exp(-Misfit) = 2.548169E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15981.8 936.232 0.838982 0.816258 0.183742 Final coordinates: 16764.3 1141.89 0.179245 0.743085 0.256915 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.007771E-3 Extraneous predicted phases: 3.082266E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 73.725 0.013617 0.139504 0.007204 0.215651 0.118879 0.505145 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 0.4 0.1 2. -1. -1. Chi 1.3E-06 2.2E-06 1.9E-06 2.1E-05 1.8E-05 2.9E-06 Composition Misfit: 4.763690E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 26.274 0.000000 0.056160 0.121920 0.164979 0.236220 0.420720 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -4. 2. -5. 6. 1. Chi 0. 2.9E-04 7.2E-05 3.6E-04 2.4E-04 2.9E-06 Composition Misfit: 9.601336E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.009951 0.116692 0.037272 0.200908 0.148890 0.006672 0.479614 Augite(G) 0.013538 0.138694 0.007162 0.214399 0.118189 0.005805 0.502213 Gt(W) 0.000000 0.055651 0.120814 0.163482 0.234076 0.009077 0.416901 ----- ----- ----- ----- ----- ----- ----- Potentials -799619. -649662. -1669947. -749756. -332258. -442241. -892762. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 37 converged, 35 successes so far. Misfit function evaluations this try => 110 Misfit this try = 2.375719E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.746014E-07 Bayes score, PP * exp(-Misfit) = 1.745599E-07 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13650.7 779.040 0.158572 0.855513 0.144487 Final coordinates: 7461.71 943.359 0.174099 0.694501 0.305499 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.364248E-4 Extraneous predicted phases: 1.147161E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 70.058 0.013404 0.140479 0.007422 0.218840 0.116607 0.503248 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.1 -0.3 -0.1 -1. 0.7 0.5 Chi 4.5E-07 1.2E-06 1.4E-06 5.0E-06 5.6E-06 9.2E-07 Composition Misfit: 1.464924E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 29.940 0.000000 0.050032 0.126183 0.154108 0.247359 0.422318 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 2. -1. 2. -3. -0.5 Chi 0. 9.0E-05 1.3E-05 6.7E-05 5.1E-05 5.7E-07 Composition Misfit: 2.217755E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 Fsp(C1) 0.001 0.080352 0.000000 0.169648 0.089295 0.000000 0.000000 0.660705 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.009300 0.112441 0.042942 0.197976 0.154979 0.006745 0.475616 Augite(G) 0.013317 0.139561 0.007374 0.217411 0.115845 0.006531 0.499961 Gt(W) 0.000000 0.049669 0.125269 0.152992 0.245567 0.007242 0.419260 ----- ----- ----- ----- ----- ----- ----- Potentials -754763. -635076. -1649917. -740688. -312331. -456496. -894321. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 38 converged, 36 successes so far. Misfit function evaluations this try => 97 Misfit this try = 1.080539E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 6.963131E-09 Bayes score, PP * exp(-Misfit) = 6.955612E-09 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18838.3 1139.88 0.761413 0.674317 0.325683 Final coordinates: 19308.8 1180.52 0.164639 0.593391 0.406609 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.080370E-3 Extraneous predicted phases: 1.695996E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 58.165 0.013793 0.139162 0.006447 0.214365 0.119722 0.506510 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.6 0.6 0.7 3. -2. -2. Chi 7.0E-06 5.8E-06 1.2E-04 5.5E-05 4.4E-05 1.3E-05 Composition Misfit: 2.433734E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 41.834 0.000000 0.056198 0.122335 0.163989 0.236603 0.420876 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -4. 2. -4. 6. 0.9 Chi 0. 2.9E-04 5.3E-05 2.7E-04 2.2E-04 2.2E-06 Composition Misfit: 8.369963E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.007945 0.103596 0.054740 0.191873 0.167647 0.006900 0.467299 Augite(G) 0.013718 0.138404 0.006412 0.213198 0.119070 0.005448 0.503750 Gt(W) 0.000000 0.055698 0.121246 0.162530 0.234498 0.008899 0.417130 ----- ----- ----- ----- ----- ----- ----- Potentials -804726. -651430. -1673155. -750019. -334693. -444592. -891809. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 39 converged, 37 successes so far. Misfit function evaluations this try => 137 Misfit this try = 7.500721E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 3.382223E-08 Bayes score, PP * exp(-Misfit) = 3.379687E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18471.4 803.998 0.564318 8.186689E-02 0.918133 Final coordinates: 16542.3 1120.32 0.132389 7.741467E-02 0.922585 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.498316E-4 Extraneous predicted phases: 2.404449E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 7.584 0.013856 0.136104 0.005958 0.214393 0.122769 0.506919 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.7 3. 1. 3. -5. -2. Chi 1.0E-05 1.2E-04 3.1E-04 5.4E-05 2.3E-04 1.8E-05 Composition Misfit: 7.412574E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 92.416 0.000000 0.052671 0.124723 0.157741 0.243093 0.421771 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.5 0.1 -0.3 0.6 0.1 Chi 0. 5.1E-06 1.9E-07 1.1E-06 2.1E-06 7.9E-09 Composition Misfit: 8.574254E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.000 0.000000 0.188277 0.000000 0.000000 0.478389 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.001036 0.058504 0.114887 0.160762 0.232232 0.007686 0.424894 Augite(G) 0.013781 0.135368 0.005926 0.213233 0.122104 0.005413 0.504176 Gt(W) 0.000000 0.052257 0.123742 0.156499 0.241180 0.007871 0.418452 ----- ----- ----- ----- ----- ----- ----- Potentials -738863. -634194. -1666629. -734199. -315159. -503850. -904435. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 40 converged, 38 successes so far. Misfit function evaluations this try => 228 Misfit this try = 3.349917E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.728484E-07 Bayes score, PP * exp(-Misfit) = 1.727905E-07 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 6046.33 666.804 0.878870 0.145919 0.854081 Final coordinates: 7359.88 941.312 0.129123 2.547517E-03 0.997452 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.300572E-4 Extraneous predicted phases: 4.934424E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.263 0.013191 0.143050 0.008264 0.219908 0.113643 0.501945 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.5 -2. -0.8 -2. 3. 2. Chi 6.4E-06 6.2E-05 1.1E-04 2.0E-05 1.3E-04 7.8E-06 Composition Misfit: 3.300509E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.735 0.000000 0.052135 0.124885 0.157321 0.243828 0.421832 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 1.6E-02 -5.7E-03 3.3E-03 -9.6E-03 -2.6E-03 Chi 0. 5.2E-09 4.1E-10 1.7E-10 5.6E-10 1.7E-11 Composition Misfit: 6.349463E-09 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.002 0.000000 0.205001 0.000000 0.000000 0.461666 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000034 0.051967 0.123606 0.156252 0.241595 0.007799 0.418747 Augite(G) 0.013101 0.142076 0.008207 0.218411 0.112869 0.006808 0.498527 Gt(W) 0.000000 0.051728 0.123910 0.156094 0.241926 0.007802 0.418541 ----- ----- ----- ----- ----- ----- ----- Potentials -734354. -629544. -1649326. -735509. -307324. -473279. -899532. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 41 converged, 39 successes so far. Misfit function evaluations this try => 262 Misfit this try = 1.67460 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 5.571928E-09 Bayes score, PP * exp(-Misfit) = 1.044083E-09 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2202.08 1084.56 0.648124 0.852149 0.147851 Final coordinates: 19982.3 1176.47 0.317378 1.00000 1.243205E-09 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.154273 Extraneous predicted phases: 1.52033 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.409 0.013649 0.141784 0.007400 0.220434 0.118805 0.497928 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 -1. -0.1 -2. -1. 5. Chi 2.0E-06 2.1E-05 8.6E-07 3.2E-05 1.6E-05 7.2E-05 Composition Misfit: 1.439797E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.022 0.000000 0.045547 0.048142 0.231066 0.282192 0.393053 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 6. 6.1E+01 -4.7E+01 -3.1E+01 2.7E+01 Chi 0. 9.6E-04 0.1 2.4E-02 5.2E-03 2.1E-03 Composition Misfit: 0.154129 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 1.570 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013357 0.138769 0.007253 0.215782 0.116333 0.009230 0.499276 Augite(G) 0.013521 0.140460 0.007331 0.218377 0.117696 0.009334 0.493281 Gt(W) 0.000000 0.043735 0.046226 0.221873 0.270964 0.039789 0.377414 ----- ----- ----- ----- ----- ----- ----- Potentials -819507. -650653. -1682554. -747806. -336491. -376722. -889780. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 42 converged, 40 successes so far. Misfit function evaluations this try => 155 Misfit this try = 9.592439E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 9.862305E-09 Bayes score, PP * exp(-Misfit) = 9.852849E-09 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18330.8 880.720 0.275834 0.295112 0.704888 Final coordinates: 19133.4 1157.05 0.137662 0.186151 0.813849 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.576352E-4 Extraneous predicted phases: 1.608659E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 18.076 0.013956 0.137053 0.005604 0.213645 0.122070 0.507673 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.9 2. 1. 4. -4. -3. Chi 1.6E-05 6.6E-05 5.3E-04 8.1E-05 1.8E-04 2.8E-05 Composition Misfit: 8.934619E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 81.922 0.000000 0.053489 0.124350 0.158704 0.241826 0.421631 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 0.4 -0.9 2. 0.2 Chi 0. 3.3E-05 2.2E-06 1.2E-05 1.6E-05 9.3E-08 Composition Misfit: 6.417330E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.002491 0.068000 0.102219 0.167314 0.218629 0.007524 0.433823 Augite(G) 0.013883 0.136340 0.005575 0.212534 0.121435 0.005202 0.505032 Gt(W) 0.000000 0.053060 0.123351 0.157430 0.239883 0.008032 0.418245 ----- ----- ----- ----- ----- ----- ----- Potentials -799049. -649410. -1669106. -748025. -331249. -448400. -889274. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 43 converged, 41 successes so far. Misfit function evaluations this try => 119 Misfit this try = 5.958437E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 5.140747E-08 Bayes score, PP * exp(-Misfit) = 5.137685E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10607.7 1000.34 0.588713 9.767239E-02 0.902328 Final coordinates: 15370.8 1106.03 0.132773 8.140657E-02 0.918593 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.783993E-4 Extraneous predicted phases: 1.744447E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 8.000 0.013819 0.136021 0.006320 0.214779 0.122718 0.506343 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.6 3. 0.8 3. -5. -2. Chi 8.2E-06 1.2E-04 1.6E-04 4.2E-05 2.3E-04 1.2E-05 Composition Misfit: 5.695103E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 91.993 0.000000 0.052692 0.124717 0.157724 0.243098 0.421769 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.5 0.1 -0.3 0.6 0.1 Chi 0. 5.5E-06 2.1E-07 1.0E-06 2.1E-06 8.6E-09 Composition Misfit: 8.888997E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.006 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.001089 0.058851 0.114421 0.161000 0.231730 0.007692 0.425216 Augite(G) 0.013741 0.135262 0.006284 0.213580 0.122034 0.005581 0.503517 Gt(W) 0.000000 0.052277 0.123735 0.156482 0.241184 0.007874 0.418448 ----- ----- ----- ----- ----- ----- ----- Potentials -792372. -647592. -1665928. -748253. -328336. -448257. -891540. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 44 converged, 42 successes so far. Misfit function evaluations this try => 144 Misfit this try = 8.870823E-06 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.729496E-07 Bayes score, PP * exp(-Misfit) = 1.729481E-07 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 3831.27 659.403 0.191001 0.825769 0.174231 Final coordinates: 10399.2 1007.25 0.202996 0.925352 7.464798E-02 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.551420E-6 Extraneous predicted phases: 3.319403E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 92.567 0.013487 0.140079 0.007309 0.217760 0.117410 0.503956 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -8.8E-03 -1.2E-02 9.1E-03 3.0E-02 5.2E-03 -2.2E-02 Chi 1.7E-09 2.2E-09 1.8E-08 5.0E-09 3.1E-10 1.6E-09 Composition Misfit: 2.840199E-08 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 7.430 0.000000 0.052332 0.124534 0.158036 0.243397 0.421700 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.2 0.3 -0.5 0.3 0.1 Chi 0. 6.3E-07 9.5E-07 3.2E-06 7.2E-07 3.9E-08 Composition Misfit: 5.523018E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.012396 0.132645 0.015993 0.211915 0.126041 0.006396 0.494615 Augite(G) 0.013402 0.139200 0.007263 0.216394 0.116674 0.006270 0.500796 Gt(W) 0.000000 0.051916 0.123544 0.156779 0.241462 0.007953 0.418347 ----- ----- ----- ----- ----- ----- ----- Potentials -778662. -642026. -1655990. -745927. -320960. -442099. -891225. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 45 converged, 43 successes so far. Misfit function evaluations this try => 113 Misfit this try = 5.208391E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 3.040725E-08 Bayes score, PP * exp(-Misfit) = 3.039141E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17914.8 1044.66 0.114132 0.335126 0.664874 Final coordinates: 16531.0 1131.23 0.147544 0.360600 0.639400 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.179910E-4 Extraneous predicted phases: 2.848052E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 35.485 0.013768 0.137627 0.006497 0.214701 0.121142 0.506265 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.5 2. 0.7 3. -3. -2. Chi 5.9E-06 4.3E-05 1.0E-04 4.5E-05 1.1E-04 1.1E-05 Composition Misfit: 3.232681E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 64.512 0.000000 0.054500 0.123968 0.159719 0.240325 0.421488 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 0.7 -2. 3. 0.3 Chi 0. 1.0E-04 6.7E-06 3.6E-05 5.1E-05 2.8E-07 Composition Misfit: 1.947229E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.004826 0.083243 0.081888 0.177830 0.196797 0.007259 0.448157 Augite(G) 0.013692 0.136865 0.006461 0.213512 0.120471 0.005538 0.503461 Gt(W) 0.000000 0.054053 0.122952 0.158410 0.238355 0.008196 0.418034 ----- ----- ----- ----- ----- ----- ----- Potentials -796761. -648953. -1668563. -749087. -330663. -447029. -891978. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 46 converged, 44 successes so far. Misfit function evaluations this try => 96 Misfit this try = 4.967620E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 7.709461E-08 Bayes score, PP * exp(-Misfit) = 7.705633E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8178.24 1112.77 0.356277 0.720164 0.279836 Final coordinates: 14212.4 1084.74 0.183585 0.780348 0.219652 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 4.918367E-4 Extraneous predicted phases: 4.925391E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 77.568 0.013588 0.140090 0.007075 0.216525 0.117906 0.504815 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.2 -2.1E-02 0.2 1. -0.4 -0.7 Chi 8.4E-07 6.0E-09 8.5E-06 7.4E-06 2.0E-06 1.6E-06 Composition Misfit: 2.036496E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 22.429 0.000000 0.054441 0.122543 0.163329 0.238734 0.420954 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 2. -4. 4. 0.8 Chi 0. 9.6E-05 4.4E-05 2.2E-04 1.1E-04 1.8E-06 Composition Misfit: 4.714717E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.003 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.010451 0.119952 0.032923 0.203157 0.144219 0.006619 0.482678 Augite(G) 0.013507 0.139253 0.007033 0.215231 0.117201 0.005979 0.501797 Gt(W) 0.000000 0.053962 0.121463 0.161890 0.236630 0.008809 0.417245 ----- ----- ----- ----- ----- ----- ----- Potentials -790671. -646212. -1663480. -747811. -327257. -441110. -891609. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 47 converged, 45 successes so far. Misfit function evaluations this try => 256 Misfit this try = 3.924155E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 4.809581E-08 Bayes score, PP * exp(-Misfit) = 4.807694E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16827.7 686.363 0.827543 0.568228 0.431772 Final coordinates: 15462.9 1111.05 0.152499 0.437075 0.562925 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.924155E-4 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 43.151 0.013717 0.138516 0.006644 0.215237 0.120008 0.505878 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.4 1. 0.5 2. -2. -2. Chi 4.0E-06 1.7E-05 6.9E-05 3.0E-05 5.6E-05 7.5E-06 Composition Misfit: 1.839381E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 56.849 0.000000 0.054471 0.123841 0.160047 0.240202 0.421440 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 0.8 -2. 3. 0.4 Chi 0. 9.9E-05 8.7E-06 4.6E-05 5.4E-05 3.6E-07 Composition Misfit: 2.084774E-04 *mole fractions relative to measured components, complete compositions below Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005850 0.089928 0.072972 0.182443 0.187224 0.007138 0.454445 Augite(G) 0.013640 0.137733 0.006606 0.214020 0.119329 0.005656 0.503017 Gt(W) 0.000000 0.054022 0.122819 0.158726 0.238220 0.008251 0.417963 ----- ----- ----- ----- ----- ----- ----- Potentials -739536. -634201. -1666473. -735023. -315563. -500045. -905543. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 48 converged, 46 successes so far. Misfit function evaluations this try => 121 Misfit this try = 9.577866E-05 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.318572E-07 Bayes score, PP * exp(-Misfit) = 1.318446E-07 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 3680.91 1091.92 0.223991 0.309085 0.690915 Final coordinates: 12100.4 1045.49 0.163905 0.583323 0.416677 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 8.915956E-5 Extraneous predicted phases: 6.619105E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 58.224 0.013558 0.139608 0.007174 0.216873 0.118229 0.504557 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.1 0.3 0.1 0.8 -0.7 -0.5 Chi 4.3E-07 1.5E-06 3.0E-06 3.9E-06 5.6E-06 7.9E-07 Composition Misfit: 1.515115E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 41.773 0.000000 0.053466 0.124169 0.159079 0.241722 0.421564 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 0.6 -1. 2. 0.3 Chi 0. 3.2E-05 4.0E-06 1.9E-05 1.8E-05 1.7E-07 Composition Misfit: 7.400841E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.004 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.007810 0.102715 0.055914 0.191265 0.168907 0.006921 0.466468 Augite(G) 0.013476 0.138763 0.007131 0.215559 0.117513 0.006059 0.501500 Gt(W) 0.000000 0.053033 0.123162 0.157789 0.239762 0.008110 0.418145 ----- ----- ----- ----- ----- ----- ----- Potentials -784414. -644218. -1659960. -747091. -324131. -443166. -891772. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 49 converged, 47 successes so far. Misfit function evaluations this try => 136 Misfit this try = 2.943878E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 6.821210E-08 Bayes score, PP * exp(-Misfit) = 6.819202E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 6030.52 1098.22 0.392028 0.249395 0.750605 Final coordinates: 14491.0 1093.64 0.145716 0.331706 0.668294 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.937294E-4 Extraneous predicted phases: 6.583861E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 32.842 0.013693 0.137931 0.006731 0.215492 0.120490 0.505663 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.4 2. 0.5 2. -3. -1. Chi 3.2E-06 3.3E-05 5.2E-05 2.5E-05 7.8E-05 6.0E-06 Composition Misfit: 1.965452E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 67.157 0.000000 0.053852 0.124273 0.158902 0.241370 0.421602 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 0.5 -1. 2. 0.2 Chi 0. 5.4E-05 2.9E-06 1.6E-05 2.5E-05 1.2E-07 Composition Misfit: 9.718421E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.004439 0.080718 0.085256 0.176088 0.200415 0.007301 0.445783 Augite(G) 0.013614 0.137142 0.006693 0.214259 0.119800 0.005722 0.502770 Gt(W) 0.000000 0.053417 0.123271 0.157621 0.239424 0.008065 0.418202 ----- ----- ----- ----- ----- ----- ----- Potentials -791348. -646911. -1664935. -748341. -327793. -445831. -892045. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 50 converged, 48 successes so far. Misfit function evaluations this try => 109 Misfit this try = 7.750841E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.561901E-08 Bayes score, PP * exp(-Misfit) = 1.560691E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18935.7 1120.04 0.114592 0.585552 0.414448 Final coordinates: 17792.7 1158.23 0.160244 0.540681 0.459319 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.749752E-4 Extraneous predicted phases: 1.089108E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 53.223 0.013744 0.138524 0.006689 0.214632 0.120272 0.506139 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.5 1. 0.5 3. -2. -2. Chi 5.0E-06 1.7E-05 6.0E-05 4.7E-05 6.8E-05 9.7E-06 Composition Misfit: 2.055762E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 46.777 0.000000 0.055818 0.123011 0.162223 0.237819 0.421129 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -4. 1. -3. 5. 0.7 Chi 0. 2.4E-04 2.8E-05 1.5E-04 1.5E-04 1.2E-06 Composition Misfit: 5.693990E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.007238 0.098987 0.060888 0.188693 0.174249 0.006981 0.462964 Augite(G) 0.013668 0.137757 0.006652 0.213444 0.119606 0.005535 0.503337 Gt(W) 0.000000 0.055337 0.121952 0.160827 0.235772 0.008608 0.417504 ----- ----- ----- ----- ----- ----- ----- Potentials -801370. -650496. -1671479. -749951. -333156. -445639. -892453. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 51 converged, 49 successes so far. Misfit function evaluations this try => 354 Misfit this try = 3.818518E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.741875E-07 Bayes score, PP * exp(-Misfit) = 1.741210E-07 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18349.5 1111.57 0.930996 0.833732 0.166268 Final coordinates: 7991.70 970.130 0.145905 0.336907 0.663093 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.579065E-4 Extraneous predicted phases: 2.394528E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 34.748 0.013170 0.138333 0.008872 0.219336 0.118693 0.501596 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.6 1. -1. -1. -1. 2. Chi 7.4E-06 2.2E-05 2.7E-04 1.1E-05 1.4E-05 1.1E-05 Composition Misfit: 3.359754E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 65.247 0.000000 0.051979 0.125502 0.155789 0.244666 0.422063 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 0.2 -0.5 1. -0.7 -0.2 Chi 0. 5.7E-07 3.1E-06 1.5E-05 3.0E-06 1.3E-07 Composition Misfit: 2.193106E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.005 0.000000 0.197359 0.000000 0.000000 0.469308 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.004509 0.081173 0.084650 0.176403 0.199765 0.007287 0.446213 Augite(G) 0.013080 0.137390 0.008812 0.217841 0.117885 0.006815 0.498177 Gt(W) 0.000000 0.051587 0.124556 0.154615 0.242823 0.007536 0.418883 ----- ----- ----- ----- ----- ----- ----- Potentials -736668. -631461. -1653496. -736780. -309651. -478844. -901656. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 52 converged, 50 successes so far. Misfit function evaluations this try => 145 Misfit this try = 5.259380E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.538786E-07 Bayes score, PP * exp(-Misfit) = 1.537977E-07 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9453.27 739.510 0.369766 9.279562E-02 0.907204 Final coordinates: 6450.50 920.443 0.131759 6.336748E-02 0.936633 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.254964E-4 Extraneous predicted phases: 4.416352E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 6.575 0.013128 0.143392 0.008683 0.220610 0.113053 0.501134 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.7 -2. -1. -3. 4. 2. Chi 9.5E-06 7.7E-05 2.1E-04 3.6E-05 1.7E-04 1.6E-05 Composition Misfit: 5.206287E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 93.424 0.000000 0.051758 0.124998 0.157021 0.244349 0.421874 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 0.4 -0.1 0.2 -0.4 -4.3E-02 Chi 0. 3.0E-06 1.2E-07 5.9E-07 1.2E-06 4.9E-09 Composition Misfit: 4.867692E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.206483 0.000000 0.000000 0.460184 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000848 0.057277 0.116523 0.159916 0.233989 0.007708 0.423740 Augite(G) 0.013036 0.142380 0.008621 0.219053 0.112255 0.007058 0.497597 Gt(W) 0.000000 0.051356 0.124029 0.155804 0.242455 0.007753 0.418604 ----- ----- ----- ----- ----- ----- ----- Potentials -733446. -628937. -1647264. -735501. -306288. -469865. -898799. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 53 converged, 51 successes so far. Misfit function evaluations this try => 118 Misfit this try = 6.271166E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 2.045549E-08 Bayes score, PP * exp(-Misfit) = 2.044267E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18304.1 1061.84 0.228419 0.396785 0.603215 Final coordinates: 17262.8 1148.93 0.150380 0.405222 0.594778 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.264936E-4 Extraneous predicted phases: 6.229501E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 39.886 0.013760 0.137426 0.006625 0.214491 0.121445 0.506254 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.5 2. 0.6 3. -3. -2. Chi 5.6E-06 5.1E-05 7.3E-05 5.1E-05 1.3E-04 1.1E-05 Composition Misfit: 3.242557E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 60.113 0.000000 0.055081 0.123742 0.160323 0.239452 0.421403 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 0.9 -2. 4. 0.4 Chi 0. 1.6E-04 1.0E-05 5.6E-05 8.0E-05 4.3E-07 Composition Misfit: 3.022379E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005424 0.087143 0.076685 0.180521 0.191212 0.007189 0.451826 Augite(G) 0.013684 0.136669 0.006588 0.213310 0.120776 0.005506 0.503467 Gt(W) 0.000000 0.054624 0.122715 0.158993 0.237466 0.008294 0.417908 ----- ----- ----- ----- ----- ----- ----- Potentials -799608. -650083. -1670709. -749795. -332297. -447400. -892501. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 54 converged, 52 successes so far. Misfit function evaluations this try => 176 Misfit this try = 4.000192E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.053718E-07 Bayes score, PP * exp(-Misfit) = 1.049512E-07 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9476.86 1015.08 0.630594 0.710884 0.289116 Final coordinates: 10346.6 1083.81 0.174744 0.700549 0.299451 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.991013E-3 Extraneous predicted phases: 9.179399E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 73.758 0.012851 0.133307 0.012048 0.217625 0.124351 0.499817 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 1. 5. -4. 0.2 -6. 3. Chi 3.1E-05 3.4E-04 1.9E-03 1.3E-07 3.9E-04 3.4E-05 Composition Misfit: 2.649300E-03 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 26.238 0.000000 0.059529 0.126938 0.149997 0.240934 0.422602 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -7. -2. 5. 2. -0.7 Chi 0. 9.1E-04 3.3E-05 3.6E-04 3.4E-05 1.4E-06 Composition Misfit: 1.341713E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 Fsp(C1) 0.004 0.077817 0.000000 0.172183 0.094365 0.000000 0.000000 0.655635 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.009381 0.112970 0.042236 0.198341 0.154221 0.006737 0.476114 Augite(G) 0.012765 0.132418 0.011968 0.216173 0.123522 0.006673 0.496482 Gt(W) 0.000000 0.059117 0.126060 0.148960 0.239268 0.006916 0.419679 ----- ----- ----- ----- ----- ----- ----- Potentials -780656. -646668. -1670056. -750873. -328237. -462934. -902842. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 55 converged, 53 successes so far. Misfit function evaluations this try => 231 Misfit this try = 1.401489E-02 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 4.758744E-08 Bayes score, PP * exp(-Misfit) = 4.692516E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12104.3 1099.59 0.728486 0.607505 0.392495 Final coordinates: 10672.5 1163.73 0.164380 0.588619 0.411381 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.384518E-2 Extraneous predicted phases: 1.697124E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 66.324 0.012034 0.124639 0.017963 0.218161 0.132746 0.494457 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 3. 1.1E+01 -9. -0.3 -1.3E+01 8. Chi 1.7E-04 1.9E-03 6.3E-03 6.2E-07 1.8E-03 1.8E-04 Composition Misfit: 1.034073E-02 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 33.659 0.000000 0.063890 0.128455 0.144219 0.240265 0.423171 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1.1E+01 -3. 8. 3. -1. Chi 0. 2.2E-03 1.0E-04 1.2E-03 5.2E-05 4.3E-06 Composition Misfit: 3.504447E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 Fsp(C1) 0.018 0.077564 0.000000 0.172436 0.094871 0.000000 0.000000 0.655129 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.007881 0.103178 0.055296 0.191584 0.168244 0.006914 0.466903 Augite(G) 0.011946 0.123735 0.017833 0.216579 0.131783 0.007253 0.490871 Gt(W) 0.000000 0.063490 0.127651 0.143316 0.238761 0.006261 0.420521 ----- ----- ----- ----- ----- ----- ----- Potentials -783867. -651940. -1684976. -756024. -335850. -483628. -914313. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 56 converged, 54 successes so far. Misfit function evaluations this try => 131 Misfit this try = 1.298182E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 8.431876E-09 Bayes score, PP * exp(-Misfit) = 8.420937E-09 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18912.0 641.651 0.804195 0.930872 6.912845E-02 Final coordinates: 18431.2 1191.08 0.167838 0.628861 0.371139 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.296949E-3 Extraneous predicted phases: 1.233302E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 62.514 0.013604 0.137612 0.007661 0.214659 0.121276 0.505188 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.2 2. -0.3 3. -3. -1. Chi 1.1E-06 4.4E-05 1.5E-05 4.6E-05 1.2E-04 3.1E-06 Composition Misfit: 2.315608E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 37.485 0.000000 0.057523 0.122554 0.163421 0.235543 0.420958 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -5. 2. -4. 7. 0.8 Chi 0. 5.0E-04 4.4E-05 2.3E-04 2.9E-04 1.8E-06 Composition Misfit: 1.065388E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.008420 0.106699 0.050601 0.194013 0.163203 0.006848 0.470215 Augite(G) 0.013527 0.136833 0.007617 0.213444 0.120589 0.005662 0.502328 Gt(W) 0.000000 0.057017 0.121475 0.161982 0.233470 0.008804 0.417252 ----- ----- ----- ----- ----- ----- ----- Potentials -807293. -653237. -1676807. -752291. -337060. -446565. -895129. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 57 converged, 55 successes so far. Misfit function evaluations this try => 158 Misfit this try = 2.748468E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.186398E-07 Bayes score, PP * exp(-Misfit) = 1.186072E-07 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17683.2 824.473 6.466833E-02 0.765157 0.234843 Final coordinates: 12537.7 1055.99 0.194764 0.868960 0.131040 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.732339E-4 Extraneous predicted phases: 1.612943E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 86.960 0.013488 0.139812 0.007515 0.217186 0.117949 0.504050 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -1.2E-02 0.2 -0.2 0.6 -0.5 -0.1 Chi 2.9E-09 4.5E-07 5.1E-06 1.7E-06 2.4E-06 3.0E-08 Composition Misfit: 9.641449E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 13.039 0.000000 0.054075 0.123240 0.161535 0.239935 0.421215 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 1. -3. 3. 0.6 Chi 0. 6.8E-05 2.2E-05 1.1E-04 6.3E-05 9.0E-07 Composition Misfit: 2.635924E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.011639 0.127709 0.022578 0.208509 0.133112 0.006481 0.489973 Augite(G) 0.013405 0.138949 0.007469 0.215845 0.117221 0.006174 0.500938 Gt(W) 0.000000 0.053615 0.122191 0.160161 0.237893 0.008510 0.417630 ----- ----- ----- ----- ----- ----- ----- Potentials -786353. -644838. -1661034. -747439. -325191. -441384. -892010. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 58 converged, 56 successes so far. Misfit function evaluations this try => 294 Misfit this try = 1.98859 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 4.645194E-09 Bayes score, PP * exp(-Misfit) = 6.358714E-10 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2752.21 813.178 0.936424 0.356911 0.643089 Final coordinates: 19693.9 1199.99 0.324901 1.00000 3.762641E-11 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.236521 Extraneous predicted phases: 1.75207 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.301 0.013659 0.141901 0.007412 0.220632 0.118928 0.497468 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 -1. -0.1 -3. -1. 5. Chi 2.3E-06 2.4E-05 1.1E-06 3.7E-05 1.9E-05 8.4E-05 Composition Misfit: 1.668855E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.011 0.000000 0.043852 0.038174 0.238925 0.289733 0.389315 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 8. 6.9E+01 -5.2E+01 -3.8E+01 3.1E+01 Chi 0. 1.6E-03 0.2 2.8E-02 7.3E-03 2.7E-03 Composition Misfit: 0.236354 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 1.687 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013354 0.138738 0.007251 0.215735 0.116307 0.009447 0.499167 Augite(G) 0.013529 0.140543 0.007341 0.218522 0.117790 0.009565 0.492710 Gt(W) 0.000000 0.041931 0.036503 0.228462 0.277045 0.043793 0.372266 ----- ----- ----- ----- ----- ----- ----- Potentials -826579. -653435. -1692187. -750217. -340419. -372468. -893398. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 59 converged, 57 successes so far. Misfit function evaluations this try => 110 Misfit this try = 7.776166E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.767956E-08 Bayes score, PP * exp(-Misfit) = 1.766582E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16341.1 1167.73 0.164692 0.760129 0.239871 Final coordinates: 17643.7 1151.49 0.162789 0.571608 0.428392 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.773607E-4 Extraneous predicted phases: 2.558738E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 56.214 0.013753 0.139086 0.006577 0.214781 0.119623 0.506180 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.5 0.7 0.6 3. -2. -2. Chi 5.3E-06 6.8E-06 8.4E-05 4.2E-05 4.1E-05 1.0E-05 Composition Misfit: 1.891282E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 43.785 0.000000 0.055648 0.122814 0.162716 0.237768 0.421055 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 2. -3. 5. 0.7 Chi 0. 2.2E-04 3.5E-05 1.8E-04 1.5E-04 1.4E-06 Composition Misfit: 5.882325E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.007653 0.101691 0.057281 0.190559 0.170376 0.006934 0.465507 Augite(G) 0.013677 0.138314 0.006540 0.213589 0.118959 0.005549 0.503371 Gt(W) 0.000000 0.055164 0.121746 0.161302 0.235701 0.008693 0.417395 ----- ----- ----- ----- ----- ----- ----- Potentials -800311. -649928. -1670380. -749498. -332450. -444678. -891954. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 60 converged, 58 successes so far. Misfit function evaluations this try => 140 Misfit this try = 9.737604E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 5.206398E-09 Bayes score, PP * exp(-Misfit) = 5.201330E-09 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18898.1 876.449 0.369566 8.539104E-02 0.914609 Final coordinates: 19969.0 1182.38 0.152784 0.440178 0.559822 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.722826E-4 Extraneous predicted phases: 1.477774E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 42.862 0.013895 0.138443 0.005965 0.213763 0.120662 0.507272 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.8 1. 1. 4. -3. -3. Chi 1.2E-05 1.9E-05 3.1E-04 7.6E-05 8.7E-05 2.2E-05 Composition Misfit: 5.243478E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 57.136 0.000000 0.055370 0.123202 0.161716 0.238512 0.421201 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 1. -3. 4. 0.6 Chi 0. 1.9E-04 2.3E-05 1.2E-04 1.2E-04 9.4E-07 Composition Misfit: 4.479348E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005892 0.090199 0.072609 0.182630 0.186835 0.007136 0.454699 Augite(G) 0.013822 0.137713 0.005934 0.212638 0.120026 0.005266 0.504600 Gt(W) 0.000000 0.054897 0.122152 0.160337 0.236478 0.008526 0.417610 ----- ----- ----- ----- ----- ----- ----- Potentials -804002. -651120. -1672465. -749325. -334061. -446558. -890552. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Augite(G) q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Augite(G) q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 62 converged, 59 successes so far. Misfit function evaluations this try => 510 Misfit this try = 1.94799 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 4.392888E-09 Bayes score, PP * exp(-Misfit) = 6.262511E-10 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18955.6 1160.89 0.903988 0.649601 0.350399 Final coordinates: 19834.6 1199.84 0.323824 0.999970 2.987647E-05 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.229837 Extraneous predicted phases: 1.71815 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.323 0.013656 0.141874 0.007416 0.220603 0.118926 0.497524 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 -1. -0.1 -3. -1. 5. Chi 2.2E-06 2.3E-05 1.2E-06 3.6E-05 1.9E-05 8.2E-05 Composition Misfit: 1.640428E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.006 0.000000 0.044097 0.038807 0.238222 0.289322 0.389553 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 8. 6.9E+01 -5.1E+01 -3.7E+01 3.1E+01 Chi 0. 1.5E-03 0.2 2.7E-02 7.2E-03 2.7E-03 Composition Misfit: 0.229673 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 1.671 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013354 0.138740 0.007255 0.215740 0.116315 0.009416 0.499180 Augite(G) 0.013526 0.140521 0.007346 0.218500 0.117792 0.009535 0.492780 Gt(W) 0.000000 0.042177 0.037117 0.227850 0.276725 0.043540 0.372591 ----- ----- ----- ----- ----- ----- ----- Potentials -826091. -653375. -1691360. -749939. -340333. -372569. -893062. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 63 converged, 60 successes so far. Misfit function evaluations this try => 126 Misfit this try = 1.415705E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 4.117260E-08 Bayes score, PP * exp(-Misfit) = 4.111436E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16351.0 927.046 0.597743 0.916786 8.321374E-02 Final coordinates: 15481.4 1126.61 0.202895 0.925530 7.447047E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.415680E-3 Extraneous predicted phases: 2.519650E-8 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 93.112 0.013409 0.139260 0.008220 0.216777 0.118749 0.503585 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.1 0.6 -0.7 0.9 -1. 0.3 Chi 3.9E-07 4.6E-06 9.8E-05 4.8E-06 1.5E-05 2.3E-07 Composition Misfit: 1.233989E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 6.888 0.000000 0.056559 0.121299 0.166579 0.235076 0.420487 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -4. 3. -6. 7. 1. Chi 0. 3.4E-04 1.1E-04 5.1E-04 3.2E-04 4.3E-06 Composition Misfit: 1.292281E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.012398 0.132661 0.015972 0.211926 0.126019 0.006392 0.494631 Augite(G) 0.013327 0.138400 0.008169 0.215439 0.118016 0.006171 0.500477 Gt(W) 0.000000 0.056030 0.120166 0.165023 0.232879 0.009344 0.416558 ----- ----- ----- ----- ----- ----- ----- Potentials -797850. -649199. -1669103. -750029. -331714. -440381. -893799. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 64 converged, 61 successes so far. Misfit function evaluations this try => 200 Misfit this try = 6.641502E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.798019E-08 Bayes score, PP * exp(-Misfit) = 1.796825E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9269.52 1038.18 0.683446 0.101226 0.898774 Final coordinates: 17626.4 1150.47 0.154249 0.461870 0.538130 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.641502E-4 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 45.357 0.013783 0.138304 0.006454 0.214528 0.120505 0.506426 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.6 1. 0.7 3. -3. -2. Chi 6.6E-06 2.2E-05 1.2E-04 5.0E-05 7.9E-05 1.2E-05 Composition Misfit: 2.864445E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 54.643 0.000000 0.055220 0.123424 0.161131 0.238941 0.421284 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 1. -2. 4. 0.5 Chi 0. 1.7E-04 1.7E-05 9.0E-05 9.9E-05 7.0E-07 Composition Misfit: 3.777056E-04 *mole fractions relative to measured components, complete compositions below Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.006183 0.092096 0.070080 0.183939 0.184119 0.007100 0.456484 Augite(G) 0.013708 0.137546 0.006418 0.213352 0.119844 0.005481 0.503650 Gt(W) 0.000000 0.054754 0.122384 0.159773 0.236926 0.008430 0.417733 ----- ----- ----- ----- ----- ----- ----- Potentials -740091. -634984. -1670306. -734519. -317281. -505911. -906784. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 65 converged, 62 successes so far. Misfit function evaluations this try => 157 Misfit this try = 1.582373E-05 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.734833E-07 Bayes score, PP * exp(-Misfit) = 1.734806E-07 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16258.0 1111.89 0.184147 0.923672 7.632803E-02 Final coordinates: 10085.1 1005.84 0.167491 0.624520 0.375480 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.220250E-5 Extraneous predicted phases: 3.621230E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 62.817 0.013452 0.139673 0.007550 0.217777 0.117830 0.503718 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.1 0.3 -0.2 1.5E-02 -0.4 0.2 Chi 6.5E-08 1.1E-06 7.0E-06 1.2E-09 1.5E-06 8.7E-08 Composition Misfit: 9.679250E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 37.180 0.000000 0.052482 0.124930 0.157140 0.243600 0.421849 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.3 -4.2E-02 0.1 0.2 -1.9E-02 Chi 0. 2.1E-06 2.2E-08 2.2E-07 1.9E-07 9.1E-10 Composition Misfit: 2.523250E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.003 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.008362 0.106319 0.051108 0.193751 0.163747 0.006857 0.469857 Augite(G) 0.013367 0.138793 0.007502 0.216404 0.117087 0.006303 0.500543 Gt(W) 0.000000 0.052074 0.123958 0.155917 0.241704 0.007782 0.418566 ----- ----- ----- ----- ----- ----- ----- Potentials -778433. -642155. -1656267. -746231. -321094. -442884. -891784. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 66 converged, 63 successes so far. Misfit function evaluations this try => 172 Misfit this try = 2.886592E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.009089E-07 Bayes score, PP * exp(-Misfit) = 1.008798E-07 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16887.3 636.359 0.439143 8.833375E-02 0.911666 Final coordinates: 13370.0 1065.97 0.129392 8.577678E-03 0.991422 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.876371E-4 Extraneous predicted phases: 1.022154E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.851 0.013703 0.137416 0.006482 0.215778 0.120885 0.505736 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.4 2. 0.7 2. -3. -1. Chi 3.6E-06 5.1E-05 1.1E-04 1.9E-05 1.0E-04 6.5E-06 Composition Misfit: 2.876004E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.148 0.000000 0.052184 0.124870 0.157353 0.243766 0.421826 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3.2E-02 6.3E-03 -1.7E-02 4.1E-02 2.8E-03 Chi 0. 2.1E-08 5.0E-10 4.7E-09 1.0E-08 2.1E-11 Composition Misfit: 3.660605E-08 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.190623 0.000000 0.000000 0.476043 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000115 0.052493 0.122904 0.156615 0.240841 0.007791 0.419241 Augite(G) 0.013624 0.136625 0.006445 0.214536 0.120190 0.005755 0.502825 Gt(W) 0.000000 0.051777 0.123895 0.156125 0.241863 0.007808 0.418532 ----- ----- ----- ----- ----- ----- ----- Potentials -738372. -633220. -1661799. -735157. -313144. -494678. -903366. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 67 converged, 64 successes so far. Misfit function evaluations this try => 162 Misfit this try = 6.727701E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 2.193670E-08 Bayes score, PP * exp(-Misfit) = 2.192195E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 5414.71 697.627 6.069587E-02 0.163685 0.836315 Final coordinates: 17335.4 1140.50 0.158743 0.522197 0.477803 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.715973E-4 Extraneous predicted phases: 1.172760E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 51.248 0.013786 0.139209 0.006351 0.214783 0.119461 0.506409 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.6 0.6 0.8 3. -2. -2. Chi 6.7E-06 5.2E-06 1.5E-04 4.2E-05 3.5E-05 1.2E-05 Composition Misfit: 2.489882E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 48.751 0.000000 0.055105 0.123126 0.161893 0.238704 0.421172 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 1. -3. 4. 0.6 Chi 0. 1.6E-04 2.5E-05 1.3E-04 1.1E-04 1.0E-06 Composition Misfit: 4.226091E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.200249 0.000000 0.000000 0.466418 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.006991 0.097370 0.063045 0.187578 0.176565 0.007007 0.461444 Augite(G) 0.013710 0.138441 0.006316 0.213599 0.118802 0.005516 0.503616 Gt(W) 0.000000 0.054634 0.122072 0.160507 0.236661 0.008559 0.417568 ----- ----- ----- ----- ----- ----- ----- Potentials -739276. -634337. -1668803. -734105. -316471. -503915. -906057. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 68 converged, 65 successes so far. Misfit function evaluations this try => 176 Misfit this try = 3.263250E-06 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.759536E-07 Bayes score, PP * exp(-Misfit) = 1.759531E-07 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13183.7 1156.25 6.828439E-02 0.891115 0.108885 Final coordinates: 10137.4 1002.99 0.209999 0.969270 3.072992E-02 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.615204E-6 Extraneous predicted phases: 1.648046E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 96.970 0.013480 0.140048 0.007341 0.217773 0.117451 0.503907 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 4.0E-03 9.3E-03 -1.7E-02 1.8E-02 -3.0E-02 1.6E-02 Chi 3.4E-10 1.2E-09 5.8E-08 1.8E-09 1.0E-08 8.2E-10 Composition Misfit: 7.290944E-08 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 3.028 0.000000 0.052145 0.124864 0.157720 0.243447 0.421824 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 6.0E-03 1.1E-02 -0.3 0.3 4.8E-03 Chi 0. 7.4E-10 1.4E-09 9.8E-07 5.6E-07 6.0E-11 Composition Misfit: 1.542294E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.012985 0.136491 0.010864 0.214568 0.120533 0.006328 0.498232 Augite(G) 0.013395 0.139169 0.007295 0.216405 0.116714 0.006281 0.500742 Gt(W) 0.000000 0.051738 0.123889 0.156488 0.241546 0.007810 0.418529 ----- ----- ----- ----- ----- ----- ----- Potentials -777940. -641847. -1655628. -745886. -320713. -442363. -891337. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 69 converged, 66 successes so far. Misfit function evaluations this try => 145 Misfit this try = 1.678092E-05 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.693255E-07 Bayes score, PP * exp(-Misfit) = 1.693227E-07 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 11811.6 665.477 5.755566E-02 0.910691 8.930930E-02 Final coordinates: 10505.9 1011.65 0.208374 0.959599 4.040126E-02 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.567973E-5 Extraneous predicted phases: 1.101186E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 96.058 0.013473 0.139989 0.007415 0.217712 0.117538 0.503874 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 1.6E-02 0.1 -0.1 0.1 -0.1 4.2E-02 Chi 5.7E-09 3.8E-08 1.2E-06 3.0E-08 1.2E-07 5.6E-09 Composition Misfit: 1.414712E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 3.940 0.000000 0.052534 0.124470 0.158376 0.242945 0.421676 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.4 0.3 -0.7 0.7 0.1 Chi 0. 2.8E-06 1.3E-06 7.0E-06 3.1E-06 5.5E-08 Composition Misfit: 1.426502E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.012855 0.135644 0.011993 0.213984 0.121746 0.006342 0.497436 Augite(G) 0.013388 0.139111 0.007368 0.216346 0.116800 0.006274 0.500713 Gt(W) 0.000000 0.052115 0.123476 0.157112 0.241006 0.007980 0.418311 ----- ----- ----- ----- ----- ----- ----- Potentials -779349. -642356. -1656548. -746164. -321453. -442085. -891487. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 70 converged, 67 successes so far. Misfit function evaluations this try => 142 Misfit this try = 5.835709E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 9.435611E-08 Bayes score, PP * exp(-Misfit) = 9.380708E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 5057.66 849.407 9.071928E-02 0.892502 0.107498 Final coordinates: 4621.97 834.240 0.203343 0.929037 7.096310E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.825609E-3 Extraneous predicted phases: 1.010015E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 91.224 0.013739 0.142846 0.004756 0.219562 0.113720 0.505377 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.5 -2. 2. -2. 3. -1. Chi 4.8E-06 5.4E-05 1.4E-03 1.4E-05 1.2E-04 4.2E-06 Composition Misfit: 1.580476E-03 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 8.773 0.000000 0.040703 0.128214 0.151038 0.256965 0.423080 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 1.1E+01 -3. 4. -1.1E+01 -1. Chi 0. 3.2E-03 8.7E-05 2.6E-04 6.7E-04 3.7E-06 Composition Misfit: 4.245134E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.003 0.000000 0.167437 0.000000 0.000000 0.499229 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.012445 0.132969 0.015562 0.212139 0.125579 0.006384 0.494922 Augite(G) 0.013652 0.141934 0.004725 0.218160 0.112994 0.006386 0.502150 Gt(W) 0.000000 0.040444 0.127397 0.150076 0.255330 0.006366 0.420387 ----- ----- ----- ----- ----- ----- ----- Potentials -728302. -625886. -1637334. -732700. -299490. -464420. -891681. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 71 converged, 68 successes so far. Misfit function evaluations this try => 258 Misfit this try = 9.81894 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 6.455172E-09 Bayes score, PP * exp(-Misfit) = 3.512351E-13 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2294.69 689.045 0.899630 0.519440 0.480560 Final coordinates: 2121.66 1199.13 0.397873 0.999874 1.256003E-04 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.30049 Extraneous predicted phases: 7.51845 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 95.986 0.013940 0.144820 0.007577 0.225190 0.112542 0.495931 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.8 -3. -0.2 -7. 4. 6. Chi 1.5E-05 1.6E-04 8.7E-06 2.4E-04 2.1E-04 1.3E-04 Composition Misfit: 7.632407E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.007 0.000000 0.020057 0.006502 0.322723 0.273280 0.377438 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 3.1E+01 9.5E+01 -1.1E+02 -2.4E+01 4.2E+01 Chi 0. 0.1 2. 0.1 3.2E-03 5.2E-03 Composition Misfit: 2.29972 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 Sp(WPC) 0.753 0.000000 0.000743 0.000743 0.000000 0.855869 0.142645 0.000000 q 3.254 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013324 0.138433 0.007250 0.215271 0.116077 0.011546 0.498099 Augite(G) 0.013794 0.143302 0.007498 0.222829 0.111362 0.010484 0.490732 Gt(W) 0.000000 0.018928 0.006136 0.304555 0.257895 0.056297 0.356190 ----- ----- ----- ----- ----- ----- ----- Potentials -840186. -673403. -1763896. -766768. -365038. -375220. -934106. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 72 converged, 69 successes so far. Misfit function evaluations this try => 121 Misfit this try = 3.742396E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 5.519355E-08 Bayes score, PP * exp(-Misfit) = 5.517289E-08 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18945.3 813.743 0.144700 8.709379E-02 0.912906 Final coordinates: 15201.7 1102.15 0.141663 0.261840 0.738160 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.735813E-4 Extraneous predicted phases: 6.583087E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 25.804 0.013760 0.137860 0.006399 0.215105 0.120708 0.506167 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.5 2. 0.7 2. -3. -2. Chi 5.6E-06 3.5E-05 1.3E-04 3.4E-05 9.0E-05 9.9E-06 Composition Misfit: 3.066364E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 74.195 0.000000 0.053538 0.124359 0.158686 0.241782 0.421635 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 0.4 -0.9 2. 0.2 Chi 0. 3.6E-05 2.2E-06 1.2E-05 1.7E-05 9.0E-08 Composition Misfit: 6.694492E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.003504 0.074613 0.093399 0.171876 0.209159 0.007408 0.440042 Augite(G) 0.013683 0.137088 0.006363 0.213899 0.120032 0.005605 0.503330 Gt(W) 0.000000 0.053108 0.123360 0.157413 0.239841 0.008028 0.418250 ----- ----- ----- ----- ----- ----- ----- Potentials -792218. -647229. -1665350. -748135. -328134. -446548. -891454. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 73 converged, 70 successes so far. Misfit function evaluations this try => 193 Misfit this try = 1.030164E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 6.662917E-09 Bayes score, PP * exp(-Misfit) = 6.656056E-09 Best Bayes score so far = 1.819476E-07 obtained on Try 17 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12232.1 822.758 0.809612 5.592744E-02 0.944073 Final coordinates: 19917.1 1163.85 0.146979 0.352562 0.647438 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.029902E-3 Extraneous predicted phases: 2.624875E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 34.154 0.013970 0.138979 0.005477 0.213773 0.120003 0.507799 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.9 0.8 1. 4. -2. -3. Chi 1.7E-05 8.4E-06 6.2E-04 7.6E-05 5.6E-05 3.0E-05 Composition Misfit: 8.069080E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 65.845 0.000000 0.054352 0.123632 0.160531 0.240123 0.421362 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 1. -2. 3. 0.4 Chi 0. 8.9E-05 1.3E-05 6.4E-05 5.7E-05 5.2E-07 Composition Misfit: 2.229939E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.004719 0.082541 0.082825 0.177346 0.197804 0.007268 0.447497 Augite(G) 0.013898 0.138259 0.005448 0.212665 0.119381 0.005182 0.505167 Gt(W) 0.000000 0.053899 0.122601 0.159192 0.238120 0.008341 0.417848 ----- ----- ----- ----- ----- ----- ----- Potentials -800147. -649297. -1668880. -747613. -331526. -446042. -888351. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 74 converged, 71 successes so far. Misfit function evaluations this try => 163 Misfit this try = 1.135617E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.822953E-07 Bayes score, PP * exp(-Misfit) = 1.822746E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 3225.46 818.402 0.483875 0.125033 0.874967 Final coordinates: 8106.50 958.584 0.134184 0.116424 0.883576 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.133175E-4 Extraneous predicted phases: 2.442589E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 11.890 0.013321 0.141597 0.007906 0.219146 0.115380 0.502649 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.3 -1. -0.5 -1. 2. 1. Chi 1.9E-06 1.7E-05 4.3E-05 8.4E-06 3.6E-05 3.3E-06 Composition Misfit: 1.095192E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 88.110 0.000000 0.051806 0.124987 0.157050 0.244288 0.421870 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 0.3 -0.1 0.2 -0.4 -3.9E-02 Chi 0. 2.3E-06 9.5E-08 4.8E-07 9.1E-07 4.0E-09 Composition Misfit: 3.798315E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.000 0.000000 0.200406 0.000000 0.000000 0.466260 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.001558 0.061910 0.110343 0.163112 0.227353 0.007627 0.428097 Augite(G) 0.013233 0.140656 0.007853 0.217690 0.114614 0.006646 0.499308 Gt(W) 0.000000 0.051404 0.124017 0.155832 0.242392 0.007758 0.418597 ----- ----- ----- ----- ----- ----- ----- Potentials -735137. -630211. -1651184. -735590. -308191. -476473. -900113. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 75 converged, 72 successes so far. Misfit function evaluations this try => 172 Misfit this try = 9.913621E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 4.319167E-09 Bayes score, PP * exp(-Misfit) = 4.314887E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 4511.65 1161.82 0.517804 0.302741 0.697259 Final coordinates: 19994.2 1196.09 0.151953 0.427718 0.572282 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.882978E-4 Extraneous predicted phases: 3.064283E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 41.818 0.013844 0.137276 0.006358 0.213602 0.121991 0.506929 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.7 2. 0.8 4. -4. -2. Chi 9.5E-06 5.7E-05 1.5E-04 8.2E-05 1.7E-04 1.8E-05 Composition Misfit: 4.830210E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 58.180 0.000000 0.055827 0.123314 0.161483 0.238134 0.421243 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -4. 1. -3. 5. 0.6 Chi 0. 2.4E-04 2.0E-05 1.1E-04 1.4E-04 8.2E-07 Composition Misfit: 5.052768E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005725 0.089110 0.074062 0.181878 0.188395 0.007157 0.453674 Augite(G) 0.013771 0.136548 0.006325 0.212469 0.121345 0.005301 0.504242 Gt(W) 0.000000 0.055354 0.122268 0.160114 0.236115 0.008478 0.417671 ----- ----- ----- ----- ----- ----- ----- Potentials -806563. -652531. -1675222. -750635. -335867. -448148. -892225. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Augite(G) q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Augite(G) q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 77 converged, 73 successes so far. Misfit function evaluations this try => 575 Misfit this try = 6.102369E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 5.403270E-09 Bayes score, PP * exp(-Misfit) = 5.370398E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 4076.80 981.274 0.889110 0.236941 0.763059 Final coordinates: 20000.0 1178.36 0.215436 1.00000 4.172728E-21 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.095429E-3 Extraneous predicted phases: 6.939377E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.959 0.013487 0.140098 0.007280 0.217810 0.117377 0.503947 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -1.0E-02 -2.6E-02 3.2E-02 -1.6E-02 3.3E-02 -1.5E-02 Chi 2.2E-09 9.3E-09 2.2E-07 1.5E-09 1.3E-08 7.6E-10 Composition Misfit: 2.441112E-07 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.037 0.000000 0.053029 0.114152 0.185164 0.229848 0.417807 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.8 9. -1.8E+01 1.1E+01 4. Chi 0. 1.5E-05 1.0E-03 4.2E-03 8.5E-04 3.9E-05 Composition Misfit: 6.095185E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.003 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013397 0.139181 0.007274 0.216424 0.116679 0.006284 0.500761 Augite(G) 0.013402 0.139217 0.007235 0.216442 0.116640 0.006282 0.500781 Gt(W) 0.000000 0.052371 0.112736 0.182868 0.226998 0.012403 0.412625 ----- ----- ----- ----- ----- ----- ----- Potentials -806574. -650967. -1671474. -748281. -334728. -428415. -889977. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 78 converged, 74 successes so far. Misfit function evaluations this try => 599 Misfit this try = 1.95357 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 4.305080E-09 Bayes score, PP * exp(-Misfit) = 6.103155E-10 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 4575.47 1022.25 0.910279 0.916834 8.316625E-02 Final coordinates: 19878.4 1199.99 0.324042 0.999996 3.676089E-06 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.228788 Extraneous predicted phases: 1.72479 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.317 0.013658 0.141884 0.007412 0.220610 0.118919 0.497518 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 -1. -0.1 -3. -1. 5. Chi 2.3E-06 2.3E-05 1.1E-06 3.6E-05 1.9E-05 8.3E-05 Composition Misfit: 1.643550E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.010 0.000000 0.044142 0.038922 0.238611 0.288730 0.389596 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 8. 6.9E+01 -5.2E+01 -3.7E+01 3.1E+01 Chi 0. 1.5E-03 0.2 2.8E-02 7.0E-03 2.7E-03 Composition Misfit: 0.228624 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 1.674 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013355 0.138741 0.007252 0.215740 0.116311 0.009422 0.499179 Augite(G) 0.013527 0.140530 0.007341 0.218505 0.117785 0.009540 0.492771 Gt(W) 0.000000 0.042222 0.037229 0.228233 0.276172 0.043494 0.372651 ----- ----- ----- ----- ----- ----- ----- Potentials -826019. -653368. -1691320. -749883. -340315. -372523. -892982. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 79 converged, 75 successes so far. Misfit function evaluations this try => 97 Misfit this try = 7.889523E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.006463E-08 Bayes score, PP * exp(-Misfit) = 1.005669E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17604.6 1136.55 0.491679 0.413852 0.586148 Final coordinates: 18677.1 1169.84 0.148636 0.378304 0.621696 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.878159E-4 Extraneous predicted phases: 1.136472E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 37.035 0.013832 0.137284 0.006314 0.213939 0.121818 0.506813 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.7 2. 0.8 4. -4. -2. Chi 8.9E-06 5.6E-05 1.6E-04 6.9E-05 1.6E-04 1.6E-05 Composition Misfit: 4.701686E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 62.963 0.000000 0.055110 0.123682 0.160498 0.239330 0.421381 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 1. -2. 4. 0.4 Chi 0. 1.6E-04 1.2E-05 6.3E-05 8.4E-05 4.8E-07 Composition Misfit: 3.176473E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005063 0.084790 0.079824 0.178898 0.194582 0.007230 0.449613 Augite(G) 0.013758 0.136548 0.006280 0.212792 0.121165 0.005361 0.504096 Gt(W) 0.000000 0.054651 0.122653 0.159163 0.237339 0.008320 0.417875 ----- ----- ----- ----- ----- ----- ----- Potentials -802431. -651006. -1672350. -749879. -333619. -447899. -891898. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 80 converged, 76 successes so far. Misfit function evaluations this try => 145 Misfit this try = 1.081232E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.195267E-08 Bayes score, PP * exp(-Misfit) = 1.193976E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17280.3 1042.27 0.471353 0.132754 0.867246 Final coordinates: 19115.0 1140.30 0.146370 0.342808 0.657192 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.081093E-3 Extraneous predicted phases: 1.382814E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 33.170 0.013987 0.140023 0.005265 0.214112 0.118739 0.507874 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.9 2.7E-02 2. 3. -1. -3. Chi 1.8E-05 1.0E-08 8.0E-04 6.3E-05 1.5E-05 3.1E-05 Composition Misfit: 9.288144E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 66.829 0.000000 0.053795 0.123720 0.160261 0.240829 0.421395 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 0.9 -2. 2. 0.4 Chi 0. 5.0E-05 1.1E-05 5.4E-05 3.7E-05 4.5E-07 Composition Misfit: 1.522789E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.004588 0.081688 0.083962 0.176758 0.199025 0.007283 0.446696 Augite(G) 0.013914 0.139294 0.005238 0.212997 0.118120 0.005209 0.505229 Gt(W) 0.000000 0.053348 0.122693 0.158930 0.238830 0.008303 0.417896 ----- ----- ----- ----- ----- ----- ----- Potentials -796305. -647590. -1665626. -746444. -329223. -444704. -887244. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 81 converged, 77 successes so far. Misfit function evaluations this try => 153 Misfit this try = 1.004963E-05 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.724177E-07 Bayes score, PP * exp(-Misfit) = 1.724160E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 4187.27 650.277 0.777184 0.712137 0.287863 Final coordinates: 10433.3 1007.92 0.215115 0.999216 7.837741E-04 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.849420E-6 Extraneous predicted phases: 2.002133E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.930 0.013481 0.140055 0.007330 0.217788 0.117428 0.503919 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 2.0E-03 4.9E-03 -8.1E-03 4.4E-03 -9.8E-03 7.1E-03 Chi 8.4E-11 3.3E-10 1.4E-08 1.1E-10 1.1E-09 1.6E-10 Composition Misfit: 1.576297E-08 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.069 0.000000 0.052263 0.124480 0.158363 0.243215 0.421680 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.1 0.3 -0.7 0.5 0.1 Chi 0. 2.4E-07 1.3E-06 6.8E-06 1.5E-06 5.3E-08 Composition Misfit: 9.833657E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013387 0.139113 0.007366 0.216378 0.116778 0.006280 0.500699 Augite(G) 0.013396 0.139175 0.007284 0.216420 0.116691 0.006279 0.500754 Gt(W) 0.000000 0.051846 0.123487 0.157100 0.241275 0.007976 0.418317 ----- ----- ----- ----- ----- ----- ----- Potentials -778788. -642070. -1656017. -745924. -321047. -441835. -891224. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 82 converged, 78 successes so far. Misfit function evaluations this try => 95 Misfit this try = 3.649705E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.714002E-07 Bayes score, PP * exp(-Misfit) = 1.713377E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 6607.38 691.687 0.191315 0.842301 0.157699 Final coordinates: 7392.27 947.823 0.191074 0.842262 0.157738 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.644189E-4 Extraneous predicted phases: 5.516369E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 84.742 0.013421 0.139970 0.007479 0.218505 0.117207 0.503417 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.1 0.1 -0.1 -0.7 0.2 0.4 Chi 2.8E-07 5.9E-08 3.4E-06 2.3E-06 3.7E-07 5.2E-07 Composition Misfit: 6.936425E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 15.257 0.000000 0.050461 0.126928 0.151918 0.248096 0.422598 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 2. -2. 3. -4. -0.7 Chi 0. 5.7E-05 3.3E-05 1.9E-04 7.4E-05 1.4E-06 Composition Misfit: 3.574825E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.190846 0.000000 0.000000 0.475821 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.011281 0.125372 0.025695 0.206897 0.136459 0.006518 0.487777 Augite(G) 0.013334 0.139068 0.007431 0.217096 0.116452 0.006445 0.500173 Gt(W) 0.000000 0.050112 0.126049 0.150866 0.246379 0.006921 0.419673 ----- ----- ----- ----- ----- ----- ----- Potentials -735983. -630716. -1650863. -736392. -308053. -477755. -899784. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 83 converged, 79 successes so far. Misfit function evaluations this try => 264 Misfit this try = 1.455517E-02 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 6.644341E-08 Bayes score, PP * exp(-Misfit) = 6.548332E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 3513.36 698.074 0.302481 0.741330 0.258670 Final coordinates: 4089.94 783.434 0.201874 0.918279 8.172085E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.451129E-2 Extraneous predicted phases: 4.387988E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 89.144 0.013888 0.144832 0.003373 0.220164 0.111436 0.506306 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.8 -3. 3. -2. 5. -2. Chi 1.2E-05 1.6E-04 4.6E-03 2.6E-05 3.2E-04 1.1E-05 Composition Misfit: 5.144130E-03 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 10.846 0.000000 0.035284 0.127595 0.153243 0.261029 0.422848 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 1.6E+01 -2. 3. -1.4E+01 -1. Chi 0. 8.1E-03 5.8E-05 1.1E-04 1.1E-03 2.5E-06 Composition Misfit: 9.367160E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.154531 0.000000 0.000000 0.512136 0.000000 0.333333 ab 0.009 0.125000 0.000000 0.125000 0.000000 0.000000 0.000000 0.750000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.012301 0.132026 0.016819 0.211488 0.126928 0.006406 0.494033 Augite(G) 0.013799 0.143908 0.003352 0.218760 0.110725 0.006379 0.503077 Gt(W) 0.000000 0.035050 0.126749 0.152227 0.259298 0.006633 0.420044 ----- ----- ----- ----- ----- ----- ----- Potentials -723582. -623041. -1630635. -729912. -294887. -457508. -887168. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 84 converged, 80 successes so far. Misfit function evaluations this try => 148 Misfit this try = 8.985438E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 6.805743E-09 Bayes score, PP * exp(-Misfit) = 6.799630E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15569.2 815.188 0.412409 0.122704 0.877296 Final coordinates: 19578.9 1173.68 0.146459 0.343747 0.656253 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 8.976010E-4 Extraneous predicted phases: 9.428555E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 33.454 0.013912 0.137739 0.005876 0.213668 0.121412 0.507393 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.8 2. 1. 4. -3. -3. Chi 1.3E-05 3.9E-05 3.6E-04 8.0E-05 1.3E-04 2.4E-05 Composition Misfit: 6.424133E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 66.545 0.000000 0.054713 0.123727 0.160353 0.239809 0.421398 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 0.9 -2. 3. 0.4 Chi 0. 1.2E-04 1.1E-05 5.7E-05 6.7E-05 4.4E-07 Composition Misfit: 2.551877E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.004601 0.081770 0.083852 0.176814 0.198907 0.007283 0.446772 Augite(G) 0.013839 0.137017 0.005845 0.212549 0.120776 0.005241 0.504734 Gt(W) 0.000000 0.054259 0.122700 0.159022 0.237819 0.008300 0.417900 ----- ----- ----- ----- ----- ----- ----- Potentials -802335. -650624. -1671503. -749022. -333175. -447643. -890341. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 85 converged, 81 successes so far. Misfit function evaluations this try => 131 Misfit this try = 1.178225E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.209112E-08 Bayes score, PP * exp(-Misfit) = 1.207688E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16738.2 1037.26 0.906514 5.088935E-02 0.949111 Final coordinates: 18863.9 1147.94 0.130937 4.223401E-02 0.957766 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.173966E-3 Extraneous predicted phases: 4.258985E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 4.089 0.014011 0.135943 0.005457 0.213522 0.123230 0.507836 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -1. 3. 1. 4. -5. -3. Chi 2.0E-05 1.2E-04 6.4E-04 8.5E-05 2.7E-04 3.0E-05 Composition Misfit: 1.170531E-03 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 95.908 0.000000 0.052473 0.124764 0.157611 0.243365 0.421786 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.3 0.1 -0.2 0.4 4.0E-02 Chi 0. 2.0E-06 1.0E-07 5.2E-07 8.4E-07 4.3E-09 Composition Misfit: 3.435511E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.003 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000565 0.055431 0.118984 0.158641 0.236631 0.007746 0.422002 Augite(G) 0.013939 0.135236 0.005429 0.212412 0.122590 0.005199 0.505195 Gt(W) 0.000000 0.052061 0.123784 0.156374 0.241454 0.007854 0.418474 ----- ----- ----- ----- ----- ----- ----- Potentials -797130. -648808. -1667879. -747512. -330199. -449177. -888754. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 86 converged, 82 successes so far. Misfit function evaluations this try => 527 Misfit this try = 0.175606 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 4.091766E-09 Bayes score, PP * exp(-Misfit) = 3.432781E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14626.4 1134.66 0.918365 0.853242 0.146758 Final coordinates: 20000.0 600.009 0.216527 0.999126 8.740108E-04 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.175292 Extraneous predicted phases: 3.141550E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 95.289 0.014137 0.146196 0.001081 0.223258 0.107718 0.507609 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -1. -4. 5. -5. 8. -3. Chi 3.0E-05 2.6E-04 3.6E-02 1.3E-04 8.7E-04 2.7E-05 Composition Misfit: 3.732617E-02 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 4.689 0.000000 0.014629 0.135954 0.106714 0.316720 0.425983 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 3.6E+01 -9. 3.2E+01 -6.0E+01 -4. Chi 0. 0.1 9.0E-04 2.4E-02 1.7E-02 4.1E-05 Composition Misfit: 0.137966 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.023 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013385 0.139100 0.007376 0.216363 0.116784 0.006322 0.500670 Augite(G) 0.014045 0.145248 0.001074 0.221810 0.107019 0.006486 0.504317 Gt(W) 0.000000 0.014585 0.135545 0.106392 0.315767 0.003011 0.424700 ----- ----- ----- ----- ----- ----- ----- Potentials -691144. -601846. -1577706. -701405. -264103. -415085. -830058. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 87 converged, 83 successes so far. Misfit function evaluations this try => 194 Misfit this try = 4.482047E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 5.877827E-09 Bayes score, PP * exp(-Misfit) = 5.851542E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14319.6 661.045 0.136600 0.697662 0.302338 Final coordinates: 19841.6 1176.90 0.206523 0.949737 5.026257E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 4.441797E-3 Extraneous predicted phases: 4.024985E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 94.243 0.013591 0.140644 0.006888 0.216885 0.117197 0.504795 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.2 -0.4 0.3 0.8 0.2 -0.7 Chi 8.9E-07 2.4E-06 2.7E-05 3.8E-06 4.1E-07 1.5E-06 Composition Misfit: 3.616908E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 5.752 0.000000 0.054145 0.116476 0.180283 0.230418 0.418678 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 7. -1.5E+01 1.1E+01 3. Chi 0. 7.3E-05 6.1E-04 2.9E-03 7.8E-04 2.4E-05 Composition Misfit: 4.405628E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.005 0.000000 0.214040 0.000000 0.000000 0.452627 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.012723 0.134781 0.013145 0.213390 0.122984 0.006350 0.496627 Augite(G) 0.013509 0.139795 0.006846 0.215575 0.116490 0.006038 0.501747 Gt(W) 0.000000 0.053527 0.115147 0.178226 0.227789 0.011410 0.413901 ----- ----- ----- ----- ----- ----- ----- Potentials -735335. -633232. -1671321. -730920. -316911. -502327. -907736. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 88 converged, 84 successes so far. Misfit function evaluations this try => 226 Misfit this try = 3.516919E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.238837E-07 Bayes score, PP * exp(-Misfit) = 1.238402E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 3201.47 631.329 0.496362 0.306367 0.693633 Final coordinates: 12311.0 1052.50 0.210493 0.972717 2.728317E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.516483E-4 Extraneous predicted phases: 4.357165E-8 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 97.599 0.013440 0.139740 0.007735 0.217480 0.117919 0.503687 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.1 0.2 -0.3 0.3 -0.4 0.2 Chi 1.3E-07 7.4E-07 2.2E-05 4.5E-07 2.1E-06 1.1E-07 Composition Misfit: 2.585791E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 2.401 0.000000 0.054033 0.122990 0.162319 0.239536 0.421121 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 2. -3. 4. 0.7 Chi 0. 6.6E-05 2.9E-05 1.5E-04 7.6E-05 1.2E-06 Composition Misfit: 3.257904E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013031 0.136793 0.010461 0.214777 0.120101 0.006320 0.498517 Augite(G) 0.013355 0.138864 0.007687 0.216118 0.117180 0.006263 0.500532 Gt(W) 0.000000 0.053568 0.121930 0.160920 0.237472 0.008617 0.417493 ----- ----- ----- ----- ----- ----- ----- Potentials -785904. -644691. -1660746. -747419. -325017. -440796. -892116. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 89 converged, 85 successes so far. Misfit function evaluations this try => 131 Misfit this try = 8.799205E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 7.311160E-09 Bayes score, PP * exp(-Misfit) = 7.304729E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18273.0 1133.38 0.680875 0.737388 0.262612 Final coordinates: 19367.6 1174.70 0.152091 0.429852 0.570148 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 8.773486E-4 Extraneous predicted phases: 2.571909E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 41.934 0.013873 0.138279 0.006074 0.213900 0.120782 0.507093 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.7 1. 1. 4. -3. -3. Chi 1.1E-05 2.3E-05 2.6E-04 7.1E-05 9.4E-05 2.0E-05 Composition Misfit: 4.740881E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 58.064 0.000000 0.055260 0.123330 0.161381 0.238780 0.421249 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 1. -3. 4. 0.6 Chi 0. 1.7E-04 1.9E-05 1.0E-04 1.1E-04 8.0E-07 Composition Misfit: 4.032604E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005754 0.089296 0.073813 0.182007 0.188128 0.007153 0.453849 Augite(G) 0.013799 0.137544 0.006042 0.212764 0.120140 0.005311 0.504400 Gt(W) 0.000000 0.054792 0.122285 0.160014 0.236757 0.008471 0.417680 ----- ----- ----- ----- ----- ----- ----- Potentials -802976. -650857. -1672017. -749407. -333629. -446724. -890946. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 90 converged, 86 successes so far. Misfit function evaluations this try => 296 Misfit this try = 1.93662 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 4.179192E-09 Bayes score, PP * exp(-Misfit) = 6.026025E-10 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 5433.76 656.835 0.919687 0.881788 0.118212 Final coordinates: 19949.5 1199.99 0.323686 1.00000 1.289403E-09 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.223080 Extraneous predicted phases: 1.71354 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.311 0.013659 0.141889 0.007408 0.220598 0.118894 0.497551 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 -1. -0.1 -3. -1. 5. Chi 2.3E-06 2.4E-05 1.0E-06 3.6E-05 1.8E-05 8.2E-05 Composition Misfit: 1.626356E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.021 0.000000 0.044201 0.039505 0.238374 0.288106 0.389814 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 8. 6.8E+01 -5.2E+01 -3.6E+01 3.0E+01 Chi 0. 1.4E-03 0.2 2.8E-02 6.8E-03 2.6E-03 Composition Misfit: 0.222917 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 1.668 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013355 0.138743 0.007251 0.215743 0.116311 0.009412 0.499184 Augite(G) 0.013529 0.140538 0.007337 0.218497 0.117762 0.009525 0.492812 Gt(W) 0.000000 0.042289 0.037796 0.228062 0.275642 0.043260 0.372951 ----- ----- ----- ----- ----- ----- ----- Potentials -825923. -653283. -1690933. -749825. -340169. -372946. -892821. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 91 converged, 87 successes so far. Misfit function evaluations this try => 186 Misfit this try = 3.192438E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.123905E-08 Bayes score, PP * exp(-Misfit) = 1.120322E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 4956.98 1169.29 0.612671 0.366393 0.633607 Final coordinates: 17389.7 1195.28 0.207086 0.952174 4.782574E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.192438E-3 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 97.256 0.013203 0.138004 0.009857 0.216288 0.120381 0.502269 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.5 1. -2. 1. -3. 1. Chi 5.9E-06 3.1E-05 6.5E-04 1.0E-05 7.3E-05 5.5E-06 Composition Misfit: 7.781891E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 2.744 0.000000 0.060556 0.121193 0.166262 0.231541 0.420448 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -8. 3. -6. 1.0E+01 1. Chi 0. 1.2E-03 1.1E-04 4.8E-04 6.5E-04 4.5E-06 Composition Misfit: 2.414249E-03 *mole fractions relative to measured components, complete compositions below Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.012755 0.134994 0.012860 0.213536 0.122678 0.006351 0.496825 Augite(G) 0.013120 0.137139 0.009795 0.214933 0.119627 0.006264 0.499122 Gt(W) 0.000000 0.059988 0.120055 0.164701 0.229367 0.009389 0.416500 ----- ----- ----- ----- ----- ----- ----- Potentials -809434. -654326. -1679143. -754188. -339130. -443115. -898030. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 92 converged, 88 successes so far. Misfit function evaluations this try => 211 Misfit this try = 6.662686E-05 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.717902E-07 Bayes score, PP * exp(-Misfit) = 1.717788E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16790.9 1134.57 0.690182 0.895842 0.104158 Final coordinates: 10543.6 1008.69 0.190808 0.836180 0.163820 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.684677E-5 Extraneous predicted phases: 4.978009E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 83.578 0.013509 0.140223 0.007201 0.217674 0.117313 0.504081 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -5.0E-02 -0.1 0.1 0.1 0.1 -0.1 Chi 5.3E-08 1.9E-07 2.0E-06 6.5E-08 9.2E-08 4.7E-08 Composition Misfit: 2.424653E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 16.413 0.000000 0.052244 0.124352 0.158600 0.243172 0.421632 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.1 0.4 -0.8 0.5 0.2 Chi 0. 1.6E-07 2.2E-06 1.0E-05 1.7E-06 9.2E-08 Composition Misfit: 1.442212E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.009 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.011199 0.124837 0.026404 0.206526 0.137219 0.006546 0.487268 Augite(G) 0.013424 0.139346 0.007156 0.216313 0.116579 0.006251 0.500930 Gt(W) 0.000000 0.051824 0.123353 0.157327 0.241220 0.008031 0.418246 ----- ----- ----- ----- ----- ----- ----- Potentials -778899. -642046. -1655965. -745845. -321034. -441624. -891060. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 93 converged, 89 successes so far. Misfit function evaluations this try => 173 Misfit this try = 9.443252E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 2.747122E-08 Bayes score, PP * exp(-Misfit) = 2.744529E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18326.1 647.267 0.941450 5.790519E-02 0.942095 Final coordinates: 17205.7 1122.41 0.129088 1.327953E-03 0.998672 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.430086E-4 Extraneous predicted phases: 1.316634E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.130 0.013874 0.136380 0.005597 0.214203 0.122591 0.507355 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.7 3. 1. 3. -4. -3. Chi 1.1E-05 9.9E-05 5.3E-04 6.0E-05 2.2E-04 2.3E-05 Composition Misfit: 9.430064E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.869 0.000000 0.052158 0.124877 0.157335 0.243802 0.421829 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -6.1E-03 5.2E-04 -5.6E-03 1.2E-02 2.3E-04 Chi 0. 7.9E-10 3.4E-12 5.0E-10 8.5E-10 1.4E-13 Composition Misfit: 2.134461E-09 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.186649 0.000000 0.000000 0.480018 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000018 0.051860 0.123748 0.156178 0.241747 0.007802 0.418646 Augite(G) 0.013801 0.135657 0.005567 0.213068 0.121941 0.005301 0.504666 Gt(W) 0.000000 0.051750 0.123902 0.156107 0.241899 0.007805 0.418536 ----- ----- ----- ----- ----- ----- ----- Potentials -737731. -633628. -1665874. -733281. -314485. -504765. -903405. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 94 converged, 90 successes so far. Misfit function evaluations this try => 150 Misfit this try = 1.017346E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.724758E-08 Bayes score, PP * exp(-Misfit) = 1.723004E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 3580.12 1012.68 0.428359 7.759603E-02 0.922404 Final coordinates: 17688.0 1152.45 0.133019 8.966724E-02 0.910333 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.015333E-3 Extraneous predicted phases: 2.012674E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 8.788 0.013850 0.134225 0.006244 0.213839 0.124979 0.506862 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.7 4. 0.9 4. -6. -2. Chi 9.8E-06 2.5E-04 1.9E-04 7.3E-05 4.6E-04 1.7E-05 Composition Misfit: 9.968607E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 91.210 0.000000 0.052940 0.124675 0.157865 0.242767 0.421753 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.8 0.2 -0.3 0.9 0.1 Chi 0. 1.2E-05 3.3E-07 1.8E-06 4.5E-06 1.4E-08 Composition Misfit: 1.847272E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.001200 0.059573 0.113459 0.161499 0.230699 0.007672 0.425898 Augite(G) 0.013776 0.133505 0.006210 0.212692 0.124309 0.005367 0.504142 Gt(W) 0.000000 0.052522 0.123691 0.156619 0.240851 0.007892 0.418425 ----- ----- ----- ----- ----- ----- ----- Potentials -799107. -650343. -1670962. -749518. -331993. -451085. -891972. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 95 converged, 91 successes so far. Misfit function evaluations this try => 156 Misfit this try = 5.204472E-06 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.748786E-07 Bayes score, PP * exp(-Misfit) = 1.748777E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13179.5 636.794 7.877321E-02 0.347193 0.652807 Final coordinates: 10225.9 1004.59 0.194598 0.867673 0.132327 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.209861E-6 Extraneous predicted phases: 1.994610E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 86.847 0.013486 0.140078 0.007313 0.217727 0.117440 0.503956 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -8.2E-03 -1.2E-02 6.1E-03 0.1 -2.0E-02 -2.3E-02 Chi 1.4E-09 2.0E-09 7.8E-09 2.0E-08 4.7E-09 1.6E-09 Composition Misfit: 3.718973E-08 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 13.151 0.000000 0.052235 0.124688 0.157901 0.243418 0.421758 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.1 0.2 -0.4 0.3 0.1 Chi 0. 1.3E-07 2.9E-07 2.1E-06 6.5E-07 1.2E-08 Composition Misfit: 3.172672E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.011622 0.127596 0.022728 0.208431 0.133273 0.006484 0.489867 Augite(G) 0.013402 0.139200 0.007267 0.216362 0.116704 0.006269 0.500797 Gt(W) 0.000000 0.051823 0.123705 0.156655 0.241499 0.007886 0.418432 ----- ----- ----- ----- ----- ----- ----- Potentials -778222. -641933. -1655787. -745909. -320815. -442260. -891317. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 96 converged, 92 successes so far. Misfit function evaluations this try => 292 Misfit this try = 10.2549 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 4.095029E-09 Bayes score, PP * exp(-Misfit) = 1.440814E-13 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2386.08 876.060 0.879497 0.937683 6.231749E-02 Final coordinates: 1000.05 1199.93 0.399834 0.999722 2.777303E-04 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.50148 Extraneous predicted phases: 7.75342 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 95.920 0.013946 0.144892 0.007600 0.225308 0.112376 0.495878 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.9 -3. -0.2 -7. 4. 6. Chi 1.5E-05 1.6E-04 1.0E-05 2.5E-04 2.3E-04 1.3E-04 Composition Misfit: 7.942734E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.009 0.000000 0.018991 0.006018 0.325798 0.271937 0.377257 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 3.2E+01 9.5E+01 -1.1E+02 -2.3E+01 4.2E+01 Chi 0. 0.1 2. 0.1 2.9E-03 5.3E-03 Composition Misfit: 2.50069 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 Sp(WPC) 0.774 0.000000 0.000704 0.000704 0.000000 0.855935 0.142656 0.000000 q 3.297 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013322 0.138412 0.007268 0.215249 0.116089 0.011604 0.498057 Augite(G) 0.013800 0.143369 0.007520 0.222941 0.111195 0.010509 0.490666 Gt(W) 0.000000 0.017918 0.005678 0.307395 0.256576 0.056485 0.355947 ----- ----- ----- ----- ----- ----- ----- Potentials -840871. -674751. -1768476. -767931. -366644. -376656. -936857. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 97 converged, 93 successes so far. Misfit function evaluations this try => 163 Misfit this try = 2.808464E-06 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.775973E-07 Bayes score, PP * exp(-Misfit) = 1.775968E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15596.3 1151.36 0.248407 0.917266 8.273436E-02 Final coordinates: 10091.1 1000.76 0.178763 0.738216 0.261784 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.097129E-6 Extraneous predicted phases: 1.711335E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 73.948 0.013492 0.140156 0.007259 0.217766 0.117338 0.503990 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -1.9E-02 -0.1 4.9E-02 2.5E-02 0.1 -4.9E-02 Chi 7.8E-09 6.4E-08 5.1E-07 3.4E-09 5.3E-08 7.7E-09 Composition Misfit: 6.478268E-07 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 26.050 0.000000 0.052076 0.124803 0.157540 0.243779 0.421801 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 0.1 0.1 -0.1 3.0E-02 2.6E-02 Chi 0. 1.1E-07 4.4E-08 2.9E-07 5.6E-09 1.8E-09 Composition Misfit: 4.493023E-07 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.009886 0.116266 0.037840 0.200614 0.149500 0.006681 0.479212 Augite(G) 0.013407 0.139277 0.007214 0.216400 0.116602 0.006270 0.500830 Gt(W) 0.000000 0.051668 0.123825 0.156305 0.241869 0.007837 0.418496 ----- ----- ----- ----- ----- ----- ----- Potentials -777615. -641683. -1655336. -745751. -320464. -442177. -891188. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 98 converged, 94 successes so far. Misfit function evaluations this try => 163 Misfit this try = 9.733060E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 5.030606E-09 Bayes score, PP * exp(-Misfit) = 5.025712E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18884.0 644.692 0.317795 8.201736E-02 0.917983 Final coordinates: 19998.4 1184.13 0.143898 0.301767 0.698233 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.733060E-4 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 29.372 0.013914 0.136827 0.005917 0.213396 0.122500 0.507446 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.8 2. 1. 4. -4. -3. Chi 1.3E-05 7.6E-05 3.3E-04 9.1E-05 2.1E-04 2.4E-05 Composition Misfit: 7.485622E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 70.628 0.000000 0.054652 0.123900 0.159944 0.240041 0.421462 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 0.8 -2. 3. 0.3 Chi 0. 1.1E-04 7.7E-06 4.3E-05 5.9E-05 3.2E-07 Composition Misfit: 2.247438E-04 *mole fractions relative to measured components, complete compositions below Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.004038 0.078102 0.088746 0.174284 0.204162 0.007345 0.443323 Augite(G) 0.013842 0.136115 0.005886 0.212285 0.121862 0.005206 0.504804 Gt(W) 0.000000 0.054203 0.122881 0.158629 0.238067 0.008226 0.417996 ----- ----- ----- ----- ----- ----- ----- Potentials -803850. -651369. -1672905. -749470. -334087. -448839. -890706. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 99 converged, 95 successes so far. Misfit function evaluations this try => 92 Misfit this try = 5.210269E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 7.520520E-08 Bayes score, PP * exp(-Misfit) = 7.516603E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9180.92 1126.15 0.254419 0.713736 0.286264 Final coordinates: 14071.8 1090.44 0.184919 0.793034 0.206966 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.206122E-4 Extraneous predicted phases: 4.146240E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 79.204 0.013524 0.139547 0.007509 0.216567 0.118463 0.504392 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.1 0.4 -0.2 1. -0.9 -0.4 Chi 1.3E-07 1.9E-06 4.7E-06 6.9E-06 9.2E-06 4.3E-07 Composition Misfit: 2.337917E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 20.796 0.000000 0.055124 0.122787 0.162671 0.238373 0.421045 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 2. -3. 4. 0.7 Chi 0. 1.6E-04 3.6E-05 1.8E-04 1.2E-04 1.5E-06 Composition Misfit: 4.972331E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.204668 0.000000 0.000000 0.461999 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.010621 0.121063 0.031442 0.203925 0.142630 0.006594 0.483725 Augite(G) 0.013442 0.138705 0.007463 0.215260 0.117748 0.006033 0.501348 Gt(W) 0.000000 0.054644 0.121718 0.161255 0.236298 0.008704 0.417380 ----- ----- ----- ----- ----- ----- ----- Potentials -739178. -633732. -1664788. -735438. -315014. -494563. -905743. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 100 converged, 96 successes so far. Misfit function evaluations this try => 129 Misfit this try = 6.489900E-05 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.384791E-07 Bayes score, PP * exp(-Misfit) = 1.384701E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 3470.73 742.805 0.114589 9.967903E-02 0.900321 Final coordinates: 11954.4 1039.31 0.155778 0.482607 0.517393 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.478427E-5 Extraneous predicted phases: 1.147280E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 48.110 0.013587 0.139773 0.006971 0.216848 0.118049 0.504772 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.2 0.2 0.3 0.9 -0.5 -0.7 Chi 8.1E-07 5.9E-07 1.7E-05 4.1E-06 3.4E-06 1.4E-06 Composition Misfit: 2.778043E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 51.890 0.000000 0.053044 0.124360 0.158627 0.242334 0.421635 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.9 0.4 -0.8 1. 0.2 Chi 0. 1.5E-05 2.2E-06 1.1E-05 9.1E-06 8.9E-08 Composition Misfit: 3.700385E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.006460 0.093909 0.067662 0.185189 0.181522 0.007069 0.458188 Augite(G) 0.013505 0.138931 0.006929 0.215542 0.117337 0.006024 0.501731 Gt(W) 0.000000 0.052618 0.123361 0.157353 0.240389 0.008028 0.418250 ----- ----- ----- ----- ----- ----- ----- Potentials -783317. -643769. -1659099. -746716. -323458. -443221. -891381. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 101 converged, 97 successes so far. Misfit function evaluations this try => 129 Misfit this try = 1.799997E-05 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.624831E-07 Bayes score, PP * exp(-Misfit) = 1.624802E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12525.8 790.261 0.103304 0.474820 0.525180 Final coordinates: 10893.3 1019.03 0.157376 0.503486 0.496514 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.714786E-5 Extraneous predicted phases: 8.521129E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 50.420 0.013525 0.139825 0.007192 0.217328 0.117861 0.504269 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.1 0.2 0.1 0.4 -0.4 -0.3 Chi 1.4E-07 4.0E-07 2.3E-06 9.9E-07 1.7E-06 2.3E-07 Composition Misfit: 5.717481E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 49.578 0.000000 0.052672 0.124632 0.157992 0.242967 0.421737 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.5 0.2 -0.4 0.7 0.1 Chi 0. 5.2E-06 4.8E-07 2.8E-06 3.0E-06 2.0E-08 Composition Misfit: 1.143038E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.006740 0.095734 0.065227 0.186448 0.178908 0.007039 0.459904 Augite(G) 0.013441 0.138962 0.007148 0.215986 0.117134 0.006173 0.501156 Gt(W) 0.000000 0.052256 0.123646 0.156742 0.241045 0.007911 0.418401 ----- ----- ----- ----- ----- ----- ----- Potentials -780371. -642732. -1657254. -746313. -321945. -442833. -891451. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 102 converged, 98 successes so far. Misfit function evaluations this try => 189 Misfit this try = 2.695651E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.081099E-07 Bayes score, PP * exp(-Misfit) = 1.080808E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 11445.6 661.873 0.454664 8.966644E-02 0.910334 Final coordinates: 13170.4 1059.83 0.129129 2.252027E-03 0.997748 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.685610E-4 Extraneous predicted phases: 1.004086E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.224 0.013692 0.137854 0.006402 0.215880 0.120418 0.505754 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.4 2. 0.7 2. -3. -1. Chi 3.2E-06 3.5E-05 1.3E-04 1.7E-05 7.5E-05 6.6E-06 Composition Misfit: 2.685590E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.775 0.000000 0.052158 0.124877 0.157334 0.243803 0.421829 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -6.2E-03 5.5E-04 -5.1E-03 1.1E-02 2.4E-04 Chi 0. 8.0E-10 3.7E-12 4.1E-10 7.5E-10 1.5E-13 Composition Misfit: 1.968007E-09 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.190793 0.000000 0.000000 0.475873 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000030 0.051941 0.123641 0.156234 0.241632 0.007800 0.418722 Augite(G) 0.013613 0.137060 0.006365 0.214637 0.119725 0.005758 0.502841 Gt(W) 0.000000 0.051751 0.123902 0.156106 0.241900 0.007805 0.418536 ----- ----- ----- ----- ----- ----- ----- Potentials -738054. -632925. -1660998. -735003. -312706. -493692. -902950. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 103 converged, 99 successes so far. Misfit function evaluations this try => 97 Misfit this try = 4.653761E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 3.786720E-08 Bayes score, PP * exp(-Misfit) = 3.784959E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16064.8 1100.08 0.189007 0.233136 0.766864 Final coordinates: 16055.2 1121.56 0.141792 0.264194 0.735806 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 4.648010E-4 Extraneous predicted phases: 5.751027E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 26.014 0.013771 0.137179 0.006462 0.214775 0.121523 0.506290 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.5 2. 0.7 3. -3. -2. Chi 6.1E-06 6.1E-05 1.1E-04 4.2E-05 1.4E-04 1.1E-05 Composition Misfit: 3.729027E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 73.985 0.000000 0.053815 0.124299 0.158833 0.241441 0.421612 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 0.5 -1. 2. 0.2 Chi 0. 5.1E-05 2.7E-06 1.4E-05 2.3E-05 1.1E-07 Composition Misfit: 9.189823E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.003535 0.074818 0.093125 0.172018 0.208864 0.007404 0.440235 Augite(G) 0.013694 0.136419 0.006426 0.213586 0.120851 0.005537 0.503487 Gt(W) 0.000000 0.053381 0.123298 0.157554 0.239496 0.008054 0.418217 ----- ----- ----- ----- ----- ----- ----- Potentials -795073. -648422. -1667592. -748833. -329794. -447453. -891874. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 104 converged, 100 successes so far. Misfit function evaluations this try => 360 Misfit this try = 2.422862E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 3.948709E-08 Bayes score, PP * exp(-Misfit) = 3.939153E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 3294.32 760.965 0.722067 0.608805 0.391195 Final coordinates: 16280.8 1111.32 0.215637 0.999930 7.001613E-05 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.395733E-3 Extraneous predicted phases: 2.712821E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.955 0.013487 0.140096 0.007286 0.217817 0.117386 0.503929 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -9.2E-03 -2.5E-02 2.8E-02 -2.2E-02 2.6E-02 -1.5E-03 Chi 1.8E-09 8.4E-09 1.6E-07 2.6E-09 8.0E-09 7.5E-12 Composition Misfit: 1.840686E-07 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.038 0.000000 0.053919 0.118385 0.173937 0.234366 0.419394 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 5. -1.1E+01 8. 2. Chi 0. 5.8E-05 3.6E-04 1.6E-03 3.8E-04 1.4E-05 Composition Misfit: 2.395549E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.007 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013396 0.139174 0.007282 0.216418 0.116687 0.006290 0.500752 Augite(G) 0.013402 0.139215 0.007240 0.216447 0.116648 0.006289 0.500760 Gt(W) 0.000000 0.053348 0.117131 0.172094 0.231883 0.010593 0.414951 ----- ----- ----- ----- ----- ----- ----- Potentials -795553. -647217. -1664859. -747251. -329102. -433204. -890113. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 105 converged, 101 successes so far. Misfit function evaluations this try => 132 Misfit this try = 9.564154E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 6.299198E-09 Bayes score, PP * exp(-Misfit) = 6.293176E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17695.0 1155.51 0.942820 0.196176 0.803824 Final coordinates: 19183.9 1192.19 0.152194 0.432097 0.567903 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.559612E-4 Extraneous predicted phases: 4.541226E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 42.496 0.013767 0.136625 0.006793 0.213827 0.122600 0.506388 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.5 2. 0.4 4. -4. -2. Chi 5.9E-06 8.6E-05 4.1E-05 7.4E-05 2.2E-04 1.2E-05 Composition Misfit: 4.379330E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 57.503 0.000000 0.056036 0.123442 0.161175 0.238056 0.421291 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -4. 1. -2. 5. 0.5 Chi 0. 2.7E-04 1.7E-05 9.2E-05 1.4E-04 6.9E-07 Composition Misfit: 5.180282E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005784 0.089493 0.073552 0.182142 0.187847 0.007147 0.454035 Augite(G) 0.013692 0.135887 0.006756 0.212672 0.121938 0.005404 0.503651 Gt(W) 0.000000 0.055564 0.122402 0.159818 0.236051 0.008423 0.417742 ----- ----- ----- ----- ----- ----- ----- Potentials -806392. -652843. -1675898. -751367. -336169. -448853. -893565. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 106 converged, 102 successes so far. Misfit function evaluations this try => 96 Misfit this try = 2.997820E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 6.516740E-08 Bayes score, PP * exp(-Misfit) = 6.514786E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18885.3 940.793 0.148594 0.396011 0.603989 Final coordinates: 14608.7 1096.47 0.147278 0.357241 0.642759 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.993677E-4 Extraneous predicted phases: 4.142925E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 35.378 0.013687 0.137997 0.006770 0.215499 0.120420 0.505627 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.4 1. 0.4 2. -3. -1. Chi 3.1E-06 3.1E-05 4.5E-05 2.4E-05 7.5E-05 5.7E-06 Composition Misfit: 1.837085E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 64.621 0.000000 0.053998 0.124208 0.159072 0.241145 0.421578 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 0.5 -1. 2. 0.2 Chi 0. 6.3E-05 3.6E-06 1.9E-05 3.0E-05 1.5E-07 Composition Misfit: 1.156592E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.004781 0.082950 0.082279 0.177628 0.197218 0.007261 0.447882 Augite(G) 0.013608 0.137207 0.006731 0.214265 0.119731 0.005726 0.502731 Gt(W) 0.000000 0.053561 0.123202 0.157785 0.239193 0.008093 0.418166 ----- ----- ----- ----- ----- ----- ----- Potentials -791705. -647128. -1665245. -748414. -328065. -446033. -892118. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 107 converged, 103 successes so far. Misfit function evaluations this try => 175 Misfit this try = 7.839748E-06 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.719377E-07 Bayes score, PP * exp(-Misfit) = 1.719364E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16250.4 656.576 0.284882 0.507890 0.492110 Final coordinates: 10413.5 1008.49 0.160002 0.536574 0.463426 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 4.670823E-6 Extraneous predicted phases: 3.168925E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 53.784 0.013509 0.140028 0.007234 0.217565 0.117539 0.504125 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -5.0E-02 2.4E-02 0.1 0.2 -0.1 -0.2 Chi 5.3E-08 7.9E-09 1.0E-06 2.4E-07 1.3E-07 7.7E-08 Composition Misfit: 1.529636E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 46.214 0.000000 0.052394 0.124712 0.157734 0.243394 0.421767 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.2 0.1 -0.3 0.3 0.1 Chi 0. 1.1E-06 2.2E-07 1.1E-06 7.3E-07 9.2E-09 Composition Misfit: 3.141187E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.007183 0.098627 0.061367 0.188444 0.174763 0.006991 0.462624 Augite(G) 0.013425 0.139157 0.007189 0.216211 0.116808 0.006221 0.500989 Gt(W) 0.000000 0.051981 0.123729 0.156492 0.241477 0.007876 0.418445 ----- ----- ----- ----- ----- ----- ----- Potentials -778843. -642136. -1656180. -746011. -321103. -442404. -891335. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 108 converged, 104 successes so far. Misfit function evaluations this try => 565 Misfit this try = 4.736553E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.244641E-08 Bayes score, PP * exp(-Misfit) = 1.238760E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17665.9 647.370 0.895024 0.660824 0.339176 Final coordinates: 18676.5 1151.52 0.215392 0.999152 8.482185E-04 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 4.721046E-3 Extraneous predicted phases: 1.550738E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.750 0.013504 0.140210 0.007152 0.217839 0.117245 0.504051 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -4.2E-02 -0.1 0.1 -4.2E-02 0.1 -0.1 Chi 3.7E-08 1.6E-07 3.9E-06 9.6E-09 2.5E-07 3.0E-08 Composition Misfit: 4.433321E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.245 0.000000 0.052279 0.115591 0.181921 0.231863 0.418347 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.1 7. -1.6E+01 10. 3. Chi 0. 3.1E-07 7.5E-04 3.3E-03 6.2E-04 2.9E-05 Composition Misfit: 4.716613E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.005 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013386 0.139106 0.007373 0.216372 0.116785 0.006289 0.500689 Augite(G) 0.013419 0.139330 0.007107 0.216472 0.116509 0.006275 0.500888 Gt(W) 0.000000 0.051663 0.114228 0.179776 0.229130 0.011788 0.413415 ----- ----- ----- ----- ----- ----- ----- Potentials -801827. -649380. -1668437. -747564. -332327. -429998. -889620. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 109 converged, 105 successes so far. Misfit function evaluations this try => 251 Misfit this try = 9.880872E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.214177E-07 Bayes score, PP * exp(-Misfit) = 1.212977E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 7644.21 800.588 0.435420 0.179986 0.820014 Final coordinates: 5265.24 889.709 0.172961 0.683098 0.316902 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.857112E-4 Extraneous predicted phases: 2.375927E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 69.251 0.013340 0.141155 0.007411 0.219905 0.115546 0.502643 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.3 -0.8 -0.1 -2. 2. 1. Chi 1.5E-06 8.5E-06 1.1E-06 2.0E-05 3.0E-05 3.3E-06 Composition Misfit: 6.496029E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 30.747 0.000000 0.047675 0.127402 0.151217 0.250930 0.422776 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 4. -2. 4. -6. -0.9 Chi 0. 4.2E-04 5.0E-05 2.5E-04 2.0E-04 2.1E-06 Composition Misfit: 9.207509E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 Fsp(C1) 0.002 0.081921 0.000000 0.168079 0.086157 0.000000 0.000000 0.663843 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.009147 0.111444 0.044273 0.197287 0.156408 0.006763 0.474678 Augite(G) 0.013249 0.140198 0.007360 0.218413 0.114762 0.006784 0.499233 Gt(W) 0.000000 0.047355 0.126546 0.150202 0.249245 0.006716 0.419936 ----- ----- ----- ----- ----- ----- ----- Potentials -734611. -629122. -1644750. -736001. -304950. -468154. -896604. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 110 converged, 106 successes so far. Misfit function evaluations this try => 224 Misfit this try = 3.722298E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 7.634377E-09 Bayes score, PP * exp(-Misfit) = 7.606012E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18802.1 781.838 5.198769E-02 0.283432 0.716568 Final coordinates: 18875.9 1186.30 0.210832 0.973293 2.670742E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.711997E-3 Extraneous predicted phases: 1.030112E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.006 0.013391 0.139382 0.008265 0.217003 0.118550 0.503410 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.2 0.5 -0.8 0.7 -1. 0.4 Chi 6.2E-07 3.3E-06 1.1E-04 2.9E-06 1.1E-05 5.3E-07 Composition Misfit: 1.261122E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 1.990 0.000000 0.056465 0.117689 0.176233 0.230480 0.419133 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -4. 6. -1.2E+01 1.1E+01 3. Chi 0. 3.3E-04 4.4E-04 2.0E-03 7.7E-04 1.7E-05 Composition Misfit: 3.585885E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.004 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013039 0.136842 0.010394 0.214810 0.120028 0.006326 0.498561 Augite(G) 0.013307 0.138513 0.008213 0.215650 0.117811 0.006233 0.500273 Gt(W) 0.000000 0.055850 0.116407 0.174313 0.227970 0.010891 0.414569 ----- ----- ----- ----- ----- ----- ----- Potentials -807808. -652446. -1674818. -750918. -336701. -435159. -893517. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 111 converged, 107 successes so far. Misfit function evaluations this try => 182 Misfit this try = 4.128281E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 5.878867E-09 Bayes score, PP * exp(-Misfit) = 5.854647E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15025.9 643.609 0.116226 0.664264 0.335736 Final coordinates: 19975.9 1172.29 0.203432 0.928950 7.104970E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 4.128189E-3 Extraneous predicted phases: 9.179206E-8 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 91.694 0.013665 0.141105 0.006467 0.216619 0.116820 0.505324 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 -0.7 0.7 1. 0.5 -1. Chi 2.5E-06 7.7E-06 1.1E-04 6.4E-06 3.0E-06 3.9E-06 Composition Misfit: 1.360020E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 8.306 0.000000 0.053845 0.116672 0.179251 0.231479 0.418752 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 7. -1.4E+01 1.0E+01 3. Chi 0. 5.3E-05 5.8E-04 2.7E-03 6.6E-04 2.3E-05 Composition Misfit: 3.992187E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.012444 0.132961 0.015572 0.212133 0.125590 0.006387 0.494913 Augite(G) 0.013584 0.140267 0.006429 0.215333 0.116127 0.005935 0.502325 Gt(W) 0.000000 0.053236 0.115351 0.177221 0.228857 0.011326 0.414009 ----- ----- ----- ----- ----- ----- ----- Potentials -804651. -650207. -1670180. -747902. -333668. -432086. -889272. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 112 converged, 108 successes so far. Misfit function evaluations this try => 175 Misfit this try = 8.281651E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 3.412769E-08 Bayes score, PP * exp(-Misfit) = 3.409944E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12507.3 918.053 0.606465 0.167691 0.832309 Final coordinates: 16371.6 1123.97 0.177922 0.731149 0.268851 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 8.281377E-4 Extraneous predicted phases: 2.740928E-8 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 72.240 0.013674 0.140142 0.006758 0.215779 0.118132 0.505516 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.4 -0.1 0.5 2. -0.6 -1. Chi 2.7E-06 4.6E-08 4.7E-05 1.9E-05 4.3E-06 5.0E-06 Composition Misfit: 7.763137E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 27.760 0.000000 0.055183 0.121998 0.164756 0.237314 0.420749 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 2. -5. 5. 1. Chi 0. 1.7E-04 6.8E-05 3.4E-04 1.8E-04 2.8E-06 Composition Misfit: 7.505064E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.009791 0.115648 0.038665 0.200188 0.150386 0.006689 0.478632 Augite(G) 0.013595 0.139333 0.006719 0.214533 0.117449 0.005775 0.502596 Gt(W) 0.000000 0.054684 0.120895 0.163266 0.235167 0.009043 0.416944 ----- ----- ----- ----- ----- ----- ----- Potentials -796588. -648244. -1667194. -748555. -330239. -441407. -891450. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Augite(G) q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Augite(G) q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 114 converged, 109 successes so far. Misfit function evaluations this try => 145 Misfit this try = 1.542152E-05 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.641617E-07 Bayes score, PP * exp(-Misfit) = 1.641592E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 11713.2 699.184 0.786912 0.342976 0.657024 Final coordinates: 10830.8 1017.26 0.138273 0.198465 0.801535 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.468144E-5 Extraneous predicted phases: 7.400866E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 19.911 0.013539 0.139531 0.007133 0.217300 0.118139 0.504359 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.1 0.4 0.2 0.5 -0.6 -0.3 Chi 2.4E-07 2.0E-06 4.9E-06 1.1E-06 4.4E-06 3.7E-07 Composition Misfit: 1.308491E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 80.088 0.000000 0.052374 0.124803 0.157512 0.243510 0.421801 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.2 0.1 -0.1 0.3 2.6E-02 Chi 0. 9.5E-07 4.4E-08 2.2E-07 3.9E-07 1.8E-09 Composition Misfit: 1.596525E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.002656 0.069076 0.100784 0.168056 0.217089 0.007504 0.434835 Augite(G) 0.013455 0.138672 0.007089 0.215963 0.117412 0.006153 0.501256 Gt(W) 0.000000 0.051963 0.123825 0.156278 0.241602 0.007837 0.418496 ----- ----- ----- ----- ----- ----- ----- Potentials -780005. -642637. -1657074. -746235. -321750. -443241. -891390. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 115 converged, 110 successes so far. Misfit function evaluations this try => 131 Misfit this try = 1.015576E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.233439E-07 Bayes score, PP * exp(-Misfit) = 1.233313E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12549.6 1021.29 0.848437 0.406930 0.593070 Final coordinates: 12351.7 1052.66 0.151568 0.422895 0.577105 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.009944E-4 Extraneous predicted phases: 5.632105E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 42.238 0.013569 0.138903 0.007144 0.216575 0.119146 0.504664 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.2 0.8 0.1 1. -1. -0.6 Chi 5.6E-07 9.7E-06 4.4E-06 6.8E-06 2.5E-05 1.1E-06 Composition Misfit: 4.759486E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 57.761 0.000000 0.053403 0.124457 0.158493 0.241975 0.421672 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 0.3 -0.7 2. 0.1 Chi 0. 2.9E-05 1.4E-06 8.6E-06 1.4E-05 5.9E-08 Composition Misfit: 5.339954E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005661 0.088688 0.074625 0.181587 0.188999 0.007162 0.453278 Augite(G) 0.013487 0.138066 0.007101 0.215271 0.118428 0.006022 0.501624 Gt(W) 0.000000 0.052976 0.123464 0.157228 0.240043 0.007986 0.418304 ----- ----- ----- ----- ----- ----- ----- Potentials -785398. -644723. -1660887. -747406. -324754. -444133. -892042. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 116 converged, 111 successes so far. Misfit function evaluations this try => 575 Misfit this try = 1.94898 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 4.294219E-09 Bayes score, PP * exp(-Misfit) = 6.115810E-10 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2739.55 1159.48 0.864193 0.440926 0.559074 Final coordinates: 19889.6 1199.84 0.323957 1.00000 5.540144E-08 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.226893 Extraneous predicted phases: 1.72208 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.318 0.013657 0.141882 0.007412 0.220608 0.118918 0.497523 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 -1. -0.1 -3. -1. 5. Chi 2.3E-06 2.3E-05 1.1E-06 3.6E-05 1.9E-05 8.2E-05 Composition Misfit: 1.640996E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.009 0.000000 0.044005 0.039121 0.238401 0.288803 0.389670 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 8. 6.9E+01 -5.2E+01 -3.7E+01 3.0E+01 Chi 0. 1.5E-03 0.2 2.8E-02 7.0E-03 2.7E-03 Composition Misfit: 0.226729 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 1.672 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013355 0.138742 0.007251 0.215741 0.116310 0.009420 0.499180 Augite(G) 0.013527 0.140529 0.007341 0.218504 0.117784 0.009537 0.492778 Gt(W) 0.000000 0.042095 0.037422 0.228051 0.276264 0.043414 0.372753 ----- ----- ----- ----- ----- ----- ----- Potentials -825997. -653316. -1691197. -749871. -340276. -372527. -892937. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 117 converged, 112 successes so far. Misfit function evaluations this try => 114 Misfit this try = 6.102954E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 3.549803E-08 Bayes score, PP * exp(-Misfit) = 3.547637E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16139.7 964.025 0.495496 0.155406 0.844594 Final coordinates: 16316.6 1121.43 0.135974 0.151164 0.848836 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.044202E-4 Extraneous predicted phases: 5.875238E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 14.829 0.013831 0.136557 0.006175 0.214479 0.122302 0.506655 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.6 3. 0.9 3. -4. -2. Chi 8.8E-06 9.0E-05 2.1E-04 5.1E-05 2.0E-04 1.5E-05 Composition Misfit: 5.720303E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 85.167 0.000000 0.053152 0.124553 0.158174 0.242414 0.421707 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 0.3 -0.5 1. 0.1 Chi 0. 1.9E-05 8.5E-07 4.5E-06 8.1E-06 3.5E-08 Composition Misfit: 3.238986E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.004 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.002023 0.064944 0.106295 0.165205 0.223006 0.007581 0.430948 Augite(G) 0.013755 0.135810 0.006142 0.213306 0.121633 0.005472 0.503883 Gt(W) 0.000000 0.052730 0.123563 0.156918 0.240488 0.007944 0.418357 ----- ----- ----- ----- ----- ----- ----- Potentials -794651. -648275. -1667190. -748437. -329421. -448215. -891265. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 118 converged, 113 successes so far. Misfit function evaluations this try => 405 Misfit this try = 2.26121 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 7.943729E-09 Bayes score, PP * exp(-Misfit) = 8.279314E-10 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2636.83 951.684 0.789398 0.933720 6.628021E-02 Final coordinates: 18332.3 1198.27 0.330568 0.999934 6.640348E-05 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.323157 Extraneous predicted phases: 1.93805 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.216 0.013667 0.141983 0.007428 0.220778 0.119029 0.497115 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 -1. -0.1 -3. -1. 5. Chi 2.5E-06 2.6E-05 1.6E-06 4.0E-05 2.2E-05 9.3E-05 Composition Misfit: 1.856577E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.004 0.000000 0.043455 0.031347 0.242034 0.296409 0.386755 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 8. 7.5E+01 -5.4E+01 -4.3E+01 3.3E+01 Chi 0. 1.7E-03 0.3 3.0E-02 9.3E-03 3.2E-03 Composition Misfit: 0.322971 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 1.780 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013351 0.138709 0.007258 0.215696 0.116296 0.009611 0.499079 Augite(G) 0.013534 0.140601 0.007355 0.218628 0.117870 0.009740 0.492273 Gt(W) 0.000000 0.041434 0.029889 0.230776 0.282621 0.046516 0.368765 ----- ----- ----- ----- ----- ----- ----- Potentials -828617. -654567. -1697679. -751693. -341849. -370763. -896266. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 119 converged, 114 successes so far. Misfit function evaluations this try => 126 Misfit this try = 6.404073E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 6.357014E-08 Bayes score, PP * exp(-Misfit) = 6.352945E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13886.4 913.387 0.679573 0.846675 0.153325 Final coordinates: 14629.0 1098.87 0.185629 0.797929 0.202071 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.380425E-4 Extraneous predicted phases: 2.364725E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 79.529 0.013550 0.139712 0.007372 0.216457 0.118333 0.504576 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.1 0.2 -4.1E-02 1. -0.8 -0.5 Chi 3.5E-07 8.8E-07 3.6E-07 8.2E-06 7.1E-06 8.3E-07 Composition Misfit: 1.775958E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 20.469 0.000000 0.055224 0.122386 0.163668 0.237827 0.420895 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 2. -4. 5. 0.9 Chi 0. 1.7E-04 5.1E-05 2.5E-04 1.5E-04 2.1E-06 Composition Misfit: 6.202830E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.010687 0.121491 0.030870 0.204219 0.142016 0.006591 0.484126 Augite(G) 0.013469 0.138874 0.007327 0.215159 0.117624 0.005996 0.501551 Gt(W) 0.000000 0.054734 0.121300 0.162215 0.235716 0.008877 0.417159 ----- ----- ----- ----- ----- ----- ----- Potentials -793023. -647214. -1665415. -748589. -328706. -441482. -892362. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 120 converged, 115 successes so far. Misfit function evaluations this try => 129 Misfit this try = 1.564620E-05 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.657122E-07 Bayes score, PP * exp(-Misfit) = 1.657096E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 4971.22 802.161 4.885566E-02 0.114401 0.885599 Final coordinates: 10769.9 1015.60 0.137061 0.173885 0.826115 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.292163E-5 Extraneous predicted phases: 2.724572E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 17.444 0.013542 0.139625 0.007121 0.217320 0.118040 0.504352 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.1 0.3 0.2 0.4 -0.5 -0.3 Chi 2.7E-07 1.4E-06 5.6E-06 1.0E-06 3.3E-06 3.6E-07 Composition Misfit: 1.189796E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 82.554 0.000000 0.052326 0.124812 0.157485 0.243573 0.421804 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.2 0.1 -0.1 0.2 2.3E-02 Chi 0. 5.8E-07 3.4E-08 1.6E-07 2.4E-07 1.4E-09 Composition Misfit: 1.023674E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.002327 0.066929 0.103648 0.166574 0.220164 0.007544 0.432815 Augite(G) 0.013459 0.138765 0.007077 0.215981 0.117313 0.006162 0.501244 Gt(W) 0.000000 0.051916 0.123834 0.156252 0.241665 0.007833 0.418500 ----- ----- ----- ----- ----- ----- ----- Potentials -779728. -642529. -1656879. -746171. -321601. -443109. -891338. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 121 converged, 116 successes so far. Misfit function evaluations this try => 112 Misfit this try = 1.674680E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.170736E-07 Bayes score, PP * exp(-Misfit) = 1.170540E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2611.78 1123.55 0.369321 0.291669 0.708331 Final coordinates: 12568.7 1057.49 0.169125 0.641507 0.358493 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.582964E-4 Extraneous predicted phases: 9.171645E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 64.045 0.013548 0.139457 0.007292 0.216748 0.118448 0.504507 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.1 0.4 2.2E-02 1. -0.9 -0.5 Chi 3.2E-07 2.6E-06 1.1E-07 5.0E-06 9.0E-06 6.7E-07 Composition Misfit: 1.773556E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 35.951 0.000000 0.053986 0.123916 0.159710 0.240919 0.421469 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 0.8 -2. 2. 0.3 Chi 0. 6.2E-05 7.5E-06 3.6E-05 3.5E-05 3.1E-07 Composition Misfit: 1.405608E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.004 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.008590 0.107804 0.049126 0.194776 0.161618 0.006833 0.471253 Augite(G) 0.013466 0.138613 0.007248 0.215437 0.117731 0.006047 0.501456 Gt(W) 0.000000 0.053543 0.122898 0.158397 0.238939 0.008219 0.418005 ----- ----- ----- ----- ----- ----- ----- Potentials -786319. -644964. -1661334. -747563. -325237. -443173. -892117. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 122 converged, 117 successes so far. Misfit function evaluations this try => 743 Misfit this try = 2.40788 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 4.655078E-09 Bayes score, PP * exp(-Misfit) = 4.189849E-10 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2361.07 759.464 0.939003 0.295384 0.704616 Final coordinates: 19721.8 1198.97 0.335277 0.983383 1.661659E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.137772 Extraneous predicted phases: 2.27011 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.029 0.013462 0.140714 0.009391 0.220021 0.121216 0.495195 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 3.6E-02 -0.5 -2. -2. -3. 7. Chi 2.8E-08 3.0E-06 4.6E-04 2.3E-05 1.2E-04 1.5E-04 Composition Misfit: 7.553457E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.049 0.000000 0.051684 0.050194 0.221220 0.283079 0.393823 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 0.4 6.0E+01 -4.1E+01 -3.2E+01 2.7E+01 Chi 0. 4.2E-06 0.1 1.8E-02 5.4E-03 2.0E-03 Composition Misfit: 0.137017 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 1.922 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013126 0.137226 0.009182 0.214638 0.118331 0.009918 0.497579 Augite(G) 0.013327 0.139300 0.009297 0.217810 0.119998 0.010050 0.490218 Gt(W) 0.000000 0.049670 0.048238 0.212602 0.272050 0.038961 0.378479 ----- ----- ----- ----- ----- ----- ----- Potentials -823943. -652474. -1686847. -751062. -339651. -377181. -893206. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 123 converged, 118 successes so far. Misfit function evaluations this try => 115 Misfit this try = 1.019936E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.348084E-07 Bayes score, PP * exp(-Misfit) = 1.347947E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8482.19 1165.08 9.184474E-02 0.114500 0.885500 Final coordinates: 12103.7 1041.99 0.132708 8.415315E-02 0.915847 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.019751E-4 Extraneous predicted phases: 1.851774E-8 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 8.391 0.013629 0.138667 0.006775 0.216504 0.119331 0.505093 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 1. 0.4 1. -2. -0.9 Chi 1.6E-06 1.4E-05 4.4E-05 7.7E-06 3.1E-05 2.7E-06 Composition Misfit: 1.004956E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 91.608 0.000000 0.052365 0.124810 0.157503 0.243517 0.421804 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.2 0.1 -0.1 0.2 2.4E-02 Chi 0. 8.7E-07 3.6E-08 2.0E-07 3.7E-07 1.5E-09 Composition Misfit: 1.479421E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.001126 0.059092 0.114102 0.161168 0.231389 0.007677 0.425447 Augite(G) 0.013548 0.137843 0.006735 0.215217 0.118621 0.005946 0.502090 Gt(W) 0.000000 0.051955 0.123833 0.156270 0.241610 0.007834 0.418500 ----- ----- ----- ----- ----- ----- ----- Potentials -783416. -643979. -1659463. -746752. -323522. -444712. -891354. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 124 converged, 119 successes so far. Misfit function evaluations this try => 121 Misfit this try = 1.258055E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 5.409807E-08 Bayes score, PP * exp(-Misfit) = 5.403006E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14139.1 911.064 0.787317 0.948463 5.153725E-02 Final coordinates: 14764.2 1113.73 0.206561 0.947670 5.233046E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.251180E-3 Extraneous predicted phases: 6.875002E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 95.513 0.013382 0.139204 0.008347 0.216967 0.118736 0.503363 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.2 0.6 -0.8 0.8 -1. 0.4 Chi 7.4E-07 5.3E-06 1.3E-04 3.1E-06 1.5E-05 6.3E-07 Composition Misfit: 1.508762E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 4.484 0.000000 0.056551 0.121611 0.165414 0.235819 0.420604 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -4. 3. -5. 7. 1. Chi 0. 3.4E-04 8.8E-05 4.0E-04 2.7E-04 3.6E-06 Composition Misfit: 1.100304E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.003 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.012695 0.134599 0.013386 0.213263 0.123242 0.006364 0.496451 Augite(G) 0.013299 0.138337 0.008295 0.215615 0.117997 0.006229 0.500228 Gt(W) 0.000000 0.056031 0.120491 0.163891 0.233647 0.009209 0.416731 ----- ----- ----- ----- ----- ----- ----- Potentials -795879. -648506. -1667893. -749815. -330695. -440572. -893858. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 125 converged, 120 successes so far. Misfit function evaluations this try => 165 Misfit this try = 4.693186E-05 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.538146E-07 Bayes score, PP * exp(-Misfit) = 1.538074E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 7147.92 781.192 0.830197 0.504360 0.495640 Final coordinates: 11269.5 1027.28 0.178640 0.737279 0.262721 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 4.594351E-5 Extraneous predicted phases: 9.883545E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 73.737 0.013513 0.139962 0.007286 0.217349 0.117691 0.504198 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.1 0.1 2.7E-02 0.4 -0.2 -0.2 Chi 7.2E-08 7.0E-08 1.6E-07 9.1E-07 6.4E-07 1.5E-07 Composition Misfit: 1.994654E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 26.261 0.000000 0.052995 0.124220 0.158956 0.242247 0.421582 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.8 0.5 -1. 1. 0.2 Chi 0. 1.3E-05 3.5E-06 1.7E-05 1.0E-05 1.4E-07 Composition Misfit: 4.394886E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.009873 0.116184 0.037950 0.200558 0.149618 0.006682 0.479135 Augite(G) 0.013430 0.139098 0.007241 0.216007 0.116965 0.006176 0.501085 Gt(W) 0.000000 0.052567 0.123215 0.157670 0.240287 0.008088 0.418173 ----- ----- ----- ----- ----- ----- ----- Potentials -781733. -643177. -1658054. -746550. -322664. -442347. -891545. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 126 converged, 121 successes so far. Misfit function evaluations this try => 108 Misfit this try = 1.350860E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.342143E-08 Bayes score, PP * exp(-Misfit) = 1.340331E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18949.3 1104.10 0.331256 7.689500E-02 0.923105 Final coordinates: 19263.7 1123.50 0.132165 7.065757E-02 0.929342 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.348530E-3 Extraneous predicted phases: 2.330450E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 6.804 0.014071 0.139787 0.004899 0.214036 0.118833 0.508375 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -1. 0.2 2. 3. -1. -4. Chi 2.5E-05 5.4E-07 1.2E-03 6.6E-05 1.7E-05 3.9E-05 Composition Misfit: 1.344090E-03 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 93.194 0.000000 0.052451 0.124683 0.157794 0.243317 0.421756 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.3 0.2 -0.3 0.4 0.1 Chi 0. 1.7E-06 3.0E-07 1.4E-06 1.0E-06 1.3E-08 Composition Misfit: 4.439381E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000945 0.057913 0.115673 0.160354 0.233076 0.007701 0.424337 Augite(G) 0.013999 0.139072 0.004873 0.212941 0.118225 0.005114 0.505775 Gt(W) 0.000000 0.052037 0.123699 0.156549 0.241397 0.007889 0.418429 ----- ----- ----- ----- ----- ----- ----- Potentials -792183. -645840. -1662120. -744671. -326681. -445399. -884852. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 127 converged, 122 successes so far. Misfit function evaluations this try => 143 Misfit this try = 8.914180E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 7.402001E-09 Bayes score, PP * exp(-Misfit) = 7.395405E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 19024.3 852.820 0.816740 0.209513 0.790487 Final coordinates: 19282.3 1176.42 0.143439 0.293091 0.706909 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 8.905671E-4 Extraneous predicted phases: 8.509440E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 28.605 0.013881 0.136503 0.006095 0.213602 0.122737 0.507182 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.7 3. 1. 4. -5. -3. Chi 1.1E-05 9.3E-05 2.5E-04 8.2E-05 2.3E-04 2.1E-05 Composition Misfit: 6.840886E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 71.394 0.000000 0.054604 0.123982 0.159708 0.240213 0.421493 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 0.7 -2. 3. 0.3 Chi 0. 1.1E-04 6.5E-06 3.6E-05 5.4E-05 2.7E-07 Composition Misfit: 2.064785E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.003922 0.077343 0.089757 0.173760 0.205248 0.007360 0.442610 Augite(G) 0.013808 0.135784 0.006063 0.212477 0.122090 0.005268 0.504511 Gt(W) 0.000000 0.054157 0.122966 0.158400 0.238246 0.008190 0.418041 ----- ----- ----- ----- ----- ----- ----- Potentials -802928. -651219. -1672673. -749696. -333767. -449092. -891354. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 128 converged, 123 successes so far. Misfit function evaluations this try => 130 Misfit this try = 6.741881E-05 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.403437E-07 Bayes score, PP * exp(-Misfit) = 1.403342E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2788.54 884.785 0.286801 0.238863 0.761137 Final coordinates: 11828.7 1038.40 0.164065 0.586496 0.413504 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.689168E-5 Extraneous predicted phases: 5.271253E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 58.544 0.013557 0.139801 0.007120 0.216979 0.117999 0.504545 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.1 0.2 0.2 0.7 -0.5 -0.5 Chi 4.1E-07 4.9E-07 5.6E-06 3.1E-06 2.9E-06 7.6E-07 Composition Misfit: 1.321804E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 41.455 0.000000 0.053201 0.124246 0.158938 0.242023 0.421592 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 0.5 -1. 1. 0.2 Chi 0. 2.1E-05 3.2E-06 1.6E-05 1.3E-05 1.3E-07 Composition Misfit: 5.367364E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.007852 0.102993 0.055544 0.191457 0.168511 0.006912 0.466731 Augite(G) 0.013474 0.138951 0.007077 0.215660 0.117282 0.006078 0.501479 Gt(W) 0.000000 0.052771 0.123243 0.157654 0.240068 0.008077 0.418187 ----- ----- ----- ----- ----- ----- ----- Potentials -783295. -643779. -1659139. -746806. -323490. -442923. -891562. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 129 converged, 124 successes so far. Misfit function evaluations this try => 144 Misfit this try = 9.767839E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 5.235847E-09 Bayes score, PP * exp(-Misfit) = 5.230735E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13469.5 925.718 0.724435 0.357211 0.642789 Final coordinates: 19961.9 1182.17 0.153270 0.447104 0.552896 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.752936E-4 Extraneous predicted phases: 1.490270E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 43.539 0.013894 0.138531 0.005966 0.213782 0.120566 0.507260 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.8 1. 1. 4. -3. -3. Chi 1.2E-05 1.7E-05 3.1E-04 7.5E-05 8.2E-05 2.2E-05 Composition Misfit: 5.158121E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 56.460 0.000000 0.055385 0.123163 0.161820 0.238446 0.421186 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 1. -3. 4. 0.6 Chi 0. 1.9E-04 2.4E-05 1.2E-04 1.2E-04 9.8E-07 Composition Misfit: 4.594815E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005985 0.090804 0.071802 0.183047 0.185968 0.007126 0.455268 Augite(G) 0.013821 0.137801 0.005935 0.212655 0.119931 0.005271 0.504587 Gt(W) 0.000000 0.054912 0.122111 0.160438 0.236409 0.008543 0.417588 ----- ----- ----- ----- ----- ----- ----- Potentials -804043. -651080. -1672428. -749326. -334049. -446312. -890542. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 130 converged, 125 successes so far. Misfit function evaluations this try => 462 Misfit this try = 6.220148E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 5.373411E-09 Bayes score, PP * exp(-Misfit) = 5.340091E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 4341.26 956.616 0.948310 0.145369 0.854631 Final coordinates: 20000.0 1178.81 0.215616 1.00000 2.376372E-20 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.197021E-3 Extraneous predicted phases: 2.312685E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.978 0.013485 0.140082 0.007303 0.217808 0.117404 0.503918 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -5.3E-03 -1.5E-02 1.4E-02 -1.4E-02 1.1E-02 7.1E-03 Chi 6.0E-10 3.1E-09 4.1E-08 1.1E-09 1.4E-09 1.6E-10 Composition Misfit: 4.711389E-08 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.016 0.000000 0.052950 0.114184 0.185448 0.229598 0.417819 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.8 9. -1.8E+01 1.2E+01 4. Chi 0. 1.2E-05 1.0E-03 4.3E-03 8.8E-04 3.8E-05 Composition Misfit: 6.196974E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.006 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013397 0.139180 0.007274 0.216423 0.116678 0.006289 0.500758 Augite(G) 0.013400 0.139201 0.007257 0.216438 0.116665 0.006289 0.500749 Gt(W) 0.000000 0.052294 0.112770 0.183151 0.226754 0.012389 0.412643 ----- ----- ----- ----- ----- ----- ----- Potentials -806590. -651004. -1671507. -748316. -334833. -428328. -890033. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 131 converged, 126 successes so far. Misfit function evaluations this try => 126 Misfit this try = 9.307731E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.792482E-08 Bayes score, PP * exp(-Misfit) = 1.790814E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18951.5 884.333 0.578993 0.703335 0.296665 Final coordinates: 17547.6 1152.96 0.170277 0.655277 0.344723 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.302633E-4 Extraneous predicted phases: 5.097896E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 64.644 0.013703 0.139336 0.006829 0.215086 0.119244 0.505803 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.4 0.5 0.4 2. -2. -1. Chi 3.6E-06 3.8E-06 3.5E-05 3.4E-05 2.8E-05 7.0E-06 Composition Misfit: 1.116849E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 35.355 0.000000 0.056082 0.122278 0.164038 0.236749 0.420854 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -4. 2. -4. 6. 0.9 Chi 0. 2.8E-04 5.5E-05 2.7E-04 2.1E-04 2.3E-06 Composition Misfit: 8.185784E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.008774 0.109010 0.047519 0.195608 0.159894 0.006807 0.472389 Augite(G) 0.013625 0.138550 0.006790 0.213874 0.118572 0.005636 0.502952 Gt(W) 0.000000 0.055581 0.121187 0.162574 0.234636 0.008923 0.417099 ----- ----- ----- ----- ----- ----- ----- Potentials -800891. -650142. -1670765. -749742. -332865. -443478. -892354. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 132 converged, 127 successes so far. Misfit function evaluations this try => 96 Misfit this try = 1.484778E-05 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.671559E-07 Bayes score, PP * exp(-Misfit) = 1.671535E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10809.7 934.143 0.245147 0.657703 0.342297 Final coordinates: 10665.6 1014.10 0.181140 0.759699 0.240301 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.339178E-5 Extraneous predicted phases: 1.455999E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 76.049 0.013498 0.140030 0.007302 0.217577 0.117528 0.504064 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -3.0E-02 2.2E-02 1.5E-02 0.2 -0.1 -0.1 Chi 2.0E-08 6.8E-09 4.6E-08 2.1E-07 1.1E-07 3.7E-08 Composition Misfit: 4.295257E-07 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 23.949 0.000000 0.052587 0.124492 0.158243 0.242993 0.421684 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.4 0.3 -0.6 0.7 0.1 Chi 0. 3.6E-06 1.2E-06 5.3E-06 2.8E-06 5.0E-08 Composition Misfit: 1.296226E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.010174 0.118146 0.035333 0.201911 0.146808 0.006648 0.480980 Augite(G) 0.013414 0.139158 0.007256 0.216222 0.116796 0.006227 0.500925 Gt(W) 0.000000 0.052168 0.123499 0.156982 0.241057 0.007971 0.418323 ----- ----- ----- ----- ----- ----- ----- Potentials -779735. -642431. -1656707. -746178. -321599. -442157. -891403. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 133 converged, 128 successes so far. Misfit function evaluations this try => 143 Misfit this try = 4.158117E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 5.111101E-08 Bayes score, PP * exp(-Misfit) = 5.108977E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 6676.45 764.072 0.767645 0.198292 0.801708 Final coordinates: 15393.2 1106.13 0.140243 0.235129 0.764871 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 4.132168E-4 Extraneous predicted phases: 2.594883E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 23.159 0.013770 0.137468 0.006386 0.215002 0.121145 0.506229 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.5 2. 0.8 3. -3. -2. Chi 6.0E-06 4.9E-05 1.4E-04 3.6E-05 1.1E-04 1.0E-05 Composition Misfit: 3.531746E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 76.838 0.000000 0.053490 0.124408 0.158551 0.241898 0.421653 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 0.4 -0.8 2. 0.2 Chi 0. 3.4E-05 1.8E-06 9.5E-06 1.5E-05 7.4E-08 Composition Misfit: 6.004224E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.003146 0.072279 0.096512 0.170265 0.212501 0.007450 0.437846 Augite(G) 0.013693 0.136700 0.006350 0.213802 0.120468 0.005585 0.503402 Gt(W) 0.000000 0.053062 0.123412 0.157281 0.239961 0.008007 0.418277 ----- ----- ----- ----- ----- ----- ----- Potentials -792723. -647476. -1665795. -748251. -328436. -446992. -891501. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 134 converged, 129 successes so far. Misfit function evaluations this try => 105 Misfit this try = 4.904825E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 5.214993E-08 Bayes score, PP * exp(-Misfit) = 5.212435E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16317.5 1162.00 6.183050E-02 0.224965 0.775035 Final coordinates: 15428.1 1103.09 0.135284 0.138029 0.861971 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 4.886862E-4 Extraneous predicted phases: 1.796268E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 13.568 0.013806 0.137140 0.006188 0.214870 0.121525 0.506470 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.6 2. 0.9 3. -3. -2. Chi 7.6E-06 6.2E-05 2.1E-04 4.0E-05 1.4E-04 1.3E-05 Composition Misfit: 4.684220E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 86.430 0.000000 0.052937 0.124615 0.158011 0.242707 0.421731 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.8 0.2 -0.4 0.9 0.1 Chi 0. 1.2E-05 5.5E-07 3.0E-06 5.1E-06 2.3E-08 Composition Misfit: 2.026427E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.001847 0.063797 0.107826 0.164413 0.224649 0.007598 0.429870 Augite(G) 0.013730 0.136380 0.006154 0.213680 0.120851 0.005542 0.503664 Gt(W) 0.000000 0.052517 0.123629 0.156760 0.240785 0.007918 0.418392 ----- ----- ----- ----- ----- ----- ----- Potentials -791987. -647186. -1665206. -747912. -327938. -447356. -891052. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 135 converged, 130 successes so far. Misfit function evaluations this try => 129 Misfit this try = 4.179942E-06 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.737335E-07 Bayes score, PP * exp(-Misfit) = 1.737327E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17879.2 992.318 0.168914 0.856436 0.143564 Final coordinates: 10196.1 1005.91 0.185092 0.794059 0.205941 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.918245E-6 Extraneous predicted phases: 2.616970E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 79.604 0.013475 0.139935 0.007406 0.217723 0.117571 0.503890 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 1.3E-02 0.1 -0.1 0.1 -0.1 3.0E-02 Chi 3.6E-09 1.1E-07 9.9E-07 2.2E-08 2.0E-07 2.8E-09 Composition Misfit: 1.338019E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 20.396 0.000000 0.052466 0.124785 0.157478 0.243477 0.421794 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.3 0.1 -0.1 0.3 3.3E-02 Chi 0. 1.9E-06 6.8E-08 1.5E-07 4.7E-07 2.8E-09 Composition Misfit: 2.580226E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.010635 0.121153 0.031322 0.203986 0.142502 0.006594 0.483809 Augite(G) 0.013390 0.139057 0.007359 0.216358 0.116834 0.006270 0.500731 Gt(W) 0.000000 0.052055 0.123806 0.156242 0.241567 0.007844 0.418486 ----- ----- ----- ----- ----- ----- ----- Potentials -778459. -642070. -1656088. -746082. -320998. -442498. -891537. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 136 converged, 131 successes so far. Misfit function evaluations this try => 201 Misfit this try = 9.441202E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 5.241519E-09 Bayes score, PP * exp(-Misfit) = 5.236573E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 5059.75 1147.12 0.850523 6.595662E-02 0.934043 Final coordinates: 19681.1 1191.19 0.152453 0.435343 0.564657 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.424360E-4 Extraneous predicted phases: 1.684158E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 42.603 0.013831 0.137411 0.006405 0.213713 0.121807 0.506833 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.6 2. 0.7 4. -4. -2. Chi 8.8E-06 5.1E-05 1.3E-04 7.8E-05 1.6E-04 1.7E-05 Composition Misfit: 4.436481E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 57.395 0.000000 0.055786 0.123310 0.161492 0.238171 0.421241 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 1. -3. 5. 0.6 Chi 0. 2.4E-04 2.0E-05 1.1E-04 1.3E-04 8.2E-07 Composition Misfit: 4.987879E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005827 0.089776 0.073173 0.182338 0.187440 0.007144 0.454301 Augite(G) 0.013757 0.136679 0.006370 0.212575 0.121158 0.005327 0.504133 Gt(W) 0.000000 0.055312 0.122264 0.160123 0.236152 0.008479 0.417669 ----- ----- ----- ----- ----- ----- ----- Potentials -805890. -652287. -1674783. -750587. -335536. -447934. -892313. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 137 converged, 132 successes so far. Misfit function evaluations this try => 328 Misfit this try = 0.176170 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 4.091257E-09 Bayes score, PP * exp(-Misfit) = 3.430419E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9149.59 1170.46 0.627940 0.897022 0.102978 Final coordinates: 20000.0 600.000 0.214894 1.00000 4.670819E-18 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.176005 Extraneous predicted phases: 1.642025E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 95.461 0.014125 0.146036 0.001166 0.223259 0.107769 0.507645 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -1. -4. 5. -5. 8. -3. Chi 2.9E-05 2.4E-04 3.2E-02 1.3E-04 8.6E-04 2.7E-05 Composition Misfit: 3.379808E-02 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 4.529 0.000000 0.014696 0.136649 0.103496 0.318916 0.426243 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 3.6E+01 -9. 3.4E+01 -6.2E+01 -4. Chi 0. 0.1 1.0E-03 2.8E-02 1.8E-02 4.6E-05 Composition Misfit: 0.142207 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.010 0.000000 0.077053 0.000000 0.000000 0.589614 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013397 0.139183 0.007274 0.216427 0.116680 0.006268 0.500769 Augite(G) 0.014034 0.145096 0.001158 0.221821 0.107076 0.006438 0.504377 Gt(W) 0.000000 0.014656 0.136279 0.103215 0.318052 0.002709 0.425089 ----- ----- ----- ----- ----- ----- ----- Potentials -657121. -593518. -1577768. -693118. -255734. -450062. -838374. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 138 converged, 133 successes so far. Misfit function evaluations this try => 143 Misfit this try = 5.839831E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 6.988304E-09 Bayes score, PP * exp(-Misfit) = 6.947612E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18790.6 786.641 0.899432 0.697350 0.302650 Final coordinates: 19645.5 1169.26 0.213881 0.990008 9.991879E-03 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.812178E-3 Extraneous predicted phases: 2.765310E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.674 0.013527 0.140351 0.007065 0.217639 0.117191 0.504226 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.1 -0.2 0.2 0.1 0.2 -0.2 Chi 1.5E-07 6.0E-07 9.2E-06 1.1E-07 4.3E-07 1.8E-07 Composition Misfit: 1.067794E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 1.319 0.000000 0.052896 0.114776 0.184522 0.229765 0.418041 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.7 8. -1.7E+01 1.2E+01 4. Chi 0. 1.0E-05 8.9E-04 4.0E-03 8.6E-04 3.4E-05 Composition Misfit: 5.801500E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.007 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013263 0.138305 0.008441 0.215819 0.117931 0.006306 0.499935 Augite(G) 0.013443 0.139477 0.007021 0.216284 0.116461 0.006227 0.501086 Gt(W) 0.000000 0.052254 0.113383 0.182283 0.226976 0.012136 0.412967 ----- ----- ----- ----- ----- ----- ----- Potentials -804797. -650320. -1670200. -747907. -333835. -429059. -889637. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 139 converged, 134 successes so far. Misfit function evaluations this try => 189 Misfit this try = 3.645424E-05 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.817117E-07 Bayes score, PP * exp(-Misfit) = 1.817051E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2269.24 642.536 0.925708 0.944272 5.572761E-02 Final coordinates: 10076.2 995.448 0.215156 0.999600 3.995142E-04 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.645424E-5 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.756 0.013510 0.140245 0.007078 0.217915 0.117155 0.504097 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.1 -0.1 0.2 -0.1 0.2 -0.1 Chi 5.8E-08 2.4E-07 8.3E-06 6.8E-08 5.8E-07 5.7E-08 Composition Misfit: 9.279026E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.244 0.000000 0.051283 0.124475 0.158653 0.243911 0.421678 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 0.8 0.3 -0.8 -0.1 0.1 Chi 0. 1.5E-05 1.3E-06 1.1E-05 3.7E-08 5.4E-08 Composition Misfit: 2.717522E-05 *mole fractions relative to measured components, complete compositions below Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013392 0.139147 0.007321 0.216401 0.116730 0.006279 0.500730 Augite(G) 0.013425 0.139365 0.007034 0.216547 0.116420 0.006275 0.500934 Gt(W) 0.000000 0.050874 0.123482 0.157387 0.241965 0.007978 0.418314 ----- ----- ----- ----- ----- ----- ----- Potentials -776837. -641249. -1654435. -745257. -319824. -441253. -890614. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 140 converged, 135 successes so far. Misfit function evaluations this try => 179 Misfit this try = 4.134653E-06 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.813150E-07 Bayes score, PP * exp(-Misfit) = 1.813142E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2225.51 634.014 7.268786E-02 0.480363 0.519637 Final coordinates: 9721.27 993.718 0.186404 0.805256 0.194744 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.993266E-6 Extraneous predicted phases: 1.413874E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 80.700 0.013478 0.140095 0.007312 0.217891 0.117337 0.503887 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 7.4E-03 -2.4E-02 6.6E-03 -0.1 0.1 3.2E-02 Chi 1.2E-09 8.2E-09 9.3E-09 4.4E-08 5.4E-08 3.2E-09 Composition Misfit: 1.194955E-07 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 19.300 0.000000 0.051900 0.125058 0.156849 0.244295 0.421897 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 0.2 -0.1 0.3 -0.4 -0.1 Chi 0. 1.2E-06 2.6E-07 1.4E-06 9.4E-07 1.1E-08 Composition Misfit: 3.873770E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.000 0.000000 0.196081 0.000000 0.000000 0.470586 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.010785 0.122133 0.030015 0.204663 0.141098 0.006575 0.484731 Augite(G) 0.013393 0.139213 0.007266 0.216519 0.116598 0.006297 0.500714 Gt(W) 0.000000 0.051499 0.124092 0.155637 0.242408 0.007727 0.418637 ----- ----- ----- ----- ----- ----- ----- Potentials -736482. -631314. -1654749. -735603. -309899. -482496. -901254. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 141 converged, 136 successes so far. Misfit function evaluations this try => 175 Misfit this try = 1.374899E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 2.868670E-08 Bayes score, PP * exp(-Misfit) = 2.864729E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12569.2 647.003 0.675328 0.189677 0.810323 Final coordinates: 17135.3 1120.12 0.184471 0.788831 0.211169 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.374592E-3 Extraneous predicted phases: 3.070289E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 77.404 0.013760 0.141296 0.006097 0.215936 0.116839 0.506071 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.5 -0.9 1. 2. 0.5 -2. Chi 5.6E-06 1.1E-05 2.5E-04 1.6E-05 2.9E-06 9.1E-06 Composition Misfit: 2.896920E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 22.595 0.000000 0.054131 0.120778 0.167899 0.236901 0.420292 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 3. -7. 6. 1. Chi 0. 7.2E-05 1.4E-04 6.7E-04 2.0E-04 5.6E-06 Composition Misfit: 1.084900E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.010565 0.120695 0.031932 0.203670 0.143157 0.006602 0.483378 Augite(G) 0.013682 0.140487 0.006062 0.214699 0.116170 0.005727 0.503173 Gt(W) 0.000000 0.053613 0.119622 0.166293 0.234634 0.009567 0.416270 ----- ----- ----- ----- ----- ----- ----- Potentials -795687. -647249. -1665054. -747066. -329068. -438215. -889248. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 142 converged, 137 successes so far. Misfit function evaluations this try => 585 Misfit this try = 1.80537 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 5.415696E-09 Bayes score, PP * exp(-Misfit) = 8.904113E-10 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2160.66 972.768 0.150342 0.665151 0.334849 Final coordinates: 19814.4 1184.36 0.320736 1.00000 6.620728E-08 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.183648 Extraneous predicted phases: 1.62173 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.368 0.013652 0.141828 0.007408 0.220524 0.118872 0.497715 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 -1. -0.1 -3. -1. 5. Chi 2.1E-06 2.2E-05 1.0E-06 3.4E-05 1.8E-05 7.8E-05 Composition Misfit: 1.543699E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.010 0.000000 0.045663 0.043894 0.233039 0.285943 0.391460 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 6. 6.5E+01 -4.8E+01 -3.5E+01 2.9E+01 Chi 0. 9.2E-04 0.1 2.5E-02 6.2E-03 2.4E-03 Composition Misfit: 0.183494 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 1.622 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013356 0.138755 0.007252 0.215761 0.116321 0.009327 0.499227 Augite(G) 0.013523 0.140490 0.007338 0.218442 0.117750 0.009440 0.493017 Gt(W) 0.000000 0.043768 0.042073 0.223368 0.274077 0.041499 0.375215 ----- ----- ----- ----- ----- ----- ----- Potentials -822110. -651612. -1685927. -748750. -337837. -375299. -891151. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 143 converged, 138 successes so far. Misfit function evaluations this try => 117 Misfit this try = 4.188952E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.095537E-07 Bayes score, PP * exp(-Misfit) = 1.095078E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12440.3 801.945 0.799579 0.948302 5.169840E-02 Final coordinates: 12826.3 1063.29 0.202397 0.921132 7.886800E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 4.131046E-4 Extraneous predicted phases: 5.790553E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 92.319 0.013461 0.139739 0.007680 0.217263 0.118003 0.503854 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 3.8E-02 0.2 -0.3 0.5 -0.5 0.1 Chi 3.1E-08 7.4E-07 1.7E-05 1.3E-06 2.9E-06 1.1E-08 Composition Misfit: 2.182852E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 7.678 0.000000 0.054408 0.122764 0.162594 0.239198 0.421037 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 2. -3. 4. 0.8 Chi 0. 9.4E-05 3.6E-05 1.7E-04 8.9E-05 1.5E-06 Composition Misfit: 3.912761E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.003 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.012339 0.132275 0.016485 0.211660 0.126570 0.006404 0.494267 Augite(G) 0.013378 0.138872 0.007632 0.215913 0.117270 0.006210 0.500725 Gt(W) 0.000000 0.053934 0.121695 0.161177 0.237113 0.008714 0.417368 ----- ----- ----- ----- ----- ----- ----- Potentials -787617. -645283. -1661857. -747720. -325891. -440867. -892214. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 144 converged, 139 successes so far. Misfit function evaluations this try => 204 Misfit this try = 9.380268E-02 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 5.294948E-08 Bayes score, PP * exp(-Misfit) = 4.820851E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15720.2 661.721 6.828160E-02 4.904610E-02 0.950954 Final coordinates: 11608.4 647.903 0.135093 2.353374E-02 0.976466 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 8.173281E-2 Extraneous predicted phases: 1.206987E-2 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 1.638 0.019403 0.193160 0.002936 0.214596 0.058736 0.511169 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -1.1E+01 -3.8E+01 4. 3. 5.0E+01 -6. Chi 1.8E-03 1.5E-02 6.5E-03 4.8E-05 0.1 1.0E-04 Composition Misfit: 8.172534E-02 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.200 0.000000 0.051975 0.124246 0.158016 0.244171 0.421592 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 0.2 0.5 -0.4 -0.3 0.2 Chi 0. 6.0E-07 3.2E-06 3.0E-06 5.2E-07 1.3E-07 Composition Misfit: 7.474192E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.162 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000315 0.053783 0.121126 0.157468 0.238898 0.008068 0.420342 Augite(G) 0.019244 0.191583 0.002912 0.212843 0.058256 0.008166 0.506995 Gt(W) 0.000000 0.051555 0.123242 0.156740 0.242199 0.008077 0.418187 ----- ----- ----- ----- ----- ----- ----- Potentials -716586. -609322. -1591174. -717332. -281435. -388382. -852538. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 145 converged, 140 successes so far. Misfit function evaluations this try => 114 Misfit this try = 3.207367E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 9.156617E-08 Bayes score, PP * exp(-Misfit) = 9.153681E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14236.6 1099.07 6.185043E-02 8.125766E-02 0.918742 Final coordinates: 13798.2 1071.12 0.131808 6.374098E-02 0.936259 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.204959E-4 Extraneous predicted phases: 2.407579E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 6.297 0.013751 0.137778 0.006309 0.215590 0.120558 0.506015 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.5 2. 0.8 2. -3. -2. Chi 5.3E-06 3.8E-05 1.6E-04 2.3E-05 8.2E-05 8.6E-06 Composition Misfit: 3.181320E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 93.702 0.000000 0.052421 0.124789 0.157554 0.243440 0.421796 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.3 0.1 -0.1 0.3 3.1E-02 Chi 0. 1.4E-06 6.3E-08 3.3E-07 5.8E-07 2.6E-09 Composition Misfit: 2.363916E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000853 0.057309 0.116479 0.159938 0.233942 0.007709 0.423770 Augite(G) 0.013673 0.136993 0.006273 0.214362 0.119871 0.005696 0.503132 Gt(W) 0.000000 0.052010 0.123810 0.156319 0.241531 0.007843 0.418488 ----- ----- ----- ----- ----- ----- ----- Potentials -787467. -645403. -1662005. -747137. -325453. -446329. -890926. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 146 converged, 141 successes so far. Misfit function evaluations this try => 180 Misfit this try = 1.533442E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.163785E-08 Bayes score, PP * exp(-Misfit) = 1.162001E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 6012.62 1142.79 0.485458 0.117649 0.882351 Final coordinates: 18359.9 1167.11 0.129736 1.680037E-02 0.983200 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.532093E-3 Extraneous predicted phases: 1.348643E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 1.648 0.013849 0.132318 0.006206 0.213403 0.127250 0.506974 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.7 6. 0.9 4. -8. -2. Chi 9.7E-06 4.5E-04 2.0E-04 9.0E-05 7.6E-04 1.8E-05 Composition Misfit: 1.531280E-03 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.351 0.000000 0.052318 0.124844 0.157428 0.243592 0.421817 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.2 2.6E-02 -0.1 0.2 1.2E-02 Chi 0. 5.3E-07 8.8E-09 6.7E-08 2.1E-07 3.6E-10 Composition Misfit: 8.133268E-07 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.182593 0.000000 0.000000 0.484074 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000225 0.053211 0.121947 0.157110 0.239813 0.007778 0.419917 Augite(G) 0.013775 0.131614 0.006173 0.212268 0.126573 0.005319 0.504277 Gt(W) 0.000000 0.051909 0.123868 0.156198 0.241688 0.007819 0.418518 ----- ----- ----- ----- ----- ----- ----- Potentials -741646. -636506. -1672816. -735140. -318276. -512076. -907145. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 147 converged, 142 successes so far. Misfit function evaluations this try => 334 Misfit this try = 1.95759 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 4.300355E-09 Bayes score, PP * exp(-Misfit) = 6.072048E-10 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2466.34 817.877 0.689714 0.372262 0.627738 Final coordinates: 19881.9 1199.97 0.324160 1.00000 1.391520E-09 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.229098 Extraneous predicted phases: 1.72849 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.317 0.013658 0.141884 0.007413 0.220613 0.118924 0.497508 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 -1. -0.1 -3. -1. 5. Chi 2.3E-06 2.3E-05 1.2E-06 3.6E-05 1.9E-05 8.3E-05 Composition Misfit: 1.648292E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.008 0.000000 0.043660 0.038948 0.239430 0.288356 0.389606 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 8. 6.9E+01 -5.2E+01 -3.7E+01 3.1E+01 Chi 0. 1.7E-03 0.2 2.8E-02 6.9E-03 2.7E-03 Composition Misfit: 0.228933 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 1.675 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013355 0.138741 0.007251 0.215740 0.116310 0.009426 0.499178 Augite(G) 0.013527 0.140530 0.007342 0.218508 0.117789 0.009544 0.492760 Gt(W) 0.000000 0.041762 0.037254 0.229019 0.275817 0.043483 0.372664 ----- ----- ----- ----- ----- ----- ----- Potentials -825991. -653384. -1691325. -749851. -340334. -372443. -892971. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 148 converged, 143 successes so far. Misfit function evaluations this try => 319 Misfit this try = 2.664246E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 4.013533E-08 Bayes score, PP * exp(-Misfit) = 4.002855E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 5700.12 1016.27 0.775389 0.940257 5.974269E-02 Final coordinates: 16176.0 1112.41 0.215305 0.999017 9.825262E-04 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.654183E-3 Extraneous predicted phases: 1.006297E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.962 0.013474 0.140009 0.007398 0.217754 0.117505 0.503860 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 1.5E-02 3.8E-02 -0.1 3.5E-02 -0.1 0.1 Chi 5.1E-09 2.0E-08 8.2E-07 6.7E-09 6.6E-08 9.0E-09 Composition Misfit: 9.302629E-07 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.034 0.000000 0.053360 0.118393 0.175167 0.233682 0.419398 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 5. -1.1E+01 8. 2. Chi 0. 2.7E-05 3.6E-04 1.8E-03 4.4E-04 1.4E-05 Composition Misfit: 2.653252E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.004 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013384 0.139095 0.007389 0.216364 0.116802 0.006287 0.500679 Augite(G) 0.013389 0.139129 0.007352 0.216386 0.116766 0.006286 0.500693 Gt(W) 0.000000 0.052795 0.117140 0.173312 0.231207 0.010590 0.414956 ----- ----- ----- ----- ----- ----- ----- Potentials -795569. -647455. -1665203. -747469. -329373. -433953. -890484. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 149 converged, 144 successes so far. Misfit function evaluations this try => 513 Misfit this try = 0.175877 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 4.091258E-09 Bayes score, PP * exp(-Misfit) = 3.431426E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2827.18 984.213 0.433033 0.814088 0.185912 Final coordinates: 20000.0 600.000 0.215589 0.999999 1.395204E-06 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.175857 Extraneous predicted phases: 2.013052E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 95.436 0.014128 0.146072 0.001130 0.223251 0.107788 0.507629 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -1. -4. 5. -5. 8. -3. Chi 3.0E-05 2.5E-04 3.4E-02 1.3E-04 8.6E-04 2.7E-05 Composition Misfit: 3.519237E-02 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 4.558 0.000000 0.014746 0.136514 0.104076 0.318472 0.426193 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 3.6E+01 -9. 3.4E+01 -6.1E+01 -4. Chi 0. 0.1 9.9E-04 2.7E-02 1.8E-02 4.5E-05 Composition Misfit: 0.140664 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.006 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013397 0.139180 0.007274 0.216423 0.116678 0.006289 0.500758 Augite(G) 0.014037 0.145129 0.001123 0.221810 0.107092 0.006457 0.504352 Gt(W) 0.000000 0.014705 0.136136 0.103788 0.317590 0.002768 0.425013 ----- ----- ----- ----- ----- ----- ----- Potentials -690740. -601857. -1577728. -701400. -264084. -416168. -830057. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 150 converged, 145 successes so far. Misfit function evaluations this try => 76 Misfit this try = 8.733177E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.746454E-08 Bayes score, PP * exp(-Misfit) = 1.744929E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17111.8 1170.84 0.120197 0.165524 0.834476 Final coordinates: 17902.3 1145.05 0.134410 0.119734 0.880266 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 8.716047E-4 Extraneous predicted phases: 1.713075E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 11.685 0.013901 0.135881 0.005899 0.213904 0.123177 0.507238 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.8 3. 1. 4. -5. -3. Chi 1.3E-05 1.3E-04 3.4E-04 7.1E-05 2.7E-04 2.2E-05 Composition Misfit: 8.450340E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 88.313 0.000000 0.053060 0.124586 0.158086 0.242547 0.421720 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.9 0.2 -0.5 1. 0.1 Chi 0. 1.6E-05 6.8E-07 3.7E-06 6.6E-06 2.8E-08 Composition Misfit: 2.657064E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.001602 0.062199 0.109957 0.163311 0.226938 0.007626 0.428367 Augite(G) 0.013827 0.135161 0.005868 0.212770 0.122524 0.005304 0.504547 Gt(W) 0.000000 0.052639 0.123598 0.156833 0.240624 0.007930 0.418376 ----- ----- ----- ----- ----- ----- ----- Potentials -797622. -649323. -1669020. -748537. -330856. -449384. -890570. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 151 converged, 146 successes so far. Misfit function evaluations this try => 136 Misfit this try = 2.754779E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.718137E-07 Bayes score, PP * exp(-Misfit) = 1.717663E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 5726.01 990.129 0.229845 6.011125E-02 0.939889 Final coordinates: 7324.79 941.903 0.131753 6.350637E-02 0.936494 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.734752E-4 Extraneous predicted phases: 2.002643E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 6.542 0.013220 0.142361 0.008328 0.219822 0.114403 0.501866 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.5 -2. -0.8 -2. 3. 2. Chi 5.2E-06 3.7E-05 1.2E-04 1.9E-05 7.9E-05 8.5E-06 Composition Misfit: 2.710151E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 93.457 0.000000 0.051871 0.124968 0.157107 0.244191 0.421863 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 0.3 -0.1 0.1 -0.3 -3.2E-02 Chi 0. 1.5E-06 6.5E-08 3.1E-07 5.8E-07 2.7E-09 Composition Misfit: 2.460095E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.201623 0.000000 0.000000 0.465044 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000850 0.057289 0.116507 0.159924 0.233972 0.007707 0.423752 Augite(G) 0.013129 0.141386 0.008271 0.218315 0.113619 0.006853 0.498427 Gt(W) 0.000000 0.051468 0.123997 0.155887 0.242295 0.007766 0.418587 ----- ----- ----- ----- ----- ----- ----- Potentials -734309. -629747. -1649563. -735609. -307408. -473892. -899645. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 152 converged, 147 successes so far. Misfit function evaluations this try => 149 Misfit this try = 2.765077E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.606591E-07 Bayes score, PP * exp(-Misfit) = 1.606147E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12953.5 639.235 0.411255 0.523625 0.476375 Final coordinates: 6725.75 925.000 0.147989 0.369168 0.630832 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.763722E-4 Extraneous predicted phases: 1.355450E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 37.758 0.013269 0.141775 0.007961 0.219849 0.114970 0.502175 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.4 -1. -0.5 -2. 2. 1. Chi 3.4E-06 2.1E-05 5.2E-05 1.9E-05 5.2E-05 6.1E-06 Composition Misfit: 1.531053E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 62.241 0.000000 0.050288 0.125608 0.155519 0.246481 0.422103 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 2. -0.6 1. -2. -0.3 Chi 0. 6.9E-05 4.3E-06 2.1E-05 2.9E-05 1.8E-07 Composition Misfit: 1.232669E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.000 0.000000 0.197161 0.000000 0.000000 0.469505 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.004941 0.083992 0.080889 0.178348 0.195726 0.007241 0.448863 Augite(G) 0.013178 0.140808 0.007907 0.218348 0.114185 0.006827 0.498747 Gt(W) 0.000000 0.049911 0.124667 0.154354 0.244635 0.007490 0.418942 ----- ----- ----- ----- ----- ----- ----- Potentials -733989. -629334. -1647862. -735513. -306393. -472101. -898607. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 153 converged, 148 successes so far. Misfit function evaluations this try => 138 Misfit this try = 1.935772E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 8.196368E-09 Bayes score, PP * exp(-Misfit) = 8.180517E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18528.3 1165.61 0.782256 0.913027 8.697336E-02 Final coordinates: 18322.7 1196.15 0.183726 0.782882 0.217118 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.935772E-3 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 78.518 0.013468 0.138225 0.008369 0.215360 0.120388 0.504191 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 2.6E-02 1. -0.8 2. -3. -0.2 Chi 1.4E-08 2.4E-05 1.3E-04 2.7E-05 7.3E-05 1.4E-07 Composition Misfit: 2.568670E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 21.482 0.000000 0.058476 0.121517 0.165914 0.233524 0.420569 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -6. 3. -5. 8. 1. Chi 0. 6.8E-04 9.3E-05 4.4E-04 4.5E-04 3.8E-06 Composition Misfit: 1.678905E-03 *mole fractions relative to measured components, complete compositions below Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.010485 0.120175 0.032627 0.203312 0.143902 0.006610 0.482890 Augite(G) 0.013389 0.137412 0.008320 0.214094 0.119680 0.005878 0.501227 Gt(W) 0.000000 0.057935 0.120393 0.164380 0.231364 0.009250 0.416679 ----- ----- ----- ----- ----- ----- ----- Potentials -744022. -637571. -1677886. -736711. -321887. -508793. -912227. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 154 converged, 149 successes so far. Misfit function evaluations this try => 110 Misfit this try = 5.758845E-05 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.590470E-07 Bayes score, PP * exp(-Misfit) = 1.590378E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 5489.79 998.084 0.338340 0.915158 8.484157E-02 Final coordinates: 10929.9 1022.88 0.204850 0.937814 6.218605E-02 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.699257E-5 Extraneous predicted phases: 5.958751E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 93.975 0.013462 0.139879 0.007536 0.217586 0.117721 0.503816 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 3.7E-02 0.1 -0.2 0.2 -0.3 0.1 Chi 3.0E-08 2.4E-07 6.2E-06 2.0E-07 7.9E-07 2.5E-08 Composition Misfit: 7.460910E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 6.024 0.000000 0.052958 0.124254 0.159152 0.242040 0.421595 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.8 0.5 -1. 1. 0.2 Chi 0. 1.2E-05 3.1E-06 2.1E-05 1.3E-05 1.3E-07 Composition Misfit: 4.953166E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.012563 0.133737 0.014537 0.212668 0.124478 0.006375 0.495642 Augite(G) 0.013377 0.139003 0.007489 0.216223 0.116984 0.006265 0.500660 Gt(W) 0.000000 0.052530 0.123251 0.157868 0.240086 0.008073 0.418192 ----- ----- ----- ----- ----- ----- ----- Potentials -781136. -643044. -1657802. -746604. -322489. -442100. -891813. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 155 converged, 150 successes so far. Misfit function evaluations this try => 243 Misfit this try = 0.176496 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 4.091257E-09 Bayes score, PP * exp(-Misfit) = 3.429299E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 1960.81 1169.49 0.749164 5.927880E-02 0.940721 Final coordinates: 20000.0 600.000 0.214552 0.999998 1.759924E-06 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.175803 Extraneous predicted phases: 6.938258E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 95.464 0.014125 0.146024 0.001177 0.223273 0.107751 0.507651 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -1. -4. 5. -5. 8. -3. Chi 2.9E-05 2.4E-04 3.2E-02 1.3E-04 8.7E-04 2.7E-05 Composition Misfit: 3.338126E-02 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 4.514 0.000000 0.014685 0.136868 0.103397 0.318724 0.426326 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 3.6E+01 -10. 3.4E+01 -6.1E+01 -4. Chi 0. 0.1 1.1E-03 2.8E-02 1.8E-02 4.7E-05 Composition Misfit: 0.142421 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.021 0.000000 0.077001 0.000000 0.000000 0.589666 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013397 0.139185 0.007275 0.216430 0.116682 0.006259 0.500773 Augite(G) 0.014034 0.145085 0.001169 0.221837 0.107058 0.006432 0.504385 Gt(W) 0.000000 0.014646 0.136511 0.103127 0.317891 0.002613 0.425212 ----- ----- ----- ----- ----- ----- ----- Potentials -656951. -593510. -1577755. -693104. -255731. -450654. -838380. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 156 converged, 151 successes so far. Misfit function evaluations this try => 145 Misfit this try = 4.528003E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 7.363079E-08 Bayes score, PP * exp(-Misfit) = 7.359746E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 5863.09 744.795 0.487408 5.733564E-02 0.942664 Final coordinates: 14547.5 1083.31 0.130535 3.401472E-02 0.965985 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 4.517123E-4 Extraneous predicted phases: 1.087982E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 3.344 0.013816 0.137388 0.006123 0.215176 0.121111 0.506386 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.6 2. 1. 2. -3. -2. Chi 8.1E-06 5.2E-05 2.3E-04 3.2E-05 1.1E-04 1.2E-05 Composition Misfit: 4.508009E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 96.654 0.000000 0.052318 0.124820 0.157469 0.243585 0.421808 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.2 4.6E-02 -0.1 0.2 2.0E-02 Chi 0. 5.3E-07 2.6E-08 1.3E-07 2.2E-07 1.1E-09 Composition Misfit: 9.113928E-07 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000455 0.054714 0.119941 0.158147 0.237659 0.007756 0.421328 Augite(G) 0.013738 0.136618 0.006088 0.213970 0.120432 0.005606 0.503547 Gt(W) 0.000000 0.051909 0.123843 0.156236 0.241678 0.007829 0.418505 ----- ----- ----- ----- ----- ----- ----- Potentials -788903. -646006. -1663013. -747251. -326235. -446822. -890675. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 157 converged, 152 successes so far. Misfit function evaluations this try => 190 Misfit this try = 1.815310E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.421638E-07 Bayes score, PP * exp(-Misfit) = 1.421380E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 3359.73 693.546 0.563121 0.438685 0.561315 Final coordinates: 11662.1 1037.80 0.208853 0.961255 3.874451E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.683533E-4 Extraneous predicted phases: 1.317765E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 96.352 0.013455 0.139832 0.007615 0.217550 0.117789 0.503760 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.1 0.2 -0.2 0.2 -0.3 0.1 Chi 5.5E-08 3.8E-07 1.1E-05 2.7E-07 1.2E-06 5.6E-08 Composition Misfit: 1.335037E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 3.643 0.000000 0.053567 0.123495 0.160639 0.240989 0.421311 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 1. -2. 2. 0.5 Chi 0. 3.7E-05 1.5E-05 6.8E-05 3.3E-05 6.4E-07 Composition Misfit: 1.550030E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.005 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.012877 0.135788 0.011800 0.214083 0.121538 0.006346 0.497569 Augite(G) 0.013370 0.138955 0.007567 0.216186 0.117051 0.006268 0.500603 Gt(W) 0.000000 0.053117 0.122458 0.159289 0.238964 0.008400 0.417772 ----- ----- ----- ----- ----- ----- ----- Potentials -783599. -643819. -1659211. -746970. -323718. -441228. -891873. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 158 converged, 153 successes so far. Misfit function evaluations this try => 102 Misfit this try = 4.004286E-06 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.814179E-07 Bayes score, PP * exp(-Misfit) = 1.814171E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10910.0 988.399 0.145616 0.780241 0.219759 Final coordinates: 9756.32 993.865 0.177599 0.728278 0.271722 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 4.004286E-6 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 73.028 0.013480 0.140163 0.007295 0.217904 0.117260 0.503898 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 4.0E-03 -0.1 2.0E-02 -0.1 0.1 2.3E-02 Chi 3.4E-10 7.4E-08 8.6E-08 5.7E-08 2.1E-07 1.7E-09 Composition Misfit: 4.293944E-07 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 26.972 0.000000 0.051839 0.124995 0.157003 0.244289 0.421873 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 0.3 -0.1 0.2 -0.4 -4.2E-02 Chi 0. 1.9E-06 1.1E-07 6.7E-07 9.2E-07 4.6E-09 Composition Misfit: 3.574891E-06 *mole fractions relative to measured components, complete compositions below Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.009753 0.115397 0.039000 0.200015 0.150746 0.006693 0.478396 Augite(G) 0.013395 0.139281 0.007249 0.216532 0.116521 0.006297 0.500725 Gt(W) 0.000000 0.051437 0.124026 0.155785 0.242395 0.007754 0.418602 ----- ----- ----- ----- ----- ----- ----- Potentials -736454. -631282. -1654717. -735558. -309869. -482442. -901204. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 159 converged, 154 successes so far. Misfit function evaluations this try => 186 Misfit this try = 6.683068E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 5.494776E-09 Bayes score, PP * exp(-Misfit) = 5.458177E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2475.29 701.416 0.766387 0.859957 0.140043 Final coordinates: 19997.0 1177.10 0.215287 0.999976 2.374173E-05 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.682289E-3 Extraneous predicted phases: 7.788701E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.909 0.013494 0.140139 0.007227 0.217821 0.117320 0.503999 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -2.2E-02 -0.1 0.1 -2.6E-02 0.1 -0.1 Chi 1.1E-08 4.3E-08 1.2E-06 3.7E-09 7.9E-08 1.0E-08 Composition Misfit: 1.360070E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.090 0.000000 0.052799 0.114205 0.186665 0.228505 0.417827 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.6 9. -1.9E+01 1.3E+01 4. Chi 0. 7.9E-06 1.0E-03 4.6E-03 1.0E-03 3.8E-05 Composition Misfit: 6.680929E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013397 0.139180 0.007277 0.216424 0.116682 0.006280 0.500761 Augite(G) 0.013409 0.139260 0.007181 0.216455 0.116584 0.006275 0.500837 Gt(W) 0.000000 0.052145 0.112791 0.184354 0.225676 0.012380 0.412654 ----- ----- ----- ----- ----- ----- ----- Potentials -806107. -650892. -1671155. -748109. -334620. -428426. -889826. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Augite(G) q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Augite(G) q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 161 converged, 155 successes so far. Misfit function evaluations this try => 133 Misfit this try = 6.596721E-04 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 8.123760E-08 Bayes score, PP * exp(-Misfit) = 8.118402E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15380.7 990.493 7.063689E-02 0.942282 5.771764E-02 Final coordinates: 13796.5 1086.22 0.200630 0.910502 8.949795E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.596137E-4 Extraneous predicted phases: 5.846013E-8 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 91.340 0.013450 0.139569 0.007835 0.217033 0.118294 0.503818 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.1 0.4 -0.4 0.7 -0.7 0.1 Chi 7.7E-08 1.7E-06 3.4E-05 2.7E-06 6.5E-06 2.4E-08 Composition Misfit: 4.480604E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 8.659 0.000000 0.055106 0.122429 0.163761 0.237794 0.420911 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 2. -4. 5. 0.9 Chi 0. 1.6E-04 4.9E-05 2.5E-04 1.5E-04 2.0E-06 Composition Misfit: 6.148076E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.012196 0.131346 0.017727 0.211019 0.127903 0.006415 0.493394 Augite(G) 0.013367 0.138707 0.007786 0.215692 0.117563 0.006181 0.500704 Gt(W) 0.000000 0.054618 0.121344 0.162310 0.235687 0.008858 0.417182 ----- ----- ----- ----- ----- ----- ----- Potentials -791163. -646709. -1664406. -748503. -327964. -441078. -892737. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 162 converged, 156 successes so far. Misfit function evaluations this try => 135 Misfit this try = 1.234634E-03 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.236074E-08 Bayes score, PP * exp(-Misfit) = 1.234549E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18163.4 734.738 0.599869 6.448187E-02 0.935518 Final coordinates: 19062.1 1139.04 0.129102 1.459920E-03 0.998540 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.234345E-3 Extraneous predicted phases: 2.885031E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.141 0.013993 0.137014 0.005201 0.213704 0.122001 0.508087 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.9 2. 2. 4. -4. -3. Chi 1.9E-05 6.8E-05 8.6E-04 7.8E-05 1.7E-04 3.4E-05 Composition Misfit: 1.234342E-03 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.858 0.000000 0.052159 0.124875 0.157336 0.243802 0.421828 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -7.9E-03 2.1E-03 -6.3E-03 1.2E-02 9.1E-04 Chi 0. 1.3E-09 5.3E-11 6.2E-10 8.7E-10 2.2E-12 Composition Misfit: 2.840601E-09 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.186519 0.000000 0.000000 0.480148 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000020 0.051872 0.123733 0.156186 0.241731 0.007802 0.418657 Augite(G) 0.013921 0.136312 0.005174 0.212609 0.121376 0.005125 0.505483 Gt(W) 0.000000 0.051752 0.123900 0.156108 0.241899 0.007806 0.418535 ----- ----- ----- ----- ----- ----- ----- Potentials -735586. -632793. -1665738. -731467. -313887. -508025. -902131. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 163 converged, 157 successes so far. Misfit function evaluations this try => 507 Misfit this try = 0.894841 Best Misfit so far = 2.041602E-06 obtained on Try 15 Prior probability, PP = 1.585828E-07 Bayes score, PP * exp(-Misfit) = 6.480845E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 3343.04 1126.03 0.558313 0.717705 0.282295 Final coordinates: 6646.11 875.412 0.292744 0.995786 4.214310E-03 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.415148E-3 Extraneous predicted phases: 0.889426 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.437 0.013526 0.141326 0.007541 0.219840 0.118566 0.499200 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.1 -0.9 -0.2 -2. -1. 4. Chi 1.5E-07 1.1E-05 6.5E-06 1.9E-05 1.1E-05 4.5E-05 Composition Misfit: 9.293141E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.199 0.000000 0.049283 0.108195 0.157224 0.269725 0.415573 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 3. 1.3E+01 0.1 -2.1E+01 6. Chi 0. 1.7E-04 2.6E-03 6.7E-08 2.5E-03 9.4E-05 Composition Misfit: 5.322216E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 Sp(WPC) 0.026 0.000000 0.004038 0.004038 0.000000 0.850221 0.141703 0.000000 Fsp(C1) 0.123 0.077355 0.000000 0.172645 0.095290 0.000000 0.000000 0.654710 q 1.215 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013310 0.138495 0.007749 0.215676 0.116940 0.008558 0.499272 Augite(G) 0.013410 0.140113 0.007477 0.217953 0.117548 0.008585 0.494915 Gt(W) 0.000000 0.048547 0.106579 0.154875 0.265696 0.014938 0.409365 ----- ----- ----- ----- ----- ----- ----- Potentials -763902. -632473. -1641148. -740410. -308430. -416993. -885324. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 164 converged, 158 successes so far. Misfit function evaluations this try => 147 Misfit this try = 1.985047E-06 Best Misfit so far = 1.985047E-06 obtained on Try 164 Prior probability, PP = 1.803439E-07 Bayes score, PP * exp(-Misfit) = 1.803436E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 6287.26 1118.49 0.198509 6.827448E-02 0.931726 Final coordinates: 9827.00 995.800 0.131220 5.094635E-02 0.949054 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.985047E-6 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 5.144 0.013474 0.140387 0.007332 0.217895 0.117052 0.503859 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 1.5E-02 -0.2 -9.8E-03 -0.1 0.3 0.1 Chi 4.6E-09 7.6E-07 2.0E-08 4.8E-08 1.1E-06 9.2E-09 Composition Misfit: 1.974427E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 94.856 0.000000 0.052131 0.124881 0.157319 0.243840 0.421830 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 2.0E-02 -2.5E-03 4.6E-03 -1.9E-02 -1.1E-03 Chi 0. 8.0E-09 7.9E-11 3.3E-10 2.2E-09 3.3E-12 Composition Misfit: 1.062064E-08 *mole fractions relative to measured components, complete compositions below Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000682 0.056192 0.117970 0.159167 0.235542 0.007727 0.422720 Augite(G) 0.013389 0.139502 0.007286 0.216522 0.116314 0.006303 0.500684 Gt(W) 0.000000 0.051724 0.123906 0.156091 0.241937 0.007803 0.418539 ----- ----- ----- ----- ----- ----- ----- Potentials -736458. -631302. -1654903. -735545. -309985. -482561. -901351. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 165 converged, 159 successes so far. Misfit function evaluations this try => 130 Misfit this try = 3.710760E-03 Best Misfit so far = 1.985047E-06 obtained on Try 164 Prior probability, PP = 5.158875E-09 Bayes score, PP * exp(-Misfit) = 5.139767E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18774.6 1152.52 0.871375 0.636494 0.363506 Final coordinates: 19443.9 1199.66 0.206898 0.948371 5.162866E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.680954E-3 Extraneous predicted phases: 2.980613E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 95.310 0.013420 0.139415 0.008211 0.216619 0.118688 0.503646 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.1 0.5 -0.7 1. -1. 0.2 Chi 2.9E-07 3.0E-06 9.7E-05 6.4E-06 1.4E-05 1.6E-07 Composition Misfit: 1.200275E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 4.683 0.000000 0.057092 0.117947 0.175583 0.230148 0.419230 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -5. 6. -1.2E+01 1.1E+01 2. Chi 0. 4.3E-04 4.1E-04 1.9E-03 8.1E-04 1.6E-05 Composition Misfit: 3.560926E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.007 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.012704 0.134659 0.013304 0.213303 0.123153 0.006370 0.496506 Augite(G) 0.013337 0.138558 0.008160 0.215287 0.117958 0.006151 0.500549 Gt(W) 0.000000 0.056477 0.116676 0.173690 0.227667 0.010781 0.414711 ----- ----- ----- ----- ----- ----- ----- Potentials -809888. -653293. -1676484. -751472. -337915. -436121. -893922. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 166 converged, 160 successes so far. Misfit function evaluations this try => 132 Misfit this try = 7.508064E-04 Best Misfit so far = 1.985047E-06 obtained on Try 164 Prior probability, PP = 1.259200E-08 Bayes score, PP * exp(-Misfit) = 1.258255E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 3372.73 1159.22 0.315875 0.181175 0.818825 Final coordinates: 18303.6 1162.07 0.153273 0.448161 0.551839 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.508064E-4 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 43.925 0.013810 0.138129 0.006358 0.214242 0.120822 0.506639 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.6 1. 0.8 3. -3. -2. Chi 7.8E-06 2.7E-05 1.5E-04 5.9E-05 9.6E-05 1.5E-05 Composition Misfit: 3.497598E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 56.075 0.000000 0.055319 0.123400 0.161233 0.238773 0.421275 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 1. -2. 4. 0.5 Chi 0. 1.8E-04 1.8E-05 9.5E-05 1.1E-04 7.3E-07 Composition Misfit: 4.010466E-04 *mole fractions relative to measured components, complete compositions below Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005999 0.090897 0.071679 0.183112 0.185836 0.007121 0.455357 Augite(G) 0.013735 0.137380 0.006324 0.213081 0.120167 0.005419 0.503894 Gt(W) 0.000000 0.054852 0.122358 0.159872 0.236758 0.008441 0.417719 ----- ----- ----- ----- ----- ----- ----- Potentials -740314. -635209. -1671409. -734351. -317754. -507837. -907057. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 167 converged, 161 successes so far. Misfit function evaluations this try => 135 Misfit this try = 5.387444E-04 Best Misfit so far = 1.985047E-06 obtained on Try 164 Prior probability, PP = 3.297518E-08 Bayes score, PP * exp(-Misfit) = 3.295742E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18446.6 780.620 0.370004 0.164141 0.835859 Final coordinates: 16382.7 1127.11 0.141410 0.257918 0.742082 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.387329E-4 Extraneous predicted phases: 1.150422E-8 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 25.370 0.013785 0.136972 0.006377 0.214563 0.121899 0.506405 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.6 2. 0.8 3. -4. -2. Chi 6.6E-06 7.0E-05 1.4E-04 4.9E-05 1.6E-04 1.2E-05 Composition Misfit: 4.414510E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 74.630 0.000000 0.053860 0.124305 0.158874 0.241347 0.421614 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 0.5 -1. 2. 0.2 Chi 0. 5.4E-05 2.6E-06 1.5E-05 2.5E-05 1.1E-07 Composition Misfit: 9.728194E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.003451 0.074270 0.093856 0.171640 0.209650 0.007412 0.439720 Augite(G) 0.013709 0.136217 0.006342 0.213381 0.121227 0.005511 0.503614 Gt(W) 0.000000 0.053426 0.123304 0.157595 0.239404 0.008051 0.418220 ----- ----- ----- ----- ----- ----- ----- Potentials -795873. -648724. -1668095. -748894. -330191. -447670. -891809. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Augite(G) q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Augite(G) q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 169 converged, 162 successes so far. Misfit function evaluations this try => 297 Misfit this try = 3.802121E-07 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.768689E-07 Bayes score, PP * exp(-Misfit) = 1.768688E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2304.59 763.476 0.179647 0.789788 0.210212 Final coordinates: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.530318E-7 Extraneous predicted phases: 2.271803E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 96.318 0.013481 0.140055 0.007330 0.217785 0.117428 0.503920 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 1.6E-03 4.5E-03 -8.1E-03 7.0E-03 -1.0E-02 5.8E-03 Chi 5.5E-11 2.8E-10 1.4E-08 2.6E-10 1.2E-09 1.1E-10 Composition Misfit: 1.577704E-08 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 3.681 0.000000 0.052174 0.124826 0.157442 0.243747 0.421810 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2.2E-02 4.1E-02 -0.1 0.1 1.8E-02 Chi 0. 1.0E-08 2.1E-08 8.6E-08 2.0E-08 8.7E-10 Composition Misfit: 1.372548E-07 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.012898 0.135923 0.011622 0.214176 0.121347 0.006336 0.497698 Augite(G) 0.013396 0.139176 0.007284 0.216418 0.116691 0.006278 0.500756 Gt(W) 0.000000 0.051766 0.123850 0.156210 0.241839 0.007827 0.418509 ----- ----- ----- ----- ----- ----- ----- Potentials -777795. -641767. -1655522. -745854. -320578. -442340. -891319. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Augite(G) q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Augite(G) q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 171 converged, 163 successes so far. Misfit function evaluations this try => 150 Misfit this try = 1.393828E-03 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.233323E-07 Bayes score, PP * exp(-Misfit) = 1.231605E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 6023.94 875.184 0.112950 0.881387 0.118613 Final coordinates: 5326.65 893.735 0.189773 0.832287 0.167713 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.392549E-3 Extraneous predicted phases: 1.278664E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 83.651 0.013436 0.140691 0.007043 0.219293 0.116139 0.503399 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.1 -0.4 0.2 -1. 1. 0.4 Chi 1.5E-07 2.8E-06 1.1E-05 1.0E-05 1.4E-05 5.6E-07 Composition Misfit: 3.880272E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 16.348 0.000000 0.047454 0.128298 0.148706 0.252430 0.423112 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 5. -3. 5. -7. -1. Chi 0. 4.6E-04 9.1E-05 5.0E-04 2.9E-04 3.9E-06 Composition Misfit: 1.353746E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.183731 0.000000 0.000000 0.482936 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.011147 0.124499 0.026859 0.206295 0.137710 0.006533 0.486956 Augite(G) 0.013348 0.139766 0.006996 0.217851 0.115375 0.006574 0.500089 Gt(W) 0.000000 0.047153 0.127486 0.147765 0.250833 0.006329 0.420434 ----- ----- ----- ----- ----- ----- ----- Potentials -734001. -629210. -1645445. -736030. -305003. -471433. -897126. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 172 converged, 164 successes so far. Misfit function evaluations this try => 183 Misfit this try = 1.733739E-05 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.639942E-07 Bayes score, PP * exp(-Misfit) = 1.639913E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9113.79 1169.91 0.463689 5.175858E-02 0.948241 Final coordinates: 10834.0 1017.45 0.134749 0.127178 0.872822 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.629513E-5 Extraneous predicted phases: 1.042257E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 12.761 0.013546 0.139473 0.007117 0.217261 0.118210 0.504393 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.1 0.4 0.2 0.5 -0.7 -0.4 Chi 3.0E-07 2.5E-06 5.8E-06 1.3E-06 5.3E-06 4.3E-07 Composition Misfit: 1.561212E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 87.238 0.000000 0.052297 0.124828 0.157447 0.243618 0.421810 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.1 4.0E-02 -0.1 0.2 1.8E-02 Chi 0. 4.1E-07 2.0E-08 9.2E-08 1.6E-07 8.2E-10 Composition Misfit: 6.830087E-07 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.001702 0.062849 0.109090 0.163760 0.226007 0.007614 0.428979 Augite(G) 0.013462 0.138616 0.007074 0.215926 0.117484 0.006145 0.501293 Gt(W) 0.000000 0.051888 0.123851 0.156214 0.241711 0.007826 0.418509 ----- ----- ----- ----- ----- ----- ----- Potentials -779987. -642656. -1657113. -746251. -321759. -443348. -891404. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 173 converged, 165 successes so far. Misfit function evaluations this try => 83 Misfit this try = 9.679734E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.529812E-08 Bayes score, PP * exp(-Misfit) = 1.528331E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17595.7 1163.08 9.450888E-02 0.141192 0.858808 Final coordinates: 18094.2 1151.27 0.133699 0.104102 0.895898 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.649261E-4 Extraneous predicted phases: 3.047280E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 10.161 0.013900 0.135247 0.005950 0.213739 0.123950 0.507214 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.8 3. 1. 4. -6. -3. Chi 1.3E-05 1.7E-04 3.2E-04 7.7E-05 3.4E-04 2.1E-05 Composition Misfit: 9.423338E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 89.837 0.000000 0.053000 0.124624 0.157996 0.242647 0.421734 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.8 0.2 -0.4 1. 0.1 Chi 0. 1.4E-05 5.2E-07 2.8E-06 5.6E-06 2.1E-08 Composition Misfit: 2.259233E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.003 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.001393 0.060834 0.111778 0.162369 0.228893 0.007651 0.427083 Augite(G) 0.013827 0.134530 0.005918 0.212606 0.123293 0.005303 0.504524 Gt(W) 0.000000 0.052580 0.123638 0.156745 0.240726 0.007914 0.418396 ----- ----- ----- ----- ----- ----- ----- Potentials -798653. -649812. -1669964. -748879. -331449. -449806. -890906. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 174 converged, 166 successes so far. Misfit function evaluations this try => 145 Misfit this try = 9.490937E-05 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.261027E-07 Bayes score, PP * exp(-Misfit) = 1.260907E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10667.8 1106.50 0.101379 0.682526 0.317474 Final coordinates: 12340.6 1049.50 0.155095 0.473098 0.526902 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.456997E-5 Extraneous predicted phases: 3.393965E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 47.149 0.013591 0.139405 0.007014 0.216623 0.118536 0.504830 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.2 0.5 0.2 1. -1. -0.7 Chi 8.8E-07 3.1E-06 1.3E-05 6.3E-06 1.1E-05 1.6E-06 Composition Misfit: 3.580898E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 52.850 0.000000 0.053364 0.124305 0.158796 0.241921 0.421614 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 0.5 -0.9 2. 0.2 Chi 0. 2.8E-05 2.6E-06 1.4E-05 1.5E-05 1.1E-07 Composition Misfit: 5.876099E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.006333 0.093077 0.068771 0.184615 0.182713 0.007084 0.457406 Augite(G) 0.013510 0.138570 0.006972 0.215326 0.117826 0.005989 0.501806 Gt(W) 0.000000 0.052934 0.123304 0.157518 0.239973 0.008051 0.418220 ----- ----- ----- ----- ----- ----- ----- Potentials -784904. -644424. -1660323. -747131. -324361. -443711. -891695. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 175 converged, 167 successes so far. Misfit function evaluations this try => 130 Misfit this try = 6.437858E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 5.317409E-08 Bayes score, PP * exp(-Misfit) = 5.313987E-08 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 6721.48 1161.94 8.880096E-02 6.511062E-02 0.934889 Final coordinates: 15451.5 1100.34 0.129372 8.291566E-03 0.991708 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.413874E-4 Extraneous predicted phases: 2.398436E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.815 0.013816 0.136414 0.006018 0.214773 0.122323 0.506656 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.6 3. 1. 3. -4. -2. Chi 8.1E-06 9.8E-05 2.8E-04 4.2E-05 2.0E-04 1.5E-05 Composition Misfit: 6.413173E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.183 0.000000 0.052196 0.124866 0.157366 0.243747 0.421825 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -4.3E-02 8.9E-03 -2.5E-02 0.1 3.9E-03 Chi 0. 3.9E-08 9.8E-10 9.9E-09 2.0E-08 4.1E-11 Composition Misfit: 7.005990E-08 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.002 0.000000 0.187778 0.000000 0.000000 0.478888 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000111 0.052468 0.122937 0.156598 0.240877 0.007791 0.419218 Augite(G) 0.013740 0.135663 0.005985 0.213592 0.121650 0.005499 0.503870 Gt(W) 0.000000 0.051789 0.123891 0.156137 0.241843 0.007809 0.418531 ----- ----- ----- ----- ----- ----- ----- Potentials -738573. -633789. -1664724. -734439. -314297. -500707. -903840. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 176 converged, 168 successes so far. Misfit function evaluations this try => 226 Misfit this try = 2.058004E-06 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.725838E-07 Bayes score, PP * exp(-Misfit) = 1.725834E-07 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2115.28 680.687 0.197986 0.423516 0.576484 Final coordinates: 10341.5 1007.63 0.143175 0.288853 0.711147 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.778923E-6 Extraneous predicted phases: 2.790814E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 29.048 0.013497 0.139824 0.007299 0.217643 0.117689 0.504049 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -2.8E-02 0.2 1.7E-02 0.1 -0.2 -0.1 Chi 1.7E-08 4.0E-07 6.1E-08 1.0E-07 6.3E-07 2.9E-08 Composition Misfit: 1.242363E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 70.951 0.000000 0.052288 0.124834 0.157416 0.243650 0.421813 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.1 3.5E-02 -0.1 0.1 1.6E-02 Chi 0. 3.6E-07 1.5E-08 5.1E-08 1.1E-07 6.4E-10 Composition Misfit: 5.365600E-07 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.003866 0.076973 0.090251 0.173505 0.205778 0.007366 0.442262 Augite(G) 0.013413 0.138952 0.007254 0.216286 0.116955 0.006234 0.500906 Gt(W) 0.000000 0.051879 0.123857 0.156184 0.241744 0.007824 0.418513 ----- ----- ----- ----- ----- ----- ----- Potentials -778632. -642124. -1656158. -746031. -321052. -442741. -891401. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 177 converged, 169 successes so far. Misfit function evaluations this try => 187 Misfit this try = 9.353568E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 5.546352E-09 Bayes score, PP * exp(-Misfit) = 5.541166E-09 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 7773.53 1164.82 0.731970 0.242699 0.757301 Final coordinates: 19555.4 1190.75 0.151984 0.428579 0.571421 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.338136E-4 Extraneous predicted phases: 1.543205E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 41.973 0.013822 0.137205 0.006470 0.213727 0.122001 0.506774 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.6 2. 0.7 4. -4. -2. Chi 8.4E-06 5.9E-05 1.1E-04 7.7E-05 1.7E-04 1.6E-05 Composition Misfit: 4.451754E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 58.026 0.000000 0.055798 0.123359 0.161347 0.238236 0.421260 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 1. -3. 5. 0.5 Chi 0. 2.4E-04 1.9E-05 1.0E-04 1.3E-04 7.7E-07 Composition Misfit: 4.886382E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005737 0.089185 0.073962 0.181930 0.188287 0.007154 0.453745 Augite(G) 0.013748 0.136474 0.006435 0.212587 0.121351 0.005333 0.504072 Gt(W) 0.000000 0.055326 0.122316 0.159982 0.236221 0.008458 0.417697 ----- ----- ----- ----- ----- ----- ----- Potentials -805860. -652364. -1674923. -750710. -335601. -448141. -892541. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 178 converged, 170 successes so far. Misfit function evaluations this try => 289 Misfit this try = 10.3471 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 4.319216E-09 Bayes score, PP * exp(-Misfit) = 1.385888E-13 Best Bayes score so far = 1.822746E-07 obtained on Try 74 P_bar T_K C_O2 Cpx Gt Initial coordinates: 5862.56 905.202 0.713273 0.879446 0.120554 Final coordinates: 1129.66 1200.00 0.400855 0.999243 7.570928E-04 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.48533 Extraneous predicted phases: 7.86174 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 95.893 0.013943 0.144883 0.007660 0.225335 0.112391 0.495788 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.9 -3. -0.3 -7. 4. 6. Chi 1.5E-05 1.6E-04 1.5E-05 2.5E-04 2.2E-04 1.3E-04 Composition Misfit: 8.016772E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.008 0.000000 0.019110 0.006054 0.325457 0.272109 0.377270 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 3.2E+01 9.5E+01 -1.1E+02 -2.3E+01 4.2E+01 Chi 0. 0.1 2. 0.1 2.9E-03 5.3E-03 Composition Misfit: 2.48453 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 Sp(WPC) 0.780 0.000000 0.000710 0.000710 0.000000 0.855925 0.142654 0.000000 q 3.319 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013315 0.138365 0.007323 0.215213 0.116144 0.011639 0.498001 Augite(G) 0.013796 0.143357 0.007579 0.222961 0.111206 0.010536 0.490564 Gt(W) 0.000000 0.018031 0.005712 0.307078 0.256743 0.056472 0.355965 ----- ----- ----- ----- ----- ----- ----- Potentials -840738. -674598. -1767962. -767820. -366510. -376313. -936559. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 179 converged, 171 successes so far. Misfit function evaluations this try => 175 Misfit this try = 1.849080E-05 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.847562E-07 Bayes score, PP * exp(-Misfit) = 1.847528E-07 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17502.4 633.701 0.567499 0.793211 0.206789 Final coordinates: 9342.84 984.890 0.180591 0.755485 0.244515 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.828319E-5 Extraneous predicted phases: 2.076038E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 75.781 0.013472 0.140196 0.007293 0.218030 0.117186 0.503824 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 1.9E-02 -0.1 2.2E-02 -0.2 0.2 0.1 Chi 7.8E-09 1.3E-07 1.0E-07 2.6E-07 4.5E-07 2.1E-08 Composition Misfit: 9.747475E-07 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 24.218 0.000000 0.051538 0.125227 0.156454 0.244821 0.421960 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 0.6 -0.3 0.6 -0.8 -0.1 Chi 0. 7.3E-06 9.8E-07 4.9E-06 4.1E-06 4.1E-08 Composition Misfit: 1.730845E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 Fsp(C1) 0.001 0.079399 0.000000 0.170601 0.091202 0.000000 0.000000 0.658798 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.010118 0.117777 0.035825 0.201657 0.147336 0.006652 0.480635 Augite(G) 0.013386 0.139308 0.007247 0.216651 0.116444 0.006328 0.500636 Gt(W) 0.000000 0.051143 0.124269 0.155256 0.242947 0.007654 0.418731 ----- ----- ----- ----- ----- ----- ----- Potentials -771941. -640023. -1653850. -744534. -318367. -445673. -891912. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 180 converged, 172 successes so far. Misfit function evaluations this try => 242 Misfit this try = 1.94576 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 4.285812E-09 Bayes score, PP * exp(-Misfit) = 6.123494E-10 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 3175.11 1135.46 0.916374 0.765518 0.234482 Final coordinates: 19905.0 1199.50 0.323874 1.00000 2.033268E-07 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.226289 Extraneous predicted phases: 1.71947 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.320 0.013657 0.141880 0.007412 0.220606 0.118919 0.497526 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 -1. -0.1 -3. -1. 5. Chi 2.3E-06 2.3E-05 1.1E-06 3.6E-05 1.9E-05 8.2E-05 Composition Misfit: 1.638979E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.009 0.000000 0.044125 0.039180 0.238563 0.288441 0.389692 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 8. 6.9E+01 -5.2E+01 -3.7E+01 3.0E+01 Chi 0. 1.5E-03 0.2 2.8E-02 6.9E-03 2.7E-03 Composition Misfit: 0.226125 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 1.671 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013355 0.138742 0.007251 0.215742 0.116311 0.009418 0.499182 Augite(G) 0.013527 0.140527 0.007341 0.218502 0.117785 0.009535 0.492783 Gt(W) 0.000000 0.042210 0.037480 0.228211 0.275925 0.043391 0.372783 ----- ----- ----- ----- ----- ----- ----- Potentials -825927. -653255. -1691069. -749839. -340171. -372692. -892859. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 181 converged, 173 successes so far. Misfit function evaluations this try => 393 Misfit this try = 6.035709E-03 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 5.442705E-09 Bayes score, PP * exp(-Misfit) = 5.409953E-09 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 4957.38 746.558 0.906925 0.298864 0.701136 Final coordinates: 19999.7 1177.78 0.215438 1.00000 2.080125E-09 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.028643E-3 Extraneous predicted phases: 7.066129E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.938 0.013490 0.140117 0.007257 0.217818 0.117353 0.503966 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -1.5E-02 -3.9E-02 0.1 -2.3E-02 0.1 -3.0E-02 Chi 5.1E-09 2.2E-08 5.5E-07 2.9E-09 3.4E-08 2.9E-09 Composition Misfit: 6.196028E-07 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.059 0.000000 0.052797 0.114581 0.185114 0.229539 0.417968 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.6 8. -1.8E+01 1.2E+01 4. Chi 0. 7.9E-06 9.3E-04 4.2E-03 8.9E-04 3.6E-05 Composition Misfit: 6.028023E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.003 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013397 0.139181 0.007274 0.216424 0.116679 0.006284 0.500761 Augite(G) 0.013405 0.139237 0.007211 0.216450 0.116616 0.006281 0.500800 Gt(W) 0.000000 0.052152 0.113181 0.182852 0.226735 0.012219 0.412861 ----- ----- ----- ----- ----- ----- ----- Potentials -806124. -650934. -1671260. -748197. -334693. -428753. -889905. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 182 converged, 174 successes so far. Misfit function evaluations this try => 194 Misfit this try = 1.038722E-03 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 8.211491E-09 Bayes score, PP * exp(-Misfit) = 8.202966E-09 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18943.6 1151.26 0.912037 9.832949E-02 0.901671 Final coordinates: 18523.1 1190.62 0.151060 0.415570 0.584430 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.038422E-3 Extraneous predicted phases: 2.996491E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 41.119 0.013690 0.135611 0.007255 0.213980 0.123619 0.505846 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.4 3. 0.1 4. -5. -2. Chi 3.2E-06 1.5E-04 5.9E-07 6.8E-05 3.1E-04 7.3E-06 Composition Misfit: 5.362104E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 58.880 0.000000 0.056177 0.123665 0.160617 0.238168 0.421374 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -4. 1. -2. 5. 0.4 Chi 0. 2.9E-04 1.2E-05 6.7E-05 1.3E-04 4.9E-07 Composition Misfit: 5.022118E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005562 0.088048 0.075479 0.181146 0.189916 0.007172 0.452677 Augite(G) 0.013615 0.134865 0.007215 0.212803 0.122939 0.005501 0.503063 Gt(W) 0.000000 0.055709 0.122635 0.159280 0.236185 0.008327 0.417866 ----- ----- ----- ----- ----- ----- ----- Potentials -806446. -653273. -1676779. -752124. -336609. -449976. -894862. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 183 converged, 175 successes so far. Misfit function evaluations this try => 190 Misfit this try = 1.034549E-05 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.758966E-07 Bayes score, PP * exp(-Misfit) = 1.758948E-07 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2183.89 642.009 6.522573E-02 0.933432 6.656794E-02 Final coordinates: 10250.0 1003.40 0.215375 0.999998 2.104761E-06 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.764279E-6 Extraneous predicted phases: 3.581212E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.965 0.013486 0.140093 0.007282 0.217816 0.117377 0.503946 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -8.7E-03 -2.3E-02 3.1E-02 -2.2E-02 3.4E-02 -1.4E-02 Chi 1.6E-09 7.1E-09 2.0E-07 2.6E-09 1.3E-08 6.5E-10 Composition Misfit: 2.297556E-07 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.033 0.000000 0.052206 0.124474 0.158179 0.243463 0.421678 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.1 0.3 -0.5 0.3 0.1 Chi 0. 5.7E-08 1.3E-06 4.6E-06 5.1E-07 5.4E-08 Composition Misfit: 6.534524E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013397 0.139181 0.007274 0.216424 0.116679 0.006282 0.500761 Augite(G) 0.013402 0.139213 0.007236 0.216448 0.116640 0.006282 0.500780 Gt(W) 0.000000 0.051789 0.123481 0.156917 0.241520 0.007978 0.418314 ----- ----- ----- ----- ----- ----- ----- Potentials -778134. -641794. -1655533. -745768. -320652. -441734. -891125. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 184 converged, 176 successes so far. Misfit function evaluations this try => 127 Misfit this try = 5.172790E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 4.907584E-08 Bayes score, PP * exp(-Misfit) = 4.905046E-08 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16665.6 766.979 0.850278 0.804690 0.195310 Final coordinates: 15333.7 1111.89 0.168667 0.637300 0.362700 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.134144E-4 Extraneous predicted phases: 3.864586E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 63.181 0.013640 0.139292 0.007024 0.215749 0.119015 0.505279 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 0.5 0.2 2. -1. -1. Chi 1.8E-06 4.3E-06 1.2E-05 1.9E-05 2.1E-05 3.6E-06 Composition Misfit: 6.299988E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 36.817 0.000000 0.055222 0.123037 0.162022 0.238580 0.421139 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 1. -3. 4. 0.7 Chi 0. 1.7E-04 2.8E-05 1.4E-04 1.1E-04 1.1E-06 Composition Misfit: 4.504145E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.003 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.008533 0.107437 0.049617 0.194522 0.162145 0.006837 0.470908 Augite(G) 0.013561 0.138484 0.006984 0.214498 0.118325 0.005801 0.502348 Gt(W) 0.000000 0.054747 0.121979 0.160629 0.236529 0.008597 0.417518 ----- ----- ----- ----- ----- ----- ----- Potentials -794610. -647927. -1666730. -748871. -329584. -443607. -892336. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 185 converged, 177 successes so far. Misfit function evaluations this try => 183 Misfit this try = 1.571618E-05 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.837775E-07 Bayes score, PP * exp(-Misfit) = 1.837746E-07 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18275.8 714.109 0.880741 0.142723 0.857277 Final coordinates: 9379.68 986.770 0.130597 3.681874E-02 0.963181 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.526391E-5 Extraneous predicted phases: 4.522694E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 3.732 0.013427 0.140626 0.007534 0.218276 0.116634 0.503503 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.1 -0.4 -0.2 -0.4 0.7 0.3 Chi 2.2E-07 2.3E-06 6.1E-06 1.1E-06 5.2E-06 3.6E-07 Composition Misfit: 1.522330E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 96.267 0.000000 0.052115 0.124889 0.157299 0.243864 0.421833 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 3.5E-02 -8.9E-03 1.7E-02 -3.9E-02 -3.9E-03 Chi 0. 2.6E-08 9.8E-10 4.6E-09 9.5E-09 4.1E-11 Composition Misfit: 4.060481E-08 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.198213 0.000000 0.000000 0.468454 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000493 0.054959 0.119615 0.158316 0.237309 0.007748 0.421560 Augite(G) 0.013341 0.139727 0.007486 0.216880 0.115888 0.006394 0.500284 Gt(W) 0.000000 0.051708 0.123914 0.156072 0.241962 0.007800 0.418543 ----- ----- ----- ----- ----- ----- ----- Potentials -736175. -631058. -1654032. -735597. -309585. -481041. -901103. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 186 converged, 178 successes so far. Misfit function evaluations this try => 549 Misfit this try = 1.93202 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 4.180631E-09 Bayes score, PP * exp(-Misfit) = 6.055856E-10 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17831.9 908.498 0.903380 0.321334 0.678666 Final coordinates: 19968.5 1199.37 0.323620 0.999977 2.333236E-05 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.220365 Extraneous predicted phases: 1.71166 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.332 0.013655 0.141867 0.007417 0.220599 0.118931 0.497531 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 -1. -0.1 -3. -1. 5. Chi 2.2E-06 2.3E-05 1.3E-06 3.6E-05 1.9E-05 8.2E-05 Composition Misfit: 1.636472E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.002 0.000000 0.044510 0.039742 0.237335 0.288510 0.389903 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 7. 6.8E+01 -5.1E+01 -3.7E+01 3.0E+01 Chi 0. 1.3E-03 0.2 2.7E-02 6.9E-03 2.6E-03 Composition Misfit: 0.220201 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 1.667 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013355 0.138741 0.007254 0.215742 0.116314 0.009410 0.499183 Augite(G) 0.013525 0.140515 0.007346 0.218497 0.117797 0.009530 0.492790 Gt(W) 0.000000 0.042589 0.038026 0.227090 0.276056 0.043166 0.373073 ----- ----- ----- ----- ----- ----- ----- Potentials -825814. -653161. -1690705. -749772. -340040. -372969. -892699. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 187 converged, 179 successes so far. Misfit function evaluations this try => 215 Misfit this try = 9.835318E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 4.981916E-09 Bayes score, PP * exp(-Misfit) = 4.977018E-09 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17350.1 929.897 0.328947 0.477711 0.522289 Final coordinates: 19660.7 1195.72 0.152278 0.432803 0.567197 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.818091E-4 Extraneous predicted phases: 1.722740E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 42.433 0.013807 0.136962 0.006566 0.213672 0.122324 0.506668 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.6 2. 0.6 4. -4. -2. Chi 7.7E-06 7.0E-05 8.7E-05 7.9E-05 2.0E-04 1.5E-05 Composition Misfit: 4.555805E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 57.565 0.000000 0.055973 0.123357 0.161413 0.237998 0.421259 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -4. 1. -3. 5. 0.5 Chi 0. 2.6E-04 1.9E-05 1.0E-04 1.4E-04 7.7E-07 Composition Misfit: 5.262286E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005793 0.089554 0.073469 0.182185 0.187758 0.007148 0.454092 Augite(G) 0.013733 0.136229 0.006531 0.212529 0.121670 0.005351 0.503957 Gt(W) 0.000000 0.055500 0.122313 0.160048 0.235985 0.008459 0.417695 ----- ----- ----- ----- ----- ----- ----- Potentials -806775. -652787. -1675754. -751055. -336159. -448573. -892932. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 188 converged, 180 successes so far. Misfit function evaluations this try => 139 Misfit this try = 7.609586E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.397817E-08 Bayes score, PP * exp(-Misfit) = 1.396753E-08 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 4005.38 644.386 0.674309 0.122413 0.877587 Final coordinates: 18178.9 1156.73 0.156347 0.490110 0.509890 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.606628E-4 Extraneous predicted phases: 2.957848E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 48.006 0.013814 0.138783 0.006292 0.214401 0.120064 0.506646 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.6 0.9 0.8 3. -2. -2. Chi 8.0E-06 1.2E-05 1.7E-04 5.4E-05 5.8E-05 1.5E-05 Composition Misfit: 3.142980E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 51.993 0.000000 0.055312 0.123163 0.161805 0.238534 0.421186 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 1. -3. 4. 0.6 Chi 0. 1.8E-04 2.4E-05 1.2E-04 1.2E-04 9.8E-07 Composition Misfit: 4.463648E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.006561 0.094565 0.066787 0.185642 0.180583 0.007058 0.458805 Augite(G) 0.013739 0.138029 0.006258 0.213235 0.119411 0.005435 0.503892 Gt(W) 0.000000 0.054839 0.122111 0.160423 0.236496 0.008542 0.417588 ----- ----- ----- ----- ----- ----- ----- Potentials -800650. -650042. -1670526. -749274. -332505. -445717. -891391. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 189 converged, 181 successes so far. Misfit function evaluations this try => 125 Misfit this try = 5.635397E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.565325E-07 Bayes score, PP * exp(-Misfit) = 1.564443E-07 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 5048.00 755.834 0.288785 0.491043 0.508957 Final coordinates: 6571.22 924.676 0.184625 0.790541 0.209459 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.632840E-4 Extraneous predicted phases: 2.556817E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 79.619 0.013414 0.140377 0.007327 0.218959 0.116625 0.503298 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.1 -0.2 -5.3E-03 -1. 0.7 0.5 Chi 3.4E-07 7.1E-07 5.9E-09 6.2E-06 5.4E-06 7.9E-07 Composition Misfit: 1.342507E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 20.380 0.000000 0.049223 0.127133 0.151649 0.249320 0.422675 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 3. -2. 4. -5. -0.8 Chi 0. 1.7E-04 4.0E-05 2.1E-04 1.2E-04 1.7E-06 Composition Misfit: 5.498589E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.000 0.000000 0.188208 0.000000 0.000000 0.478458 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.010588 0.120845 0.031733 0.203774 0.142943 0.006598 0.483520 Augite(G) 0.013327 0.139460 0.007279 0.217527 0.115863 0.006537 0.500008 Gt(W) 0.000000 0.048887 0.126264 0.150613 0.247617 0.006832 0.419787 ----- ----- ----- ----- ----- ----- ----- Potentials -734912. -629941. -1648374. -736065. -306623. -474540. -898539. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 190 converged, 182 successes so far. Misfit function evaluations this try => 239 Misfit this try = 7.601396E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.175084E-08 Bayes score, PP * exp(-Misfit) = 1.174191E-08 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2698.41 990.006 0.911440 0.259242 0.740758 Final coordinates: 18315.5 1167.60 0.151438 0.421250 0.578750 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.599649E-4 Extraneous predicted phases: 1.746611E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 41.357 0.013791 0.137429 0.006525 0.214141 0.121598 0.506517 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.6 2. 0.6 3. -4. -2. Chi 6.9E-06 5.0E-05 9.7E-05 6.2E-05 1.4E-04 1.3E-05 Composition Misfit: 3.735906E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 58.642 0.000000 0.055407 0.123547 0.160855 0.238861 0.421330 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 1. -2. 4. 0.5 Chi 0. 1.9E-04 1.4E-05 7.7E-05 1.0E-04 5.9E-07 Composition Misfit: 3.863743E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005639 0.088544 0.074817 0.181488 0.189205 0.007163 0.453144 Augite(G) 0.013716 0.136683 0.006489 0.212980 0.120938 0.005424 0.503769 Gt(W) 0.000000 0.054942 0.122512 0.159507 0.236860 0.008377 0.417801 ----- ----- ----- ----- ----- ----- ----- Potentials -802393. -651065. -1672513. -750155. -333737. -447643. -892438. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 191 converged, 183 successes so far. Misfit function evaluations this try => 77 Misfit this try = 7.600997E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.354392E-08 Bayes score, PP * exp(-Misfit) = 1.353363E-08 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17802.4 1162.14 0.162128 0.196790 0.803210 Final coordinates: 18277.1 1156.55 0.141918 0.266582 0.733418 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.597110E-4 Extraneous predicted phases: 3.887279E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 26.052 0.013867 0.136824 0.006081 0.213928 0.122250 0.507051 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.7 2. 1. 4. -4. -2. Chi 1.1E-05 7.7E-05 2.5E-04 7.0E-05 1.9E-04 1.9E-05 Composition Misfit: 6.201565E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 73.947 0.000000 0.054163 0.124137 0.159284 0.240864 0.421552 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 0.6 -1. 2. 0.3 Chi 0. 7.5E-05 4.4E-06 2.4E-05 3.6E-05 1.8E-07 Composition Misfit: 1.395545E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.003567 0.075027 0.092847 0.172162 0.208566 0.007400 0.440432 Augite(G) 0.013793 0.136095 0.006048 0.212788 0.121599 0.005326 0.504350 Gt(W) 0.000000 0.053723 0.123129 0.157990 0.238908 0.008123 0.418127 ----- ----- ----- ----- ----- ----- ----- Potentials -799988. -650054. -1670502. -749140. -332147. -448337. -891147. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 192 converged, 184 successes so far. Misfit function evaluations this try => 208 Misfit this try = 8.798895E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.315021E-07 Bayes score, PP * exp(-Misfit) = 1.313865E-07 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13233.8 637.734 4.821374E-02 0.688539 0.311461 Final coordinates: 5622.19 910.731 0.178026 0.731895 0.268105 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 8.743005E-4 Extraneous predicted phases: 5.589009E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 74.479 0.013284 0.139781 0.007987 0.219565 0.117044 0.502339 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.4 0.2 -0.5 -2. 0.3 1. Chi 3.0E-06 5.6E-07 5.6E-05 1.4E-05 1.2E-06 5.0E-06 Composition Misfit: 7.971733E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 25.518 0.000000 0.049279 0.127877 0.149681 0.250210 0.422954 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 3. -2. 5. -5. -1. Chi 0. 1.7E-04 7.0E-05 3.9E-04 1.6E-04 3.0E-06 Composition Misfit: 7.945832E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 Fsp(C1) 0.003 0.081761 0.000000 0.168239 0.086479 0.000000 0.000000 0.663521 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.009801 0.115713 0.038578 0.200233 0.150293 0.006689 0.478693 Augite(G) 0.013194 0.138838 0.007933 0.218083 0.116254 0.006751 0.498947 Gt(W) 0.000000 0.048958 0.127044 0.148706 0.248580 0.006511 0.420200 ----- ----- ----- ----- ----- ----- ----- Potentials -737447. -630595. -1647619. -737318. -307044. -470591. -898068. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 193 converged, 185 successes so far. Misfit function evaluations this try => 269 Misfit this try = 1.93755 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 4.225994E-09 Bayes score, PP * exp(-Misfit) = 6.087792E-10 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 3238.64 810.087 0.832856 0.272802 0.727198 Final coordinates: 19922.8 1200.00 0.323642 1.00000 9.881165E-12 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.225412 Extraneous predicted phases: 1.71214 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.330 0.013656 0.141871 0.007414 0.220601 0.118925 0.497534 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 -1. -0.1 -3. -1. 5. Chi 2.2E-06 2.3E-05 1.2E-06 3.6E-05 1.9E-05 8.2E-05 Composition Misfit: 1.635081E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.003 0.000000 0.043833 0.039292 0.238557 0.288584 0.389734 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 8. 6.9E+01 -5.2E+01 -3.7E+01 3.0E+01 Chi 0. 1.6E-03 0.2 2.8E-02 6.9E-03 2.6E-03 Composition Misfit: 0.225248 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 1.667 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013355 0.138743 0.007251 0.215743 0.116312 0.009411 0.499185 Augite(G) 0.013526 0.140519 0.007343 0.218498 0.117792 0.009530 0.492793 Gt(W) 0.000000 0.041933 0.037589 0.228217 0.276075 0.043346 0.372841 ----- ----- ----- ----- ----- ----- ----- Potentials -825906. -653334. -1691095. -749832. -340242. -372725. -892882. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 194 converged, 186 successes so far. Misfit function evaluations this try => 166 Misfit this try = 3.650306E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.711343E-07 Bayes score, PP * exp(-Misfit) = 1.710719E-07 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8561.94 640.040 0.695432 0.897103 0.102897 Final coordinates: 7305.74 942.581 0.187077 0.810443 0.189557 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.619925E-4 Extraneous predicted phases: 3.038079E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 81.544 0.013423 0.140173 0.007383 0.218657 0.116955 0.503409 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.1 -0.1 -0.1 -0.8 0.4 0.4 Chi 2.6E-07 8.9E-08 5.4E-07 3.4E-06 1.8E-06 5.3E-07 Composition Misfit: 6.651514E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 18.453 0.000000 0.050029 0.126789 0.152426 0.248210 0.422546 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 2. -2. 3. -4. -0.7 Chi 0. 9.0E-05 2.9E-05 1.6E-04 7.8E-05 1.2E-06 Composition Misfit: 3.553410E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 Fsp(C1) 0.002 0.080953 0.000000 0.169047 0.088093 0.000000 0.000000 0.661907 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.010854 0.122587 0.029410 0.204976 0.140448 0.006569 0.485157 Augite(G) 0.013336 0.139265 0.007335 0.217241 0.116198 0.006474 0.500150 Gt(W) 0.000000 0.049680 0.125904 0.151362 0.246477 0.006981 0.419596 ----- ----- ----- ----- ----- ----- ----- Potentials -753094. -634786. -1650110. -740501. -311974. -459170. -894942. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 195 converged, 187 successes so far. Misfit function evaluations this try => 139 Misfit this try = 2.018896E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.697912E-07 Bayes score, PP * exp(-Misfit) = 1.697569E-07 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 4157.52 670.065 5.576989E-02 0.243700 0.756300 Final coordinates: 7179.64 936.722 0.144607 0.314319 0.685681 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.996107E-4 Extraneous predicted phases: 2.278969E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 32.149 0.013276 0.141563 0.007996 0.219630 0.115278 0.502257 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.4 -1. -0.5 -2. 2. 1. Chi 3.2E-06 1.6E-05 5.7E-05 1.5E-05 4.0E-05 5.6E-06 Composition Misfit: 1.367837E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 67.850 0.000000 0.050815 0.125405 0.156036 0.245718 0.422027 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 1. -0.4 0.8 -2. -0.2 Chi 0. 3.5E-05 2.2E-06 1.1E-05 1.5E-05 9.3E-08 Composition Misfit: 6.282691E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.197924 0.000000 0.000000 0.468742 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.004207 0.079199 0.087283 0.175040 0.202592 0.007324 0.444356 Augite(G) 0.013186 0.140602 0.007942 0.218140 0.114496 0.006783 0.498851 Gt(W) 0.000000 0.050430 0.124454 0.154853 0.243856 0.007578 0.418829 ----- ----- ----- ----- ----- ----- ----- Potentials -734461. -629686. -1649067. -735594. -307054. -473669. -899164. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 196 converged, 188 successes so far. Misfit function evaluations this try => 110 Misfit this try = 2.140703E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.078092E-07 Bayes score, PP * exp(-Misfit) = 1.077861E-07 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 11292.3 1049.00 0.286202 0.130618 0.869382 Final coordinates: 13101.6 1061.35 0.131932 6.672823E-02 0.933272 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.139772E-4 Extraneous predicted phases: 9.312658E-8 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 6.623 0.013691 0.137917 0.006573 0.215942 0.120304 0.505573 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.4 2. 0.6 2. -2. -1. Chi 3.2E-06 3.3E-05 8.5E-05 1.6E-05 6.9E-05 5.4E-06 Composition Misfit: 2.120453E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 93.377 0.000000 0.052398 0.124802 0.157523 0.243476 0.421801 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.2 0.1 -0.1 0.3 2.7E-02 Chi 0. 1.2E-06 4.5E-08 2.5E-07 4.8E-07 1.9E-09 Composition Misfit: 1.931875E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000893 0.057570 0.116131 0.160118 0.233568 0.007704 0.424015 Augite(G) 0.013612 0.137117 0.006535 0.214688 0.119606 0.005804 0.502639 Gt(W) 0.000000 0.051987 0.123824 0.156288 0.241568 0.007837 0.418495 ----- ----- ----- ----- ----- ----- ----- Potentials -786137. -645043. -1661370. -747175. -324934. -445839. -891354. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 197 converged, 189 successes so far. Misfit function evaluations this try => 675 Misfit this try = 5.206016E-03 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 8.702497E-09 Bayes score, PP * exp(-Misfit) = 8.657310E-09 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2074.23 1087.07 6.936394E-02 0.651345 0.348655 Final coordinates: 19181.0 1166.24 0.216308 0.999704 2.963130E-04 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.015158E-3 Extraneous predicted phases: 1.908582E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.981 0.013480 0.140055 0.007355 0.217804 0.117468 0.503838 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 3.7E-03 4.4E-03 -2.8E-02 -1.1E-02 -4.4E-02 0.1 Chi 3.0E-10 2.7E-10 1.6E-07 6.3E-10 2.3E-08 1.6E-08 Composition Misfit: 2.015609E-07 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.001 0.000000 0.053712 0.115188 0.182151 0.230753 0.418195 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 8. -1.6E+01 1.1E+01 3. Chi 0. 4.5E-05 8.2E-04 3.4E-03 7.4E-04 3.2E-05 Composition Misfit: 5.014956E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.018 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013393 0.139151 0.007309 0.216400 0.116713 0.006311 0.500723 Augite(G) 0.013395 0.139171 0.007308 0.216430 0.116727 0.006312 0.500657 Gt(W) 0.000000 0.053070 0.113810 0.179973 0.227993 0.011961 0.413194 ----- ----- ----- ----- ----- ----- ----- Potentials -804349. -650405. -1670365. -748271. -333956. -428886. -890310. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 198 converged, 190 successes so far. Misfit function evaluations this try => 1015 Misfit this try = 1.94935 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 4.234900E-09 Bayes score, PP * exp(-Misfit) = 6.029069E-10 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17915.0 681.409 0.942592 0.279818 0.720182 Final coordinates: 19917.7 1200.00 0.324015 1.00000 7.962436E-11 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.225438 Extraneous predicted phases: 1.72391 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.321 0.013657 0.141879 0.007413 0.220610 0.118926 0.497515 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 -1. -0.1 -3. -1. 5. Chi 2.2E-06 2.3E-05 1.2E-06 3.6E-05 1.9E-05 8.3E-05 Composition Misfit: 1.644987E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.006 0.000000 0.043911 0.039270 0.238085 0.289008 0.389726 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 8. 6.9E+01 -5.1E+01 -3.7E+01 3.0E+01 Chi 0. 1.5E-03 0.2 2.7E-02 7.1E-03 2.6E-03 Composition Misfit: 0.225273 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 1.673 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013355 0.138742 0.007251 0.215741 0.116310 0.009422 0.499180 Augite(G) 0.013527 0.140526 0.007342 0.218505 0.117791 0.009540 0.492768 Gt(W) 0.000000 0.042007 0.037567 0.227763 0.276478 0.043355 0.372830 ----- ----- ----- ----- ----- ----- ----- Potentials -826051. -653291. -1691070. -749871. -340229. -372754. -892894. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 199 converged, 191 successes so far. Misfit function evaluations this try => 156 Misfit this try = 1.014893E-03 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 6.512244E-09 Bayes score, PP * exp(-Misfit) = 6.505638E-09 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13296.7 1100.75 0.727886 0.385923 0.614077 Final coordinates: 19067.0 1193.07 0.143974 0.302594 0.697406 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.014522E-3 Extraneous predicted phases: 3.712790E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 29.771 0.013777 0.134862 0.006815 0.213587 0.124476 0.506484 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.5 4. 0.4 4. -6. -2. Chi 6.3E-06 2.0E-04 3.7E-05 8.3E-05 4.0E-04 1.3E-05 Composition Misfit: 7.402755E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 70.228 0.000000 0.055148 0.124010 0.159653 0.239686 0.421504 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 0.7 -1. 3. 0.3 Chi 0. 1.6E-04 6.1E-06 3.4E-05 7.1E-05 2.5E-07 Composition Misfit: 2.742464E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.004050 0.078174 0.088649 0.174333 0.204059 0.007345 0.443391 Augite(G) 0.013703 0.134140 0.006778 0.212442 0.123809 0.005358 0.503770 Gt(W) 0.000000 0.054697 0.122995 0.158348 0.237725 0.008178 0.418056 ----- ----- ----- ----- ----- ----- ----- Potentials -806108. -653152. -1676416. -751616. -336242. -451138. -893941. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 200 converged, 192 successes so far. Misfit function evaluations this try => 143 Misfit this try = 1.064562E-03 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 7.153713E-09 Bayes score, PP * exp(-Misfit) = 7.146101E-09 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18954.6 738.335 0.935501 8.469715E-02 0.915303 Final coordinates: 19495.8 1172.32 0.136266 0.157845 0.842155 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.061670E-3 Extraneous predicted phases: 2.892360E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 15.352 0.013939 0.135586 0.005802 0.213355 0.123752 0.507565 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.8 3. 1. 4. -5. -3. Chi 1.5E-05 1.5E-04 4.0E-04 9.2E-05 3.2E-04 2.6E-05 Composition Misfit: 1.002466E-03 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 84.646 0.000000 0.053496 0.124435 0.158499 0.241907 0.421663 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 0.4 -0.7 2. 0.2 Chi 0. 3.4E-05 1.6E-06 8.7E-06 1.5E-05 6.5E-08 Composition Misfit: 5.920382E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.002112 0.065528 0.105517 0.165607 0.222170 0.007569 0.431497 Augite(G) 0.013867 0.134882 0.005772 0.212246 0.123110 0.005194 0.504929 Gt(W) 0.000000 0.053068 0.123440 0.157232 0.239973 0.007995 0.418292 ----- ----- ----- ----- ----- ----- ----- Potentials -801503. -650707. -1671572. -749008. -332855. -450124. -890358. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 201 converged, 193 successes so far. Misfit function evaluations this try => 143 Misfit this try = 1.674593E-03 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 3.810912E-08 Bayes score, PP * exp(-Misfit) = 3.804535E-08 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15699.7 653.409 0.810231 0.773535 0.226465 Final coordinates: 15650.6 1130.48 0.206795 0.948088 5.191159E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.652234E-3 Extraneous predicted phases: 2.235890E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 95.521 0.013387 0.139225 0.008343 0.216893 0.118764 0.503389 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.2 0.6 -0.8 0.8 -1. 0.4 Chi 6.8E-07 5.0E-06 1.3E-04 3.7E-06 1.5E-05 5.8E-07 Composition Misfit: 1.506759E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 4.472 0.000000 0.056769 0.120938 0.167498 0.234444 0.420352 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -4. 3. -6. 8. 1. Chi 0. 3.8E-04 1.3E-04 6.2E-04 3.7E-04 5.2E-06 Composition Misfit: 1.501559E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.006 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.012701 0.134635 0.013337 0.213287 0.123189 0.006369 0.496483 Augite(G) 0.013303 0.138359 0.008291 0.215543 0.118025 0.006221 0.500258 Gt(W) 0.000000 0.056229 0.119789 0.165907 0.232217 0.009499 0.416359 ----- ----- ----- ----- ----- ----- ----- Potentials -798599. -649430. -1669525. -750158. -332117. -439641. -893889. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 202 converged, 194 successes so far. Misfit function evaluations this try => 143 Misfit this try = 2.550423E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 9.897033E-08 Bayes score, PP * exp(-Misfit) = 9.894509E-08 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14717.3 721.598 0.736668 0.210190 0.789810 Final coordinates: 13466.7 1066.90 0.132311 7.464655E-02 0.925353 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.543696E-4 Extraneous predicted phases: 6.727614E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 7.389 0.013725 0.137957 0.006447 0.215743 0.120329 0.505799 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.5 2. 0.7 2. -2. -1. Chi 4.3E-06 3.2E-05 1.2E-04 1.9E-05 7.1E-05 6.9E-06 Composition Misfit: 2.515772E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 92.610 0.000000 0.052444 0.124780 0.157576 0.243408 0.421793 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.3 0.1 -0.2 0.3 3.5E-02 Chi 0. 1.6E-06 7.6E-08 4.0E-07 6.9E-07 3.2E-09 Composition Misfit: 2.792412E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000999 0.058262 0.115209 0.160595 0.232578 0.007693 0.424665 Augite(G) 0.013646 0.137164 0.006410 0.214503 0.119638 0.005749 0.502891 Gt(W) 0.000000 0.052032 0.123801 0.156340 0.241498 0.007847 0.418483 ----- ----- ----- ----- ----- ----- ----- Potentials -786838. -645279. -1661766. -747191. -325272. -446055. -891180. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 203 converged, 195 successes so far. Misfit function evaluations this try => 173 Misfit this try = 1.350799E-05 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.746766E-07 Bayes score, PP * exp(-Misfit) = 1.746743E-07 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 14116.6 649.751 0.349111 0.952474 4.752579E-02 Final coordinates: 10092.5 1004.41 0.214244 0.994631 5.369285E-03 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.298211E-5 Extraneous predicted phases: 5.258785E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.566 0.013468 0.139972 0.007437 0.217738 0.117538 0.503847 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 2.5E-02 0.1 -0.1 5.0E-02 -0.1 0.1 Chi 1.3E-08 5.8E-08 1.8E-06 1.4E-08 1.3E-07 1.3E-08 Composition Misfit: 2.043907E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.434 0.000000 0.052630 0.124963 0.156361 0.244185 0.421861 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.5 -0.1 0.6 -0.3 -3.0E-02 Chi 0. 4.4E-06 5.8E-08 6.0E-06 5.6E-07 2.4E-09 Composition Misfit: 1.093820E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.197592 0.000000 0.000000 0.469075 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013325 0.138712 0.007901 0.216101 0.117353 0.006286 0.500322 Augite(G) 0.013384 0.139093 0.007390 0.216371 0.116800 0.006279 0.500683 Gt(W) 0.000000 0.052221 0.123992 0.155146 0.242289 0.007768 0.418584 ----- ----- ----- ----- ----- ----- ----- Potentials -737255. -631718. -1656006. -735859. -310633. -483836. -901858. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 204 converged, 196 successes so far. Misfit function evaluations this try => 449 Misfit this try = 6.553819E-03 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 5.191685E-09 Bayes score, PP * exp(-Misfit) = 5.157771E-09 Best Bayes score so far = 1.847528E-07 obtained on Try 179 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16399.4 632.283 6.944946E-02 0.165541 0.834459 Final coordinates: 19993.4 1181.79 0.215683 0.998978 1.022026E-03 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.492492E-3 Extraneous predicted phases: 6.132651E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.977 0.013471 0.139993 0.007427 0.217752 0.117540 0.503817 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 2.0E-02 4.8E-02 -0.1 3.8E-02 -0.1 0.1 Chi 9.0E-09 3.3E-08 1.5E-06 7.8E-09 1.3E-07 2.4E-08 Composition Misfit: 1.739529E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.013 0.000000 0.053217 0.114416 0.186056 0.228405 0.417906 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 8. -1.8E+01 1.3E+01 4. Chi 0. 2.1E-05 9.6E-04 4.4E-03 1.0E-03 3.7E-05 Composition Misfit: 6.490753E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.010 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013383 0.139090 0.007393 0.216360 0.116805 0.006298 0.500670 Augite(G) 0.013386 0.139112 0.007380 0.216380 0.116800 0.006298 0.500644 Gt(W) 0.000000 0.052563 0.113010 0.183769 0.225598 0.012290 0.412770 ----- ----- ----- ----- ----- ----- ----- Potentials -806979. -651326. -1672050. -748601. -335277. -428839. -890423. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 205 converged, 197 successes so far. Misfit function evaluations this try => 111 Misfit this try = 5.876079E-05 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.854813E-07 Bayes score, PP * exp(-Misfit) = 1.854704E-07 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 4544.40 901.138 0.373719 0.863287 0.136713 Final coordinates: 9005.96 978.355 0.205013 0.939330 6.067025E-02 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.839457E-5 Extraneous predicted phases: 3.662177E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 93.943 0.013488 0.140149 0.007209 0.217961 0.117245 0.503947 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -1.2E-02 -0.1 0.1 -0.2 0.1 -1.5E-02 Chi 3.1E-09 5.5E-08 1.7E-06 1.3E-07 2.5E-07 7.5E-10 Composition Misfit: 2.140521E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 6.056 0.000000 0.051438 0.125721 0.155204 0.245492 0.422145 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 0.7 -0.7 1. -1. -0.3 Chi 0. 9.9E-06 5.7E-06 2.9E-05 1.1E-05 2.4E-07 Composition Misfit: 5.625405E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.193827 0.000000 0.000000 0.472840 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.012583 0.133870 0.014360 0.212760 0.124288 0.006370 0.495768 Augite(G) 0.013403 0.139266 0.007164 0.216588 0.116506 0.006300 0.500772 Gt(W) 0.000000 0.051055 0.124785 0.154049 0.243666 0.007441 0.419004 ----- ----- ----- ----- ----- ----- ----- Potentials -736202. -631046. -1653320. -735752. -309177. -481045. -900609. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 206 converged, 198 successes so far. Misfit function evaluations this try => 432 Misfit this try = 6.120292E-03 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 5.832159E-09 Bayes score, PP * exp(-Misfit) = 5.796573E-09 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18944.4 634.395 0.841707 0.315768 0.684232 Final coordinates: 19876.3 1176.36 0.215542 0.999948 5.157566E-05 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.104118E-3 Extraneous predicted phases: 1.617323E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.963 0.013486 0.140090 0.007292 0.217809 0.117392 0.503932 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -7.7E-03 -2.1E-02 2.3E-02 -1.5E-02 2.1E-02 -3.2E-03 Chi 1.3E-09 6.0E-09 1.1E-07 1.2E-09 5.3E-09 3.3E-11 Composition Misfit: 1.232313E-07 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.032 0.000000 0.053066 0.114634 0.185197 0.229115 0.417988 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.9 8. -1.8E+01 1.2E+01 4. Chi 0. 1.6E-05 9.2E-04 4.2E-03 9.4E-04 3.5E-05 Composition Misfit: 6.103995E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.005 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013396 0.139176 0.007280 0.216420 0.116685 0.006288 0.500755 Augite(G) 0.013401 0.139210 0.007246 0.216439 0.116654 0.006286 0.500764 Gt(W) 0.000000 0.052419 0.113236 0.182938 0.226321 0.012197 0.412890 ----- ----- ----- ----- ----- ----- ----- Potentials -805791. -650867. -1671164. -748260. -334625. -428805. -890006. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Augite(G) q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Augite(G) q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 208 converged, 199 successes so far. Misfit function evaluations this try => 180 Misfit this try = 9.491962E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 2.752440E-08 Bayes score, PP * exp(-Misfit) = 2.749829E-08 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17401.4 969.337 0.351545 0.215441 0.784559 Final coordinates: 17099.2 1125.37 0.129213 4.657112E-03 0.995343 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.450376E-4 Extraneous predicted phases: 4.158552E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.456 0.013876 0.135762 0.005735 0.214148 0.123251 0.507228 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.7 3. 1. 3. -5. -3. Chi 1.1E-05 1.4E-04 4.4E-04 6.2E-05 2.8E-04 2.1E-05 Composition Misfit: 9.450073E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.542 0.000000 0.052179 0.124872 0.157354 0.243768 0.421827 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2.7E-02 4.6E-03 -1.8E-02 4.0E-02 2.0E-03 Chi 0. 1.5E-08 2.6E-10 5.0E-09 9.7E-09 1.1E-11 Composition Misfit: 3.028307E-08 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.002 0.000000 0.186056 0.000000 0.000000 0.480611 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000062 0.052151 0.123361 0.156379 0.241331 0.007796 0.418920 Augite(G) 0.013802 0.135038 0.005705 0.213007 0.122594 0.005331 0.504524 Gt(W) 0.000000 0.051772 0.123897 0.156126 0.241865 0.007807 0.418534 ----- ----- ----- ----- ----- ----- ----- Potentials -738418. -634067. -1666678. -733714. -314985. -505229. -903991. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Augite(G) q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Augite(G) q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Augite(G) q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Augite(G) q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 211 converged, 200 successes so far. Misfit function evaluations this try => 117 Misfit this try = 8.214173E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 8.832423E-09 Bayes score, PP * exp(-Misfit) = 8.825171E-09 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 18180.8 1119.49 0.616967 0.420808 0.579192 Final coordinates: 18968.3 1171.76 0.149719 0.396199 0.603801 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 8.199067E-4 Extraneous predicted phases: 1.510602E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 38.731 0.013849 0.137670 0.006200 0.213906 0.121427 0.506948 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.7 2. 0.9 4. -3. -2. Chi 9.8E-06 4.2E-05 2.0E-04 7.1E-05 1.3E-04 1.8E-05 Composition Misfit: 4.749565E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 61.268 0.000000 0.055154 0.123572 0.160805 0.239130 0.421339 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 1. -2. 4. 0.5 Chi 0. 1.6E-04 1.4E-05 7.5E-05 9.2E-05 5.7E-07 Composition Misfit: 3.449502E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.196741 0.000000 0.000000 0.469926 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005303 0.086355 0.077738 0.179978 0.192342 0.007199 0.451085 Augite(G) 0.013775 0.136935 0.006167 0.212765 0.120780 0.005334 0.504244 Gt(W) 0.000000 0.054693 0.122538 0.159459 0.237129 0.008367 0.417814 ----- ----- ----- ----- ----- ----- ----- Potentials -740242. -635351. -1672189. -734073. -318008. -509933. -907071. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 212 converged, 201 successes so far. Misfit function evaluations this try => 130 Misfit this try = 6.513406E-05 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.477916E-07 Bayes score, PP * exp(-Misfit) = 1.477820E-07 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15056.4 755.129 0.203005 9.771807E-02 0.902282 Final coordinates: 11564.1 1032.13 0.131905 6.620962E-02 0.933790 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.508929E-5 Extraneous predicted phases: 4.477459E-8 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 6.622 0.013594 0.138772 0.006928 0.216812 0.119086 0.504808 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.2 0.9 0.3 0.9 -1. -0.7 Chi 9.3E-07 1.2E-05 2.2E-05 4.4E-06 2.3E-05 1.5E-06 Composition Misfit: 6.446995E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 93.378 0.000000 0.052293 0.124837 0.157431 0.243626 0.421814 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.1 3.3E-02 -0.1 0.2 1.5E-02 Chi 0. 3.9E-07 1.3E-08 7.0E-08 1.5E-07 5.6E-10 Composition Misfit: 6.193316E-07 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.000886 0.057525 0.116192 0.160087 0.233633 0.007704 0.423973 Augite(G) 0.013512 0.137936 0.006887 0.215506 0.118369 0.006023 0.501768 Gt(W) 0.000000 0.051884 0.123860 0.156199 0.241720 0.007822 0.418514 ----- ----- ----- ----- ----- ----- ----- Potentials -782034. -643483. -1658571. -746580. -322836. -444281. -891436. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 213 converged, 202 successes so far. Misfit function evaluations this try => 316 Misfit this try = 0.176466 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 4.091257E-09 Bayes score, PP * exp(-Misfit) = 3.429404E-09 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2559.71 1111.01 0.707065 0.864551 0.135449 Final coordinates: 20000.0 600.000 0.215620 1.00000 3.113865E-44 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.176442 Extraneous predicted phases: 2.353582E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 95.434 0.014129 0.146078 0.001131 0.223249 0.107784 0.507630 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -1. -4. 5. -5. 8. -3. Chi 3.0E-05 2.5E-04 3.4E-02 1.3E-04 8.6E-04 2.7E-05 Composition Misfit: 3.517431E-02 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 4.560 0.000000 0.014683 0.136461 0.104178 0.318505 0.426173 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 3.6E+01 -9. 3.4E+01 -6.1E+01 -4. Chi 0. 0.1 9.8E-04 2.7E-02 1.8E-02 4.4E-05 Composition Misfit: 0.141268 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.006 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013397 0.139180 0.007274 0.216423 0.116678 0.006290 0.500758 Augite(G) 0.014037 0.145134 0.001124 0.221807 0.107088 0.006457 0.504352 Gt(W) 0.000000 0.014642 0.136080 0.103888 0.317616 0.002791 0.424984 ----- ----- ----- ----- ----- ----- ----- Potentials -690645. -601844. -1577762. -701417. -264062. -416428. -830057. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 214 converged, 203 successes so far. Misfit function evaluations this try => 382 Misfit this try = 46.8592 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 2.276258E-08 Bayes score, PP * exp(-Misfit) = 1.015165E-28 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13157.6 1162.54 0.880572 9.808367E-02 0.901916 Final coordinates: 14487.1 1194.81 0.354991 0.111128 0.888872 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.607162 Extraneous predicted phases: 46.2520 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.000 0.002124 0.034793 0.113311 0.267425 0.220974 0.361372 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 2.1E+01 7.5E+01 -8.5E+01 -4.6E+01 -8.8E+01 1.1E+02 Chi 0.1 0.3 0.1 9.2E-03 4.9E-02 0.1 Composition Misfit: 0.592336 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 84.597 0.000000 0.070108 0.096996 0.175747 0.245776 0.411373 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1.7E+01 2.2E+01 -1.2E+01 -2. 10. Chi 0. 4.6E-03 8.0E-03 1.9E-03 1.6E-05 2.7E-04 Composition Misfit: 1.482621E-02 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 Sp(WPC) 0.623 0.000000 0.014001 0.014001 0.000000 0.833141 0.138857 0.000000 Fsp(C1) 6.918 0.030934 0.000000 0.219066 0.188133 0.000000 0.000000 0.561867 ky 3.956 0.000000 0.000000 0.500000 0.000000 0.000000 0.000000 0.500000 q 3.358 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 hem 0.548 0.000000 0.000000 0.000000 0.000000 0.800000 0.200000 0.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.001468 0.060683 0.109579 0.160767 0.225178 0.019984 0.422340 Augite(G) 0.002038 0.033372 0.108684 0.256503 0.211949 0.040840 0.346614 Gt(W) 0.000000 0.068729 0.095088 0.172290 0.240941 0.019670 0.403282 ----- ----- ----- ----- ----- ----- ----- Potentials -832697. -660630. -1670407. -764121. -348260. -359869. -904630. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 215 converged, 204 successes so far. Misfit function evaluations this try => 194 Misfit this try = 9.625651E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.154684E-08 Bayes score, PP * exp(-Misfit) = 1.153573E-08 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 6957.22 1067.18 0.672103 6.762183E-02 0.932378 Final coordinates: 18745.0 1155.96 0.136192 0.156202 0.843798 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.591976E-4 Extraneous predicted phases: 3.367563E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 15.198 0.013934 0.136240 0.005743 0.213639 0.122955 0.507488 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.8 3. 1. 4. -5. -3. Chi 1.5E-05 1.1E-04 4.3E-04 8.1E-05 2.5E-04 2.5E-05 Composition Misfit: 9.102880E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 84.799 0.000000 0.053358 0.124459 0.158431 0.242081 0.421672 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 0.3 -0.7 1. 0.1 Chi 0. 2.7E-05 1.4E-06 7.7E-06 1.2E-05 5.8E-08 Composition Misfit: 4.890954E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.003 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.002090 0.065384 0.105708 0.165508 0.222376 0.007571 0.431362 Augite(G) 0.013861 0.135526 0.005713 0.212519 0.122310 0.005243 0.504828 Gt(W) 0.000000 0.052932 0.123465 0.157166 0.240148 0.007985 0.418305 ----- ----- ----- ----- ----- ----- ----- Potentials -799099. -649671. -1669637. -748446. -331468. -449093. -890016. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Augite(G) q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Augite(G) q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 217 converged, 205 successes so far. Misfit function evaluations this try => 260 Misfit this try = 1.93410 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 4.271714E-09 Bayes score, PP * exp(-Misfit) = 6.174966E-10 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 5162.83 1156.42 0.929838 0.877647 0.122353 Final coordinates: 19916.8 1199.38 0.323568 1.00000 1.718622E-08 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.224293 Extraneous predicted phases: 1.70980 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.330 0.013656 0.141870 0.007413 0.220599 0.118923 0.497539 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 -1. -0.1 -3. -1. 5. Chi 2.2E-06 2.3E-05 1.2E-06 3.6E-05 1.9E-05 8.2E-05 Composition Misfit: 1.632566E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.003 0.000000 0.044161 0.039382 0.238446 0.288243 0.389768 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 8. 6.8E+01 -5.2E+01 -3.6E+01 3.0E+01 Chi 0. 1.4E-03 0.2 2.8E-02 6.8E-03 2.6E-03 Composition Misfit: 0.224129 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 1.666 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013355 0.138744 0.007251 0.215744 0.116312 0.009409 0.499186 Augite(G) 0.013526 0.140518 0.007343 0.218497 0.117790 0.009528 0.492799 Gt(W) 0.000000 0.042248 0.037677 0.228119 0.275759 0.043310 0.372888 ----- ----- ----- ----- ----- ----- ----- Potentials -825862. -653261. -1690983. -749785. -340156. -372731. -892817. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 218 converged, 206 successes so far. Misfit function evaluations this try => 127 Misfit this try = 3.985923E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 4.627488E-08 Bayes score, PP * exp(-Misfit) = 4.625644E-08 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10134.5 982.227 0.947778 0.367327 0.632673 Final coordinates: 15619.0 1111.45 0.146705 0.347909 0.652091 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.979854E-4 Extraneous predicted phases: 6.069530E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 34.277 0.013754 0.138168 0.006464 0.215042 0.120431 0.506141 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.5 1. 0.7 3. -3. -2. Chi 5.4E-06 2.6E-05 1.1E-04 3.5E-05 7.5E-05 9.7E-06 Composition Misfit: 2.650878E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 65.722 0.000000 0.054051 0.124093 0.159384 0.240938 0.421535 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 0.6 -1. 2. 0.3 Chi 0. 6.7E-05 5.0E-06 2.7E-05 3.4E-05 2.1E-07 Composition Misfit: 1.328975E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.004656 0.082134 0.083367 0.177065 0.198387 0.007276 0.447115 Augite(G) 0.013677 0.137394 0.006428 0.213839 0.119757 0.005598 0.503308 Gt(W) 0.000000 0.053611 0.123082 0.158086 0.238976 0.008143 0.418102 ----- ----- ----- ----- ----- ----- ----- Potentials -793810. -647752. -1666349. -748449. -328981. -446320. -891633. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 219 converged, 207 successes so far. Misfit function evaluations this try => 126 Misfit this try = 8.480230E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.686547E-08 Bayes score, PP * exp(-Misfit) = 1.685117E-08 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 3071.41 1138.36 0.236292 5.493872E-02 0.945061 Final coordinates: 17381.6 1162.75 0.160659 0.544602 0.455398 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 8.439497E-4 Extraneous predicted phases: 4.073343E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 53.954 0.013659 0.137601 0.007243 0.214754 0.121208 0.505534 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 2. 0.1 3. -3. -1. Chi 2.3E-06 4.4E-05 8.1E-07 4.3E-05 1.2E-04 5.1E-06 Composition Misfit: 2.138178E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 46.043 0.000000 0.056357 0.123175 0.161790 0.237487 0.421191 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -4. 1. -3. 5. 0.6 Chi 0. 3.1E-04 2.4E-05 1.2E-04 1.7E-04 9.7E-07 Composition Misfit: 6.301319E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.003 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.007291 0.099329 0.060431 0.188929 0.173758 0.006979 0.463284 Augite(G) 0.013582 0.136826 0.007203 0.213544 0.120525 0.005635 0.502685 Gt(W) 0.000000 0.055876 0.122124 0.160409 0.235460 0.008537 0.417595 ----- ----- ----- ----- ----- ----- ----- Potentials -802410. -651300. -1673096. -750968. -334187. -446744. -893950. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Augite(G) q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Augite(G) q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 221 converged, 208 successes so far. Misfit function evaluations this try => 125 Misfit this try = 4.371573E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 4.907252E-08 Bayes score, PP * exp(-Misfit) = 4.905107E-08 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 10265.9 988.389 0.414022 0.157762 0.842238 Final coordinates: 15559.4 1106.58 0.139861 0.227794 0.772206 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 4.337325E-4 Extraneous predicted phases: 3.424828E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 22.396 0.013794 0.137704 0.006260 0.214923 0.120918 0.506400 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.6 2. 0.9 3. -3. -2. Chi 7.1E-06 4.0E-05 1.8E-04 3.8E-05 1.0E-04 1.2E-05 Composition Misfit: 3.786862E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 77.601 0.000000 0.053411 0.124404 0.158554 0.241980 0.421651 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 0.4 -0.8 2. 0.2 Chi 0. 3.0E-05 1.8E-06 9.5E-06 1.4E-05 7.5E-08 Composition Misfit: 5.504626E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.003 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.003048 0.071638 0.097367 0.169823 0.213419 0.007462 0.437243 Augite(G) 0.013718 0.136940 0.006226 0.213730 0.120247 0.005550 0.503589 Gt(W) 0.000000 0.052984 0.123407 0.157284 0.240042 0.008009 0.418274 ----- ----- ----- ----- ----- ----- ----- Potentials -792683. -647372. -1665580. -748068. -328322. -446894. -891177. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Augite(G) O(HP) ne iron the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Augite(G) O(HP) ne iron -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 223 converged, 209 successes so far. Misfit function evaluations this try => 227 Misfit this try = 9.383397E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 5.271710E-09 Bayes score, PP * exp(-Misfit) = 5.266765E-09 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 6408.64 646.697 0.459640 0.186960 0.813040 Final coordinates: 19854.5 1185.18 0.150659 0.409915 0.590085 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.383152E-4 Extraneous predicted phases: 2.458587E-8 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 39.976 0.013878 0.137781 0.006090 0.213669 0.121406 0.507177 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.7 2. 1. 4. -3. -3. Chi 1.1E-05 3.8E-05 2.5E-04 8.0E-05 1.3E-04 2.1E-05 Composition Misfit: 5.290227E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 60.024 0.000000 0.055372 0.123403 0.161233 0.238716 0.421276 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 1. -2. 4. 0.5 Chi 0. 1.9E-04 1.8E-05 9.5E-05 1.1E-04 7.3E-07 Composition Misfit: 4.092925E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005487 0.087554 0.076138 0.180805 0.190624 0.007180 0.452212 Augite(G) 0.013805 0.137055 0.006058 0.212543 0.120766 0.005270 0.504504 Gt(W) 0.000000 0.054905 0.122361 0.159872 0.236702 0.008439 0.417721 ----- ----- ----- ----- ----- ----- ----- Potentials -804504. -651531. -1673267. -749759. -334517. -447522. -891163. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Augite(G) q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Augite(G) q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 225 converged, 210 successes so far. Misfit function evaluations this try => 199 Misfit this try = 5.550585E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 2.902089E-08 Bayes score, PP * exp(-Misfit) = 2.900479E-08 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 5156.88 887.121 0.936700 4.892106E-02 0.951079 Final coordinates: 16712.7 1130.97 0.144930 0.318685 0.681315 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.545265E-4 Extraneous predicted phases: 5.319486E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 31.291 0.013801 0.137571 0.006302 0.214534 0.121272 0.506520 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.6 2. 0.8 3. -3. -2. Chi 7.4E-06 4.5E-05 1.6E-04 4.9E-05 1.2E-04 1.3E-05 Composition Misfit: 4.023237E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 68.708 0.000000 0.054219 0.124080 0.159448 0.240723 0.421530 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 0.6 -1. 3. 0.3 Chi 0. 7.9E-05 5.1E-06 2.8E-05 4.0E-05 2.1E-07 Composition Misfit: 1.522028E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.004265 0.079580 0.086774 0.175303 0.202045 0.007321 0.444713 Augite(G) 0.013725 0.136817 0.006267 0.213358 0.120606 0.005485 0.503741 Gt(W) 0.000000 0.053777 0.123069 0.158149 0.238761 0.008148 0.418095 ----- ----- ----- ----- ----- ----- ----- Potentials -796489. -648788. -1668213. -748814. -330408. -447238. -891533. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 226 converged, 211 successes so far. Misfit function evaluations this try => 298 Misfit this try = 6.029916E-03 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 5.503725E-09 Bayes score, PP * exp(-Misfit) = 5.470638E-09 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2732.72 1006.73 0.453591 0.909027 9.097339E-02 Final coordinates: 19939.3 1178.93 0.215900 0.999999 1.130583E-06 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.962007E-3 Extraneous predicted phases: 6.790930E-5 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 99.985 0.013483 0.140076 0.007316 0.217812 0.117421 0.503892 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -3.1E-03 -1.1E-02 3.4E-03 -1.7E-02 -3.7E-03 2.8E-02 Chi 2.1E-10 1.6E-09 2.4E-09 1.6E-09 1.6E-10 2.5E-09 Composition Misfit: 8.604303E-09 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.005 0.000000 0.053228 0.114233 0.184759 0.229942 0.417838 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 9. -1.7E+01 1.1E+01 4. Chi 0. 2.2E-05 9.9E-04 4.1E-03 8.4E-04 3.8E-05 Composition Misfit: 5.961998E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.011 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013397 0.139179 0.007274 0.216421 0.116677 0.006298 0.500754 Augite(G) 0.013399 0.139194 0.007270 0.216440 0.116681 0.006298 0.500718 Gt(W) 0.000000 0.052570 0.112821 0.182474 0.227098 0.012368 0.412670 ----- ----- ----- ----- ----- ----- ----- Potentials -806548. -651030. -1671619. -748452. -334892. -428547. -890185. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 227 converged, 212 successes so far. Misfit function evaluations this try => 163 Misfit this try = 7.814880E-05 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.840038E-07 Bayes score, PP * exp(-Misfit) = 1.839894E-07 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 5418.48 686.919 0.170524 0.805387 0.194613 Final coordinates: 8223.80 959.654 0.157106 0.500855 0.499145 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 7.735815E-5 Extraneous predicted phases: 7.906507E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 50.643 0.013399 0.140717 0.007507 0.218728 0.116420 0.503228 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.2 -0.5 -0.2 -0.9 0.8 0.6 Chi 5.1E-07 3.1E-06 4.7E-06 4.0E-06 8.5E-06 9.7E-07 Composition Misfit: 2.172431E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 49.356 0.000000 0.050938 0.125419 0.156004 0.245608 0.422032 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 1. -0.4 0.8 -1. -0.2 Chi 0. 2.9E-05 2.3E-06 1.1E-05 1.3E-05 9.8E-08 Composition Misfit: 5.563384E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.195671 0.000000 0.000000 0.470995 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.006705 0.095504 0.065534 0.186290 0.179238 0.007040 0.459689 Augite(G) 0.013312 0.139800 0.007458 0.217303 0.115661 0.006516 0.499949 Gt(W) 0.000000 0.050552 0.124469 0.154822 0.243749 0.007572 0.418837 ----- ----- ----- ----- ----- ----- ----- Potentials -735233. -630359. -1651315. -735546. -308138. -477601. -899910. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Augite(G) q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Augite(G) q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 229 converged, 213 successes so far. Misfit function evaluations this try => 161 Misfit this try = 5.289014E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 2.818545E-08 Bayes score, PP * exp(-Misfit) = 2.817054E-08 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15762.1 1167.74 8.816114E-02 0.571326 0.428674 Final coordinates: 16691.6 1134.35 0.148660 0.378350 0.621650 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.267485E-4 Extraneous predicted phases: 2.152868E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 37.220 0.013770 0.137764 0.006504 0.214676 0.120989 0.506296 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.5 2. 0.7 3. -3. -2. Chi 6.0E-06 3.8E-05 1.0E-04 4.5E-05 1.1E-04 1.1E-05 Composition Misfit: 3.086756E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 62.778 0.000000 0.054611 0.123880 0.159925 0.240128 0.421455 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 0.8 -2. 3. 0.4 Chi 0. 1.1E-04 8.0E-06 4.2E-05 5.7E-05 3.3E-07 Composition Misfit: 2.180729E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005064 0.084794 0.079818 0.178901 0.194576 0.007231 0.449616 Augite(G) 0.013694 0.137004 0.006468 0.213490 0.120321 0.005523 0.503500 Gt(W) 0.000000 0.054162 0.122860 0.158609 0.238151 0.008234 0.417985 ----- ----- ----- ----- ----- ----- ----- Potentials -797261. -649114. -1668869. -749170. -330932. -446881. -891997. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 230 converged, 214 successes so far. Misfit function evaluations this try => 125 Misfit this try = 8.352910E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.750537E-08 Bayes score, PP * exp(-Misfit) = 1.749075E-08 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 19009.5 851.917 0.642840 0.822013 0.177987 Final coordinates: 17487.9 1156.69 0.165134 0.599120 0.400880 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 8.351630E-4 Extraneous predicted phases: 1.280338E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 59.184 0.013691 0.138635 0.006960 0.214909 0.120059 0.505746 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.4 1. 0.3 3. -2. -1. Chi 3.2E-06 1.5E-05 1.9E-05 3.9E-05 5.8E-05 6.5E-06 Composition Misfit: 1.399347E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 40.816 0.000000 0.056166 0.122773 0.162826 0.237194 0.421040 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -4. 2. -3. 5. 0.7 Chi 0. 2.9E-04 3.6E-05 1.9E-04 1.8E-04 1.5E-06 Composition Misfit: 6.952283E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.008022 0.104098 0.054071 0.192219 0.166929 0.006891 0.467770 Augite(G) 0.013614 0.137855 0.006921 0.213700 0.119384 0.005623 0.502902 Gt(W) 0.000000 0.055677 0.121704 0.161408 0.235128 0.008710 0.417373 ----- ----- ----- ----- ----- ----- ----- Potentials -801430. -650581. -1671664. -750211. -333333. -445159. -892953. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 231 converged, 215 successes so far. Misfit function evaluations this try => 123 Misfit this try = 6.359049E-06 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.676699E-07 Bayes score, PP * exp(-Misfit) = 1.676688E-07 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 15083.1 914.544 8.453021E-02 0.181701 0.818299 Final coordinates: 10617.8 1013.55 0.146414 0.343241 0.656759 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.855997E-6 Extraneous predicted phases: 5.030521E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 34.453 0.013514 0.139797 0.007235 0.217451 0.117818 0.504186 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.1 0.2 0.1 0.3 -0.3 -0.2 Chi 7.8E-08 5.0E-07 1.0E-06 5.4E-07 1.4E-06 1.3E-07 Composition Misfit: 3.628286E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 65.546 0.000000 0.052400 0.124776 0.157582 0.243451 0.421791 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.2 0.1 -0.2 0.3 3.6E-02 Chi 0. 1.2E-06 8.3E-08 4.1E-07 5.5E-07 3.4E-09 Composition Misfit: 2.227711E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.004594 0.081726 0.083911 0.176784 0.198971 0.007283 0.446731 Augite(G) 0.013431 0.138931 0.007190 0.216104 0.117088 0.006196 0.501062 Gt(W) 0.000000 0.051989 0.123797 0.156345 0.241541 0.007848 0.418481 ----- ----- ----- ----- ----- ----- ----- Potentials -779515. -642450. -1656751. -746192. -321517. -442949. -891450. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 232 converged, 216 successes so far. Misfit function evaluations this try => 295 Misfit this try = 10.1896 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 5.289405E-09 Bayes score, PP * exp(-Misfit) = 1.986726E-13 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 1927.62 863.395 0.370025 0.477827 0.522173 Final coordinates: 1337.19 1191.06 0.399883 0.999793 2.073139E-04 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.39983 Extraneous predicted phases: 7.78973 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 95.917 0.013947 0.144902 0.007592 0.225344 0.112317 0.495897 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.9 -3. -0.2 -7. 4. 6. Chi 1.6E-05 1.6E-04 9.7E-06 2.5E-04 2.3E-04 1.3E-04 Composition Misfit: 8.016362E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.001 0.000000 0.019091 0.006262 0.325282 0.272017 0.377348 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 3.2E+01 9.5E+01 -1.1E+02 -2.3E+01 4.2E+01 Chi 0. 0.1 2. 0.1 2.9E-03 5.2E-03 Composition Misfit: 2.39903 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 Sp(WPC) 0.780 0.000000 0.000716 0.000716 0.000000 0.855915 0.142652 0.000000 q 3.301 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013323 0.138418 0.007259 0.215253 0.116080 0.011605 0.498063 Augite(G) 0.013801 0.143381 0.007512 0.222977 0.111137 0.010503 0.490689 Gt(W) 0.000000 0.018014 0.005909 0.306940 0.256678 0.056391 0.356069 ----- ----- ----- ----- ----- ----- ----- Potentials -838715. -673438. -1764493. -766774. -364941. -376178. -934920. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Although Augite(G) q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Augite(G) q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 234 converged, 217 successes so far. Misfit function evaluations this try => 146 Misfit this try = 4.150263E-06 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.720444E-07 Bayes score, PP * exp(-Misfit) = 1.720437E-07 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 3016.15 947.762 0.298533 0.324445 0.675555 Final coordinates: 10308.3 1008.23 0.153101 0.445132 0.554868 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.691697E-6 Extraneous predicted phases: 4.585658E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 44.741 0.013484 0.139775 0.007370 0.217644 0.117766 0.503960 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -4.8E-03 0.2 -4.0E-02 0.1 -0.3 -2.6E-02 Chi 5.0E-10 5.9E-07 3.3E-07 1.0E-07 1.0E-06 2.1E-09 Composition Misfit: 2.062128E-06 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 55.258 0.000000 0.052395 0.124821 0.157457 0.243519 0.421808 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.2 4.5E-02 -0.1 0.2 2.0E-02 Chi 0. 1.1E-06 2.5E-08 1.1E-07 3.6E-07 1.1E-09 Composition Misfit: 1.629569E-06 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.005958 0.090632 0.072032 0.182929 0.186215 0.007127 0.455107 Augite(G) 0.013400 0.138901 0.007324 0.216284 0.117030 0.006251 0.500810 Gt(W) 0.000000 0.051985 0.123844 0.156224 0.241613 0.007829 0.418506 ----- ----- ----- ----- ----- ----- ----- Potentials -778766. -642192. -1656300. -746136. -321177. -442717. -891546. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 235 converged, 218 successes so far. Misfit function evaluations this try => 197 Misfit this try = 6.878963E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 4.206070E-08 Bayes score, PP * exp(-Misfit) = 4.203178E-08 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16203.2 752.356 0.891390 0.910917 8.908261E-02 Final coordinates: 15564.1 1122.63 0.174227 0.695382 0.304618 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.871950E-4 Extraneous predicted phases: 7.012367E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 69.199 0.013583 0.139049 0.007383 0.215824 0.119266 0.504894 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.2 0.7 -0.1 2. -2. -0.8 Chi 7.6E-07 7.4E-06 5.3E-07 1.8E-05 2.9E-05 1.9E-06 Composition Misfit: 5.715042E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 30.800 0.000000 0.055883 0.122768 0.162731 0.237581 0.421038 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -4. 2. -3. 5. 0.8 Chi 0. 2.5E-04 3.6E-05 1.8E-04 1.6E-04 1.5E-06 Composition Misfit: 6.300446E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.009312 0.112518 0.042839 0.198029 0.154868 0.006746 0.475688 Augite(G) 0.013504 0.138234 0.007340 0.214559 0.118567 0.005860 0.501935 Gt(W) 0.000000 0.055396 0.121698 0.161313 0.235511 0.008712 0.417370 ----- ----- ----- ----- ----- ----- ----- Potentials -796551. -648770. -1668359. -749583. -330825. -443540. -893122. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 236 converged, 219 successes so far. Misfit function evaluations this try => 131 Misfit this try = 5.345956E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 3.399622E-08 Bayes score, PP * exp(-Misfit) = 3.397805E-08 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9679.35 1081.72 0.789961 0.289374 0.710626 Final coordinates: 16288.2 1126.51 0.158247 0.513857 0.486143 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 5.295521E-4 Extraneous predicted phases: 5.043499E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 50.651 0.013729 0.138842 0.006637 0.215096 0.119736 0.505960 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.5 0.9 0.5 2. -2. -2. Chi 4.5E-06 1.1E-05 7.0E-05 3.4E-05 4.5E-05 8.2E-06 Composition Misfit: 1.723459E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 49.346 0.000000 0.055040 0.123380 0.161211 0.239101 0.421267 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3. 1. -2. 4. 0.5 Chi 0. 1.5E-04 1.8E-05 9.4E-05 9.3E-05 7.5E-07 Composition Misfit: 3.572061E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.003 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.006879 0.096641 0.064017 0.187074 0.177608 0.007026 0.460756 Augite(G) 0.013652 0.138061 0.006600 0.213886 0.119062 0.005626 0.503113 Gt(W) 0.000000 0.054575 0.122337 0.159849 0.237081 0.008449 0.417708 ----- ----- ----- ----- ----- ----- ----- Potentials -796450. -648605. -1667949. -748965. -330439. -444999. -891950. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 237 converged, 220 successes so far. Misfit function evaluations this try => 428 Misfit this try = 6.649524E-03 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 8.300670E-08 Bayes score, PP * exp(-Misfit) = 8.245658E-08 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2527.62 838.925 7.039809E-02 6.615259E-02 0.933847 Final coordinates: 4371.55 815.780 0.161530 0.561042 0.438958 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 6.016895E-3 Extraneous predicted phases: 6.326287E-4 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 55.446 0.013682 0.149505 0.004682 0.220373 0.106782 0.504976 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.4 -7. 2. -2. 9. -0.8 Chi 2.9E-06 6.0E-04 1.5E-03 3.0E-05 1.1E-03 2.2E-06 Composition Misfit: 3.177592E-03 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 44.532 0.000000 0.042149 0.125986 0.155344 0.254276 0.422245 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 10. -0.9 1. -9. -0.4 Chi 0. 2.4E-03 9.7E-06 2.5E-05 4.3E-04 4.1E-07 Composition Misfit: 2.839303E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 Sp(WPC) 0.018 0.000000 0.004770 0.008552 0.000000 0.846264 0.140414 0.000000 Fsp(C1) 0.004 0.082380 0.000000 0.167620 0.085240 0.000000 0.000000 0.664760 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.007511 0.100769 0.058514 0.189924 0.171702 0.006934 0.464646 Augite(G) 0.013592 0.148524 0.004651 0.218927 0.106082 0.006560 0.501664 Gt(W) 0.000000 0.041840 0.125063 0.154206 0.252413 0.007327 0.419151 ----- ----- ----- ----- ----- ----- ----- Potentials -728421. -624576. -1634410. -732002. -298338. -456202. -890048. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 238 converged, 221 successes so far. Misfit function evaluations this try => 588 Misfit this try = 1.97768 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 4.899584E-09 Bayes score, PP * exp(-Misfit) = 6.780546E-10 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 11918.4 1160.71 0.887990 0.821070 0.178930 Final coordinates: 19667.9 1196.76 0.324683 0.999664 3.360752E-04 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.229557 Extraneous predicted phases: 1.74812 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.308 0.013654 0.141863 0.007453 0.220609 0.118978 0.497442 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 -1. -0.1 -3. -1. 5. Chi 2.2E-06 2.3E-05 2.4E-06 3.6E-05 2.0E-05 8.5E-05 Composition Misfit: 1.684594E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.006 0.000000 0.044505 0.038782 0.237283 0.289887 0.389543 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 7. 6.9E+01 -5.1E+01 -3.8E+01 3.1E+01 Chi 0. 1.3E-03 0.2 2.7E-02 7.3E-03 2.7E-03 Composition Misfit: 0.229388 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 1.685 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013350 0.138709 0.007290 0.215716 0.116350 0.009444 0.499141 Augite(G) 0.013523 0.140507 0.007382 0.218499 0.117840 0.009564 0.492684 Gt(W) 0.000000 0.042567 0.037093 0.226949 0.277263 0.043550 0.372578 ----- ----- ----- ----- ----- ----- ----- Potentials -825720. -653119. -1691034. -749949. -340013. -372707. -893048. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 239 converged, 222 successes so far. Misfit function evaluations this try => 114 Misfit this try = 1.117107E-03 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 8.182118E-09 Bayes score, PP * exp(-Misfit) = 8.172983E-09 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 19097.6 1145.00 0.775992 0.425940 0.574060 Final coordinates: 19769.7 1151.24 0.143031 0.285498 0.714502 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.114922E-3 Extraneous predicted phases: 2.184755E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 27.589 0.014008 0.139242 0.005247 0.213815 0.119649 0.508039 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -1. 0.6 2. 4. -2. -3. Chi 2.0E-05 4.8E-06 8.2E-04 7.4E-05 4.2E-05 3.3E-05 Composition Misfit: 9.923690E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 72.408 0.000000 0.053763 0.123927 0.159731 0.241107 0.421473 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 0.8 -2. 2. 0.3 Chi 0. 4.8E-05 7.3E-06 3.6E-05 3.0E-05 3.0E-07 Composition Misfit: 1.225531E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.003821 0.076680 0.090642 0.173302 0.206198 0.007373 0.441985 Augite(G) 0.013936 0.138525 0.005220 0.212714 0.119033 0.005148 0.505424 Gt(W) 0.000000 0.053321 0.122909 0.158419 0.239126 0.008214 0.418011 ----- ----- ----- ----- ----- ----- ----- Potentials -797666. -648164. -1666654. -746602. -329942. -445776. -887118. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 240 converged, 223 successes so far. Misfit function evaluations this try => 337 Misfit this try = 2.16703 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 6.550826E-09 Bayes score, PP * exp(-Misfit) = 7.501840E-10 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 3186.08 1166.91 0.525189 0.650358 0.349642 Final coordinates: 18811.7 1199.87 0.328642 0.999963 3.662092E-05 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 0.293310 Extraneous predicted phases: 1.87372 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 98.248 0.013664 0.141952 0.007422 0.220730 0.119000 0.497232 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 -1. -0.1 -3. -1. 5. Chi 2.4E-06 2.5E-05 1.4E-06 3.9E-05 2.1E-05 9.0E-05 Composition Misfit: 1.793388E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.003 0.000000 0.043758 0.033393 0.241505 0.293822 0.387522 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 8. 7.3E+01 -5.4E+01 -4.1E+01 3.3E+01 Chi 0. 1.6E-03 0.3 2.9E-02 8.5E-03 3.0E-03 Composition Misfit: 0.293131 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 1.748 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013352 0.138720 0.007255 0.215709 0.116299 0.009555 0.499109 Augite(G) 0.013531 0.140578 0.007351 0.218593 0.117848 0.009682 0.492418 Gt(W) 0.000000 0.041758 0.031867 0.230468 0.280394 0.045702 0.369812 ----- ----- ----- ----- ----- ----- ----- Potentials -828101. -654283. -1695997. -751248. -341547. -371015. -895382. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 241 converged, 224 successes so far. Misfit function evaluations this try => 133 Misfit this try = 2.191683E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.359592E-07 Bayes score, PP * exp(-Misfit) = 1.359294E-07 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 17386.6 656.618 0.647711 0.945507 5.449309E-02 Final coordinates: 11840.3 1043.36 0.207452 0.953713 4.628662E-02 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.167826E-4 Extraneous predicted phases: 2.385711E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 95.660 0.013447 0.139753 0.007695 0.217476 0.117902 0.503728 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.1 0.2 -0.3 0.3 -0.4 0.2 Chi 9.2E-08 6.8E-07 1.8E-05 4.6E-07 2.0E-06 7.9E-08 Composition Misfit: 2.153254E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 4.338 0.000000 0.053890 0.123452 0.160843 0.240521 0.421294 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 1. -2. 3. 0.5 Chi 0. 5.6E-05 1.6E-05 7.7E-05 4.5E-05 6.8E-07 Composition Misfit: 1.952500E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.012776 0.135128 0.012680 0.213628 0.122484 0.006352 0.496950 Augite(G) 0.013362 0.138878 0.007647 0.216115 0.117164 0.006258 0.500576 Gt(W) 0.000000 0.053436 0.122413 0.159489 0.238497 0.008418 0.417748 ----- ----- ----- ----- ----- ----- ----- Potentials -784497. -644192. -1659915. -747244. -324260. -441296. -892117. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 242 converged, 225 successes so far. Misfit function evaluations this try => 108 Misfit this try = 9.429899E-07 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.759106E-07 Bayes score, PP * exp(-Misfit) = 1.759104E-07 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 13607.1 721.098 0.228874 0.748470 0.251530 Final coordinates: 10140.1 1003.05 0.196692 0.883305 0.116695 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 8.431179E-7 Extraneous predicted phases: 9.987202E-8 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 88.423 0.013483 0.140062 0.007329 0.217758 0.117433 0.503936 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -1.5E-03 -4.6E-04 -6.9E-03 3.2E-02 -1.4E-02 -6.8E-03 Chi 4.8E-11 2.9E-12 1.0E-08 5.7E-09 2.4E-09 1.4E-10 Composition Misfit: 1.826175E-08 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 11.577 0.000000 0.052187 0.124763 0.157624 0.243640 0.421786 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -3.5E-02 0.1 -0.2 0.1 4.1E-02 Chi 0. 2.5E-08 1.0E-07 5.6E-07 1.3E-07 4.4E-09 Composition Misfit: 8.248561E-07 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.011832 0.128965 0.020903 0.209376 0.131313 0.006457 0.491155 Augite(G) 0.013398 0.139184 0.007283 0.216392 0.116697 0.006272 0.500775 Gt(W) 0.000000 0.051777 0.123783 0.156386 0.241726 0.007854 0.418473 ----- ----- ----- ----- ----- ----- ----- Potentials -778012. -641849. -1655673. -745900. -320695. -442267. -891338. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 243 converged, 226 successes so far. Misfit function evaluations this try => 125 Misfit this try = 2.143012E-03 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 9.339699E-09 Bayes score, PP * exp(-Misfit) = 9.319705E-09 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 5643.56 1087.01 0.888721 0.299477 0.700523 Final coordinates: 18149.5 1190.69 0.189881 0.832956 0.167044 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.143012E-3 Extraneous predicted phases: 0.00000 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 83.672 0.013441 0.138534 0.008429 0.215686 0.119953 0.503958 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 0.1 1. -0.9 2. -2. -2.4E-02 Chi 1.3E-07 1.7E-05 1.5E-04 2.1E-05 5.4E-05 1.9E-09 Composition Misfit: 2.370407E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 16.328 0.000000 0.058544 0.121069 0.167093 0.232893 0.420401 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -6. 3. -6. 9. 1. Chi 0. 7.0E-04 1.2E-04 5.7E-04 5.1E-04 4.9E-06 Composition Misfit: 1.905972E-03 *mole fractions relative to measured components, complete compositions below Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.011156 0.124557 0.026781 0.206336 0.137625 0.006533 0.487011 Augite(G) 0.013361 0.137709 0.008379 0.214400 0.119238 0.005958 0.500955 Gt(W) 0.000000 0.057991 0.119926 0.165515 0.230694 0.009442 0.416431 ----- ----- ----- ----- ----- ----- ----- Potentials -743277. -637164. -1677030. -736394. -321422. -507540. -911918. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 244 converged, 227 successes so far. Misfit function evaluations this try => 140 Misfit this try = 2.666142E-03 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.253592E-08 Bayes score, PP * exp(-Misfit) = 1.250254E-08 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 16431.1 1118.85 0.797128 0.881806 0.118194 Final coordinates: 18882.7 1144.00 0.193766 0.862577 0.137423 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.664349E-3 Extraneous predicted phases: 1.792842E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 84.501 0.013775 0.141684 0.005908 0.216112 0.116379 0.506142 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.5 -1. 1. 2. 0.9 -2. Chi 6.2E-06 1.9E-05 3.4E-04 1.3E-05 9.2E-06 9.7E-06 Composition Misfit: 3.942073E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 15.497 0.000000 0.053705 0.118687 0.173576 0.234524 0.419508 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -1. 5. -1.0E+01 8. 2. Chi 0. 4.5E-05 3.2E-04 1.5E-03 3.7E-04 1.3E-05 Composition Misfit: 2.270142E-03 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 O(HP) 0.001 0.000000 0.208470 0.000000 0.000000 0.458197 0.000000 0.333333 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.011554 0.127150 0.023323 0.208124 0.133912 0.006487 0.489449 Augite(G) 0.013696 0.140869 0.005874 0.214869 0.115710 0.005750 0.503232 Gt(W) 0.000000 0.053143 0.117445 0.171760 0.232070 0.010464 0.415118 ----- ----- ----- ----- ----- ----- ----- Potentials -734422. -631934. -1666564. -730546. -314422. -499719. -904498. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 245 converged, 228 successes so far. Misfit function evaluations this try => 147 Misfit this try = 9.700666E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.659627E-08 Bayes score, PP * exp(-Misfit) = 1.658018E-08 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 12943.4 752.855 0.900543 0.110330 0.889670 Final coordinates: 18237.5 1139.34 0.133922 0.107916 0.892084 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 9.628074E-4 Extraneous predicted phases: 7.259187E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 10.478 0.013966 0.136863 0.005549 0.213820 0.122183 0.507619 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.9 2. 1. 4. -4. -3. Chi 1.7E-05 7.5E-05 5.7E-04 7.4E-05 1.9E-04 2.7E-05 Composition Misfit: 9.437352E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 89.518 0.000000 0.052892 0.124596 0.158046 0.242742 0.421724 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.7 0.2 -0.5 0.9 0.1 Chi 0. 1.0E-05 6.3E-07 3.3E-06 4.8E-06 2.6E-08 Composition Misfit: 1.907225E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.004 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.001444 0.061167 0.111333 0.162598 0.228415 0.007647 0.427395 Augite(G) 0.013893 0.136144 0.005520 0.212698 0.121542 0.005250 0.504954 Gt(W) 0.000000 0.052473 0.123609 0.156793 0.240818 0.007926 0.418381 ----- ----- ----- ----- ----- ----- ----- Potentials -796302. -648429. -1667264. -747540. -329764. -448285. -889108. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 246 converged, 229 successes so far. Misfit function evaluations this try => 633 Misfit this try = 10.0885 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.450755E-08 Bayes score, PP * exp(-Misfit) = 6.028497E-13 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 2153.35 1132.05 9.655917E-02 0.528829 0.471171 Final coordinates: 2042.00 1127.37 0.402517 0.999387 6.128372E-04 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.86692 Extraneous predicted phases: 8.22159 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 95.792 0.013957 0.145027 0.007649 0.225555 0.111935 0.495877 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.9 -4. -0.3 -7. 5. 6. Chi 1.6E-05 1.7E-04 1.4E-05 2.7E-04 2.7E-04 1.3E-04 Composition Misfit: 8.664969E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 0.006 0.000000 0.017543 0.008021 0.326471 0.269957 0.378008 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 3.3E+01 9.4E+01 -1.1E+02 -2.1E+01 4.2E+01 Chi 0. 0.1 2. 0.1 2.5E-03 5.1E-03 Composition Misfit: 1.86605 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 Sp(WPC) 0.826 0.000000 0.000751 0.000751 0.000000 0.855856 0.142643 0.000000 q 3.375 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.013316 0.138371 0.007306 0.215211 0.116121 0.011685 0.497989 Augite(G) 0.013811 0.143503 0.007568 0.223185 0.110759 0.010506 0.490668 Gt(W) 0.000000 0.016566 0.007574 0.308285 0.254919 0.055705 0.356951 ----- ----- ----- ----- ----- ----- ----- Potentials -823796. -666262. -1742664. -760205. -354921. -376252. -925209. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 247 converged, 230 successes so far. Misfit function evaluations this try => 106 Misfit this try = 1.196653E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.201715E-07 Bayes score, PP * exp(-Misfit) = 1.201571E-07 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 9160.67 1096.07 0.283929 0.244844 0.755156 Final coordinates: 12555.7 1053.89 0.138791 0.209171 0.790829 This model fits all data within observational uncertainty Components of the Misfit Score Predicted compositions 1.196511E-4 Extraneous predicted phases: 1.423066E-8 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 20.841 0.013626 0.138401 0.006874 0.216334 0.119661 0.505104 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.3 1. 0.4 1. -2. -0.9 Chi 1.5E-06 2.0E-05 2.9E-05 9.8E-06 4.2E-05 2.7E-06 Composition Misfit: 1.050353E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 79.159 0.000000 0.052830 0.124666 0.157876 0.242879 0.421750 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -0.7 0.2 -0.3 0.8 0.1 Chi 0. 8.7E-06 3.6E-07 1.9E-06 3.6E-06 1.5E-08 Composition Misfit: 1.461578E-05 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.002799 0.070011 0.099537 0.168702 0.215750 0.007486 0.435715 Augite(G) 0.013545 0.137583 0.006834 0.215055 0.118953 0.005914 0.502117 Gt(W) 0.000000 0.052412 0.123682 0.156629 0.240961 0.007896 0.418420 ----- ----- ----- ----- ----- ----- ----- Potentials -785305. -644755. -1660882. -747225. -324598. -444982. -891721. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 248 converged, 231 successes so far. Misfit function evaluations this try => 126 Misfit this try = 3.560573E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 1.768373E-07 Bayes score, PP * exp(-Misfit) = 1.767743E-07 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 6139.83 892.644 0.380554 0.899746 0.100254 Final coordinates: 7589.58 945.453 0.195734 0.876568 0.123432 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.556714E-4 Extraneous predicted phases: 3.858416E-7 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 87.774 0.013479 0.140373 0.007086 0.218421 0.116819 0.503821 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. 4.3E-03 -0.2 0.2 -0.6 0.5 0.1 Chi 4.0E-10 6.9E-07 7.7E-06 1.8E-06 3.1E-06 2.2E-08 Composition Misfit: 1.329224E-05 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 12.225 0.000000 0.049856 0.126650 0.152807 0.248193 0.422494 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. 2. -1. 3. -4. -0.6 Chi 0. 1.1E-04 2.5E-05 1.3E-04 7.7E-05 1.0E-06 Composition Misfit: 3.423792E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 Fsp(C1) 0.001 0.081005 0.000000 0.168995 0.087991 0.000000 0.000000 0.662009 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.011741 0.128375 0.021689 0.208969 0.132158 0.006467 0.490601 Augite(G) 0.013393 0.139476 0.007041 0.217026 0.116073 0.006386 0.500604 Gt(W) 0.000000 0.049505 0.125759 0.151731 0.246446 0.007041 0.419519 ----- ----- ----- ----- ----- ----- ----- Potentials -755628. -635380. -1650133. -740894. -312575. -456934. -894062. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 249 converged, 232 successes so far. Misfit function evaluations this try => 97 Misfit this try = 3.352259E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 6.220227E-08 Bayes score, PP * exp(-Misfit) = 6.218142E-08 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 8802.72 1132.11 0.358275 0.433789 0.566211 Final coordinates: 14767.0 1098.43 0.156544 0.493017 0.506983 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 3.351917E-4 Extraneous predicted phases: 3.414738E-8 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 48.814 0.013674 0.138828 0.006805 0.215642 0.119523 0.505528 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.4 0.9 0.4 2. -2. -1. Chi 2.7E-06 1.1E-05 3.9E-05 2.1E-05 3.7E-05 5.1E-06 Composition Misfit: 1.162865E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 51.185 0.000000 0.054501 0.123782 0.160175 0.240123 0.421418 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 0.9 -2. 3. 0.4 Chi 0. 1.0E-04 9.7E-06 5.1E-05 5.7E-05 4.0E-07 Composition Misfit: 2.189052E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.006600 0.094819 0.066448 0.185817 0.180219 0.007053 0.459044 Augite(G) 0.013595 0.138029 0.006766 0.214401 0.118835 0.005757 0.502618 Gt(W) 0.000000 0.054050 0.122758 0.158849 0.238136 0.008276 0.417931 ----- ----- ----- ----- ----- ----- ----- Potentials -792198. -647139. -1665261. -748379. -328251. -444886. -891994. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- Central model Try 250 converged, 233 successes so far. Misfit function evaluations this try => 231 Misfit this try = 2.844036E-04 Best Misfit so far = 3.802121E-07 obtained on Try 169 Prior probability, PP = 6.886746E-08 Bayes score, PP * exp(-Misfit) = 6.884788E-08 Best Bayes score so far = 1.854704E-07 obtained on Try 205 P_bar T_K C_O2 Cpx Gt Initial coordinates: 3135.70 892.218 0.539866 7.350141E-02 0.926499 Final coordinates: 14466.5 1093.03 0.153707 0.453098 0.546902 This model DOES NOT fit all data within observational uncertainty Components of the Misfit Score Predicted compositions 2.822656E-4 Extraneous predicted phases: 2.137988E-6 Missed observed phases: 0.00000 The following observed phases are predicted:* Augite(G) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 44.886 0.013671 0.138717 0.006824 0.215696 0.119597 0.505495 observed 0.013482 0.140061 0.007320 0.217793 0.117417 0.503927 std_resid. -0.4 1. 0.4 2. -2. -1. Chi 2.6E-06 1.3E-05 3.6E-05 2.0E-05 4.0E-05 4.9E-06 Composition Misfit: 1.167824E-04 Gt(W) vol % Na2O MgO Al2O3 CaO FeO SiO2 predicted 55.112 0.000000 0.054237 0.123946 0.159711 0.240625 0.421480 observed 0.000000 0.052151 0.124877 0.157326 0.243816 0.421829 std_resid. 0. -2. 0.7 -2. 3. 0.3 Chi 0. 8.0E-05 7.0E-06 3.6E-05 4.2E-05 2.9E-07 Composition Misfit: 1.654833E-04 *mole fractions relative to measured components, complete compositions below The following predicted phases** are not observed: vol % Na2O MgO Al2O3 CaO FeO O2 SiO2 q 0.002 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 Complete compositions** and chemical potentials (J/mol) Na2O MgO Al2O3 CaO FeO O2 SiO2 Bulk 0.006065 0.091328 0.071103 0.183409 0.185217 0.007117 0.455761 Augite(G) 0.013593 0.137917 0.006784 0.214452 0.118908 0.005767 0.502580 Gt(W) 0.000000 0.053792 0.122929 0.158401 0.238651 0.008206 0.418021 ----- ----- ----- ----- ----- ----- ----- Potentials -791348. -646865. -1664771. -748286. -327832. -445059. -892027. **mole fractions -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 2 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10755.2 992.767 0.213495 0.947933 5.206707E-02 5.860817E-04 Mean perturbed parameters: 10415.8 997.192 0.211174 0.955356 4.464360E-02 2.932310E-04 Parameter standard deviation: 678.829 8.85019 4.641971E-03 1.484694E-02 1.484694E-02 5.857015E-04 -------------------------------------------------------------------------------- After 3 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10623.9 1002.91 0.212970 0.947013 5.298701E-02 4.797590E-05 Mean perturbed parameters: 10485.2 999.099 0.211773 0.952575 4.742474E-02 2.114793E-04 Parameter standard deviation: 616.656 6.32468 4.387374E-03 1.531382E-02 1.531382E-02 4.155187E-04 -------------------------------------------------------------------------------- Although Augite(G) Sp(WPC) fak q the result will be rejected because one or more observed phases are not predicted. To use such results set the mc_fit no_missing_phases option to F. The predicted assemblage was: Augite(G) Sp(WPC) fak q -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- After 4 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 9546.31 992.873 0.193974 0.951773 4.822721E-02 3.730339E-04 Mean perturbed parameters: 10250.5 997.542 0.207323 0.952375 4.762535E-02 2.518679E-04 Parameter standard deviation: 589.216 7.22156 9.307422E-03 1.402595E-02 1.402595E-02 4.017389E-04 -------------------------------------------------------------------------------- After 5 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 8551.65 1035.78 0.216256 0.960523 3.947721E-02 1.298902E-03 Mean perturbed parameters: 9910.69 1005.19 0.209110 0.954004 4.599572E-02 4.612747E-04 Parameter standard deviation: 917.388 18.1925 8.869591E-03 1.219914E-02 1.219914E-02 7.366038E-04 -------------------------------------------------------------------------------- After 6 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 8081.90 991.535 0.198778 0.947283 5.271732E-02 3.288835E-04 Mean perturbed parameters: 9605.89 1002.91 0.207388 0.952884 4.711599E-02 4.392095E-04 Parameter standard deviation: 1211.98 16.8850 9.123434E-03 1.292625E-02 1.292625E-02 6.750193E-04 -------------------------------------------------------------------------------- After 7 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 9873.61 1020.24 0.207236 0.969118 3.088223E-02 1.862784E-04 Mean perturbed parameters: 9644.14 1005.39 0.207366 0.955203 4.479688E-02 4.030765E-04 Parameter standard deviation: 1109.47 17.1872 8.354637E-03 1.208034E-02 1.208034E-02 6.208614E-04 -------------------------------------------------------------------------------- After 8 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 12047.3 1010.68 0.204235 0.957503 4.249714E-02 2.942591E-04 Mean perturbed parameters: 9944.53 1006.05 0.206975 0.955491 4.450941E-02 3.894743E-04 Parameter standard deviation: 1268.86 16.2769 7.929388E-03 1.136068E-02 1.136068E-02 5.854398E-04 -------------------------------------------------------------------------------- After 9 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 6511.59 989.300 0.238371 0.948773 5.122704E-02 2.582544E-03 Mean perturbed parameters: 9563.09 1004.19 0.210463 0.954744 4.525582E-02 6.331488E-04 Parameter standard deviation: 1731.25 15.8362 1.280353E-02 1.172417E-02 1.172417E-02 1.064586E-03 -------------------------------------------------------------------------------- After 10 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 8557.96 969.915 0.208158 0.943939 5.606085E-02 3.246776E-04 Mean perturbed parameters: 9462.58 1000.76 0.210233 0.953664 4.633632E-02 6.023016E-04 Parameter standard deviation: 1708.92 18.2917 1.207350E-02 1.271317E-02 1.271317E-02 1.009506E-03 -------------------------------------------------------------------------------- After 11 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10165.8 1003.39 0.208350 0.933968 6.603247E-02 4.157011E-05 Mean perturbed parameters: 9526.51 1001.00 0.210062 0.951873 4.812688E-02 5.513261E-04 Parameter standard deviation: 1621.47 17.3621 1.145504E-02 1.511546E-02 1.511546E-02 9.577899E-04 -------------------------------------------------------------------------------- After 12 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 1180.27 1199.41 0.328821 0.999951 4.888848E-05 12.5316 Mean perturbed parameters: 8830.99 1017.54 0.219958 0.955880 4.412038E-02 1.04480 Parameter standard deviation: 3095.93 61.8914 3.778466E-02 1.825694E-02 1.825694E-02 3.77841 -------------------------------------------------------------------------------- After 13 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10037.3 1031.23 0.149015 0.429441 0.570559 3.418494E-04 Mean perturbed parameters: 8923.78 1018.59 0.214501 0.915384 8.461563E-02 0.964459 Parameter standard deviation: 2964.15 59.8701 4.008856E-02 0.154951 0.154951 3.61755 -------------------------------------------------------------------------------- After 14 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 11891.8 1017.82 0.206288 0.960342 3.965775E-02 1.761493E-04 Mean perturbed parameters: 9135.78 1018.53 0.213915 0.918596 8.140436E-02 0.895582 Parameter standard deviation: 2892.03 57.6965 3.852242E-02 0.148873 0.148873 3.47563 -------------------------------------------------------------------------------- After 15 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 12768.1 1024.79 0.195717 0.948010 5.198980E-02 1.578932E-03 Mean perturbed parameters: 9377.93 1018.95 0.212701 0.920557 7.944339E-02 0.835981 Parameter standard deviation: 2878.18 55.9417 3.728677E-02 0.143512 0.143512 3.34920 -------------------------------------------------------------------------------- After 16 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 9880.14 1013.24 0.232123 0.954365 4.563492E-02 2.478566E-04 Mean perturbed parameters: 9409.32 1018.59 0.213915 0.922670 7.733036E-02 0.783748 Parameter standard deviation: 2781.05 54.1282 3.652007E-02 0.138663 0.138663 3.23563 -------------------------------------------------------------------------------- After 17 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 11311.6 990.774 0.221980 0.952358 4.764158E-02 2.946495E-04 Mean perturbed parameters: 9521.22 1016.96 0.214390 0.924416 7.558396E-02 0.737663 Parameter standard deviation: 2710.38 52.4794 3.551236E-02 0.134285 0.134285 3.13289 -------------------------------------------------------------------------------- After 18 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 14564.4 1067.43 0.204311 0.986626 1.337365E-02 1.376030E-04 Mean perturbed parameters: 9801.39 1019.76 0.213830 0.927872 7.212783E-02 0.696689 Parameter standard deviation: 2845.85 53.3562 3.446966E-02 0.130404 0.130404 3.03935 -------------------------------------------------------------------------------- After 19 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 1000.00 1200.00 0.680631 1.00000 1.749586E-17 46.8570 Mean perturbed parameters: 9338.16 1029.25 0.238398 0.931668 6.833163E-02 3.12618 Parameter standard deviation: 3496.52 69.8223 0.116135 0.127033 0.127033 11.4324 -------------------------------------------------------------------------------- After 20 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 6496.98 967.841 0.195619 0.940496 5.950407E-02 9.530664E-04 Mean perturbed parameters: 9196.10 1026.18 0.236259 0.932110 6.789025E-02 2.96992 Parameter standard deviation: 3500.93 68.4004 0.113078 0.123751 0.123751 11.1275 -------------------------------------------------------------------------------- After 21 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 7769.25 1026.17 0.201139 0.974791 2.520927E-02 1.634766E-03 Mean perturbed parameters: 9128.16 1026.18 0.234587 0.934142 6.585782E-02 2.82857 Parameter standard deviation: 3451.06 66.8940 0.110229 0.120647 0.120647 10.8458 -------------------------------------------------------------------------------- After 22 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 8331.07 994.080 0.202217 0.944245 5.575478E-02 5.891664E-04 Mean perturbed parameters: 9091.92 1024.72 0.233116 0.934601 6.539859E-02 2.70002 Parameter standard deviation: 3389.36 65.3026 0.107582 0.117809 0.117809 10.5844 -------------------------------------------------------------------------------- After 23 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 6307.61 943.695 0.204014 0.906638 9.336189E-02 2.889497E-05 Mean perturbed parameters: 8970.87 1021.20 0.231850 0.933386 6.661439E-02 2.58263 Parameter standard deviation: 3407.52 64.9853 0.105114 0.115721 0.115721 10.3410 -------------------------------------------------------------------------------- After 24 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 11054.3 996.996 0.209393 0.941729 5.827121E-02 1.665365E-04 Mean perturbed parameters: 9057.68 1020.19 0.230914 0.933733 6.626676E-02 2.47503 Parameter standard deviation: 3338.86 63.5642 0.102803 0.113263 0.113263 10.1137 -------------------------------------------------------------------------------- After 25 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 12436.9 998.956 0.215603 0.944526 5.547375E-02 2.179718E-04 Mean perturbed parameters: 9192.85 1019.34 0.230302 0.934165 6.583504E-02 2.37604 Parameter standard deviation: 3303.88 62.2282 0.100648 0.110940 0.110940 9.90079 -------------------------------------------------------------------------------- After 26 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 9888.36 1009.11 0.208936 0.945051 5.494930E-02 8.978942E-05 Mean perturbed parameters: 9219.60 1018.94 0.229480 0.934584 6.541635E-02 2.28466 Parameter standard deviation: 3237.35 60.9894 9.861456E-02 0.108757 0.108757 9.70075 -------------------------------------------------------------------------------- After 27 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 9763.83 1155.24 0.328564 0.995749 4.250590E-03 7.01466 Mean perturbed parameters: 9239.75 1023.99 0.233150 0.936849 6.315096E-02 2.45984 Parameter standard deviation: 3175.07 66.9654 9.950871E-02 0.106841 0.106841 9.61133 -------------------------------------------------------------------------------- After 28 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10164.5 991.519 0.213274 0.933985 6.601525E-02 6.442516E-04 Mean perturbed parameters: 9272.78 1022.83 0.232440 0.936747 6.325325E-02 2.37201 Parameter standard deviation: 3115.77 65.7423 9.765227E-02 0.104990 0.104990 9.43166 -------------------------------------------------------------------------------- After 29 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 5637.69 975.131 0.199339 0.938633 6.136680E-02 1.828239E-03 Mean perturbed parameters: 9147.43 1021.19 0.231299 0.936812 6.318820E-02 2.29028 Parameter standard deviation: 3172.53 64.7514 9.590948E-02 0.103199 0.103199 9.26171 -------------------------------------------------------------------------------- After 30 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 6080.09 985.367 0.191737 0.902314 9.768553E-02 1.326915E-03 Mean perturbed parameters: 9045.19 1019.99 0.229980 0.935662 6.433811E-02 2.21398 Parameter standard deviation: 3204.46 63.6968 9.429495E-02 0.102024 0.102024 9.10062 -------------------------------------------------------------------------------- After 31 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10105.2 1062.00 0.209174 0.976481 2.351910E-02 2.266841E-03 Mean perturbed parameters: 9079.38 1021.35 0.229309 0.936979 6.302137E-02 2.14264 Parameter standard deviation: 3150.61 63.5890 9.271006E-02 0.100340 0.100340 8.94766 -------------------------------------------------------------------------------- After 32 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 1026.11 1199.99 0.420452 0.999946 5.371215E-05 19.8715 Mean perturbed parameters: 8827.72 1026.93 0.235282 0.938946 6.105363E-02 2.69667 Parameter standard deviation: 3499.76 71.9894 9.880390E-02 9.893387E-02 9.893387E-02 9.49821 -------------------------------------------------------------------------------- After 33 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10529.6 1033.78 0.209241 0.947377 5.262268E-02 4.816484E-04 Mean perturbed parameters: 8879.29 1027.14 0.234493 0.939202 6.079815E-02 2.61496 Parameter standard deviation: 3445.57 71.0834 9.724786E-02 9.741382E-02 9.741382E-02 9.34863 -------------------------------------------------------------------------------- After 34 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 16997.7 1096.82 0.198469 0.999722 2.778527E-04 6.469939E-04 Mean perturbed parameters: 9118.07 1029.19 0.233433 0.940982 5.901814E-02 2.53807 Parameter standard deviation: 3600.54 71.9333 9.578013E-02 9.614182E-02 9.614182E-02 9.20589 -------------------------------------------------------------------------------- After 35 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 9665.41 1026.56 0.199654 0.968833 3.116653E-02 3.203026E-04 Mean perturbed parameters: 9133.71 1029.11 0.232468 0.941778 5.822238E-02 2.46556 Parameter standard deviation: 3547.89 70.9966 9.437428E-02 9.472311E-02 9.472311E-02 9.06950 -------------------------------------------------------------------------------- After 36 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 6788.40 980.292 0.207116 0.948008 5.199192E-02 2.026508E-03 Mean perturbed parameters: 9068.56 1027.76 0.231764 0.941951 5.804931E-02 2.39713 Parameter standard deviation: 3540.73 70.0678 9.301677E-02 9.339350E-02 9.339350E-02 8.93900 -------------------------------------------------------------------------------- After 37 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 8591.38 1029.42 0.225347 0.946768 5.323226E-02 1.042845E-03 Mean perturbed parameters: 9055.66 1027.80 0.231591 0.942081 5.791912E-02 2.33237 Parameter standard deviation: 3499.97 69.2430 9.175695E-02 9.212589E-02 9.212589E-02 8.81397 -------------------------------------------------------------------------------- After 38 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 9610.72 1003.71 0.212716 0.950181 4.981947E-02 4.215118E-04 Mean perturbed parameters: 9070.27 1027.17 0.231094 0.942294 5.770597E-02 2.27101 Parameter standard deviation: 3453.20 68.3017 9.051073E-02 9.089602E-02 9.089602E-02 8.69405 -------------------------------------------------------------------------------- After 39 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 9829.65 972.303 0.232823 0.954867 4.513271E-02 3.062513E-04 Mean perturbed parameters: 9089.74 1025.76 0.231138 0.942616 5.738358E-02 2.21278 Parameter standard deviation: 3407.69 67.5646 8.939646E-02 8.970123E-02 8.970123E-02 8.57889 -------------------------------------------------------------------------------- After 40 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10248.1 1080.39 0.299278 0.999926 7.381339E-05 13.4677 Mean perturbed parameters: 9118.70 1027.13 0.232842 0.944049 5.595084E-02 2.49416 Parameter standard deviation: 3363.83 67.8749 8.942297E-02 8.874332E-02 8.874332E-02 8.73847 -------------------------------------------------------------------------------- After 41 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 13108.3 1031.61 0.205798 0.924087 7.591283E-02 9.180717E-04 Mean perturbed parameters: 9216.01 1027.24 0.232182 0.943562 5.643771E-02 2.43334 Parameter standard deviation: 3355.94 67.1888 8.829943E-02 8.784031E-02 8.784031E-02 8.62855 -------------------------------------------------------------------------------- After 42 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 12046.0 1004.55 0.234245 0.974530 2.547037E-02 2.188122E-04 Mean perturbed parameters: 9283.39 1026.70 0.232231 0.944300 5.570040E-02 2.37541 Parameter standard deviation: 3329.00 66.3659 8.730606E-02 8.678187E-02 8.678187E-02 8.52268 -------------------------------------------------------------------------------- After 43 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 12418.9 1037.47 0.206393 0.945408 5.459151E-02 3.505964E-05 Mean perturbed parameters: 9356.31 1026.95 0.231630 0.944325 5.567461E-02 2.32017 Parameter standard deviation: 3308.93 65.8041 8.626128E-02 8.578442E-02 8.578442E-02 8.42060 -------------------------------------------------------------------------------- After 44 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 9991.57 1006.25 0.201133 0.963661 3.633881E-02 1.032108E-03 Mean perturbed parameters: 9370.74 1026.48 0.230937 0.944765 5.523516E-02 2.26746 Parameter standard deviation: 3270.25 65.0383 8.526047E-02 8.478117E-02 8.478117E-02 8.32211 -------------------------------------------------------------------------------- After 45 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10465.0 1026.41 0.205285 0.959333 4.066727E-02 1.407048E-03 Mean perturbed parameters: 9395.06 1026.47 0.230367 0.945089 5.491143E-02 2.21711 Parameter standard deviation: 3233.41 64.4035 8.428775E-02 8.381382E-02 8.381382E-02 8.22700 -------------------------------------------------------------------------------- After 46 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10464.5 1166.24 0.209760 0.997286 2.714019E-03 31.1595 Mean perturbed parameters: 9418.31 1029.51 0.229919 0.946223 5.377670E-02 2.84629 Parameter standard deviation: 3197.80 68.2485 8.334607E-02 8.303680E-02 8.303680E-02 9.36778 -------------------------------------------------------------------------------- After 47 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 6368.16 1024.50 0.192930 0.902628 9.737191E-02 2.723335E-03 Mean perturbed parameters: 9353.41 1029.41 0.229132 0.945296 5.470426E-02 2.78579 Parameter standard deviation: 3209.76 67.5869 8.246858E-02 8.260674E-02 8.260674E-02 9.26540 -------------------------------------------------------------------------------- After 48 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 9930.37 1057.53 0.190305 0.971688 2.831157E-02 5.053453E-04 Mean perturbed parameters: 9365.43 1029.99 0.228323 0.945846 5.415441E-02 2.72776 Parameter standard deviation: 3175.50 67.3596 8.163138E-02 8.173355E-02 8.173355E-02 9.16630 -------------------------------------------------------------------------------- After 49 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 9716.26 999.196 0.193541 0.965263 3.473721E-02 1.558093E-04 Mean perturbed parameters: 9372.59 1029.36 0.227613 0.946242 5.375814E-02 2.67210 Parameter standard deviation: 3142.68 66.6552 8.080681E-02 8.087847E-02 8.087847E-02 9.07031 -------------------------------------------------------------------------------- After 50 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10225.6 1036.71 0.189480 0.972756 2.724351E-02 6.383753E-04 Mean perturbed parameters: 9389.65 1029.51 0.226851 0.946772 5.322785E-02 2.61867 Parameter standard deviation: 3110.52 66.1618 8.002587E-02 8.006161E-02 8.006161E-02 8.97728 -------------------------------------------------------------------------------- After 51 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 13616.1 1062.83 4.186116E-02 0.998722 1.278236E-03 8.31128 Mean perturbed parameters: 9472.52 1030.16 0.223224 0.947791 5.220923E-02 2.73029 Parameter standard deviation: 3119.68 66.0664 8.266671E-02 7.941978E-02 7.941978E-02 8.96445 -------------------------------------------------------------------------------- After 52 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 8429.39 1014.30 0.192648 0.955197 4.480267E-02 1.675674E-04 Mean perturbed parameters: 9452.46 1029.86 0.222636 0.947933 5.206679E-02 2.67778 Parameter standard deviation: 3097.55 65.4396 8.188369E-02 7.864447E-02 7.864447E-02 8.87612 -------------------------------------------------------------------------------- After 53 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 11355.2 1030.46 0.197352 0.961590 3.841033E-02 2.444622E-04 Mean perturbed parameters: 9488.36 1029.87 0.222159 0.948191 5.180913E-02 2.62726 Parameter standard deviation: 3072.74 64.9306 8.110821E-02 7.788477E-02 7.788477E-02 8.79036 -------------------------------------------------------------------------------- After 54 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 9974.79 1017.34 0.203466 0.966007 3.399287E-02 3.006341E-04 Mean perturbed parameters: 9497.37 1029.64 0.221812 0.948521 5.147920E-02 2.57862 Parameter standard deviation: 3043.64 64.3513 8.034280E-02 7.714779E-02 7.714779E-02 8.70704 -------------------------------------------------------------------------------- After 55 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 9452.40 1016.22 0.210719 0.965187 3.481311E-02 3.440797E-04 Mean perturbed parameters: 9496.55 1029.39 0.221611 0.948824 5.117618E-02 2.53174 Parameter standard deviation: 3016.53 63.7837 7.959582E-02 7.643082E-02 7.643082E-02 8.62604 -------------------------------------------------------------------------------- After 56 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10163.8 984.389 0.198909 0.943399 5.660108E-02 1.290334E-03 Mean perturbed parameters: 9508.47 1028.59 0.221205 0.948727 5.127305E-02 2.48655 Parameter standard deviation: 2989.00 63.2439 7.888030E-02 7.577788E-02 7.577788E-02 8.54726 -------------------------------------------------------------------------------- After 57 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 9276.29 1065.94 0.179237 0.931980 6.801965E-02 6.083963E-04 Mean perturbed parameters: 9504.40 1029.25 0.220469 0.948433 5.156685E-02 2.44294 Parameter standard deviation: 2964.12 63.2633 7.827295E-02 7.521094E-02 7.521094E-02 8.47061 -------------------------------------------------------------------------------- After 58 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 7764.27 984.198 0.204667 0.914805 8.519478E-02 2.772398E-04 Mean perturbed parameters: 9474.39 1028.47 0.220197 0.947853 5.214664E-02 2.40082 Parameter standard deviation: 2953.92 62.7483 7.758529E-02 7.481861E-02 7.481861E-02 8.39597 -------------------------------------------------------------------------------- After 59 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 1026.99 1200.00 0.368857 0.998033 1.967412E-03 14.6892 Mean perturbed parameters: 9331.22 1031.38 0.222716 0.948704 5.129615E-02 2.60910 Parameter standard deviation: 3160.25 67.4389 7.973138E-02 7.431512E-02 7.431512E-02 8.54384 -------------------------------------------------------------------------------- After 60 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10076.3 1001.43 0.206217 0.927643 7.235729E-02 1.833700E-04 Mean perturbed parameters: 9343.64 1030.88 0.222441 0.948353 5.164716E-02 2.56562 Parameter standard deviation: 3133.35 66.8650 7.905355E-02 7.382450E-02 7.382450E-02 8.47112 -------------------------------------------------------------------------------- After 61 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 13402.2 1064.64 0.118054 0.992062 7.937988E-03 11.1539 Mean perturbed parameters: 9410.17 1031.43 0.220730 0.949069 5.093062E-02 2.70641 Parameter standard deviation: 3136.65 66.8027 7.926357E-02 7.330425E-02 7.330425E-02 8.52276 -------------------------------------------------------------------------------- After 62 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10043.0 1019.60 0.182804 0.952264 4.773582E-02 5.248003E-04 Mean perturbed parameters: 9420.38 1031.24 0.220118 0.949121 5.087909E-02 2.66277 Parameter standard deviation: 3110.84 66.2928 7.868191E-02 7.271338E-02 7.271338E-02 8.45261 -------------------------------------------------------------------------------- After 63 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 13903.0 1174.11 0.257898 0.999095 9.053341E-04 16.3335 Mean perturbed parameters: 9491.53 1033.51 0.220718 0.949914 5.008586E-02 2.87976 Parameter standard deviation: 3123.69 69.3091 7.829296E-02 7.227190E-02 7.227190E-02 8.63697 -------------------------------------------------------------------------------- After 64 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 4890.68 1181.65 0.348238 0.999846 1.544156E-04 5.33319 Mean perturbed parameters: 9419.64 1035.82 0.222710 0.950694 4.930568E-02 2.91810 Parameter standard deviation: 3166.92 72.4015 7.962959E-02 7.184794E-02 7.184794E-02 8.59445 -------------------------------------------------------------------------------- After 65 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10214.1 1030.09 0.204651 0.963254 3.674614E-02 9.826837E-05 Mean perturbed parameters: 9431.87 1035.73 0.222433 0.950888 4.911245E-02 2.87320 Parameter standard deviation: 3142.13 71.9218 7.900678E-02 7.128445E-02 7.128445E-02 8.52704 -------------------------------------------------------------------------------- After 66 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 14623.4 1043.49 0.154950 0.997974 2.025525E-03 4.86567 Mean perturbed parameters: 9510.53 1035.85 0.221410 0.951601 4.839902E-02 2.90339 Parameter standard deviation: 3168.47 71.5551 7.868126E-02 7.086856E-02 7.086856E-02 8.48269 -------------------------------------------------------------------------------- After 67 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 11395.9 1001.85 0.186213 0.917651 8.234857E-02 1.353763E-03 Mean perturbed parameters: 9538.66 1035.34 0.220885 0.951094 4.890573E-02 2.86008 Parameter standard deviation: 3148.56 71.0110 7.813263E-02 7.054866E-02 7.054866E-02 8.41818 -------------------------------------------------------------------------------- After 68 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 8495.40 1033.88 0.218526 0.950370 4.963036E-02 1.052618E-03 Mean perturbed parameters: 9523.32 1035.32 0.220850 0.951084 4.891638E-02 2.81803 Parameter standard deviation: 3130.94 70.5892 7.755636E-02 7.003661E-02 7.003661E-02 8.35513 -------------------------------------------------------------------------------- After 69 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 13784.8 1050.43 0.203706 0.982711 1.728881E-02 1.346856E-04 Mean perturbed parameters: 9585.08 1035.54 0.220602 0.951542 4.845801E-02 2.77720 Parameter standard deviation: 3140.20 70.3178 7.698651E-02 6.956173E-02 6.956173E-02 8.29346 -------------------------------------------------------------------------------- After 70 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 13449.0 1024.27 0.206060 0.966652 3.334823E-02 3.016350E-05 Mean perturbed parameters: 9640.28 1035.38 0.220394 0.951758 4.824216E-02 2.73752 Parameter standard deviation: 3143.69 69.8596 7.642734E-02 6.905739E-02 6.905739E-02 8.23315 -------------------------------------------------------------------------------- After 71 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10042.3 992.957 0.221949 0.947493 5.250738E-02 1.576155E-04 Mean perturbed parameters: 9645.94 1034.78 0.220416 0.951698 4.830223E-02 2.69897 Parameter standard deviation: 3121.16 69.3666 7.589561E-02 6.858669E-02 6.858669E-02 8.17413 -------------------------------------------------------------------------------- After 72 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 1000.01 1200.00 0.652197 1.00000 5.265368E-08 37.3906 Mean perturbed parameters: 9525.86 1037.08 0.226413 0.952369 4.763137E-02 3.18080 Parameter standard deviation: 3280.96 72.7891 9.190959E-02 6.824508E-02 6.824508E-02 9.25020 -------------------------------------------------------------------------------- After 73 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 9505.40 1024.49 0.196159 0.946017 5.398265E-02 3.614646E-04 Mean perturbed parameters: 9525.58 1036.91 0.225998 0.952282 4.771837E-02 3.13723 Parameter standard deviation: 3258.79 72.3321 9.128136E-02 6.779829E-02 6.779829E-02 9.18574 -------------------------------------------------------------------------------- After 74 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 15586.1 1054.13 0.198104 0.992164 7.836050E-03 1.776363E-04 Mean perturbed parameters: 9607.48 1037.14 0.225621 0.952821 4.717942E-02 3.09484 Parameter standard deviation: 3300.02 72.0975 9.066272E-02 6.742009E-02 6.742009E-02 9.12260 -------------------------------------------------------------------------------- After 75 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 1363.85 1199.79 0.354647 0.999995 4.568169E-06 8.31836 Mean perturbed parameters: 9497.56 1039.31 0.227342 0.953450 4.655042E-02 3.16448 Parameter standard deviation: 3430.56 75.2230 9.162908E-02 6.710260E-02 6.710260E-02 9.11221 -------------------------------------------------------------------------------- After 76 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 9870.25 1002.25 0.208465 0.923184 7.681582E-02 4.341678E-04 Mean perturbed parameters: 9502.47 1038.82 0.227093 0.953051 4.694865E-02 3.12285 Parameter standard deviation: 3407.70 74.7198 9.101618E-02 6.681038E-02 6.681038E-02 9.05126 -------------------------------------------------------------------------------- After 77 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10228.2 1026.82 0.201703 0.965504 3.449552E-02 3.277867E-04 Mean perturbed parameters: 9511.89 1038.66 0.226764 0.953213 4.678692E-02 3.08230 Parameter standard deviation: 3385.25 74.2829 9.041913E-02 6.637012E-02 6.637012E-02 8.99151 -------------------------------------------------------------------------------- After 78 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10035.8 1052.38 0.177506 0.942804 5.719560E-02 8.076640E-04 Mean perturbed parameters: 9518.61 1038.84 0.226132 0.953080 4.692037E-02 3.04279 Parameter standard deviation: 3363.20 74.0253 8.990108E-02 6.597702E-02 6.597702E-02 8.93294 -------------------------------------------------------------------------------- After 79 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 13943.5 1198.73 1.150430E-02 0.999325 6.752969E-04 14.6573 Mean perturbed parameters: 9574.62 1040.86 0.223415 0.953665 4.633499E-02 3.18981 Parameter standard deviation: 3370.13 76.8610 9.207552E-02 6.568319E-02 6.568319E-02 9.02932 -------------------------------------------------------------------------------- After 80 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 11586.3 1029.79 0.193920 0.963418 3.658151E-02 4.094544E-04 Mean perturbed parameters: 9599.77 1040.72 0.223047 0.953787 4.621307E-02 3.14994 Parameter standard deviation: 3353.04 76.4387 9.150634E-02 6.526619E-02 6.526619E-02 8.97199 -------------------------------------------------------------------------------- After 81 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 20000.0 1199.98 0.372022 0.999998 2.003659E-06 4.34989 Mean perturbed parameters: 9728.17 1042.69 0.224886 0.954357 4.564256E-02 3.16476 Parameter standard deviation: 3511.88 79.1308 9.274449E-02 6.499034E-02 6.499034E-02 8.92899 -------------------------------------------------------------------------------- After 82 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 9054.93 1008.90 0.208840 0.935181 6.481901E-02 3.075805E-04 Mean perturbed parameters: 9719.96 1042.28 0.224690 0.954124 4.587642E-02 3.12617 Parameter standard deviation: 3491.98 78.6450 9.217021E-02 6.466068E-02 6.466068E-02 8.87370 -------------------------------------------------------------------------------- After 83 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 9452.09 1014.08 0.197268 0.962631 3.736889E-02 1.139768E-03 Mean perturbed parameters: 9716.73 1041.94 0.224360 0.954226 4.577392E-02 3.08852 Parameter standard deviation: 3471.31 78.1761 9.161541E-02 6.426520E-02 6.426520E-02 8.81943 -------------------------------------------------------------------------------- After 84 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10765.1 1002.51 0.211059 0.950027 4.997348E-02 1.128080E-04 Mean perturbed parameters: 9729.21 1041.47 0.224201 0.954176 4.582392E-02 3.05175 Parameter standard deviation: 3451.16 77.7038 9.106216E-02 6.389222E-02 6.389222E-02 8.76614 -------------------------------------------------------------------------------- After 85 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10809.4 1195.19 0.366322 1.00000 4.351001-108 5.29406 Mean perturbed parameters: 9741.92 1043.28 0.225873 0.954715 4.528481E-02 3.07813 Parameter standard deviation: 3431.49 80.0754 9.213464E-02 6.364048E-02 6.364048E-02 8.73293 -------------------------------------------------------------------------------- After 86 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 8087.87 972.504 0.193562 0.974264 2.573613E-02 5.377813E-04 Mean perturbed parameters: 9722.68 1042.46 0.225498 0.954942 4.505750E-02 3.04234 Parameter standard deviation: 3418.06 79.6656 9.160609E-02 6.327727E-02 6.327727E-02 8.68141 -------------------------------------------------------------------------------- After 87 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 13390.3 1028.42 0.191508 0.987357 1.264273E-02 5.213802E-04 Mean perturbed parameters: 9764.84 1042.29 0.225107 0.955315 4.468492E-02 3.00738 Parameter standard deviation: 3416.86 79.2538 9.109114E-02 6.296411E-02 6.296411E-02 8.63079 -------------------------------------------------------------------------------- After 88 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 7770.16 960.780 0.199785 0.959241 4.075892E-02 4.554669E-05 Mean perturbed parameters: 9742.17 1041.37 0.224819 0.955360 4.464030E-02 2.97321 Parameter standard deviation: 3406.16 78.9185 9.057134E-02 6.260235E-02 6.260235E-02 8.58104 -------------------------------------------------------------------------------- After 89 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 14565.4 1076.25 0.208403 0.936720 6.327964E-02 2.057254E-04 Mean perturbed parameters: 9796.37 1041.76 0.224635 0.955150 4.484973E-02 2.93980 Parameter standard deviation: 3420.39 78.8711 9.005527E-02 6.230760E-02 6.230760E-02 8.53215 -------------------------------------------------------------------------------- After 90 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 4697.59 1197.05 0.326490 0.999752 2.480359E-04 7.09970 Mean perturbed parameters: 9739.71 1043.48 0.225767 0.955646 4.435416E-02 2.98602 Parameter standard deviation: 3448.58 81.1165 9.041192E-02 6.208039E-02 6.208039E-02 8.51739 -------------------------------------------------------------------------------- After 91 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 14913.9 1077.94 0.190317 0.913917 8.608301E-02 3.092363E-04 Mean perturbed parameters: 9796.57 1043.86 0.225377 0.955187 4.481272E-02 2.95321 Parameter standard deviation: 3467.07 81.0648 8.992946E-02 6.194902E-02 6.194902E-02 8.46994 -------------------------------------------------------------------------------- After 92 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 10851.8 984.486 0.234051 0.958229 4.177098E-02 5.016231E-04 Mean perturbed parameters: 9808.04 1043.22 0.225471 0.955220 4.477966E-02 2.92112 Parameter standard deviation: 3448.92 80.6382 8.947298E-02 6.160955E-02 6.160955E-02 8.42327 -------------------------------------------------------------------------------- After 93 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 8355.71 1003.74 0.187549 0.963024 3.697573E-02 3.581479E-04 Mean perturbed parameters: 9792.43 1042.79 0.225063 0.955304 4.469574E-02 2.88971 Parameter standard deviation: 3434.81 80.1990 8.901310E-02 6.127381E-02 6.127381E-02 8.37737 -------------------------------------------------------------------------------- After 94 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 6655.03 987.495 0.190345 0.916985 8.301475E-02 3.806402E-04 Mean perturbed parameters: 9759.05 1042.21 0.224694 0.954897 4.510339E-02 2.85897 Parameter standard deviation: 3434.67 79.7801 8.855404E-02 6.112821E-02 6.112821E-02 8.33221 -------------------------------------------------------------------------------- After 95 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 8504.87 1135.74 0.185169 0.790665 0.209335 1.142300E-02 Mean perturbed parameters: 9745.85 1043.19 0.224278 0.953168 4.683215E-02 2.82900 Parameter standard deviation: 3420.19 80.5514 8.811562E-02 6.334075E-02 6.334075E-02 8.28777 -------------------------------------------------------------------------------- After 96 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 9219.97 988.681 0.218934 0.949993 5.000681E-02 6.683324E-05 Mean perturbed parameters: 9740.37 1042.62 0.224222 0.953135 4.686522E-02 2.79953 Parameter standard deviation: 3403.28 80.1373 8.765673E-02 6.302016E-02 6.302016E-02 8.24403 -------------------------------------------------------------------------------- After 97 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 11161.9 1001.56 0.183631 0.960537 3.946336E-02 2.896139E-04 Mean perturbed parameters: 9755.03 1042.20 0.223804 0.953211 4.678891E-02 2.77067 Parameter standard deviation: 3387.32 79.7189 8.723698E-02 6.269148E-02 6.269148E-02 8.20098 -------------------------------------------------------------------------------- After 98 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 12249.1 1000.20 0.203401 0.965954 3.404584E-02 1.072442E-03 Mean perturbed parameters: 9780.47 1041.77 0.223596 0.953341 4.665888E-02 2.74241 Parameter standard deviation: 3377.03 79.3070 8.678790E-02 6.236833E-02 6.236833E-02 8.15860 -------------------------------------------------------------------------------- After 99 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 11112.7 1001.91 0.215198 0.950443 4.955677E-02 6.358213E-05 Mean perturbed parameters: 9793.93 1041.37 0.223511 0.953312 4.668815E-02 2.71471 Parameter standard deviation: 3361.39 78.9014 8.634635E-02 6.206182E-02 6.206182E-02 8.11687 -------------------------------------------------------------------------------- After 100 successful perturbations: P_bar T_K C_O2 Cpx Gt OBJF Central model parameters: 10076.4 1001.62 0.208853 0.962780 3.722013E-02 3.802121E-07 Perturbed central model parameter: 12781.1 1037.80 0.230278 0.962586 3.741352E-02 8.140671E-05 Mean perturbed parameters: 9823.80 1041.33 0.223579 0.953405 4.659540E-02 2.68757 Parameter standard deviation: 3355.39 78.5861 8.593613E-02 6.174758E-02 6.174758E-02 8.07577